smr summary sh:eet · 2016. 6. 24. · t i gza . geoenvironmental, inc. engineers and. scientists....
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IGZA GeoEnvironmental Inc
Engineers and
Scientists
380 Harvey Road Manchester New Hampshire 03103-3347 603-623-3600 FAX 603-624-9463
wwwgzacom
March 31 2012 File No 04002930700
Ms Amy Daigneault Pretreatment Coordinator Lowell Regional Wastewater Utility 451 First St Blvd (Rte 110) Lowell Massachusetts 01850
Re Monthly SelfMonitoring Report March 2012 Merrimack Station Public Service ofNew Hampshire Bow New Hampshire
Dear Ms Daigneault
On behalfofPublic Service of New Hampshire (PSNH) GZA GeoEnvironmental Inc (GZA) is pleased to submit the attached Self-Monitoring Report (SMR) for the period March 1 2012 through March 31 2012 This SMR is intended to satisfy Conditions 7 and 8 of the Interim Discharge Authorization (IDA) issued to PSNH by the Lowell Regional Wastewater Utility (Utility) dated September 28 2011 A supplemental Stream B report from samples collected on March 14 2012 will be submitted in April The analysis on samples collected on March 2 2012 was performed in accordance with the United States Environmental Protection Agency (EPA) draft Standard Operating Procedure (SOP) for trace metals analysis of flue gas desulfurization (FGD) wastewater The SOP is described below
The attached SMR Summary Sheet summarizes the analytical results for all required parameters as outlined in Condition 8 of the IDA The attached Analytical Data Report however contains a more comprehensive list of parameters The results indicate that pollutant concentrations were within the Local Sewer Discharge Limits Wastewater flow data for the monitoring period was estimated based on the actual number of tanker trucks sent to the Utility from March 1 2012 through March 31 2012 and tanker capacity
ANALYTICAL DISCUSSION
FGD wastewater requires specialized analytical techniques to overcome matrix interference for certain analysis of trace metals To assist you in evaluating this issue further we offer an excerpt below from the United States Environmental Protection Agency (EPA) web site and a link to their draft SOP for trace metals analysis ofFGD wastewater that contains further guidance
LABORATORY ANALYSIS OF FGD WASTEWATER
Wastewater from FGD systems can contain constituents lmown to cause matrix interferences EPA has observed that during inductively coupled plasma - mass spectrometry (ICP-MS) analysis of FGD wastewater certain elements commonly present in the wastewater may cause polyatomic interferences that bias the detection andor quantization of certain elements of interest These potential interferences may become significant when measuring trace elements at concentrations in the low parts-per-billion range
Copyrightcopy 2012 GZA GeoEnvironmental Inc
All poundqua Opponunity Employer MFNH
Lowell Regional Wastewater Utility File No 04002930700
March 31 2012 Page2
As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed an SOP that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses of FGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPA s draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOPs For further information see
Standard Operating Procedure Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K) httpwaterepagovscitechwastetechguideuploadsteam_draft _soppd EPA May 2011
Considering that specialized analytical techniques are necessary to overcome matrix interference for certain analysis of trace metals in FGD wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater
Should you have any questions concerning this report please do not hesitate to contact me at (603) 232-8744
Very truly yours
GZA GEOENVIRONMENTAL INC
(fdotJti ~ Ronald A Breton PE Michael P North P E Principal ConsultantReviewer
RABMPNtmd
Attachments SMR Summary Sheet Analytical Data Report
SMR SUMMARY SHEET
LOWELL REGIONAL WASTEWATER UTILITY Industrial Sewer User Self-Monitoring Report Summary Sheet
Facilitv Information Company Name Public Service ofNew Hampshire NA(lnterim Discharge
Facility Address 97 River Road Bow New Hampshire Permit No Authorization)
Facility Contact _H_arol_d_~~eyes~-- --------- Telephone (603) 2244081
----UseASeparate Summary Sheet For Each llonitorlng Point--- -shy
Monitoring Report Monitoring Point End ofpretreatment process Submittal Date March 31 2012 Reporting Period (circle applicable) Baseline Annually Semi-Annually Quarterly Re-Sample8
Reporting Period Start Date March 1 2012 Reporting Period End Date ___ = _1--2012M=arch 3 ~
Sample Analvsis Certified Analytical lab Ea== == (=EAi)______________ _= stem An=a41yticalrlnc~
Authorized Rep Lorraine Olashaw 12__ ___Certification No _10 _
Analytical Sub-Contractor Frontier Global Sciences Certification No E87575 ____=__ _
Sample Collection Sampler (labSelfOther) Jim Blackwell Gregg Thompson EAi
Sanie Type(s)(cirde all that apply) Time Composite Flow Composite8 = ===____ _~= =_____ _
pH (Standard Units) __1 __ Instantaneous Flow Rate (GPM) Nl____
Grab Sampling Sample Date 3022012 _ _ Sam~eTime 1100~am
7_ A
Comoosite Sampling Start DateTime _Nc_A_______ Stop DateTime -N---A--------- shy
No Aliquots NIA Aliquot Volume -N=A------- Sample Volume __c_A------- shyN
9174 (Average of FlowData Sampling Interval Volume (Gal) NIA Daily Flow Rate (GPO) =~__d_isch==arg-e-days) _
Stream A 24000 Monitoring Period Industrial Wastewater Flaw (Gal) _ _______~ 2 __ [ [ X ] Estimate_St=re=am B 3104 ] Meter
Monitoring Period Start Date March 1 2012 Monitortng Period End Date March 31 2012
Refer to Sell-Monitoring ReportInstructions for details on completing this SIIR SummarySheet LRWWU Use Only Self-Monitoring Report Summary Sheet Page 1 of2
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LOWELL REGIONAL WASTEWATER UTILITY Industrial Sewer User Self-Monitoring Report Summary Sheet
An~i=IR-lfflt middot PararnetGt J r bullbull ~Date
Result tnml Parameter AnalYsis obullmiddot I bull1 rResult (maiil middot
BOD Cooner I coo 03052012 170 Cvankle ITotan
OampG 4131IMC Fluoride
TSS lead 03Agt82012 lt 0000800
roemiddot Merourv 03082012 00000172
rro-9241 ~ - 6251am Mtwbdampnum I
Aluminum Nickel
Antimonv Nitro1en OOeldahO
Arsenic 03092012 000812 Phenols (Total)
Barium Selenium
Bervtlium SilYer 03092012 lt0000400
cadmium 0309J2012 lt0000400 Thawn
Chromium (Hexavalentl Zinc
Chromium ITotlllI Other
BOD= Bloclemcal Oxygen Demand COD =ChemicalOxygen Demand OampG=OilampGrease TSS =Total Suspended Saids 1TO Total Toraquoc Otgoocs -roe (Total Organic Cattlon) =Is the amount ofcarbonbound in an Ofg8fllc coovotrd andis often usedas anonspoci6cirdcatorotwaerquality roe measuresbolh tigtamp total carbonpt11sentaswellas the no(garic C8lbon (IC Soo0llc6ng themianlcC8lbon tom the totalC8lbon )Mids TOC HTTOs =Summation of1111quantilable valws greaterthan 001 mgl for toxic orgaic lstedin 40 CFR 41302(i) TTOsinclude PCBs (Poly-Olbrinaled8pherrJs) VOCs (Voatto Organic Cofryen)0Ufl(ls) SVOCs(Seml-Vollllile Organic C-Ompounds) PCBs VOCs and SVOCs shall be anafzed using EPAMethods 608 624and 625 respedively
zero pjscharge LSetfMoQitorillQ (initial Itapplicable)
_ ___ No industrial wastewaterfrom permitted processes has been discharged to sewerduring the monitoring period
____ Nosampling has been conducted on pennitted sewer discharges during the monit~ period
Certification Statement
ceftify under penallf of law that this document and all attachmentswete pnipared under mycfrection or supervision il acoordance with asystem designed to assure that qualified personnel properly gather and evaluate Ile Information submitted Based on my lnqulry ofIle person or persons who manage the system or those persons diredly resp()Ml)le for ~ Ile ilfonnalon tie inbmation Stbmitted Is to Iha best of my knowledge and befief true acctrale and complete Iam awre that llere tre SVificant penalties for ~ false ilfonnation idicfing Ile posslblltyoffine and imprisonmentfor knowing ~alions bull
Harold Keyes Station Manager
I l Date
LRWWU Use Only Self-Monitoring Report Summary Sheet Page 2 of2
i
i I
bull
ANALYTICAL DATAREPORT
_middotmiddot_ ~ _l________f
___e_a_s_t_e_rn_a_n_a_l_y_t1_middotc_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report Eastern Analytical Inc ID 108078
Client Identification Wastewater Analysis
Date Received 322012
Report revisionreissue Revision replaces report dated 32612
Revision lnfonnatlon Per your request Lead as been analyzed on the samples submitted to Frontier Global Sciences
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
r The following standard abbreviations and conventions apply to all EAi reports
Solid samples are reported on a dry weight basis unless otherwise noted lt less thanbull followed by the reporting limit gt greater thanbull followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following Information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
Ifyou have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
of pages (excluding cover letter)
I J bull - bull ~ bull I i middot 1n1wcaibb~cc1m t middot middot middot
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SAMPLE CONDITIONS PAGE EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Temperature upon receipt (degC) 21 Received on ice or cold packs (YesNo) Y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10807801 Effluent_Fiekl Blank B-3621 3212 3212 aqueous Adheres to Sample Acceptance Policy
10807802 Final Effluent B-3625 8middot3727 3212 3212 aqueous Adheres to Sample Acceptance Polley B-3722
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint shylgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
Afl results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
II LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 8-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 32112
Units ug1
Date of Analysis 3l712
Analyst BAM
Method 624 1DIiution Factor
Chloromethane lt5 Vinyl chloride lt2 Bromomethane lt2 Chloroethane lt5 Trichlorofluoromethane lt5 Acrolein lt 50 Acetone lt50 1 1-Dichloroethene lt1 Methylene chloride lt5 Carbon disulfide lt5 Acry1onitrile lt 50 Methy-t-butyl ether(MTBE) lt 10 trans-12-Dichloroethene lt2 Vinyl acetate lt 10 1 1-Dichloroethane lt2 cis-12-Dichloroethene lt2 2-Butanone(MEK) lt 10 Chloroform lt2 1 1 1-Trichloroethane lt2 Carbon tetrachloride lt2 Benzene lt 1 12-0lchloroethane lt2 Trichloroethene lt2 12-Dichloropropane lt2 Bromodichloromethane lt2 2-Chloroethylvinylether lt2 4-Methyl-2-pentanone(MIBK) lt 10 cis-13-Dichloropropene lt2 Toluene lt1 trans-13-Dlchloropropene lt2 112-Trichloroethane lt2 2-Hexanone lt 10 Tetrachloroethene lt2 Dlbromochloromethane lt2 Chlorobenzene lt2 Ethylbenzene lt1 mp-Xylene lt1 o-Xylene lt 1 Styrene lt 1 Bromoform lt2 1122-Tetrachloroethane lt2 13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 4-Bromofluorobenzene (surr) 93degoR 12-Dichlorobenzene-d4 (surr) 99degoR
~
eastern analytical inc wwweaifabscom Phone (603) 228-0525 2
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LABORATORY REPORT EAi I 0 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent B-3625 B-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 3212
Units ug1
Date of Analysis 3712
Analyst BAM Method 624
Dllution Factor 1
Toluene-dB (surr) 94R
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
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QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Parameter Name
Chloromethane
Blank LCS LCSO Analysis Date Units Limits RPO Method
624 lt5 20 (99 R) 20 (101 R) (2 RPD) 372012 ug1 0-273 20 Vinyl chloride lt2 20 (102 R) 21 (106 R) (4 RPO) 372012 ug1 0- 251 20 624 Bromomethane lt2 19 (93 R) 21 (103 R) (10 RPD) 372012 ug1 0- 242 20 624 Chloroethane lt5 23 (113 R) 22 (110 R) (3 RPO) 3172012 ug1 14 - 230 20 624 Trichlorofluoromethane lt5 22 (108 R) 22 (108 R) (0 RPO) 372012 ug1 17-181 20 624 Acrolein lt 50 bull lt 50 (R bull lt 50 (R NIA) (RPO NIA) 372012 ug1 40-160 20 624 Acetone lt 50 bull lt 50 (188 R) lt 50 (114 R) (49 RPO) 372012 ug1 40 - 160 20 624 1 1-0lchloroethene lt 1 19 (97 R) 19 (95 R) (2 RPO) 372012 ug1 0-234 20 624 Methylene chloride lt5 22 (110 R) 22 (108 R) (2 RPO) 372012 ug1 0 - 221 20 624 Carbon disulfide lt5 17 (85 R) 17 (83 R) (2 RPO) 372012 ug1 70 - 130 20 624 Acrylonitrile lt 50 lt 50 (109 R) lt 50 (104 R) (5 RPO) 372012 ug1 40 - 160 20 624 Methyl-t-butyl ether(MTBE) lt10 20 114 R) 20 (113 R) (1 RPO) 372012 ug1 70 - 130 20 624 trans-12-0ichloroethene lt2 19 (96 R) 19 (96 R) O RPO) 372012 ugJ 54-156 20 624 Vinyl acetate lt 10 30 (137 R) 30 (134 R) (2 RPO) 372012 ug1 40- 160 20 624 1 1-0ichlloroethane lt2 21 (106 R) 21 (104 R) (2 RPO) 372012 ug1 59 - 155 20 624 cis-12-Dichloroethene lt2 20 (101 R) 20 (99 R) (2 RPO) 372012 ug1 70 - 130 20 624 2-Butanone(MEK) lt10 30 (130 R) 20 (100 R) (26 RPO) 372012 ug1 40 - 160 20 624 Chloroform lt2 21 (104 R) 21 (104 R) (0 RPO) 372012 ug1 51 - 138 20 624 1 1 1-Trichloroethane
Carbon t etrachloride
lt2 22 (111 R) 22 (110 R) (1 RPO) lt2 24 (122 R) 24 (121 R) (1 RPO)
3172012 ugl
372012 ug1
52-162
70 - 140
20
20
624 624
Benzene lt 1 20 (100 R) 20 (100 R) (0 RPO) 3172012 ug1 37 - 151 20 624 1 2-0ichlrroethane lt2 22 (111 R) 22 (110 R) (1 RPO) 372012 ug1 49 - 155 20 624 T richloroethene lt2 21 (105 R) 20 (102 R) (3 RPO) 372012 ug1 71 - 157 20 624 12-0ichloropropane lt2 21 (103 R) 21 (103 R) O RPO) 372012 ug1 0- 210 20 624 Bromodichloromethane lt2 22 (110 R) 22 (110 R) (0 RPO) 372012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 29 (143 R) 29 (144 R) (1 RPO) 372012 ug1 0 - 305 20 624 4-Methyl-2-pentanone(MIBK) lt10 20 (107 R) 20 (105 R) (2 RPO) 3172012 ug1 40-160 20 624 cis-13-Dichloropropene
Toluene
trans-13-0ichloropropene
1 12-Trichloroethane
2-Hexanone
Tetrachloroethene
Dibromochloromethane
Chlorobenzene
Ethylbenzene
mp-Xylene
o-Xylene
Styrene
Bromoform
1 122-Tetrachloroethane
13-0ichlorobenzene
14-0ichlorobenzene
12-Dichlorobenzene
4-Bromofluorobenzene (surr)
lt2 23 (115 R) 23 (115 R) (0 RPO) lt 1 20 (98 R) 20 (98 R) (0 RPO lt2 22 (110 ooR) 22 (108 R) (2 RPO) lt 2 19 (95 R) 19 (94 R) (1 RPO)
lt 10 20 (120 R) 20 (101 ooR) (17 RPO) lt2 20 (102 R) 20 102 R) O RPO) lt2 22 110 R) 22 (109 R) (1 RPO) lt 2 20 (100 R) 20 (99 R) (1 RPO) lt1 20 (102 ooR) 20 (101 R) (1 RPO) lt 1 40 (99 R) 40 (100 R) (1 RPO) lt 1 20 (100 R) 20 (100 R) (0 RPO) lt 1 20 (102 R) 20 (102 R) (0 RPO) lt2 19 (96 R) 19 (95 R) (1 RPO) lt2 19 (94 R) 19 (97 R) (3 RPO) lt 1 20 (102 R 21 (106 R) (4 RPO) lt 1 20 (102 R) 21 (105 R) (3 RPO lt 1 20 (102 R) 21 (105 R)(3 RPO)
93R 98 R 99R
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 Rec
0 - 227
47 - 150
17 -183
52 -150
40-160
64 - 148
53 - 149
37 - 160
37 -162
70 - 130
70 - 130
70 - 130
45- 169
46 - 157
59 - 156
18 - 190
18 - 190
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
eastern analytical wwweailabscom Phone (603) 228-0525 4
inc
IW QC REPORT EAi ID 108078
Client GZA GeoEnvironmentaf Inc NH)
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method
12-Dichlorobenzene--d4 (surr) 99R 105R 103 R 372012 Rec 70-130 624 Toluene-dB (surr) 94R 96R 96R 372012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated-matrix spikes andor laboratory-Control Samples metacceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QNQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units Date of ExtractionPrep
Date of Analysis
Analyst
Method
DIiution Factor
Oil amp Grease (HEM)
Final Effluent 8-3625 B-3727 B-3722
10807802 aqueous
3212 3212
mgL
31212
31212
LAS 1664A
1
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
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FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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Lowell Regional Wastewater Utility File No 04002930700
March 31 2012 Page2
As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed an SOP that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses of FGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPA s draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOPs For further information see
Standard Operating Procedure Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K) httpwaterepagovscitechwastetechguideuploadsteam_draft _soppd EPA May 2011
Considering that specialized analytical techniques are necessary to overcome matrix interference for certain analysis of trace metals in FGD wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater
Should you have any questions concerning this report please do not hesitate to contact me at (603) 232-8744
Very truly yours
GZA GEOENVIRONMENTAL INC
(fdotJti ~ Ronald A Breton PE Michael P North P E Principal ConsultantReviewer
RABMPNtmd
Attachments SMR Summary Sheet Analytical Data Report
SMR SUMMARY SHEET
LOWELL REGIONAL WASTEWATER UTILITY Industrial Sewer User Self-Monitoring Report Summary Sheet
Facilitv Information Company Name Public Service ofNew Hampshire NA(lnterim Discharge
Facility Address 97 River Road Bow New Hampshire Permit No Authorization)
Facility Contact _H_arol_d_~~eyes~-- --------- Telephone (603) 2244081
----UseASeparate Summary Sheet For Each llonitorlng Point--- -shy
Monitoring Report Monitoring Point End ofpretreatment process Submittal Date March 31 2012 Reporting Period (circle applicable) Baseline Annually Semi-Annually Quarterly Re-Sample8
Reporting Period Start Date March 1 2012 Reporting Period End Date ___ = _1--2012M=arch 3 ~
Sample Analvsis Certified Analytical lab Ea== == (=EAi)______________ _= stem An=a41yticalrlnc~
Authorized Rep Lorraine Olashaw 12__ ___Certification No _10 _
Analytical Sub-Contractor Frontier Global Sciences Certification No E87575 ____=__ _
Sample Collection Sampler (labSelfOther) Jim Blackwell Gregg Thompson EAi
Sanie Type(s)(cirde all that apply) Time Composite Flow Composite8 = ===____ _~= =_____ _
pH (Standard Units) __1 __ Instantaneous Flow Rate (GPM) Nl____
Grab Sampling Sample Date 3022012 _ _ Sam~eTime 1100~am
7_ A
Comoosite Sampling Start DateTime _Nc_A_______ Stop DateTime -N---A--------- shy
No Aliquots NIA Aliquot Volume -N=A------- Sample Volume __c_A------- shyN
9174 (Average of FlowData Sampling Interval Volume (Gal) NIA Daily Flow Rate (GPO) =~__d_isch==arg-e-days) _
Stream A 24000 Monitoring Period Industrial Wastewater Flaw (Gal) _ _______~ 2 __ [ [ X ] Estimate_St=re=am B 3104 ] Meter
Monitoring Period Start Date March 1 2012 Monitortng Period End Date March 31 2012
Refer to Sell-Monitoring ReportInstructions for details on completing this SIIR SummarySheet LRWWU Use Only Self-Monitoring Report Summary Sheet Page 1 of2
middot-middot------middot-middotmiddot-middotmiddot------middot-middot----- -middot-middot--middot-middotmiddotmiddot--middotmiddot-middot-middotmiddot-----middot-middot--middot--middot-middot middot-middot-middot-- -middotmiddot- shy
LOWELL REGIONAL WASTEWATER UTILITY Industrial Sewer User Self-Monitoring Report Summary Sheet
An~i=IR-lfflt middot PararnetGt J r bullbull ~Date
Result tnml Parameter AnalYsis obullmiddot I bull1 rResult (maiil middot
BOD Cooner I coo 03052012 170 Cvankle ITotan
OampG 4131IMC Fluoride
TSS lead 03Agt82012 lt 0000800
roemiddot Merourv 03082012 00000172
rro-9241 ~ - 6251am Mtwbdampnum I
Aluminum Nickel
Antimonv Nitro1en OOeldahO
Arsenic 03092012 000812 Phenols (Total)
Barium Selenium
Bervtlium SilYer 03092012 lt0000400
cadmium 0309J2012 lt0000400 Thawn
Chromium (Hexavalentl Zinc
Chromium ITotlllI Other
BOD= Bloclemcal Oxygen Demand COD =ChemicalOxygen Demand OampG=OilampGrease TSS =Total Suspended Saids 1TO Total Toraquoc Otgoocs -roe (Total Organic Cattlon) =Is the amount ofcarbonbound in an Ofg8fllc coovotrd andis often usedas anonspoci6cirdcatorotwaerquality roe measuresbolh tigtamp total carbonpt11sentaswellas the no(garic C8lbon (IC Soo0llc6ng themianlcC8lbon tom the totalC8lbon )Mids TOC HTTOs =Summation of1111quantilable valws greaterthan 001 mgl for toxic orgaic lstedin 40 CFR 41302(i) TTOsinclude PCBs (Poly-Olbrinaled8pherrJs) VOCs (Voatto Organic Cofryen)0Ufl(ls) SVOCs(Seml-Vollllile Organic C-Ompounds) PCBs VOCs and SVOCs shall be anafzed using EPAMethods 608 624and 625 respedively
zero pjscharge LSetfMoQitorillQ (initial Itapplicable)
_ ___ No industrial wastewaterfrom permitted processes has been discharged to sewerduring the monitoring period
____ Nosampling has been conducted on pennitted sewer discharges during the monit~ period
Certification Statement
ceftify under penallf of law that this document and all attachmentswete pnipared under mycfrection or supervision il acoordance with asystem designed to assure that qualified personnel properly gather and evaluate Ile Information submitted Based on my lnqulry ofIle person or persons who manage the system or those persons diredly resp()Ml)le for ~ Ile ilfonnalon tie inbmation Stbmitted Is to Iha best of my knowledge and befief true acctrale and complete Iam awre that llere tre SVificant penalties for ~ false ilfonnation idicfing Ile posslblltyoffine and imprisonmentfor knowing ~alions bull
Harold Keyes Station Manager
I l Date
LRWWU Use Only Self-Monitoring Report Summary Sheet Page 2 of2
i
i I
bull
ANALYTICAL DATAREPORT
_middotmiddot_ ~ _l________f
___e_a_s_t_e_rn_a_n_a_l_y_t1_middotc_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report Eastern Analytical Inc ID 108078
Client Identification Wastewater Analysis
Date Received 322012
Report revisionreissue Revision replaces report dated 32612
Revision lnfonnatlon Per your request Lead as been analyzed on the samples submitted to Frontier Global Sciences
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
r The following standard abbreviations and conventions apply to all EAi reports
Solid samples are reported on a dry weight basis unless otherwise noted lt less thanbull followed by the reporting limit gt greater thanbull followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following Information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
Ifyou have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
of pages (excluding cover letter)
I J bull - bull ~ bull I i middot 1n1wcaibb~cc1m t middot middot middot
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SAMPLE CONDITIONS PAGE EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Temperature upon receipt (degC) 21 Received on ice or cold packs (YesNo) Y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10807801 Effluent_Fiekl Blank B-3621 3212 3212 aqueous Adheres to Sample Acceptance Policy
10807802 Final Effluent B-3625 8middot3727 3212 3212 aqueous Adheres to Sample Acceptance Polley B-3722
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint shylgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
Afl results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
II LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 8-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 32112
Units ug1
Date of Analysis 3l712
Analyst BAM
Method 624 1DIiution Factor
Chloromethane lt5 Vinyl chloride lt2 Bromomethane lt2 Chloroethane lt5 Trichlorofluoromethane lt5 Acrolein lt 50 Acetone lt50 1 1-Dichloroethene lt1 Methylene chloride lt5 Carbon disulfide lt5 Acry1onitrile lt 50 Methy-t-butyl ether(MTBE) lt 10 trans-12-Dichloroethene lt2 Vinyl acetate lt 10 1 1-Dichloroethane lt2 cis-12-Dichloroethene lt2 2-Butanone(MEK) lt 10 Chloroform lt2 1 1 1-Trichloroethane lt2 Carbon tetrachloride lt2 Benzene lt 1 12-0lchloroethane lt2 Trichloroethene lt2 12-Dichloropropane lt2 Bromodichloromethane lt2 2-Chloroethylvinylether lt2 4-Methyl-2-pentanone(MIBK) lt 10 cis-13-Dichloropropene lt2 Toluene lt1 trans-13-Dlchloropropene lt2 112-Trichloroethane lt2 2-Hexanone lt 10 Tetrachloroethene lt2 Dlbromochloromethane lt2 Chlorobenzene lt2 Ethylbenzene lt1 mp-Xylene lt1 o-Xylene lt 1 Styrene lt 1 Bromoform lt2 1122-Tetrachloroethane lt2 13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 4-Bromofluorobenzene (surr) 93degoR 12-Dichlorobenzene-d4 (surr) 99degoR
~
eastern analytical inc wwweaifabscom Phone (603) 228-0525 2
bull
LABORATORY REPORT EAi I 0 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent B-3625 B-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 3212
Units ug1
Date of Analysis 3712
Analyst BAM Method 624
Dllution Factor 1
Toluene-dB (surr) 94R
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
middot
~
--
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Parameter Name
Chloromethane
Blank LCS LCSO Analysis Date Units Limits RPO Method
624 lt5 20 (99 R) 20 (101 R) (2 RPD) 372012 ug1 0-273 20 Vinyl chloride lt2 20 (102 R) 21 (106 R) (4 RPO) 372012 ug1 0- 251 20 624 Bromomethane lt2 19 (93 R) 21 (103 R) (10 RPD) 372012 ug1 0- 242 20 624 Chloroethane lt5 23 (113 R) 22 (110 R) (3 RPO) 3172012 ug1 14 - 230 20 624 Trichlorofluoromethane lt5 22 (108 R) 22 (108 R) (0 RPO) 372012 ug1 17-181 20 624 Acrolein lt 50 bull lt 50 (R bull lt 50 (R NIA) (RPO NIA) 372012 ug1 40-160 20 624 Acetone lt 50 bull lt 50 (188 R) lt 50 (114 R) (49 RPO) 372012 ug1 40 - 160 20 624 1 1-0lchloroethene lt 1 19 (97 R) 19 (95 R) (2 RPO) 372012 ug1 0-234 20 624 Methylene chloride lt5 22 (110 R) 22 (108 R) (2 RPO) 372012 ug1 0 - 221 20 624 Carbon disulfide lt5 17 (85 R) 17 (83 R) (2 RPO) 372012 ug1 70 - 130 20 624 Acrylonitrile lt 50 lt 50 (109 R) lt 50 (104 R) (5 RPO) 372012 ug1 40 - 160 20 624 Methyl-t-butyl ether(MTBE) lt10 20 114 R) 20 (113 R) (1 RPO) 372012 ug1 70 - 130 20 624 trans-12-0ichloroethene lt2 19 (96 R) 19 (96 R) O RPO) 372012 ugJ 54-156 20 624 Vinyl acetate lt 10 30 (137 R) 30 (134 R) (2 RPO) 372012 ug1 40- 160 20 624 1 1-0ichlloroethane lt2 21 (106 R) 21 (104 R) (2 RPO) 372012 ug1 59 - 155 20 624 cis-12-Dichloroethene lt2 20 (101 R) 20 (99 R) (2 RPO) 372012 ug1 70 - 130 20 624 2-Butanone(MEK) lt10 30 (130 R) 20 (100 R) (26 RPO) 372012 ug1 40 - 160 20 624 Chloroform lt2 21 (104 R) 21 (104 R) (0 RPO) 372012 ug1 51 - 138 20 624 1 1 1-Trichloroethane
Carbon t etrachloride
lt2 22 (111 R) 22 (110 R) (1 RPO) lt2 24 (122 R) 24 (121 R) (1 RPO)
3172012 ugl
372012 ug1
52-162
70 - 140
20
20
624 624
Benzene lt 1 20 (100 R) 20 (100 R) (0 RPO) 3172012 ug1 37 - 151 20 624 1 2-0ichlrroethane lt2 22 (111 R) 22 (110 R) (1 RPO) 372012 ug1 49 - 155 20 624 T richloroethene lt2 21 (105 R) 20 (102 R) (3 RPO) 372012 ug1 71 - 157 20 624 12-0ichloropropane lt2 21 (103 R) 21 (103 R) O RPO) 372012 ug1 0- 210 20 624 Bromodichloromethane lt2 22 (110 R) 22 (110 R) (0 RPO) 372012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 29 (143 R) 29 (144 R) (1 RPO) 372012 ug1 0 - 305 20 624 4-Methyl-2-pentanone(MIBK) lt10 20 (107 R) 20 (105 R) (2 RPO) 3172012 ug1 40-160 20 624 cis-13-Dichloropropene
Toluene
trans-13-0ichloropropene
1 12-Trichloroethane
2-Hexanone
Tetrachloroethene
Dibromochloromethane
Chlorobenzene
Ethylbenzene
mp-Xylene
o-Xylene
Styrene
Bromoform
1 122-Tetrachloroethane
13-0ichlorobenzene
14-0ichlorobenzene
12-Dichlorobenzene
4-Bromofluorobenzene (surr)
lt2 23 (115 R) 23 (115 R) (0 RPO) lt 1 20 (98 R) 20 (98 R) (0 RPO lt2 22 (110 ooR) 22 (108 R) (2 RPO) lt 2 19 (95 R) 19 (94 R) (1 RPO)
lt 10 20 (120 R) 20 (101 ooR) (17 RPO) lt2 20 (102 R) 20 102 R) O RPO) lt2 22 110 R) 22 (109 R) (1 RPO) lt 2 20 (100 R) 20 (99 R) (1 RPO) lt1 20 (102 ooR) 20 (101 R) (1 RPO) lt 1 40 (99 R) 40 (100 R) (1 RPO) lt 1 20 (100 R) 20 (100 R) (0 RPO) lt 1 20 (102 R) 20 (102 R) (0 RPO) lt2 19 (96 R) 19 (95 R) (1 RPO) lt2 19 (94 R) 19 (97 R) (3 RPO) lt 1 20 (102 R 21 (106 R) (4 RPO) lt 1 20 (102 R) 21 (105 R) (3 RPO lt 1 20 (102 R) 21 (105 R)(3 RPO)
93R 98 R 99R
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 Rec
0 - 227
47 - 150
17 -183
52 -150
40-160
64 - 148
53 - 149
37 - 160
37 -162
70 - 130
70 - 130
70 - 130
45- 169
46 - 157
59 - 156
18 - 190
18 - 190
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
eastern analytical wwweailabscom Phone (603) 228-0525 4
inc
IW QC REPORT EAi ID 108078
Client GZA GeoEnvironmentaf Inc NH)
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method
12-Dichlorobenzene--d4 (surr) 99R 105R 103 R 372012 Rec 70-130 624 Toluene-dB (surr) 94R 96R 96R 372012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated-matrix spikes andor laboratory-Control Samples metacceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QNQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units Date of ExtractionPrep
Date of Analysis
Analyst
Method
DIiution Factor
Oil amp Grease (HEM)
Final Effluent 8-3625 B-3727 B-3722
10807802 aqueous
3212 3212
mgL
31212
31212
LAS 1664A
1
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
CIOBAL SCICtS uD~05 S Plt1g_e I of I_ bttpwwwFro11tieltGScom
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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Sarn-1bull 10Samnle OeacrftJon Oat bullnd TImo of Samole Co11--1on S a moledl O p-aervetton TVoe
Reauebulltbulld AnaJvbullebullmiddot l
le Cntcmo1 chbullin ofouat- middot --uld X
Sample Condittonnnte---- Yes No Commenl8 Sbullmlbull oontalnera WWbull cetved Intact
S ambullbull to on oontolner metchCOC Correct bullbullmJbull eontalners u sed fol ueatbulld bullnart-bullbull Samnfbullbull recetvampd wllhln hoJdJnn tlmbull Samole volumbull bullufflclbullnt for re~uted anehfaIbull Con-ct o-vbullWbull ubulled ~or ro-uted bullnbull-C$
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lt
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
SMR SUMMARY SHEET
LOWELL REGIONAL WASTEWATER UTILITY Industrial Sewer User Self-Monitoring Report Summary Sheet
Facilitv Information Company Name Public Service ofNew Hampshire NA(lnterim Discharge
Facility Address 97 River Road Bow New Hampshire Permit No Authorization)
Facility Contact _H_arol_d_~~eyes~-- --------- Telephone (603) 2244081
----UseASeparate Summary Sheet For Each llonitorlng Point--- -shy
Monitoring Report Monitoring Point End ofpretreatment process Submittal Date March 31 2012 Reporting Period (circle applicable) Baseline Annually Semi-Annually Quarterly Re-Sample8
Reporting Period Start Date March 1 2012 Reporting Period End Date ___ = _1--2012M=arch 3 ~
Sample Analvsis Certified Analytical lab Ea== == (=EAi)______________ _= stem An=a41yticalrlnc~
Authorized Rep Lorraine Olashaw 12__ ___Certification No _10 _
Analytical Sub-Contractor Frontier Global Sciences Certification No E87575 ____=__ _
Sample Collection Sampler (labSelfOther) Jim Blackwell Gregg Thompson EAi
Sanie Type(s)(cirde all that apply) Time Composite Flow Composite8 = ===____ _~= =_____ _
pH (Standard Units) __1 __ Instantaneous Flow Rate (GPM) Nl____
Grab Sampling Sample Date 3022012 _ _ Sam~eTime 1100~am
7_ A
Comoosite Sampling Start DateTime _Nc_A_______ Stop DateTime -N---A--------- shy
No Aliquots NIA Aliquot Volume -N=A------- Sample Volume __c_A------- shyN
9174 (Average of FlowData Sampling Interval Volume (Gal) NIA Daily Flow Rate (GPO) =~__d_isch==arg-e-days) _
Stream A 24000 Monitoring Period Industrial Wastewater Flaw (Gal) _ _______~ 2 __ [ [ X ] Estimate_St=re=am B 3104 ] Meter
Monitoring Period Start Date March 1 2012 Monitortng Period End Date March 31 2012
Refer to Sell-Monitoring ReportInstructions for details on completing this SIIR SummarySheet LRWWU Use Only Self-Monitoring Report Summary Sheet Page 1 of2
middot-middot------middot-middotmiddot-middotmiddot------middot-middot----- -middot-middot--middot-middotmiddotmiddot--middotmiddot-middot-middotmiddot-----middot-middot--middot--middot-middot middot-middot-middot-- -middotmiddot- shy
LOWELL REGIONAL WASTEWATER UTILITY Industrial Sewer User Self-Monitoring Report Summary Sheet
An~i=IR-lfflt middot PararnetGt J r bullbull ~Date
Result tnml Parameter AnalYsis obullmiddot I bull1 rResult (maiil middot
BOD Cooner I coo 03052012 170 Cvankle ITotan
OampG 4131IMC Fluoride
TSS lead 03Agt82012 lt 0000800
roemiddot Merourv 03082012 00000172
rro-9241 ~ - 6251am Mtwbdampnum I
Aluminum Nickel
Antimonv Nitro1en OOeldahO
Arsenic 03092012 000812 Phenols (Total)
Barium Selenium
Bervtlium SilYer 03092012 lt0000400
cadmium 0309J2012 lt0000400 Thawn
Chromium (Hexavalentl Zinc
Chromium ITotlllI Other
BOD= Bloclemcal Oxygen Demand COD =ChemicalOxygen Demand OampG=OilampGrease TSS =Total Suspended Saids 1TO Total Toraquoc Otgoocs -roe (Total Organic Cattlon) =Is the amount ofcarbonbound in an Ofg8fllc coovotrd andis often usedas anonspoci6cirdcatorotwaerquality roe measuresbolh tigtamp total carbonpt11sentaswellas the no(garic C8lbon (IC Soo0llc6ng themianlcC8lbon tom the totalC8lbon )Mids TOC HTTOs =Summation of1111quantilable valws greaterthan 001 mgl for toxic orgaic lstedin 40 CFR 41302(i) TTOsinclude PCBs (Poly-Olbrinaled8pherrJs) VOCs (Voatto Organic Cofryen)0Ufl(ls) SVOCs(Seml-Vollllile Organic C-Ompounds) PCBs VOCs and SVOCs shall be anafzed using EPAMethods 608 624and 625 respedively
zero pjscharge LSetfMoQitorillQ (initial Itapplicable)
_ ___ No industrial wastewaterfrom permitted processes has been discharged to sewerduring the monitoring period
____ Nosampling has been conducted on pennitted sewer discharges during the monit~ period
Certification Statement
ceftify under penallf of law that this document and all attachmentswete pnipared under mycfrection or supervision il acoordance with asystem designed to assure that qualified personnel properly gather and evaluate Ile Information submitted Based on my lnqulry ofIle person or persons who manage the system or those persons diredly resp()Ml)le for ~ Ile ilfonnalon tie inbmation Stbmitted Is to Iha best of my knowledge and befief true acctrale and complete Iam awre that llere tre SVificant penalties for ~ false ilfonnation idicfing Ile posslblltyoffine and imprisonmentfor knowing ~alions bull
Harold Keyes Station Manager
I l Date
LRWWU Use Only Self-Monitoring Report Summary Sheet Page 2 of2
i
i I
bull
ANALYTICAL DATAREPORT
_middotmiddot_ ~ _l________f
___e_a_s_t_e_rn_a_n_a_l_y_t1_middotc_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report Eastern Analytical Inc ID 108078
Client Identification Wastewater Analysis
Date Received 322012
Report revisionreissue Revision replaces report dated 32612
Revision lnfonnatlon Per your request Lead as been analyzed on the samples submitted to Frontier Global Sciences
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
r The following standard abbreviations and conventions apply to all EAi reports
Solid samples are reported on a dry weight basis unless otherwise noted lt less thanbull followed by the reporting limit gt greater thanbull followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following Information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
Ifyou have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
of pages (excluding cover letter)
I J bull - bull ~ bull I i middot 1n1wcaibb~cc1m t middot middot middot
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SAMPLE CONDITIONS PAGE EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Temperature upon receipt (degC) 21 Received on ice or cold packs (YesNo) Y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10807801 Effluent_Fiekl Blank B-3621 3212 3212 aqueous Adheres to Sample Acceptance Policy
10807802 Final Effluent B-3625 8middot3727 3212 3212 aqueous Adheres to Sample Acceptance Polley B-3722
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint shylgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
Afl results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
II LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 8-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 32112
Units ug1
Date of Analysis 3l712
Analyst BAM
Method 624 1DIiution Factor
Chloromethane lt5 Vinyl chloride lt2 Bromomethane lt2 Chloroethane lt5 Trichlorofluoromethane lt5 Acrolein lt 50 Acetone lt50 1 1-Dichloroethene lt1 Methylene chloride lt5 Carbon disulfide lt5 Acry1onitrile lt 50 Methy-t-butyl ether(MTBE) lt 10 trans-12-Dichloroethene lt2 Vinyl acetate lt 10 1 1-Dichloroethane lt2 cis-12-Dichloroethene lt2 2-Butanone(MEK) lt 10 Chloroform lt2 1 1 1-Trichloroethane lt2 Carbon tetrachloride lt2 Benzene lt 1 12-0lchloroethane lt2 Trichloroethene lt2 12-Dichloropropane lt2 Bromodichloromethane lt2 2-Chloroethylvinylether lt2 4-Methyl-2-pentanone(MIBK) lt 10 cis-13-Dichloropropene lt2 Toluene lt1 trans-13-Dlchloropropene lt2 112-Trichloroethane lt2 2-Hexanone lt 10 Tetrachloroethene lt2 Dlbromochloromethane lt2 Chlorobenzene lt2 Ethylbenzene lt1 mp-Xylene lt1 o-Xylene lt 1 Styrene lt 1 Bromoform lt2 1122-Tetrachloroethane lt2 13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 4-Bromofluorobenzene (surr) 93degoR 12-Dichlorobenzene-d4 (surr) 99degoR
~
eastern analytical inc wwweaifabscom Phone (603) 228-0525 2
bull
LABORATORY REPORT EAi I 0 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent B-3625 B-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 3212
Units ug1
Date of Analysis 3712
Analyst BAM Method 624
Dllution Factor 1
Toluene-dB (surr) 94R
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
middot
~
--
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Parameter Name
Chloromethane
Blank LCS LCSO Analysis Date Units Limits RPO Method
624 lt5 20 (99 R) 20 (101 R) (2 RPD) 372012 ug1 0-273 20 Vinyl chloride lt2 20 (102 R) 21 (106 R) (4 RPO) 372012 ug1 0- 251 20 624 Bromomethane lt2 19 (93 R) 21 (103 R) (10 RPD) 372012 ug1 0- 242 20 624 Chloroethane lt5 23 (113 R) 22 (110 R) (3 RPO) 3172012 ug1 14 - 230 20 624 Trichlorofluoromethane lt5 22 (108 R) 22 (108 R) (0 RPO) 372012 ug1 17-181 20 624 Acrolein lt 50 bull lt 50 (R bull lt 50 (R NIA) (RPO NIA) 372012 ug1 40-160 20 624 Acetone lt 50 bull lt 50 (188 R) lt 50 (114 R) (49 RPO) 372012 ug1 40 - 160 20 624 1 1-0lchloroethene lt 1 19 (97 R) 19 (95 R) (2 RPO) 372012 ug1 0-234 20 624 Methylene chloride lt5 22 (110 R) 22 (108 R) (2 RPO) 372012 ug1 0 - 221 20 624 Carbon disulfide lt5 17 (85 R) 17 (83 R) (2 RPO) 372012 ug1 70 - 130 20 624 Acrylonitrile lt 50 lt 50 (109 R) lt 50 (104 R) (5 RPO) 372012 ug1 40 - 160 20 624 Methyl-t-butyl ether(MTBE) lt10 20 114 R) 20 (113 R) (1 RPO) 372012 ug1 70 - 130 20 624 trans-12-0ichloroethene lt2 19 (96 R) 19 (96 R) O RPO) 372012 ugJ 54-156 20 624 Vinyl acetate lt 10 30 (137 R) 30 (134 R) (2 RPO) 372012 ug1 40- 160 20 624 1 1-0ichlloroethane lt2 21 (106 R) 21 (104 R) (2 RPO) 372012 ug1 59 - 155 20 624 cis-12-Dichloroethene lt2 20 (101 R) 20 (99 R) (2 RPO) 372012 ug1 70 - 130 20 624 2-Butanone(MEK) lt10 30 (130 R) 20 (100 R) (26 RPO) 372012 ug1 40 - 160 20 624 Chloroform lt2 21 (104 R) 21 (104 R) (0 RPO) 372012 ug1 51 - 138 20 624 1 1 1-Trichloroethane
Carbon t etrachloride
lt2 22 (111 R) 22 (110 R) (1 RPO) lt2 24 (122 R) 24 (121 R) (1 RPO)
3172012 ugl
372012 ug1
52-162
70 - 140
20
20
624 624
Benzene lt 1 20 (100 R) 20 (100 R) (0 RPO) 3172012 ug1 37 - 151 20 624 1 2-0ichlrroethane lt2 22 (111 R) 22 (110 R) (1 RPO) 372012 ug1 49 - 155 20 624 T richloroethene lt2 21 (105 R) 20 (102 R) (3 RPO) 372012 ug1 71 - 157 20 624 12-0ichloropropane lt2 21 (103 R) 21 (103 R) O RPO) 372012 ug1 0- 210 20 624 Bromodichloromethane lt2 22 (110 R) 22 (110 R) (0 RPO) 372012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 29 (143 R) 29 (144 R) (1 RPO) 372012 ug1 0 - 305 20 624 4-Methyl-2-pentanone(MIBK) lt10 20 (107 R) 20 (105 R) (2 RPO) 3172012 ug1 40-160 20 624 cis-13-Dichloropropene
Toluene
trans-13-0ichloropropene
1 12-Trichloroethane
2-Hexanone
Tetrachloroethene
Dibromochloromethane
Chlorobenzene
Ethylbenzene
mp-Xylene
o-Xylene
Styrene
Bromoform
1 122-Tetrachloroethane
13-0ichlorobenzene
14-0ichlorobenzene
12-Dichlorobenzene
4-Bromofluorobenzene (surr)
lt2 23 (115 R) 23 (115 R) (0 RPO) lt 1 20 (98 R) 20 (98 R) (0 RPO lt2 22 (110 ooR) 22 (108 R) (2 RPO) lt 2 19 (95 R) 19 (94 R) (1 RPO)
lt 10 20 (120 R) 20 (101 ooR) (17 RPO) lt2 20 (102 R) 20 102 R) O RPO) lt2 22 110 R) 22 (109 R) (1 RPO) lt 2 20 (100 R) 20 (99 R) (1 RPO) lt1 20 (102 ooR) 20 (101 R) (1 RPO) lt 1 40 (99 R) 40 (100 R) (1 RPO) lt 1 20 (100 R) 20 (100 R) (0 RPO) lt 1 20 (102 R) 20 (102 R) (0 RPO) lt2 19 (96 R) 19 (95 R) (1 RPO) lt2 19 (94 R) 19 (97 R) (3 RPO) lt 1 20 (102 R 21 (106 R) (4 RPO) lt 1 20 (102 R) 21 (105 R) (3 RPO lt 1 20 (102 R) 21 (105 R)(3 RPO)
93R 98 R 99R
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 Rec
0 - 227
47 - 150
17 -183
52 -150
40-160
64 - 148
53 - 149
37 - 160
37 -162
70 - 130
70 - 130
70 - 130
45- 169
46 - 157
59 - 156
18 - 190
18 - 190
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
eastern analytical wwweailabscom Phone (603) 228-0525 4
inc
IW QC REPORT EAi ID 108078
Client GZA GeoEnvironmentaf Inc NH)
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method
12-Dichlorobenzene--d4 (surr) 99R 105R 103 R 372012 Rec 70-130 624 Toluene-dB (surr) 94R 96R 96R 372012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated-matrix spikes andor laboratory-Control Samples metacceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QNQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units Date of ExtractionPrep
Date of Analysis
Analyst
Method
DIiution Factor
Oil amp Grease (HEM)
Final Effluent 8-3625 B-3727 B-3722
10807802 aqueous
3212 3212
mgL
31212
31212
LAS 1664A
1
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
CIOBAL SCICtS uD~05 S Plt1g_e I of I_ bttpwwwFro11tieltGScom
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
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LOWELL REGIONAL WASTEWATER UTILITY Industrial Sewer User Self-Monitoring Report Summary Sheet
Facilitv Information Company Name Public Service ofNew Hampshire NA(lnterim Discharge
Facility Address 97 River Road Bow New Hampshire Permit No Authorization)
Facility Contact _H_arol_d_~~eyes~-- --------- Telephone (603) 2244081
----UseASeparate Summary Sheet For Each llonitorlng Point--- -shy
Monitoring Report Monitoring Point End ofpretreatment process Submittal Date March 31 2012 Reporting Period (circle applicable) Baseline Annually Semi-Annually Quarterly Re-Sample8
Reporting Period Start Date March 1 2012 Reporting Period End Date ___ = _1--2012M=arch 3 ~
Sample Analvsis Certified Analytical lab Ea== == (=EAi)______________ _= stem An=a41yticalrlnc~
Authorized Rep Lorraine Olashaw 12__ ___Certification No _10 _
Analytical Sub-Contractor Frontier Global Sciences Certification No E87575 ____=__ _
Sample Collection Sampler (labSelfOther) Jim Blackwell Gregg Thompson EAi
Sanie Type(s)(cirde all that apply) Time Composite Flow Composite8 = ===____ _~= =_____ _
pH (Standard Units) __1 __ Instantaneous Flow Rate (GPM) Nl____
Grab Sampling Sample Date 3022012 _ _ Sam~eTime 1100~am
7_ A
Comoosite Sampling Start DateTime _Nc_A_______ Stop DateTime -N---A--------- shy
No Aliquots NIA Aliquot Volume -N=A------- Sample Volume __c_A------- shyN
9174 (Average of FlowData Sampling Interval Volume (Gal) NIA Daily Flow Rate (GPO) =~__d_isch==arg-e-days) _
Stream A 24000 Monitoring Period Industrial Wastewater Flaw (Gal) _ _______~ 2 __ [ [ X ] Estimate_St=re=am B 3104 ] Meter
Monitoring Period Start Date March 1 2012 Monitortng Period End Date March 31 2012
Refer to Sell-Monitoring ReportInstructions for details on completing this SIIR SummarySheet LRWWU Use Only Self-Monitoring Report Summary Sheet Page 1 of2
middot-middot------middot-middotmiddot-middotmiddot------middot-middot----- -middot-middot--middot-middotmiddotmiddot--middotmiddot-middot-middotmiddot-----middot-middot--middot--middot-middot middot-middot-middot-- -middotmiddot- shy
LOWELL REGIONAL WASTEWATER UTILITY Industrial Sewer User Self-Monitoring Report Summary Sheet
An~i=IR-lfflt middot PararnetGt J r bullbull ~Date
Result tnml Parameter AnalYsis obullmiddot I bull1 rResult (maiil middot
BOD Cooner I coo 03052012 170 Cvankle ITotan
OampG 4131IMC Fluoride
TSS lead 03Agt82012 lt 0000800
roemiddot Merourv 03082012 00000172
rro-9241 ~ - 6251am Mtwbdampnum I
Aluminum Nickel
Antimonv Nitro1en OOeldahO
Arsenic 03092012 000812 Phenols (Total)
Barium Selenium
Bervtlium SilYer 03092012 lt0000400
cadmium 0309J2012 lt0000400 Thawn
Chromium (Hexavalentl Zinc
Chromium ITotlllI Other
BOD= Bloclemcal Oxygen Demand COD =ChemicalOxygen Demand OampG=OilampGrease TSS =Total Suspended Saids 1TO Total Toraquoc Otgoocs -roe (Total Organic Cattlon) =Is the amount ofcarbonbound in an Ofg8fllc coovotrd andis often usedas anonspoci6cirdcatorotwaerquality roe measuresbolh tigtamp total carbonpt11sentaswellas the no(garic C8lbon (IC Soo0llc6ng themianlcC8lbon tom the totalC8lbon )Mids TOC HTTOs =Summation of1111quantilable valws greaterthan 001 mgl for toxic orgaic lstedin 40 CFR 41302(i) TTOsinclude PCBs (Poly-Olbrinaled8pherrJs) VOCs (Voatto Organic Cofryen)0Ufl(ls) SVOCs(Seml-Vollllile Organic C-Ompounds) PCBs VOCs and SVOCs shall be anafzed using EPAMethods 608 624and 625 respedively
zero pjscharge LSetfMoQitorillQ (initial Itapplicable)
_ ___ No industrial wastewaterfrom permitted processes has been discharged to sewerduring the monitoring period
____ Nosampling has been conducted on pennitted sewer discharges during the monit~ period
Certification Statement
ceftify under penallf of law that this document and all attachmentswete pnipared under mycfrection or supervision il acoordance with asystem designed to assure that qualified personnel properly gather and evaluate Ile Information submitted Based on my lnqulry ofIle person or persons who manage the system or those persons diredly resp()Ml)le for ~ Ile ilfonnalon tie inbmation Stbmitted Is to Iha best of my knowledge and befief true acctrale and complete Iam awre that llere tre SVificant penalties for ~ false ilfonnation idicfing Ile posslblltyoffine and imprisonmentfor knowing ~alions bull
Harold Keyes Station Manager
I l Date
LRWWU Use Only Self-Monitoring Report Summary Sheet Page 2 of2
i
i I
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ANALYTICAL DATAREPORT
_middotmiddot_ ~ _l________f
___e_a_s_t_e_rn_a_n_a_l_y_t1_middotc_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report Eastern Analytical Inc ID 108078
Client Identification Wastewater Analysis
Date Received 322012
Report revisionreissue Revision replaces report dated 32612
Revision lnfonnatlon Per your request Lead as been analyzed on the samples submitted to Frontier Global Sciences
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
r The following standard abbreviations and conventions apply to all EAi reports
Solid samples are reported on a dry weight basis unless otherwise noted lt less thanbull followed by the reporting limit gt greater thanbull followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following Information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
Ifyou have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
of pages (excluding cover letter)
I J bull - bull ~ bull I i middot 1n1wcaibb~cc1m t middot middot middot
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SAMPLE CONDITIONS PAGE EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Temperature upon receipt (degC) 21 Received on ice or cold packs (YesNo) Y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10807801 Effluent_Fiekl Blank B-3621 3212 3212 aqueous Adheres to Sample Acceptance Policy
10807802 Final Effluent B-3625 8middot3727 3212 3212 aqueous Adheres to Sample Acceptance Polley B-3722
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint shylgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
Afl results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
II LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 8-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 32112
Units ug1
Date of Analysis 3l712
Analyst BAM
Method 624 1DIiution Factor
Chloromethane lt5 Vinyl chloride lt2 Bromomethane lt2 Chloroethane lt5 Trichlorofluoromethane lt5 Acrolein lt 50 Acetone lt50 1 1-Dichloroethene lt1 Methylene chloride lt5 Carbon disulfide lt5 Acry1onitrile lt 50 Methy-t-butyl ether(MTBE) lt 10 trans-12-Dichloroethene lt2 Vinyl acetate lt 10 1 1-Dichloroethane lt2 cis-12-Dichloroethene lt2 2-Butanone(MEK) lt 10 Chloroform lt2 1 1 1-Trichloroethane lt2 Carbon tetrachloride lt2 Benzene lt 1 12-0lchloroethane lt2 Trichloroethene lt2 12-Dichloropropane lt2 Bromodichloromethane lt2 2-Chloroethylvinylether lt2 4-Methyl-2-pentanone(MIBK) lt 10 cis-13-Dichloropropene lt2 Toluene lt1 trans-13-Dlchloropropene lt2 112-Trichloroethane lt2 2-Hexanone lt 10 Tetrachloroethene lt2 Dlbromochloromethane lt2 Chlorobenzene lt2 Ethylbenzene lt1 mp-Xylene lt1 o-Xylene lt 1 Styrene lt 1 Bromoform lt2 1122-Tetrachloroethane lt2 13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 4-Bromofluorobenzene (surr) 93degoR 12-Dichlorobenzene-d4 (surr) 99degoR
~
eastern analytical inc wwweaifabscom Phone (603) 228-0525 2
bull
LABORATORY REPORT EAi I 0 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent B-3625 B-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 3212
Units ug1
Date of Analysis 3712
Analyst BAM Method 624
Dllution Factor 1
Toluene-dB (surr) 94R
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
middot
~
--
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Parameter Name
Chloromethane
Blank LCS LCSO Analysis Date Units Limits RPO Method
624 lt5 20 (99 R) 20 (101 R) (2 RPD) 372012 ug1 0-273 20 Vinyl chloride lt2 20 (102 R) 21 (106 R) (4 RPO) 372012 ug1 0- 251 20 624 Bromomethane lt2 19 (93 R) 21 (103 R) (10 RPD) 372012 ug1 0- 242 20 624 Chloroethane lt5 23 (113 R) 22 (110 R) (3 RPO) 3172012 ug1 14 - 230 20 624 Trichlorofluoromethane lt5 22 (108 R) 22 (108 R) (0 RPO) 372012 ug1 17-181 20 624 Acrolein lt 50 bull lt 50 (R bull lt 50 (R NIA) (RPO NIA) 372012 ug1 40-160 20 624 Acetone lt 50 bull lt 50 (188 R) lt 50 (114 R) (49 RPO) 372012 ug1 40 - 160 20 624 1 1-0lchloroethene lt 1 19 (97 R) 19 (95 R) (2 RPO) 372012 ug1 0-234 20 624 Methylene chloride lt5 22 (110 R) 22 (108 R) (2 RPO) 372012 ug1 0 - 221 20 624 Carbon disulfide lt5 17 (85 R) 17 (83 R) (2 RPO) 372012 ug1 70 - 130 20 624 Acrylonitrile lt 50 lt 50 (109 R) lt 50 (104 R) (5 RPO) 372012 ug1 40 - 160 20 624 Methyl-t-butyl ether(MTBE) lt10 20 114 R) 20 (113 R) (1 RPO) 372012 ug1 70 - 130 20 624 trans-12-0ichloroethene lt2 19 (96 R) 19 (96 R) O RPO) 372012 ugJ 54-156 20 624 Vinyl acetate lt 10 30 (137 R) 30 (134 R) (2 RPO) 372012 ug1 40- 160 20 624 1 1-0ichlloroethane lt2 21 (106 R) 21 (104 R) (2 RPO) 372012 ug1 59 - 155 20 624 cis-12-Dichloroethene lt2 20 (101 R) 20 (99 R) (2 RPO) 372012 ug1 70 - 130 20 624 2-Butanone(MEK) lt10 30 (130 R) 20 (100 R) (26 RPO) 372012 ug1 40 - 160 20 624 Chloroform lt2 21 (104 R) 21 (104 R) (0 RPO) 372012 ug1 51 - 138 20 624 1 1 1-Trichloroethane
Carbon t etrachloride
lt2 22 (111 R) 22 (110 R) (1 RPO) lt2 24 (122 R) 24 (121 R) (1 RPO)
3172012 ugl
372012 ug1
52-162
70 - 140
20
20
624 624
Benzene lt 1 20 (100 R) 20 (100 R) (0 RPO) 3172012 ug1 37 - 151 20 624 1 2-0ichlrroethane lt2 22 (111 R) 22 (110 R) (1 RPO) 372012 ug1 49 - 155 20 624 T richloroethene lt2 21 (105 R) 20 (102 R) (3 RPO) 372012 ug1 71 - 157 20 624 12-0ichloropropane lt2 21 (103 R) 21 (103 R) O RPO) 372012 ug1 0- 210 20 624 Bromodichloromethane lt2 22 (110 R) 22 (110 R) (0 RPO) 372012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 29 (143 R) 29 (144 R) (1 RPO) 372012 ug1 0 - 305 20 624 4-Methyl-2-pentanone(MIBK) lt10 20 (107 R) 20 (105 R) (2 RPO) 3172012 ug1 40-160 20 624 cis-13-Dichloropropene
Toluene
trans-13-0ichloropropene
1 12-Trichloroethane
2-Hexanone
Tetrachloroethene
Dibromochloromethane
Chlorobenzene
Ethylbenzene
mp-Xylene
o-Xylene
Styrene
Bromoform
1 122-Tetrachloroethane
13-0ichlorobenzene
14-0ichlorobenzene
12-Dichlorobenzene
4-Bromofluorobenzene (surr)
lt2 23 (115 R) 23 (115 R) (0 RPO) lt 1 20 (98 R) 20 (98 R) (0 RPO lt2 22 (110 ooR) 22 (108 R) (2 RPO) lt 2 19 (95 R) 19 (94 R) (1 RPO)
lt 10 20 (120 R) 20 (101 ooR) (17 RPO) lt2 20 (102 R) 20 102 R) O RPO) lt2 22 110 R) 22 (109 R) (1 RPO) lt 2 20 (100 R) 20 (99 R) (1 RPO) lt1 20 (102 ooR) 20 (101 R) (1 RPO) lt 1 40 (99 R) 40 (100 R) (1 RPO) lt 1 20 (100 R) 20 (100 R) (0 RPO) lt 1 20 (102 R) 20 (102 R) (0 RPO) lt2 19 (96 R) 19 (95 R) (1 RPO) lt2 19 (94 R) 19 (97 R) (3 RPO) lt 1 20 (102 R 21 (106 R) (4 RPO) lt 1 20 (102 R) 21 (105 R) (3 RPO lt 1 20 (102 R) 21 (105 R)(3 RPO)
93R 98 R 99R
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 Rec
0 - 227
47 - 150
17 -183
52 -150
40-160
64 - 148
53 - 149
37 - 160
37 -162
70 - 130
70 - 130
70 - 130
45- 169
46 - 157
59 - 156
18 - 190
18 - 190
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
eastern analytical wwweailabscom Phone (603) 228-0525 4
inc
IW QC REPORT EAi ID 108078
Client GZA GeoEnvironmentaf Inc NH)
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method
12-Dichlorobenzene--d4 (surr) 99R 105R 103 R 372012 Rec 70-130 624 Toluene-dB (surr) 94R 96R 96R 372012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated-matrix spikes andor laboratory-Control Samples metacceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QNQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units Date of ExtractionPrep
Date of Analysis
Analyst
Method
DIiution Factor
Oil amp Grease (HEM)
Final Effluent 8-3625 B-3727 B-3722
10807802 aqueous
3212 3212
mgL
31212
31212
LAS 1664A
1
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
CIOBAL SCICtS uD~05 S Plt1g_e I of I_ bttpwwwFro11tieltGScom
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
FGS VoMc Order middot~ )391t1poundpound sampre Recerp1 clgteclltlltt
C lrent
Projoot
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SOG of Cootors R~ved FG9PM
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0-J~ Ve _ -Cshy
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Thormer PrbullaorvaUon __Joo-o fee __x__GeVSlve loo ___rJono (Amb1C9-nO ___Oth04 (bullpocdy)
Thermomoter JO $ lScgt
Cooler Jbull middotc Cooler2 middotc Cooter 3 bullc Coo ter 4 middotc Coo1-ebull bullc---
CorrecUon Factor (Ctr) plusmn amp2gtgt d9C10S C
C oolbullrOmiddot middotc Cooler 7 middotc -CooJera -Coor a -Cootbullrr 10 middot c
Cooler 1 1 _ middot c Cooler 1t - middotc
-c- shy
C hein orCubulltody CCC Ja pre$ent and rncfudes tho 1ollowing information for o-ech samplbullt No NA Cornmbullnta
Sarn-1bull 10Samnle OeacrftJon Oat bullnd TImo of Samole Co11--1on S a moledl O p-aervetton TVoe
Reauebulltbulld AnaJvbullebullmiddot l
le Cntcmo1 chbullin ofouat- middot --uld X
Sample Condittonnnte---- Yes No Commenl8 Sbullmlbull oontalnera WWbull cetved Intact
S ambullbull to on oontolner metchCOC Correct bullbullmJbull eontalners u sed fol ueatbulld bullnart-bullbull Samnfbullbull recetvampd wllhln hoJdJnn tlmbull Samole volumbull bullufflclbullnt for re~uted anehfaIbull Con-ct o-vbullWbull ubulled ~or ro-uted bullnbull-C$
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lt
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
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LOWELL REGIONAL WASTEWATER UTILITY Industrial Sewer User Self-Monitoring Report Summary Sheet
An~i=IR-lfflt middot PararnetGt J r bullbull ~Date
Result tnml Parameter AnalYsis obullmiddot I bull1 rResult (maiil middot
BOD Cooner I coo 03052012 170 Cvankle ITotan
OampG 4131IMC Fluoride
TSS lead 03Agt82012 lt 0000800
roemiddot Merourv 03082012 00000172
rro-9241 ~ - 6251am Mtwbdampnum I
Aluminum Nickel
Antimonv Nitro1en OOeldahO
Arsenic 03092012 000812 Phenols (Total)
Barium Selenium
Bervtlium SilYer 03092012 lt0000400
cadmium 0309J2012 lt0000400 Thawn
Chromium (Hexavalentl Zinc
Chromium ITotlllI Other
BOD= Bloclemcal Oxygen Demand COD =ChemicalOxygen Demand OampG=OilampGrease TSS =Total Suspended Saids 1TO Total Toraquoc Otgoocs -roe (Total Organic Cattlon) =Is the amount ofcarbonbound in an Ofg8fllc coovotrd andis often usedas anonspoci6cirdcatorotwaerquality roe measuresbolh tigtamp total carbonpt11sentaswellas the no(garic C8lbon (IC Soo0llc6ng themianlcC8lbon tom the totalC8lbon )Mids TOC HTTOs =Summation of1111quantilable valws greaterthan 001 mgl for toxic orgaic lstedin 40 CFR 41302(i) TTOsinclude PCBs (Poly-Olbrinaled8pherrJs) VOCs (Voatto Organic Cofryen)0Ufl(ls) SVOCs(Seml-Vollllile Organic C-Ompounds) PCBs VOCs and SVOCs shall be anafzed using EPAMethods 608 624and 625 respedively
zero pjscharge LSetfMoQitorillQ (initial Itapplicable)
_ ___ No industrial wastewaterfrom permitted processes has been discharged to sewerduring the monitoring period
____ Nosampling has been conducted on pennitted sewer discharges during the monit~ period
Certification Statement
ceftify under penallf of law that this document and all attachmentswete pnipared under mycfrection or supervision il acoordance with asystem designed to assure that qualified personnel properly gather and evaluate Ile Information submitted Based on my lnqulry ofIle person or persons who manage the system or those persons diredly resp()Ml)le for ~ Ile ilfonnalon tie inbmation Stbmitted Is to Iha best of my knowledge and befief true acctrale and complete Iam awre that llere tre SVificant penalties for ~ false ilfonnation idicfing Ile posslblltyoffine and imprisonmentfor knowing ~alions bull
Harold Keyes Station Manager
I l Date
LRWWU Use Only Self-Monitoring Report Summary Sheet Page 2 of2
i
i I
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ANALYTICAL DATAREPORT
_middotmiddot_ ~ _l________f
___e_a_s_t_e_rn_a_n_a_l_y_t1_middotc_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report Eastern Analytical Inc ID 108078
Client Identification Wastewater Analysis
Date Received 322012
Report revisionreissue Revision replaces report dated 32612
Revision lnfonnatlon Per your request Lead as been analyzed on the samples submitted to Frontier Global Sciences
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
r The following standard abbreviations and conventions apply to all EAi reports
Solid samples are reported on a dry weight basis unless otherwise noted lt less thanbull followed by the reporting limit gt greater thanbull followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following Information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
Ifyou have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
of pages (excluding cover letter)
I J bull - bull ~ bull I i middot 1n1wcaibb~cc1m t middot middot middot
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SAMPLE CONDITIONS PAGE EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Temperature upon receipt (degC) 21 Received on ice or cold packs (YesNo) Y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10807801 Effluent_Fiekl Blank B-3621 3212 3212 aqueous Adheres to Sample Acceptance Policy
10807802 Final Effluent B-3625 8middot3727 3212 3212 aqueous Adheres to Sample Acceptance Polley B-3722
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint shylgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
Afl results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
II LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 8-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 32112
Units ug1
Date of Analysis 3l712
Analyst BAM
Method 624 1DIiution Factor
Chloromethane lt5 Vinyl chloride lt2 Bromomethane lt2 Chloroethane lt5 Trichlorofluoromethane lt5 Acrolein lt 50 Acetone lt50 1 1-Dichloroethene lt1 Methylene chloride lt5 Carbon disulfide lt5 Acry1onitrile lt 50 Methy-t-butyl ether(MTBE) lt 10 trans-12-Dichloroethene lt2 Vinyl acetate lt 10 1 1-Dichloroethane lt2 cis-12-Dichloroethene lt2 2-Butanone(MEK) lt 10 Chloroform lt2 1 1 1-Trichloroethane lt2 Carbon tetrachloride lt2 Benzene lt 1 12-0lchloroethane lt2 Trichloroethene lt2 12-Dichloropropane lt2 Bromodichloromethane lt2 2-Chloroethylvinylether lt2 4-Methyl-2-pentanone(MIBK) lt 10 cis-13-Dichloropropene lt2 Toluene lt1 trans-13-Dlchloropropene lt2 112-Trichloroethane lt2 2-Hexanone lt 10 Tetrachloroethene lt2 Dlbromochloromethane lt2 Chlorobenzene lt2 Ethylbenzene lt1 mp-Xylene lt1 o-Xylene lt 1 Styrene lt 1 Bromoform lt2 1122-Tetrachloroethane lt2 13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 4-Bromofluorobenzene (surr) 93degoR 12-Dichlorobenzene-d4 (surr) 99degoR
~
eastern analytical inc wwweaifabscom Phone (603) 228-0525 2
bull
LABORATORY REPORT EAi I 0 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent B-3625 B-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 3212
Units ug1
Date of Analysis 3712
Analyst BAM Method 624
Dllution Factor 1
Toluene-dB (surr) 94R
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
middot
~
--
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Parameter Name
Chloromethane
Blank LCS LCSO Analysis Date Units Limits RPO Method
624 lt5 20 (99 R) 20 (101 R) (2 RPD) 372012 ug1 0-273 20 Vinyl chloride lt2 20 (102 R) 21 (106 R) (4 RPO) 372012 ug1 0- 251 20 624 Bromomethane lt2 19 (93 R) 21 (103 R) (10 RPD) 372012 ug1 0- 242 20 624 Chloroethane lt5 23 (113 R) 22 (110 R) (3 RPO) 3172012 ug1 14 - 230 20 624 Trichlorofluoromethane lt5 22 (108 R) 22 (108 R) (0 RPO) 372012 ug1 17-181 20 624 Acrolein lt 50 bull lt 50 (R bull lt 50 (R NIA) (RPO NIA) 372012 ug1 40-160 20 624 Acetone lt 50 bull lt 50 (188 R) lt 50 (114 R) (49 RPO) 372012 ug1 40 - 160 20 624 1 1-0lchloroethene lt 1 19 (97 R) 19 (95 R) (2 RPO) 372012 ug1 0-234 20 624 Methylene chloride lt5 22 (110 R) 22 (108 R) (2 RPO) 372012 ug1 0 - 221 20 624 Carbon disulfide lt5 17 (85 R) 17 (83 R) (2 RPO) 372012 ug1 70 - 130 20 624 Acrylonitrile lt 50 lt 50 (109 R) lt 50 (104 R) (5 RPO) 372012 ug1 40 - 160 20 624 Methyl-t-butyl ether(MTBE) lt10 20 114 R) 20 (113 R) (1 RPO) 372012 ug1 70 - 130 20 624 trans-12-0ichloroethene lt2 19 (96 R) 19 (96 R) O RPO) 372012 ugJ 54-156 20 624 Vinyl acetate lt 10 30 (137 R) 30 (134 R) (2 RPO) 372012 ug1 40- 160 20 624 1 1-0ichlloroethane lt2 21 (106 R) 21 (104 R) (2 RPO) 372012 ug1 59 - 155 20 624 cis-12-Dichloroethene lt2 20 (101 R) 20 (99 R) (2 RPO) 372012 ug1 70 - 130 20 624 2-Butanone(MEK) lt10 30 (130 R) 20 (100 R) (26 RPO) 372012 ug1 40 - 160 20 624 Chloroform lt2 21 (104 R) 21 (104 R) (0 RPO) 372012 ug1 51 - 138 20 624 1 1 1-Trichloroethane
Carbon t etrachloride
lt2 22 (111 R) 22 (110 R) (1 RPO) lt2 24 (122 R) 24 (121 R) (1 RPO)
3172012 ugl
372012 ug1
52-162
70 - 140
20
20
624 624
Benzene lt 1 20 (100 R) 20 (100 R) (0 RPO) 3172012 ug1 37 - 151 20 624 1 2-0ichlrroethane lt2 22 (111 R) 22 (110 R) (1 RPO) 372012 ug1 49 - 155 20 624 T richloroethene lt2 21 (105 R) 20 (102 R) (3 RPO) 372012 ug1 71 - 157 20 624 12-0ichloropropane lt2 21 (103 R) 21 (103 R) O RPO) 372012 ug1 0- 210 20 624 Bromodichloromethane lt2 22 (110 R) 22 (110 R) (0 RPO) 372012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 29 (143 R) 29 (144 R) (1 RPO) 372012 ug1 0 - 305 20 624 4-Methyl-2-pentanone(MIBK) lt10 20 (107 R) 20 (105 R) (2 RPO) 3172012 ug1 40-160 20 624 cis-13-Dichloropropene
Toluene
trans-13-0ichloropropene
1 12-Trichloroethane
2-Hexanone
Tetrachloroethene
Dibromochloromethane
Chlorobenzene
Ethylbenzene
mp-Xylene
o-Xylene
Styrene
Bromoform
1 122-Tetrachloroethane
13-0ichlorobenzene
14-0ichlorobenzene
12-Dichlorobenzene
4-Bromofluorobenzene (surr)
lt2 23 (115 R) 23 (115 R) (0 RPO) lt 1 20 (98 R) 20 (98 R) (0 RPO lt2 22 (110 ooR) 22 (108 R) (2 RPO) lt 2 19 (95 R) 19 (94 R) (1 RPO)
lt 10 20 (120 R) 20 (101 ooR) (17 RPO) lt2 20 (102 R) 20 102 R) O RPO) lt2 22 110 R) 22 (109 R) (1 RPO) lt 2 20 (100 R) 20 (99 R) (1 RPO) lt1 20 (102 ooR) 20 (101 R) (1 RPO) lt 1 40 (99 R) 40 (100 R) (1 RPO) lt 1 20 (100 R) 20 (100 R) (0 RPO) lt 1 20 (102 R) 20 (102 R) (0 RPO) lt2 19 (96 R) 19 (95 R) (1 RPO) lt2 19 (94 R) 19 (97 R) (3 RPO) lt 1 20 (102 R 21 (106 R) (4 RPO) lt 1 20 (102 R) 21 (105 R) (3 RPO lt 1 20 (102 R) 21 (105 R)(3 RPO)
93R 98 R 99R
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 Rec
0 - 227
47 - 150
17 -183
52 -150
40-160
64 - 148
53 - 149
37 - 160
37 -162
70 - 130
70 - 130
70 - 130
45- 169
46 - 157
59 - 156
18 - 190
18 - 190
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
eastern analytical wwweailabscom Phone (603) 228-0525 4
inc
IW QC REPORT EAi ID 108078
Client GZA GeoEnvironmentaf Inc NH)
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method
12-Dichlorobenzene--d4 (surr) 99R 105R 103 R 372012 Rec 70-130 624 Toluene-dB (surr) 94R 96R 96R 372012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated-matrix spikes andor laboratory-Control Samples metacceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QNQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units Date of ExtractionPrep
Date of Analysis
Analyst
Method
DIiution Factor
Oil amp Grease (HEM)
Final Effluent 8-3625 B-3727 B-3722
10807802 aqueous
3212 3212
mgL
31212
31212
LAS 1664A
1
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
CIOBAL SCICtS uD~05 S Plt1g_e I of I_ bttpwwwFro11tieltGScom
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
FGS VoMc Order middot~ )391t1poundpound sampre Recerp1 clgteclltlltt
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Thermomoter JO $ lScgt
Cooler Jbull middotc Cooler2 middotc Cooter 3 bullc Coo ter 4 middotc Coo1-ebull bullc---
CorrecUon Factor (Ctr) plusmn amp2gtgt d9C10S C
C oolbullrOmiddot middotc Cooler 7 middotc -CooJera -Coor a -Cootbullrr 10 middot c
Cooler 1 1 _ middot c Cooler 1t - middotc
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C hein orCubulltody CCC Ja pre$ent and rncfudes tho 1ollowing information for o-ech samplbullt No NA Cornmbullnta
Sarn-1bull 10Samnle OeacrftJon Oat bullnd TImo of Samole Co11--1on S a moledl O p-aervetton TVoe
Reauebulltbulld AnaJvbullebullmiddot l
le Cntcmo1 chbullin ofouat- middot --uld X
Sample Condittonnnte---- Yes No Commenl8 Sbullmlbull oontalnera WWbull cetved Intact
S ambullbull to on oontolner metchCOC Correct bullbullmJbull eontalners u sed fol ueatbulld bullnart-bullbull Samnfbullbull recetvampd wllhln hoJdJnn tlmbull Samole volumbull bullufflclbullnt for re~uted anehfaIbull Con-ct o-vbullWbull ubulled ~or ro-uted bullnbull-C$
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lt
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
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GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
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ANALYTICAL DATAREPORT
_middotmiddot_ ~ _l________f
___e_a_s_t_e_rn_a_n_a_l_y_t1_middotc_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report Eastern Analytical Inc ID 108078
Client Identification Wastewater Analysis
Date Received 322012
Report revisionreissue Revision replaces report dated 32612
Revision lnfonnatlon Per your request Lead as been analyzed on the samples submitted to Frontier Global Sciences
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
r The following standard abbreviations and conventions apply to all EAi reports
Solid samples are reported on a dry weight basis unless otherwise noted lt less thanbull followed by the reporting limit gt greater thanbull followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following Information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
Ifyou have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
of pages (excluding cover letter)
I J bull - bull ~ bull I i middot 1n1wcaibb~cc1m t middot middot middot
bull
SAMPLE CONDITIONS PAGE EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Temperature upon receipt (degC) 21 Received on ice or cold packs (YesNo) Y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10807801 Effluent_Fiekl Blank B-3621 3212 3212 aqueous Adheres to Sample Acceptance Policy
10807802 Final Effluent B-3625 8middot3727 3212 3212 aqueous Adheres to Sample Acceptance Polley B-3722
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint shylgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
Afl results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
II LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 8-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 32112
Units ug1
Date of Analysis 3l712
Analyst BAM
Method 624 1DIiution Factor
Chloromethane lt5 Vinyl chloride lt2 Bromomethane lt2 Chloroethane lt5 Trichlorofluoromethane lt5 Acrolein lt 50 Acetone lt50 1 1-Dichloroethene lt1 Methylene chloride lt5 Carbon disulfide lt5 Acry1onitrile lt 50 Methy-t-butyl ether(MTBE) lt 10 trans-12-Dichloroethene lt2 Vinyl acetate lt 10 1 1-Dichloroethane lt2 cis-12-Dichloroethene lt2 2-Butanone(MEK) lt 10 Chloroform lt2 1 1 1-Trichloroethane lt2 Carbon tetrachloride lt2 Benzene lt 1 12-0lchloroethane lt2 Trichloroethene lt2 12-Dichloropropane lt2 Bromodichloromethane lt2 2-Chloroethylvinylether lt2 4-Methyl-2-pentanone(MIBK) lt 10 cis-13-Dichloropropene lt2 Toluene lt1 trans-13-Dlchloropropene lt2 112-Trichloroethane lt2 2-Hexanone lt 10 Tetrachloroethene lt2 Dlbromochloromethane lt2 Chlorobenzene lt2 Ethylbenzene lt1 mp-Xylene lt1 o-Xylene lt 1 Styrene lt 1 Bromoform lt2 1122-Tetrachloroethane lt2 13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 4-Bromofluorobenzene (surr) 93degoR 12-Dichlorobenzene-d4 (surr) 99degoR
~
eastern analytical inc wwweaifabscom Phone (603) 228-0525 2
bull
LABORATORY REPORT EAi I 0 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent B-3625 B-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 3212
Units ug1
Date of Analysis 3712
Analyst BAM Method 624
Dllution Factor 1
Toluene-dB (surr) 94R
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
middot
~
--
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Parameter Name
Chloromethane
Blank LCS LCSO Analysis Date Units Limits RPO Method
624 lt5 20 (99 R) 20 (101 R) (2 RPD) 372012 ug1 0-273 20 Vinyl chloride lt2 20 (102 R) 21 (106 R) (4 RPO) 372012 ug1 0- 251 20 624 Bromomethane lt2 19 (93 R) 21 (103 R) (10 RPD) 372012 ug1 0- 242 20 624 Chloroethane lt5 23 (113 R) 22 (110 R) (3 RPO) 3172012 ug1 14 - 230 20 624 Trichlorofluoromethane lt5 22 (108 R) 22 (108 R) (0 RPO) 372012 ug1 17-181 20 624 Acrolein lt 50 bull lt 50 (R bull lt 50 (R NIA) (RPO NIA) 372012 ug1 40-160 20 624 Acetone lt 50 bull lt 50 (188 R) lt 50 (114 R) (49 RPO) 372012 ug1 40 - 160 20 624 1 1-0lchloroethene lt 1 19 (97 R) 19 (95 R) (2 RPO) 372012 ug1 0-234 20 624 Methylene chloride lt5 22 (110 R) 22 (108 R) (2 RPO) 372012 ug1 0 - 221 20 624 Carbon disulfide lt5 17 (85 R) 17 (83 R) (2 RPO) 372012 ug1 70 - 130 20 624 Acrylonitrile lt 50 lt 50 (109 R) lt 50 (104 R) (5 RPO) 372012 ug1 40 - 160 20 624 Methyl-t-butyl ether(MTBE) lt10 20 114 R) 20 (113 R) (1 RPO) 372012 ug1 70 - 130 20 624 trans-12-0ichloroethene lt2 19 (96 R) 19 (96 R) O RPO) 372012 ugJ 54-156 20 624 Vinyl acetate lt 10 30 (137 R) 30 (134 R) (2 RPO) 372012 ug1 40- 160 20 624 1 1-0ichlloroethane lt2 21 (106 R) 21 (104 R) (2 RPO) 372012 ug1 59 - 155 20 624 cis-12-Dichloroethene lt2 20 (101 R) 20 (99 R) (2 RPO) 372012 ug1 70 - 130 20 624 2-Butanone(MEK) lt10 30 (130 R) 20 (100 R) (26 RPO) 372012 ug1 40 - 160 20 624 Chloroform lt2 21 (104 R) 21 (104 R) (0 RPO) 372012 ug1 51 - 138 20 624 1 1 1-Trichloroethane
Carbon t etrachloride
lt2 22 (111 R) 22 (110 R) (1 RPO) lt2 24 (122 R) 24 (121 R) (1 RPO)
3172012 ugl
372012 ug1
52-162
70 - 140
20
20
624 624
Benzene lt 1 20 (100 R) 20 (100 R) (0 RPO) 3172012 ug1 37 - 151 20 624 1 2-0ichlrroethane lt2 22 (111 R) 22 (110 R) (1 RPO) 372012 ug1 49 - 155 20 624 T richloroethene lt2 21 (105 R) 20 (102 R) (3 RPO) 372012 ug1 71 - 157 20 624 12-0ichloropropane lt2 21 (103 R) 21 (103 R) O RPO) 372012 ug1 0- 210 20 624 Bromodichloromethane lt2 22 (110 R) 22 (110 R) (0 RPO) 372012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 29 (143 R) 29 (144 R) (1 RPO) 372012 ug1 0 - 305 20 624 4-Methyl-2-pentanone(MIBK) lt10 20 (107 R) 20 (105 R) (2 RPO) 3172012 ug1 40-160 20 624 cis-13-Dichloropropene
Toluene
trans-13-0ichloropropene
1 12-Trichloroethane
2-Hexanone
Tetrachloroethene
Dibromochloromethane
Chlorobenzene
Ethylbenzene
mp-Xylene
o-Xylene
Styrene
Bromoform
1 122-Tetrachloroethane
13-0ichlorobenzene
14-0ichlorobenzene
12-Dichlorobenzene
4-Bromofluorobenzene (surr)
lt2 23 (115 R) 23 (115 R) (0 RPO) lt 1 20 (98 R) 20 (98 R) (0 RPO lt2 22 (110 ooR) 22 (108 R) (2 RPO) lt 2 19 (95 R) 19 (94 R) (1 RPO)
lt 10 20 (120 R) 20 (101 ooR) (17 RPO) lt2 20 (102 R) 20 102 R) O RPO) lt2 22 110 R) 22 (109 R) (1 RPO) lt 2 20 (100 R) 20 (99 R) (1 RPO) lt1 20 (102 ooR) 20 (101 R) (1 RPO) lt 1 40 (99 R) 40 (100 R) (1 RPO) lt 1 20 (100 R) 20 (100 R) (0 RPO) lt 1 20 (102 R) 20 (102 R) (0 RPO) lt2 19 (96 R) 19 (95 R) (1 RPO) lt2 19 (94 R) 19 (97 R) (3 RPO) lt 1 20 (102 R 21 (106 R) (4 RPO) lt 1 20 (102 R) 21 (105 R) (3 RPO lt 1 20 (102 R) 21 (105 R)(3 RPO)
93R 98 R 99R
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 Rec
0 - 227
47 - 150
17 -183
52 -150
40-160
64 - 148
53 - 149
37 - 160
37 -162
70 - 130
70 - 130
70 - 130
45- 169
46 - 157
59 - 156
18 - 190
18 - 190
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
eastern analytical wwweailabscom Phone (603) 228-0525 4
inc
IW QC REPORT EAi ID 108078
Client GZA GeoEnvironmentaf Inc NH)
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method
12-Dichlorobenzene--d4 (surr) 99R 105R 103 R 372012 Rec 70-130 624 Toluene-dB (surr) 94R 96R 96R 372012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated-matrix spikes andor laboratory-Control Samples metacceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QNQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units Date of ExtractionPrep
Date of Analysis
Analyst
Method
DIiution Factor
Oil amp Grease (HEM)
Final Effluent 8-3625 B-3727 B-3722
10807802 aqueous
3212 3212
mgL
31212
31212
LAS 1664A
1
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
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FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
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shy
_middotmiddot_ ~ _l________f
___e_a_s_t_e_rn_a_n_a_l_y_t1_middotc_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report Eastern Analytical Inc ID 108078
Client Identification Wastewater Analysis
Date Received 322012
Report revisionreissue Revision replaces report dated 32612
Revision lnfonnatlon Per your request Lead as been analyzed on the samples submitted to Frontier Global Sciences
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
r The following standard abbreviations and conventions apply to all EAi reports
Solid samples are reported on a dry weight basis unless otherwise noted lt less thanbull followed by the reporting limit gt greater thanbull followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following Information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
Ifyou have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
of pages (excluding cover letter)
I J bull - bull ~ bull I i middot 1n1wcaibb~cc1m t middot middot middot
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SAMPLE CONDITIONS PAGE EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Temperature upon receipt (degC) 21 Received on ice or cold packs (YesNo) Y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10807801 Effluent_Fiekl Blank B-3621 3212 3212 aqueous Adheres to Sample Acceptance Policy
10807802 Final Effluent B-3625 8middot3727 3212 3212 aqueous Adheres to Sample Acceptance Polley B-3722
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint shylgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
Afl results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
II LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 8-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 32112
Units ug1
Date of Analysis 3l712
Analyst BAM
Method 624 1DIiution Factor
Chloromethane lt5 Vinyl chloride lt2 Bromomethane lt2 Chloroethane lt5 Trichlorofluoromethane lt5 Acrolein lt 50 Acetone lt50 1 1-Dichloroethene lt1 Methylene chloride lt5 Carbon disulfide lt5 Acry1onitrile lt 50 Methy-t-butyl ether(MTBE) lt 10 trans-12-Dichloroethene lt2 Vinyl acetate lt 10 1 1-Dichloroethane lt2 cis-12-Dichloroethene lt2 2-Butanone(MEK) lt 10 Chloroform lt2 1 1 1-Trichloroethane lt2 Carbon tetrachloride lt2 Benzene lt 1 12-0lchloroethane lt2 Trichloroethene lt2 12-Dichloropropane lt2 Bromodichloromethane lt2 2-Chloroethylvinylether lt2 4-Methyl-2-pentanone(MIBK) lt 10 cis-13-Dichloropropene lt2 Toluene lt1 trans-13-Dlchloropropene lt2 112-Trichloroethane lt2 2-Hexanone lt 10 Tetrachloroethene lt2 Dlbromochloromethane lt2 Chlorobenzene lt2 Ethylbenzene lt1 mp-Xylene lt1 o-Xylene lt 1 Styrene lt 1 Bromoform lt2 1122-Tetrachloroethane lt2 13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 4-Bromofluorobenzene (surr) 93degoR 12-Dichlorobenzene-d4 (surr) 99degoR
~
eastern analytical inc wwweaifabscom Phone (603) 228-0525 2
bull
LABORATORY REPORT EAi I 0 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent B-3625 B-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 3212
Units ug1
Date of Analysis 3712
Analyst BAM Method 624
Dllution Factor 1
Toluene-dB (surr) 94R
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
middot
~
--
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Parameter Name
Chloromethane
Blank LCS LCSO Analysis Date Units Limits RPO Method
624 lt5 20 (99 R) 20 (101 R) (2 RPD) 372012 ug1 0-273 20 Vinyl chloride lt2 20 (102 R) 21 (106 R) (4 RPO) 372012 ug1 0- 251 20 624 Bromomethane lt2 19 (93 R) 21 (103 R) (10 RPD) 372012 ug1 0- 242 20 624 Chloroethane lt5 23 (113 R) 22 (110 R) (3 RPO) 3172012 ug1 14 - 230 20 624 Trichlorofluoromethane lt5 22 (108 R) 22 (108 R) (0 RPO) 372012 ug1 17-181 20 624 Acrolein lt 50 bull lt 50 (R bull lt 50 (R NIA) (RPO NIA) 372012 ug1 40-160 20 624 Acetone lt 50 bull lt 50 (188 R) lt 50 (114 R) (49 RPO) 372012 ug1 40 - 160 20 624 1 1-0lchloroethene lt 1 19 (97 R) 19 (95 R) (2 RPO) 372012 ug1 0-234 20 624 Methylene chloride lt5 22 (110 R) 22 (108 R) (2 RPO) 372012 ug1 0 - 221 20 624 Carbon disulfide lt5 17 (85 R) 17 (83 R) (2 RPO) 372012 ug1 70 - 130 20 624 Acrylonitrile lt 50 lt 50 (109 R) lt 50 (104 R) (5 RPO) 372012 ug1 40 - 160 20 624 Methyl-t-butyl ether(MTBE) lt10 20 114 R) 20 (113 R) (1 RPO) 372012 ug1 70 - 130 20 624 trans-12-0ichloroethene lt2 19 (96 R) 19 (96 R) O RPO) 372012 ugJ 54-156 20 624 Vinyl acetate lt 10 30 (137 R) 30 (134 R) (2 RPO) 372012 ug1 40- 160 20 624 1 1-0ichlloroethane lt2 21 (106 R) 21 (104 R) (2 RPO) 372012 ug1 59 - 155 20 624 cis-12-Dichloroethene lt2 20 (101 R) 20 (99 R) (2 RPO) 372012 ug1 70 - 130 20 624 2-Butanone(MEK) lt10 30 (130 R) 20 (100 R) (26 RPO) 372012 ug1 40 - 160 20 624 Chloroform lt2 21 (104 R) 21 (104 R) (0 RPO) 372012 ug1 51 - 138 20 624 1 1 1-Trichloroethane
Carbon t etrachloride
lt2 22 (111 R) 22 (110 R) (1 RPO) lt2 24 (122 R) 24 (121 R) (1 RPO)
3172012 ugl
372012 ug1
52-162
70 - 140
20
20
624 624
Benzene lt 1 20 (100 R) 20 (100 R) (0 RPO) 3172012 ug1 37 - 151 20 624 1 2-0ichlrroethane lt2 22 (111 R) 22 (110 R) (1 RPO) 372012 ug1 49 - 155 20 624 T richloroethene lt2 21 (105 R) 20 (102 R) (3 RPO) 372012 ug1 71 - 157 20 624 12-0ichloropropane lt2 21 (103 R) 21 (103 R) O RPO) 372012 ug1 0- 210 20 624 Bromodichloromethane lt2 22 (110 R) 22 (110 R) (0 RPO) 372012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 29 (143 R) 29 (144 R) (1 RPO) 372012 ug1 0 - 305 20 624 4-Methyl-2-pentanone(MIBK) lt10 20 (107 R) 20 (105 R) (2 RPO) 3172012 ug1 40-160 20 624 cis-13-Dichloropropene
Toluene
trans-13-0ichloropropene
1 12-Trichloroethane
2-Hexanone
Tetrachloroethene
Dibromochloromethane
Chlorobenzene
Ethylbenzene
mp-Xylene
o-Xylene
Styrene
Bromoform
1 122-Tetrachloroethane
13-0ichlorobenzene
14-0ichlorobenzene
12-Dichlorobenzene
4-Bromofluorobenzene (surr)
lt2 23 (115 R) 23 (115 R) (0 RPO) lt 1 20 (98 R) 20 (98 R) (0 RPO lt2 22 (110 ooR) 22 (108 R) (2 RPO) lt 2 19 (95 R) 19 (94 R) (1 RPO)
lt 10 20 (120 R) 20 (101 ooR) (17 RPO) lt2 20 (102 R) 20 102 R) O RPO) lt2 22 110 R) 22 (109 R) (1 RPO) lt 2 20 (100 R) 20 (99 R) (1 RPO) lt1 20 (102 ooR) 20 (101 R) (1 RPO) lt 1 40 (99 R) 40 (100 R) (1 RPO) lt 1 20 (100 R) 20 (100 R) (0 RPO) lt 1 20 (102 R) 20 (102 R) (0 RPO) lt2 19 (96 R) 19 (95 R) (1 RPO) lt2 19 (94 R) 19 (97 R) (3 RPO) lt 1 20 (102 R 21 (106 R) (4 RPO) lt 1 20 (102 R) 21 (105 R) (3 RPO lt 1 20 (102 R) 21 (105 R)(3 RPO)
93R 98 R 99R
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 Rec
0 - 227
47 - 150
17 -183
52 -150
40-160
64 - 148
53 - 149
37 - 160
37 -162
70 - 130
70 - 130
70 - 130
45- 169
46 - 157
59 - 156
18 - 190
18 - 190
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
eastern analytical wwweailabscom Phone (603) 228-0525 4
inc
IW QC REPORT EAi ID 108078
Client GZA GeoEnvironmentaf Inc NH)
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method
12-Dichlorobenzene--d4 (surr) 99R 105R 103 R 372012 Rec 70-130 624 Toluene-dB (surr) 94R 96R 96R 372012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated-matrix spikes andor laboratory-Control Samples metacceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QNQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units Date of ExtractionPrep
Date of Analysis
Analyst
Method
DIiution Factor
Oil amp Grease (HEM)
Final Effluent 8-3625 B-3727 B-3722
10807802 aqueous
3212 3212
mgL
31212
31212
LAS 1664A
1
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
CIOBAL SCICtS uD~05 S Plt1g_e I of I_ bttpwwwFro11tieltGScom
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
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bull
SAMPLE CONDITIONS PAGE EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Temperature upon receipt (degC) 21 Received on ice or cold packs (YesNo) Y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10807801 Effluent_Fiekl Blank B-3621 3212 3212 aqueous Adheres to Sample Acceptance Policy
10807802 Final Effluent B-3625 8middot3727 3212 3212 aqueous Adheres to Sample Acceptance Polley B-3722
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint shylgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
Afl results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
II LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 8-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 32112
Units ug1
Date of Analysis 3l712
Analyst BAM
Method 624 1DIiution Factor
Chloromethane lt5 Vinyl chloride lt2 Bromomethane lt2 Chloroethane lt5 Trichlorofluoromethane lt5 Acrolein lt 50 Acetone lt50 1 1-Dichloroethene lt1 Methylene chloride lt5 Carbon disulfide lt5 Acry1onitrile lt 50 Methy-t-butyl ether(MTBE) lt 10 trans-12-Dichloroethene lt2 Vinyl acetate lt 10 1 1-Dichloroethane lt2 cis-12-Dichloroethene lt2 2-Butanone(MEK) lt 10 Chloroform lt2 1 1 1-Trichloroethane lt2 Carbon tetrachloride lt2 Benzene lt 1 12-0lchloroethane lt2 Trichloroethene lt2 12-Dichloropropane lt2 Bromodichloromethane lt2 2-Chloroethylvinylether lt2 4-Methyl-2-pentanone(MIBK) lt 10 cis-13-Dichloropropene lt2 Toluene lt1 trans-13-Dlchloropropene lt2 112-Trichloroethane lt2 2-Hexanone lt 10 Tetrachloroethene lt2 Dlbromochloromethane lt2 Chlorobenzene lt2 Ethylbenzene lt1 mp-Xylene lt1 o-Xylene lt 1 Styrene lt 1 Bromoform lt2 1122-Tetrachloroethane lt2 13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 4-Bromofluorobenzene (surr) 93degoR 12-Dichlorobenzene-d4 (surr) 99degoR
~
eastern analytical inc wwweaifabscom Phone (603) 228-0525 2
bull
LABORATORY REPORT EAi I 0 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent B-3625 B-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 3212
Units ug1
Date of Analysis 3712
Analyst BAM Method 624
Dllution Factor 1
Toluene-dB (surr) 94R
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
middot
~
--
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Parameter Name
Chloromethane
Blank LCS LCSO Analysis Date Units Limits RPO Method
624 lt5 20 (99 R) 20 (101 R) (2 RPD) 372012 ug1 0-273 20 Vinyl chloride lt2 20 (102 R) 21 (106 R) (4 RPO) 372012 ug1 0- 251 20 624 Bromomethane lt2 19 (93 R) 21 (103 R) (10 RPD) 372012 ug1 0- 242 20 624 Chloroethane lt5 23 (113 R) 22 (110 R) (3 RPO) 3172012 ug1 14 - 230 20 624 Trichlorofluoromethane lt5 22 (108 R) 22 (108 R) (0 RPO) 372012 ug1 17-181 20 624 Acrolein lt 50 bull lt 50 (R bull lt 50 (R NIA) (RPO NIA) 372012 ug1 40-160 20 624 Acetone lt 50 bull lt 50 (188 R) lt 50 (114 R) (49 RPO) 372012 ug1 40 - 160 20 624 1 1-0lchloroethene lt 1 19 (97 R) 19 (95 R) (2 RPO) 372012 ug1 0-234 20 624 Methylene chloride lt5 22 (110 R) 22 (108 R) (2 RPO) 372012 ug1 0 - 221 20 624 Carbon disulfide lt5 17 (85 R) 17 (83 R) (2 RPO) 372012 ug1 70 - 130 20 624 Acrylonitrile lt 50 lt 50 (109 R) lt 50 (104 R) (5 RPO) 372012 ug1 40 - 160 20 624 Methyl-t-butyl ether(MTBE) lt10 20 114 R) 20 (113 R) (1 RPO) 372012 ug1 70 - 130 20 624 trans-12-0ichloroethene lt2 19 (96 R) 19 (96 R) O RPO) 372012 ugJ 54-156 20 624 Vinyl acetate lt 10 30 (137 R) 30 (134 R) (2 RPO) 372012 ug1 40- 160 20 624 1 1-0ichlloroethane lt2 21 (106 R) 21 (104 R) (2 RPO) 372012 ug1 59 - 155 20 624 cis-12-Dichloroethene lt2 20 (101 R) 20 (99 R) (2 RPO) 372012 ug1 70 - 130 20 624 2-Butanone(MEK) lt10 30 (130 R) 20 (100 R) (26 RPO) 372012 ug1 40 - 160 20 624 Chloroform lt2 21 (104 R) 21 (104 R) (0 RPO) 372012 ug1 51 - 138 20 624 1 1 1-Trichloroethane
Carbon t etrachloride
lt2 22 (111 R) 22 (110 R) (1 RPO) lt2 24 (122 R) 24 (121 R) (1 RPO)
3172012 ugl
372012 ug1
52-162
70 - 140
20
20
624 624
Benzene lt 1 20 (100 R) 20 (100 R) (0 RPO) 3172012 ug1 37 - 151 20 624 1 2-0ichlrroethane lt2 22 (111 R) 22 (110 R) (1 RPO) 372012 ug1 49 - 155 20 624 T richloroethene lt2 21 (105 R) 20 (102 R) (3 RPO) 372012 ug1 71 - 157 20 624 12-0ichloropropane lt2 21 (103 R) 21 (103 R) O RPO) 372012 ug1 0- 210 20 624 Bromodichloromethane lt2 22 (110 R) 22 (110 R) (0 RPO) 372012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 29 (143 R) 29 (144 R) (1 RPO) 372012 ug1 0 - 305 20 624 4-Methyl-2-pentanone(MIBK) lt10 20 (107 R) 20 (105 R) (2 RPO) 3172012 ug1 40-160 20 624 cis-13-Dichloropropene
Toluene
trans-13-0ichloropropene
1 12-Trichloroethane
2-Hexanone
Tetrachloroethene
Dibromochloromethane
Chlorobenzene
Ethylbenzene
mp-Xylene
o-Xylene
Styrene
Bromoform
1 122-Tetrachloroethane
13-0ichlorobenzene
14-0ichlorobenzene
12-Dichlorobenzene
4-Bromofluorobenzene (surr)
lt2 23 (115 R) 23 (115 R) (0 RPO) lt 1 20 (98 R) 20 (98 R) (0 RPO lt2 22 (110 ooR) 22 (108 R) (2 RPO) lt 2 19 (95 R) 19 (94 R) (1 RPO)
lt 10 20 (120 R) 20 (101 ooR) (17 RPO) lt2 20 (102 R) 20 102 R) O RPO) lt2 22 110 R) 22 (109 R) (1 RPO) lt 2 20 (100 R) 20 (99 R) (1 RPO) lt1 20 (102 ooR) 20 (101 R) (1 RPO) lt 1 40 (99 R) 40 (100 R) (1 RPO) lt 1 20 (100 R) 20 (100 R) (0 RPO) lt 1 20 (102 R) 20 (102 R) (0 RPO) lt2 19 (96 R) 19 (95 R) (1 RPO) lt2 19 (94 R) 19 (97 R) (3 RPO) lt 1 20 (102 R 21 (106 R) (4 RPO) lt 1 20 (102 R) 21 (105 R) (3 RPO lt 1 20 (102 R) 21 (105 R)(3 RPO)
93R 98 R 99R
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 Rec
0 - 227
47 - 150
17 -183
52 -150
40-160
64 - 148
53 - 149
37 - 160
37 -162
70 - 130
70 - 130
70 - 130
45- 169
46 - 157
59 - 156
18 - 190
18 - 190
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
eastern analytical wwweailabscom Phone (603) 228-0525 4
inc
IW QC REPORT EAi ID 108078
Client GZA GeoEnvironmentaf Inc NH)
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method
12-Dichlorobenzene--d4 (surr) 99R 105R 103 R 372012 Rec 70-130 624 Toluene-dB (surr) 94R 96R 96R 372012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated-matrix spikes andor laboratory-Control Samples metacceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QNQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units Date of ExtractionPrep
Date of Analysis
Analyst
Method
DIiution Factor
Oil amp Grease (HEM)
Final Effluent 8-3625 B-3727 B-3722
10807802 aqueous
3212 3212
mgL
31212
31212
LAS 1664A
1
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
CIOBAL SCICtS uD~05 S Plt1g_e I of I_ bttpwwwFro11tieltGScom
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
FGS VoMc Order middot~ )391t1poundpound sampre Recerp1 clgteclltlltt
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C oolbullrOmiddot middotc Cooler 7 middotc -CooJera -Coor a -Cootbullrr 10 middot c
Cooler 1 1 _ middot c Cooler 1t - middotc
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C hein orCubulltody CCC Ja pre$ent and rncfudes tho 1ollowing information for o-ech samplbullt No NA Cornmbullnta
Sarn-1bull 10Samnle OeacrftJon Oat bullnd TImo of Samole Co11--1on S a moledl O p-aervetton TVoe
Reauebulltbulld AnaJvbullebullmiddot l
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Sample Condittonnnte---- Yes No Commenl8 Sbullmlbull oontalnera WWbull cetved Intact
S ambullbull to on oontolner metchCOC Correct bullbullmJbull eontalners u sed fol ueatbulld bullnart-bullbull Samnfbullbull recetvampd wllhln hoJdJnn tlmbull Samole volumbull bullufflclbullnt for re~uted anehfaIbull Con-ct o-vbullWbull ubulled ~or ro-uted bullnbull-C$
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lt
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
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II LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 8-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 32112
Units ug1
Date of Analysis 3l712
Analyst BAM
Method 624 1DIiution Factor
Chloromethane lt5 Vinyl chloride lt2 Bromomethane lt2 Chloroethane lt5 Trichlorofluoromethane lt5 Acrolein lt 50 Acetone lt50 1 1-Dichloroethene lt1 Methylene chloride lt5 Carbon disulfide lt5 Acry1onitrile lt 50 Methy-t-butyl ether(MTBE) lt 10 trans-12-Dichloroethene lt2 Vinyl acetate lt 10 1 1-Dichloroethane lt2 cis-12-Dichloroethene lt2 2-Butanone(MEK) lt 10 Chloroform lt2 1 1 1-Trichloroethane lt2 Carbon tetrachloride lt2 Benzene lt 1 12-0lchloroethane lt2 Trichloroethene lt2 12-Dichloropropane lt2 Bromodichloromethane lt2 2-Chloroethylvinylether lt2 4-Methyl-2-pentanone(MIBK) lt 10 cis-13-Dichloropropene lt2 Toluene lt1 trans-13-Dlchloropropene lt2 112-Trichloroethane lt2 2-Hexanone lt 10 Tetrachloroethene lt2 Dlbromochloromethane lt2 Chlorobenzene lt2 Ethylbenzene lt1 mp-Xylene lt1 o-Xylene lt 1 Styrene lt 1 Bromoform lt2 1122-Tetrachloroethane lt2 13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 4-Bromofluorobenzene (surr) 93degoR 12-Dichlorobenzene-d4 (surr) 99degoR
~
eastern analytical inc wwweaifabscom Phone (603) 228-0525 2
bull
LABORATORY REPORT EAi I 0 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent B-3625 B-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 3212
Units ug1
Date of Analysis 3712
Analyst BAM Method 624
Dllution Factor 1
Toluene-dB (surr) 94R
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
middot
~
--
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Parameter Name
Chloromethane
Blank LCS LCSO Analysis Date Units Limits RPO Method
624 lt5 20 (99 R) 20 (101 R) (2 RPD) 372012 ug1 0-273 20 Vinyl chloride lt2 20 (102 R) 21 (106 R) (4 RPO) 372012 ug1 0- 251 20 624 Bromomethane lt2 19 (93 R) 21 (103 R) (10 RPD) 372012 ug1 0- 242 20 624 Chloroethane lt5 23 (113 R) 22 (110 R) (3 RPO) 3172012 ug1 14 - 230 20 624 Trichlorofluoromethane lt5 22 (108 R) 22 (108 R) (0 RPO) 372012 ug1 17-181 20 624 Acrolein lt 50 bull lt 50 (R bull lt 50 (R NIA) (RPO NIA) 372012 ug1 40-160 20 624 Acetone lt 50 bull lt 50 (188 R) lt 50 (114 R) (49 RPO) 372012 ug1 40 - 160 20 624 1 1-0lchloroethene lt 1 19 (97 R) 19 (95 R) (2 RPO) 372012 ug1 0-234 20 624 Methylene chloride lt5 22 (110 R) 22 (108 R) (2 RPO) 372012 ug1 0 - 221 20 624 Carbon disulfide lt5 17 (85 R) 17 (83 R) (2 RPO) 372012 ug1 70 - 130 20 624 Acrylonitrile lt 50 lt 50 (109 R) lt 50 (104 R) (5 RPO) 372012 ug1 40 - 160 20 624 Methyl-t-butyl ether(MTBE) lt10 20 114 R) 20 (113 R) (1 RPO) 372012 ug1 70 - 130 20 624 trans-12-0ichloroethene lt2 19 (96 R) 19 (96 R) O RPO) 372012 ugJ 54-156 20 624 Vinyl acetate lt 10 30 (137 R) 30 (134 R) (2 RPO) 372012 ug1 40- 160 20 624 1 1-0ichlloroethane lt2 21 (106 R) 21 (104 R) (2 RPO) 372012 ug1 59 - 155 20 624 cis-12-Dichloroethene lt2 20 (101 R) 20 (99 R) (2 RPO) 372012 ug1 70 - 130 20 624 2-Butanone(MEK) lt10 30 (130 R) 20 (100 R) (26 RPO) 372012 ug1 40 - 160 20 624 Chloroform lt2 21 (104 R) 21 (104 R) (0 RPO) 372012 ug1 51 - 138 20 624 1 1 1-Trichloroethane
Carbon t etrachloride
lt2 22 (111 R) 22 (110 R) (1 RPO) lt2 24 (122 R) 24 (121 R) (1 RPO)
3172012 ugl
372012 ug1
52-162
70 - 140
20
20
624 624
Benzene lt 1 20 (100 R) 20 (100 R) (0 RPO) 3172012 ug1 37 - 151 20 624 1 2-0ichlrroethane lt2 22 (111 R) 22 (110 R) (1 RPO) 372012 ug1 49 - 155 20 624 T richloroethene lt2 21 (105 R) 20 (102 R) (3 RPO) 372012 ug1 71 - 157 20 624 12-0ichloropropane lt2 21 (103 R) 21 (103 R) O RPO) 372012 ug1 0- 210 20 624 Bromodichloromethane lt2 22 (110 R) 22 (110 R) (0 RPO) 372012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 29 (143 R) 29 (144 R) (1 RPO) 372012 ug1 0 - 305 20 624 4-Methyl-2-pentanone(MIBK) lt10 20 (107 R) 20 (105 R) (2 RPO) 3172012 ug1 40-160 20 624 cis-13-Dichloropropene
Toluene
trans-13-0ichloropropene
1 12-Trichloroethane
2-Hexanone
Tetrachloroethene
Dibromochloromethane
Chlorobenzene
Ethylbenzene
mp-Xylene
o-Xylene
Styrene
Bromoform
1 122-Tetrachloroethane
13-0ichlorobenzene
14-0ichlorobenzene
12-Dichlorobenzene
4-Bromofluorobenzene (surr)
lt2 23 (115 R) 23 (115 R) (0 RPO) lt 1 20 (98 R) 20 (98 R) (0 RPO lt2 22 (110 ooR) 22 (108 R) (2 RPO) lt 2 19 (95 R) 19 (94 R) (1 RPO)
lt 10 20 (120 R) 20 (101 ooR) (17 RPO) lt2 20 (102 R) 20 102 R) O RPO) lt2 22 110 R) 22 (109 R) (1 RPO) lt 2 20 (100 R) 20 (99 R) (1 RPO) lt1 20 (102 ooR) 20 (101 R) (1 RPO) lt 1 40 (99 R) 40 (100 R) (1 RPO) lt 1 20 (100 R) 20 (100 R) (0 RPO) lt 1 20 (102 R) 20 (102 R) (0 RPO) lt2 19 (96 R) 19 (95 R) (1 RPO) lt2 19 (94 R) 19 (97 R) (3 RPO) lt 1 20 (102 R 21 (106 R) (4 RPO) lt 1 20 (102 R) 21 (105 R) (3 RPO lt 1 20 (102 R) 21 (105 R)(3 RPO)
93R 98 R 99R
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 Rec
0 - 227
47 - 150
17 -183
52 -150
40-160
64 - 148
53 - 149
37 - 160
37 -162
70 - 130
70 - 130
70 - 130
45- 169
46 - 157
59 - 156
18 - 190
18 - 190
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
eastern analytical wwweailabscom Phone (603) 228-0525 4
inc
IW QC REPORT EAi ID 108078
Client GZA GeoEnvironmentaf Inc NH)
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method
12-Dichlorobenzene--d4 (surr) 99R 105R 103 R 372012 Rec 70-130 624 Toluene-dB (surr) 94R 96R 96R 372012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated-matrix spikes andor laboratory-Control Samples metacceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QNQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units Date of ExtractionPrep
Date of Analysis
Analyst
Method
DIiution Factor
Oil amp Grease (HEM)
Final Effluent 8-3625 B-3727 B-3722
10807802 aqueous
3212 3212
mgL
31212
31212
LAS 1664A
1
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
CIOBAL SCICtS uD~05 S Plt1g_e I of I_ bttpwwwFro11tieltGScom
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
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LABORATORY REPORT EAi I 0 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent B-3625 B-3727 B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212
Date Received 3212
Units ug1
Date of Analysis 3712
Analyst BAM Method 624
Dllution Factor 1
Toluene-dB (surr) 94R
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
middot
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--
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Parameter Name
Chloromethane
Blank LCS LCSO Analysis Date Units Limits RPO Method
624 lt5 20 (99 R) 20 (101 R) (2 RPD) 372012 ug1 0-273 20 Vinyl chloride lt2 20 (102 R) 21 (106 R) (4 RPO) 372012 ug1 0- 251 20 624 Bromomethane lt2 19 (93 R) 21 (103 R) (10 RPD) 372012 ug1 0- 242 20 624 Chloroethane lt5 23 (113 R) 22 (110 R) (3 RPO) 3172012 ug1 14 - 230 20 624 Trichlorofluoromethane lt5 22 (108 R) 22 (108 R) (0 RPO) 372012 ug1 17-181 20 624 Acrolein lt 50 bull lt 50 (R bull lt 50 (R NIA) (RPO NIA) 372012 ug1 40-160 20 624 Acetone lt 50 bull lt 50 (188 R) lt 50 (114 R) (49 RPO) 372012 ug1 40 - 160 20 624 1 1-0lchloroethene lt 1 19 (97 R) 19 (95 R) (2 RPO) 372012 ug1 0-234 20 624 Methylene chloride lt5 22 (110 R) 22 (108 R) (2 RPO) 372012 ug1 0 - 221 20 624 Carbon disulfide lt5 17 (85 R) 17 (83 R) (2 RPO) 372012 ug1 70 - 130 20 624 Acrylonitrile lt 50 lt 50 (109 R) lt 50 (104 R) (5 RPO) 372012 ug1 40 - 160 20 624 Methyl-t-butyl ether(MTBE) lt10 20 114 R) 20 (113 R) (1 RPO) 372012 ug1 70 - 130 20 624 trans-12-0ichloroethene lt2 19 (96 R) 19 (96 R) O RPO) 372012 ugJ 54-156 20 624 Vinyl acetate lt 10 30 (137 R) 30 (134 R) (2 RPO) 372012 ug1 40- 160 20 624 1 1-0ichlloroethane lt2 21 (106 R) 21 (104 R) (2 RPO) 372012 ug1 59 - 155 20 624 cis-12-Dichloroethene lt2 20 (101 R) 20 (99 R) (2 RPO) 372012 ug1 70 - 130 20 624 2-Butanone(MEK) lt10 30 (130 R) 20 (100 R) (26 RPO) 372012 ug1 40 - 160 20 624 Chloroform lt2 21 (104 R) 21 (104 R) (0 RPO) 372012 ug1 51 - 138 20 624 1 1 1-Trichloroethane
Carbon t etrachloride
lt2 22 (111 R) 22 (110 R) (1 RPO) lt2 24 (122 R) 24 (121 R) (1 RPO)
3172012 ugl
372012 ug1
52-162
70 - 140
20
20
624 624
Benzene lt 1 20 (100 R) 20 (100 R) (0 RPO) 3172012 ug1 37 - 151 20 624 1 2-0ichlrroethane lt2 22 (111 R) 22 (110 R) (1 RPO) 372012 ug1 49 - 155 20 624 T richloroethene lt2 21 (105 R) 20 (102 R) (3 RPO) 372012 ug1 71 - 157 20 624 12-0ichloropropane lt2 21 (103 R) 21 (103 R) O RPO) 372012 ug1 0- 210 20 624 Bromodichloromethane lt2 22 (110 R) 22 (110 R) (0 RPO) 372012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 29 (143 R) 29 (144 R) (1 RPO) 372012 ug1 0 - 305 20 624 4-Methyl-2-pentanone(MIBK) lt10 20 (107 R) 20 (105 R) (2 RPO) 3172012 ug1 40-160 20 624 cis-13-Dichloropropene
Toluene
trans-13-0ichloropropene
1 12-Trichloroethane
2-Hexanone
Tetrachloroethene
Dibromochloromethane
Chlorobenzene
Ethylbenzene
mp-Xylene
o-Xylene
Styrene
Bromoform
1 122-Tetrachloroethane
13-0ichlorobenzene
14-0ichlorobenzene
12-Dichlorobenzene
4-Bromofluorobenzene (surr)
lt2 23 (115 R) 23 (115 R) (0 RPO) lt 1 20 (98 R) 20 (98 R) (0 RPO lt2 22 (110 ooR) 22 (108 R) (2 RPO) lt 2 19 (95 R) 19 (94 R) (1 RPO)
lt 10 20 (120 R) 20 (101 ooR) (17 RPO) lt2 20 (102 R) 20 102 R) O RPO) lt2 22 110 R) 22 (109 R) (1 RPO) lt 2 20 (100 R) 20 (99 R) (1 RPO) lt1 20 (102 ooR) 20 (101 R) (1 RPO) lt 1 40 (99 R) 40 (100 R) (1 RPO) lt 1 20 (100 R) 20 (100 R) (0 RPO) lt 1 20 (102 R) 20 (102 R) (0 RPO) lt2 19 (96 R) 19 (95 R) (1 RPO) lt2 19 (94 R) 19 (97 R) (3 RPO) lt 1 20 (102 R 21 (106 R) (4 RPO) lt 1 20 (102 R) 21 (105 R) (3 RPO lt 1 20 (102 R) 21 (105 R)(3 RPO)
93R 98 R 99R
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 Rec
0 - 227
47 - 150
17 -183
52 -150
40-160
64 - 148
53 - 149
37 - 160
37 -162
70 - 130
70 - 130
70 - 130
45- 169
46 - 157
59 - 156
18 - 190
18 - 190
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
eastern analytical wwweailabscom Phone (603) 228-0525 4
inc
IW QC REPORT EAi ID 108078
Client GZA GeoEnvironmentaf Inc NH)
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method
12-Dichlorobenzene--d4 (surr) 99R 105R 103 R 372012 Rec 70-130 624 Toluene-dB (surr) 94R 96R 96R 372012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated-matrix spikes andor laboratory-Control Samples metacceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QNQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units Date of ExtractionPrep
Date of Analysis
Analyst
Method
DIiution Factor
Oil amp Grease (HEM)
Final Effluent 8-3625 B-3727 B-3722
10807802 aqueous
3212 3212
mgL
31212
31212
LAS 1664A
1
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
CIOBAL SCICtS uD~05 S Plt1g_e I of I_ bttpwwwFro11tieltGScom
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
FGS VoMc Order middot~ )391t1poundpound sampre Recerp1 clgteclltlltt
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Thermomoter JO $ lScgt
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CorrecUon Factor (Ctr) plusmn amp2gtgt d9C10S C
C oolbullrOmiddot middotc Cooler 7 middotc -CooJera -Coor a -Cootbullrr 10 middot c
Cooler 1 1 _ middot c Cooler 1t - middotc
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C hein orCubulltody CCC Ja pre$ent and rncfudes tho 1ollowing information for o-ech samplbullt No NA Cornmbullnta
Sarn-1bull 10Samnle OeacrftJon Oat bullnd TImo of Samole Co11--1on S a moledl O p-aervetton TVoe
Reauebulltbulld AnaJvbullebullmiddot l
le Cntcmo1 chbullin ofouat- middot --uld X
Sample Condittonnnte---- Yes No Commenl8 Sbullmlbull oontalnera WWbull cetved Intact
S ambullbull to on oontolner metchCOC Correct bullbullmJbull eontalners u sed fol ueatbulld bullnart-bullbull Samnfbullbull recetvampd wllhln hoJdJnn tlmbull Samole volumbull bullufflclbullnt for re~uted anehfaIbull Con-ct o-vbullWbull ubulled ~or ro-uted bullnbull-C$
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lt
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
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QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Parameter Name
Chloromethane
Blank LCS LCSO Analysis Date Units Limits RPO Method
624 lt5 20 (99 R) 20 (101 R) (2 RPD) 372012 ug1 0-273 20 Vinyl chloride lt2 20 (102 R) 21 (106 R) (4 RPO) 372012 ug1 0- 251 20 624 Bromomethane lt2 19 (93 R) 21 (103 R) (10 RPD) 372012 ug1 0- 242 20 624 Chloroethane lt5 23 (113 R) 22 (110 R) (3 RPO) 3172012 ug1 14 - 230 20 624 Trichlorofluoromethane lt5 22 (108 R) 22 (108 R) (0 RPO) 372012 ug1 17-181 20 624 Acrolein lt 50 bull lt 50 (R bull lt 50 (R NIA) (RPO NIA) 372012 ug1 40-160 20 624 Acetone lt 50 bull lt 50 (188 R) lt 50 (114 R) (49 RPO) 372012 ug1 40 - 160 20 624 1 1-0lchloroethene lt 1 19 (97 R) 19 (95 R) (2 RPO) 372012 ug1 0-234 20 624 Methylene chloride lt5 22 (110 R) 22 (108 R) (2 RPO) 372012 ug1 0 - 221 20 624 Carbon disulfide lt5 17 (85 R) 17 (83 R) (2 RPO) 372012 ug1 70 - 130 20 624 Acrylonitrile lt 50 lt 50 (109 R) lt 50 (104 R) (5 RPO) 372012 ug1 40 - 160 20 624 Methyl-t-butyl ether(MTBE) lt10 20 114 R) 20 (113 R) (1 RPO) 372012 ug1 70 - 130 20 624 trans-12-0ichloroethene lt2 19 (96 R) 19 (96 R) O RPO) 372012 ugJ 54-156 20 624 Vinyl acetate lt 10 30 (137 R) 30 (134 R) (2 RPO) 372012 ug1 40- 160 20 624 1 1-0ichlloroethane lt2 21 (106 R) 21 (104 R) (2 RPO) 372012 ug1 59 - 155 20 624 cis-12-Dichloroethene lt2 20 (101 R) 20 (99 R) (2 RPO) 372012 ug1 70 - 130 20 624 2-Butanone(MEK) lt10 30 (130 R) 20 (100 R) (26 RPO) 372012 ug1 40 - 160 20 624 Chloroform lt2 21 (104 R) 21 (104 R) (0 RPO) 372012 ug1 51 - 138 20 624 1 1 1-Trichloroethane
Carbon t etrachloride
lt2 22 (111 R) 22 (110 R) (1 RPO) lt2 24 (122 R) 24 (121 R) (1 RPO)
3172012 ugl
372012 ug1
52-162
70 - 140
20
20
624 624
Benzene lt 1 20 (100 R) 20 (100 R) (0 RPO) 3172012 ug1 37 - 151 20 624 1 2-0ichlrroethane lt2 22 (111 R) 22 (110 R) (1 RPO) 372012 ug1 49 - 155 20 624 T richloroethene lt2 21 (105 R) 20 (102 R) (3 RPO) 372012 ug1 71 - 157 20 624 12-0ichloropropane lt2 21 (103 R) 21 (103 R) O RPO) 372012 ug1 0- 210 20 624 Bromodichloromethane lt2 22 (110 R) 22 (110 R) (0 RPO) 372012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 29 (143 R) 29 (144 R) (1 RPO) 372012 ug1 0 - 305 20 624 4-Methyl-2-pentanone(MIBK) lt10 20 (107 R) 20 (105 R) (2 RPO) 3172012 ug1 40-160 20 624 cis-13-Dichloropropene
Toluene
trans-13-0ichloropropene
1 12-Trichloroethane
2-Hexanone
Tetrachloroethene
Dibromochloromethane
Chlorobenzene
Ethylbenzene
mp-Xylene
o-Xylene
Styrene
Bromoform
1 122-Tetrachloroethane
13-0ichlorobenzene
14-0ichlorobenzene
12-Dichlorobenzene
4-Bromofluorobenzene (surr)
lt2 23 (115 R) 23 (115 R) (0 RPO) lt 1 20 (98 R) 20 (98 R) (0 RPO lt2 22 (110 ooR) 22 (108 R) (2 RPO) lt 2 19 (95 R) 19 (94 R) (1 RPO)
lt 10 20 (120 R) 20 (101 ooR) (17 RPO) lt2 20 (102 R) 20 102 R) O RPO) lt2 22 110 R) 22 (109 R) (1 RPO) lt 2 20 (100 R) 20 (99 R) (1 RPO) lt1 20 (102 ooR) 20 (101 R) (1 RPO) lt 1 40 (99 R) 40 (100 R) (1 RPO) lt 1 20 (100 R) 20 (100 R) (0 RPO) lt 1 20 (102 R) 20 (102 R) (0 RPO) lt2 19 (96 R) 19 (95 R) (1 RPO) lt2 19 (94 R) 19 (97 R) (3 RPO) lt 1 20 (102 R 21 (106 R) (4 RPO) lt 1 20 (102 R) 21 (105 R) (3 RPO lt 1 20 (102 R) 21 (105 R)(3 RPO)
93R 98 R 99R
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 ug1
3172012 ug1
372012 ug1
372012 ug1
372012 ug1
372012 Rec
0 - 227
47 - 150
17 -183
52 -150
40-160
64 - 148
53 - 149
37 - 160
37 -162
70 - 130
70 - 130
70 - 130
45- 169
46 - 157
59 - 156
18 - 190
18 - 190
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
eastern analytical wwweailabscom Phone (603) 228-0525 4
inc
IW QC REPORT EAi ID 108078
Client GZA GeoEnvironmentaf Inc NH)
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method
12-Dichlorobenzene--d4 (surr) 99R 105R 103 R 372012 Rec 70-130 624 Toluene-dB (surr) 94R 96R 96R 372012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated-matrix spikes andor laboratory-Control Samples metacceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QNQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units Date of ExtractionPrep
Date of Analysis
Analyst
Method
DIiution Factor
Oil amp Grease (HEM)
Final Effluent 8-3625 B-3727 B-3722
10807802 aqueous
3212 3212
mgL
31212
31212
LAS 1664A
1
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
CIOBAL SCICtS uD~05 S Plt1g_e I of I_ bttpwwwFro11tieltGScom
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
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GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
IW QC REPORT EAi ID 108078
Client GZA GeoEnvironmentaf Inc NH)
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method
12-Dichlorobenzene--d4 (surr) 99R 105R 103 R 372012 Rec 70-130 624 Toluene-dB (surr) 94R 96R 96R 372012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated-matrix spikes andor laboratory-Control Samples metacceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QNQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units Date of ExtractionPrep
Date of Analysis
Analyst
Method
DIiution Factor
Oil amp Grease (HEM)
Final Effluent 8-3625 B-3727 B-3722
10807802 aqueous
3212 3212
mgL
31212
31212
LAS 1664A
1
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
FGS VoMc Order middot~ )391t1poundpound sampre Recerp1 clgteclltlltt
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
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GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
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LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units Date of ExtractionPrep
Date of Analysis
Analyst
Method
DIiution Factor
Oil amp Grease (HEM)
Final Effluent 8-3625 B-3727 B-3722
10807802 aqueous
3212 3212
mgL
31212
31212
LAS 1664A
1
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
CIOBAL SCICtS uD~05 S Plt1g_e I of I_ bttpwwwFro11tieltGScom
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
DATeT1Memiddot w
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HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
QC REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH) Batch ID 734574-36453A0312120G1661
Client Designation Wastewater Analysis
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method
Oil amp Grease (HEM) lt5 36 (90 R) 36(90R)(ORPD) 3122012 mgL 78-114 18 1664A
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525
7
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
CIOBAL SCICtS uD~05 S Plt1g_e I of I_ bttpwwwFro11tieltGScom
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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lt
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
LABORATORY REPORT EAi ID 108078
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis
Sample ID Final Effluent 8-3625 B-3727
B-3722
Lab Sample ID 10807802
Matrix aqueous
Date Sampled 3212 Analysis
Date Received 3212 Units Date Time Method Analyst
Solids Suspended 43 mgL 30512 1400 2540D DLS Solids Dissolved 24000 mgL 30512 1500 2540C DLS Chloride 11000 mgL 30912 1101 4SOOCIE DLS Cyanide Total 002 mgL 30612 930 4500CNE KJR BOD lt6 mgL 30212 1630 52108 SKC COD 170 mgL 30512 1025 HSOOO KJR pH 71 SU 30212 1600 4500H+B NZ
eastern analytical inc wwweailabscom Phone (603) 228-0525 8
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
CIOBAL SCICtS uD~05 S Plt1g_e I of I_ bttpwwwFro11tieltGScom
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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lt
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
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GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
QC REPORT EAi ID 1080781~1 Client GZA GeoEnvlron mental Inc (NH)
C l ient Designation Wastewater Analysis
Date of
Parameter Name Blank LC$ LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 100 (101 ooR) NA mgL 3512 90-110 20 2540D
Solids Dissolved lt5 920 (92 ooR) NA mgL 3512 85 - 115 20 2540C
Chloride lt 1 26 (102 R) 26 (102 R) (0 RPO) mgL 3912 90 - 110 20 4500CIE
Cyanide Total lt 002 026 (104 R) NA mgL 3612 85- 115 20 4500CNE
BOD lt6 360 (91 R) 380 (96 R) (5 RPO) mgL 3212 84-115 20 52108
COD lt 10 110 (109 R) 110 (106 R) (3 RPO) mgL 3512 85- 115 20 H8000
pH 60 (100 ooR) 60 (99 R) (1 RPO) SU 3212 595-607 10 4500H+B
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPO Method
Solids Suspended
Solids Dissolved
Chloride
Cyanide Total 10807802
BOO 10805301
coo 10806907
pH
NA NA NA NA NA NA NA NA NA
0 02 029 (109 R) 028 (104 R) (5 RPO)
lt6 44 (110 ooR) NA 60 110 (101 ooR) 110 (89 R) (13 RPO)
NA NA NA
mgL
mgL
mgL
mgfl
mgL
mgL
SU
3512
3512
3912
3612
3212
3512
3212
20
20
20
75-125 20
75-125 20
80-120 20
10
2540D
2540C
4500CIE
4500CNE
5210B
H8000
4500H+B
Duplicate Parameter Name Parent ID
Duplicate Parent Duplicate Units
Date of Analysis RPO Method
Solids Suspended 10805401 290 320 (10 RPO) mgL
Solids Dissolved 10807802 24000 21000 (10 RPO) mgL
Chloride NA NA mgL
Cyanide Total NA NA mgL
BOD 10805301 lt6 lt6 (RPO NIA) mgL
coo NA NA mgL
pH 10807802 71 71 (0 RPO) SU
3512
3512 3912 3612
3212
3512
3212
20 2540D 20 2540C 20 4500CIE 20 4500CNE
20 52108 20 H8000
10 4500H+B
Samples were analyzed within holding times U1nless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
Fax 206-622middot-6870Hydrocarbon Sr Qther Samples middot u(Qfr11atltrraquoiiom ~
CIOBAL SCICtS uD~05 S Plt1g_e I of I_ bttpwwwFro11tieltGScom
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Rcaoivcd By
Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
FGS VoMc Order middot~ )391t1poundpound sampre Recerp1 clgteclltlltt
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Thermomoter JO $ lScgt
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CorrecUon Factor (Ctr) plusmn amp2gtgt d9C10S C
C oolbullrOmiddot middotc Cooler 7 middotc -CooJera -Coor a -Cootbullrr 10 middot c
Cooler 1 1 _ middot c Cooler 1t - middotc
-c- shy
C hein orCubulltody CCC Ja pre$ent and rncfudes tho 1ollowing information for o-ech samplbullt No NA Cornmbullnta
Sarn-1bull 10Samnle OeacrftJon Oat bullnd TImo of Samole Co11--1on S a moledl O p-aervetton TVoe
Reauebulltbulld AnaJvbullebullmiddot l
le Cntcmo1 chbullin ofouat- middot --uld X
Sample Condittonnnte---- Yes No Commenl8 Sbullmlbull oontalnera WWbull cetved Intact
S ambullbull to on oontolner metchCOC Correct bullbullmJbull eontalners u sed fol ueatbulld bullnart-bullbull Samnfbullbull recetvampd wllhln hoJdJnn tlmbull Samole volumbull bullufflclbullnt for re~uted anehfaIbull Con-ct o-vbullWbull ubulled ~or ro-uted bullnbull-C$
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lt
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
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GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G LO BA L S CI E ~ ~ S
27 March 2012
JeffGagne
Eastern Analytical Inc
25 Cbenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
10
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
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FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
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FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
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GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011 bull
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
B-3621 Effluent Field Blank 1203055-01 Water 02-Mar-121100 05-Mar-12 0851
Final Effluent 1203055-02 Water 02-Mar-12 11 00 05-Mar-12 0851
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chai11 ofcustody docwnent This analytical report must be reproduced in its enJirety
Page 1 o17 1203055 Revised Report
03272012
1 1 Liz Siska Project Manager
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
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FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
bull
11720 North Creek Parkway North Suite 400 Bothe~ WA 980 ll
Ph 425-686-1996 Fx 425-686-3096
G L O 13 A l middot S C I E N C E S middot
CASE NARRATIVE
Revised Report 03262012- Client requested Pb be added to the work order
SAMPLE RECEIPT
Samples were received at Frontiec Global Sciences (FGS) on March 15th 2012 The samples were received intact on-ice with temperatures measured at 132 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 1631E
ANALYTICAL ISSUES
The Zn result for Effluent Field Blank ( 1203055-0 I) was greater than the MRL the sample was re-digested and re-analyzed for coofinnation
As an additional measure ofthe accuracy of the methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measme ofthe precision of the analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section of the following report
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcwrody document This analylical report must be reproductd in its enrlritty
Liz Siska Project Manager
Page2ofl7 12030SS ampvised ampport
03272012
12
Chain of Custqdy Recqrd amp ~ltmiddotbor~tory Analysl~ Request 411 Pontius Ave N Seittle WA 98109 Air Water Sediments PIZ3ntand Animal 11ssue Phone 206622~6960
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Sample Disposal By signing YoU dcciarc that you agr~ wil f-GS terms and ogtnltlitfOns ard that o Return (shippin(l iees may apply) you outJorlze FGS to perform ttie specified analyses p Standard Disposal - 30 bays after report bull middot middot middot O Retain for __ weeks after report (storage fuesmay apply) Customer Approli~I ~-o Date iJz1-gt
FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
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FRONTIER
11720 North Creek Parkway North Suit~ 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCl~~CES
CHAIN OF CUSTODY FORMS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirery
Liz Siska Project Manager
Page3of17 1203055 Revised Report
031272012
13
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
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BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
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PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
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S ambullbull to on oontolner metchCOC Correct bullbullmJbull eontalners u sed fol ueatbulld bullnart-bullbull Samnfbullbull recetvampd wllhln hoJdJnn tlmbull Samole volumbull bullufflclbullnt for re~uted anehfaIbull Con-ct o-vbullWbull ubulled ~or ro-uted bullnbull-C$
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lt
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GL08 td SC IENCE S
CHAIN OF CUSTOPY FORMS
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustodydocu=nt This analytical report must be reproduced in its enlinty
Page1of7 1203055 Revised Report
OJ2712012
14 Liz Siska Project Manager
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
I
11720 North Creek Parkway North Suite 400 ~Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOSAL SCIENCES
ANALYTICAL RESULTS
B-3621 Effluent Field Blank
Matrix Water Laboratory ID 1203055-01
Aoalyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic ND 005 015 microgL F203108 2CI2010 030912 EPA 2008 Mod u Cadmium ND 0004 0020 microgL l F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 0009 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Copper ND OQl 010 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 13 100 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Lead ND 0004 0040 microgL 1 F203108 2Cl2010 030912 EPA 2008 Mod u Mercury ND 008 050 ngL 1 F203099 2C08017 030812 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F203108 2CI2010 030912 EPA 2008 Mod u Nickel ND 0008 010 microgL l F203108 2Cl2010 030912 EPA 2008 Mod u Selenium ND 019 060 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Silver ND 0006 0020 microgL F203108 2Cl2010 030912 EPA 2008 Mod u Zinc 050 002 020 microgL F203108 2CI2010 030912 EPA2008Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 5 of17 1203055 Revised Report
031272012
15
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
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HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
g ~ ~ s- 0 i ~ ~f~- ~
~-~~ deg ~ bi 2 aQ
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
~ 11720 North Creek Parkway North Suite 400 Bothell WA 98011
I Ph 425-686-1996 Fx 425-686-3096
CLO B AL SCIENCESij ~ 1
ANALYTICAL RESULTS iol or~ 71~JFinal Effluent --shy
Matrix Water Laboratory ID 1203055-Q2
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 812 102 300 microgL 20 F203108 2Cl20 IO 030912 EPA2008 Mod
Cadmiwn ND 0083 0400 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod QM-12 U
Chromium ND 018 200 microgL 20 F203I08 2CI2010 030912 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod u Iron ND 260 200 microgL 20 F203108 2C120IO 030912 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203108 2CI20l0 030912 EPA 2008 Mod u Mercury 172 083 500 ngL 10 F203099 2C08017 030812 EPA l631E
Molybdenum 419 012 120 microgL 20 F203108 2Cl20IO 030912 EPA 2008 Mod
Nickel 291 016 200 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Selenium 109 388 120 microgL 20 F203108 2Cl2010 030912 EPA 2008 Mod
Silver ND 0120 0400 microgL 20 F203108 2Cl20I0 030912 EPA 2008 Mod u Zinc ND 033 400 microgL 20 F203108 2Cl2010 030912 EPA2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with 1he chain ofcustody document This analytical report musl be rtproduad In Its enlfrety
Liz Siska Project Manager
Page 6017 1203055 Revisedampport
031272012
16
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
DATeT1Memiddot w
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IF COMPOSITE w 0 ~ u
SAMPLE tD IN01CATE BorH -~ ~middot-START amp FINISH
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PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
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5~-shy i~~w 0~ -~l= ~ - bull =ii s ~ ~amp t
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
GLOBA L SCIEN C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203016-05
Batch F203099
Preparation BrCl Oxidation
Sequence 2C08017
Lab Number F203099-DUP1
Sample Duplicate Concentration Concentration Oo RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 248 244 l01 148 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its errtirety
Liz Siska Project Manager
Page 7 of17 1203055 Revised Report
03272012
17
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
DATeT1Memiddot w
D w I
IF COMPOSITE w 0 ~ u
SAMPLE tD IN01CATE BorH -~ ~middot-START amp FINISH
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DATETIME I )
1100 A (~
uoo ~eG
HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
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i
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CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
FRONTIER p L 0 B A L S C I EN C E S
11720 North Creek Parkway North Suite 400 Bothell WA 980 II
Ph 425-686-1996 Fx 425-686-3096
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203014-01
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-MSMSDl
Analyte
Sample Concentration
(ngL)
Spike Added (ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits
71 - 125
Method
EPA 1631E
Notes
Mercury 738 25500 3234 979
Analyte
Spike Added (ngL)
MSD Concentration
(ngL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit
24
Method
EPA 1631E
Notes
Mercury 25500 3244 983 0314 71 - 125
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed fn accordance with che chain ofcus1ody doc~nt This analytical rtporl must be reprodulaquod In Its entirety
Page8ofl7 J203055 Revised Report
0312712012
18 Liz Siska Project Manager
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
DATeT1Memiddot w
D w I
IF COMPOSITE w 0 ~ u
SAMPLE tD IN01CATE BorH -~ ~middot-START amp FINISH
a ~ ltt tt
DATETIME I )
1100 A (~
uoo ~eG
HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
g ~ ~ s- 0 i ~ ~f~- ~
~-~~ deg ~ bi 2 aQ
~~ ~~ i
middot X I I
rl
~
~ lt)~
~ ~o ~
lil --
~
c
= = ~ Q i
~z ~~
I I I
11CP-CS
sect ] bullbull ~ 0
~i ~ i g ~ ~ - ~ ~ deg 00 - t ~ -~ bull
pound ~~ Ii ~ 2 - g~ ~
5~-shy i~~w 0~ -~l= ~ - bull =ii s ~ ~amp t
i
I IXI I IXIXIXIgtlt
f 51tk
lj ~ e 5 i5 -I a
me I~ S ~2 0 iii i = o~~isect~5 ~ ~ ~ sect~3g~i
cac- ~ ~- ~c
l
j I NOTES MEOH V1u II_
I
ltXgt
CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
~
11720 North Creek Parkway North Suite 400 Bothell WA 98011 middotmiddot
Ph 425-686-1996 Fx 425-686-3096
G LO BAL SC IE NC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203055-02
Batch F203099
Preparation BrCI Oxidation
Sequence 2C08017
Lab Number F203099-MSMSD2
Sample Spike MS MS Concentration Added Concentration oo Recovery
Analyte (ngL) ngL) (ngL) Recovery Method Notes Limits
Mercury 1716 45450 6367 102 71-125 EPA 1631E
Spike MSD MSD Recovery Added Concentration RPD
RPD Limits Limit Method Notes (ngL) (ogL) Recovery Analyte
Mercury 45450 6191 984 281 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of17 1203055 Revised Report
032712012
19Liz Siska Project Manager
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
DATeT1Memiddot w
D w I
IF COMPOSITE w 0 ~ u
SAMPLE tD IN01CATE BorH -~ ~middot-START amp FINISH
a ~ ltt tt
DATETIME I )
1100 A (~
uoo ~eG
HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
g ~ ~ s- 0 i ~ ~f~- ~
~-~~ deg ~ bi 2 aQ
~~ ~~ i
middot X I I
rl
~
~ lt)~
~ ~o ~
lil --
~
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pound ~~ Ii ~ 2 - g~ ~
5~-shy i~~w 0~ -~l= ~ - bull =ii s ~ ~amp t
i
I IXI I IXIXIXIgtlt
f 51tk
lj ~ e 5 i5 -I a
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l
j I NOTES MEOH V1u II_
I
ltXgt
CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203016-01
Batch F203099 Seqnence 2C08017
Preparation BrCl Oxidation Lab Number F203099-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ngL) Recovery Method NotesLimits
Mercwy 1964 51000 7079 100 71 - 125 EPA I631E
Spike MSD MSD Recovery RPD Added Concentration Oo
RPD Limits Limit Method Notes (ogL) (ngL) Recovery Analyte
Mercury 51000 7243 104 230 71 - 125 24 EPA I631E
Frontier Global Sciences Inc The results In this report only apply to the samples analyred in accordance with the chain ofcustody document This analytical report must be reproduced In tu entirety
Page IO of17 I203055 Revised Report
032712012
20 Liz Siska Project Manager
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
DATeT1Memiddot w
D w I
IF COMPOSITE w 0 ~ u
SAMPLE tD IN01CATE BorH -~ ~middot-START amp FINISH
a ~ ltt tt
DATETIME I )
1100 A (~
uoo ~eG
HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
g ~ ~ s- 0 i ~ ~f~- ~
~-~~ deg ~ bi 2 aQ
~~ ~~ i
middot X I I
rl
~
~ lt)~
~ ~o ~
lil --
~
c
= = ~ Q i
~z ~~
I I I
11CP-CS
sect ] bullbull ~ 0
~i ~ i g ~ ~ - ~ ~ deg 00 - t ~ -~ bull
pound ~~ Ii ~ 2 - g~ ~
5~-shy i~~w 0~ -~l= ~ - bull =ii s ~ ~amp t
i
I IXI I IXIXIXIgtlt
f 51tk
lj ~ e 5 i5 -I a
me I~ S ~2 0 iii i = o~~isect~5 ~ ~ ~ sect~3g~i
cac- ~ ~- ~c
l
j I NOTES MEOH V1u II_
I
ltXgt
CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
bull I 1720 North Creek Parkway North Suite 4~
~Bothell WA 98011 Ph 425-686-1996 ~ ~ Fx 425-686-3096 9
GLOBAL SClENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203l08 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203108-MSMSD1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 70700 778 106 70 - 130 EPA 2008 Mod
Iron ND 50500 5224 103 70 - 130 EPA 2008 Mod
Nickel 2914 40400 3061 366 70-130 EPA 2008 Mod QM-02
Copper 041 40400 4 22 942 70 - 130 EPA 2008 Mod
Zinc 275 10100 1893 160 70 - 130 EPA 2008 Mod QM-07
Arsenic 812 15150 2550 115 70 - 130 EPA 2008 Mod
Selenium 1093 30300 1369 912 70 - 130 EPA 2008 Mod
Molybdenum 4186 20200 4165 -105 70 - 130 EPA 2008 Mod QM-02
Silver ND 15150 1450 957 70 - 130 EPA 2008 Mod
Cadmium 0379 080800 l335 118 70-130 EPA2008Mod
Lead ND 15150 1636 108 70- 130 EPA 2008 Mod
Analyte
Chromium
Spike Added (microgL)
70700
MSD Concentration
(microgL)
764
MSD
Recovery
104
RPD
178
Recovery Limits
70- 130
RPDLimit
20
Method
EPA 2008 Mod
Notes
Iron 50500 521l 103 0257 70 - 130 20 EPA 2008 Mod
Nickel 40400 3286 921 707 70 - 130 20 EPA 2008 Mod QM-02
Copper 40400 431 966 226 70 - 130 20 EPA 2008 Mod
Zinc 10100 1107 824 524 70 - 130 20 EPA 2008 Mod QM-07 QR-08
Arsenic 151 50 2503 112 187 70- 130 20 EPA 2008 Mod
Selenium 30300 1341 820 207 70 - 130 20 EPA 2008 Mod
Molybdenum 20200 4168 -893 00753 70 -130 20 EPA2008 Mod QM-02
Silver 15150 1361 898 634 70 - 130 20 EPA 2008 Mod
Cadmium 080800 l278 111 434 70 - 130 20 EPA 2008 Mod
Lead 15150 l487 982 953 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anaped in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 11 of17 1203055 Revised Report
032712012
21
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
DATeT1Memiddot w
D w I
IF COMPOSITE w 0 ~ u
SAMPLE tD IN01CATE BorH -~ ~middot-START amp FINISH
a ~ ltt tt
DATETIME I )
1100 A (~
uoo ~eG
HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
g ~ ~ s- 0 i ~ ~f~- ~
~-~~ deg ~ bi 2 aQ
~~ ~~ i
middot X I I
rl
~
~ lt)~
~ ~o ~
lil --
~
c
= = ~ Q i
~z ~~
I I I
11CP-CS
sect ] bullbull ~ 0
~i ~ i g ~ ~ - ~ ~ deg 00 - t ~ -~ bull
pound ~~ Ii ~ 2 - g~ ~
5~-shy i~~w 0~ -~l= ~ - bull =ii s ~ ~amp t
i
I IXI I IXIXIXIgtlt
f 51tk
lj ~ e 5 i5 -I a
me I~ S ~2 0 iii i = o~~isect~5 ~ ~ ~ sect~3g~i
cac- ~ ~- ~c
l
j I NOTES MEOH V1u II_
I
ltXgt
CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
~
tbull middot lt11
bull 11720 North Creek Parkway North Suite 400 J Bothell WA 98011
Ph 425-686-1996bull Fx 425-686-3096 GL(BALmiddot SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203055-02
Batch F203108 Sequence 2C12010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20308-MSMSD2
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Chromium 031 40400 4252 105 70 - 130 EPA 2008 Mod AS Iron ND 20200 2097 104 70 - 130 EPA 2008 Mod AS Nickel 2914 50500 5308 993 70 - 130 EPA 2008 Mod AS Copper 041 50500 4659 922 70- 130 EPA 2008 Mod AS Zinc 275 10100 8983 887 70 - 130 EPA 2008 Mod AS Arsenic 812 40400 4294 104 70 - 130 EPA 2008 Mod AS Selenium 1093 40400 5346 105 70- 130 EPA 2008 Mod AS Molybdeoum 4186 20200 6234 IOI 70- 130 EPA 2008 Mod AS Silver ND 20200 1802 892 70 - 130 EPA 2008 Mod AS Cadmium 0379 40400 3746 918 70 - 130 EPA 2008 Mod AS Lead ND 10100 9825 973 70 - 130 EPA 2008 Mod AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Chromium 40400 4252 105 000134 70- 130 20 EPA 2008 Mod AS Iron 20200 2093 104 0171 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5313 994 00878 70 - 130 20 EPA2008Mod AS Copper 50500 4694 929 0751 70 - 130 20 EPA 2008 Mod AS Zinc 10100 8988 887 00641 70- 130 20 EPA 2008 Mod AS Arsenic 40400 4392 107 227 70 - 130 20 EPA2008Mod AS Selenium 40400 4977 961 714 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 616l 978 118 70 - 130 20 EPA 2008 Mod AS Silver 20200 1784 883 101 70 - 130 20 EPA2008 Mod AS Cadmium 40400 3727 913 0512 70- 130 20 EPA 2008 Mod AS Lead 10100 9844 975 0193 70 130 20 EPA 2008 Mod AS shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the cha11 ofcustody document This analytical rtport must be reproduced In Its tnrety
Page l]of7 J203055 Revised Report
031272012
22 Liz Siska Project Manager
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
DATeT1Memiddot w
D w I
IF COMPOSITE w 0 ~ u
SAMPLE tD IN01CATE BorH -~ ~middot-START amp FINISH
a ~ ltt tt
DATETIME I )
1100 A (~
uoo ~eG
HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
g ~ ~ s- 0 i ~ ~f~- ~
~-~~ deg ~ bi 2 aQ
~~ ~~ i
middot X I I
rl
~
~ lt)~
~ ~o ~
lil --
~
c
= = ~ Q i
~z ~~
I I I
11CP-CS
sect ] bullbull ~ 0
~i ~ i g ~ ~ - ~ ~ deg 00 - t ~ -~ bull
pound ~~ Ii ~ 2 - g~ ~
5~-shy i~~w 0~ -~l= ~ - bull =ii s ~ ~amp t
i
I IXI I IXIXIXIgtlt
f 51tk
lj ~ e 5 i5 -I a
me I~ S ~2 0 iii i = o~~isect~5 ~ ~ ~ sect~3g~i
cac- ~ ~- ~c
l
j I NOTES MEOH V1u II_
I
ltXgt
CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
bull 11720 North Creek Parkway North Suite419
Bothell WA 98011 Ph 425-686-1996 middotFx 425-686-3096
GLOBAL SCIENCES
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203099 Sequence 2C08017
Preparation BrCI Oxidation Lab Number F203099-BSBSD1
LCS Source LCS
Spike LCS middot LCS Added Concentration Oo Recovery
Analyte (ogL) (ngL) Recovery Limits Method Notes
Mercury 15679 1562 996 80 - 120 EPA I631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (agL) Recovery RPD Limits Limit Method Notes
Mercury 15679 1574 100 0806 80 - 120 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain of custody document This analytical report must be reproduced in its entirery
Liz Siska Project Manager
Page 13 o17 I203055 Revised Report
03272012
23
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
DATeT1Memiddot w
D w I
IF COMPOSITE w 0 ~ u
SAMPLE tD IN01CATE BorH -~ ~middot-START amp FINISH
a ~ ltt tt
DATETIME I )
1100 A (~
uoo ~eG
HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
g ~ ~ s- 0 i ~ ~f~- ~
~-~~ deg ~ bi 2 aQ
~~ ~~ i
middot X I I
rl
~
~ lt)~
~ ~o ~
lil --
~
c
= = ~ Q i
~z ~~
I I I
11CP-CS
sect ] bullbull ~ 0
~i ~ i g ~ ~ - ~ ~ deg 00 - t ~ -~ bull
pound ~~ Ii ~ 2 - g~ ~
5~-shy i~~w 0~ -~l= ~ - bull =ii s ~ ~amp t
i
I IXI I IXIXIXIgtlt
f 51tk
lj ~ e 5 i5 -I a
me I~ S ~2 0 iii i = o~~isect~5 ~ ~ ~ sect~3g~i
cac- ~ ~- ~c
l
j I NOTES MEOH V1u II_
I
ltXgt
CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
~
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
t G l OBAt SCIENCES
~
shy
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203108 Sequence 2Cl20I0
Preparation Closed Vessel Nitric Oven Dig~io11 Lab Number F203108-BSBSD I
LCS Source Blank S12ike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (pgL) Recovery Limits Method Notes
Chromium 70000 667 953 85 - 115 EPA 2008 Mod
Iron 50000 4689 938 85 - 115 EPA 2008 Mod
Nickel 40000 407 middot102 85 - 115 EPA2008 Mod
Copper 40000 422 106 85 - ll5 EPA 2008 Mod
Zinc 10000 1042 104 85-115 EPA2008Mod
Arsenic 15000 1444 963 85- ll5 EPA2008Mod
Selenium 30000 2984 995 85-115 EPA2008Mod
Molybdenum 20000 l80 900 85 - 115 EPA2008 Mod
Silver 15000 1476 984 85 - 115 EPA2008 Mod
Cadmium 080000 0918 115 85 - 115 EPA 2008 Mod
Lead l5000 l542 103 85 - 115 EPA 2008 Mod
~
Frontier Globa~ Sciences Inc The results in this report ~11y apply to the samples analyzed in accor~nce with rhe chain ofcustody document This analytical report must be reproduced In Is entirety
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Chromium 70000 657 939 148 85 - 115 20 EPA 2008 Mod
Iron 50000 4652 930 0801 85 - 115 20 EPA2008 Mod
Nickel 40000 400 999 186 85 - 115 20 EPA 2008 Mod
Copper 40000 417 104 117 85 - 115 20 EPA 2008 Mod
Zinc 10000 1017 102 238 85 - 115 20 EPA 2008 Mod
Arsenic 15000 1425 950 137 85 - 115 20 EPA 2008 Mod
Selenium 30000 3040 101 184 85 - 115 20 EPA2008 Mod
MolybdeollIIl 20000 178 888 140 85 - 115 20 EPA 2008 Mod
Silver l5000 l458 972 126 85 - 115 20 EPA 2008 Mod
Cadmium 080000 0933 117 156 85 - ll5 20 EPA 2008 Mod QM-12 Lead 15000 1522 101 131 85 - 115 20 EPA 2008 Mod
PageU o17 I203055 Revised Report
031272012
24 Liz Sisk~ Project Manager
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
DATeT1Memiddot w
D w I
IF COMPOSITE w 0 ~ u
SAMPLE tD IN01CATE BorH -~ ~middot-START amp FINISH
a ~ ltt tt
DATETIME I )
1100 A (~
uoo ~eG
HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
g ~ ~ s- 0 i ~ ~f~- ~
~-~~ deg ~ bi 2 aQ
~~ ~~ i
middot X I I
rl
~
~ lt)~
~ ~o ~
lil --
~
c
= = ~ Q i
~z ~~
I I I
11CP-CS
sect ] bullbull ~ 0
~i ~ i g ~ ~ - ~ ~ deg 00 - t ~ -~ bull
pound ~~ Ii ~ 2 - g~ ~
5~-shy i~~w 0~ -~l= ~ - bull =ii s ~ ~amp t
i
I IXI I IXIXIXIgtlt
f 51tk
lj ~ e 5 i5 -I a
me I~ S ~2 0 iii i = o~~isect~5 ~ ~ ~ sect~3g~i
cac- ~ ~- ~c
l
j I NOTES MEOH V1u II_
I
ltXgt
CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
11720 North Creek Parkway North Suite 4~ Bothell WA 98011 - ~ Ph 425-686-1996
Fx 425-686-3096 GLOBAL SCIErICES
PREPARATION BLANKS
Instrument ICPMS-3 Sequence
Preparation
2C08017
BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203099~BLK1 Mercury 0003 050 ngL F203099 EPA I63lE u F20 3099-BLK2 Mercury 0009 050 ngL F203099 EPA 1631E u F203099-BLK3 Mercury 005 050 ngL F203099 EPA 163IE u F203099-BLK4 Mercury OQ3 050 ngL F203099 EPA 163lE QB-04 U
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 15 o17 1203055 Revised Report
03272012
25
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
DATeT1Memiddot w
D w I
IF COMPOSITE w 0 ~ u
SAMPLE tD IN01CATE BorH -~ ~middot-START amp FINISH
a ~ ltt tt
DATETIME I )
1100 A (~
uoo ~eG
HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
g ~ ~ s- 0 i ~ ~f~- ~
~-~~ deg ~ bi 2 aQ
~~ ~~ i
middot X I I
rl
~
~ lt)~
~ ~o ~
lil --
~
c
= = ~ Q i
~z ~~
I I I
11CP-CS
sect ] bullbull ~ 0
~i ~ i g ~ ~ - ~ ~ deg 00 - t ~ -~ bull
pound ~~ Ii ~ 2 - g~ ~
5~-shy i~~w 0~ -~l= ~ - bull =ii s ~ ~amp t
i
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j I NOTES MEOH V1u II_
I
ltXgt
CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
11720 North Creek Parkway North Suite 400 Bothell WA 980II
Ph 425-686-1996 fx 425-686-3096
G LO 8 AL SC I ENCE S
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2Cl2010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203108-BLKI Chromium -001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Iron -01 100 microgL F203108 PA 2008 Moc u F203108-BLKI Nickel 001 010 microgL F203108 PA 2008 Moc u F203108-BLK1 Copper 0008 010 microgL F203108 PA 2008 Moc u F203108-BLKI Zinc 008 020 microgL F203108 PA 2008 Moc u F203108-BLK1 Arsenic -006 015 microgL F203108 PA 2008 Moc u F203108-BLK1 Seleniwn 003 060 microgL F203108 PA 2008 Moc u F203108-BLK1 Molybdenum 0007 006 microgL F203108 PA 2008 Moc u F203 l 08-BLKl Silver -0003 0020 microgL F203I08 PA 2008 Moc u F203108-BLKI Cadmiwn -00003 0020 microgL F203108 PA 2008 Moc u F203108-BLKI Lead 0005 0040 microgL F203108 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples ana61Zed in accordance with th$ drain ofcustody document This analytical report must~ reprodJad In Its entirety
Page 16of17 J203055 RevisedReport
OJ2712012
26 Liz Siska Project Manager
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
DATeT1Memiddot w
D w I
IF COMPOSITE w 0 ~ u
SAMPLE tD IN01CATE BorH -~ ~middot-START amp FINISH
a ~ ltt tt
DATETIME I )
1100 A (~
uoo ~eG
HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
g ~ ~ s- 0 i ~ ~f~- ~
~-~~ deg ~ bi 2 aQ
~~ ~~ i
middot X I I
rl
~
~ lt)~
~ ~o ~
lil --
~
c
= = ~ Q i
~z ~~
I I I
11CP-CS
sect ] bullbull ~ 0
~i ~ i g ~ ~ - ~ ~ deg 00 - t ~ -~ bull
pound ~~ Ii ~ 2 - g~ ~
5~-shy i~~w 0~ -~l= ~ - bull =ii s ~ ~amp t
i
I IXI I IXIXIXIgtlt
f 51tk
lj ~ e 5 i5 -I a
me I~ S ~2 0 iii i = o~~isect~5 ~ ~ ~ sect~3g~i
cac- ~ ~- ~c
l
j I NOTES MEOH V1u II_
I
ltXgt
CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
11720 North Creek Parkway North Suite~ Bothell WA98011 -
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPO value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-04 The blank was preserved to 2 BrCI rather than 1 The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS Tllis MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproducedin its entirety
Liz Siska Project Manager
Pagel7ofl7 203055 Revised Report
03272012
27
w I shy
SAMPLING g 0
DATeT1Memiddot w
D w I
IF COMPOSITE w 0 ~ u
SAMPLE tD IN01CATE BorH -~ ~middot-START amp FINISH
a ~ ltt tt
DATETIME I )
1100 A (~
uoo ~eG
HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
g ~ ~ s- 0 i ~ ~f~- ~
~-~~ deg ~ bi 2 aQ
~~ ~~ i
middot X I I
rl
~
~ lt)~
~ ~o ~
lil --
~
c
= = ~ Q i
~z ~~
I I I
11CP-CS
sect ] bullbull ~ 0
~i ~ i g ~ ~ - ~ ~ deg 00 - t ~ -~ bull
pound ~~ Ii ~ 2 - g~ ~
5~-shy i~~w 0~ -~l= ~ - bull =ii s ~ ~amp t
i
I IXI I IXIXIXIgtlt
f 51tk
lj ~ e 5 i5 -I a
me I~ S ~2 0 iii i = o~~isect~5 ~ ~ ~ sect~3g~i
cac- ~ ~- ~c
l
j I NOTES MEOH V1u II_
I
ltXgt
CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy
w I shy
SAMPLING g 0
DATeT1Memiddot w
D w I
IF COMPOSITE w 0 ~ u
SAMPLE tD IN01CATE BorH -~ ~middot-START amp FINISH
a ~ ltt tt
DATETIME I )
1100 A (~
uoo ~eG
HATRIX A-Al~ S-SOIL GW-GROUHD WATER swsumCI WATER DWORINKING WATER WW-WAm WATER
PmERVATIYE H-HCL N-HN01 HLtOi Na-NaOH H-HEOH
g ~ ~ s- 0 i ~ ~f~- ~
~-~~ deg ~ bi 2 aQ
~~ ~~ i
middot X I I
rl
~
~ lt)~
~ ~o ~
lil --
~
c
= = ~ Q i
~z ~~
I I I
11CP-CS
sect ] bullbull ~ 0
~i ~ i g ~ ~ - ~ ~ deg 00 - t ~ -~ bull
pound ~~ Ii ~ 2 - g~ ~
5~-shy i~~w 0~ -~l= ~ - bull =ii s ~ ~amp t
i
I IXI I IXIXIXIgtlt
f 51tk
lj ~ e 5 i5 -I a
me I~ S ~2 0 iii i = o~~isect~5 ~ ~ ~ sect~3g~i
cac- ~ ~- ~c
l
j I NOTES MEOH V1u II_
I
ltXgt
CHAIN-OF-CUSTODY RECORD Page I of f 108078 J
BOLO FIELDS REQUIRED PLEASE CIRCLE REQUESTED ANALYSIS
PROJECT MANAGER Po 1 I Yci er DATE NEEDED METALS 8 RCRA 13 PP FE HH PB cu r-11_ r - r TENr 21 C feHsflSl-f CJCrCvAli
1 1(OMPAN2V ~ l)cecllvw1MtrtCL QAQC REPORTING OPTIONS J(E1 No OTHU METALS MofAj~c I -r Aooam gtpoundl +aryo 7 yJ REPORTING LEVEL PAELtHS YES Ol No CITY MoruLe~+cr STATE rll- ZIP oJtoJ A B C IFYES fu 01 PDF DtSSOLYEDMmu ftEUgtf1mm1 Yu No
PHONE l j ~ middot81 f Exr HomIESPECIALDETECTION LIIIITS BILLJHG INFO If DlffEREIIT)6ltYt~ f(6 2 OR ELECTRONIC OPTIONS 5middot 1 bull
FAX No FAX E-HAJL PDF EQUIS ~ 411 +-act Md__ i f( C E-MAIL pa1fJ~yer-e0-ctCQM p-iJ rM~ttmiddotSr11c~-fimiddot~ microtf(l1Sf)nr
SITE MAHE tJa skwe3ec -A1ciLrslaquo$ -d(7
PlOJECT i ( I O - _ A 1 1 ~ -T VS 11Ml )t(ilUlt gt bull (T(I
Smr ) MA ME VT OrHER T _ bull o 1 1 1IHE h_tvo-i -+middot ~-1 Nmiddot~-roU middot REGULATORY PROGRAM NPDES RGP POTW STOAHWAm OR
GWP Oil fUND BROWNFIELD OR 0TlER -------- - SITE H1noRY ___-------- shyRELINQUISHED BY DATE TIHE RECEIVED BT QUOTE PO_ ______ _ SUSfpoundCTED CoHTAKIHATIOH degV()I- J151i-i r~I I RELINQUISHED 8Y DATE TIME RmlVfD BY I ftHO READINGS
tJULA easter~ analytical_ inc 2s CH~Niu DRvE ICoNcoRo NH 03301 I TeL 603228052511soo2a1os2s I FAx 6032284591 I E-MAIL cusroMeR_se11v1ceeA1LAsscoMI wwweA1LAascoM
profimo11nllnbomtoryurvw (WHITE ORIGINAL GREEN PROJECT MANAGER)
-i bull middotmiddot ~i -~middot
shy