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Photo by Lovena, Harrisburg, PA

Module 3: Stormwater Effects and Pollutant SourcesRobert Pitt, P.E., Ph.D., DEEDepartment of Civil and Environmental EngineeringThe University of Alabama

Presentation based on material further discussed in: Burton, G.A. Jr., and R. Pitt. Stormwater Effects Handbook: A Tool Box for Watershed Managers, Scientists, and Engineers. ISBN 0-87371-924-7. CRC Press, Inc., Boca Raton, FL. 2002. 911 pages.

Stormwater Management Steps• Identify beneficial use impairments• Identify causes of impairments• Identify sources (magnitude, seasonality,

flow phases, etc.) of problem constituents• Identify, select, and design controls

suitable for problem pollutants and locations

• Implement controls, conduct validation monitoring, modify controls as needed

Major Receiving Water Beneficial Uses

• Stormwater Conveyance (flood prevention)• Recreation (non-water contact) Uses• Biological Uses (Warm water fishery,

aquatic life use, biological integrity, etc.)• Human Health Related Uses (Swimming,

Fishing, and Water Supply)

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Basic Goals for Urban Streams• Stormwater conveyance and aesthetics should

be the basic beneficial use goals for all urban waters.

• Biological integrity should also be a goal, but with the realization that the natural stream ecosystem will be severely modified with urbanization.– “Biological integrity is the capacity to support and

maintain a balanced, integrated and adaptive biological system having the full range of elements [the form] and process [the function] expected in a region’s habitat.” James Karr 1991, modified

• Certain basic stormwater controls at the time of development, plus protection of stream habitat, may enable partial use of some of these goals in urbanized watersheds.

• Water contact recreation, consumptive fisheries, and water supplies are not appropriate goals for most heavily urbanized watersheds.

Receiving Water Effects of Water Pollutant Discharges

• Sediment (amount and quality)• Habitat destruction (mostly through high flows

[energy] and sedimentation)• Eutrophication (nutrient enrichment)• Low dissolved oxygen (from organic materials)• Pathogens (mostly from municipal wastewater and

agricultural runoff)• Toxicants (heavy metals and organic toxicants)• Temperature• Debris and unsafe conditions• etc.

Historical concerns focused on increased flows during rains and associated flooding. However, decreased flows during dry periods are now seen to also cause receiving water problems.

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Bank instability and habitat destruction due to increased flows

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Sediment transported in stormwater causes significant receiving water impacts.

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R. Bannerman photo

One Early Method of Getting Rid of Wastewater

Coombs and Boucher

Wastewater treatmenthas only been aroundsince the late 1800s.People dumped wastesinto gutters and ditches,or sometimes out anopen window. Wastes then flowed into nearest stream or pond.

“Sewer” is from the old English meaning seaward.

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Polluted New York Harbor in 1883

Coombs andBoucher

Gross floatables most important wet weather flow pollutant in many urban areas.

Basic Wastewater Conveyance in Sanitary Condition not Always Achieved

McKinney and Schoch

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Sewage contamination of storm drainage system Beach Closings in the US in 1994(Water Envir. & Tech. 1995)

106 (7.8%)Wastewater Treatment Plant Malfunctions

136 (10%)Agricultural Runoff

194 (14%)Combined Sewer Overflows (CSOs)

345 (25%)Stormwater Runoff

584 (43%)Sanitary Sewer Overflows (SSOs)

Public swimming beach located in utility right-of-way adjacent to stormwater outfall (not uncommon)

Children frequently play in urban creeks, irrespective of their designation as water contact recreation waters

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Fishing in urban waters also occurs, both for recreation and for food.

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Historical approach to urban drainage has been devastating to environment and recharge of groundwaters

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Eutrophication dramatically detracts from recreational uses, along with affecting aquatic life

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Inappropriate discharges, including accidental hazardous material releases, into storm drainage can cause acute receiving water effects.

Cuyahoga River in Cleveland Often Caught on Fire Between 1952 and 1969

Coombs andBoucher

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Whatcom Creek, Bellingham, WA, fire-fighting foam

Fire from 200,000 gallons of spilled gasoline in residential area from pipeline rupture (June 1999)

Bellingham Herald (Washington)

Birmingham News (Alabama)

Alabama has about 200 transportation accidents a year involving hazardous materials. This is typical for most states.

Groundwater ContaminationThe potential for groundwater contamination associated

with stormwater infiltration is often asked.

Book published by Ann Arbor Press/CRC, 219 pages. 1996, based on EPA research and NRC committee work.

Road cut showing direct recharge of Edwards Aquifer, Austin, TX

http://civil.eng.ua.edu/~rpitt/Publications/BooksandReports/Groundwater%20EPA%20report.pdf

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Barton Springs, Austin, TX Example Weak-Link Model Influencing Factors

very lowvery lowmoderateLead

highintermediatehighPyrenemoderateintermediatelowAnthracene

very lowintermediatemoderateChlordane

highmobilelow/moderateNitrates

Filterable Fraction (treatability

Mobility (sandy/low organic soils)

Abundance in Stormwater

Constituent

Links Depend on Infiltration Method(contamination potential is the lowest rating of the

influencing factors)

• Surface infiltration with no pretreatment (grass swales or roof disconnections)– Mobility and abundance most critical

• Surface infiltration with sedimentation pretreatment (treatment train: percolation pond after wet detention pond)– Mobility, abundance, and treatability all

important• Subsurface injection with minimal pretreatment

(infiltration trench in parking lot or dry well)– Abundance most critical

Moderate to High Groundwater Contamination Potential

ChlorideChlorideChloride

Nickel, chromium, lead, zinc

Enteroviruses, some bacteria and protozoa

EnterovirusesEnteroviruses

1,3-dichlorobenzene, benzo (a) anthracene, bis (2-ethylhexl phthalate), fluoranthene, pentachlorophenol, phenanthrene, pyrene

Fluoranthene, pyreneBenzo (a) anthracene, bis (2-ethylhexl phthalate), fluoranthene, pentachlorophenol, phenanthrene, pyrene

Lindane, chlordaneLindane, chlordane

Injection after Minimal Pretreatment

Surface Infiltration after Sedimentation

Surface Infiltration with no Pretreatment

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Basic Premise for Receiving Water Assessments

• No one single approach can be routinely used to accurately determine or predict ecosystem health and beneficial use impairment.

• Each assessment approach or component has associated strengths and weaknesses.

Major Components of Receiving Water Assessments• Chemical (major impairments and uses)• Biological (community tolerance)• Physical/habitat (ecological integrity)• Toxicity (availability of chemical

contaminants)

The complexity of ecosystems require thatthese assessment tools be used in an integrated manner.

Reported State’s Bioassessment Tools• macroinvertebrate surveys (almost all programs,

but with varying identification and sampling efforts)• habitat surveys (almost all programs)• some simple water quality analyses• some watershed characterizations• few fish surveys• limited sediment quality analyses• limited stream flow analyses• hardly any toxicity testing• hardly any comprehensive water quality analyses

The main objectives of most monitoring studies may be divided

into two general categories:

• Characterization (quantifying a few simple attributes of the parameter of interest ), and/or

• comparisons (to standards or reference conditions).

Other common objectives include identifying hot spots, examining trends, etc.

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Experimental Design Issues

• Budget• Basic Study Approach• Duration• Sampling Effort• Sampling Locations• Data Analyses• Quality Control/Quality Assurance

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Basic Study ApproachExperimental designs can be organized in one

of the following basic patterns:

1. Parallel watersheds (developed and undeveloped)

2. Upstream and downstream of a city3. Long-term trend

Preferably, most elements of all of the above approaches can be combined in a staged approach

Parallel Stream Study (urban and rural stream) (Bellevue, WA)

urban

urban

ruralrural

Large Rain

Small Rain

Longitudinal Trend Study (above and below city) (San Jose, CA)

Long-Term Trend Study (Sweden)

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Likely Follow-up Testing

• Short-term chronic toxicity testing with additional species (lab and in situ),

• Increased testing of toxicants,• Characterizing fish, plankton, periphyton, or

mussel populations,• Measuring assimilative capacity via long

term BOD and SOD testing, and/or• Measuring productivity with light/dark bottle

BOD in situ tests.

Source Area Monitoring to Predict Sources of Runoff

Pollutants

• Controlled washoff tests• Small area sheetflow sampling• Large area sheetflow sampling• Outfall monitoring

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Stormwater quality can vary greatly, even at a single site. Variations between events is greater than variations within events.

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Stormwater NPDES Data Collection and Evaluation Project

• The University of Alabama and the Center for Watershed Protection were awarded an EPA 104(b)3 grant in 2001 to collect, review, and analyze selected Phase 1 NPDES stormwater permit data.

• We created a national database, the National Stormwater Quality Database (NSQD), that is available on the Internet, as version 1.1.

• We received an extension of the project in 2005 to expand the database to include under-represented areas. We are currently preparing version 3.1 of the database (version 2 was not posted as it was an interim version that had not undergone complete QA/QC reviews).

Version 3 incorporates version 1.1 data, plus additional MS4 data, along with selected data from the International BMP Database, the USGS, and NURP.

Communities Included in NSQD version 3

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1008,602TOTAL2197Zone 9- Midwest

0.324Zone 8- Rocky Mountains10865Zone 7- Northwest5417Zone 6- Southwest9799Zone 5- Texas4301

Zone 4- Lower Mississippi Valley

9744Zone 3- Southeast463,984Zone 2- Mid Atlantic151,271

Zone 1- Great Lakes and Northeast

PERCENTAGETOTAL EVENTSRAIN ZONE

Number of Events and Geographical Coverage in NSQD ver. 3

1008,602TOTAL5404Open Space9763Freeway3269Mixed Industrial10887Industrial1115Institutional6525Mixed Commercial151,288Commercial151,245Mixed Residential352,979Residential

PERCENTAGETOTAL EVENTSLAND USE

Number of Events and Land Use Coverage in NSQD ver. 3

2.21.71.51.51.71.6COV6,7474434884203,4661,132Count1361261389597155Mean

ALL

2.00.91.01.61.71.2COV2,3461701071221,388332Count11410010910785140Mean

Residential

1.61.21.61.31.01.4COV683244382304100Count1601822449678177Mean

Industrial

1.81.11.62.01.81.2COV934424050454237Count11081676086135Mean

Commercial

All75321

Total Suspended Solids by Land Use and Geographical Area (mg/L)

These grouped box-whisker plots sort all of the data by land use. Kruskal-Wallis analyses indicate that all constituents have at least one significantly different category from the others. Heavy metal differences are most obvious.

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Residential area concentrations grouped by EPA rain zones. Zones 1-4 are east half of country, zones 5-9 are western half of country. Zones 3 and 7 are the wettest zones.

These grouped box-whisker plots sort residential data by sampling season. The most obvious difference is shown for fecal coliforms (a similar conclusion was found during NURP, EPA 1983). (These plots are only for residential data)

Comparison of Control Practices (Residential Land Uses EPA Rain Zone 2) In-Stream and Laboratory

Biological and Toxicity Assessments needed to Identify and Quantify Actual Receiving

Water Problems

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Contaminated sediments in urban receiving waters likely much more responsible for biological impacts than contaminated water.

Fish surveys in urban streams typically find similar biomass as in control streams, but sensitive native fish displaced by hardy exotics

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Benthic macroinvertebrate populations on natural and artificial substrates have been extensively used to indicate receiving water effects.

EXCELLENT

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0 10 20 30 40 50 60 70 80 90 100Watershed Urbanization (%TIA)

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Riparian IntegrityBiotic Integrity

C. May 1996

Toxicity tests using stormwater find much of the toxicity associated with small particulates, not just filtered portions of the water.

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Interstitial water in urban sediments highly contaminated and directly affected by contaminated sediment

WI DNR and USGS tests

Side-stream bioassay tests show chronic toxicity after about 1 to 2 weeks of exposure to urban stream water, and no 96-hr toxicity

Side-stream bioassay tests demonstrated the benefits of stormwater controls for the removal of fine particulates. Residual toxicity remains, however.

WI DNR and USGS tests

Conclusions• We can learn from the past several

decades of receiving water investigations• Problems are site specific and require

sequential investigations• Must use combination of study

components, including:- habitat evaluations, - rain and flow monitoring, - chemical, and biological monitoring, and- toxicity investigations

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Conclusions (continued)• Must evaluate both sediment and water

in most cases• All flow phases (dry and wet weather)

and seasons (including snowmelt) may be important

• May require extensive and long-term effort to obtain data with small uncertainty

• Need to balance resources with study objectives