nutrient reduction through the use of advanced …...permeate results below detection limit of hand...
TRANSCRIPT
![Page 1: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/1.jpg)
NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED BIOLOGICAL NUTRIENT
RECOVERY
Rick Johnson Vice President, Market Development
1
![Page 2: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/2.jpg)
Agenda • What is the trend • Technology description • Results • Economics
"Vision without action is a daydream. Action without vision is a nightmare“ -Japanese Proverb
2
![Page 3: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/3.jpg)
3
Level 5 Complete set of N and P criteria for all watertypes
Level 4 2 or more watertypes with N and/or P criteria
Level 3 1 watertype with N and/or P criteria
Level 2 Some waters with N and/or P criteria
Level 1 No N and/or P criteria
State Nitrogen and Phosphorus Criteria
Source: http://cfpub.epa.gov/wqsits/nnc-development/
![Page 4: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/4.jpg)
4
1998
2016 (est)
![Page 5: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/5.jpg)
5
1998 2013 2016 est
Level 5 4 4 5
Level 4 1 4 6
Level 3 2 4 4
Level 2 7 16 16
Level 1 42 28 25
0%
20%
40%
60%
80%
100%
Pe
rce
nta
ge
Numeric Criteria Trend: States & Territories
Level 1 Level 2 Level 3 Level 4 Level 5
![Page 6: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/6.jpg)
6
0.10
0.02
0.04
0.075 ????
![Page 7: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/7.jpg)
The challenge: • Reducing targeted nutrients in a cost effective manner
Our solution: • View algae as a process…not a product • Sustainable, advanced nutrient recovery
o US Patent 8,101,080
The benefits: • Best in Class performance • No chemical sludge produced • Sustainable • Multi-generational, single technology
CO2 recycling & O2 release
Biomass co-product 7
![Page 8: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/8.jpg)
SEPARATION
NUTRIENT RECOVERY
MIX
Clean Water
Algae Return
CO2
Algae Harvest Pure
oxygen
8
![Page 9: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/9.jpg)
0.000
0.100
0.200
0.300
0.400
0.500
0.600
TP, m
g/L
Date
Controlled experiment: Nitrogen : Phosphorus relationship
Raw
NH3 dosing
Permeate
Target
9
![Page 10: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/10.jpg)
TP TN NH3 TKN BOD TSS
Raw 2.247 16.706 4.167 10.904 27.000 15.487
Treated 0.028 6.872 0.210 1.578 4.000 0.609
0.000
10.000
20.000
30.000
Co
nce
ntr
atio
n, m
g/l
Municipal Summary
Raw Treated
Nutrient Recovery Test
Multi constituent performance
10
![Page 11: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/11.jpg)
0.00
0.05
0.10
0.15
0.20
0.25
0.30
Raw Separation Permeate Raw Separation Permeate
Res
ult
, mg/
L
Influence of separation on phosphorus reduction
TP Ortho
Run2 Run1
Membranes alone cannot remove dissolved phosphorus
11
![Page 12: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/12.jpg)
5.2
11.75
0
2
4
6
8
10
12
14
Current DMR ABNR
Dis
solv
ed
Oxy
gen
, mg/
L
Dissolved Oxygen
3 year DMR average (ECHO)
Median of 1 minute recordings from 2.5 month component evaluation
12
![Page 13: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/13.jpg)
Municipal wastewater treatment
Constituent Before After % Removal
Total P (mg/L) 0.625 0.036 94.14%
TSS (mg/L) 12.18 0.24 98.00%
PCB (pg) 2141 144.1 93.00%
5 MGD Municipality Primarily residential 36,000 Residents TMDL: 0.075mg/L TP
13
![Page 14: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/14.jpg)
14
0.0
0.5
1.0
1.5
2.0
2.5
3.0
0
0.2
0.4
0.6
0.8
1
1.2
1.4
9/20
/201
0
9/21
/201
0
9/22
/201
0
9/23
/201
0
9/24
/201
0
9/25
/201
0
9/26
/201
0
9/27
/201
0
9/28
/201
0
9/29
/201
0
9/30
/201
0
10/1
/201
0
10/2
/201
0
10/3
/201
0
10/4
/201
0
10/5
/201
0
10/6
/201
0
10/7
/201
0
10/8
/201
0
10/9
/201
0
10/1
0/20
10
10/1
1/20
10
10/1
2/20
10
10/1
3/20
10
10/1
4/20
10
10/1
5/20
10
M Ts W Th F Sa Su M Ts W Th F Sa Su M Ts W Th F Sa Su M Ts W Th F
CPF
EFF
Flow
, mgd
Tota
l Pho
spho
rus,
mg/
L
Post Falls Effluent AlgEvolve Effluent PF Flow, mgd
Second 21 day pilot: Average Raw TP: 0.151mg/L Average Permeate TP: 0.024mg/L
![Page 15: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/15.jpg)
Results:
Constituent Before After % Removal
Total P (mg/L) 2.68 0.18 93.3%
Ammonia (mg/L) 0.60 0.05 91.7%
Total N (mg/L) 14.1 3.26 76.9%
![Page 16: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/16.jpg)
Inland Empire Paper Company Results
3 MGD Pulp & Paper Process recycled paper 130 year old company TMDL: ~0.075mg/L TP
16
![Page 17: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/17.jpg)
0.0001
0.001
0.01
0.1
1
10
2-J
un
9-J
un
16
-Ju
n
23
-Ju
n
30
-Ju
n
7-J
ul
14
-Ju
l
21
-Ju
l
28
-Ju
l
4-A
ug
11
-Au
g
18
-Au
g
25
-Au
g
1-S
ep
8-S
ep
15
-Sep
22
-Sep
29
-Sep
6-O
ct
13
-Oct
20
-Oct
27
-Oct
3-N
ov
10
-No
v
17
-No
v
24
-No
v
1-D
ec
8-D
ec
15
-Dec
22
-Dec
29
-Dec
5-J
an
12
-Jan
19
-Jan
26
-Jan
2-F
eb
9-F
eb
Tota
l Ph
osp
ho
rus,
mg/
L
Total Phosphorus Trend
Raw Treated
Average Raw: 0.126mg/LAverage Permeate: 0.024mg/L
Separation Technology Vendor performance evaluations
17
Average Raw TP: 0.126mg/L Average Permeate TP: 0.024mg/L
![Page 18: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/18.jpg)
45 MGD Municipality • 250,000 residents • Biosolids management for 14 communities Heavy Industrial Base (26 SIU’s) Seasonal Permit: 0.1mg/L TP & 5.0mg/L TN
18
![Page 19: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/19.jpg)
Raw 0.366 0.155 0.182 0.33
Treated 0.020 0.005 0.029 0.038
0.00
0.05
0.10
0.15
0.20
0.25
0.30
0.35
0.40
Ave
rage
co
nce
ntr
atio
n, m
g/L
Total Phosphorus
Raw Treated
19
![Page 20: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/20.jpg)
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Period 1 Period 2 Period 3
TN, m
g/L
Weekly period
Total Nitrogen response
Raw Permeate
Additional nitrogen reduction
20
![Page 21: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/21.jpg)
Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results
0.01
0.10
1.00
10.00
10/
31
11/
2
11/
5
11/
8
11/
11
11/
14
11/
17
11/
20
12/
9
12/
12
12/
15
12/
18
1/1
3
1/1
6
1/1
9
1/2
2
1/2
5
1/2
8
1/3
1
2/2
1
2/2
4
2/2
7
3/8
3/1
1
3/1
5
3/1
8
3/2
1
3/2
4
3/2
7
5/1
4
5/1
7
5/2
0
5/2
3
5/2
6
6/3
6/6
6/9
6/1
2
mg
/L P
Total Phosphorus Feed and Permeate
avg Feed Water TP avg Permeate TP 0.1 mg/L P Discharge Permit Feed Alpha Labs Permeate Alpha Labs
City Water BaselineNo light study
Hypo threshold
study
Average 3rd party lab (TP) • Feed: 0.285mg/L • Permeate: 0.02mg/L
![Page 22: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/22.jpg)
Date COD, mg/L TOC, mg/L
Feed Permeate Feed Permeate
3/19 26 24 4.86 4.81
3/20 35 24 5.17 4.62
5/18 20 20 6.54 5.91
5/25 26 20 6.91 2.5
6/4 28 20 5.94 5.86
Average 27.00 21.60 5.88 4.74
Reduction 20.0% 19.4%
Numbers in red reported as “Non Detect”. Level of detection shown
22
![Page 23: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/23.jpg)
23
![Page 24: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/24.jpg)
0
10
20
30
40
50
60
70
10/3
0/20
14
11/6
/201
4
11/1
3/20
14
11/2
0/20
14
11/2
7/20
14
12/4
/201
4
12/1
1/20
14
12/1
8/20
14
12/2
5/20
14
1/1/
2015
1/8/
2015
1/15
/201
5
1/22
/201
5
1/29
/201
5
2/5/
2015
2/12
/201
5
2/19
/201
5
2/26
/201
5
Tem
pera
ture
, F
Temperature influence
Feed fluid temp Avg PBR fluid Avg Outsid Air Temp
Feed PBR Air
Average 58.2 59.6 30.4
St Dev 2.63 2.54 11.14
Temperature, F
24
![Page 25: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/25.jpg)
Average Biomass characteristics
Average of 25 municipal / industrial sources
N, % P2O5, % Potash, % Protein, % Fat, % Carb, %
Average 4.4 1.7 0.6 30.3 3.1 32.4
Low 0.6 0.3 0.1 11.4 0.2 6.1
High 7.8 3.4 2.3 48.3 7.8 63.2
Sample size 25 25 25 18 18 18
Typical applications 5 Year TAM, $M • Bio-plastics $478 - $638 • Soil amendment / composting aid $71 - $94 • Fuel source $2 - $3 • Others In development
Biomass Market
25
![Page 26: NUTRIENT REDUCTION THROUGH THE USE OF ADVANCED …...Permeate results below detection limit of hand held meter-results supplemented with 3rd party lab results 0.01 0.10 1.00 10.00](https://reader035.vdocument.in/reader035/viewer/2022071012/5fcae246043c045dbc07f045/html5/thumbnails/26.jpg)
26
$-
$5,000,000
$10,000,000
$15,000,000
$20,000,000
$25,000,000
$30,000,000
$35,000,000
5 10 15 20 25 30
20
ye
ar P
W
Molar ratio, FeCl3
Break even technology comparison
MBR + chem P ABNR
Breakeven point for low P reduction at Molar Ratio = 8