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REPUBLIC OF TURKEY GOVERNORSHIP OF SAMSUN PROVINCIAL HEALTH DIRACTORATE SAMSUN PUBLIC HEALTH LABORATORY ANALYSIS REPORT

F81/SHSL/03 Report Printing Date : 07.09.2020 Address: Adalet Mahallesi Mevlana Cad. No:66 55070 İlkadım / SAMSUN Tel: 03622348950 Fax: 03622303772 This document has been signed with secure electronic signature pursuant to the electronic signature law no. 5070.

(logo: TÜRKAK) Test TS EN ISO/IEC *7025

AB-0834-T

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Ref. Date and Number 19.08.2020 / 2672 AB-0834-T Date/Time of Sampling 20.08.2020 / 10:30 Date/Time of Sample Incoming to HSL (Lab) 20.08.2020 / 16:12 2020-1960-1 Protocol No / Sample Barcode No 2020-1960 - 1 / 11161816 CSBYS No 118715 09.20 Report Page Number 6 Person/Company/Entity Sending the Sample ERZİNCAN PROVINCIAL HEALTH DIRECTORATE Sampling Address AKTOPRAK MAHALLESİ ERZURUM CADDESİ NO:91 - ERZİNCAN Sample Monitoring Address KIZILAY İÇECEK SAN. VE TİC. ERZİNCAN BRANCH WATER OPERATION

FILLING SITE Sample Incoming Reason INSPECTION MONITORING *CHEMICAL AND MICROBIOLOGICAL

ANALYSES Sample Receival Date-Time / Incoming Reason 21.08.2020 - 13:19 Filling Site Sample Group WATER ANALYSES Sample Type / Name / Brand / Manufacturer NATURAL MINERAL WATER

--- KIZILAY KIZILAY İÇECEK

SANAYİ VE TİCARET A.Ş.

Sample Packaging Type/ Label/ Amount Original Package + Glass Bottle

LABELED 200cc x 60

Sample Mnf.Date/ Exp.Date/ Batch No / Serial No 20.08.2020 20.11.2021 PN233 0944 Seal Status / Minute-Contract Date/No SEALED ... ... ... Invoiced To KIZILAY İÇECEK SANAYİ VE TİCARET A.Ş. Receipt Date and No / Voucher Date and No ______ . ______ ... Declr. Date-No /Import Pre-Approval Doc. Date-No ____________________________ Condition of the Sample Suitable for Analysis Sample Information ... ... Analysis Start/End Date 21.08.2020 13:20 04.09.2020 13:55 Reporting Date 05.09.2020 14:26

CHEMICAL ANALYSES Analyses Unit Method Limit of Quantification

(LOQ) Legislation Limit Result

Carbonate mg/L Spectrophotometric # 0 MICROBIOLOGICAL ANALYSES Analyses Unit Method Limit of Quantification


*Total germ count at 22 °C cfu/mL TS EN ISO 6222 100 1 Parasite pcs/5 L Internal method 0 0 Pathogen Staphylococ. cfu/100mL AFNOR NFT 90-412 0 0 *Pseudomonas aeruginosa cfu/250mL TS EN ISO 16266 0 0 *Sulfite Reducing Spore- formingAnaerobic Bacteria

cfu/50mL TS 8020 EN 26461-2 0 0

*Escherichia coli cfu/250mL TS EN ISO 9308-1 0 0




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Ref. Date and No 19.08.2020 / 2672 AB-0834-T Date/Time of Sampling 20.08.2020 / 10:30 Date/Time of Sample Incoming to HSL (Lab) 20.08.2020 / 16:12 2020-1960-1 Protocol No / Sample Barcode No 2020-1960 - 1 / 11161816 CSBYS No 118715 09.20 Report Page Number 6

MICROBIOLOGICAL ANALYSES Analyses Unit Method Limit of Quantification


Salmonella Spp. cfu/L TS EN ISO 19250 0 Not Found *Total germ count at 37°C cfu/mL TS EN ISO 6222 20 1 *Coliform Bacteria cfu/250mL AFNOR NFT 9308-1 0 0 *Enterococ./ Fecal Streptococ. cfu/250mL TS EN ISO 7899-2 0 0



Turbidity (Physical) Physical conforming Odor (Physical) Physical conforming Sulphur mg/L Spectrophotometric 0 Color (Physical) Physical conforming Taste (Physical) Physical conforming Bicarbonate TITRIMETRIC # 1475 Oxidizability mg/L TITRIMETRIC 2.56 Cyanide Spectrophotometric 0.01 0.07 Not Found Nitrate mg/L TS EN ISO 10304-1 0.15 50 0.25 Magnesium mg/L TS EN ISO 14911 0.1 312 Sulfate mg/L TS EN ISO 10304-1 0.15 1.38 *Phosphate mg/L TS EN ISO 10304-1 0.3 0.31 Sodium mg/L TS EN ISO 14911 0.4 114 Calcium mg/L TS EN ISO 14911 1 47.0 Potassium mg/L TS EN ISO 14911 1 3.92 Chloride mg/L TS EN ISO 10304-1 0.15 150 Nitrite mg/L TS EN ISO 10304-1 0.02 0.1 Not Found Ammonium mg/L TS EN ISO 14911 0.01 0.79 Fluoride mg/L TS EN ISO 10304-1 0.03 5 0.060 *Copper mg/L EPA 200.8 0.002 1 Not Found



Address: Adalet Mahallesi Mevlana Cad. No:66 55070 İlkadım / SAMSUN Tel: 03622348950 Fax: 03622303772 This document has been signed with secure electronic signature pursuant to the electronic signature law no. 5070.

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*Arsenic mg/L EPA 200.8 0.002 0.01 Not Found

*Aluminum mg/L EPA 200.8 2 200 5.53

Borate mg/L EPA 200.8 30 9.16

*Lead mg/L EPA 200.8 0.002 0.01 Not Found

*Cadmium mg/L EPA 200.8 0.002 0.003 Not Found

*Mercury mg/L EPA 200.8 0.00015 0.001 Not Found

*Barium mg/L EPA 200.8 0.002 1 0.032

*Nickel mg/L EPA 200.8 0.002 0.02 Not Found

*Chrome mg/L EPA 200.8 0.002 0.05 0.011

*Antimony mg/L EPA 200.8 0.002 0.005 Not Found

*Manganese mg/L EPA 200.8 0.002 0.5 0.139

*Iron mg/L EPA 200.8 0.002 0.046

*Selenium mg/L EPA 200.8 0.002 0.01 0.007

Organochlorine Compounds Analyses Unit Method Limit of Quantification


Alpha-Endosulfan mg/L Internal Method 0.00001 0.0001 Not Found

Total DDT (op-DDT, pp-DDT, pp-DDD, pp-DDE)

mg/L Internal Method 0.00001 0.0001 Not Found

HCB mg/L Internal Method 0.00001 0.0001 Not Found

Dieldrin mg/L Internal Method 0.00001 0.00003 Not Found

Gamma - HCH (Lindane) mg/L Internal Method 0.00001 0.0001 Not Found

Heptachlor Epoxide (Endo) mg/L Internal Method 0.00001 0.00003 Not Found

Alpha-HCH (BCH) mg/L Internal Method 0.00001 0.0001 Not Found F81/SHSL/03 Report Printing Date :07.09.2020




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Organochlorine Compounds Analyses Unit Method Limit of Quantification


Aldrin mg/L Internal Method 0.00001 0.00003 Not Found

Beta-Endosulfan mg/L Internal Method 0.00001 0.0001 Not Found

Heptachlor mg/L Internal Method 0.00001 0.00003 Not Found

Organophosphorus Compounds Analyses Unit Method Limit of Quantification


Azinphos-methyl mg/L Internal Method 0.00001 0.0001 Not Found

Chlorpyriphos-ethyl mg/L Internal Method 0.00001 0.0001 Not Found

Ethion mg/L Internal Method 0.00001 0.0001 Not Found

Parathion-ethyl mg/L Internal Method 0.00001 0.0001 Not Found

Disulfoton mg/L Internal Method 0.00001 0.0001 Not Found

Diazinon mg/L Internal Method 0.00001 0.0001 Not Found

Parathion-methyl mg/L Internal Method 0.00001 0.0001 Not Found

Azinphos-ethyl mg/L Internal Method 0.00001 0.0001 Not Found

Chlorpyripho s -methyl mg/L Internal Method 0.00001 0.0001 Not Found

Demethon (O+S) mg/L Internal Method 0.00001 0.0001 Not Found

Malathion mg/L Internal Method 0.00001 0.0001 Not Found

Carbamates Analyses Unit Method Limit of Quantification


Methiocarb mg/L Internal / LCMSMS Not Found

Aldicarb mg/L Internal / LCMSMS Not Found




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Carbamates Analyses Unit Method Limit of Quantification


Aldicarb-sulfoxide mg/L Internal / LCMSMS Not Found

Oxamyl mg/L Internal / LCMSMS Not Found

Carbofuran mg/L Internal / LCMSMS Not Found

Carbaryl mg/L Internal / LCMSMS Not Found

1-Naphtol mg/L Internal / LCMSMS Not Found

Aldicarb-sulfane mg/L Internal / LCMSMS Not Found

Carbofuran-3 -hydroxy mg/L Internal / LCMSMS Not Found

Propoxur mg/L Internal / LCMSMS Not Found

Methomyl mg/L Internal / LCMSMS Not Found Polycyclic Aromatic Hydrocarbons

Analyses Unit Method Limit of Quantification (LOQ)

Legislation Limit Result

*Benzo (b) fluoranthene mg/L Internal / HPLC Not Found

*Benzo (k) fluoranthene mg/L Internal / HPLC Not Found

*Benzo (ghi) perylene mg/L Internal / HPLC Not Found

*Fluoranthene mg/L Internal / HPLC Not Found

*Indeno (1.2.3 -cd) pyrene mg/L Internal / HPLC Not Found

*Benzo (a) pyrene mg/L Internal / HPLC Not Found




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Ref. Date and No 19.08.2020 / 2672 AB-0834-T Date/Time of Sampling 20.08.2020 / 10:30 Date/Time of Sample Incoming to HSL (Lab) 20.08.2020 / 16:12 2020-1960-1 Protocol No / Sample Barcode No 2020-1960 - 1 /11161816 CSBYS No 118715 09.20 Report Page Number 6

Evaluation: The results for the tested parameters are conforming as per Regulation on Natural Mineral Waters published in the Offıcial Gazette dated 01.12.2004 no 25657.

Remarks: - The results are evaluated as per Regulation on Natural Mineral Waters published in the Offıcial Gazette dated 01.12.2004 no 25657. - The analysis results written bold are out of the relevant legislation limit. - The sample was no taken by us, but received in accordance with SAMSUN PUBLIC HEALTH LABORATORY Sample Acceptance Criteria, based on the information provided by the customer.- The analyses on special request were performed based on the information provided by the customer, and evaluated for conformity as per the applicable regulation. - The results and opinions in this report apply to the above-mentioned and tested sample in its condition when received. No section of this report can be used separately or partially, and the report cannot be reproduced without the permission of SAMSUN PUBLIC HEALTH LABORATORY. Unsigned reports are invalid. Reports of sample analyses on special request cannot be used for judicial andadministrative procedures and for advertisement purposes. - Extended measurement uncertainties are stated when requested by the customer or required by legal legislations. - TKEDY: Acceptable for consumers or no abnormal change - cfu: Colony forming unit - Tests marked with * are within the scope of accreditation. - When not requested by the customer or required by legal legislations, the analytical results are reported as x. “x” indicates the analytical result. - When the customer requests measurement uncertainty, the analytical results are reported as x=Ux, where x refers to the analytical result and U refers to extended measurement uncertainty. TGHSLDB (Consumer Safety and Public Health Laboratories Department) Decision Rule: - In case the customer requests measurement uncertainty, the result found for the relevant parameter within the confidence interval determined by the laboratory (k=2, 95%) is

considered “non-conforming” if above the upper legislation limit when the measurement uncertainty is added to the result, or if below the lower legislation limit when the measurement uncertainty issubtracted from the result. The results that are within or equal to the specified legislation limits are considered “conforming”.

Water Microbiology Laboratory Function Supervisor Ümran ALBAYRAK Biologist

05.09.2020

Environmental Sciences Laboratory Function Supervisor HASAN ALTAY Food Engineer

05.09.2020 Laboratory Supervisor DUYGU SAVCI Spec. Dr. 05.09.2020

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