organic and biological chemistry © 2009, prentice-hall, inc. chapter 25 organic and biological...
TRANSCRIPT
![Page 1: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/1.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Chapter 25Organic and
Biological Chemistry
Chemistry, The Central Science, 11th editionTheodore L. Brown; H. Eugene LeMay, Jr.;
and Bruce E. Bursten
John D. BookstaverSt. Charles Community College
Cottleville, MO
![Page 2: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/2.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Organic Chemistry• Organic chemistry is the chemistry
of carbon compounds.• Carbon has the ability to form long
chains.• Without this property, large
biomolecules such as proteins, lipids, carbohydrates, and nucleic acids could not form.
![Page 3: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/3.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Structure of Carbon Compounds
• There are three hybridization states and geometries found in organic compounds:– sp3 Tetrahedral– sp2 Trigonal planar– sp Linear
![Page 4: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/4.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Hydrocarbons
• There are four basic types of hydrocarbons:– Alkanes– Alkenes– Alkynes– Aromatic hydrocarbons
![Page 5: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/5.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Alkanes
• Alkanes contain only single bonds.• They are also known as saturated
hydrocarbons.– They are “saturated” with hydrogens.
![Page 6: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/6.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Formulas
• Lewis structures of alkanes look like this.• They are also called structural formulas.• They are often not convenient, though…
![Page 7: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/7.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Formulas
…so more often condensed formulas are used.
![Page 8: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/8.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Properties of Alkanes
• The only van der Waals force is the London dispersion force.
• The boiling point increases with the length of the chain.
![Page 9: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/9.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Structure of Alkanes
• Carbons in alkanes are sp3 hybrids.• They have a tetrahedral geometry and 109.5°
bond angles.
![Page 10: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/10.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Structure of Alkanes
• There are only -bonds in alkanes.
• There is free rotation about the C—C bonds.
![Page 11: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/11.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Isomers
Isomers have the same molecular formulas, but the atoms are bonded in a different order.
![Page 12: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/12.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Stereoisomers• With these geometric
isomers, two chlorines and two NH3 groups are bonded to the platinum metal, but are clearly different.
cis-Isomers have like groups on the same side.trans-Isomers have like groups on opposite sides.
![Page 13: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/13.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Stereoisomers
• Other stereoisomers, called optical isomers or enantiomers, are mirror images of each other.
• Just as a right hand will not fit into a left glove, two enantiomers cannot be superimposed on each other.
![Page 14: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/14.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Enantiomers
A molecule or ion that exists as a pair of enantiomers is said to be chiral.
![Page 15: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/15.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Enantiomers
• The physical properties of chiral molecules are the same except in instances where the spatial placement of atoms matters.
• One example is the interaction of a chiral molecule with plane-polarized light.
![Page 16: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/16.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Enantiomers
• If one enantiomer of a chiral compound is placed in a polarimeter and polarized light is shone through it, the plane of polarization of the light will rotate.
• If one enantiomer rotates the light 32° to the right, the other will rotate it 32° to the left.
![Page 17: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/17.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Organic Nomenclature
• There are three parts to a compound name:– Base: This tells how many carbons are in the
longest continuous chain.
![Page 18: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/18.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Organic Nomenclature
• There are three parts to a compound name:– Base: This tells how many carbons are in the
longest continuous chain.– Suffix: This tells what type of compound it is.
![Page 19: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/19.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Organic Nomenclature
• There are three parts to a compound name:– Base: This tells how many carbons are in the
longest continuous chain.– Suffix: This tells what type of compound it is.– Prefix: This tells what groups are attached to the
chain.
![Page 20: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/20.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
How to Name a Compound
1. Find the longest chain in the molecule.
2. Number the chain from the end nearest the first substituent encountered.
3. List the substituents as a prefix along with the number(s) of the carbon(s) to which they are attached.
![Page 21: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/21.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
How to Name a Compound
If there is more than one type of substituent in the molecule, list them alphabetically.
![Page 22: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/22.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Cycloalkanes
• Carbon can also form ringed structures.• Five- and six-membered rings are most stable.
– They can take on conformations in which their bond angles are very close to the tetrahedral angle.
– Smaller rings are quite strained.
![Page 23: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/23.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Reactions of Alkanes
• Alkanes are rather unreactive due to the presence of only C—C and C—H -bonds.
• Therefore, they make great nonpolar solvents.
![Page 24: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/24.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Alkenes
• Alkenes contain at least one carbon–carbon double bond.
• They are unsaturated.– That is, they have fewer than the maximum number of
hydrogens.
![Page 25: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/25.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Structure of Alkenes
• Unlike alkanes, alkenes cannot rotate freely about the double bond.– The side-to-side overlap in the -bond makes this
impossible without breaking the -bond.
![Page 26: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/26.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Structure of Alkenes
This creates geometric isomers, which differ from each other in the spatial arrangement of groups about the double bond.
![Page 27: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/27.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Properties of Alkenes
Structure also affects the physical properties of alkenes.
![Page 28: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/28.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Nomenclature of Alkenes• The chain is numbered so the double bond gets the
smallest possible number.• cis-Alkenes have the carbons in the chain on the
same side of the molecule.• trans-Alkenes have the carbons in the chain on
opposite sides of the molecule.
![Page 29: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/29.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Reactions of Alkenes
• One reaction of alkenes is the addition reaction.– In it, two atoms (e.g., bromine) add across the
double bond.– One -bond and one -bond are replaced by two
-bonds; therefore, H is negative.
![Page 30: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/30.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Alkynes
• Alkynes contain at least one carbon–carbon triple bond.
• The carbons in the triple bond are sp-hybridized and have a linear geometry.
• They are also unsaturated.
![Page 31: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/31.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Nomenclature of Alkynes
• The method for naming alkynes is analogous to the naming of alkenes.
• However, the suffix is -yne rather than -ene.
4-methyl-2-pentyne
![Page 32: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/32.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Reactions of Alkynes
• Alkynes undergo many of the same reactions alkenes do.
• As with alkenes, the impetus for reaction is the replacement of -bonds with -bonds.
![Page 33: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/33.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Aromatic Hydrocarbons
• Aromatic hydrocarbons are cyclic hydrocarbons that have some particular features.
• There is a p-orbital on each atom.– The molecule is planar.
• There is an odd number of electron pairs in the -system.
![Page 34: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/34.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Aromatic Nomenclature
Many aromatic hydrocarbons are known by their common names.
![Page 35: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/35.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Reactions of Aromatic Compounds• In aromatic
compounds, unlike in alkenes and alkynes, each pair of -electrons does not sit between two atoms.
• Rather, the electrons are delocalized; this stabilizes aromatic compounds.
![Page 36: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/36.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Reactions of Aromatic Compounds
• Due to this stabilization, aromatic compounds do not undergo addition reactions; they undergo substitution.
• In substitution reactions, hydrogen is replaced by a substituent.
![Page 37: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/37.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Structure of Aromatic Compounds
• Two substituents on a benzene ring could have three possible relationships:– ortho-: On adjacent carbons.– meta-: With one carbon between them.– para-: On opposite sides of ring.
![Page 38: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/38.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Reactions of Aromatic Compounds
Reactions of aromatic compounds often require a catalyst.
Halogenation
Friedel-Crafts Reaction
![Page 39: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/39.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.Func
Functional Groups
The term functional group is used to refer to parts of organic molecules where reactions tend to occur.
![Page 40: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/40.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Alcohols• Alcohols contain one or more hydroxyl groups,
—OH.• They are named
from the parent hydrocarbon; the suffix is changed to -ol and a number designates the carbon to which the hydroxyl is attached.
![Page 41: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/41.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Alcohols
• Alcohols are much more acidic than hydrocarbons.– pKa ~15 for most
alcohols.– Aromatic alcohols
have pKa ~10.
![Page 42: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/42.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Ethers
• Ethers tend to be quite unreactive.• Therefore, they are good polar solvents.
![Page 43: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/43.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Carbonyl Compounds
• The carbonyl group is a carbon-oxygen double bond.
• Carbonyl compounds include many classes of compounds.
![Page 44: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/44.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
AldehydesIn an aldehyde, at least one hydrogen is attached to the carbonyl carbon.
![Page 45: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/45.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Ketones
In ketones, there are two carbons bonded to the carbonyl carbon.
![Page 46: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/46.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Carboxylic Acids
• Acids have a hydroxyl group bonded to the carbonyl group.
• They are tart tasting.• Carboxylic acids are
weak acids.
![Page 47: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/47.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Esters
• Esters are the products of reactions between carboxylic acids and alcohols.
• They are found in many fruits and perfumes.
![Page 48: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/48.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Amides
Amides are formed by the reaction of carboxylic acids with amines.
![Page 49: Organic and Biological Chemistry © 2009, Prentice-Hall, Inc. Chapter 25 Organic and Biological Chemistry Chemistry, The Central Science, 11th edition Theodore](https://reader035.vdocument.in/reader035/viewer/2022062804/5697bf851a28abf838c87300/html5/thumbnails/49.jpg)
Organic andBiologicalChemistry
© 2009, Prentice-Hall, Inc.
Amines
• Amines are organic bases.• They generally have strong, unpleasant
odors.