me4331 – dsc review part 2
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ME4331 – DSC Review PART 2. MAY 1 , 2008. Jeung Hwan Choi. FREEZE-THAW METHOD. Prenucleated cooling and reheating (1xPBS + 2M glycerol). Prenucleation procedure. Sample is cooled to bring about supercooled nucleation. - PowerPoint PPT PresentationTRANSCRIPT
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ME4331 DSC Review PART 2MAY 1 , 2008Jeung Hwan Choi
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Prenucleation procedureFREEZE-THAW METHOD Prenucleated cooling and reheating (1xPBS + 2M glycerol)Reference : Hhne et al. Differential Scanning Calorimetry 1996 Perkin Elmer, Inc.supercooling(cooling / heating rate = 5 C/min) Sample is cooled to bring about supercooled nucleation Sample is reheated close to the melting point, allowing small ice crystals to be present Sample is cooled from a prenucleated state, minimizing non-equilibrium effects
Chart3
-2.17082.60714.237814.3448
-2.1632.61860.784414.5896
-2.15012.6314-1.976414.8318
-2.13742.6473-4.207515.0778
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-2.09712.7034-8.953915.8051
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-2.07792.7763-11.704516.5212
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-2.05992.8332-12.814216.9735
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-150.4972-1.41962.4882
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0.1224
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0.146
0.1588
0.1715
0.1839
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0.2059
0.2177
0.2288
0.2385
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0.2574
0.2668
0.274
0.2811
0.2896
0.3005
0.3126
0.3249
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0.3448
0.3514
0.3564
0.3617
0.3676
0.3747
0.3841
0.3931
0.4011
0.4082
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0.4197
0.4243
0.4288
0.4341
0.4393
0.4441
0.4496
0.455
0.4605
0.4654
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
Sheet1
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-0.1-2.1708
-0.5-2.163
-1-2.1501
-1.5-2.1374
-2-2.1236
-2.5-2.1109
-3-2.0971
-3.5-2.0929
-4-2.0862
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-5-2.0693
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-6-2.0502
-6.5-2.0395
-7-2.0288
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-8-2.0081
-8.5-1.9968
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-9.5-1.9761
-10.00-1.9678
-10.5-1.9581
-11-1.9474
-11.5-1.9345
-12-1.9256
-12.5-1.9185
-13-1.9128
-13.5-1.9073
-14-1.9015
-14.5-1.8923
-15-1.8785
-15.5-1.867
-16-1.8569
-16.5-1.8461
-17-1.8334
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-18-1.8148
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-21-1.7678
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-24-1.7126
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-25-1.6941
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-26.5-1.6729
-27-1.667
-27.5-1.6604
-28-1.653
-28.5-1.6454
-29-1.6389
-29.5-1.628
-30-1.6162
-30.5-1.6129
-31-1.6035
-31.5-1.6003
-31.6-1.5966
-31.7-150.4972
-31.8-101.5396
-31.9-56.4215
-32-31.4601
-32.1-13.7891
-32.2-4.0918
-32.3-0.592
-32.4-0.0905
-32.5-0.4746
-33-1.3559
-33.5-1.3185
-34-1.2679
-34.5-1.2254
-35-1.1929
Sheet1
Sheet2
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-352.6071
-34.52.6186
-342.6314
-33.52.6473
-332.6648
-32.52.6833
-322.7034
-31.52.7251
-312.7482
-30.52.7763
-302.8054
-29.52.8332
-292.8607
-28.52.8883
-282.9175
-27.52.9546
-272.9908
-26.53.0291
-263.0701
-25.53.1136
-253.1621
-24.53.2115
-243.2677
-23.53.3274
-233.3981
-22.53.4714
-223.5512
-21.53.6297
-213.7108
-20.53.8038
-203.9032
-19.54.0167
-194.1324
-18.54.257
-184.3954
-17.54.548
-174.7115
-16.54.8942
-165.0896
-15.55.3057
-155.5503
-14.55.8108
-146.0964
-13.56.4089
-136.7517
-12.57.1382
-127.5661
-11.58.0436
-118.5693
-10.59.1652
-109.8355
-9.510.5948
-911.4464
-8.712.0067
-8.412.6064
-8.113.2457
-7.913.6957
-7.714.1603
-7.614.3986
Sheet2
Sheet3
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-7.54.2378
-7.60.7844
-7.7-1.9764
-7.8-4.2075
-7.9-6.0753
-8-7.6376
-8.1-8.9539
-8.2-10.042
-8.3-10.95
-8.4-11.7045
-8.5-12.3182
-8.6-12.8142
-8.7-13.1995
-8.8-13.4838
-8.9-13.6881
-9-13.8186
-9.1-13.8838
-9.2-13.8917
-9.3-13.8407
-9.4-13.7479
-9.5-13.6169
-10-12.5874
-10.5-11.3551
-11-10.1875
-11.5-9.1958
-12-8.3595
-12.5-7.6557
-13-7.064
-13.5-6.5529
-14-6.1003
-14.5-5.7101
-15-5.3545
-15.5-5.0412
-16-4.754
-16.5-4.4957
-17-4.2641
-17.5-4.054
-18-3.8533
-18.5-3.6709
-19-3.508
-19.5-3.36
-20-3.2177
-20.5-3.0811
-21-2.9563
-21.5-2.8417
-22-2.7327
-22.5-2.6297
-23-2.5341
-23.5-2.4438
-24-2.3577
-24.5-2.2771
-25-2.2015
-25.5-2.1275
-26-2.0555
-26.5-1.985
-27-1.9214
-27.5-1.8625
-28-1.8037
-28.5-1.7463
-29-1.6905
-29.5-1.6456
-30-1.6004
-30.5-1.555
-31-1.509
-31.5-1.4639
-32-1.4196
-32.5-1.3775
-33-1.3301
-33.5-1.2982
-34-1.2642
-34.5-1.2299
-35-1.1965
-35.5-1.164
-36-1.1326
-36.5-1.1022
-37-1.0726
-37.5-1.0443
-38-1.016
-38.5-0.9867
-39-0.9555
-39.5-0.9224
-40-0.8934
-40.5-0.8669
-41-0.843
-41.5-0.8192
-42-0.7974
-42.5-0.7752
-43-0.7538
-43.5-0.7323
-44-0.7108
-44.5-0.6849
-45-0.6615
-45.5-0.6393
-46-0.6186
-46.5-0.6006
-47-0.58
-47.5-0.5604
-48-0.5417
-48.5-0.5241
-49-0.506
-49.5-0.4869
-50-0.4685
-50.5-0.4506
-51-0.4331
-51.5-0.4167
-52-0.4022
-52.5-0.3866
-53-0.369
-53.5-0.3498
-54-0.3317
-54.5-0.3153
-55-0.2997
-55.5-0.2851
-56-0.2705
-56.5-0.2557
-57-0.2416
-57.5-0.2268
-58-0.2109
-58.5-0.1936
-59-0.1735
-59.5-0.156
-60-0.1416
-60.5-0.1285
-61-0.1157
-61.5-0.101
-62-0.0856
-62.5-0.0695
-63-0.0545
-63.5-0.04
-64-0.0257
-64.5-0.0125
-650.00075584
-65.50.0135
-660.0267
-66.50.0406
-670.0548
-67.50.0719
-680.0883
-68.50.0991
-690.1106
-69.50.1224
-700.1343
-70.50.146
-710.1588
-71.50.1715
-720.1839
-72.50.1949
-730.2059
-73.50.2177
-740.2288
-74.50.2385
-750.2481
-75.50.2574
-760.2668
-76.50.274
-770.2811
-77.50.2896
-780.3005
-78.50.3126
-790.3249
-79.50.3361
-800.3448
-80.50.3514
-810.3564
-81.50.3617
-820.3676
-82.50.3747
-830.3841
-83.50.3931
-840.4011
-84.50.4082
-850.4145
-85.50.4197
-860.4243
-86.50.4288
-870.4341
-87.50.4393
-880.4441
-88.50.4496
-890.455
-89.50.4605
-900.4654
Sheet3
Sheet4
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-7.614.3448
-7.514.5896
-7.414.8318
-7.315.0778
-7.215.3191
-7.115.5622
-715.8051
-6.916.0487
-6.816.2862
-6.716.5212
-6.616.7465
-6.516.9735
-6.417.1857
-6.317.3891
-6.217.5775
-6.117.751
-617.8919
-5.918.0068
-5.818.0906
-5.718.1413
-5.618.1348
-5.518.0768
-5.417.9425
-5.317.7209
-5.217.398
-5.116.9409
-516.3216
-4.915.561
-4.814.6679
-4.713.5972
-4.612.3308
-4.510.9292
-4.49.3541
-4.37.7244
-4.26.1263
-4.14.6647
-43.5797
-3.92.9633
-3.82.6937
-3.72.5702
-3.62.5141
-3.52.4912
-3.42.483
-3.32.4776
-3.22.4727
-3.12.4708
-32.4712
-2.92.4707
-2.82.471
-2.72.471
-2.62.4716
-2.52.4719
-2.42.4722
-2.32.4724
-2.22.4734
-2.12.4741
-22.4768
-1.92.4786
-1.82.48
-1.72.4814
-1.62.4828
-1.52.484
-1.42.4855
-1.32.4868
-1.22.4875
-1.12.4882
-12.4891
-0.92.4903
-0.82.4912
-0.72.4922
-0.62.4931
-0.52.4938
-0.42.4944
-0.32.4954
-0.22.4969
-0.12.4992
Sheet4
Sheet6
supercooled nucleationpartial meltingprenucleated coolingcomplete melting
-0.1-2.1708-352.6071-7.54.2378-7.614.3448
-0.5-2.163-34.52.6186-7.60.7844-7.514.5896
-1-2.1501-342.6314-7.7-1.9764-7.414.8318
-1.5-2.1374-33.52.6473-7.8-4.2075-7.315.0778
-2-2.1236-332.6648-7.9-6.0753-7.215.3191
-2.5-2.1109-32.52.6833-8-7.6376-7.115.5622
-3-2.0971-322.7034-8.1-8.9539-715.8051
-3.5-2.0929-31.52.7251-8.2-10.042-6.916.0487
-4-2.0862-312.7482-8.3-10.95-6.816.2862
-4.5-2.0779-30.52.7763-8.4-11.7045-6.716.5212
-5-2.0693-302.8054-8.5-12.3182-6.616.7465
-5.5-2.0599-29.52.8332-8.6-12.8142-6.516.9735
-6-2.0502-292.8607-8.7-13.1995-6.417.1857
-6.5-2.0395-28.52.8883-8.8-13.4838-6.317.3891
-7-2.0288-282.9175-8.9-13.6881-6.217.5775
-7.5-2.0188-27.52.9546-9-13.8186-6.117.751
-8-2.0081-272.9908-9.1-13.8838-617.8919
-8.5-1.9968-26.53.0291-9.2-13.8917-5.918.0068
-9-1.9866-263.0701-9.3-13.8407-5.818.0906
-9.5-1.9761-25.53.1136-9.4-13.7479-5.718.1413
-10.00-1.9678-253.1621-9.5-13.6169-5.618.1348
-10.5-1.9581-24.53.2115-10-12.5874-5.518.0768
-11-1.9474-243.2677-10.5-11.3551-5.417.9425
-11.5-1.9345-23.53.3274-11-10.1875-5.317.7209
-12-1.9256-233.3981-11.5-9.1958-5.217.398
-12.5-1.9185-22.53.4714-12-8.3595-5.116.9409
-13-1.9128-223.5512-12.5-7.6557-516.3216
-13.5-1.9073-21.53.6297-13-7.064-4.915.561
-14-1.9015-213.7108-13.5-6.5529-4.814.6679
-14.5-1.8923-20.53.8038-14-6.1003-4.713.5972
-15-1.8785-203.9032-14.5-5.7101-4.612.3308
-15.5-1.867-19.54.0167-15-5.3545-4.510.9292
-16-1.8569-194.1324-15.5-5.0412-4.49.3541
-16.5-1.8461-18.54.257-16-4.754-4.37.7244
-17-1.8334-184.3954-16.5-4.4957-4.26.1263
-17.5-1.8218-17.54.548-17-4.2641-4.14.6647
-18-1.8148-174.7115-17.5-4.054-43.5797
-18.5-1.8077-16.54.8942-18-3.8533-3.92.9633
-19-1.8035-165.0896-18.5-3.6709-3.82.6937
-19.5-1.7992-15.55.3057-19-3.508-3.72.5702
-20-1.7923-155.5503-19.5-3.36-3.62.5141
-20.5-1.7789-14.55.8108-20-3.2177-3.52.4912
-21-1.7678-146.0964-20.5-3.0811-3.42.483
-21.5-1.7585-13.56.4089-21-2.9563-3.32.4776
-22-1.7479-136.7517-21.5-2.8417-3.22.4727
-22.5-1.739-12.57.1382-22-2.7327-3.12.4708
-23-1.7303-127.5661-22.5-2.6297-32.4712
-23.5-1.7218-11.58.0436-23-2.5341-2.92.4707
-24-1.7126-118.5693-23.5-2.4438-2.82.471
-24.5-1.7027-10.59.1652-24-2.3577-2.72.471
-25-1.6941-109.8355-24.5-2.2771-2.62.4716
-25.5-1.6857-9.510.5948-25-2.2015-2.52.4719
-26-1.6786-911.4464-25.5-2.1275-2.42.4722
-26.5-1.6729-8.712.0067-26-2.0555-2.32.4724
-27-1.667-8.412.6064-26.5-1.985-2.22.4734
-27.5-1.6604-8.113.2457-27-1.9214-2.12.4741
-28-1.653-7.913.6957-27.5-1.8625-22.4768
-28.5-1.6454-7.714.1603-28-1.8037-1.92.4786
-29-1.6389-7.614.3986-28.5-1.7463-1.82.48
-29.5-1.628-29-1.6905-1.72.4814
-30-1.6162-29.5-1.6456-1.62.4828
-30.5-1.6129-30-1.6004-1.52.484
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-32-31.4601-33.5-1.2982-0.82.4912
-32.1-13.7891-34-1.2642-0.72.4922
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-33-1.3559-36.5-1.1022-0.22.4969
-33.5-1.3185-37-1.0726-0.12.4992
-34-1.2679-37.5-1.0443
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-35-1.1929-38.5-0.9867
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-82.50.3747
-830.3841
-83.50.3931
-840.4011
-84.50.4082
-850.4145
-85.50.4197
-860.4243
-86.50.4288
-870.4341
-87.50.4393
-880.4441
-88.50.4496
-890.455
-89.50.4605
-900.4654
Sheet6
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
Chart5
-2.17082.60714.237814.3448
-2.1632.61860.784414.5896
-2.15012.6314-1.976414.8318
-2.13742.6473-4.207515.0778
-2.12362.6648-6.075315.3191
-2.11092.6833-7.637615.5622
-2.09712.7034-8.953915.8051
-2.09292.7251-10.04216.0487
-2.08622.7482-10.9516.2862
-2.07792.7763-11.704516.5212
-2.06932.8054-12.318216.7465
-2.05992.8332-12.814216.9735
-2.05022.8607-13.199517.1857
-2.03952.8883-13.483817.3891
-2.02882.9175-13.688117.5775
-2.01882.9546-13.818617.751
-2.00812.9908-13.883817.8919
-1.99683.0291-13.891718.0068
-1.98663.0701-13.840718.0906
-1.97613.1136-13.747918.1413
-1.96783.1621-13.616918.1348
-1.95813.2115-12.587418.0768
-1.94743.2677-11.355117.9425
-1.93453.3274-10.187517.7209
-1.92563.3981-9.195817.398
-1.91853.4714-8.359516.9409
-1.91283.5512-7.655716.3216
-1.90733.6297-7.06415.561
-1.90153.7108-6.552914.6679
-1.89233.8038-6.100313.5972
-1.87853.9032-5.710112.3308
-1.8674.0167-5.354510.9292
-1.85694.1324-5.04129.3541
-1.84614.257-4.7547.7244
-1.83344.3954-4.49576.1263
-1.82184.548-4.26414.6647
-1.81484.7115-4.0543.5797
-1.80774.8942-3.85332.9633
-1.80355.0896-3.67092.6937
-1.79925.3057-3.5082.5702
-1.79235.5503-3.362.5141
-1.77895.8108-3.21772.4912
-1.76786.0964-3.08112.483
-1.75856.4089-2.95632.4776
-1.74796.7517-2.84172.4727
-1.7397.1382-2.73272.4708
-1.73037.5661-2.62972.4712
-1.72188.0436-2.53412.4707
-1.71268.5693-2.44382.471
-1.70279.1652-2.35772.471
-1.69419.8355-2.27712.4716
-1.685710.5948-2.20152.4719
-1.678611.4464-2.12752.4722
-1.672912.0067-2.05552.4724
-1.66712.6064-1.9852.4734
-1.660413.2457-1.92142.4741
-1.65313.6957-1.86252.4768
-1.645414.1603-1.80372.4786
-1.638914.3986-1.74632.48
-1.628-1.69052.4814
-1.6162-1.64562.4828
-1.6129-1.60042.484
-1.6035-1.5552.4855
-1.6003-1.5092.4868
-1.5966-1.46392.4875
-150.4972-1.41962.4882
-101.5396-1.37752.4891
-56.4215-1.33012.4903
-31.4601-1.29822.4912
-13.7891-1.26422.4922
-4.0918-1.22992.4931
-0.592-1.19652.4938
-0.0905-1.1642.4944
-0.4746-1.13262.4954
-1.3559-1.10222.4969
-1.3185-1.07262.4992
-1.2679-1.0443
-1.2254-1.016
-1.1929-0.9867
-0.9555
-0.9224
-0.8934
-0.8669
-0.843
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-0.7974
-0.7752
-0.7538
-0.7323
-0.7108
-0.6849
-0.6615
-0.6393
-0.6186
-0.6006
-0.58
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-0.5417
-0.5241
-0.506
-0.4869
-0.4685
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-0.4022
-0.3866
-0.369
-0.3498
-0.3317
-0.3153
-0.2997
-0.2851
-0.2705
-0.2557
-0.2416
-0.2268
-0.2109
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-0.1735
-0.156
-0.1416
-0.1285
-0.1157
-0.101
-0.0856
-0.0695
-0.0545
-0.04
-0.0257
-0.0125
0.00075584
0.0135
0.0267
0.0406
0.0548
0.0719
0.0883
0.0991
0.1106
0.1224
0.1343
0.146
0.1588
0.1715
0.1839
0.1949
0.2059
0.2177
0.2288
0.2385
0.2481
0.2574
0.2668
0.274
0.2811
0.2896
0.3005
0.3126
0.3249
0.3361
0.3448
0.3514
0.3564
0.3617
0.3676
0.3747
0.3841
0.3931
0.4011
0.4082
0.4145
0.4197
0.4243
0.4288
0.4341
0.4393
0.4441
0.4496
0.455
0.4605
0.4654
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
Sheet1
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-0.1-2.1708
-0.5-2.163
-1-2.1501
-1.5-2.1374
-2-2.1236
-2.5-2.1109
-3-2.0971
-3.5-2.0929
-4-2.0862
-4.5-2.0779
-5-2.0693
-5.5-2.0599
-6-2.0502
-6.5-2.0395
-7-2.0288
-7.5-2.0188
-8-2.0081
-8.5-1.9968
-9-1.9866
-9.5-1.9761
-10.00-1.9678
-10.5-1.9581
-11-1.9474
-11.5-1.9345
-12-1.9256
-12.5-1.9185
-13-1.9128
-13.5-1.9073
-14-1.9015
-14.5-1.8923
-15-1.8785
-15.5-1.867
-16-1.8569
-16.5-1.8461
-17-1.8334
-17.5-1.8218
-18-1.8148
-18.5-1.8077
-19-1.8035
-19.5-1.7992
-20-1.7923
-20.5-1.7789
-21-1.7678
-21.5-1.7585
-22-1.7479
-22.5-1.739
-23-1.7303
-23.5-1.7218
-24-1.7126
-24.5-1.7027
-25-1.6941
-25.5-1.6857
-26-1.6786
-26.5-1.6729
-27-1.667
-27.5-1.6604
-28-1.653
-28.5-1.6454
-29-1.6389
-29.5-1.628
-30-1.6162
-30.5-1.6129
-31-1.6035
-31.5-1.6003
-31.6-1.5966
-31.7-150.4972
-31.8-101.5396
-31.9-56.4215
-32-31.4601
-32.1-13.7891
-32.2-4.0918
-32.3-0.592
-32.4-0.0905
-32.5-0.4746
-33-1.3559
-33.5-1.3185
-34-1.2679
-34.5-1.2254
-35-1.1929
Sheet1
Sheet2
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-352.6071
-34.52.6186
-342.6314
-33.52.6473
-332.6648
-32.52.6833
-322.7034
-31.52.7251
-312.7482
-30.52.7763
-302.8054
-29.52.8332
-292.8607
-28.52.8883
-282.9175
-27.52.9546
-272.9908
-26.53.0291
-263.0701
-25.53.1136
-253.1621
-24.53.2115
-243.2677
-23.53.3274
-233.3981
-22.53.4714
-223.5512
-21.53.6297
-213.7108
-20.53.8038
-203.9032
-19.54.0167
-194.1324
-18.54.257
-184.3954
-17.54.548
-174.7115
-16.54.8942
-165.0896
-15.55.3057
-155.5503
-14.55.8108
-146.0964
-13.56.4089
-136.7517
-12.57.1382
-127.5661
-11.58.0436
-118.5693
-10.59.1652
-109.8355
-9.510.5948
-911.4464
-8.712.0067
-8.412.6064
-8.113.2457
-7.913.6957
-7.714.1603
-7.614.3986
Sheet2
Sheet3
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-7.54.2378
-7.60.7844
-7.7-1.9764
-7.8-4.2075
-7.9-6.0753
-8-7.6376
-8.1-8.9539
-8.2-10.042
-8.3-10.95
-8.4-11.7045
-8.5-12.3182
-8.6-12.8142
-8.7-13.1995
-8.8-13.4838
-8.9-13.6881
-9-13.8186
-9.1-13.8838
-9.2-13.8917
-9.3-13.8407
-9.4-13.7479
-9.5-13.6169
-10-12.5874
-10.5-11.3551
-11-10.1875
-11.5-9.1958
-12-8.3595
-12.5-7.6557
-13-7.064
-13.5-6.5529
-14-6.1003
-14.5-5.7101
-15-5.3545
-15.5-5.0412
-16-4.754
-16.5-4.4957
-17-4.2641
-17.5-4.054
-18-3.8533
-18.5-3.6709
-19-3.508
-19.5-3.36
-20-3.2177
-20.5-3.0811
-21-2.9563
-21.5-2.8417
-22-2.7327
-22.5-2.6297
-23-2.5341
-23.5-2.4438
-24-2.3577
-24.5-2.2771
-25-2.2015
-25.5-2.1275
-26-2.0555
-26.5-1.985
-27-1.9214
-27.5-1.8625
-28-1.8037
-28.5-1.7463
-29-1.6905
-29.5-1.6456
-30-1.6004
-30.5-1.555
-31-1.509
-31.5-1.4639
-32-1.4196
-32.5-1.3775
-33-1.3301
-33.5-1.2982
-34-1.2642
-34.5-1.2299
-35-1.1965
-35.5-1.164
-36-1.1326
-36.5-1.1022
-37-1.0726
-37.5-1.0443
-38-1.016
-38.5-0.9867
-39-0.9555
-39.5-0.9224
-40-0.8934
-40.5-0.8669
-41-0.843
-41.5-0.8192
-42-0.7974
-42.5-0.7752
-43-0.7538
-43.5-0.7323
-44-0.7108
-44.5-0.6849
-45-0.6615
-45.5-0.6393
-46-0.6186
-46.5-0.6006
-47-0.58
-47.5-0.5604
-48-0.5417
-48.5-0.5241
-49-0.506
-49.5-0.4869
-50-0.4685
-50.5-0.4506
-51-0.4331
-51.5-0.4167
-52-0.4022
-52.5-0.3866
-53-0.369
-53.5-0.3498
-54-0.3317
-54.5-0.3153
-55-0.2997
-55.5-0.2851
-56-0.2705
-56.5-0.2557
-57-0.2416
-57.5-0.2268
-58-0.2109
-58.5-0.1936
-59-0.1735
-59.5-0.156
-60-0.1416
-60.5-0.1285
-61-0.1157
-61.5-0.101
-62-0.0856
-62.5-0.0695
-63-0.0545
-63.5-0.04
-64-0.0257
-64.5-0.0125
-650.00075584
-65.50.0135
-660.0267
-66.50.0406
-670.0548
-67.50.0719
-680.0883
-68.50.0991
-690.1106
-69.50.1224
-700.1343
-70.50.146
-710.1588
-71.50.1715
-720.1839
-72.50.1949
-730.2059
-73.50.2177
-740.2288
-74.50.2385
-750.2481
-75.50.2574
-760.2668
-76.50.274
-770.2811
-77.50.2896
-780.3005
-78.50.3126
-790.3249
-79.50.3361
-800.3448
-80.50.3514
-810.3564
-81.50.3617
-820.3676
-82.50.3747
-830.3841
-83.50.3931
-840.4011
-84.50.4082
-850.4145
-85.50.4197
-860.4243
-86.50.4288
-870.4341
-87.50.4393
-880.4441
-88.50.4496
-890.455
-89.50.4605
-900.4654
Sheet3
Sheet4
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-7.614.3448
-7.514.5896
-7.414.8318
-7.315.0778
-7.215.3191
-7.115.5622
-715.8051
-6.916.0487
-6.816.2862
-6.716.5212
-6.616.7465
-6.516.9735
-6.417.1857
-6.317.3891
-6.217.5775
-6.117.751
-617.8919
-5.918.0068
-5.818.0906
-5.718.1413
-5.618.1348
-5.518.0768
-5.417.9425
-5.317.7209
-5.217.398
-5.116.9409
-516.3216
-4.915.561
-4.814.6679
-4.713.5972
-4.612.3308
-4.510.9292
-4.49.3541
-4.37.7244
-4.26.1263
-4.14.6647
-43.5797
-3.92.9633
-3.82.6937
-3.72.5702
-3.62.5141
-3.52.4912
-3.42.483
-3.32.4776
-3.22.4727
-3.12.4708
-32.4712
-2.92.4707
-2.82.471
-2.72.471
-2.62.4716
-2.52.4719
-2.42.4722
-2.32.4724
-2.22.4734
-2.12.4741
-22.4768
-1.92.4786
-1.82.48
-1.72.4814
-1.62.4828
-1.52.484
-1.42.4855
-1.32.4868
-1.22.4875
-1.12.4882
-12.4891
-0.92.4903
-0.82.4912
-0.72.4922
-0.62.4931
-0.52.4938
-0.42.4944
-0.32.4954
-0.22.4969
-0.12.4992
Sheet4
Sheet6
supercooled nucleationpartial meltingprenucleated coolingcomplete melting
-0.1-2.1708-352.6071-7.54.2378-7.614.3448
-0.5-2.163-34.52.6186-7.60.7844-7.514.5896
-1-2.1501-342.6314-7.7-1.9764-7.414.8318
-1.5-2.1374-33.52.6473-7.8-4.2075-7.315.0778
-2-2.1236-332.6648-7.9-6.0753-7.215.3191
-2.5-2.1109-32.52.6833-8-7.6376-7.115.5622
-3-2.0971-322.7034-8.1-8.9539-715.8051
-3.5-2.0929-31.52.7251-8.2-10.042-6.916.0487
-4-2.0862-312.7482-8.3-10.95-6.816.2862
-4.5-2.0779-30.52.7763-8.4-11.7045-6.716.5212
-5-2.0693-302.8054-8.5-12.3182-6.616.7465
-5.5-2.0599-29.52.8332-8.6-12.8142-6.516.9735
-6-2.0502-292.8607-8.7-13.1995-6.417.1857
-6.5-2.0395-28.52.8883-8.8-13.4838-6.317.3891
-7-2.0288-282.9175-8.9-13.6881-6.217.5775
-7.5-2.0188-27.52.9546-9-13.8186-6.117.751
-8-2.0081-272.9908-9.1-13.8838-617.8919
-8.5-1.9968-26.53.0291-9.2-13.8917-5.918.0068
-9-1.9866-263.0701-9.3-13.8407-5.818.0906
-9.5-1.9761-25.53.1136-9.4-13.7479-5.718.1413
-10.00-1.9678-253.1621-9.5-13.6169-5.618.1348
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-13-1.9128-223.5512-12.5-7.6557-516.3216
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-14-1.9015-213.7108-13.5-6.5529-4.814.6679
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-15-1.8785-203.9032-14.5-5.7101-4.612.3308
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-16-1.8569-194.1324-15.5-5.0412-4.49.3541
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-17-1.8334-184.3954-16.5-4.4957-4.26.1263
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-18-1.8148-174.7115-17.5-4.054-43.5797
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-19-1.8035-165.0896-18.5-3.6709-3.82.6937
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-21-1.7678-146.0964-20.5-3.0811-3.42.483
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-22-1.7479-136.7517-21.5-2.8417-3.22.4727
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-24-1.7126-118.5693-23.5-2.4438-2.82.471
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-25-1.6941-109.8355-24.5-2.2771-2.62.4716
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-87.50.4393
-880.4441
-88.50.4496
-890.455
-89.50.4605
-900.4654
Sheet6
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
Chart6
-2.17082.60714.237814.3448
-2.1632.61860.784414.5896
-2.15012.6314-1.976414.8318
-2.13742.6473-4.207515.0778
-2.12362.6648-6.075315.3191
-2.11092.6833-7.637615.5622
-2.09712.7034-8.953915.8051
-2.09292.7251-10.04216.0487
-2.08622.7482-10.9516.2862
-2.07792.7763-11.704516.5212
-2.06932.8054-12.318216.7465
-2.05992.8332-12.814216.9735
-2.05022.8607-13.199517.1857
-2.03952.8883-13.483817.3891
-2.02882.9175-13.688117.5775
-2.01882.9546-13.818617.751
-2.00812.9908-13.883817.8919
-1.99683.0291-13.891718.0068
-1.98663.0701-13.840718.0906
-1.97613.1136-13.747918.1413
-1.96783.1621-13.616918.1348
-1.95813.2115-12.587418.0768
-1.94743.2677-11.355117.9425
-1.93453.3274-10.187517.7209
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-4.0918-1.22992.4931
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0.0406
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0.0719
0.0883
0.0991
0.1106
0.1224
0.1343
0.146
0.1588
0.1715
0.1839
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0.2059
0.2177
0.2288
0.2385
0.2481
0.2574
0.2668
0.274
0.2811
0.2896
0.3005
0.3126
0.3249
0.3361
0.3448
0.3514
0.3564
0.3617
0.3676
0.3747
0.3841
0.3931
0.4011
0.4082
0.4145
0.4197
0.4243
0.4288
0.4341
0.4393
0.4441
0.4496
0.455
0.4605
0.4654
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
Sheet1
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-0.1-2.1708
-0.5-2.163
-1-2.1501
-1.5-2.1374
-2-2.1236
-2.5-2.1109
-3-2.0971
-3.5-2.0929
-4-2.0862
-4.5-2.0779
-5-2.0693
-5.5-2.0599
-6-2.0502
-6.5-2.0395
-7-2.0288
-7.5-2.0188
-8-2.0081
-8.5-1.9968
-9-1.9866
-9.5-1.9761
-10.00-1.9678
-10.5-1.9581
-11-1.9474
-11.5-1.9345
-12-1.9256
-12.5-1.9185
-13-1.9128
-13.5-1.9073
-14-1.9015
-14.5-1.8923
-15-1.8785
-15.5-1.867
-16-1.8569
-16.5-1.8461
-17-1.8334
-17.5-1.8218
-18-1.8148
-18.5-1.8077
-19-1.8035
-19.5-1.7992
-20-1.7923
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-21-1.7678
-21.5-1.7585
-22-1.7479
-22.5-1.739
-23-1.7303
-23.5-1.7218
-24-1.7126
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-25-1.6941
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-27-1.667
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-28-1.653
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-29-1.6389
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-30-1.6162
-30.5-1.6129
-31-1.6035
-31.5-1.6003
-31.6-1.5966
-31.7-150.4972
-31.8-101.5396
-31.9-56.4215
-32-31.4601
-32.1-13.7891
-32.2-4.0918
-32.3-0.592
-32.4-0.0905
-32.5-0.4746
-33-1.3559
-33.5-1.3185
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-35-1.1929
Sheet1
Sheet2
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-352.6071
-34.52.6186
-342.6314
-33.52.6473
-332.6648
-32.52.6833
-322.7034
-31.52.7251
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-30.52.7763
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-29.52.8332
-292.8607
-28.52.8883
-282.9175
-27.52.9546
-272.9908
-26.53.0291
-263.0701
-25.53.1136
-253.1621
-24.53.2115
-243.2677
-23.53.3274
-233.3981
-22.53.4714
-223.5512
-21.53.6297
-213.7108
-20.53.8038
-203.9032
-19.54.0167
-194.1324
-18.54.257
-184.3954
-17.54.548
-174.7115
-16.54.8942
-165.0896
-15.55.3057
-155.5503
-14.55.8108
-146.0964
-13.56.4089
-136.7517
-12.57.1382
-127.5661
-11.58.0436
-118.5693
-10.59.1652
-109.8355
-9.510.5948
-911.4464
-8.712.0067
-8.412.6064
-8.113.2457
-7.913.6957
-7.714.1603
-7.614.3986
Sheet2
Sheet3
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-7.54.2378
-7.60.7844
-7.7-1.9764
-7.8-4.2075
-7.9-6.0753
-8-7.6376
-8.1-8.9539
-8.2-10.042
-8.3-10.95
-8.4-11.7045
-8.5-12.3182
-8.6-12.8142
-8.7-13.1995
-8.8-13.4838
-8.9-13.6881
-9-13.8186
-9.1-13.8838
-9.2-13.8917
-9.3-13.8407
-9.4-13.7479
-9.5-13.6169
-10-12.5874
-10.5-11.3551
-11-10.1875
-11.5-9.1958
-12-8.3595
-12.5-7.6557
-13-7.064
-13.5-6.5529
-14-6.1003
-14.5-5.7101
-15-5.3545
-15.5-5.0412
-16-4.754
-16.5-4.4957
-17-4.2641
-17.5-4.054
-18-3.8533
-18.5-3.6709
-19-3.508
-19.5-3.36
-20-3.2177
-20.5-3.0811
-21-2.9563
-21.5-2.8417
-22-2.7327
-22.5-2.6297
-23-2.5341
-23.5-2.4438
-24-2.3577
-24.5-2.2771
-25-2.2015
-25.5-2.1275
-26-2.0555
-26.5-1.985
-27-1.9214
-27.5-1.8625
-28-1.8037
-28.5-1.7463
-29-1.6905
-29.5-1.6456
-30-1.6004
-30.5-1.555
-31-1.509
-31.5-1.4639
-32-1.4196
-32.5-1.3775
-33-1.3301
-33.5-1.2982
-34-1.2642
-34.5-1.2299
-35-1.1965
-35.5-1.164
-36-1.1326
-36.5-1.1022
-37-1.0726
-37.5-1.0443
-38-1.016
-38.5-0.9867
-39-0.9555
-39.5-0.9224
-40-0.8934
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-41-0.843
-41.5-0.8192
-42-0.7974
-42.5-0.7752
-43-0.7538
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-44-0.7108
-44.5-0.6849
-45-0.6615
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-51-0.4331
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-52-0.4022
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-53-0.369
-53.5-0.3498
-54-0.3317
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-55-0.2997
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-56-0.2705
-56.5-0.2557
-57-0.2416
-57.5-0.2268
-58-0.2109
-58.5-0.1936
-59-0.1735
-59.5-0.156
-60-0.1416
-60.5-0.1285
-61-0.1157
-61.5-0.101
-62-0.0856
-62.5-0.0695
-63-0.0545
-63.5-0.04
-64-0.0257
-64.5-0.0125
-650.00075584
-65.50.0135
-660.0267
-66.50.0406
-670.0548
-67.50.0719
-680.0883
-68.50.0991
-690.1106
-69.50.1224
-700.1343
-70.50.146
-710.1588
-71.50.1715
-720.1839
-72.50.1949
-730.2059
-73.50.2177
-740.2288
-74.50.2385
-750.2481
-75.50.2574
-760.2668
-76.50.274
-770.2811
-77.50.2896
-780.3005
-78.50.3126
-790.3249
-79.50.3361
-800.3448
-80.50.3514
-810.3564
-81.50.3617
-820.3676
-82.50.3747
-830.3841
-83.50.3931
-840.4011
-84.50.4082
-850.4145
-85.50.4197
-860.4243
-86.50.4288
-870.4341
-87.50.4393
-880.4441
-88.50.4496
-890.455
-89.50.4605
-900.4654
Sheet3
Sheet4
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-7.614.3448
-7.514.5896
-7.414.8318
-7.315.0778
-7.215.3191
-7.115.5622
-715.8051
-6.916.0487
-6.816.2862
-6.716.5212
-6.616.7465
-6.516.9735
-6.417.1857
-6.317.3891
-6.217.5775
-6.117.751
-617.8919
-5.918.0068
-5.818.0906
-5.718.1413
-5.618.1348
-5.518.0768
-5.417.9425
-5.317.7209
-5.217.398
-5.116.9409
-516.3216
-4.915.561
-4.814.6679
-4.713.5972
-4.612.3308
-4.510.9292
-4.49.3541
-4.37.7244
-4.26.1263
-4.14.6647
-43.5797
-3.92.9633
-3.82.6937
-3.72.5702
-3.62.5141
-3.52.4912
-3.42.483
-3.32.4776
-3.22.4727
-3.12.4708
-32.4712
-2.92.4707
-2.82.471
-2.72.471
-2.62.4716
-2.52.4719
-2.42.4722
-2.32.4724
-2.22.4734
-2.12.4741
-22.4768
-1.92.4786
-1.82.48
-1.72.4814
-1.62.4828
-1.52.484
-1.42.4855
-1.32.4868
-1.22.4875
-1.12.4882
-12.4891
-0.92.4903
-0.82.4912
-0.72.4922
-0.62.4931
-0.52.4938
-0.42.4944
-0.32.4954
-0.22.4969
-0.12.4992
Sheet4
Sheet6
supercooled nucleationpartial meltingprenucleated coolingcomplete melting
-0.1-2.1708-352.6071-7.54.2378-7.614.3448
-0.5-2.163-34.52.6186-7.60.7844-7.514.5896
-1-2.1501-342.6314-7.7-1.9764-7.414.8318
-1.5-2.1374-33.52.6473-7.8-4.2075-7.315.0778
-2-2.1236-332.6648-7.9-6.0753-7.215.3191
-2.5-2.1109-32.52.6833-8-7.6376-7.115.5622
-3-2.0971-322.7034-8.1-8.9539-715.8051
-3.5-2.0929-31.52.7251-8.2-10.042-6.916.0487
-4-2.0862-312.7482-8.3-10.95-6.816.2862
-4.5-2.0779-30.52.7763-8.4-11.7045-6.716.5212
-5-2.0693-302.8054-8.5-12.3182-6.616.7465
-5.5-2.0599-29.52.8332-8.6-12.8142-6.516.9735
-6-2.0502-292.8607-8.7-13.1995-6.417.1857
-6.5-2.0395-28.52.8883-8.8-13.4838-6.317.3891
-7-2.0288-282.9175-8.9-13.6881-6.217.5775
-7.5-2.0188-27.52.9546-9-13.8186-6.117.751
-8-2.0081-272.9908-9.1-13.8838-617.8919
-8.5-1.9968-26.53.0291-9.2-13.8917-5.918.0068
-9-1.9866-263.0701-9.3-13.8407-5.818.0906
-9.5-1.9761-25.53.1136-9.4-13.7479-5.718.1413
-10.00-1.9678-253.1621-9.5-13.6169-5.618.1348
-10.5-1.9581-24.53.2115-10-12.5874-5.518.0768
-11-1.9474-243.2677-10.5-11.3551-5.417.9425
-11.5-1.9345-23.53.3274-11-10.1875-5.317.7209
-12-1.9256-233.3981-11.5-9.1958-5.217.398
-12.5-1.9185-22.53.4714-12-8.3595-5.116.9409
-13-1.9128-223.5512-12.5-7.6557-516.3216
-13.5-1.9073-21.53.6297-13-7.064-4.915.561
-14-1.9015-213.7108-13.5-6.5529-4.814.6679
-14.5-1.8923-20.53.8038-14-6.1003-4.713.5972
-15-1.8785-203.9032-14.5-5.7101-4.612.3308
-15.5-1.867-19.54.0167-15-5.3545-4.510.9292
-16-1.8569-194.1324-15.5-5.0412-4.49.3541
-16.5-1.8461-18.54.257-16-4.754-4.37.7244
-17-1.8334-184.3954-16.5-4.4957-4.26.1263
-17.5-1.8218-17.54.548-17-4.2641-4.14.6647
-18-1.8148-174.7115-17.5-4.054-43.5797
-18.5-1.8077-16.54.8942-18-3.8533-3.92.9633
-19-1.8035-165.0896-18.5-3.6709-3.82.6937
-19.5-1.7992-15.55.3057-19-3.508-3.72.5702
-20-1.7923-155.5503-19.5-3.36-3.62.5141
-20.5-1.7789-14.55.8108-20-3.2177-3.52.4912
-21-1.7678-146.0964-20.5-3.0811-3.42.483
-21.5-1.7585-13.56.4089-21-2.9563-3.32.4776
-22-1.7479-136.7517-21.5-2.8417-3.22.4727
-22.5-1.739-12.57.1382-22-2.7327-3.12.4708
-23-1.7303-127.5661-22.5-2.6297-32.4712
-23.5-1.7218-11.58.0436-23-2.5341-2.92.4707
-24-1.7126-118.5693-23.5-2.4438-2.82.471
-24.5-1.7027-10.59.1652-24-2.3577-2.72.471
-25-1.6941-109.8355-24.5-2.2771-2.62.4716
-25.5-1.6857-9.510.5948-25-2.2015-2.52.4719
-26-1.6786-911.4464-25.5-2.1275-2.42.4722
-26.5-1.6729-8.712.0067-26-2.0555-2.32.4724
-27-1.667-8.412.6064-26.5-1.985-2.22.4734
-27.5-1.6604-8.113.2457-27-1.9214-2.12.4741
-28-1.653-7.913.6957-27.5-1.8625-22.4768
-28.5-1.6454-7.714.1603-28-1.8037-1.92.4786
-29-1.6389-7.614.3986-28.5-1.7463-1.82.48
-29.5-1.628-29-1.6905-1.72.4814
-30-1.6162-29.5-1.6456-1.62.4828
-30.5-1.6129-30-1.6004-1.52.484
-31-1.6035-30.5-1.555-1.42.4855
-31.5-1.6003-31-1.509-1.32.4868
-31.6-1.5966-31.5-1.4639-1.22.4875
-31.7-150.4972-32-1.4196-1.12.4882
-31.8-101.5396-32.5-1.3775-12.4891
-31.9-56.4215-33-1.3301-0.92.4903
-32-31.4601-33.5-1.2982-0.82.4912
-32.1-13.7891-34-1.2642-0.72.4922
-32.2-4.0918-34.5-1.2299-0.62.4931
-32.3-0.592-35-1.1965-0.52.4938
-32.4-0.0905-35.5-1.164-0.42.4944
-32.5-0.4746-36-1.1326-0.32.4954
-33-1.3559-36.5-1.1022-0.22.4969
-33.5-1.3185-37-1.0726-0.12.4992
-34-1.2679-37.5-1.0443
-34.5-1.2254-38-1.016
-35-1.1929-38.5-0.9867
-39-0.9555
-39.5-0.9224
-40-0.8934
-40.5-0.8669
-41-0.843
-41.5-0.8192
-42-0.7974
-42.5-0.7752
-43-0.7538
-43.5-0.7323
-44-0.7108
-44.5-0.6849
-45-0.6615
-45.5-0.6393
-46-0.6186
-46.5-0.6006
-47-0.58
-47.5-0.5604
-48-0.5417
-48.5-0.5241
-49-0.506
-49.5-0.4869
-50-0.4685
-50.5-0.4506
-51-0.4331
-51.5-0.4167
-52-0.4022
-52.5-0.3866
-53-0.369
-53.5-0.3498
-54-0.3317
-54.5-0.3153
-55-0.2997
-55.5-0.2851
-56-0.2705
-56.5-0.2557
-57-0.2416
-57.5-0.2268
-58-0.2109
-58.5-0.1936
-59-0.1735
-59.5-0.156
-60-0.1416
-60.5-0.1285
-61-0.1157
-61.5-0.101
-62-0.0856
-62.5-0.0695
-63-0.0545
-63.5-0.04
-64-0.0257
-64.5-0.0125
-650.00075584
-65.50.0135
-660.0267
-66.50.0406
-670.0548
-67.50.0719
-680.0883
-68.50.0991
-690.1106
-69.50.1224
-700.1343
-70.50.146
-710.1588
-71.50.1715
-720.1839
-72.50.1949
-730.2059
-73.50.2177
-740.2288
-74.50.2385
-750.2481
-75.50.2574
-760.2668
-76.50.274
-770.2811
-77.50.2896
-780.3005
-78.50.3126
-790.3249
-79.50.3361
-800.3448
-80.50.3514
-810.3564
-81.50.3617
-820.3676
-82.50.3747
-830.3841
-83.50.3931
-840.4011
-84.50.4082
-850.4145
-85.50.4197
-860.4243
-86.50.4288
-870.4341
-87.50.4393
-880.4441
-88.50.4496
-890.455
-89.50.4605
-900.4654
Sheet6
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
-
Prenuc vs non-prenuc DSCFREEZE-THAW METHOD Prenucleated vs. non-prenucleated freeze-thaw (1xPBS + 6M glycerol, DSC)Reference : Choi & Bischof In Review 2006(cooling / heating rate = 5 C/min)prenucleatednon-prenucleated
Chart8
-2.64342.1149
-2.63852.1089
-2.63782.1022
-2.63612.0963
-2.63762.092
-2.63782.1871
-2.63772.8509
-2.63754.1432
-2.64035.0136
-2.64425.4065
-2.64695.5126
-2.64855.4221
-2.6485.2933
-2.64835.157
-2.64795.0305
-2.64644.906
-2.64374.7807
-2.63684.66
-2.63274.5521
-2.63844.4482
-2.64384.3458
-2.64384.2436
-2.64264.1483
-2.64194.0549
-2.6423.9656
-2.643.8748
-2.63873.7908
-2.63943.7155
-2.64493.6415
-2.65063.5687
-2.65513.4977
-2.65553.4292
-2.65473.3617
-2.65423.2975
-2.65163.2337
-2.64993.1722
-2.6483.124
-2.64513.0754
-2.64363.0247
-2.6442.9726
-2.64662.9204
-2.64912.8701
-2.65642.8248
-2.65142.7784
-2.6462.7329
-2.64162.6874
-2.63992.6424
-2.63862.5981
-2.63892.5583
-2.63682.5174
-2.6342.4734
-2.63032.4361
-2.62842.4044
-2.62832.3712
-2.62962.3329
-2.62952.2888
-2.62832.2519
-2.62832.2208
-2.62912.1905
-2.63092.1596
-2.65812.1292
-2.63962.1011
-2.63772.0719
-2.63652.043
-2.6352.0159
-2.63531.9871
-2.63791.9575
-2.64271.9294
-2.64441.9036
-2.63841.8804
-2.63381.874
-2.63071.8247
-2.62961.817
-2.62731.7958
-2.62431.7745
-2.61991.7542
-2.61771.7343
-2.62591.7143
-2.6421.6962
-2.66341.6787
-2.69251.6591
-2.72851.6376
-2.77371.6172
-2.821.5976
-2.87071.5804
-2.92531.5617
-2.97961.5445
-3.0471.5256
-3.11711.5049
-3.18691.483
-3.25281.4597
-3.30371.4366
-3.3421.4146
-3.36721.3953
-3.39441.3792
-3.41681.3626
-3.41181.3447
-3.40261.327
-3.39331.307
-3.38371.2861
-3.37261.268
-3.35811.2522
-3.34331.2387
-3.32761.2232
-3.31151.1979
-3.29021.17
-3.26241.1521
-3.22871.1378
-3.19431.1249
-3.16131.1073
-3.131.0858
-3.09651.0636
-3.06151.0442
-3.03381.0241
-3.00011.0051
-2.96790.987
-2.93850.9714
-2.91160.9538
-2.88640.9355
-2.86320.9164
-2.84010.8964
-2.81680.8781
-2.79030.859
-2.76530.8385
-2.7410.8167
-2.72090.7979
-2.70240.779
-2.68430.7624
-2.66760.7449
-2.65170.7287
-2.63890.7139
-2.62710.7007
-2.61560.689
-2.60630.6769
-2.5980.6629
-2.5940.6456
-2.58850.6274
-2.57920.6094
-2.56880.5909
-2.55820.5638
-2.54810.5304
-2.53860.4927
-2.52960.4539
-2.52290.4119
-2.52380.3631
-2.52650.301
-2.52890.2289
-2.53140.1433
-2.5330.0302
-2.5329-0.117
-2.5296-0.3189
-2.5264-0.5892
-2.5243-0.933
-2.5217-1.3446
-2.5186-1.8029
-2.513-2.2806
-2.5067-2.7426
-2.4993-3.123
-2.4923-3.3319
-2.4863-3.2865
-2.4792-2.9586
-2.4703-2.4102
-2.4611-1.7663
-2.4503-1.1377
-2.4404-0.6063
-2.432-0.1939
-2.42530.1062
-2.42010.3156
-2.41470.455
-2.40890.5458
-2.40160.6065
-2.39170.6437
-2.38230.666
-2.37490.6764
-2.37170.6844
-2.370.6906
-2.3690.6966
-2.36560.6997
-2.35840.7025
-2.35020.704
-2.34140.708
-2.33260.7186
-2.32470.748
-2.31730.7844
-2.30990.8206
-2.29750.8408
-2.28130.8369
-2.26460.8019
-2.24630.7416
-2.22560.662
-2.20520.5809
-2.1850.5056
-2.16520.4342
-2.14250.3708
-2.11830.3128
-2.09380.2593
-2.07140.2136
-2.05230.1739
-2.03920.1446
-2.02080.1221
-2.00180.1018
-1.98410.0851
-1.96770.0674
-1.95330.0546
-1.94090.0431
-1.93180.0329
-1.92680.021
-1.9074-0.0129
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-1.8521-0.0486
-1.8359-0.0573
-1.8193-0.0676
-1.8071-0.0788
-1.8059-0.0894
-1.8104-0.1031
-1.7875-0.1234
-1.7625-0.1456
-1.7432-0.2047
-1.7289-0.2047
-1.7012-0.2079
-1.6969-0.2105
-1.6948-0.2182
-1.694-0.223
-1.6926-0.2267
-1.6904-0.2294
-1.6873-0.2324
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-1.6782-0.2835
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-1.6615-0.3184
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-1.6715-0.3453
-1.6709-0.3522
-1.6691-0.357
-1.664-0.3622
-1.6578-0.368
-1.6534-0.373
-1.6531-0.3774
-1.655-0.3915
cool
heat
temperature [C]
heat flow (endo up) [mW]
6MG w pre
coolheat
-27.730.344-20.232.5817
-28.23-3.5363-20.732.5825
-28.73-3.9883-21.232.583
-29.23-3.9497-21.732.5826
-29.73-3.8482-22.232.5833
-30.23-3.7398-22.732.5861
-30.73-3.634-23.232.6
-31.23-3.5321-23.732.7299
-31.73-3.4371-24.233.359
-32.23-3.3462-24.734.4164
-32.73-3.2586-25.235.1053
-33.23-3.1769-25.735.4057
-33.73-3.0977-26.235.4582
-34.23-3.0174-26.735.3997
-34.73-2.9396-27.235.316
-35.23-2.8703-27.735.2222
-35.73-2.8042-28.235.1234
-36.23-2.7386-28.735.0273
-36.73-2.6731-29.234.938
-37.23-2.6101-29.734.8522
-37.73-2.5499-30.234.7683
-38.23-2.4912-30.734.6886
-38.73-2.4343-31.234.6165
-39.23-2.3771-31.734.5481
-39.73-2.3265-32.234.4794
-40.23-2.2802-32.734.4098
-40.73-2.2358-33.234.35
-41.23-2.1944-33.734.292
-41.73-2.1495-34.234.2343
-42.23-2.1031-34.734.1818
-42.73-2.0561-35.234.1308
-43.23-2.0043-35.734.0797
-43.73-1.958-36.234.0251
-44.23-1.917-36.733.9659
-44.73-1.8794-37.233.9167
-45.23-1.8432-37.733.8724
-45.73-1.8067-38.233.832
-46.23-1.7699-38.733.7902
-46.73-1.7337-39.233.7539
-47.23-1.6987-39.733.7185
-47.73-1.664-40.233.6831
-48.23-1.6305-40.733.6463
-48.73-1.5986-41.233.6111
-49.23-1.568-41.733.5791
-49.73-1.5379-42.233.5504
-50.23-1.5083-42.733.5221
-50.73-1.4776-43.233.4924
-51.23-1.4477-43.733.4622
-51.73-1.4174-44.233.4338
-52.23-1.3882-44.733.4084
-52.73-1.3589-45.233.3834
-53.23-1.3322-45.733.3584
-53.73-1.3069-46.233.3381
-54.23-1.2838-46.733.3185
-54.73-1.2614-47.233.2991
-55.23-1.2383-47.733.2776
-55.73-1.2143-48.233.2545
-56.23-1.1901-48.733.239
-56.73-1.1638-49.233.2262
-57.23-1.1369-49.733.2085
-57.73-1.1099-50.233.1915
-58.23-1.0831-50.733.173
-58.73-1.0584-51.233.156
-59.23-1.0333-51.733.1395
-59.73-1.0094-52.233.123
-60.23-0.9849-52.733.1069
-60.73-0.9623-53.233.0912
-61.23-0.9395-53.733.0787
-61.73-0.9161-54.233.0833
-62.23-0.8921-54.733.0895
-62.73-0.8669-55.233.0851
-63.23-0.8423-55.733.0804
-63.73-0.8195-56.233.0737
-64.23-0.7983-56.733.0647
-64.73-0.7798-57.233.0529
-65.23-0.76-57.733.0376
-65.73-0.7314-58.233.021
-66.23-0.7074-58.732.9963
-66.73-0.6854-59.232.9721
-67.23-0.6614-59.732.9426
-67.73-0.6377-60.232.9152
-68.23-0.6167-60.732.9005
-68.73-0.6015-61.232.8912
-69.23-0.5856-61.732.8643
-69.73-0.5651-62.232.8331
-70.23-0.5449-62.732.8009
-70.73-0.5262-63.232.77
-71.23-0.5069-63.732.7376
-71.73-0.4874-64.232.7032
-72.23-0.4684-64.732.6675
-72.73-0.4506-65.232.6324
-73.23-0.4328-65.732.6044
-73.73-0.4143-66.232.5774
-74.23-0.3966-66.732.5512
-74.73-0.3834-67.232.5319
-75.23-0.3714-67.732.519
-75.73-0.3608-68.232.5069
-76.23-0.3513-68.732.4902
-76.73-0.3407-69.232.472
-77.23-0.3291-69.732.4578
-77.73-0.3155-70.232.4509
-78.23-0.3029-70.732.4443
-78.73-0.2919-71.232.4393
-79.23-0.2801-71.732.4361
-79.73-0.2685-72.232.4348
-80.23-0.2574-72.732.4351
-80.73-0.2479-73.232.4362
-81.23-0.2413-73.732.4372
-81.73-0.2347-74.232.4341
-82.23-0.2248-74.732.4307
-82.73-0.2144-75.232.43
-83.23-0.2027-75.732.4324
-83.73-0.1916-76.232.436
-84.23-0.1801-76.732.4395
-84.73-0.1686-77.232.4431
-85.23-0.1581-77.732.4487
-85.73-0.15-78.232.4575
-86.23-0.1446-78.732.4651
-86.73-0.1417-79.232.462
-87.23-0.1384-79.732.4573
-87.73-0.1332-80.232.4619
-88.23-0.1248-80.732.4671
-88.73-0.117-81.232.4713
-89.23-0.1099-81.732.4736
-89.73-0.1016-82.232.475
-90.23-0.0926-82.732.4765
-90.73-0.0807-83.232.4781
-91.23-0.0701-83.732.4804
-91.73-0.0611-84.232.4837
-92.23-0.0538-84.732.4873
-92.73-0.0474-85.232.4918
-93.23-0.0398-85.732.4961
-93.73-0.0318-86.232.5006
-94.23-0.024-86.732.5035
-94.73-0.0156-87.232.5039
-95.23-0.0081-87.732.5092
-95.73-0.0003002-88.232.5165
-96.230.0092-88.732.5239
-96.730.0199-89.232.5288
-97.230.0329-89.732.5325
-97.730.0448-90.232.5362
-98.230.0579-90.732.5399
-98.730.0732-91.232.5429
-99.230.089-91.732.5461
-99.730.1067-92.232.5519
-100.230.1248-92.732.558
-100.730.1478-93.232.5619
-101.230.1677-93.732.5632
-101.730.1886-94.232.5654
-102.230.2099-94.732.5697
-102.730.233-95.232.5769
-103.230.2567-95.732.587
-103.730.2804-96.232.6003
-104.230.3029-96.732.6159
-104.730.323-97.232.638
-105.230.3429-97.732.6599
-105.730.3656-98.232.6816
-106.230.3904-98.732.6997
-106.730.4151-99.232.7031
-107.230.4384-99.732.702
-107.730.4576-100.232.6873
-108.230.4706-100.732.6558
-108.730.4812-101.232.6129
-109.230.4934-101.732.5631
-109.730.5098-102.232.5092
-110.230.5316-102.732.4534
-110.730.5461-103.232.4007
-111.230.5616-103.732.3579
-111.730.5751-104.232.3206
-112.230.587-104.732.2977
-112.730.5971-105.232.2797
-113.230.608-105.732.2622
-113.730.6168-106.232.2441
-114.230.6239-106.732.2267
-114.730.6317-107.232.2144
-115.230.6437-107.732.2016
-115.730.6594-108.232.189
-116.230.6741-108.732.1778
-116.730.6845-109.232.1729
-117.230.6926-109.732.1762
-117.730.6987-110.232.1798
-118.230.7047-110.732.1817
-118.730.7116-111.232.1806
-119.230.7211-111.732.1783
-119.730.7296-112.232.1777
-120.230.7385-112.732.1785
-120.730.747-113.232.1802
-121.230.7559-113.732.1812
-121.730.7658-114.232.1822
-122.230.7733-114.732.1826
-122.730.7787-115.232.1841
-123.230.7839-115.732.1864
-123.730.7909-116.232.1892
-124.230.7996-116.732.193
-124.730.8077-117.232.1933
-125.230.8137-117.732.1918
-125.730.8171-118.232.1886
-126.230.8201-118.732.1892
-126.730.8247-119.232.192
-127.230.8315-119.732.1972
-127.730.8406-120.232.1969
-128.230.8493-120.732.196
-128.730.8581-121.232.1944
-129.230.8663-121.732.1952
-129.730.8724-122.232.1964
-130.230.8777-122.732.1969
-130.730.8824-123.232.1968
-131.230.889-123.732.1981
-131.730.8963-124.232.202
-132.230.904-124.732.206
-132.730.9119-125.232.2092
-133.230.9188-125.732.2113
-133.730.9252-126.232.2141
-134.230.9313-126.732.2164
-134.730.942-127.232.2175
-135.230.9532-127.732.2187
-135.730.9607-128.232.2207
-136.230.964-128.732.2218
-136.730.9681-129.232.222
-137.230.9727-129.732.2207
-137.730.9775-130.232.2203
-138.230.9823-130.732.221
-138.730.9876-131.232.2236
-139.230.9931-131.732.2284
-139.731.0004-132.232.2341
-140.231.0079-132.732.2324
-140.731.0142-133.232.2316
-141.231.0191-133.732.2312
-141.731.0232-134.232.2314
-142.231.0257-134.732.2317
-142.731.0285-135.232.2331
-143.231.0309-135.732.2359
-143.731.0391-136.232.2394
-144.231.0488-136.732.2437
-144.731.0582-137.232.2468
-145.231.0653-137.732.2495
-145.731.0662-138.232.2509
-146.231.0638-138.732.2525
-146.731.0758-139.232.2549
-147.231.0815-139.732.2574
-147.731.0882-140.232.2589
-148.231.0932-140.732.2599
-148.731.0972-141.232.2598
-149.231.0998-141.732.2599
-149.731.1036-142.232.2601
-142.732.2597
-143.232.2599
-143.732.2599
-144.232.261
-144.732.2637
-145.232.2675
-145.732.2715
-146.232.2739
-146.732.2754
-147.232.2764
-147.732.2767
-148.232.2755
-148.732.2725
-149.232.2645
-149.732.2271
6MG w pre
cool
heat
temperature [C]
heat flow (endo up) [mW]
6MG wo pre
coolheat
-20.23-2.6434-20.432.1149
-20.73-2.6385-20.932.1089
-21.23-2.6378-21.432.1022
-21.73-2.6361-21.932.0963
-22.23-2.6376-22.432.092
-22.73-2.6378-22.932.1871
-23.23-2.6377-23.432.8509
-23.73-2.6375-23.934.1432
-24.23-2.6403-24.435.0136
-24.73-2.6442-24.935.4065
-25.23-2.6469-25.435.5126
-25.73-2.6485-25.935.4221
-26.23-2.648-26.435.2933
-26.73-2.6483-26.935.157
-27.23-2.6479-27.435.0305
-27.73-2.6464-27.934.906
-28.23-2.6437-28.434.7807
-28.73-2.6368-28.934.66
-29.23-2.6327-29.434.5521
-29.73-2.6384-29.934.4482
-30.23-2.6438-30.434.3458
-30.73-2.6438-30.934.2436
-31.23-2.6426-31.434.1483
-31.73-2.6419-31.934.0549
-32.23-2.642-32.433.9656
-32.73-2.64-32.933.8748
-33.23-2.6387-33.433.7908
-33.73-2.6394-33.933.7155
-34.23-2.6449-34.433.6415
-34.73-2.6506-34.933.5687
-35.23-2.6551-35.433.4977
-35.73-2.6555-35.933.4292
-36.23-2.6547-36.433.3617
-36.73-2.6542-36.933.2975
-37.23-2.6516-37.433.2337
-37.73-2.6499-37.933.1722
-38.23-2.648-38.433.124
-38.73-2.6451-38.933.0754
-39.23-2.6436-39.433.0247
-39.73-2.644-39.932.9726
-40.23-2.6466-40.432.9204
-40.73-2.6491-40.932.8701
-41.23-2.6564-41.432.8248
-41.73-2.6514-41.932.7784
-42.23-2.646-42.432.7329
-42.73-2.6416-42.932.6874
-43.23-2.6399-43.432.6424
-43.73-2.6386-43.932.5981
-44.23-2.6389-44.432.5583
-44.73-2.6368-44.932.5174
-45.23-2.634-45.432.4734
-45.73-2.6303-45.932.4361
-46.23-2.6284-46.432.4044
-46.73-2.6283-46.932.3712
-47.23-2.6296-47.432.3329
-47.73-2.6295-47.932.2888
-48.23-2.6283-48.432.2519
-48.73-2.6283-48.932.2208
-49.23-2.6291-49.432.1905
-49.73-2.6309-49.932.1596
-50.23-2.6581-50.432.1292
-50.73-2.6396-50.932.1011
-51.23-2.6377-51.432.0719
-51.73-2.6365-51.932.043
-52.23-2.635-52.432.0159
-52.73-2.6353-52.931.9871
-53.23-2.6379-53.431.9575
-53.73-2.6427-53.931.9294
-54.23-2.6444-54.431.9036
-54.73-2.6384-54.931.8804
-55.23-2.6338-55.431.874
-55.73-2.6307-55.931.8247
-56.23-2.6296-56.431.817
-56.73-2.6273-56.931.7958
-57.23-2.6243-57.431.7745
-57.73-2.6199-57.931.7542
-58.23-2.6177-58.431.7343
-58.73-2.6259-58.931.7143
-59.23-2.642-59.431.6962
-59.73-2.6634-59.931.6787
-60.23-2.6925-60.431.6591
-60.73-2.7285-60.931.6376
-61.23-2.7737-61.431.6172
-61.73-2.82-61.931.5976
-62.23-2.8707-62.431.5804
-62.73-2.9253-62.931.5617
-63.23-2.9796-63.431.5445
-63.73-3.047-63.931.5256
-64.23-3.1171-64.431.5049
-64.73-3.1869-64.931.483
-65.23-3.2528-65.431.4597
-65.73-3.3037-65.931.4366
-66.23-3.342-66.431.4146
-66.73-3.3672-66.931.3953
-67.23-3.3944-67.431.3792
-67.73-3.4168-67.931.3626
-68.23-3.4118-68.431.3447
-68.73-3.4026-68.931.327
-69.23-3.3933-69.431.307
-69.73-3.3837-69.931.2861
-70.23-3.3726-70.431.268
-70.73-3.3581-70.931.2522
-71.23-3.3433-71.431.2387
-71.73-3.3276-71.931.2232
-72.23-3.3115-72.431.1979
-72.73-3.2902-72.931.17
-73.23-3.2624-73.431.1521
-73.73-3.2287-73.931.1378
-74.23-3.1943-74.431.1249
-74.73-3.1613-74.931.1073
-75.23-3.13-75.431.0858
-75.73-3.0965-75.931.0636
-76.23-3.0615-76.431.0442
-76.73-3.0338-76.931.0241
-77.23-3.0001-77.431.0051
-77.73-2.9679-77.930.987
-78.23-2.9385-78.430.9714
-78.73-2.9116-78.930.9538
-79.23-2.8864-79.430.9355
-79.73-2.8632-79.930.9164
-80.23-2.8401-80.430.8964
-80.73-2.8168-80.930.8781
-81.23-2.7903-81.430.859
-81.73-2.7653-81.930.8385
-82.23-2.741-82.430.8167
-82.73-2.7209-82.930.7979
-83.23-2.7024-83.430.779
-83.73-2.6843-83.930.7624
-84.23-2.6676-84.430.7449
-84.73-2.6517-84.930.7287
-85.23-2.6389-85.430.7139
-85.73-2.6271-85.930.7007
-86.23-2.6156-86.430.689
-86.73-2.6063-86.930.6769
-87.23-2.598-87.430.6629
-87.73-2.594-87.930.6456
-88.23-2.5885-88.430.6274
-88.73-2.5792-88.930.6094
-89.23-2.5688-89.430.5909
-89.73-2.5582-89.930.5638
-90.23-2.5481-90.430.5304
-90.73-2.5386-90.930.4927
-91.23-2.5296-91.430.4539
-91.73-2.5229-91.930.4119
-92.23-2.5238-92.430.3631
-92.73-2.5265-92.930.301
-93.23-2.5289-93.430.2289
-93.73-2.5314-93.930.1433
-94.23-2.533-94.430.0302
-94.73-2.5329-94.93-0.117
-95.23-2.5296-95.43-0.3189
-95.73-2.5264-95.93-0.5892
-96.23-2.5243-96.43-0.933
-96.73-2.5217-96.93-1.3446
-97.23-2.5186-97.43-1.8029
-97.73-2.513-97.93-2.2806
-98.23-2.5067-98.43-2.7426
-98.73-2.4993-98.93-3.123
-99.23-2.4923-99.43-3.3319
-99.73-2.4863-99.93-3.2865
-100.23-2.4792-100.43-2.9586
-100.73-2.4703-100.93-2.4102
-101.23-2.4611-101.43-1.7663
-101.73-2.4503-101.93-1.1377
-102.23-2.4404-102.43-0.6063
-102.73-2.432-102.93-0.1939
-103.23-2.4253-103.430.1062
-103.73-2.4201-103.930.3156
-104.23-2.4147-104.430.455
-104.73-2.4089-104.930.5458
-105.23-2.4016-105.430.6065
-105.73-2.3917-105.930.6437
-106.23-2.3823-106.430.666
-106.73-2.3749-106.930.6764
-107.23-2.3717-107.430.6844
-107.73-2.37-107.930.6906
-108.23-2.369-108.430.6966
-108.73-2.3656-108.930.6997
-109.23-2.3584-109.430.7025
-109.73-2.3502-109.930.704
-110.23-2.3414-110.430.708
-110.73-2.3326-110.930.7186
-111.23-2.3247-111.430.748
-111.73-2.3173-111.930.7844
-112.23-2.3099-112.430.8206
-112.73-2.2975-112.930.8408
-113.23-2.2813-113.430.8369
-113.73-2.2646-113.930.8019
-114.23-2.2463-114.430.7416
-114.73-2.2256-114.930.662
-115.23-2.2052-115.430.5809
-115.73-2.185-115.930.5056
-116.23-2.1652-116.430.4342
-116.73-2.1425-116.930.3708
-117.23-2.1183-117.430.3128
-117.73-2.0938-117.930.2593
-118.23-2.0714-118.430.2136
-118.73-2.0523-118.930.1739
-119.23-2.0392-119.430.1446
-119.73-2.0208-119.930.1221
-120.23-2.0018-120.430.1018
-120.73-1.9841-120.930.0851
-121.23-1.9677-121.430.0674
-121.73-1.9533-121.930.0546
-122.23-1.9409-122.430.0431
-122.73-1.9318-122.930.0329
-123.23-1.9268-123.430.021
-123.73-1.9074-123.93-0.0129
-124.23-1.8686-124.43-0.0398
-124.73-1.8521-124.93-0.0486
-125.23-1.8359-125.43-0.0573
-125.73-1.8193-125.93-0.0676
-126.23-1.8071-126.43-0.0788
-126.73-1.8059-126.93-0.0894
-127.23-1.8104-127.43-0.1031
-127.73-1.7875-127.93-0.1234
-128.23-1.7625-128.43-0.1456
-128.73-1.7432-128.93-0.2047
-129.23-1.7289-129.43-0.2047
-129.73-1.7012-129.93-0.2079
-130.23-1.6969-130.43-0.2105
-130.73-1.6948-130.93-0.2182
-131.23-1.694-131.43-0.223
-131.73-1.6926-131.93-0.2267
-132.23-1.6904-132.43-0.2294
-132.73-1.6873-132.93-0.2324
-133.23-1.6859-133.43-0.2358
-133.73-1.6849-133.93-0.2401
-134.23-1.684-134.43-0.2453
-134.73-1.6834-134.93-0.2524
-135.23-1.6824-135.43-0.2617
-135.73-1.682-135.93-0.2711
-136.23-1.6801-136.43-0.2789
-136.73-1.6782-136.93-0.2835
-137.23-1.6773-137.43-0.2867
-137.73-1.6796-137.93-0.2904
-138.23-1.6804-138.43-0.2975
-138.73-1.6791-138.93-0.3055
-139.23-1.6859-139.43-0.313
-139.73-1.6615-139.93-0.3184
-140.23-1.6649-140.43-0.3227
-140.73-1.669-140.93-0.327
-141.23-1.6719-141.43-0.3298
-141.73-1.6721-141.93-0.3331
-142.23-1.6719-142.43-0.338
-142.73-1.6715-142.93-0.3453
-143.23-1.6709-143.43-0.3522
-143.73-1.6691-143.93-0.357
-144.23-1.664-144.43-0.3622
-144.73-1.6578-144.93-0.368
-145.23-1.6534-145.43-0.373
-145.73-1.6531-145.93-0.3774
-146.23-1.655-146.43-0.3915
6MG wo pre
cool
heat
temperature [C]
heat flow (endo up) [mW]
Sheet3
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-7.54.2378
-7.60.7844
-7.7-1.9764
-7.8-4.2075
-7.9-6.0753
-8-7.6376
-8.1-8.9539
-8.2-10.042
-8.3-10.95
-8.4-11.7045
-8.5-12.3182
-8.6-12.8142
-8.7-13.1995
-8.8-13.4838
-8.9-13.6881
-9-13.8186
-9.1-13.8838
-9.2-13.8917
-9.3-13.8407
-9.4-13.7479
-9.5-13.6169
-10-12.5874
-10.5-11.3551
-11-10.1875
-11.5-9.1958
-12-8.3595
-12.5-7.6557
-13-7.064
-13.5-6.5529
-14-6.1003
-14.5-5.7101
-15-5.3545
-15.5-5.0412
-16-4.754
-16.5-4.4957
-17-4.2641
-17.5-4.054
-18-3.8533
-18.5-3.6709
-19-3.508
-19.5-3.36
-20-3.2177
-20.5-3.0811
-21-2.9563
-21.5-2.8417
-22-2.7327
-22.5-2.6297
-23-2.5341
-23.5-2.4438
-24-2.3577
-24.5-2.2771
-25-2.2015
-25.5-2.1275
-26-2.0555
-26.5-1.985
-27-1.9214
-27.5-1.8625
-28-1.8037
-28.5-1.7463
-29-1.6905
-29.5-1.6456
-30-1.6004
-30.5-1.555
-31-1.509
-31.5-1.4639
-32-1.4196
-32.5-1.3775
-33-1.3301
-33.5-1.2982
-34-1.2642
-34.5-1.2299
-35-1.1965
-35.5-1.164
-36-1.1326
-36.5-1.1022
-37-1.0726
-37.5-1.0443
-38-1.016
-38.5-0.9867
-39-0.9555
-39.5-0.9224
-40-0.8934
-40.5-0.8669
-41-0.843
-41.5-0.8192
-42-0.7974
-42.5-0.7752
-43-0.7538
-43.5-0.7323
-44-0.7108
-44.5-0.6849
-45-0.6615
-45.5-0.6393
-46-0.6186
-46.5-0.6006
-47-0.58
-47.5-0.5604
-48-0.5417
-48.5-0.5241
-49-0.506
-49.5-0.4869
-50-0.4685
-50.5-0.4506
-51-0.4331
-51.5-0.4167
-52-0.4022
-52.5-0.3866
-53-0.369
-53.5-0.3498
-54-0.3317
-54.5-0.3153
-55-0.2997
-55.5-0.2851
-56-0.2705
-56.5-0.2557
-57-0.2416
-57.5-0.2268
-58-0.2109
-58.5-0.1936
-59-0.1735
-59.5-0.156
-60-0.1416
-60.5-0.1285
-61-0.1157
-61.5-0.101
-62-0.0856
-62.5-0.0695
-63-0.0545
-63.5-0.04
-64-0.0257
-64.5-0.0125
-650.00075584
-65.50.0135
-660.0267
-66.50.0406
-670.0548
-67.50.0719
-680.0883
-68.50.0991
-690.1106
-69.50.1224
-700.1343
-70.50.146
-710.1588
-71.50.1715
-720.1839
-72.50.1949
-730.2059
-73.50.2177
-740.2288
-74.50.2385
-750.2481
-75.50.2574
-760.2668
-76.50.274
-770.2811
-77.50.2896
-780.3005
-78.50.3126
-790.3249
-79.50.3361
-800.3448
-80.50.3514
-810.3564
-81.50.3617
-820.3676
-82.50.3747
-830.3841
-83.50.3931
-840.4011
-84.50.4082
-850.4145
-85.50.4197
-860.4243
-86.50.4288
-870.4341
-87.50.4393
-880.4441
-88.50.4496
-890.455
-89.50.4605
-900.4654
Sheet3
Sheet4
Filename:\\Dsc.me.umn.edu\e\Pyris\Data\Choiboy\20031229-1xPBS+2MGlyc(New)\1xPBS+2MGlyc(New)_Pre2.dcd
Temperature (C)Heat Flow Endo Up (mW)
-7.614.3448
-7.514.5896
-7.414.8318
-7.315.0778
-7.215.3191
-7.115.5622
-715.8051
-6.916.0487
-6.816.2862
-6.716.5212
-6.616.7465
-6.516.9735
-6.417.1857
-6.317.3891
-6.217.5775
-6.117.751
-617.8919
-5.918.0068
-5.818.0906
-5.718.1413
-5.618.1348
-5.518.0768
-5.417.9425
-5.317.7209
-5.217.398
-5.116.9409
-516.3216
-4.915.561
-4.814.6679
-4.713.5972
-4.612.3308
-4.510.9292
-4.49.3541
-4.37.7244
-4.26.1263
-4.14.6647
-43.5797
-3.92.9633
-3.82.6937
-3.72.5702
-3.62.5141
-3.52.4912
-3.42.483
-3.32.4776
-3.22.4727
-3.12.4708
-32.4712
-2.92.4707
-2.82.471
-2.72.471
-2.62.4716
-2.52.4719
-2.42.4722
-2.32.4724
-2.22.4734
-2.12.4741
-22.4768
-1.92.4786
-1.82.48
-1.72.4814
-1.62.4828
-1.52.484
-1.42.4855
-1.32.4868
-1.22.4875
-1.12.4882
-12.4891
-0.92.4903
-0.82.4912
-0.72.4922
-0.62.4931
-0.52.4938
-0.42.4944
-0.32.4954
-0.22.4969
-0.12.4992
Sheet4
Proc
supercooled nucleationpartial meltingprenucleated coolingcomplete melting
-0.1-2.1708-352.6071-7.54.2378-7.614.3448
-0.5-2.163-34.52.6186-7.60.7844-7.514.5896
-1-2.1501-342.6314-7.7-1.9764-7.414.8318
-1.5-2.1374-33.52.6473-7.8-4.2075-7.315.0778
-2-2.1236-332.6648-7.9-6.0753-7.215.3191
-2.5-2.1109-32.52.6833-8-7.6376-7.115.5622
-3-2.0971-322.7034-8.1-8.9539-715.8051
-3.5-2.0929-31.52.7251-8.2-10.042-6.916.0487
-4-2.0862-312.7482-8.3-10.95-6.816.2862
-4.5-2.0779-30.52.7763-8.4-11.7045-6.716.5212
-5-2.0693-302.8054-8.5-12.3182-6.616.7465
-5.5-2.0599-29.52.8332-8.6-12.8142-6.516.9735
-6-2.0502-292.8607-8.7-13.1995-6.417.1857
-6.5-2.0395-28.52.8883-8.8-13.4838-6.317.3891
-7-2.0288-282.9175-8.9-13.6881-6.217.5775
-7.5-2.0188-27.52.9546-9-13.8186-6.117.751
-8-2.0081-272.9908-9.1-13.8838-617.8919
-8.5-1.9968-26.53.0291-9.2-13.8917-5.918.0068
-9-1.9866-263.0701-9.3-13.8407-5.818.0906
-9.5-1.9761-25.53.1136-9.4-13.7479-5.718.1413
-10.00-1.9678-253.1621-9.5-13.6169-5.618.1348
-10.5-1.9581-24.53.2115-10-12.5874-5.518.0768
-11-1.9474-243.2677-10.5-11.3551-5.417.9425
-11.5-1.9345-23.53.3274-11-10.1875-5.317.7209
-12-1.9256-233.3981-11.5-9.1958-5.217.398
-12.5-1.9185-22.53.4714-12-8.3595-5.116.9409
-13-1.9128-223.5512-12.5-7.6557-516.3216
-13.5-1.9073-21.53.6297-13-7.064-4.915.561
-14-1.9015-213.7108-13.5-6.5529-4.814.6679
-14.5-1.8923-20.53.8038-14-6.1003-4.713.5972
-15-1.8785-203.9032-14.5-5.7101-4.612.3308
-15.5-1.867-19.54.0167-15-5.3545-4.510.9292
-16-1.8569-194.1324-15.5-5.0412-4.49.3541
-16.5-1.8461-18.54.257-16-4.754-4.37.7244
-17-1.8334-184.3954-16.5-4.4957-4.26.1263
-17.5-1.8218-17.54.548-17-4.2641-4.14.6647
-18-1.8148-174.7115-17.5-4.054-43.5797
-18.5-1.8077-16.54.8942-18-3.8533-3.92.9633
-19-1.8035-165.0896-18.5-3.6709-3.82.6937
-19.5-1.7992-15.55.3057-19-3.508-3.72.5702
-20-1.7923-155.5503-19.5-3.36-3.62.5141
-20.5-1.7789-14.55.8108-20-3.2177-3.52.4912
-21-1.7678-146.0964-20.5-3.0811-3.42.483
-21.5-1.7585-13.56.4089-21-2.9563-3.32.4776
-22-1.7479-136.7517-21.5-2.8417-3.22.4727
-22.5-1.739-12.57.1382-22-2.7327-3.12.4708
-23-1.7303-127.5661-22.5-2.6297-32.4712
-23.5-1.7218-11.58.0436-23-2.5341-2.92.4707
-24-1.7126-118.5693-23.5-2.4438-2.82.471
-24.5-1.7027-10.59.1652-24-2.3577-2.72.471
-25-1.6941-109.8355-24.5-2.2771-2.62.4716
-25.5-1.6857-9.510.5948-25-2.2015-2.52.4719
-26-1.6786-911.4464-25.5-2.1275-2.42.4722
-26.5-1.6729-8.712.0067-26-2.0555-2.32.4724
-27-1.667-8.412.6064-26.5-1.985-2.22.4734
-27.5-1.6604-8.113.2457-27-1.9214-2.12.4741
-28-1.653-7.913.6957-27.5-1.8625-22.4768
-28.5-1.6454-7.714.1603-28-1.8037-1.92.4786
-29-1.6389-7.614.3986-28.5-1.7463-1.82.48
-29.5-1.628-29-1.6905-1.72.4814
-30-1.6162-29.5-1.6456-1.62.4828
-30.5-1.6129-30-1.6004-1.52.484
-31-1.6035-30.5-1.555-1.42.4855
-31.5-1.6003-31-1.509-1.32.4868
-31.6-1.5966-31.5-1.4639-1.22.4875
-31.7-150.4972-32-1.4196-1.12.4882
-31.8-101.5396-32.5-1.3775-12.4891
-31.9-56.4215-33-1.3301-0.92.4903
-32-31.4601-33.5-1.2982-0.82.4912
-32.1-13.7891-34-1.2642-0.72.4922
-32.2-4.0918-34.5-1.2299-0.62.4931
-32.3-0.592-35-1.1965-0.52.4938
-32.4-0.0905-35.5-1.164-0.42.4944
-32.5-0.4746-36-1.1326-0.32.4954
-33-1.3559-36.5-1.1022-0.22.4969
-33.5-1.3185-37-1.0726-0.12.4992
-34-1.2679-37.5-1.0443
-34.5-1.2254-38-1.016
-35-1.1929-38.5-0.9867
-39-0.9555
-39.5-0.9224
-40-0.8934
-40.5-0.8669
-41-0.843
-41.5-0.8192
-42-0.7974
-42.5-0.7752
-43-0.7538
-43.5-0.7323
-44-0.7108
-44.5-0.6849
-45-0.6615
-45.5-0.6393
-46-0.6186
-46.5-0.6006
-47-0.58
-47.5-0.5604
-48-0.5417
-48.5-0.5241
-49-0.506
-49.5-0.4869
-50-0.4685
-50.5-0.4506
-51-0.4331
-51.5-0.4167
-52-0.4022
-52.5-0.3866
-53-0.369
-53.5-0.3498
-54-0.3317
-54.5-0.3153
-55-0.2997
-55.5-0.2851
-56-0.2705
-56.5-0.2557
-57-0.2416
-57.5-0.2268
-58-0.2109
-58.5-0.1936
-59-0.1735
-59.5-0.156
-60-0.1416
-60.5-0.1285
-61-0.1157
-61.5-0.101
-62-0.0856
-62.5-0.0695
-63-0.0545
-63.5-0.04
-64-0.0257
-64.5-0.0125
-650.00075584
-65.50.0135
-660.0267
-66.50.0406
-670.0548
-67.50.0719
-680.0883
-68.50.0991
-690.1106
-69.50.1224
-700.1343
-70.50.146
-710.1588
-71.50.1715
-720.1839
-72.50.1949
-730.2059
-73.50.2177
-740.2288
-74.50.2385
-750.2481
-75.50.2574
-760.2668
-76.50.274
-770.2811
-77.50.2896
-780.3005
-78.50.3126
-790.3249
-79.50.3361
-800.3448
-80.50.3514
-810.3564
-81.50.3617
-820.3676
-82.50.3747
-830.3841
-83.50.3931
-840.4011
-84.50.4082
-850.4145
-85.50.4197
-860.4243
-86.50.4288
-870.4341
-87.50.4393
-880.4441
-88.50.4496
-890.455
-89.50.4605
-900.4654
Proc
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
supercooled nucleation
partial melting
prenucleated cooling
complete melting
temperature [C]
heat flow (endo up) [mW]
Chart7
0.3442.5817
-3.53632.5825
-3.98832.583
-3.94972.5826
-3.84822.5833
-3.73982.5861
-3.6342.6
-3.53212.7299
-3.43713.359
-3.34624.4164
-3.25865.1053
-3.17695.4057
-3.09775.4582
-3.01745.3997
-2.93965.316
-2.87035.2222
-2.80425.1234
-2.73865.0273
-2.67314.938
-2.61014.8522
-2.54994.7683
-2.49124.6886
-2.43434.6165
-2.37714.5481
-2.32654.4794
-2.28024.4098
-2.23584.35
-2.19444.292
-2.14954.2343
-2.10314.1818
-2.05614.1308
-2.00434.0797
-1.9584.0251
-1.9173.9659
-1.87943.9167
-1.84323.8724
-1.80673.832
-1.76993.7902
-1.73373.7539
-1.69873.7185
-1.6643.6831
-1.63053.6463
-1.59863.6111
-1.5683.5791
-1.53793.5504
-1.50833.5221
-1.47763.4924
-1.44773.4622
-1.41743.4338
-1.38823.4084
-1.35893.3834
-1.33223.3584
-1.30693.3381
-1.28383.3185
-1.26143.2991
-1.23833.2776
-1.21433.2545
-1.19013.239
-1.16383.2262
-1.13693.2085
-1.10993.1915
-1.08313.173
-1.05843.156
-1.03333.1395
-1.00943.123
-0.98493.1069
-0.96233.0912
-0.93953.0787
-0.91613.0833
-0.89213.0895
-0.86693.0851
-0.84233.0804
-0.81953.0737
-0.79833.0647
-0.77983.0529
-0.763.0376
-0.73143.021
-0.70742.9963
-0.68542.9721
-0.66142.9426
-0.63772.9152
-0.61672.9005
-0.60152.8912
-0.58562.8643
-0.56512.8331
-0.54492.8009
-0.52622.77
-0.50692.7376
-0.48742.7032
-0.46842.6675
-0.45062.6324
-0.43282.6044
-0.41432.5774
-0.39662.5512
-0.38342.5319
-0.37142.519
-0.36082.5069
-0.35132.4902
-0.34072.472
-0.32912.4578
-0.31552.4509
-0.30292.4443
-0.29192.4393
-0.28012.4361
-0.26852.4348
-0.25742.4351
-0.24792.4362
-0.24132.4372
-0.23472.4341
-0.22482.4307
-0.21442.43
-0.20272.4324
-0.19162.436
-0.18012.4395
-0.16862.4431
-0.15812.4487
-0.152.4575
-0.14462.4651
-0.14172.462
-0.13842.4573
-0.13322.4619
-0.12482.4671
-0.1172.4713
-0.10992.4736
-0.10162.475
-0.09262.4765
-0.08072.4781
-0.07012.4804
-0.06112.4837
-0.05382.4873
-0.04742.4918
-0.03982.4961
-0.03182.5006
-0.0242.5035
-0.01562.5039
-0.00812.5092
-0.00030022.5165
0.00922.5239
0.01992.5288
0.03292.5325
0.04482.5362
0.05792.5399
0.07322.5429
0.0892.5461
0.10672.5519
0.12482.558
0.14782.5619
0.16772.5632
0.18862.5654
0.20992.5697
0.2332.5769
0.25672.587
0.28042.6003
0.30292.6159
0.3232.638
0.34292.6599
0.36562.6816
0.39042.6997
0.41512.7031
0.43842.702
0.45762.6873
0.47062.6558
0.48122.6129
0.49342.5631
0.50982.5092
0.53162.