lewis structures of organic molecules

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1 1 Lewis Structures of Organic Molecules Dr. C. Yau Fall 2013

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Lewis Structures of Organic Molecules. Dr. C. Yau Fall 2013. 1. 1. Organic Molecules. Organic chemistry is a study of compounds containing carbon . In addition, they contain mostly H, O and some N, S and P, and other elements. Those containing metals are said to be “organometallic.” - PowerPoint PPT Presentation

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Page 1: Lewis Structures of Organic Molecules

111

Lewis Structuresof Organic Molecules

Dr. C. YauFall 2013

Page 2: Lewis Structures of Organic Molecules

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Organic MoleculesOrganic chemistry is a study of compounds

containing carbon.In addition, they contain mostly H, O and

some N, S and P, and other elements.Those containing metals are said to be

“organometallic.”Hydrocarbons are compounds containing

only H and C.They are nonpolar because they contain onlyC-C and C-H bonds, which are nonpolar.

Page 3: Lewis Structures of Organic Molecules

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Hydrocarbons

CH4

C2H6

C3H8

CH H

H

H

CH

H

H

C HH

H

CH

H

HC

C

H

HH

H

H

H C H

H

H

H C C C H

H

H

H

H

H

H

H C C H

H

H

H

H

Remember that C with 4 bonds is tetrahedral.

Page 4: Lewis Structures of Organic Molecules

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Various Representations of Organic Molecules

Abbreviated

Line Drawings

Page 5: Lewis Structures of Organic Molecules

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Isomers of Hydrocarbons

Beyond C3H8, there are isomers.

For example C5H12 has 3 isomers.

CH3CH2CH2CH2CH3

CH3CHCH2CH3

CH3

CH3CCH3

CH3

CH3

Page 6: Lewis Structures of Organic Molecules

Classification of Organic Compounds

Organic compounds are classified by the “functional group” that replaces one or more of the H atoms in a hydrocarbon.Substitution of a H with –OH transforms it into an alcohol.For example, replacing one H with –OH in methane makes it methyl alcohol (or methanol).

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Page 7: Lewis Structures of Organic Molecules

Alcohols

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H C H

H

HH C OH

H

H

C C H

H

H

H

H

HC C OH

H

H

H

H

H

methane methyl alcohol

ethane ethyl alcohol (in booze)

Page 8: Lewis Structures of Organic Molecules

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Alcohols Contain -OH....but don’t call them hydroxides!!!Hydroxides are only for ionic cmpds.

They contain O-H and C-O bonds, which are polar.

Page 9: Lewis Structures of Organic Molecules

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Carboxylic AcidsThese contain –COOH group or –CO2H

Learn this structure:

Formic acid HCOOH or HCO2H

CO

O H..:

: :

H CO

O H..:

: :

Page 10: Lewis Structures of Organic Molecules

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MEMORIZE THIS!

Acetic acid CH3COOH or CH3CO2H

CO

O H

CH

H

H ..:

: :

Is it polar?

Page 11: Lewis Structures of Organic Molecules

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Amines Contain N

CH3NH2

CH3CH2NH2

CH3NHCH3

CH3 NHH

CH3CH2 NHH

CH3 N HCH3

NH2

(CH3)2NH

..

..

..

They typically have an unpleasant odor, some with a fishy smell.

Page 12: Lewis Structures of Organic Molecules

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Acetone (fingernail polish remover)

Acetone belongs in class called ketones.Memorize the structure of acetone.It is a very common organic solvent.CH3COCH3 or (CH3)2CO

CH3C CH3

O: :

Page 13: Lewis Structures of Organic Molecules

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BenzeneBenzene is another very common organic

solvent.

What is its molecular formula?