medicion de nanoparticulas con tecnologia “cpc” …

19
MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” APLICADA A INSPECCION DE VEHICULOS 10/17/2019 © TSI Incorporated Francisco Romay, Ph. D. Senior Product Manager Dan Bissell Regional Sales Manager Jürgen Spielvogel Senior Global Product Manager

Upload: others

Post on 25-Jun-2022

2 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

MEDICION DE NANOPARTICULASCON TECNOLOGIA “CPC” APLICADAA INSPECCION DE VEHICULOS

10/17/2019© TSI Incorporated

Francisco Romay, Ph. D.Senior Product Manager

Dan BissellRegional Sales Manager

Jürgen SpielvogelSenior Global Product Manager

Page 2: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

TSI, líder en Medición de Aerosoles

210/17/2019© TSI Incorporated

- Founded in 1961 by students of the University of Minnesota- Since 1967 production of submicron particle sizers- TSI has been building CPCs (3020 CPCs since 1979) and DCs (3070 EAD since 1974)

for more than 40 years.- Today, more than 100 people work on particle measuring instruments every day

Page 3: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

+ Used >20 years in engine emission testing

+ Suitable for Diesel, gasoline, HD engine and aircraft turbine emissions+ Reliable, accurate and traceable results

Medición de Partículas en emisionesde escape de motores con CPCs

Aircraft emissions SAE E-31Solid PN >10nm

Type approval testingEURO 5b/6 – Reg. 83/49

Source: www.horiba.com

Real Driving EmissionsPN-PEMS

NRMM - SR 941.242/Swiss ships SR 747.201.3

310/17/2019© TSI Incorporated

PMP Methodology

Page 4: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

Homologación de Tipo de VehículosMétodo PMP para PN (partículassólidas); Regulaciones 49 y 83

410/17/2019© TSI Incorporated

Horiba MEXA-2000SPCS

Turn-key PMP

Particle number (PN) legislation implementedby EU based on Particulate MeasurementProgramme (PMP) method for solid PN11 Giechaskiel et al., AS&T, 2008

Page 5: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

Principio de Detección en un CPC(Contador de Partículas via Condensación)

510/17/2019© TSI Incorporated

HOT

(1) Saturationwith vapor

(2) Condensationinduced on every

particle

CO

LD

To Pump

> 1 µm

(3) Optical Detection ofevery particle

Pulse height

Each particle generates avoltage pulse

Page 6: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

Porqué usar CPCs?

610/17/2019© TSI Incorporated

+ Direct counting of particles(just like Euro 5/ Euro 6/ upcoming Euro 7)• No assumptions (no dependence on size distribution)• Flow rate can be measured accurately• Pulse height detector for reliable measurements• Experience with excluding volatiles efficiently

+ Sensitive and linear response over full size rangerelevant for this test+ Traceable Calibration is covered by ISO 27891:2015“Aerosol particle number concentration — Calibration of

condensation particle counters”

Page 7: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

Legislación PN para Pruebas deCampo en Maquinaria+ Swiss Ordinance of Air Pollution Control in 2015 isfirst to limit PN emissions for off-road vehicles

• Regulation SR 941.242 mandates in-use compliancetesting of construction machinery DPFs PN measurement in the field

• Followed by SR 747.201.3 for ships on Swisslakes and rivers, mandatory from January 2019710/17/2019© TSI Incorporated

Page 8: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

Solución en Uso: NPETNanoparticle Emission Tester (TSI 3795)

Photo and schematic © TSI Inc.

+ Probe for tailpipe measurement (up to 300°C)+ 1 µm cyclone with water trap+ Integrated, dried 10:1 probe-dilution+ Catalytic stripper+ Isopropanol-based condensation particlecounter (CPC)+ Research/general & official Swiss test mode

8

Page 9: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

Linearidad en Concentración (log scale)3795 NPET and 3790A EECPC

9

80 nm GMD, polydisperseCAST generated soot

Page 10: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

PN-PTI para Maquinaria deConstrucción

1010/17/2019© TSI IncorporatedPresented by S. Krähenbühl (FOEN) at VERT-Forum 2018

CPCs are more sensitive than Opacimeters!

Page 11: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

11

Modo de Operación SR 941.242

NPET

Page 12: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

12

Pruebas en buses con DPF enSantiago, Chile

2014 DPF project in Chile (initiated by ). Fleetupdate of new buses with DFP and a retrofit program.NPET measurements were made at 10 in-use buses inthe official Swiss Mode either as on-route testing or atthe terminal.

Page 13: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

13

Pruebas de DPF en Santiago, Chile –Step 2: 400 buses

„The NPET has opened the eyesof the people involved ininspection and maintenance.”

- Many buses with excellentresults < 5.000 P/cc whereasambient air showed 50.000 P/cc- Small filter failures are visible- Opacity measurement doesnot correlate well to PN

3s acceleration (yellow section), 7 seconds at high idle (high stable portion), return tolow idle for 5 sec, then repeat 3 times with the last 20 seconds at low idle.

Page 14: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

Nueva Iniciativa*: PN-PTI enAlemania, Bélgica y Holanda+ NPET is already the reference in The Netherlands

1410/17/2019© TSI Incorporated

Presented by Louis Zuidgeest (Netherlands Ministry of Infrastructure and Water management) on several ocassions in 2019

* Initiated by

Page 15: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

Mediciones en TNO (Holanda)

15

Source: Presentation at VERT-Forum 2018 by Gerrit KadijkNEWTSI APET (Automotive Particle

Emission Tester)+ Full system+ Lower price

Page 16: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

CPC es un componente delSistema de medición de PN

+ Tailpipe exhaust contains solid particles & volatilecomponents• Need for removing volatiles to avoid nucleation

+ Tailpipe exhaust contains high humidity• Need for drying to avoid condensation – water

+ Tailpipe exhaust can contain a high number of particles• Need for dilution

1610/17/2019© TSI Incorporated

APET

Page 17: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

Nuevo instrumento paraestaciones de servicio – TSI APET

1710/17/2019© TSI Incorporated

Docking Station:- Charging the battery (daily)- Liquid reservoir (1 L, ~1 year)

Automotive Particle Emission Tester:- Complete measurement system:

Sampling + aerosol conditioning+ particle counting

- Lightweight ( < 5kg)- Small (hand held)- Robust (no free liquid)- Low maintenance (yearly)

Page 18: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

ConclusionesCPCs para mediciones de escape

+ Tecnología ProbadaProven technology and in-use for over 20 years (PMP, RDE)+ Medición directa y homologadaDirect measurement & certified single particle counting

• Comparable & reputable results from station to station• Traceable calibration according to ISO 27891

+ CPCs son fáciles de mantenerCPCs are maintenance-free (≥1 Year)• Robust & suitable for workshops. Measurement not affected byvibrations, electric fields, ambient conditions• Liquid (isopropyl alcohol) refill about once a year

+ CPCs están listos para el futuroCPCs are fit for the future• Ready to measure gasoline vehicles• Detection limit can be easily updated from 23 nm to 10 nm(Thousands of TSI‘s 10nm CPCs are in use worldwide) 1810/17/2019© TSI Incorporated

Page 19: MEDICION DE NANOPARTICULAS CON TECNOLOGIA “CPC” …

Gracias por su Atención

1910/17/2019© TSI Incorporated