numerical modeling of the ordinary chondrites shock ... · tectic contact between iron and...

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NUMERICAL MODELING OF THE ORDINARY CHONDRITES SHOCK METAMORPHISM TRANSI- TION FROM SHOCK STAGE 5 TO 6. J. Moreau 1 , T. Kohout¹ , ² and K. Wünnemann 3 , 1 Department of Geo- sciences and Geography, University of Helsinki, Finland ([email protected] ), 2 Institute of Geology, The Czech Academy of Sciences, Prague, Czech Republic, ³Museum für Naturkunde, Leibniz Institute for Evolution and Biodiversity Science – Freie Universität, Institute of Geological Sciences, Berlin, Germany. Introduction: To study shock metamorphism in or- dinary chondrites, [1] successfully established a shock classification, com- prising six shock stages until whole rock melting. In the classification, the shock stage 5 and 6 are defined with specific shock ef- fects in silicates, and observation of localized melt pock- ets and melt veins. The estimated pres- sure range for the transition from stage 5 to 6 is 45-55 GPa. By shock physics mesoscale model- ing, we gave insight to the post-heating and melting, encom- passing the transi- tion, using: olivine, enstatite, troilite, and iron phases. We also considered eu- tectic melting at contact between iron and troilite. We carried out a systematic study in the 38-68 GPa pressure range and we observed the ef- fects of open pores (macro-porosity) and olivine poros- ity (distention, micro-porosity [2]). We used backscat- tered electron microscope (BSE) images of chondrites thin sections, Annama H5 (two models), Neuschwanstein EL6 (two models), and Chelyabinsk LL5, to setup our models. Using BSE images enables to setup more realistic sample meshes and grain distri- bution in the mesoscale models. Methods: To study the melting and post-heating of multi-phase models, we used the shock physics code iSALE [2] with a setup similar to [3]. In the mesoscale approach we used an olivine flyer-plate impacting olivine sub-layers between which we intercalated the converted BSE image mesh (analogous to the setup of planar shock wave recovery experiments). In Fig. 1 we illustrate the BSE image conversion of Annama (1) to a BMP image containing one RGB value per chosen phase. We adapted thermal properties, such as the melting points, heat capacities integration, and heat of fusion, to the material and chondrite original composition. Strength and porosity models followed those from [4, 2, 3]. Results: Fig. 2 displays the mesh after shock com- pression in term of post-shock temperatures and melt fraction at 55 GPa in Annama (1). In Fig. 3, we com- pile melt production for troilite, olivine, and the bulk material, for all models, and the resulting bulk post- heating with literature data [5,6]. We also carried out models on Annama (1) in which we varied porosity or the initial temperature. Discussion: In our work, the transition from shock stage 5 to 6 is illustrated by: the melting of troilite from ~40 GPa to ~68 GPa with melt fraction reaching 0.9; Fig 1. Conversion of a BSE image to a numerical mesh (light gray: iron; dark gray: troilite; white: olivine; black: pores). Green and blue zones are eu- tectic contact between iron and troilite. We also converted the large phosphate grain from the BSE image to olivine, because we defined only 3 phases for numerical accuracy. Fig 2. Post-shock temperature and melt fraction panel in the An- nama (1) model at 55 GPa. The dashed circles are zones of in- terest. 1164.pdf 49th Lunar and Planetary Science Conference 2018 (LPI Contrib. No. 2083)

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Page 1: NUMERICAL MODELING OF THE ORDINARY CHONDRITES SHOCK ... · tectic contact between iron and troilite. We also converted the large phosphate grain from the BSE image to olivine, because

NUMERICAL MODELING OF THE ORDINARY CHONDRITES SHOCK METAMORPHISM TRANSI-TION FROM SHOCK STAGE 5 TO 6. J. Moreau1, T. Kohout¹,² and K. Wünnemann3, 1Department of Geo-sciences and Geography, University of Helsinki, Finland ([email protected]), 2Institute of Geology, TheCzech Academy of Sciences, Prague, Czech Republic, ³Museum für Naturkunde, Leibniz Institute for Evolution andBiodiversity Science – Freie Universität, Institute of Geological Sciences, Berlin, Germany.

Introduction: To study shock metamorphism in or-dinary chondrites, [1] successfully established a shockclassification, com-prising six shockstages until wholerock melting. In theclassification, theshock stage 5 and 6are defined withspecific shock ef-fects in silicates,and observation oflocalized melt pock-ets and melt veins.The estimated pres-sure range for thetransition from stage5 to 6 is 45-55 GPa.By shock physicsmesoscale model-ing, we gave insightto the post-heatingand melting, encom-passing the transi-tion, using: olivine,enstatite, troilite,and iron phases. Wealso considered eu-tectic melting atcontact betweeniron and troilite. We carried out a systematic study inthe 38-68 GPa pressure range and we observed the ef-fects of open pores (macro-porosity) and olivine poros-ity (distention, micro-porosity [2]). We used backscat-tered electron microscope (BSE) images of chondritesthin sections, Annama H5 (two models),Neuschwanstein EL6 (two models), and ChelyabinskLL5, to setup our models. Using BSE images enablesto setup more realistic sample meshes and grain distri-bution in the mesoscale models.

Methods: To study the melting and post-heating ofmulti-phase models, we used the shock physics codeiSALE [2] with a setup similar to [3]. In the mesoscaleapproach we used an olivine flyer-plate impactingolivine sub-layers between which we intercalated theconverted BSE image mesh (analogous to the setup ofplanar shock wave recovery experiments). In Fig. 1 we

illustrate the BSE image conversion of Annama (1) to aBMP image containing one RGB value per chosenphase.We adapted thermal properties, such as the meltingpoints, heat capacities integration, and heat of fusion,to the material and chondrite original composition.Strength and porosity models followed those from [4,2, 3].

Results: Fig. 2 displays the mesh after shock com-pression in term of post-shock temperatures and meltfraction at 55 GPa in Annama (1). In Fig. 3, we com-pile melt production for troilite, olivine, and the bulkmaterial, for all models, and the resulting bulk post-heating with literature data [5,6]. We also carried outmodels on Annama (1) in which we varied porosity orthe initial temperature.

Discussion: In our work, the transition from shockstage 5 to 6 is illustrated by:

the melting of troilite from ~40 GPa to ~68GPa with melt fraction reaching 0.9;

Fig 1. Conversion of a BSE image to anumerical mesh (light gray: iron; darkgray: troilite; white: olivine; black:pores). Green and blue zones are eu-tectic contact between iron andtroilite. We also converted the largephosphate grain from the BSE imageto olivine, because we defined only 3phases for numerical accuracy.

Fig 2. Post-shock temperature and melt fraction panel in the An-nama (1) model at 55 GPa. The dashed circles are zones of in-terest.

1164.pdf49th Lunar and Planetary Science Conference 2018 (LPI Contrib. No. 2083)

Page 2: NUMERICAL MODELING OF THE ORDINARY CHONDRITES SHOCK ... · tectic contact between iron and troilite. We also converted the large phosphate grain from the BSE image to olivine, because

the progressive melting of olivine startingfrom 50 GPa with low melt fraction from 0.01to 0.1 at 68 GPa.

In Annama (1), Fig. 2, we highlighted some effects oflocalized melting and other features:

heating-melting by pore crushing in olivine; heating and melting of olivine at iron bound-

aries, due to strong pressure reflexions [5]; melting of troilite at borders of larger grains

[7], depending on the grain geometry.While pure shock melting of olivine, regardless of ex-ternal factors (e.g. pressure reflexions, pore crushing),is characteristic of the whole rock melt, stage 5 and 6are characterized by localized melting, such as de-scribed by [1] and observed in our work. The transitionfrom shock stage 5 to 6 is also dependent on olivineporosity (10% and 15% porosity tests, Fig. 3).

Conclusion: With the model-based predictions ofthe shock heating and melting in ordinary chondrites,we provide more insight to the transition from shock

stage 5 and 6 of the shock classification. The numericalmodels based on real meteorites BSE images of chon-drites, give realistic results comparable to results ofshock experiments.

Acknowledgments: Our thanks go to the iSALEdevelopers and the team of the Museum fürNaturkunde in Berlin, Germany, for sharing theirknowledge and ideas with us. This work is also sup-ported by the Academy of Finland.

References: [1] Stöffler D. et al. (1991). Geochim.Cosmochim. Acta, 55(12), 3845-3867. [2] WünnemannK. et al. (2006) Icarus, 180, 514-527. [3] Moreau J. etal. (2017) Meteorit. Planet. Sci., 52(11), 2375-2390.[4] Moreau J. et al. (2018). Phys. Earth Planet. In.,submitted. [5] Schmitt R. T. (2000). Meteorit. Planet.Sci., 35, 545-560. [6] Xie X. and Chen . (2016).Suizhou Meteorite: Mineralogy and Shock Metamor-phism. Springer-Verlag Berlin and Heidelberg, 258 pp.[7] Bennett M. E. and McSween Jr. H. Y. (1996). Me-teorit. Planet. Sci. 31, 255:264.

Fig 3. Melt fractions and post-shock temperatures in all models with shock experiment literature data as reference. Graphic c) is inlogarithm scale.

1164.pdf49th Lunar and Planetary Science Conference 2018 (LPI Contrib. No. 2083)