potassium - home | agronomy | kansas state university • absorbed by plant as k+ ion • unique...
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Potassium Management
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Potassium
• Absorbed by plant as K+ ion
• Unique nutrient - not a part of any plant compound - exists in plant sap
• Functions in plant– Activation of > 60 different enzymes– Role in photosynthesis and metabolism– Conversion of N to protein (high levels required for high
protein crops)– Reduces plant disease
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Nutrient Deficiency Symptoms• Alfalfa - slow growth, white or yellowish
spots around tips of older leaflets.
• Corn - slow growth, lower leaf tips and margins turn brown and fire, chaffy ears; plants die prematurely from stalk rot and leaf diseases.
• Small Grains - Slow growth, delayed maturity, shriveled grain, tendency to lodge.
• Soybeans - leaves turn yellow and later brown on the tips and edges; base of the leaf usually remains green; seeds are shriveled.
• Cotton - yellow spots between veins, browning of leaf margins, premature dropping of leaves.
Firing
Soybeans
Corn
Alfalfa
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K Deficiency Symptoms in Alfalfa
• Slow growth
• White or yellowish spots around tips of older leaflets
• Reduced winter hardiness
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K Deficiency Symptoms in Corn
• Slow growth
• Lower leaf tips and margins turn brown and fire
• Chaffy ears
• Plants die prematurely from stalk rot and disease.
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K Deficiency Symptoms in Soybean
• Leaves turn yellow and later brown on the tips edges
• Base of leaf usually remains green
• Shrived seeds
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Potassium Uptake
• Rapidly taken up in plants– Corn
• Uptake soon completed after silking• Moved from leaves and stalks as plant matures
– Soybean• Larger percentage of K is moved to grain by soybeans
compared to cereal crops• More K removed per pound of soybeans harvested in
comparison to these crops
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K+
K+
K+
K+
K+
K+
K+ K+
Soil Rocks
and
Minerals
Soil Colloid
Soil ColloidTrapped K+
Soil Colloid
K+K+
K+
K+K+
K+
K+
K+K+ K+
K+K+
K+
K+
(Exchangeable)
K+
K+
K+
K+
Soil Water
Forms of Soil Potassium
Unavailable 90-98% of Total
Slowly Available
Readily Available
(1-2 % of Total)
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Readily Available K
• Exchangeable plus solution forms
• Soil tests extract these forms
• K absorbed by plants in solution phase
• Equilibrium replenishes K+
ions in the soil water from exchangeable or slowly available forms
Soil Colloid
K+K+
K+K+
K+ K+
K+
K+K+
K+
K+
K+K+
K+
(Exchangeable)
K+
K+
K+
K+
Soil Water
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Unavailable K
• Mica, feldspar and clay minerals contain 90% to 98%
• Decompose releasing K+ ions
• Great Plains rich in K compared to eastern states with precipitation >30 inches
K+
K+
K+K+
K+
K+
K+
K+
Soil Rocks
and
Minerals
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Factors Affecting K Uptake By Plants
• Poor Soil Aeration– Oxygen required for root uptake– Ridge-till/No-till– Compaction
• Soil Moisture– Very dry– Very wet
• Soil Temperature– Cold
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K Uptake By Plants Affected By Soil Moisture
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Tillage Induced K Deficiency
• K availability can be less in reduced till systems (no-till, ridge till)
No-till (left) Conventional tillage (right)
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Potassium Stratification: Ridge-Till
• 24 consecutive years in ridge-till.• Localized high concentrations of K in inter-
rows of ridges.
300 310180 16080
80 88
30 in.30 in.
0
18Dep
th (i
n.)
Gordon, KSU
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Starter fertilizer effects on ridge-tilled corn, 2002-2003
TreatmentsN-P2O5-K2O-S
V6 Dry Weight
Days to Mid-Silk
Grain Yield
lb/acre lb/acre bu/acre0-0-0-0 208 82 16130-15-5-5 312 76 18930-15-15-5 395 72 19830-15-25-5 398 72 19730-15-0 290 76 18530-15-15-0 398 72 198
Soil Test K=150 ppm
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Atchison County, KansasJune 2004
Average K Test = 153 ppmMinimum K Test = 112 ppmMaximum K Test = 229 ppm
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Potassium Application Effects On Corn YieldK2O Rate Croplan 599 Croplan 678
Sig. Level
Lbs/A Yield Test Weight Yield Test Weight
0 125 56 199 6140 170 59 208 6180 189 58 204 61
120 179 59 203 620.01 0.01 NS 0.25
Atchison County, KansasJune 2004
Average K Test = 153 ppmMinimum K Test = 112 ppmMaximum K Test = 229 ppm
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Sample Point Good Bad Good Bad1 162 139 184 802 169 119 116 693 135 113 155 794 169 147 176 1015 137 175 143 926 155 134 193 1177 164 118 170 688 165 140 184 719 170 153 151 14410 143 127 153 6111 128 118 188 10612 130 113 161 23
Good and Bad Field Areas Yield/Soil Test ComparisonAtchison Co., 2004
Soil Test Exch. K Corn Yield
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Corn Response To Potassium Soil Test Atchison Co., KS - 2004
R2 = 0.3517
0
20
40
60
80
100
120
140
160
100 110 120 130 140 150 160 170 180Exch. K Soil Test (ppm)
Yiel
d (B
u/A
)
'Bad' Points
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Effect Of Surface Applied Potash On CornStu Duncan, 2005
K Corn TestRate Yield Wt.Lb K20/A Bu/A Lb/Bu
0 101.9 56.980 112.3 58.0
p > f 0.156 0.10
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Crop Removal
• K removal similar to N but > P
• More K in legumes than grasses
• Highest with forage/silage
• Easily leached from crop residue
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Crop Unit P2O5Alfalfa lbs/ton 12.00Red clover lbs/ton 12.00Bermudagrass lbs/ton 12.00Bromegrass lbs/ton 12.00Fescue, tall lbs/ton 12.00Corn lbs/bu 0.33Corn silage lbs/ton 3.20Grain sorghum lbs/bu 0.40Sorghum silage lbs/ton 3.20Wheat lbs/bu 0.50Sunflowers lbs/cwt 1.50Oats lbs/bu 0.25Soybeans lbs/bu 0.80Native grass lbs/ton 5.40
K2O60.0050.0040.0040.0040.000.268.700.268.700.300.600.201.4030.00
Potassium Removal By Crops
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Potassium Uptake Curve - Corn
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Fertilizer Sources of Potassium
• Reported as K2O or percent potassium oxide
• Found in salt beds beneath the earth’s surface
• Potash deposits occur in Canada, former Soviet Union and U.S. in states of NM and Utah
• Mining and solution mining
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K Mining• KCl exists in beds
below the surface– Carlsbad, NM, 600’
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K Mining
• K is granulated into different sizes for dry spreading or making liquids– White soluble is
most suited for liquid grades
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Potassium Chloride (KCl)
• Most commonly used source, sometimes called muriate of potassium
• Analysis range from 60% to 63% and 45% to 46% chloride
• Color ranges from deep red to pink to white
• Red potash made by grinding ore, suspended in water and skimmed off, iron adheres giving a red color
• White potash made by dissolving under a not brine under pressure, iron is removed
• White best source for making clear fertilizer solutions because colorless when dissolved
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–K-Mag or Sulfate of Potash-Magnesia
–22% K2O, 11% Mg, 22% S
Potassium-Magnesium Sulfate K2SO4-2MgSO4
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Other Sources
• Potassium Sulfate (K2SO4)
– Contains 50% K2O and 18% S
– Special Uses• Tobacco• Sulfur source
– Expensive
• Potassium Nitrate (KNO3)
– Saltpeter
– 44% K2O, 13% N
– Expensive
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Application of K Fertilizer
• Incorporate for most crops
• Topdressing effective on perennials
• Broadcast - when large amounts of K required– Unless soil has high fixing capacity
• Banding - ridge-till or no-till; soils with low subsoil K
• Starter - K is a salt so care must be taken when applied near seed
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Seed Placed Fertilizer• Effect of Row Spacing
– Higher rate of N + K2O can be applied on a per acre basis as the row spacing narrows.
• Crop Species Tolerance– Small Grains > Corn > Grain Sorghum – Soybeans, field beans and sunflowers are sensitive
and pop-up should not be used
• Soil Type and Environment– Maximum limit of salt should be reduced about 1/3
for dry soil and sandy-textured soil conditions– Slow growing conditions such as cool weather
increase the contact time of salt and seed
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Salt and Free Ammonia Levels of Different Fertilizer Products
• Salt Index of fertilizers is largely determined by N and K2O.
• Phosphate contributes very little
• Boron is highly toxic
• Ammonium thiosulfate (12-0-0-26S) may cause problems
• Free ammonia– Urea– UAN
• All liquid and dry fertilizers including “premium grade” clear liquids are comparable in their ability to cause salt damage
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Salt Index - N + K2O
Pounds N +K2O* (No urea or UAN)
Row Spacing in Inches Medium to Fine Textured Soils
Sandy or Dry Soils
40 6 4 30 8 6 20 12 8 15 16 11 12 20 14 10 24 17 6-8 30 21
Suggested Maximum Rates of Fertilizer to be Applied Directly With Seed
(Corn and Small Grains)
Reduce salt rates 30% for grain sorghum.
No seed-placed fertilizer is recommended for soybeans, sunflowers, field beans, or sugar beets.
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Potassium Management
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Potassium Application Effects On Corn YieldK2O Rate Hybrid A Hybrid B
Sig. Level
Lbs/A Yield Test Weight Yield Test Weight
0 125 56 199 61
40 170 59 208 61
80 189 58 204 61
120 179 59 203 62
0.01 0.01 NS 0.25
Atchison County, KansasJune 2004
Average K Test = 153 ppmMinimum K Test = 112 ppmMaximum K Test = 229 ppm
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FieldLocation Yield K ppm Yield K ppm
1 80 139 184 1622 69 119 116 1693 79 113 155 1354 101 147 176 1695 92 175 143 1376 117 134 193 1557 68 118 170 1648 71 140 184 1659 144 153 151 17010 61 127 153 14311 106 118 188 12812 23 113 161 130
Bad' Area Good' Area
Potassium Comparisons - Atchison Co., 2004
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Corn Response To Potassium Atchison Co., KS - 2004
y = -6E-05x2 + 0.022x - 1.3573R2 = 0.3015
0%
20%
40%
60%
80%
100%
100 120 140 160 180Yield Sufficiency (%)
Exch
. K S
oil T
est (
ppm
)
K Suf
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Slowly Available K• K+ ions are trapped or
fixed between clay layers so become unavailable to plant roots
• Equilibrium with available forms of K and slowly escape
• Provides a reservoir of K which continually resupplies available form
Soil Colloid
Soil Colloid
Trapped K+
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K+K+
K+
K+
K+
Soil Water
Soil Colloid
Soil Colloid
Trapped K+
Fixation of K+
K+ From Fertilizer Fixation
Release