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    Petrogasoline Purity Tester

    CONTENTS

    Page No.

    1. INTRODUCTION... 2

    2. BLOCK DIAGRAM 4

    3.BLOCK DESCRIPTION....5

    4. THEORY & PRINCIPLE OF OPERATION. .6

    5. CIRCUIT DIAGRAM... 8

    6. CIRCUIT DESCRIPTION... 9

    7. HARDWARE DETAILS..11

    8. MICROCONTROLLER PROGRAM..19

    9. CONCLUSION..

    10.REFERENCES.

    Dept. of Electronics & Communication Engg.(Stream:- M&TV Engg.) COLLEGE OF ENGINEERING

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    I. INTRODUCTION.

    Recent years have witnessed dramatic progress in the design

    and development of fiber optic sensors as detection of chemical species is

    important in many industrial and chemical processes in addition to

    environmental control. Fiber optic sensors offer several advantages over

    conventional chemical sensing systems, specifically immunity to

    electromagnetic interference, possibility of distributed sensing over long

    lengths of fiber and their capability for safe operation in hazardous

    environments. Fiber optic chemical sensors include refractometric` sensors

    and evanescent wave absorption sensors, more recently indicator mediated,

    in which the evanescent field of guided light is absorbed by the chemical of

    interest.

    Adulteration of petroleum products especially petrol and diesel

    has become a serious problem. Kerosene is the most important domestic fuel

    for economically weaker sections of society and hence is heavily subsidized.

    The large differences in the prices of petrol, diesel and kerosene, the easy

    availability of kerosene and the fact that it is miscible in petrol and diesel,

    make the unhealthy and unethical practice of adulteration of petrol and

    diesel. This not only results in less availability of kerosene to the poor, but

    results in severely damaging automotive engines and increased motor

    vehicle emissions which are a cause of major concern to environmental

    pollution.

    There have been a number of methods proposed for checking

    adulteration of petrol and diesel by kerosene such as the filter test, American

    Standards for Testing Materials (ASTM) distillation, checking properties

    like density, flash point and viscosity, microprocessor based electronic

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    method using principle of cooling on evaporation, odor based method,

    ultrasonic techniques, titration techniques, optical techniques, dyeing

    kerosene and adding chemical markers for kerosene etc. All the above

    methods suffer from limitations in terms of accuracy and sensitivity in

    determining adulteration levels.

    In this project, we propose an intrinsic intensity modulated fiber

    optic sensor based on the principle of change in refractive index and

    evanescent wave absorption for detecting adulteration in petrol by kerosene,

    and trying to demonstrate its suitability. The proposed configuration is

    simple, safe and versatile and can be employed for on-site roadmeasurements.

    Dept. of Electronics & Communication Engg.(Stream:- M&TV Engg.) COLLEGE OF ENGINEERING

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    SOURCE

    (LED)

    PHOTODETECTO

    R

    AMPLIFIER ADC

    MICROCONTROLLE

    R

    DISPLAY(LCD)

    Optical Fiber

    Petrogasoline Purity Tester

    II. BLOCK DIAGRAM.

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    III. BLOCK DESCRIPTION.

    Source: LED is used as the fiber optic source since it requires less complexdrive circuitry than laser diodes.

    Optical fiber: Optical fiber consists of core & cladding in which refractive

    index of core is greater than that of cladding. Here we used a fiber in which

    the cladding is removed. This forms the sensor head. As the length of thefiber increases the sensitivity of the instrument also increases.

    Photo detector: Converts the optical power from the channel into electrical

    form. Here phototransistor is used for this purpose.

    Amplifier: Amplifies the photo detector output in order to drive the ADC.

    ADC: Analog to digital converters are the most widely used devices for data

    acquisition. We need an analog to digital converter to translate the analog

    signals into digital data so that the microcontroller can read them. A widely

    used ADC chip is ADC0804.

    Microcontroller: A single chip microcomputer is called a microcontroller. It

    contains the CPU, ROM/EPROM, RAM, I/O Ports, timer, counters, decoder,

    interrupts etc. Examples of single chip microcomputers are Intel 8048, 8051

    and 8096 series, Motorolas M6801 series, Texas instrument TMS 1000,

    Atmel 89C51, 89C52 and Zilog Z-80.

    LCD Display: LCD module is used for displaying the percentage of

    adulterant in petrol. The liquid crystals are one of the most fascinatingmaterials in nature, having properties of liquid as well as solid crystal.

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    LCDs do not emit or generate light, but rather alter externally generated

    illumination.

    IV. THEORY & PRINCIPLE OF OPERATION.

    Light is guided inside an optical fiber through the principle of

    total internal reflection. If the cladding of an optical fiber is removed over a

    small length of the fiber and is surrounded by a medium whose refractive

    index changes with some physical or chemical parameter, it results in

    variation of the output power. The output power varies due to variation inthe numerical aperture (NA) of the sensing region. Thus, one can measure

    the refractive index of the surrounding medium and hence, the physical or

    chemical parameter affecting it, by monitoring the output power. This

    principle forms the basis of fiber optic refractometry.

    When light is reflected at the boundary of a denser and a rarer

    optical medium, the field associated with the wave extends beyond theinterface in the cladding region. This field has an amplitude which decreases

    exponentially with increasing distance from the boundary and is referred to

    as an evanescent field. When this field interacts with an absorbing cladding,

    it results in attenuation of the power of the propagating wave. If Po is the

    power transmitted by the fiber in the absence of an absorbing species, then

    the power transmitted in the presence of an absorbing medium is given by

    P(z) = Po exp(-z) (1)

    where z is the distance along the unclad length and is the evanescent

    absorption coefficient of the medium. The evanescent absorbance A of an

    unclad fiber of length L surrounded by a fluid of evanescent absorption

    coefficient is given by

    A = log10 [Po/P(z)] = L / 2.303 (2)

    For a fluid obeying the LambertBeer law of absorption

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    (where the bulk absorption coefficient is directly proportional to

    concentration), Eq. (2) predicts that evanescent absorbance depends linearly

    on both exposed fiber length L and fluid concentration.

    Hence, the sensitivity of a sensor based on the above principle

    can be increased by increasing the length of the exposed region of the core

    which forms the sensor head and by increasing the depth of penetration of

    the evanescent field inside the absorbing medium.

    Variation of refractive index of petrol with percentage

    concentration of kerosene.

    The variation in the refractive index of petrol with

    The variation in refractive index of petrol with the

    increase in the percentage of adulteration by kerosene is as shown. From the

    figure it is evident that the refractive index increases with increase in

    adulteration by kerosene. The refractive index of the solution with 50%

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    concentration of kerosene was measured to be 1.433, which is less than that

    of the core of the fiber.

    The refractive index of petrol at different levels of

    adulteration will make a drastic decrease in output power as the condition of

    total internal reflection gets violated.

    V. CIRCUIT DIAGRAM.

    VI. CIRCUIT DESCRIPTION.

    The system consists of an input section, phototransistor,

    amplifier section, ADC, microcontroller, LCD module and a power supply

    unit.

    Input section: This section comprises of an LED source and an optical fiber

    in which the cladding is removed. This acts as the sensor head. When thePetrol which contains kerosene as the adulterant is in contact with the clad

    less fiber, the adulterated fuel acts as the cladding and the intensity of light

    which propagates through the fiber varies with the percentage of kerosene

    concentration.

    Phototransistor: An NPN phototransistor together with a 220K resistor is

    used for photo detection. The variation of light intensity is converted into

    electrical current by the phototransistor. The phototransistor is shunted with

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    a 220K resistor and the output current through the resistor develops a

    voltage which is proportional to the phototransistor output and thus to the

    light intensity variation.

    Amplifier: The voltage developed across the resistor is amplified in order to

    drive the ADC section. For this an LM358 op-amp is used. It works in the

    non-inverting mode and works with +5 V.

    ADC: The amplified voltage is given as the ADC input. ADC converts the

    analog variation into digital data so that the microcontroller can read them.

    Here ADC 0804 chip is used. The ADC 0804 IC is an analog to digital

    converter in the family of ADC 800 series from National Semiconductor. Itworks with +5 V and has a resolution of 8 bits.

    Microcontroller: The digital output from ADC is given to the input ports of

    the microcontroller. The digital output is converted to its corresponding

    ASCII by using the program in the flash programmable memory of the

    microcontroller and the LCD display module connected to the output ports

    of the controller displays the corresponding output. Atmel 89C51microcontroller is used here.

    Power Supply unit: All components in the circuit require a +5 V dc. For that

    a 12-0-12V/1 Amp transformer is connected to the main supply. The

    secondary side of the transformer is connected to a centre tap full wave

    rectifier section to convert the 12 V ac into 12 V dc. A capacitor of 1000

    mF/25 V is used for filtering purpose and is fed to the input of the 7805regulator IC for getting a constant output voltage of +5 V dc. A capacitor of

    470 mF/25 V.

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    VII. HARDWARE DETAILS.

    7.1.Microcontroller : - IC ATMEL 89C51

    The microcontroller used here is Atmels 89C51. The AT89C51

    is a low power, high-performance CMOS 8-bit microcomputer with 4

    Kbytes of Flash Electrically Programmable and Erasable Read Only

    Memory (EEPROM). The device is manufactured using Atmels high-

    density nonvolatile memory technology and is compatible with the industry

    standard MCS-51 instruction set and pin out. The on-chip flash allows the

    program memory to be reprogrammed in-system or by a conventional

    nonvolatile memory programmer. The Atmel AT89C51 is a powerful

    microcomputer which provides a highly flexible and cost effective solution

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    to many embedded control applications. (The AT89C51 provides the

    following standard features: 4 Kbytes of Flash, 128 bytes of RAM, 32 I/O

    lines, two 16-bit timer/counters, five vector two-level interrupt architecture,

    a full duplex serial port, ON-chip oscillator and clock circuitry.

    Figure. Pin diagram of AT 89C51

    Pin Descriptions :-

    VCC: Supply voltage.

    GND: Ground.

    Port 0: Port 0 is an 8-bit open drain bi-directional I/O port. As an output

    port, each pin can sink eight TTL inputs. When 1s are written to port 0 pins,the pins can be used this mode P0 has internal pull-ups. Port 0 also receives

    the code bytes during Flash as high-impedance inputs. Port 0 may also be

    configured to be the multiplexed low order address/data bus during accesses

    to external program and data memory. In programming, and outputs the code

    bytes during program verification. External pull-ups are required during

    program verification.

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    Port 1: Port 1 is an 8-bit bi-directional I/O port with internal pull-ups. The

    Port 1 output buffers can sink/source four TTL inputs. When 1s are written

    to Port 1 pins they are pulled high by the internal pull-ups and can be used as

    inputs. As inputs, Port 1 pins that are externally being pulled low will source

    current (IIL) because of the internal pull-ups. Port 1 also receives the low-

    order address bytes during Flash programming and program verification.

    Port 2: Port 2 is an 8-bit bi-directional I/O port with internal pull-ups. The

    Port 2 output buffers can sink/source four TTL inputs. When 1s are written

    to Port 2 pins they are pulled high by the internal pull-ups and can be used as

    inputs. As inputs, Port 2 pins that are externally being pulled low will sourcecurrent (IIL) because of the internal pull-ups. Port 2 emits the high-order

    address byte during fetches from external program memory and during

    accesses to external data, memory that uses 16-bit addresses (MOVX@

    DPTR). In this application, it uses strong internal pull-ups when emitting

    1s. During accesses to external data, memory that uses 8-bit addresses

    (MOVX @ RI); Port 2 emits the contents of the P2 Special FunctionRegister. Port 2 also receives the high-order address bits and some control

    signals during Flash programming and verification.

    Port 3: Port 3 is an 8-bit bi-directional I/O port with internal pull-ups. The

    Port 3 output buffers can sink/source four TTL inputs. When 1s are written

    to Port 3 pins they are pulled high by the internal pull-ups and can be used as

    inputs. As inputs, Port 3 pins that are externally being pulled low will sourcecurrent (IIL) because of the pull-ups. Port 3 also serves the functions of

    various special features of the AT89C51 as listed below:

    Port

    Pin

    Alternate Functions

    P3.0 RXD (serial input port)

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    P3.1

    P3.2

    P3.3

    P3.4

    P3.5

    P3.6

    P3.7

    TXD (serial output port)

    INT0 (external interrupt 0)

    INT1 (external interrupt 1)

    T0 (timer 0 external input)

    T1 (timer 1 external input)

    WR (external data memory write

    strobe)

    RD (external data memory read

    strobe)Table. Port description

    Port 3 also receives some control signals for Flash programming and

    programming verification.

    RST: Reset input. A high on this pin for two machine cycles while the

    oscillator is running resets the device.

    ALE/PROG: Address Latch Enable output pulse for latching the low byte

    of the address during accesses to external memory. This pin is also the

    program pulse Input (PROG) during flash programming. In normal

    operation ALE is emitted at a constant rate of 1/6 the oscillator frequency,

    and may be used for external timing or clocking purposes. Note, however,

    that one ALE pulse is skipped during each access to external Data Memory.

    If desired, ALE operation can be disabled by setting bit 0 of SFR location

    8EH. With the bit set, ALE is active only during a MOVX or MOVC

    instruction. Otherwise, the pin is weakly pulled high. Setting the ALE-

    disable bit has no effect if the microcontroller is in external execution mode.

    PSEN: Program Store Enable is the read strobe to external program

    memory. When the AT89C51 is executing code from external program

    memory, PSEN is activated twice each machine cycle, except that two PSEN

    activations are skipped during each access to external data memory.

    EA/VPP: External Access Enable. EA must be strapped to GND in order toenable the device to fetch code from external program memory locations

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    starting at 0000H up to FFFFH. Note, however, that if lock bit 1 is

    programmed, EA will be internally latched on reset. EA should be strapped

    to VCC for internal program executions. This pin also receives the 12-volt

    programming enable voltage (VPP) during Flash programming, for parts that

    require 12-volt VPP.

    XTAL1: Input to the inverting oscillator amplifier and input to the internal

    clock operating circuit.

    XTAL2: Output from the inverting oscillator amplifier.

    CRYSTAL: The crystal l (XTL1) used here is of 11.059MHz. Here the

    crystal is used for internal clock timing. The two terminals of the crystals areconnected across pin 19(X1) and pin 18(X2) Crystal oscillator must be

    designed to provide a load Capacitance on the crystal as specified by the

    manufacturer. This requirement is necessary to obtain oscillation at the

    specified frequency. It is also important that the power fed to the crystal be

    held to the specified maximum. Typical maximum drive levels for plated

    crystals range from 2mW to10mW.

    7.2. Analog to Digital Converter :- IC ADC 0804

    Figure. Pin diagram of ADC0804

    Pin Descriptions :-

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    CS: Chip select is an active low input used to activate the ADC 0804 chip.

    To access the ADC 0804, this pin must be low.

    RD: Read is an active low input signal. It is used to get the converted data

    out of the ADC 0804 chip. The RD pin is also referred to as output enable.

    WR: Write is an active low input signal. It is used to inform the ADC to

    start the conversion process. It is also referred to as SOC (Start of

    Conversion).

    CLK IN and CLK R: CLK IN is an input pin connected to an external clock

    source when an external clock is used for timing. To use the internal clock

    generator the CLK IN and CLK R pins are connected to a capacitor and aresistor. In that case the clock frequency is determined by the equation:

    f = 1 / 1.1RC.

    INTR: Interrupt is an active low output pin. It is normally a high pin and

    when the conversion is finished, it goes low to signal the CPU that the

    converted data is ready to be picked up. It is also referred to as EOC (End of

    Conversion).Vin(+) and Vin(-): These are the differential analog inputs where Vin =

    Vin(+)-Vin(-). Often the Vin (-) pin is connected to ground and the Vin (+)

    pin is used to connect the analog input.

    Vref/2: This is an input voltage used for the reference voltage. If this pin is

    open, the analog input for ADC is in the range of 0-5 V. Vref/2 is used to

    implement the analog input voltage other than 0-5 V.D0-D7: These are the digital data output pins, where D7 is the MSB and D0

    is the LSB. These are tristate buffered and the converted data is accessed

    only when CS = 0 and RD is forced low.

    AGND and DGND: Analog ground and digital ground are the input pins

    providing the ground for both the analog and digital signal. Analog ground is

    connected to the ground of analog Vin while digital ground is connected to

    the ground of Vcc pin. The two ground pins is used to isolate the analog Vin

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    signal from transient voltages caused by digital switching of the output.

    Such isolation increases the accuracy of the digital output.

    7.3.Operational Amplifier :- IC LM 358

    Figure. Pin diagram of LM358

    General Description :-

    These devices consist of two independent, high-gain, frequency-

    compensated operational amplifiers designed to operate from a single supply

    over a wide range of voltages. Operation from split supplies also is possible

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    if the difference between the two supplies is 3 V to 32 V (3 V to 26 V for the

    LM2904), and VCC is at least 1.5 V more positive than the input common-

    mode voltage. The low supply-current drain is independent of the magnitude

    of the supply voltage.

    Applications include transducer amplifiers, dc amplification

    blocks, and all the conventional operational amplifier circuits that now can

    be implemented more easily in single-supply-voltage systems. For example,

    these devices can be operated directly from the standard 5-V supply used in

    digital systems and easily can provide the required interface electronics

    without additional 5V supplies.

    7.4. LCD Module

    LCD module is used for displaying message that send from

    remote location. The liquid crystals are one of the most fascinating materials

    systems in nature, having properties of liquid as well as solid crystal. LCDs

    do not emit or generate light, but rather alter externally generatedillumination. Their ability to modulate light when electrical signal is applied

    has made them very useful in flat panel display technology. The crystal is

    made up of organic molecules, which are rod like In shape with a length of ~

    20 A 100 A., the different arrangements of this rod like molecules led to

    three main categories of liquid crystals.

    Smectic Nematic

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    Cholestric

    There are two types of LCDs according to the theory operation

    Dynamic scattering

    Field effect

    Advantages

    Less power consumption

    Low cost

    Uniform brightness with good contrast

    Low operating voltage and current

    Disadvantages

    Poor reliability

    Limited temperature range

    Slow speed

    LCD panel used here has 15 pins (8-data line, 3-control line and a

    contrast line). Data line and control line are connected to microcontroller.Contrast line is connected to a voltage divider using preset (R9). Contrast

    can vary by this preset.

    VIII. MICROCONTROLLER PROGRAM.

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    IX. CONCLUSION.

    We proposed an intrinsic intensity modulated fibre optic sensor

    based on the principle of evanescent wave absorption and change in

    refractive index for detecting adulteration in petrol by kerosene. The

    proposed sensor would be useful in automotive and petrochemical industries

    due to its simple design, safety with inflammable fuels, sensitivity and the

    fact that it can be made into a portable device for on-road measurements.

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    X. REFERENCES.

    1. www.sciencedirect.com

    2. www.intertek-cb.com/petrotesting/gasolinetest.shtml

    3. Optical Fiber Communications: Gerd Keiser

    4. Kenneth J Ayala, 8051 Programming and application

    5. www.microchip.com.

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