oza geoenvironmental, inc. - united states … geoenvironmental, inc. 380 harvey road manchester new...

Englnurs Qld

Scientists IOZA GeoEnvironmental Inc

380 Harvey Road Manchester New Hampshire 03103-3347 603-623-3600 FAX 603-624-9463 wwwgzacom

April 12 2012 File No 04002930700

Ms Amy Daigneault Pretreatment Coordinator Lowell Regional Wastewater Utility 451 First St Blvd (Rte 110) Lowell Massachusetts O1850

Re Supplemental Monthly Self-Monitoring Report March 2012 Merrimack Station Public Service ofNew Hampshire Bow New Hampshire

Dear Ms Daigneault

On behalf of Public Service of New Hampshire (PSNH) OZA OeoEnvironmental Inc (OZA) is pleased to submit a supplement to the Self-Monitoring Report previously submitted for the period March 1 2012 through March 31 2012 The attached Table 1 summarizes the data contained in the attached Analytical Data Report from the Stream B sample collected on March 14 2012 The results indicate that pollutant concentrations were within the Local Sewer Discharge Limits

The analysis on samples collected on March 14 2012 was performed in accordance with the United States Environmental Protection Agency (EPA) draft Standard Operating Procedure (SOP) for trace metals analysis of flue gas desulfurization (FOD) wastewater The SOP is described below

ANALYTICAL DISCUSSION

FOD wastewater requires specialized analytical techniques to overcome matrix interference for certain analysis of trace metals To assist you in evaluating this issue further we offer an excerpt below from the EPA web site and a link to their draft SOP for trace metals analysis ofFOD wastewater that contains further guidance

LABORATORY ANALYSIS OF FOO WASTEWATER

Wastewater from FOD systems can contain constituents known to cause matrix interferences E PA has observed that during inductively coupled plasma - mass spectrometry (ICP-MS) analysis ofFOD wastewater certain elements commonly present in the wastewater may cause polyatomic interferences that bias the detection andor quantification of certain elements of interest These potential interferences may become significant when measuring trace elements at concentrations in the low parts-per-billion range

Copyrightcopy 2012 OZA OeoEnvironmental Inc

An Equal Owortuniiy Employer MFNH

Lowell Regional Wastewater Utility File No 04002930700

April 12 2012 Page2

As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed an SOP that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses ofFGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs ofmeasurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewatermiddot takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOPs For further information please see the following

bull Draft SOP Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K ) httpwater epagovlscitechwastetechguideuploadlsteam _draft _soppdf EPA May 2011

Considering that specialized analytical techniques are necessary to overcome matrix interference for certain analysis of trace metals in FGD wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater

Should you have any questions concerning this report please do not hesitate to contact me at (603) 232-8744

Very truly yours

GZA GEOENVIRONMENT AL INC

Ronald A Breton PE Michael P North PE Principal ConsultantReviewer

RABMPN tmd P-l)IJobs0029)00$(W002910lOCJWarlSAMtlNG ANO REPORTINGREPORTSlvelJStJQm13Mir(h B 5Upp)cmcn1final 29307 STREAMB March Splmnt 041212docN

Attachments Table Analytical Data Report

TABLE

TABLEl SUMMARY OF STREAM B CONCENTRATIONS

COMPARED TO LOWELL SEWER DISCHARGE LIMITS Public Service ofNew Hampshire

Merrimack Station Bow New Hampshire

PARAMETER LOWELL SEWER

DISCHARGE LIMITS (mgL)

STREAM B RESULTS 3142012

(mgIL)

Aluminum 2469 0371

Arsenic 0556 00377

Cadmium 0056 000248 Chromium (T) 8108 00532

Copper 3124 00182

Lead 0857 lt 000198

Mercury 0004 00000612

Nickel 1541 0303 pH 50-95 69

Silver 0053 lt 0000990

Zinc 4959 00775

P04obsl0029300sl04002930700WortSAMPLING AND REPORTINGIDATAI 04002930700 RESULTS 032112xll1ltLltgtwcll B GZA GeoEnvironmental Inc

ANALYTICAL DATA REPORT

~--fLAA____________e_a_s_t_e_r_n_a_n_a_ly_t_i_c_a_l__

Paul Pepler

GZA GeoEnvironmental Inc (NH)

380 Harvey Road

Manchester NH 03103

Subject Laboratory Report

Eastern Analytical Inc ID 108420

Client Identification MK

Date Received 3142012

Dear Mr Pepler

Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy ofour NELAP certificate and accredited parameters

The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery

Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)

The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory

If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date

We appreciate this opportunity to be of service and look forward to your continued patronage

Sincerely

11micro3= Date

JS of pages (excluding cover letter)

11middot1111Llibb ~(( 1111

SAMPLE CONDITIONS PAGE EAi ID 108420

Client middot GZA GeoEnvironmental Inc (NH)

Client Designation MK

Temperature upon receipt (degC) 184 Received on ice or cold packs (YesNo) y Acceptable temperature range (degC) 0-6

Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)

10842001 SWWTF 31412 31412 aqueous Adheres to Sample Acceptance Policy

Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis

All results contained in this report relate only to the above listed samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition Including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992

eastern analytical inc wwweailabscom Phone (603) 228-0525 1

LABORATORY REPORT EAi I 0 108420

Client GZA GeoEnvironmental Inc (NH)


Sample ID SWNTF

Lab Sample ID 10842001

Matrix aqueous

Date Sampled 31412

31412Date Received

Solids Suspended 25000 Solids Dissolved 180000 Chloride 75000 BOD 140 COD 900 pH 69

Analysis

Units Date Time Method Analyst

mgL 31912 1345 2540D DLS mgL 31912 1500 2540C DLS mgL 311912 1030 4500CIE DLS mgL 31512 1412 52108 SKC mgL 32012 900 H8000 KJR SU 31412 1705 4500H+B Jl

TDS Due to sample matrix a constant weight of 000059 could not be achieved


QC REPORT EAIID 10842011Jul Client GZA GeoEnvironmental Inc (NH)


Date of

Parameter Name Blank LCS LCSO Units Analysis Limits RPO Method

Solids Suspended lt5 96 (96 ooR) 100 (100 ooR) (4 RPO) mgL 31912 90 -110 20 2540D

Solids Dissolved lt5 990 (99 R) NA mgL 31912 85 - 115 20 2540C

Chloride lt 1 27 (106 ooR) 26 (106 ooR) (0 RPD) mgL 31912 90 - 110 20 4500CIE

BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108

COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000

pH 60 (100 ooR) 60 (100 ooR) (0 RPD) SU 31412 595 - 607 10 4500H+B

Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysls RPO Method

Solids Suspended 10850303 200 190 (4RPD) mgL 31912 20 2540D Solids Dissolved 10843101 270 270 (0 RPO) mgL 31912 20 2540C Chloride NA NA mgL 31912 20 4500CIE BOD NA NA mgL 31512 20 52108 COD NA NA mgl 32012 20 H8000 pH 10838601 82 82 (0 RPO) SU 31412 10 4500H+B

Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bull11 Flagged analyte recoveries deviated from the QAQC limits


Ill

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

G L OS AL S ( I E N lt ES

04 April 2012

JeffGagne

Eastern Analytical Inc

25 Chenell Drive

Concord NH 03301

RE Merrimack Station 2008

Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control

measurements are within established control limits and there were no analytical difficulties encountered

with the exception ofthose listed in the case narrative section of this report

Ifyou have any questions concerning this report please feel free to contact me

Sincerely 44

Liz Siska

Project Manager

4

~ 11720 North Creek Parkway North Suite 400

Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096

GLOBAl SCIENCES

ANALYTICAL REPORT FOR SAMPLES

Laboratory Frontier Global Sciences Inc SDG

Client Eastern Analytical ]nc Project Merrimack Station 2008

Sample ID Lab ID Matrix Date Sampled Date Received

SWWTF 1203203-01 Water 14-Mar-12 1305 16-Mar-12 0940

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Pagel o20 1203203 Final Report-SWWTF REV2

041042012

Liz Siska Project Manager 5


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

CASE NARRATIVE

Revised Report 4412- Sample name corrected to SWWTF

SAMPLE RECEIPT

Samples were received at Frontier Global Sciences (FGS) on March 16th 2012 The samples were received intact on-ice with temperatures measuredat 22 degrees Celsius

SAMPLE PREPARATION AND ANALYSIS

Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)

Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 JE

ANALYTICAL ISSUES

The client requested sample SWWTF (1203203-0 l) be analyzed for Mn via email on 31512

Samples were received in a cooler ofmelted ice There was water in the inner most bag of sample Evaporator (1203203-02)

As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report

A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report

Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 2 of20 1203203 Final Report- SWWTF REV2

04042012


FRONTIER


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIE NCES

CHAIN OF CUSTODY FORMS

bullbull _ ~ -bull uer ( A c 2 - gt Sampre Recefpt CHockJlst

Data Looobulld tn ~tZfrPkttr ~~middot0 middot1)d bull MSi~~gtamp Loss bull d I n Sy

SOG o f Coolns- R~oetvbullG I ( FGSPM

Sarn01 AnIVed bull)I ----Shipp ing --=--___~~-=-------=_lta=~-=--===---------

___Nona (ArnblbullnQ

SbullNfo Cour1bullr TrecklngJAtrtgtIII Nubbulltbull) e Xlt---Z-~q gt

-rhermal PreuorvatJon Loo~ l~ ___GeleJubull lea

rT~hbull_ornebullur_10~gt~(~5z2~_--CorrftCtfan rbullclOf (Cfl) ~lt2 - 3 degre-bull O eoolbullr- 1 L ~ middoto CoCttbullr a bullc eoolbullr-2 middot c Cootbullr7 middotc

middot c Cooler a bullc middot c

middotc middot c

Coolar 18

Chbullln orCutody COO $ pria1-ct-n bullnd lneludee thbull folto~ng Information for obulloh ~~mple

NA Comrnbullnta

Sbullrnolampd BvshyPrbullbullation bullmiddot ~uoa1bulld Ana1vbullbullbullmiddot Roaulbulld SlcnHt vrbullr

middot------------ shy ---ilnt-nat chaln or custOdv irv1d

l-~=V

---l shy ---+--~-shy ----+-----------1

Samplbull CondltJonltnte-oi $bullmole containerbull wbullra -oehbulld Jr1tlact bull--bull labolbull bullshy _nt bulln lenfbln

lteon-eet aamIbull oontarners U ~ltftd fcrr reauect1Dd 0rnafv8ebull sbullm-reraquo roCHtlvOd In holdrna tlmomiddot bullbullrn- bull vohnlIbull auMolen ~~r raubullbulltbulld anaalvbull a

Voa No

CotTbulld orbullbullbulltvotlvbull ucact for aue atect -nahrbull _ -shyM of bull-n~tshy Qhertced a-d mthod l~e-ntbull -

Cllent Communloatfott Po~ Contaicta Oat611mbull _____ _

Commentbull

Mbulltnod ____ _

Olbull~bullronJRbullbullo1utlon

The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety

Page3of20 1203203 Final Rtport- SWWTFREV2

04042012


l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011

Ph 425-686-1996 Fx 425-686-3096

FRONTIER GLOBAL SCIENCES


The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety

Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2

04042012

Liz Siska Project Manager

8

11720 North Creek Parkway North Suite 40U Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

FRONTIER C L 0 B AL SC I~ NC ES

CHAlN OF CUSTODY FORMS

i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-

CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~

The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety

Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2

ommo12

Liz SiskaProject Manager

9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096

Matrix Water Laboratory ID 1203203-01

ANALYTICAL RESULTS

SWWTF

Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes

Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod

Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod

Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod

Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod

Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod

Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod

Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod

Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631

Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod

Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod

Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod

Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page6 o20 I203203 Final Report- SWWTF REV2

04042012


gt

C LO BA L S CI E N C ES


Ph 425-686-1996 Fx 425-686-3096

MATRIX DUPLICATESTRIPLICATES

SOURCE 1203203-01

Batch F203288

Preparation BrCl Oxidation

Sequence 2C22016

Lab Number F203288-DUPI

Sample Duplicate Concentration Concentration RPD

Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety

Page 7of20 l 103203 Final Report- SWWTF REV2

04042012 bull 1 1 Liz Siska Project Manager


Ph 425-686-1996

FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1203203-01

Batch F203232 Sequence 2C20001

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1

Sample Spike MS MS Concentration Added Concentration 0o Recovery

Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits

Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod

Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod

Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod

Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod

Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod

Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod

Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery

Limits RPOLimit Method Notes

Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod

Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod

Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod

Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

PageBo20 1203203 FinalReport- SWWTFREV2

04042012


iii

11720 North Creek Parkway North Suite 400

Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES

ij


SOURCE 1203203-01

Batch F203232 Sequence 2Q20001

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3

Analyte

Sample Concentration

(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS

Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS

Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS

middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery

Limits RPDLimit Method Notes

Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS

~~ middotmiddot1 bull

bulli

bullmiddot

Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety

Page 9of20 1203203 Final Report-SWWTF REY2

04M2012



Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1203203-01RE3



Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02

Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits

RPO Limit Method Notes

Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page Oo20 1203203 Final Report- SWWTFREV2

04042012


Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety



Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1203203-0lREJ

Batch F203260

Preparation Closed Vessel Nitric Oven Digestion

Sequence 2C2200

Lab Number F203260-MSMSD6

Sample Spike MS MS

Analyte Concentration Added

(JtgL) (microgL) Concentration

(microgL)

Recovery Recovery

Method Limits Notes

Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS

Spike MSD Added Concentration

MSD Recovery RPD

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS

1 o20 1203203 Final Report- SWWTF REJ2

040412012

15


Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1203203-01

Batch F203288

Preparation BrCI Oxidation

Sequence 2C22016

Lab Number F203288-MSMSD 1

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits

Mercury 6116 25500 3096 974 71 - 125 EPA 1631E

Spike MSD MSD Oo Recovery RPD Added Concentration Oo

Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte

Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 12of20 1203203 Final Report- SWWTF REV2

04042012


bull 11720 North Creek Parkway North Suite 400

Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17


Preparation BrCI Oxidation Lab Number F203288-MSMSD2

Sample Spike MS MS

Analyte Concentration

(ngL) Added (ngL)

Concentration (ngL) Recovery

Recovery Limits Method Notes

Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO

Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes

Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety

Page 13of20 1203203 Final Report- SWWTFREV2

04042012



Ph 425-686-1996

bull ~ Fx 425-686-3096 GLPBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD


Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1

LCS Source mank Siiike

Spike LCS LCS Added Concentration Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod

Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod

shy

Spike LCSD LCSD Added Concentration Oo Recovery RPD

Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum

Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod

Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod

Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod

Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod

Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod

Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod

Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod

Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod

Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod

Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod

Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety


04042012 ~~


11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996

FRONTIER Fx 425-686-3096 GLOBAL SCIENCES


RECOVERY AND RPD



LCS Source Blank Spike

Spike LCS LC$ Added Concentration Recovery

Analyte (ptgL) (JJgL) Recovery Limits Method Notes

Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod

Spike LCSD LCSD Added Concentration Recovery RPD


Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety

Page 15 o20 I203203 Ftnal ampport- SWWTFREV2

04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO


Preparation BrCI Oxidation Lab Number F203288-BSBSD I

LCS Source NIST 1641d


Analyte (ngL) (ngL) Recovery Limits Method Notes

Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679

Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 16 o20 1203203 Final Report- SWWIFREV2

041042012

20Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 middot Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C20001


Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u

middoti

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty

Page7of20 J203203 Final ampport-SWWTF REV2

04042012




PREPARATION BLANKS




F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u

Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety


04042012


~ CLOSAL SCIENCES

~

J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS

Instrument Hg-17 Sequence 2C22016


The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety

Page I9oj20 1203203 Final Report- SWWTF REJ2

04042012

Frontier Global Sciences Inc

bull 23bull Liz Siska Project Manager


F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD

QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

l1RL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation



The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety


04042012

24

bull bull

irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~

Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS

i w I shy i

SAMPLING 0 iii 0 ~

w = ~ DATET1ME QIll c X

w ~sacw 0IF COMPOSITE -gtc ~ u - ~

INDICATE 80TH ~ bulllo- t5a5 START amp FINISH

er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~

bull 7gtItJJJI JWj T ~ tlt

IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl

PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH

i ~~ ~ I ~ X

j i I i= -shy 2 s~ ~ == a~ -shy I t

~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j

M ICRO middot-- -shy108420

sshyj

sect= s

~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3

I 3 ~ It _ c

1

DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No

A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1

J pbNo FAX E-MAIL PDF EQUIS

E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W

PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy

SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull

REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=

GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______

PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2

eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM

prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)

shy

shy

Lowell Regional Wastewater Utility File No 04002930700

April 12 2012 Page2

As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed an SOP that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses ofFGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs ofmeasurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewatermiddot takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOPs For further information please see the following

bull Draft SOP Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K ) httpwater epagovlscitechwastetechguideuploadlsteam _draft _soppdf EPA May 2011

Considering that specialized analytical techniques are necessary to overcome matrix interference for certain analysis of trace metals in FGD wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater

Should you have any questions concerning this report please do not hesitate to contact me at (603) 232-8744

Very truly yours

GZA GEOENVIRONMENT AL INC

Ronald A Breton PE Michael P North PE Principal ConsultantReviewer

RABMPN tmd P-l)IJobs0029)00$(W002910lOCJWarlSAMtlNG ANO REPORTINGREPORTSlvelJStJQm13Mir(h B 5Upp)cmcn1final 29307 STREAMB March Splmnt 041212docN

Attachments Table Analytical Data Report

TABLE







(mgIL)

Aluminum 2469 0371

Arsenic 0556 00377


Copper 3124 00182

Lead 0857 lt 000198

Mercury 0004 00000612

Nickel 1541 0303 pH 50-95 69

Silver 0053 lt 0000990

Zinc 4959 00775




Paul Pepler


380 Harvey Road

Manchester NH 03103





Dear Mr Pepler







Sincerely

11micro3= Date















Sample ID SWNTF


Matrix aqueous

Date Sampled 31412

31412Date Received


Analysis







Date of





BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108

COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000






Ill


Ph 425-686-1996 Fx 425-686-3096


04 April 2012

JeffGagne


25 Chenell Drive

Concord NH 03301






Sincerely 44

Liz Siska

Project Manager

4


Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096

GLOBAl SCIENCES








041042012



Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

CASE NARRATIVE


SAMPLE RECEIPT





ANALYTICAL ISSUES






of20 1203203 Final Report- SWWTF REV2

04042012


FRONTIER


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIE NCES











middotc middot c

Coolar 18


NA Comrnbullnta



l-~=V

---l shy ---+--~-shy ----+-----------1



Voa No



Commentbull

Mbulltnod ____ _




04042012



Ph 425-686-1996 Fx 425-686-3096





04042012


8


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~



ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD



Page 11 o20 1203203 Final Report- SWWTF REJ2

040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy

TABLE







(mgIL)

Aluminum 2469 0371

Arsenic 0556 00377


Copper 3124 00182

Lead 0857 lt 000198

Mercury 0004 00000612

Nickel 1541 0303 pH 50-95 69

Silver 0053 lt 0000990

Zinc 4959 00775




Paul Pepler


380 Harvey Road

Manchester NH 03103





Dear Mr Pepler







Sincerely

11micro3= Date















Sample ID SWNTF


Matrix aqueous

Date Sampled 31412

31412Date Received


Analysis







Date of





BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108

COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000






Ill


Ph 425-686-1996 Fx 425-686-3096


04 April 2012

JeffGagne


25 Chenell Drive

Concord NH 03301






Sincerely 44

Liz Siska

Project Manager

4


Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096

GLOBAl SCIENCES








041042012



Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

CASE NARRATIVE


SAMPLE RECEIPT





ANALYTICAL ISSUES







04042012


FRONTIER


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIE NCES











middotc middot c

Coolar 18


NA Comrnbullnta



l-~=V

---l shy ---+--~-shy ----+-----------1



Voa No



Commentbull

Mbulltnod ____ _




04042012



Ph 425-686-1996 Fx 425-686-3096





04042012


8


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~



ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy







(mgIL)

Aluminum 2469 0371

Arsenic 0556 00377


Copper 3124 00182

Lead 0857 lt 000198

Mercury 0004 00000612

Nickel 1541 0303 pH 50-95 69

Silver 0053 lt 0000990

Zinc 4959 00775




Paul Pepler


380 Harvey Road

Manchester NH 03103





Dear Mr Pepler







Sincerely

11micro3= Date















Sample ID SWNTF


Matrix aqueous

Date Sampled 31412

31412Date Received


Analysis







Date of





BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108

COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000






Ill


Ph 425-686-1996 Fx 425-686-3096


04 April 2012

JeffGagne


25 Chenell Drive

Concord NH 03301






Sincerely 44

Liz Siska

Project Manager

4


Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096

GLOBAl SCIENCES








041042012



Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

CASE NARRATIVE


SAMPLE RECEIPT





ANALYTICAL ISSUES







04042012


FRONTIER


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIE NCES











middotc middot c

Coolar 18


NA Comrnbullnta



l-~=V

---l shy ---+--~-shy ----+-----------1



Voa No



Commentbull

Mbulltnod ____ _




04042012



Ph 425-686-1996 Fx 425-686-3096




Frontier Global Sciences Inc o20 1203203 Final Report- SWWTF REV2

04042012


8


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~



ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy



Paul Pepler


380 Harvey Road

Manchester NH 03103





Dear Mr Pepler







Sincerely

11micro3= Date















Sample ID SWNTF


Matrix aqueous

Date Sampled 31412

31412Date Received


Analysis







Date of





BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108

COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000






Ill


Ph 425-686-1996 Fx 425-686-3096


04 April 2012

JeffGagne


25 Chenell Drive

Concord NH 03301






Sincerely 44

Liz Siska

Project Manager

4


Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096

GLOBAl SCIENCES








041042012



Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

CASE NARRATIVE


SAMPLE RECEIPT





ANALYTICAL ISSUES







04042012


FRONTIER


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIE NCES











middotc middot c

Coolar 18


NA Comrnbullnta



l-~=V

---l shy ---+--~-shy ----+-----------1



Voa No



Commentbull

Mbulltnod ____ _




04042012



Ph 425-686-1996 Fx 425-686-3096





04042012


8


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~


Frontier Global Sciences Inc o20 T203203 Final Report-SWWTFREV2

ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy


Paul Pepler


380 Harvey Road

Manchester NH 03103





Dear Mr Pepler







Sincerely

11micro3= Date















Sample ID SWNTF


Matrix aqueous

Date Sampled 31412

31412Date Received


Analysis







Date of





BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108

COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000






Ill


Ph 425-686-1996 Fx 425-686-3096


04 April 2012

JeffGagne


25 Chenell Drive

Concord NH 03301






Sincerely 44

Liz Siska

Project Manager

4


Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096

GLOBAl SCIENCES








041042012



Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

CASE NARRATIVE


SAMPLE RECEIPT





ANALYTICAL ISSUES







04042012


FRONTIER


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIE NCES











middotc middot c

Coolar 18


NA Comrnbullnta



l-~=V

---l shy ---+--~-shy ----+-----------1



Voa No



Commentbull

Mbulltnod ____ _




04042012



Ph 425-686-1996 Fx 425-686-3096





04042012


8


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~



ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy













Sample ID SWNTF


Matrix aqueous

Date Sampled 31412

31412Date Received


Analysis







Date of





BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108

COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000






Ill


Ph 425-686-1996 Fx 425-686-3096


04 April 2012

JeffGagne


25 Chenell Drive

Concord NH 03301






Sincerely 44

Liz Siska

Project Manager

4


Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096

GLOBAl SCIENCES








041042012



Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

CASE NARRATIVE


SAMPLE RECEIPT





ANALYTICAL ISSUES







04042012


FRONTIER


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIE NCES











middotc middot c

Coolar 18


NA Comrnbullnta



l-~=V

---l shy ---+--~-shy ----+-----------1



Voa No



Commentbull

Mbulltnod ____ _




04042012



Ph 425-686-1996 Fx 425-686-3096





04042012


8


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~



ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116


of20 l 103203 Final Report- SWWTF REV2



Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy




Sample ID SWNTF


Matrix aqueous

Date Sampled 31412

31412Date Received


Analysis







Date of





BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108

COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000






Ill


Ph 425-686-1996 Fx 425-686-3096


04 April 2012

JeffGagne


25 Chenell Drive

Concord NH 03301






Sincerely 44

Liz Siska

Project Manager

4


Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096

GLOBAl SCIENCES








041042012



Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

CASE NARRATIVE


SAMPLE RECEIPT





ANALYTICAL ISSUES







04042012


FRONTIER


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIE NCES











middotc middot c

Coolar 18


NA Comrnbullnta



l-~=V

---l shy ---+--~-shy ----+-----------1



Voa No



Commentbull

Mbulltnod ____ _




04042012



Ph 425-686-1996 Fx 425-686-3096





04042012


8


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~



ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy



Date of





BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108

COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000






Ill


Ph 425-686-1996 Fx 425-686-3096


04 April 2012

JeffGagne


25 Chenell Drive

Concord NH 03301






Sincerely 44

Liz Siska

Project Manager

4


Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096

GLOBAl SCIENCES








041042012



Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

CASE NARRATIVE


SAMPLE RECEIPT





ANALYTICAL ISSUES







04042012


FRONTIER


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIE NCES











middotc middot c

Coolar 18


NA Comrnbullnta



l-~=V

---l shy ---+--~-shy ----+-----------1



Voa No



Commentbull

Mbulltnod ____ _




04042012



Ph 425-686-1996 Fx 425-686-3096





04042012


8


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~



ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot


of20 1203203 Final Report-SWWTF REY2

04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy

Ill


Ph 425-686-1996 Fx 425-686-3096


04 April 2012

JeffGagne


25 Chenell Drive

Concord NH 03301






Sincerely 44

Liz Siska

Project Manager

4


Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096

GLOBAl SCIENCES








041042012



Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

CASE NARRATIVE


SAMPLE RECEIPT





ANALYTICAL ISSUES







04042012


FRONTIER


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIE NCES











middotc middot c

Coolar 18


NA Comrnbullnta



l-~=V

---l shy ---+--~-shy ----+-----------1



Voa No



Commentbull

Mbulltnod ____ _




04042012



Ph 425-686-1996 Fx 425-686-3096





04042012


8


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~



ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy


Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096

GLOBAl SCIENCES








041042012



Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

CASE NARRATIVE


SAMPLE RECEIPT





ANALYTICAL ISSUES







04042012


FRONTIER


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIE NCES











middotc middot c

Coolar 18


NA Comrnbullnta



l-~=V

---l shy ---+--~-shy ----+-----------1



Voa No



Commentbull

Mbulltnod ____ _




04042012



Ph 425-686-1996 Fx 425-686-3096





04042012


8


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~



ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD



o20 1203203 Final Report- SWWTF REJ2

040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

CASE NARRATIVE


SAMPLE RECEIPT





ANALYTICAL ISSUES







04042012


FRONTIER


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIE NCES











middotc middot c

Coolar 18


NA Comrnbullnta



l-~=V

---l shy ---+--~-shy ----+-----------1



Voa No



Commentbull

Mbulltnod ____ _




04042012



Ph 425-686-1996 Fx 425-686-3096





04042012


8


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~



ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy

FRONTIER


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIE NCES











middotc middot c

Coolar 18


NA Comrnbullnta



l-~=V

---l shy ---+--~-shy ----+-----------1



Voa No



Commentbull

Mbulltnod ____ _




04042012



Ph 425-686-1996 Fx 425-686-3096





04042012


8


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~



ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E


of20 1203203 Final Report- SWWTFREV2

04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy


Ph 425-686-1996 Fx 425-686-3096





04042012


8


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~



ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy


Ph 425-686-1996 Fx 425-686-3096




CN _r(gt --shyshy~

_lj _D ~ -~ Irgt ~ -f

~ ~



ommo12


9

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD











o20 I203203 Ftnal ampport- SWWTFREV2

04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy

)--J middot ~~

)J fl~~J~c1N~r


Ph 425-686-1996 Fx 425-686-3096


ANALYTICAL RESULTS

SWWTF
















04042012


gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679


o20 1203203 Final Report- SWWIFREV2

041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy

gt



Ph 425-686-1996 Fx 425-686-3096


SOURCE 1203203-01

Batch F203288


Sequence 2C22016



Analyte DgL ngL

5848

MRL 505

RPD 448

Limit

24

Method

EPA 163IE

Notes

Mercury 6116





Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy


Ph 425-686-1996



SOURCE 1203203-01





Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod

Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod


Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod

Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod

Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod

Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod


Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod


Lead 0763 15152 1544 968 70-130 EPA2008Mod

Analyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery



Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod


Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod

Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod

Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod

Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod

Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod

Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod

Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod

Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod



04042012


iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy

iii



ij


SOURCE 1203203-01



Analyte


(microgL)

Spike Added (pgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes




middoti

i

Aoalyte


MSD Concentration

(microgL)

MSD o

Recovery

RPD Recovery




bulli

bullmiddot



04M2012








Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy







Analyte


(microgL)


MS Conctntration

(microgL)

MS

Recovery Recovery

Method Limits Notes


Analyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





04042012





Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy




Ph 425-686-1996 Fx 425-686-3096

CLO~AL SCIENCES



Batch F203260


Sequence 2C2200


Sample Spike MS MS



(microgL)

Recovery Recovery

Method Limits Notes



MSD Recovery RPD




040412012

15




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy




SOURCE 1203203-01

Batch F203288


Sequence 2C22016




Mercury 6116 25500 3096 974 71 - 125 EPA 1631E



Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E



04042012



Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy


Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES


SOURCE 1203194-17



Sample Spike MS MS


(ngL) Added (ngL)



Mercury 142800 505000 627200 959 71 - 125 EPA 1631E

Spike Added

MSD Concentration

MSD Recovery RPO


Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E



04042012



Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy


Ph 425-686-1996



RECOVERY AND RPD








shy


Analyte (microgL)

15000

(microgL)

1424

Recovery

949

RPD

140

Limits

85 bull 115

Limit

20

Method

EPA 2008 Mod

Notes

Aluminum



Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod


Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod

Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod


Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod




Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod



04042012 ~~





RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy




RECOVERY AND RPD












04041202


middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy

middot

I


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SC IE NC ES


RECOVERY AND RPO






Mercury 15679 1525 973 80 - 120 EPA l631E


Analyte (ngL) (ngL)

1516

Recovery

967

RPD

0622

Limits

80 - 120

Limit

24

Method

EPA 1631E

Notes

Mercury 15679



041042012




PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy



PREPARATION BLANKS





middoti



04042012




PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy



PREPARATION BLANKS







04042012


~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy

~ CLOSAL SCIENCES

~


Ph 425-686-1996 Fx 425-686-3096

PREPARATION BLANKS





04042012






Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy


Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES



















04042012

24

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy

bull bull



i w I shy i

SAMPLING 0 iii 0 ~








i ~~ ~ I ~ X


~~ =~ 2 ~~

~ X a c 2 ~ ~ = -- 2 ~

l j t z i () ~

C 0 5~ s~ = IC 0

C -s ~ = ~ ~e f

0 ~= ~ _sC a ~ C) -shyt( I rt

1 g0

3 i ~-

]-

f~ js~ i

~bull m = olt 1 o(

1 e

j


sshyj

sect= s


I 3 ~ It _ c

1












shy

shy

oza geoenvironmental, inc. - united states … geoenvironmental, inc. 380 harvey road manchester new...

Documents