pace analy*cal services ku resources - nawt sampler & run a manual sample 6. ... volatiles epa...
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PaceAnaly*calServicesKUResources
WasteWaterSampling Itinerary! TypesofSamplingEquipment! Composite&GrabSampling! AutoSamplerSetUp! Bottles,Labels,COC�s,HoldTimes! ContaminationIssues! VirtualLabTour
SamplingEquipmentISCOAutosamplerSubmersiblePumpBucketsSamplingPolesCrowbars
SamplingEquipmentEquipmentRentalCompanies
WasteWaterCompositeSampling
SetupProcedures1.Checkinwithplantcontact/safetypersonnel2.ReviewPermit(grab,composite,timeorflow)3.Readflowmetersandrecordreadings4.Determinedurationofcomposite
WasteWaterCompositeSampling
SetupTimeComposite1.Placesamplernearsamplingpoint2.Runnewtubingfromsamplingpointtosampler3.Determinetimebetweenaliquots4.Determineneedvolumeperaliquots>makesureyouhaveenoughvolumebutdonotexceedcontainer<
5.Programsampler&runamanualsample6.Icedowncompositesamplercontainer7.Startsamplerandrecordfieldnotes
WasteWaterCompositeSampling
SetupFlowComposite1.Determinesamplerpacingvolume2.Determineapprox24hrflowvolume3.Calculatevolumeofcompositesampleneeded4.Programsamplerforflowproportional5.Runamanualsample6.Icedownthecompositesamplercontainer7.Startsamplerandrecordfieldnotes
WasteWaterCompositeSampling
CollectionCompositeSample1.Haltsamplingandremovesamplercontainer2.Stirthecontainertoensureuniformity3.Filloutbottlelabels4.Fillallbottlesanddonotoverflow5.RecordFilednotes6.Placesamplesincoolerandicedown7.Completechainofcustody
WasteWaterCompositeSampling
CollectionGrabSample1.Samplingequipmentwilldependonaccessibility2.Samplebottle,bailerorISCOmaybeused3.Allequipmentshouldbecleanandappropriate
forlaboratoryanalyses4.Recordfielddata,labelbottles,completechain
ofcustodyandicedownsamplesincooler
WasteWaterCompositeSampling
CleaningEquipment1.CleansamplingequipmentwithAlconoxor
equivalent2.Rinsewithtapwater3.RinseagainwithDIwater4.Allowtodryandreturntostorage
WasteWaterSamplingSendSamplestotheLaboratory1.PrepareBottleLabels2.FillOutChainofCustody3.PackShippingCooler
Analy6calSamplingGuideParameterMethod ContainerVolumePresHoldTimeAlkalinityEPA 301.1 P,G 250 ml 4 C 14 Days Metals EPA 200.7 P,G 500 ml HNO3 / 4 C 6 Months Volatiles EPA 624 40 ml vial 3 vials HCL / 4 C 14 Days BOD EPA 405.1 P,G 500 ml 4 C 48 Hours Bacteria SM 9223 P 100 ml Na2SO3 24 Hours
Sampling&Bo<leWare
ChainofCustody
CommonProblems! NotEnoughInformation! IncorrectInformation! UnreadableInformation! NoInformation! Labelinformationmustmatchchainofcustody
CHAIN-OF-CUSTODY / Analytical Request DocumentThe Chain-of-Custody is a LEGAL DOCUMENT. All relevant f ields must be completed accurately.
Section A Section B Section CRequired Client Information: Required Project Information: Invoice Information:
REGULATORY AGENCY
Phone: Fax:
Y/ N
DATE TIME DA T E TIME Unpre
serve
d H2
SO4
HNO3
HCI
NaOH
Na2S
2O3
Meth
anol
Othe
r
Ana
lysis
Test
Targe
t Com
poun
d VOC
- 826
0
Targe
t Ana
lyte M
etals -
6010
, 747
0
Targe
t Com
poun
d SVO
C - 82
70
Resid
ual C
hlorin
e (Y/N
)
1 SL G x x x
2 WT G x x x
3 WT G x
4 WT G x x x
5 WT G x x x
6
7
8
9
10
11
12
Requested Due Date/TAT:
Page: of
NPDES GROUND WATER DRINKING WATER
UST RCRA OTHER
Company:
Address:
Email To: Myemailaddress
4250 Route 6
Edinboro, PA 16412
ER&R Attention:
Company Name:
Address:
Report To:
Copy To:
PA
Your Name
P aceQuo teR eference:
Purchase Order No.:
DATEADDITIONAL COMMENTS RELINQUISHED BY / AFFILIATION TIME
Tim Reed Site Location
STATE:
DATE ACCEPTED BY / AFFILIATION
PRINT Name of SAMPLER:
SAMPLER NAME AND SIGNATURE
DATE Signed (MM/DD/YY):
SIGNATURE of SAMPLER:
South Groundwater SampleTrip Blank
Equipment Blank
SAMPLE ID (A-Z, 0-9 / ,-)
Sample IDs MUST BE UNIQUE SA
MPLE
TYPE
(G
=GRA
B C=
COMP
)
# OF
CONT
AINER
S
Preservatives
Rece
ived o
n Ice
(Y/N)
Temp
in °C
Custo
dy
Seale
d Coo
ler
(Y/N)
Samp
les In
tact
(Y/N)
SAMPLE CONDITIONS
ITEM
#
MAT
RIX CO
DE
South Core Sample
DR INK INGWATER WA TER WA S TE WA TER PR ODUC T S OIL/S OLID OILWIPE A IR OTHER T IS S UE
Valid Matrix Codes MA T R IX C OD E
Section D R e qu ire d C lientInfo rmation
DWWT WWP S LOLWPA R OT T S
Field Blank
TIME
SAMP
LE TE
MP AT
COLL
ECTIO
N
Requested Analysis Filtered (Y/N)
P aceP ro file# :
Pace Project No./ Lab I.D.
10 da y
COLLECTED
814 734-6411 Project Name:
Project Number:
ABC Site Assessment P aceP ro jec tManager:
COMPOSITE START
COMPOSITE END/GRAB
FieldContamina6onIssues! Subpartperbillionanalysis! SamplingEquipmentDecon! Gloves! Samplefromlowtohighcontamination! Contaminationbroughtonsite(sunscreen,tape,gasoline,WD40,etc)
! Ice! Marksuspectedcontaminationonfieldnotes
LaboratoryServices
SampleLogIn
> Unpack sample coolers > Take sample temperature > Review Chain of Custody with sample bottle labels > Log project into LIMS
Samplesareplacedincoldstorage
SamplePrepGroup
SamplePrepGroup
PrepareSamplesforVariousAnalyses! Digestions! Extractions! Leachates
DistributiontoAnalyticalGroups
MetalsGroup
Instrumenta6on! ICP(InductivelyCoupledPlasma)
! As,Ba,Cd,Cr,Cr,Pb,Se,Ag………! ICPMS(MassSpec)
! LowerDetectionLevels! MercuryAnalyzer! LowLevelMercuryAnalyzer! MethylMercuryAnalyzer! Otherlessusedinstruments–AA,GFAA
Vola6leOrganicsGroup
SemiVola6leOrganicsGroup
Instrumenta6on
! GC(GasChromatograph)! GCMS(MassSpec)! GCFID(FlameIonizationDetector)
WetChemistryGroup
Instrumenta6on
! IC(IonChromatography)–fluoride,bromide,chloride
! TOCAnalyzer(TotalOrganicCarbon)! TOXAnalyzer(TotalOrganicHalogens)! LachatAutomatedAnalyzer! Spectrophotometers(colormetricanalyses)
CommonCompoundLists
MetalsVolatiles
SemiVolatilesPesticides
PCBs
RCRA(8)Metals
TargetAnalyte(TAL)Metals
PriorityPollutant(PP)Vola6les
TargetCompound(TCL)VOC�s
PriorityPollutant(PP)SemiVola6les
TargetCompound(TCL)SemiVola6les
(TCL)SemiVola6lescont.
PolyAroma6cHydrocarbons(PAH)
TargetCompound(TCL)Pes6cides
TargetCompound(TCL)PCBs
Conclusions! FinalReportsarethesummationsofallsampleactivities:! FieldSampling! SampleReceiving! SamplePreparation! AnalyticalMethods! DataInterpretationandVerification