material safety data sheet - sd pickups · ki nco tac serious skin contact inh al tion serious...
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Secondary Alcohol Ethoxylate
Alkyloxypolyethyleneoxyethanol
C12-14-H25-29-O(C2-H4-O)xH
Polyethylene Glycol Ethers
WZ5600000
84133-50-6
T1261
Not available.
CALL (310) 516-8000
SPECTRUM LABORATORY PRODUCTS INC.14422 S. SAN PEDRO STREETGARDENA, CA 90248
12 0
Material Safety Data SheetNFPA HMIS Personal Protective Equipment
Section 1. Chemical Product and Company Identification
Common Name/Trade Name
CatalogNumber(s).
CAS#
RTECS
CI#
Manufacturer
Synonym
Chemical Name
Chemical Family
IN CASE OF EMERGENCYCHEMTREC (24hr) 800-424-9300
Chemical Formula
Supplier
See Section 15.
Commercial Name(s)
TSCA T S C A 8 ( b ) i n v e n t o r y :S e c o n d a r y a l c o h o lethoxylate; PolyethyleneGlycol
210
Health Hazard
Fire Hazard
Reactivity
Page Number: 1
ORAL (LD50): Acute: 2380 mg/kg [Rat]. >412 mg/kg [Rat] DERMAL (LD50): Acute: 2000 mg/kg [Rabbit]. >14000 mg/kg [Rat]
1) Secondary alcohol ethoxylate 84133-50-6 >972) Polyethylene Glycol 25322-68-3 <3.0
Toxicological Dataon Ingredients
Name
Section 2.Composition and Information on IngredientsExposure Limits
TWA (mg/m3) STEL (mg/m3) CEIL (mg/m3) % by WeightCAS #
Hazardous in case of eye contact (irritant). Slightly hazardous in case of skin contact (irritant, permeator), ofingestion, of inhalation.
CARCINOGENIC EFFECTS: Not available.MUTAGENIC EFFECTS: Not available.TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available.Repeated or prolonged exposure is not known to aggravate medical condition.
Section 3. Hazards IdentificationPotential Acute Health Effects
Potential Chronic HealthEffects
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SD ESSENTIALS1100 N.W. 9TH WAYBATTLE GROUND, WA 98604
Tergitol 15-S-9 Surfactant / Tergitol 15-S-3 Surfactant
Tergitol 15-S-9 Surfactant
Tergitol 15-S-3 SurfactantTergitol 15-S-9 Surfactant
Tergikleen record cleaning concentrate
A Product Of:
Tergitol 15-S-9 Surfactant / Tergitol 15-S-3 Surfactant Page Number: 2
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to anunconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention ifsymptoms appear.
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water forat least 15 minutes. Cold water may be used. Get medical attention.
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient.Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughlyclean shoes before reuse. Get medical attention.
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediatemedical attention.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.Get medical attention.
Not available.
Not available.
Section 4. First Aid MeasuresEye Contact
Skin Contact
Serious Skin Contact
Inhalation
Serious Inhalation
Ingestion
Serious Ingestion
Not available.
May be combustible at high temperature.
These products are carbon oxides (CO, CO2).
CLOSED CUP: 193°C (379.4°F). (Pensky-Martens.) OPE N CUP: 243°C (469.4°F) (Cleveland.).
Not available.
SMALL FIRE: Use DRY chemical powder.LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Slightly flammable to flammable in presence of open flames and sparks, of heat.Non-flammable in presence of shocks.
Not available.
Risks of explosion of the product in presence of mechanical impact: Not available.Risks of explosion of the product in presence of static discharge: Not available.
Not available.
Section 5. Fire and Explosion DataFlammability of the Product
Auto-Ignition Temperature
Flash Points
Flammable Limits
Products of Combustion
Fire Hazards in Presence ofVarious Substances
Explosion Hazards in Presenceof Various Substances
Fire Fighting Mediaand Instructions
Special Remarks onFire Hazards
Special Remarks on ExplosionHazards
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposalcontainer. Finish cleaning by spreading water on the contaminated surface and dispose of according to localand regional authority requirements.
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning byspreading water on the contaminated surface and allow to evacuate through the sanitary system.
Section 6. Accidental Release MeasuresSmall Spill
Large Spill
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do notingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficientventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show thecontainer or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizingagents, acids, alkalis.
Section 7. Handling and StoragePrecautions
Storage
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Tergitol 15-S-9 Surfactant / Tergitol 15-S-3 Surfactant Page Number: 3
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors belowtheir respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to thework-station location.
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.Gloves.
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should beused to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult aspecialist BEFORE handling this product.
Polyethylene Glycol:TWA: 10 (mg/m3) from AIHA [United States] Inhalation
Consult local authorities for acceptable exposure limits.
Section 8. Exposure Controls/Personal ProtectionEngineering Controls
Personal Protection
Personal Protection in Case ofa Large Spill
Exposure Limits
Decomposes >250°C (482°F)
Liquid.
Not available.
7.1 [Neutral.]
Pour point: 9°C (48.2°F)
1.006 (Water = 1)
>1 (Air = 1)
<0 kPa (@ 20°C)
Not available.
Not available.
See solubility in water.
Easily soluble in cold water, hot water. Completely soluble, but some compositions may form gels.
Not available.
Not available.
596 g/mole (approximate)
Mild (Slight.)
Not available.
Colorless. Clear
Section 9. Physical and Chemical PropertiesPhysical state and appearance Odor
Taste
ColorMolecular Weight
pH (1% soln/water)
Boiling Point
Melting Point
Critical Temperature
Specific Gravity
Vapor Pressure
Vapor Density
Volatility
Odor Threshold
Water/Oil Dist. Coeff.
Ionicity (in Water)
Dispersion Properties
Solubility
The product is stable.
Not available.
Reactive with oxidizing agents, acids, alkalis.
Not available.
Normally unreactive. However, avoid strong bases at high temperatures, strong acids, strong oxidizingagents, and materials reactive with hydroxyl compounds.
Not available.
Excess heat, incompatible materials
Section 10. Stability and Reactivity DataStability
Instability Temperature
Conditions of Instability
Incompatibility with varioussubstances
Corrosivity
Special Remarks onReactivity
Special Remarks onCorrosivity
Polymerization Will not occur.
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Tergitol 15-S-9 Surfactant / Tergitol 15-S-3 Surfactant Page Number: 4
Absorbed through skin. Dermal contact. Eye contact.
Acute oral toxicity (LD50): 2380 mg/kg [Rat]. >412 mg/kg [Rat]Acute dermal toxicity (LD50): 2000 mg/kg [Rabbit]. >14000 mg/kg [Rat]
Hazardous in case of eye contact (irritant)Slightly hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.
Not available.
Not available
Acute Potential Health Effects:Skin: May cause mild to moderate skin irritation with redness and itching. May cause drying , and flaking ofthe skin.Eyes: Causes moderate to severe eye irritation and conjunctivitis. Corneal injury may occur.Inhalation: May cause respiratory tract irritation. Short-term harmful health effects are not expected fromvapor generated at ambient (room) temperature do to low volatility. Vapor from heated material may causerespiratory tract irritation. Excess exposure may cause lung injuryIngestion: May cause irritation of the digestive tract (mouth, throat, esophagus, and stomach) with pain ordiscomfort in the abdomen, nausea, vomiting, diarrhea, salivation,Chronic Potential Health Effects:Skin: Repeated or prolonged skin contact is unlikely to result in absorption of harmful amounts.Medical Conditions Aggravated by Exposure: Skin contact may aggravate an existing dermatitis
Not available.
Section 11. Toxicological InformationRoutes of Entry
Toxicity to Animals
Chronic Effects on Humans
Other Toxic Effects onHumans
Special Remarks onToxicity to Animals
Special Remarks onChronic Effects on Humans
Special Remarks on otherToxic Effects on Humans
Ecotoxicity in water (LC50): 4.1 mg/l 48 hours [Daphnia (daphnia)]. 7.3 mg/l 48 hours [Daphnia (daphnia)].3.2 mg/l 96 hours [Fish (Fathead minnow)]. 3.6 mg/l 96 hours [Fish (Fathead minnow)].
Not available.
Possibly hazardous short term degradation products are not likely. However, long term degradation productsmay arise.
The products of degradation are less toxic than the product itself.
Not available.
Section 12. Ecological InformationEcotoxicity
BOD5 and COD
Products of Biodegradation
Toxicity of the Productsof Biodegradation
Special Remarks on theProducts of Biodegradation
Section 13. Disposal ConsiderationsWaste Disposal Waste must be disposed of in accordance with federal, state and local environmental
control regulations.
DOT Classification Not a DOT controlled material (United States).
Not applicable.
Not applicable.
Section 14. Transport Information
Identification
DOT (Pictograms)
Special Provisions forTransport
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Tergitol 15-S-9 Surfactant / Tergitol 15-S-3 Surfactant Page Number: 5
Not available.
01
2210h
Not controlled under WHMIS (Canada). However, it might be classified as WHMISClass D-2B: Material causing other toxic effects (TOXIC).
R36/38- Irritating to eyes and skin.
Section 15. Other Regulatory Information and Pictograms
Other Regulations
Other Classifications WHMIS (Canada)
DSCL (EEC)
HMIS (U.S.A.) Health Hazard
Fire Hazard
Reactivity
National Fire ProtectionAssociation (U.S.A.)
Personal Protection
Health
Flammability
Reactivity
Specific hazard
WHMIS (Canada)(Pictograms)
DSCL (Europe)(Pictograms)
TDG (Canada)(Pictograms)
ADR (Europe)(Pictograms)
Protective Equipment
Vapor respirator. Be sure to use anapproved/certified respirator orequivalent.
Lab coat.
Splash goggles.
Gloves.
Federal and StateRegulations
TSCA 8(b) inventory: Secondary alcohol ethyoxylate; Polyethylene GlycolMinnesota: Polyethylene Glycol
CaliforniaProposition 65Warnings
California prop. 65: This product contains the following ingredients for which the State of California hasfound to cause cancer which would require a warning under the statute: No products were found.California prop. 65: This product contains the following ingredients for which the State of California hasfound to cause birth defects which would require a warning under the statute: No products were found.
S26- In case of contact with eyes, rinseimmediately with plenty of water and seekmedical advice.S37- Wear suitable gloves.
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Tergitol 15-S-9 Surfactant / Tergitol 15-S-3 Surfactant Page Number: 6
Major Uses: Hight performance cleaners and detergents; Hard surface cleaners; Prewash spotters; Paper andtextile processing; Paints adn coatings; Agrochemicals; Oil field chemicals
Not available.
CALL (310) 516-8000
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product iscombined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop propermethods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.
Notice to Reader
Verified by Sonia Owen.Printed 7/17/2012.
Validated by Sonia Owen on 7/17/2012.
Other SpecialConsiderations
References
Section 16. Other InformationMSDS Code T3124