•".. I• f, "',

~ Rs. 20/-

NORTH MAHARASHTRA UNIVERSITY,JALGAON - 415001

SYLLABUSFOR

M.Sc. [Chemical Technology]From June, 1993

Semester I to IV

~->epartment of Chemical Technology

\,

•

------------- .-----._~-----~--.P-----

M.Sc. CHEMICAL TECHNOLOGY

FIRST YEAR

CHT-H'l1

CHT-102

CHT-103

CHT-J04

CHT-105

CHT-201

CHT-202

CHT-203

CHT-204

APPLIED MATHEMATICS

APPLIED CHEMISTRY

DASIC PRINCIPLES OF CHEMICAL-PROCESSES

COMPUTER PROGRAMMING AND UTILIZATION;

LAEORATORY COURSE-l

SEMESTER - II

MOMENTlDS TRANSFER

CHEMICAL ENGINEERING THERMODYNAMiCS

CHEMICAL PROCESS CALCULATIONS

CHEMICAL PROCESSES TECHNOLOGYLABORATORY COURSE-II

.,

CHT-301

CHT-302CHT-30:3

CHT-304

CHT-305

ClIT-401

CHT-402

CHT-40.'3

CHT-404

CHT-405

SEMESTER - III

t1ATERIAL TECHNOLrlGYCHEMICAL REACTION ENGINEERINGMASS TRASNFER OPERATIONSHEAT TRANSFER OPERATIONSLABORATORY GOURSE III

SEMESTER - IV

INSTRUMENTATION AND PROCESS COllTROLCHEMICAL EQUIPMEHT DESIGNUNIT PROCESSES IN ORGANIC SYNTHESiS.LABORATORY COURSE-IVPROJECT

M. 5c. [CHEi1 i CI1L TECHt>JCLQGYJ

FIRST ~ SEMESTER 1

Scheme of E~aminationInternal E~ternal Total MarksSubject

Subjectcodes

----~--~-------------------~--~----------------~---------------------------~-------------------------~----------------------------CHT-II'l1 APPLIED MATHEMATICS '0 '"CHT-102 APPLIED CHEMISTRY '0 bO '00

CHT~103 BASIC PRINCIPLES OFCHEMICAL PROCESSES 60 '00

CHT-104 COMPUTER PROGRAMMINGAND UTILIZATION '00

CI-IT-105 LABORATORY COURSE-I 60 '00

-------------~-----------------------------~----------------------TOTAL '"----~---------------~-----------~----~-----~---------------------

/

CHT-Hll , APPLIED t'lATHEMATlC5

A) STATISTICS - I-..-equenc:y ci~st'-lbutlon, M"dsures Df cent •..••,ter-dency. mean, meOl"", mode, l1ea"ure of va.rl"bll1ty. R"nge,Percent,1E's. V"''-'il.nCe, 5tandard DevIatIon, s~e",nes5, moments,Discrete ..-andom var,ablE''', Normal dlstrlbutl<:m. P,-opertles ofno,-ma1 d,strlbwtion. CoefficIent of correlation, LInes ofRegression. Rank Corn"Jat,on. r,me serles.

B) NUMERICALMETHODS:- Finite D1HerencE's ,-f first and higherc'-aer, Forward, 8ac:k",,,..-d. Comtra! and D"'ld"d diffe.-ene",,,,Differem:" t ••bles. Taylors uperator5-D. shlft-opE'rator,Aver-aging, oDerator~ lhfferenc:es of polynomials, F"c:to.-ialpalynomia15, Newtons fo,-w"..-d and bac""'ard differomeE',inte...-polatlon, polynomlaJs, 5tirllng i1nd Bessel's~nterpolation fm-mulae, Legrang" and Newtons divideddifference interpOJatl0n polynomials, "l,<utl0n of Linearalgebreic simultaneous equatl0n by Gaus"ien. elimin<lt;lon,Gauss- "eldel, end Jacobl, iterative methods.

C) DEFINITION OF TRIGONOMETRIC ANDFOURIER SERIES,- Fouriercnefficient" Dirilhelt's condition", stateo,ent 0" Dirich.,lt'stheorem, Expan"ion nf "u"'ctians in FouriEr SErlE". Even and oddfunction", Half range Faw-iEr "eri.,s eamplEx form af FaurierSerlES, Differentiation and integration (f Fourier seriES,Fourier series w~th respect ta set of orthagonal funetians nver(",b). (Fou'"ier Series over ;-1, Ill, ((';,2' and for ••rbiterrangE (a, a+2L) must be treatedJ.

•

- ----~"-"",

CfIT - 102 APPLIED CHEMISTRY(1) Water Treatment : Soft water, herd water, methods ofeoftenlng of hard water, lime-aocia, zeolite and ion exchangeproceSRee. Calculation of softening reagents. Estimation ofhardne88 of water EDTA and Boap titration method.Characteristics of boiler feed water and boiler troubles.

(2) Fuels : Fuel8 and their cla::l'l."lficatiolls, c-alorif.i,c value.type8 of coal and' its anl'llY$is, prep81'atioll and propertiee ofmetallurgical coke. clasaiflcation origin and refining ofpetroleum>~method8 of cracking, Synthetic gasoline, Durificationof gaaol1ne. knockillg, oct.Bne nUlllber, catene number. Natural gas,coal gas. producer gas water gas. Simple problems based oncalorific valUe and cOllihu$ticn calculationa. '

(3) Synthetic Fibers: Glasflification, types of polYlllBrisation,clasaifioatioll of plflBticB, oOllstituBllts of plastica. Fabrioationof plastics, EnginBerillg proyertlea a.nd uaes of. plaaticB.Manufacture, prQpei't feB an>:>-uet's' of plaBtics. Manufacture,propertiee and uaes of thermoplastica like polyethylene,polystyrene, and thermosetting res.iuB like urea-formaldehyde,phenol-formaldehyde. Common types of synthetic rubber likeneoprene. Thikols, Silicone. polyurethane. Industrial usee ofrubber recovery cf wa~te rubber.

(4) Lubricantsprepert,ie",. testing

Mechanism ofand "'election

lubrication,of lubricants.

classification,

(5) Reft'actorieB : Definition, Criteria of I!ood refractory,claBBific:>ticn, propertiee, conditione whidl lead to failure ofrefractoriee and teBting of refra~toriee. manufacture, propertiesand ueea of )rr~on refractoriea.

(6)Corrosion : EJectrochemical corrosion, factors affecting therete of (:torrosion, different. t,ypes of corrosion, l1etallie,in-or~anic and organic coating for corrcaion protection.

Environmental Pollution . 1

i. Air pollution : Introduction, env~ronmenta~ segmenta,compot'ition o.-r the atmosphere, atmoephel'ic atructure,cl:>saification of air pollutants and their effects.control of air pollution, techniques employed for thec~ltrol Df air pollution.

ii. Water pollution: Introduction, classification of waterpollutantB, me~hcds uBed in waete water treatment.

iii. Soil pollution : Intt'oduction, cauees of soilPOllllt.h~n, control of soil pollution.

RecommendedBooks ;

1) Engineering Chemistry2) EnBineering G'nemietry:3) Engineering Chemistry4) Polymer Chemist!'y

5

p.e. Jain3.S. DaraAgrawal

Gowarikar.

/-- --- --

CHT-HI3 BEste PRINCI1L.BS- OF CHEHTCi\L PROCESSES

Import"nc~ of ChemiciI! Industry, its Dev",lopmE'nt dnd Growth.

-Importance of theChemical Technology,products,

chemical Industry, N"•.,The Qual~ty ",nd on,duetl"",

Deve"lcpments incost of Chemical

Basic Principles of Chemical Technology

-A ChemicalTechnologicalTEehnolog ic a 1Technological

Reactor" types

Technological process, Classificat~on of Chemicalp,..ocess, Che(l'~cal Equ.llib"-lum , Rate" of

Frocesses, Method of increasing the process rates,Schemes.

-For homogeneous processes, Heterogenous processes in Gas-liquid,liquid -solid & Gas -Solid.

Introduction ~o unit processes and unit operatlons

Industrial Processes

Suipr,l.lrIndustries - Production of 5l.i.,huric"'-'dNitrogen Indu5tries - Productio" of N1tric acid, Ammoni •••lI,-ea,

Ammon1um Nitrate.Phosphorus Industr1es - Production of Calcium phosphatesCement and lime Indu5triesStarch and sugar industr1es

..

Recommended Books

2.C.E.Dryden, Outline of Chem1cal TeChnology. Ed. by M.Gop"lRao & Marsnall Slttlng Affl111ated East-West Press.R.N.ShrevE & J.A. Bri,,~, Chemical P~ocess Industries,McGra •.•I-<i1], 3rd Ed.

•

CHT-104,v COMPUTER PROGRAMi1ING AND UTILIZATION

I. Logical orgOlrtii:ationcofcomputer system, introdwctiD" tDnumber systems, introduction to compwter programming.Algorithms & flow charts, programs development procoss.

2. Introduction to FORTRAN-77, Ch~racter set, datae~pressions, operations, standard f~nct~Qrs.

,.•

3. SeQwential Structures,.Assignment Stat~ment.Input & output statement" nist-directed).STOP Statement.END State,oent

4. Selective Structures.GOTO State~ents , Assigned GOTO, Com~wted GOTO ..IF Statement" ; L:>gic:.IIF. BI'ock IF. Arithmetic IF..Nested Block Ie structures.Multi - alternative selectivo structure

5. Reps-e1:ativa Structur",,,. IF Loop.00 Loop.Nested DO Loof'

6. Subscripted variables , NotationAm:,,-.m.DHIEN5iON St"''''c>'''>?nt.input/Output of prray~.PARAMETER Stateme~t

7. Format - Directed Inpwt & Owtput.1~p~t/Owtvwt St~te~ent5.FOR~lAT Statement-_.Fo,~~t SpeLific~tio~s

Subprograms.Pur"",se & us".Fwnctions , Library, St~tement, Function subporgrows.Subroutine : CALL StatE'm~nt.Df'oT,:l,SAVE, CO,"l,'-JDNStateme"ts.

••

I,9. File prOCeSSlng

.Opening & clc>sing files

.Obtaining information about ~ file

.Fil~ input & Qwtpwt

.File po~itioning

7

-"-- •

Additional f~atu~es.W~it~ng FORTRAN- 77 p.-oq.-ams fo'" the h.llowing.

1. Finding la.-gest/Smallest cf g~ven numbe,.. us~nq a.-ray &,without ••.-.-ay,

2. Fo.- a,..,-••nging qiven numbe.-s .'in Asc:end~n~IOes<:ending orde.-

using ~~~y& without array.

3. Matriy, Multiplication

4. To find Transpose ",f '" given Mat.-i>:

,4-;;;I

s.

,.Find Sin ~ using Taylor-s se.-ies &, comp",,..e the obtainedvalue with the -value obtained using stand",.-d fc,ncti",n.

J::integerTo "cc",pt eny 7 numb",'" & w.-ite it ~n '-ev"r-se o.-der. "'Is'"find "um of ~ts digit",

7. Gene.-at" fir"t llM1 prime number "tarting f.-om any prime no.

8. Find GCDof given numbers.

Text Book&

1. v. Raja,-aman, Computer programming in FORTRAN-77,PHI (1990),

2. P.-ogramming with FORTRAN-77, Ram t<;uma..-,TH~I

Reference

••,.

O"vice & Hoffmn•••FORTRAN-77

Kern~ghan 8.W.& Plught"r P.J,

A "t.-ucturedOisc:~plined styleMe Gl-fa•• Hill

EI"m£.nts of programmingsty1",Me Gnaw Hi] l, New y",-k

-----------------------------------

.<'\~i5t of E~periments for 1st Semester

. CHT-105 LABORATORY COURSE - !

PART A

1. Kinetics (Volu",,,tr-ic 'and co!ourimetr-yJ.2. Saponification value.3. Refracto~et,..y4. Determination of C.O.D.5. 0.,(;' Analysis6. Iodine Value7. Complex preparation8. Spectrophotometry

PART B

,

L,.,.,.,.o.

Conducto",,,tric titration of mixture of acidsC" 1urn" chrclnatographypH metric titr-ations.Experiments on Potentiometr-ySeparation techniquesFlame photometry

~..•..- '--',--

•

/PART C I LIST OF EXPERIMENTS FOR COMPUTER PROGRAMMING

1. Finding Larg"",,t/Smallest of given numb", S using ",,-relY f;without erraf.

2. Arranging numbers in a,,~ending & descendlng order usingarray & without arrey.

3. Matri~ Multiplication

4. To find Tran5pose <of a given matri~

5. Find Sin(x) uSlng Taylor Series Expanslon & Compare theobtained valu"" with the value obtained l.lSlng standardfum:tl0n.

6. To accept any integ"'''- number $< ",rite it ,n rever5" crder.Plso find sum of its digits.

7. Gen",..-ate first 101Z1prime nllmpe.-" start1ng from any primenumber.

NOTE

'"

STUDENTS"PART. A"

ARE ADVJSED TO COMPLFTE AT LEA';T 6 EXPERIMENTSAND 5 EXPER1~lENTS FRO~l "PART B & C"

FROM

•

M. Be:. [CHEMICAL TECHNOLOGY J

SEMESTER - II•,

-~-----------~------------- ------------------------------------Subjectcodes Subject

Scheme o~ E~aminatio~Internal External Tot"l Marks-----------------------------------------------------------------

CHT-.21Z11 MOMENTUM TR"INSFER

CHT-202

CHT-Z<i3

CHT-ZiJ"

CHT-205

CHEMiCAL ENGINEERINGTHERi"10DYNAMICSC"EMICAL PROCESSCALCULATIONS

CHEMICAL PROCESSESTECHNOLOGY

LABORATORY COURSE-II

,"

'"~ -------------------------------------------------------------------

TOTAL 300-------------------------------------------------------------------In thE'

industrial trainingsummer v~cation studentsand $ub~it a report.

ShOl.!1 d undergo

•

MOMENTUM TRANSFER

5cope and ••pplicaticms cf flulO '1\",."ani<:s" Newt",,.,-,, liiwof viscosity, Classificatio" <:>f fluids, "Iewton-s and ncm-Newtoni••~ fluids, ld~al and ~eal fluiDS, systems of U~lts,Physical p~"perties of fluids densit, speclfic weight,specific volume, speei-hc gravlty, v.s<:osity, (dynamic andki 'lemati c v1scosi ty) .Compressi bi 11ty, cohes. on, adhesion, surf acetensio", capillarity, vapour P~eS,.u~",

•

(b) Fluid StaticsLiquid p~essu~e at a pOlnt, Va~iatlun

liquid, Pas"al' slaw, Atmospherlc pressc.r",n"gative pressure & absolute pressure

of pressure in agauge pressure,

,['l;:mo",ete~,

p~essure onp~"cti"al'or g••tes

simple~e8S1.1~ement 0' pressureDiffere~tial m••no~",ter mec~~~ical guages

Total p~",ssure ,~centrE of pressure, totalpiane and cl.l~ved 5~rf~"es, pressure diagram,applications of total pressu~e "n,: cent,.. •• "f pres$u~"anf t"nks.

Relative ",,,uilib~ium, fluid m~sSes subjected to u"iformline"r ac:celer"tion and r",t"tic:'n, or••e "I'd +o'-"es vortices.

(c:) Kinematic: fluids flo~

Velocity of fluid p"rticle, ty~es of fluid flowste"dy "nO unste"dy, uniform and non-ue'lform, i"mi""r, "notUl'"bulent, one, t"lO and thre", dim!"nsion;;! .:"'ws, str!""m lines,p"th lines "nd streak \lnes, stre"," tubes. ,"quation of c:ontinuityfol'" one dimension,,] "nd thl'"ee dimensional f ,ows.

Ac:eelel'"atio" of fluid parti<:l ••, ~",tational irrot",tior:almotions stream functions, veloclty potential and equipotentiallines, flow net, g~aphi"al and experlment", methods of dl'"awingflow nets. use of flow ne""

(d) Dyn"",ics of fluid

Forces acting or +lu~ds ~n motion, Euler's equ"tion ofmotion ~IQng streamline a"eI in three dimensl<:",al form,Be~noulli's equ"tion uS an integration of ~ule~'s equation ofmotion. simple applic:"tions of c:o"tin\.. tv and Bernoulli'sequations suc:h as pi tot tube, ventur1m"ter, "riflce meterc••vit"tiO:"l"

(e) Flow through Openin~O~ifiees, mouthpieces, coef-itc _"nts

c:c:r,tr"ction .md d1sc:hargE, flow i;:--.roughno. zles,flow through c.~ific:e "I'd ",outh pieLe '--"derh••"d, tirr.e of emptving to t'FI~ b\- "leans <:r,+~c:s.

of velL'c:ity,slu1ce gate",v~rying varying

I~-,(f) Flo~ through pip~s

La~",Reynold numbe,.,I ine and tota 1E'Qivalent pipe,branched pipes.

of fluid fr.ll:tion, Dan:y-Weisbach equ<ltion,Energy losses in pipelin", hydraulic g""dient

energy lin" pipps in series Or compound pipe,pip!?s in parall"l, flow through, a bye-pass,

Water hammer - cause, effect and remedial meaSures.

(g) Centrifugal pump

Typical layout of aCcessories, c"mponent parts workingand types of centrifugal pump, Head of a pump, ~ffici~ncy & powerfor a c~ntrifugal pump, aelection, troubles and remedies ofcentrifugal pump.

Books Recommended

L Fluid mechanics ""0 hydraulics 'y Ran",ld V. Giles!.2, Fluid mechi'lnics ""0 hydraulics 'V Modi ,Seth

" Fluid mechanics ""0 hYdraulics 'V Jagdish '"'" Fluid mechanics Oy Kumar

" Fluid MechanilOs 'V K.R.Arora

==- --.

//'-. .

CHT 2021 CHEMICAL ENGINEER!NG THERMODYNAMICS

,I

Review of the first dnd 5,,<:ono laW of thermody"",mi<:5 dndother oasic c:onc:epts, carnot's cycle - ""'l1"" and thea!'"!?"" ottoengine, power- engine, Rankine cycle, li"~ef,,c:tion of gases,claud's proc",ss, Lend,,'s process, J,,',e-Thompson effect,volumetric: properti,," of pure fluids, heat effects andthermoc:hemistr-y, thermODynamic: properties of fluids, generalis ••dcorrelations, propeer-ty of homogeneous mixtur-es, partidl mOli""properties, fugacity, fugacity coefClcient, activitycoeff1ec:ients, phase equilibrid, vapour-l~qutd equilibria, Gibb'5_ Duhem "Quatio", e:hemic:al ,...••action equiliD~,a, thermodynamH:s offlow processes, refrigeration.

Books ~~commended

1. Int~odLlctiofl to chemi<;al rea<;t~on ThermodynamicsSmith Van Ness, McG~awHill.

2. Chemic"l Eng~nee~ing Th~~modynamics - :'.f\I. Pandey,J.C.ChaLldhari, Khanna PLlbl~sh~,..-s, D~Jh~.

3. Chemical Th~rmodyn"mics - R~H:.M<:Graw-1ilJ .

••....~--------~-~~~----------- "

,

;;CHT -2~3 CHEMICAL PROCESS CALCULAT!UONS

1. Dimensions and Units ~ Introduct10n, dimensionsunits, Fundamental quantities, derived quantities,recommendations for use of units

_and Syste>fficOnver-SHlnS,

2. BasicmolecularImportant

Chemic ••lweight,physical

Calculations - Introduction, mole,equivalent weight, solids, liquids,properties of solutions, Gases

"tomic andsolution",

3. Mate•..i ••l 8",lan<:615Without Cherni"",l Peac:tior,s -Pro!:es", flowsheets, mat",,-i,,l bal •••n"••", Graphic:alproblems, Ree!:y"ling ••nO bYP""5ing operationsMaterial balances of unsteady operations

Int,-odul: tion,solution of

5. Stoichiollll~try and unit oper"tions Introduction,distillation, ~bsorption and stripping, extraction and leaching,crystallization, psychrometry, Drying, Evaporation, Lenconventional Operations.

4. Material B,dan.:"" Involving Chemical ReaLtions introduction,Energy and thermochemistry, energy balan~es, he~t ~Qpa~ity ofg••seous mi~tures, spe~ifi~ he••.t of liquitlmi~tures, I••tent heats,enth••lpy cha~ge during pha~e transfer ••ccomp••nietl by sensiblehe••t changes, equilibrium flash c••.lcul••tions of multicomponentsystem, enthalpy changes accompanying chemical reactions,••bsolute enthalpy, Adiabatic reactions, thermochemistry of mi~ingprocesses, dissolution of solids, liqu~d-liquid mi~tures,gas-li~uid systems, heat of solution by partial molal

,"" quantities.\..

6. Combu5-Lion, Introduction, Fuel5, Calorific:Coal, Liquid Fuels, Air Requirement ,& Fluec••.l~ulatio,.•.

ValuesGa5es

of Fuels,Combw5tion

7. stoleh1omntry & lndu-striedProbl"ms Introduction.

8. aoichJ.OIl\£!tJ:y & DigitalApolic:ationJ Justification AnalogComputation, U5e of ProgrammableLanguages, General Procedure

Computation-Introduction,computatin Vs DigitalCalculators, Programming

Sooks Recommended

1. Stoichiometry- Bhatt 8.T.& Vora Ed.2, TataMcGraw Hill2. Basi~ Principl2s and Calculations in Chemi~al Engineering

Himmelblani D.M., Ed.4, Prentice Hall3. Chemical Engineering Cal~ulations- Shukla S.D. & Pandey G.N.

Lion Press, Kanpur

,.

. 204

// CHEMICAL PROCESS TECHNOLOGY

•

I. Natural Products Industr1es-Oils,gly<:".-i""

i<. Synthetic Organic [:h""n<:,,1 lndust"'ies -i. P"tr-ochernic"ls- refi'le'-ies

pyr-olrsis and cr-ac~ing.-"fclI-mingpoly",,,..-izati,,,..alky18tioniSDm",r i ~'"t10nHydrodealkylation

ii. Chemicals ~rom C compounds,MethanolFo.-mald'",hydeChIo,-"methane"

iii. Chemicals frC'm C C""'l:;c,uncis-,etnylE'ne &. ""etyl"" ••vinyl ••chloride,",thy 1"",,,, ides

iv, Chemicals from C compounds,lsoprop,,"ol,Cume"e,acryJonitirle,ox"proce55.

v. Chemic"l" fro," C compounds•

But"'llene

vi. Chemicals from aromaticsPh!>"o.,Styrne,Phth.,lic anMyd..-id",MaJ~ic anhydride.

3. Polimerz;:;tion I"ciustri"s:

1. Dutlin",s of chemical inciustri ••s - DrycJer., A~filiated EastWest P.-ess.

2. Chemic"l P~<lcess lndust"-ies ~ B. Sh..-"ve. ~kG•.."•• Hill,III,-d editi;:>n.

,'I "

,

CHT-205 LABORATORY COURSE - Ii

A.

Instrumental methods.

thE'oremdis~harge, ~oefficiE'nt ofof VE'locity for a short edge

Gas chromatographyLR.N.M.R.

a rE'~tangular notcha triangular notcha cin:ular pipE'

2. Bourdan's gauge

dischar.ge ofdischarge offriction for

Visc~sity measurement and its relationship with molecularweight of polyme.rs ..End Group analysisViscosity by Brookfield ViscometerFlash point b~ Fensky Marken"s apparatusFlash point by Abel's ApparatusSynthesis of Novolak resin.Synthesis of polyethlene terphthalateDetermination of B.O.D.Relative surface tension of solvents.

flows aJReyn01d E'xperimentb) HE'lE'shawapparatus

Study and use of component parts of centrifugal pump

Measurement of pressure by 1. manometersCoefficient of venturimeterVerification of BernoulliesTo determim", coefficient ofcontraction and coefficientcin::ular o,.-ifi<:eTo determine coefficient ofTo determine coefficient ofTo determine ~oeffi~ient o~Study ExperimentsTo observe various typRS of

L

7.,.,.,.o.,.8.0,.

"L"•••" .L,.,.

..-, ,.1-.

,.O.7.

S.,.

M.Sc. (CHEMICAL TECHNOLOGY]

SEMESTER - I: 1

-------------------------------------------------~~--------------Subjectcodes Subject

Scheme of E~aminationInternal E~ternal Total Marks

CHT-301 MATERIAL TECHNOLOGY " " '"CHT-302 CHEMICAL REACTION " 6. '"ENGINEERING

CHT-303 MASS TRASNFER ,. " '"OPERATIONS

CHT-304 HEAT TRANSFER ,. " ,..OPERATIONS

CHT-305 LAEORATDRY COURSE IH " " "0

-----------------------------------------------------------------TOT ilL

PractiC<l1 courses 1nChemical Reaction EngineeringTransfer.

,,,

(11 M"ter.al t"chnology (2';3\ ~l••ss T"••nsf".- un Heat

4-~T ~ 301

Solid Stat •• ;-

MATERIALS TECHNOLOGY

Electrons and 80nding, wave mechanics and electronbehaviour, electronic structure of atoms.

atomic:atoms.

~lE'tallicpacking bonding, lanie

direc:tionall,.bonding, and secondary bonding,and non-directionally bonded

CrY5tai sto"ucture - space l ••ttice, ionic andC,.-ystals, interfaCing in crystal", point, line surfaceimperfections.

mole<:ul ••...-and volume

Noncrystalline solids Elastomers,molecular compounds and three dimensional networ~s,EJectronic Properties of Materials

Long chain

Electrical conduction, Eand model, ~ayeElectrical sensitivity, semiconductors,thermoelectricity seebeck, Thomson andThermoelectricity in semiconductors.

mechanicalhall

Peltiermode 1,effect.effects,

Magnetism-Magnetization, diamagnetism, Paramagnetism,Ferromagnetism, Magnetic energy and domain structure, Elements of

~ superconducting and dielectric materials. Relation betweenmicrostructure and mechanical properties.

Mechanical Properties of Materials

Elasticity, mechanism of elastic action, Linear andnonlinear elastic properties. Elasticity yielding in crystals,dislocations, str",in hard.ming. ductile, brittle and <:r""pcharacteristics of common engin"eril'lgmaterials.

Books Recommended

1) The structure and Properties of Materials 101.8.Moffatt,8.101.Peausell, and J. Wulf.

2) The Structure and Properties of Materials A. Rose, L.A.Steford and J. Wulf.

3) E~periments in Material Science - E.C. SubbaRao.

,

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-

MASS TRANSFER OPERATIONS

"

Equipment for Gas Liquid operations

Plate Columns Bubbles cap plate column, Sieve plate column,valve plate column

Packed Columns - Differential types of peckings, column internalslike packing supports, liquid distributors andredistributors, relative merits of plate andpacking columns, flooding, loading characteristics of plate and packed column, Mechanicallyagitated ,e55e15.

Distillation vapour Liquid EquilibriumP-XY, T-7.'1, XY diagrams

Roult"s Law, Dalton"s LawDerivation of relative relation between various

like total pressure, vapour pressure, liquid phase and gascomposition using above laws.termsphase

Volatlli ty of cotnponents, Relative, ¥olatili ty,relation between relative volatility and liquid phaseand gas phase composition.

Methods at Distillation Differential or simple distillation _Material Balance (Raleigh"s Equation)

Flash or Equilibrium distillation - Material Balance,Fractional distillation or rectification - Material BalanceAnalysis of Fractionating Column - Mc~be and Thiele Method,PONCHON end SAVARIT Method.Feed plate location = q - line [feed line Equation)Effect of feed condition on q-lineReflux Ratio, minimum reflux ratio & optimum reflux ratio Batchdistillation,Azeotropes, h?eotropic distillation, Extractive distillation.Steam distillationPacked Column Analysistheoritical plate (HETPj Concept of Height Equivalen~

,-.V

Concept of Heigh~ of Transfer Unit (HTU) & Number of transferUnit (NTU)

Height of Packed Bed (Z) Calculation.Abggrptiou .:.. Gas Liquid equilibria

Boult's Law, Henry'g LawMaterial Balance -(Operating line equation)Minimum liquid gas ratio for absorptionMinimum 50vleut requirementNumber of theortical stages reuqiredabsorption in pla~e column.

21

Packed Column Concept of HETP ,:Height eqtl~.lIalenttotheoritical plate)HTU (Height of Transfer Unit: & NTU (Numberof Trane;fer Unit concept f~r eb50rption)

Calculation of pacted bed height (Z)Selection Criteria for sovlent in gas abscrpth,u.Bxtraction'

Equilibrium conditionTernary System - Triangular DiagramRight angle triangular diagramPartially miscible systemInvisible system

Extraction Operations' Single stage, multistage, cross-currentoperation, multistage continuous counter-current operation.E~traction Equipments.extraction.

Selection cri teria of solvent "nd

ADSORPTION, Types of Adsorption, Nature of Ads~rbent Equilibriumcondition Fruendlich Equation.

Single stage operation, minimum adsorbent requirement,multistage, cross-current operations.

Drying - Different terms used in drying proc.,asRate of drying curvesTime of drying under constant dryin~ condition

Drying EquipmentCrystallisationformation

Solution and eolubilit,y curvef';, crystal

Mier's super saturation theoryYield of crystalization systemMethods of 'luper :laturatioliEquipments for crystallizationMaterial bala~ce over crystallizer

Books Recommended1. Chemical Engineering by Richardson & Coult-,m2. Unit Operation by Brown and associates3. Mass Transfer operation by Trybel4. Absorption & Distillation by Norman

-.=-------------:-----~~- •••(-,~-,,

HEAT TRANSFER OPERATIONSCHT304i,{"_

t1od~ of Heat Tram:fer ConductionConvectiot'lRadiation

Conduction;

Fourier"z Law of ConductionThermal ConductivityConduction through single flat wall,COlilPos1te WollElectrical Analogy for solving the conduction problem.Conduction through single cylinderComposite CylinderConduction through sphereComposite Sphere.

Gonvec'tion: Forced convectionNatural convection.

Individual heat transfer coefficientOverall heat transfer coefficientflouling ft1.ctorApplication of dimensional analysis to heat transfer by

•.••••••

Convection

Wilson Plot -

for Natural convectionfor forced convection

Combined heat transfer by conduction and convectionCondensaticn- dropwise and filmwise condensationCondensation on surfaces - Nusselt's theoryCondensation on vertical, inclined, horizontal tubes.Heat Transfer in Boilln~ Liquid ; Mechanism of Boiling

Different remies of boiling like -Natural convectionNucleate Boilin~Transi tion BoilingFilm BoilingCorrelations in Beiling Heat Transfer -

~ Exchange Eguipments ~ Double pipe heat exchanger, sheel &tube heat exchanger, Finned tube heatexchange~' ,

23

CondenserReboilersPlate Heat ExchangerScrapped Surface ExchangerSpiral heat Exchanger

Analysis QL ~ Exchanger ~ Co-current, counter-currentCross current exchanger.Calculation of Heat Transfer Coefficient.H~at Transfer Area for Process Heat Trans~er

Radiation ~ Basic theory of Radiatio~ Heat Transfer-Wave theory,Quantum Theory

Absorption, Reflection, TransmissionBlack BodyKirshoff LawSteafan Boltzmann LawWein Displacement LawRadiation Heat Transfer

Eyaporation' Capacity, Economy, Steam ConsumPtion of evaporation-Boiling Point Elevation -Duhring's LawMaterial & Enthalpy balance in evaporatorTypes of evaporatorsMultiple Effect EVaporation - Forward feed, Backward feed, mixed-feed evaporationVapour recompression

Sooke RecommendedProce5s H<eat Tranefer - D.Q.KernIntroduction to Chemical Eng1r.eer1ng - Ba<fger & Banchero[!nit Operations in Chemical Engineering - "Ie-Cabe & SmithChemical Engineering by Coulscfl & Richardson Vol-IChemical Engineer's Hand Book - PerryHeat Transfer - Me-Adams

24

~.••

•

Cil"1- 3eJ5••• Laboratory cour~e III

1. St~fan - Boltzroan constant apparatus2, Thermal conductivity of metal rod3. Emmisivity of giv~n plate4. Critical heat flux at various bulk temperatures5. Energy heat transfer coefficient for vertical tube losing

heatby natural convection6. pin-fin aPN,ratus7. Thermal conductivity of inbulating powder8_ Tube in tube concentric9. Dropwise and filmwis€ condensation-' .. , '".

I

•i

,

--

-.-------- --

M.Sc. [CHEMICAL TECHNOLOGY;

SEMESTER - IV

Scheme of ExaminationInternal External Total MarksSubject

Subjectcode~-------------------------------------------------~-----,--------------------------------------------------------------------------CHT-401 INSTROMENTATION A~~ ,. 6. 100PROCESS CONTROLCHT-4"'2 CHEMICAL EQUIPMENT ,. 6. 100DESIGN

CHT-403 UNIT PROCESSES IN 4. 6. ,..ORGANIC SYNTHESIS.CHT-404 LABORATORY COURSE-IV 4. 6. w.CHT-405 PROJECT 4. 6. 100

---------------------------------------------- ------------- -----TOTAL 2•• SO. 5••-----------------------------------~-----------------------------(1) Practical COUI::S€in Reaction Engineering and Design.

(6) Project - II : Practical/Theory work and report sub1ll1ss1on,

--

• -------~ ..---------'---'<:,••~~~-401 INSTRUMENTATION AND PROCESS CONTROL

A) Instrumentation-

i) Flow measurementii) Level measurement

iii) Temperature measurementiv) Pressure measurementv) Others

a. pH measurementb. Density measurementc. Viscosity measurementd. Gas Liquid Chromatography GLC/HPLCe. Mass Spectroscopyf. I. R. Spectroscopyg, NMR SpectroscOpyh. Humidity measurement1. Thermal conductivity measurement

B) Control -a. Terminologyb. Block Diagram, Transfer Functionc. Feed back and feed forward control systemd. Servo and regulator operatione, Inherent characteristics of control valves

Controllersa. ON-OFF, proportionalb. Proportional Integral (P-I)c. Proportional Integral Derivative (PID) actiond. Response of controllers to different forcing

functionse. Valve positionorsf. Valve Sizing

Bocks Recommended

,

12.

3.4.

.• 5 .- 6.

Industrial Instrumentation - Eckman. Donald, Wiley EasternInstrumentation Devices and System - Rangan C.S .. Sarma G.R.,Mani V.S.V .. Tata McGraw Hill. New DelhiPrinci~les of Industrial Instrumentation Patranabis D. TataMcGraw Hill, New DelhiInstrUmentation Measurement and AnalysisNakra B.C., Chaudhary K.K .. Tata McGraw Hill, New DelhiProcess Control Eck~an. Hiley EasternProcess Control - Peter Harriott, HcGraw Hill.

27

'. -CHT-402 CHEMICAL EQUIPMENT DESIGN !J'-

Sieve tray, B~bble captray, Packed ~olumnDouble pipe heat exchanger, shelltube heat ex~hanger, condenser,reboiler, eva~orators

driertower

Rotarycooling

Process & mechanical design of following pro~e5S equipmentsi) Reaction vesselii) Absorption columniii) Distillation columnIv) Heat exchange equipments-

Books Recommended1) Ap~lied Frocess Design fer Chemical and ~ectrochemlcal plants

vol. I,II & III. 2nd ed, Ernest E. Ludwlll.2) Frocess Equipment Design - tl.V.Joshl3) Process Equipment Design - Brownell & Yo~ng4) Chemical Equipment Design - B.C. EhattacI,aryya5) Chemical Engineer's Hand Book - Perry

,

/'tCif( - 4£13 Unit processe in Org~nic Synthesis

on'findof

Amina~ion by reduction .methods of reduction, Iron an ~et !ntrod~ctlon and definition.acid reductions,_met~l .end altali8i ~eduction , other me~als and

Amination by amminolysis _ ~; uctlQn , sulphide reductionagents, Survey of aminat<n ~~eral discussion, aminatingfactors affecting amminol;5f~rea;:;on, phYsical .and chemicalreactions, corrosion and pHof~th .- ~~lY5t5 used In al~lnatior,the~mOdynamics of amminolYSls€ aUc~~laye charge, kineticsandaUXIliaries, technical a1k"1-t' ' thd.~ign of reactors and

A1ky .~ '"' Ion Ins odslation - Introduction and t ~~:i~i:~t~~s~ge~i;~c~ac;~rSa~~~fr~~lingadlk;i;tio~~fequf;:~*~ti~~;methods a Ion an technLcal alkylation

Oxidation - Liquid and vapour phase oxidations, kinetics andthe:mochemistry, apparatus for oxidation, technical oxidation of150 eugenol, acetaldehyde, cyclhexane, iso-propylalcOhol,naphthalene, benzene and naphthalene suIphonic acid .

Esterification and hydrOlysis - esterification of organicacid, esterification of carboxylic acid derivatives, esters byaddition to unsaturated system, interesterification of lardtechnical preparation of ethyl acetate, cellulose acetate:nitroglycelC" polyethyl ether, phthalate. Kineticsthermodynam1CS and mechanism of hydrolysis, Technical preparationinvolving hydrolysis e,g. hydrolysis of fat preparation offurfural, glycol phenol from chlorobenzenes etc.

Hydrogenation catalytic hydrogenation, kineticsthermodynamics of hydrogenation reactions , apparatusmaterial of construction, Industrial processes, hydrogenationfatty oils, synthesis of methanol.

Polymerization - general introduction, resin manufacturingprocess, condensation polymerization, addition polymeriza~ion,intermediates for resin - phenolformaldehyde, HHT, vinyl ester,phthalic anhydride.

Books Recommended1) Unit processes in organic synthesis by P.H.Groggins2) Outlines of chemical industries - Dryden.3) Chemical Process Industries - B. Shrieve.

29

CHT-404

GRAPHICS

Laboratory course lV

••

Introduction. Lettering, dimensions, and Standards.plane curves, orthographies views. Isometric vtelols, perspectiveDevelopment of 5urfaces, Mechanical Drawings (Nuts, Bolts,Screws, Beams etc), Information display techaiques.

Isometric projections and oblique parallel projection,isometric scale.

obliqueSection f solids by different cutting planes

plane), true shape of section.(excluding

Machinefoundation bolts,

BOOKS RECOMMENDED

elements,for looking

rivets, rivetedarnmgements.

joints haishevs,

1. Engineering Drawing - N.B, Bhatt.

Other practicals .'"-;1.2.,.4.5.6.

measurements of pH, viscosity & dIR Spectroscopy ensity reaction mixturesNNF SpectroscopyGas liquid chromatographyHumidity measurementsThermal conductivity measurements

J/WS/SYLL/CHEM,SYL

30

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