r13 permit applicationdep.wv.gov/daq/documents/october 2016 applications/003-00154_appl_13... ·...

Environmental solutions delivered uncommonly well

R13 PERMIT APPLICATION Procter and Gamble

Tabler Station, West Virginia

PreparedBy:

TRINITYCONSULTANTS15ESalemAve.

Suite201Roanoke,VA24011

(540)342‐5945

Submitted:April2016Revised:October2016

Project141801.0078

P&G – Tabler Station | R13 Permit Trinity Consultants 1

TABLE OF CONTENTS

1. INTRODUCTION 3

1.1.FacilityandProjectDescription 3

1.2.R‐13ApplicationOrganization 3

2. SAMPLE EMISSION SOURCE CALCULATIONS 4

2.1.SurfactantManufacturing 4

2.1.1.ProcessDescription 4

2.1.2.EmissionsCalculations 5

2.2.LiquidSoapMakingAandB 6



2.3.DryConsumerLaundryandCleaningProductsA 7



2.4.Utilities 10



2.5.PlasticsMolding 11


2.5.2.EmissionsCalculationsforPlasticsMolding 12

2.6.PlasticsMoldingUtilities 12



2.7.SourcesofMinorSignificance 13

3. R13 APPLICATION FORM 14

ATTACHMENT A: CURRENT BUSINESS CERTIFICATE

ATTACHMENT B: MAP

ATTACHMENT C: INSTALLATION AND START UP SCHEDULE

ATTACHMENT D: REGULATORY DISCUSSION

ATTACHMENT E: PLOT PLAN

ATTACHMENT F: DETAILED PROCESS FLOW DIAGRAM

ATTACHMENT G: PROCESS DESCRIPTION

ATTACHMENT H: MATERIAL SAFETY DATA SHEETS

ATTACHMENT I: EMISSION UNITS TABLE

ATTACHMENT J: EMISSION POINTS DATA SUMMARY SHEET

ATTACHMENT K: FUGITIVE EMISSIONS DATA SUMMARY SHEET


ATTACHMENT L: EMISSIONS UNIT DATA SHEETS

ATTACHMENT M: AIR POLLUTION CONTROL DEVICE SHEET

ATTACHMENT N: SUPPORTING EMISSION CALCULATIONS

ATTACHMENT O: MONITORING/RECORDKEEPING/REPORTING/TESTING PLANS


1. INTRODUCTION

1.1. FACILITY AND PROJECT DESCRIPTION

ProcterandGamble(P&G)issubmittingthisRule‐13(R‐13)permitapplicationtotheWestVirginiaDepartmentofEnvironmentalProtection(DEP)fortheproposedconstructionofagreenfieldfacilitytobelocatedinBerkleyCounty,WestVirginiaintheunincorporatedcommunityofTablerStation(TablerStationfacility).TheTablerStationfacilitywillproduceliquidsoapanddryconsumerlaundryandcleaningproducts,includingdryerappliedfabricsoftener,shampoo,andbodywash.Thefacilitywillproducesurfactantpasteandrawmaterialswhichwillbeusedinliquidsoapmakingprocesses.Thefacilitywillhaveutilitiestosupporttheheating,cooling,ventilation,andsteamneedsofthemanufacturingprocesses.Thefacilitywillincorporatethirdpartysupplierswhowillprovideaplasticsmoldingprocessforthemanufactureofbottles,caps,andotherformedplasticparts.Theequipmentandoperationsatthefacilitywillbeinstalledandstartedupinmultiplephases.Thebusinessoperationscontainedinthispermitapplicationarethoseexpectedtobeinstalledinthefirstphaseoftheproject.Additionalphasesarestillindetaileddesignandwillbepermittedatalaterdate.Itisanticipatedthatallphasesofthisprojectwillbepermitted,installed,andoperationalwithin5yearsofbeginningconstruction.Athoroughanalysisofthecurrentscopeoftheentirefacilityandplannedoperationsindicatesthatallphasestogetherdonottriggermajornewsourcereview(majorNSR)permitting,alsocalledpreventionofsignificantdeterioration(PSD)permitting.AdescriptionofeachsourcecategoryapplicabletothecurrentprojectcanbefoundinSection2.AprocessflowdiagramfortheplannedPhase1operationsisincludedinAttachmentF.

1.2. R-13 APPLICATION ORGANIZATION

ThisR‐13permitapplicationisorganizedasfollows:> Section2:SampleEmissionSourceCalculations;> Section3:R‐13ApplicationForms;> AttachmentA:BusinessCertificate;> AttachmentB:AerialMap;> AttachmentC:InstallationandStartUpSchedule;> AttachmentD:RegulatoryApplicabilityDiscussion;> AttachmentE:PlotPlan;> AttachmentF:DetailedProcessFlowDiagram;> AttachmentG:ProcessDescription;> AttachmentH:MaterialSafetyDataSheets> AttachmentI:EmissionUnitsTable;> AttachmentJ:EmissionPointsDataSummarySheet;> AttachmentK:FugitiveEmissionsDataSummarySheet;> AttachmentL:EmissionsUnitDataSheets;> AttachmentM:AirPollutionControlDeviceSheet;> AttachmentN:SupportingEmissionCalculations;and> AttachmentO:Monitoring/Recordkeeping/Reporting/TestingPlans.


2. SAMPLE EMISSION SOURCE CALCULATIONS

Aspartofthefirstphaseoftheproject,P&Gproposestoinstallequipmentinseveraldistinctmanufacturingareas:

SurfactantManufacturing; LiquidSoapMakingAandB; DryConsumerProductsA; SiteSupportingUtilities;and PlasticsMoldingSuppliers.

Eachofthesebusinessareaswillbediscussedingreaterdetailinthissection.AprocessflowdiagramisincludedasAttachmentF.Theinstallationofequipmentatthefacilitywillbeinstalledinmorethanonephase.Thebusinessareascontainedinthispermitapplicationmakeupphase1.Additionalphaseswillbepermittedatalaterdate.Itisanticipatedthatallphasesofthisprojectwillbepermitted,installed,andoperationalwithin5yearsofbeginningconstruction.Inaddition,thecharacteristicsofexpectedsiteairemissions,alongwiththemethodologyusedforcalculatingemissionsfromtheproposednewsources,aredescribedinnarrativeformbelow.TheTablerStationfacilityhasthepotentialtoemitthefollowingpollutants:

> Oxidesofnitrogen(NOX);> Sulfurdioxide(SO2);> SulfurTrioxide(SO3);> Carbonmonoxide(CO);> SulfuricAcid(H2SO4);> Volatileorganiccompounds(VOC);> Hazardousairpollutants(HAP);> Particulatematter(PM);> Particulatelessthan10micrometers(PM10);and> Particulatelessthan2.5micrometers(PM2.5).

DetailedsupportingcalculationsarealsoprovidedinAttachmentN.

2.1. SURFACTANT MANUFACTURING

2.1.1. Process Description

P&Gproposestoinstallequipmenttomanufacturesurfactants.Thepurposeofthesurfactantmakingoperationisprimarilytomanufacturesurfactantpastesusedintheliquidsoapmanufacturingprocesswhichisalsoincludedinthisapplication.Asecondarybyproductproducedbythesurfactantprocessisaprecipitatedacidmix(PAM).Similarly,anumberofvariationstothesurfactantpasteproductareintended,basedontheenduse.Thesevariationsareachievedthroughtheuseofvaryingrawmaterialsindifferentquantitiesinthesurfactantmanufacturingprocess.Withthestartupofthesurfactantprocess,itisnecessarytopreheatthesulfurreactors,whichisaccomplishedwiththeuseoffour(4)naturalgaspreheaters;Startupisintendedtooccurapproximatelyfour(4)timesperyearperreactor.Gassesfromthepreheaters(onlyusedduringstartup)areventedtothecommonstack.Duringstartup,anySO3producedwillbeventedtotheSO3absorberandthenthroughtheSO2scrubber.Rawsulfurisstoredinsulfurtanks.Gasesfromthecombustionofsulfur(normaloperation)areventedthroughaSO2packedbedscrubber.Duringchangeover,theSO3isventedtotheSO3absorber,andexhaustgasisventedthroughtheSO2scrubber.Abyproductproducedduringchangeoverperiodsissulfuricacid(H2SO4).


Thesurfactantprocessesareanticipatedtoemitthefollowingcriteriapollutants:SO2,VOC,PM10,andPM2.5.

Additionally,asmallamountofNOX,CO,SO2areanticipatedtobeemittedthroughthepreheatingofthesulfurreactorusinganaturalgaspreheaterand/ortheoxidationofsulfurinvolvedinmakingthesurfactantpaste.Allsurfactantpotentialemissions,withtheexceptionofthenaturalgaspreheaters,areventedthroughaSO2packedbedscrubber.Additionally,VOCemissionsareanticipatedfromrawmaterialandproducttanks,inlinemixingtanks,andrailandtruckloading.EmissionsarecalculatedforthesurfactantmanufacturingcanbefoundinAttachmentN.Proposedemissionsourcesinthesurfactantprocessesincludethefollowing:

Rawmaterial,intermediate,andproducttanks; Naturalgaspreheatersandsulfurreactors; In‐linemixingand/ormixingtanks;and Producttruckloading.

TheproposedsurfactantprocesswillbecontrolledwiththefollowingequipmenttocontrolSO2andPMemissions:

PackedbedscrubberAdditionalinformationrelatedtocontroldevicescanbefoundinAttachmentM.

2.1.2. Emissions Calculations

2.1.2.1. Scrubber for Surfactant Manufacturing

TheTablerStationfacilitywillemitNOx,SO2,VOC,H2SO4,andPMthroughapackedbedSO2scrubberasaresultofsurfactantmanufacturing.ThepotentialtoemitforVOCisderivedfromthestacktestdatarecordedbysimilarP&Gsites.TheNOx,SO2,PM10,andPM2.5emissionratesarecalculatedusingemissionfactorssuppliedbythemanufacturer.Duringlimitedstartupperiods,naturalgaspreheatersareruntopreheattheprocessfromacoldstart;emissionsarecalculatedusingAP‐42emissionfactors.

AmajorityofthesulfurburnedistransformedintoSO3,absorbedandconvertedintofinishedproductinthesurfactantmakingprocess.However,afractionoftheSO2isnotconvertedtoSO3andnotalloftheSO3isconsumedinthereaction.TheexcessSO2isnotemitted;itiscontrolledbytheSO2scrubbers.Inthepresenceofwatervapor,SO3becomesdropletsofH2SO4(i.e.sulfuricacidmist).H2SO4dropletscontributetothecondensablefractionofPM10andPM2.5emissions.ForpurposesofthisapplicationitwasassumedthatthePM10andPM2.5emissionsfromthescrubberduringnormaloperationswereequaltotheresidualSO3fromthescrubber(which,inthepresenceofwatervaporisH2SO4).

2.1.2.2. Vertical Fixed Roof Tank Emission Calculation Methodology

TheproposedTablerStationprojectincludestanksineachoftheproposedprocessareas.MonthlyVOCemissionsfromfixedrooftanksarecalculatedusingproceduresinAP‐42Section7.1.

Fixedrooftankstypicallyhavetwomajortypesofemissions:workinglossesandbreathinglosses.Workinglossesoccurduringtheday‐to‐dayoperationsofthetankfromthereleaseofthevaporspaceasthetankisfilledandemptied.Breathinglossesoccuratoutdoorambienttanksthataresubjecttodailytemperaturechangeswiththeweather.AmajorityofthetanksattheTablerStationfacilityaretemperaturecontrolledand,assuch,donothavebreathinglosses.Breathinglosseswerecalculatedforambientoutdoortanks.


ThetanksattheTablerStationfacilitycontainavarietyoforganicmaterialsusedinthemanufactureofsurfactants,liquidsoap,anddryconsumerlaundryandcleaningproducts.Emissionsfromtankscontainingrawmaterialswerecalculatedusingthespecificpropertiesofthatmaterial.EmissionsfromtankscontainingintermediatematerialsormixtureswerecalculatedusingRaoult’slaw1andthepropertiesofthemostvolatilecomponentofthemixture.MinorcomponentsofrawmaterialHAPhavebeenincludedinindividualmaterialusagetankcalculations,asapplicable.HAPamountsinrawmaterialsbasedonreviewofMaterialSafetyDataSheets.

2.1.2.3. Liquid Material Handling

AsdiscussedinSection2.1.2.2,severaloftheproductsandprocessesattheTablerStationfacilitycontainorganicliquidswitharangeofvolatility.FugitiveemissionsofVOCthatoccurduringthemixingofrawmaterials,intermediatesandproducts;ortransferandpackagingofproducts,arecalculatedthroughtheuseofaworkinglossequation;thisequationcalculatestheemissionsthatresultfromlostvaporsduetoliquidmovementwhentanksarebeingfilledoremptiedandcanbefoundinAP‐42Section7.1asEquation1‐29.Thisworkinglossduetoliquidmovementissimilartowhatoccurswhenmixingorpackagingliquidrawmaterials,intermediates,andproductsandthereforeisusedforestimatingtheassociatedemissionrate.

2.1.2.4. Truck Loading and Unloading

ThetransferoforganicchemicalsintoandoutoftruckswilloccurasapartoftheoperationsattheTablerStationfacility.IntermediatesandfinalproductsthatareloadedintotrucksproducevaporscontainingVOC,HAPandH2SO4.Theemissionsfromunloadingoftrucksisaccountedforintheworkinglossesofthetanks.TheemissionsfromtheloadingoftrucksarecalculatedusingEquation1inAP‐42Section5.2.Asaturationfactorof0.6isselectedbasedonTable5.2‐1ofAP‐42Section5.1forbottom/submergedloadingofatruckduringnormalloadout.VOCconcentrationisassumedtobe100%whereasHAPandH2SO4varybystream.

2.2. LIQUID SOAP MAKING A AND B


P&GalsoproposestoinstallLiquidSoapAandBmanufacturingprocesses.BothSoapAandSoapBmanufacturingprocessesinvolveprimarilymixingoperationswithnochemicaltransformations.Therawmaterialsprimarilyconsistofbutarenotlimitedtodyes,perfumes,surfactantsessentialforsoapmanufacturing,andminorcomponentadditivesintendedtodeliverproductperformanceattributes.Liquidrawmaterialswilleitherbepipedfromelsewhereon‐siteorbetransportedtothesiteintotes/drumswhichwillbeunloadedintothebuildingforplacementintothemixingtanks.Dryrawmaterialswillbeweighedonascalebeforebeingmanuallyaddedtothemixingtanks.LiquidSoapAisavariationoftheproductthatmaycontainahighervolatilityprocessingaid,dependingonproductformulation.Thehighervolatilityprocessingaidmaybeprocessedhotoratambienttemperature.WhenLiquidSoapAisbeingmanufacturedhotandthehighervolatilityprocessingaidisused,volatileemissionsfromthemixingtankswillberoutedthrougharegenerativethermaloxidizer(RTO).WhenLiquidSoapAisbeingmanufacturedatambienttemperatureandthehighervolatilityprocessingaidisused,volatileemissionsfromthemixingtanksarenotcontrolled.LiquidSoapBdoesnotcontainthehighervolatilityprocessingaidandwillnothaveemissionsroutedthroughtheRTO.

1 The partial vapor pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component multiplied by its mole fraction in the mixture.


Theresultantmixturerepresentsthefinalproduct.Variationsofthemixturearedependentuponthesoapproducttobemanufactured.Theproduct,oncemade,ispipedintoapackinglineforfillingcontainers.Afterfilling,theproductwillproceedtofinalpackagingforoff‐sitetransport.Aspartofqualityassurance,processtanksandliquidfillingequipmentisperiodicallycleanedandsanitizedusinghotwater.Residualrawmaterialrelatedemissionsthatmayoccurduringcleaningandsanitizationareaccountedforinstorageandprocesstankemissionscalculations.Theemissionsourcesfortheliquidsoapmanufacturingprocessincludes:

Storingrawmaterialsintanks,totes,ordrums Weighingandmixingrawmaterials Productpackaging

EmissioncalculationsforLiquidSoapAandBmanufacturingcanbefoundinAttachmentN.TheproposedliquidsoapprocesseswillbecontrolledwiththefollowingequipmenttocontrolVOCandPMemissions:

RegenerativeThermalOxidizer(RTO)(LiquidSoapAonly);and Rotoclones,liquid(water)scrubbers.

AdditionalinformationrelatedtothesecontroldevicescanbefoundinAttachmentM.Asdiscussedinthenextsection,perfumemaybeusedintheLiquidSoapA&Bmakingprocess.Asmallquantityofperfumemaybeemitted,amongothervolatileorganiccompounds,asafugitive.AdditionalinformationcanbefoundinAttachmentN.7


EmissionscalculationmethodologyfortanksandpackaginghasalreadybeendiscussedinSections2.1.2.2and2.1.2.3,respectively.Thissectionwilldiscusstheemissionscalculationsfortheprocesstanks.

2.2.2.1. Process Tanks

TheprocesstanksforLiquidSoapAandBmanufacturingareequippedwithrotoclonesfordustcontrol.Inaddition,someoftheprocesstanksforLiquidSoapAareequippedwithanRTO.PM,PM10,andPM2.5emissionsfromtherotoclonesarecalculatedbasedongrainloadingbasedonP&Gprocessknowledge.ItisconservativelyassumedthatPM10andPM2.5emissionsareequaltoPMemissions.TheVOCemissionsfromtheprocesstanksforLiquidSoapAandBarecalculatedbasedonP&Gprocessknowledge.TheRTOemissionfactorsarebasedonamassbalanceofVOC,vendorguarantees(NOX,CO),andAP‐42factors(PM10,PM2.5,SO2).

2.3. DRY CONSUMER LAUNDRY AND CLEANING PRODUCTS A


Additionally,P&GproposestoinstallmanufacturinglinestomanufactureDryConsumerLaundryandCleaningProducts.Theprocessincludesdeliveryofrawmaterialsandtransferofmaterialtodayandmixingtanks.Themixtureisthenappliedontoasubstratetoproducethefinalproduct.Thefinalproductistrimmedtosize,packaged,andsenttoawarehousefordistribution.Variousprocessinglinesareinvolvedwithmanufacturingcleaningarticlesintothedifferentconsumercleaningproducts.Thesourcesofemissionsincludethefollowingequipment:


Rawmaterialtanks Intermediatemixing Additionofliquidrawmaterials Finishedproductpackaging

EmissionsestimatesarebasedontherawmaterialswiththehighestvaporpressuretoaccountforthepotentialVOCemissionstorepresentthemultipleformulationsinthecleaningarticlemanufacturingprocess.EmissionsestimatescanbefoundinAttachmentN.TheproposedDryConsumerLaundryandCleaningProductsprocesswillbecontrolledwiththefollowingequipmenttocontrolparticulateemissions:

BaghousesandbinventfiltersAdditionalinformationrelatedtothesecontroldevicescanbefoundinAttachmentM.Asdiscussedinthenextsection,asmallamountofperfumemaybeincludedintheproductformulation.Emissionpointswiththepotentialtoemitodor,suchastheareawereliquidrawmaterialsareadded,arecontrolledwithactivatedcarbon.Theactivatedcarbonservesasacontrolforemployeecomfortandtopreventnuisanceodors,ratherthanforcriteriapollutants,suchasVOC.Assuch,itwillnotbeconsideredacontroldeviceinthisapplication.


EmissionscalculationmethodologyfortanksandintermediatemixingtankshasalreadybeendiscussedinSections2.1.2.2and2.1.2.3,respectively.Thissectionwilldiscusstheemissionscalculationsfortheadditionofliquidrawmaterialsandparticulateemissionscontrolforfinishedproductpackaging.

2.3.2.1. Addition of Liquid Raw Materials

TheDryConsumerLaundryandCleaningProductsAprocessproducesavarietyofconsumergoods,allofwhichbeginwithasubstrate.Thissubstratemayreceiveavarietyofliquidrawmaterialsintendedtoenhancetheperformanceandfunctionalityoftheconsumerproduct.Therawmaterialstypicallyconsistoflow‐volatile,highmolecularweightorganicmaterialspairedwithasmallamountofperfume.Aftertherawmaterialsareapplied,thesubstrateiscuttosize,andpackaged.AsmallamountofVOCemissionswillresultfromtheapplicationprocessandsubsequentexposedsubstratesurface.Regardlessofthetypeofmaterialappliedorsubstrateused,emissionsevaporatingfromthesubstratewilldispersesimilartoemissionsevaporatingfromaresidual“puddle”,whichprovidesaconservativeestimateofpotentialemissions.Theareaoverwhichemissionscouldpotentiallydischargeintotheatmosphereisthesameastheareaoverwhichrawmaterialswouldbeappliedandthereforevariesbasedontheapplicationprocess.TheevaporationandemissionsofVOCcanbeestimatedusingthefollowingequationfoundinEPA’s2007EmissionInventoryImprovementProgram’sTechnicalReportSeriesVolumeIISection16,pages49‐50.


EM K AP

RT

Where:

En = Evaporationrateofthevolatilecomponent

Mn = Molecularweightofthevolatilecomponent

Kn = Masstransfercoefficient

A = Surfaceareaofsubstrateexposed ft Pnsat = Saturatedsolventvaporpressure psia

R = Universalgasconstant 10.73

°

TL = Absolutetemperatureoftheliquid (˚R)

ThemasstransfercoefficientfortheVOCmixtureisrelatedtoareferencecompound,inthiscasewater,throughthefollowingequation.

KK

MM

Where:

Kn = MasstransfercoefficientofVOCmixture

K0 = Masstransfercoefficientofwater 98.03

Mn = Molecularweightofthevolatilecompound

M0 = Molecularweightofwater 18

TheareaoverwhichVOChavethepotentialtoevaporateisrelatedtotheapplicationprocessofthevolatilematerial.Therefore,thespillareaisequaltothesurfaceareaofthelinefromthepointofapplicationofthevolatilematerialuntilthesubstrateiswoundforstorage.

A L ∗ W Where: A = Areaoftherepresentative“puddle” ft Ll = Lengthoftheline (ft) Wl = Widthoftheline (ft)

2.3.2.2. Particulate Emission Control for Raw Material Addition

BaghousesandfabricfiltersareproposedtocontrolparticulateemissionsforTablerStationintheDryConsumerLaundryandCleaningProducts.PM,PM10,andPM2.5emissionsfromthebaghousesarecalculatedbasedonfabricfiltergrainloadingandbaghouseflowratesbasedonP&Gprocessknowledge.ItisconservativelyassumedthatPM10andPM2.5emissionsareequaltoPMemissions.


2.4. UTILITIES


Tosupporttheheating,cooling,ventilation,andsteamneedsfortheprocessesthatarebeingproposedwiththisproject,P&Gisproposingtoinstallthefollowingequipment:2

Two(2)50,267poundperhour(pph)steamboilers One(1)25,134poundperhour(pph)steamboiler One(1)8,918poundperhour(pph)steamtemporaryboiler Six(6)naturalgasfiredbuildingheaters Three(3)coolingtowers

Theboilerswillbefueledprimarilybynaturalgas.Thepurposeoftheboilersistosupplyheatorsteam.Thetemporaryboilerwillbeamobileunitthatwillprovidesupporttoplantprocessesasthemainfacilityboilersareinstalled.Thetemporaryboilerwillnotberunatthesametimeasthemainfacilityboilers.Emissionsfromthetemporaryboilerwillbelessthanemissionsfromthemainfacilityboilers.Thepurposeofthebuildingheatersistoprovidecomfortheatingforthewarehouseandotherbuildings.Thecoolingtowersareforbothcomfortandprocesscoolingwatersupplytobuildingsandmanufacturingequipmentassociatedwiththevariousprocesses.Tobepreparedforpoweroutagesandtobeequippedtoquicklyrespondtofires,thefollowingequipmentisalsoproposedbeinstalled:

Three(3)350KWstandby/backupelectricgeneratorswithdieselengines Two(2)311horsepower(HP)firepumpswithdieselengines

Thestandby/backupgeneratorandfirepumpengineswillbefueledwithULSDandmeetU.S.EPA’sTier3specifications.Additionally,theplantintendstoinstallfivedieseltanks,lessthan500gallons,tosupplythestandby/backupgeneratorsandfirepumpengines.Also,adieselrefuelingstationtosupplyon‐sitemobileequipmentisproposedtobeinstalled.Thefollowingfueltankswillbeinstalledatthesite:

5,000gallonULSDtankforvehiclerefuelingTheTablerStationfacilityintendstoinstallawaterpretreatmentsystemaswellasawastewaterpretreatmentsystem.Thewaterpretreatmentsystemwillpurifyandsoftenthewaterbeforeusetomaintainproductquality.Thewastewatersystemwillusechlorinationandotherprocesstocleanthewastewaterbeforedischargetothesanitarysewer.EmissionscalculationsfortheabovelistedequipmentareenclosedinAttachmentNoftheapplication.Emissionshavebeenestimatedusingeithervendorsuppliedspecifications,applicableAP‐42factors,and/ormassbalanceequationsassociatedtothetypeofemissionssourcelistedabove.

2 Final sizes and numbers of equipment in the utilities area subject to change.



2.4.2.1. Boilers

CO,VOC,PM10,PM2.5,SO2andleademissionsfromtheproposedboilersarecalculatedusingtheemissionfactorsfoundinAP‐42Section1.4(naturalgas),exceptwhereamanufacturer’sguaranteeapplies.TheH2SO4emissionfactorwascalculatedbyassumingonepercentofthesulfurcontainedwithinthenaturalgasisemittedassulfuricacid.3

2.4.2.2. Standby/Backup Generators and Fire Pump

ThethreegeneratorenginesandtwofirepumpenginesproposedfortheTablerStationfacilitywillbesubjecttotheemissionlimitationsinNSPSSubpartIIII(thegeneratorwillonlybesubjecttothenotificationrequirementsofNESHAPZZZZ).Toverifycompliancewiththesestandards,emissionsfromtheenginesarecalculatedbasedonemissionsfactorsprovidedbythemanufacturers.Sincethisequipmentwillonlyoperateduringemergencysituationsandroutinemaintenanceandtesting,annualemissionsarecalculatedbasedon500hoursofoperations.

2.4.2.3. Heater Emissions

Theproposedprocessheaterswillbefiredonnaturalgas.EmissionfactorsforNOx,CO,PM,PM2.5,PM10,SO2,lead,andVOCfromAP‐42Section1.4wereused.TheH2SO4emissionfactorwascalculatedbyassumingonepercentofthesulfurcontainedwithinthenaturalgasisemittedassulfuricacidinthesamemannerasfortheboilers.

2.4.2.4. Cooling Towers

TheTablerStationfacilityincludesthreecoolingtowers.TheanticipatedpollutantsarePM,PM10,andPM2.5.PotentialhourlyemissionsfromthecoolingtowerarecalculatedusingthemethodologyinAP‐42Section13.4‐1.

2.4.2.5. Water and Wastewater Pretreatment

TheTablerStationfacilitywillhavewaterpretreatmentonsitetomaintainthequalityofthecoolingtowerandboilerfeedwater.Inaddition,thefacilitywillhavepretreatmentprocessesforthewastewater.Theequipmentintheseareasmayincludetanksforwastewatercollectionandtreatmentandtotesoftreatmentchemicals.Processesmayincludeadissolvedairflotationunit,physicalandchemicalpretreatment,biologicaltreatment,andsettlingtanks.Emissionswerecalculatedusinganengineeringestimateoftheamountofeachtreatmentchemicalusedanditsvolatileand/orhazardouscontent.

2.5. PLASTICS MOLDING


TheTablersStationfacilitywillincorporatethirdpartysupplierswhowillprovideaplasticsmoldingprocessforthemanufactureofbottles,caps,andotherformedplasticparts.

3 Emergency Planning and Community Right-To-Know Act, EPCRA - Section 313: Guidance for Reporting Sulfuric Acid (acid aerosols including mists, vapors, gas, fog, and other airborne forms of any particle size). (March 1998) EPA-745-R-97-007.


Theplasticbottleandcapmakingprocessinvolvesinjectionmolding,blowmolding,andextrusionblowmolding.Theprocessstartswiththeunloadingofplasticpelletsfromrailcarsintostoragesilos.Fromthesilos,thepelletsarepipedtopressesandmoldingmachineswhichmakebottles,capsandotherformedplasticpartsdependingonproductneeds.Thepressesandmoldingmachinesheattheplasticwithelectricalheatersandviafrictionheating.Scrapplasticisregroundandreuseddirectlyinthemakingprocess.EmissionscalculationsfortheabovelistedequipmentareenclosedinAttachmentNoftheapplication.EmissionshavebeenestimatedusingeithervendorsuppliedspecificationsorapplicableAP‐42factors.


2.5.2.1. Dry Material Handling

Plasticpelletsarestored,conveyedandground.Particulateemissionsfortheseareasareestimatedbythesupplierbasedontheaverageofpublishedfactorsavailableforothertypesofpelletstorage,includinggrainandwoodpellets.

2.5.2.2. Fugitive VOC

WhentheplasticpelletsareheatedtobepressedormoldedtheyemitasmallquantityofVOC.TheVOCemittediscalculatedusingafactorfromafactsheetfromtheMichiganDepartmentofEnvironmentalQualityentitled“PlasticsProductionandProductsManufacturing”(#9847,revisedNovember2005).TheotherfugitiveVOCsarefromcleaningproductsandarecalculatedassuming100%lossrateofvolatilecomponentsofcleaningproducts.

2.6. PLASTICS MOLDING UTILITIES


Tosupporttheheating,cooling,andventilationneedsfortheplasticsmoldingsuppliers,P&Gisproposingtoinstallthefollowingequipment:4

Six(6)naturalgasfiredbuildingheaters; One(1)coolingtower;and One(1)70kWstandby/backupelectricgeneratorwithnaturalgasengine.

Thepurposeofthebuildingheatersistoprovidecomfortheatingforthewarehouseandotherbuildings.Thecoolingtowerisforbothcomfortandprocesscoolingwatersupplytobuildingsandmanufacturingequipmentassociatedwiththevariousprocesses.Thebackupelectricgeneratoristobepreparedforpoweroutages.EmissionscalculationsfortheabovelistedequipmentareenclosedinAttachmentNoftheapplication.Emissionshavebeenestimatedusingeithervendorsuppliedspecifications,applicableAP‐42factors,and/ormassbalanceequationsassociatedtothetypeofemissionssourcelistedabove.

4 Final sizes and numbers of equipment in the utilities area subject to change.



Emissionscalculationmethodologyfornaturalgasheaters,andcoolingtowershasalreadybeendiscussedinSection2.4.2.Thissectionwilldiscusstheemissionscalculationsforthenaturalgasenginethatpowersthestandby/backupelectricgenerator.

2.6.2.1. Standby/Backup Generator and Fire Pump

ThegeneratorengineproposedfortheTablerStationfacilitywillbesubjecttotheemissionlimitationsinNSPSSubpartJJJJ.Toverifycompliancewiththesestandards,emissionsfromtheenginesarecalculatedbasedonemissionsfactorsprovidedbythemanufacturers.Sincethisequipmentwillonlyoperateduringemergencysituationsandroutinemaintenanceandtesting,annualemissionsarecalculatedbasedon500hoursofoperations.

2.7. SOURCES OF MINOR SIGNIFICANCE

Eachoftheprocessareas(surfactants,liquidsoapAandB,dryconsumerlaundryandcleaningproductsA,utilities,andplasticsmolding)containemissionsunitsthatProcterandGambledefinesas“sourcesofminorsignificance”.SomeofthesesourcesarealreadydefinedasdeminimissourcesbyDEPin45CSR13,Table45‐13b,suchashaulroademissions,labvents,andwelding.Additionalsources,withemissionslessthan0.5tpyofanypollutant,suchastanksstoringmaterialswithalowvolatility,havebeenaddedtoalistof“sourcesofminorsignificance”.Alistofthesesourcescanbefoundinpage2ofAttachmentI.


3. R13 APPLICATION FORM

TheDEPpermitapplicationformscontainedinthisapplicationincludeallapplicableR‐13applicationformsincludingtherequiredattachments.

P&G – Tabler Station | R13 Permit Trinity Consultants

ATTACHMENT A

Current Business Certificate


ATTACHMENT B

Aerial Map

756,000 757,000 758,000 759,000

4,366

,000

4,367

,000

4,368

,000

4,369

,000

Attachment B - Aerial Map

UTM Easting (m)

UTM

North

ing (m

)

All coordinates shown in UTM projection,Zone 17, NAD 83

Area Map Extent

Tablers Station Location

Procter and Gamble


ATTACHMENT C

Startup and Installation Schedule

Attachment CTabler Station

Unit InstallationSchedule StartupScheduleSurfactantMakingLiquidSoapAandB

DryConsumerProductsAUtilities

December2016 April2017

PlasticsMoldingAreaPlasticsMoldingUtilities

December2016 August2017

AttachmentCScheduleofPlannedInstallationandStart‐Up

Page 1 of 1Trinity Consultants

141801.0078


ATTACHMENT D

Regulatory Applicability Discussion

P&G|AttachmentDTrinityConsultants 1

ATTACHMENT D – REGULATORY APPLICABILITY

ThissectiondocumentstheapplicabilitydeterminationsmadeforFederalandStateairqualityregulations.Themonitoring,recordkeeping,reporting,andtestingplanispresentedinAttachmentO.Inthissection,applicabilityornon‐applicabilityofthefollowingregulatoryprogramsisaddressed:

> PreventionofSignificantDeterioration(PSD)permitting;> MinorNewSourceReview;> TitleVofthe1990CleanAirActAmendments;> NewSourcePerformanceStandards(NSPS);> NationalEmissionStandardsforHazardousAirPollutants(NESHAP);and> WestVirginiaStateImplementationPlan(SIP)regulations.

Thisreviewispresentedtosupplementand/oraddclarificationtotheinformationprovidedintheWestVirginiaDepartmentofEnvironmentalProtection(DEP)Rule13(R‐13)permitapplicationforms.Inadditiontoprovidingasummaryofapplicablerequirements,thissectionoftheapplicationalsoprovidesnon‐applicabilitydeterminationsforcertainregulations,allowingtheDEPtoconfirmthatidentifiedregulationsarenotapplicabletotheproposedproject.Notethatexplanationsofnon‐applicabilityarelimitedtothoseregulationsforwhichtheremaybesomequestionofapplicabilityspecifictotheoperationsattheTablerStationfacility.Regulationsthatarecategoricallynon‐applicablearenotdiscussed(e.g.,NSPSSubpartJ,StandardsofPerformanceforPetroleumRefineries).

Prevention of Significant Deterioration (PSD) Source Classification

FederalconstructionpermittingprogramsregulatenewandmodifiedsourcesofattainmentpollutantsunderPSDandnewandmodifiedsourcesofnon‐attainmentpollutantsunderNon‐AttainmentNewSourceReview(NNSR).TheTablerStationfacilitywillbelocatedinBerkeleyCounty,WestVirginia,whichisdesignatedasinattainment/unclassifiableforallpollutants.Therefore,PSDpermittingispotentiallyapplicabletothefacility.PSDpermittinginWestVirginiaisregulatedunderTitle45,Series14,WestVirginiaCodeofStateRegulations(45CSR14).PSDpermittingappliestoconstructionofnewmajorstationarysourcesoranyphysicalchangein,orchangeinthemethodofoperationofanexistingmajorstationarysourcethatresultsinasignificantemissionsincrease.AmajorstationarysourceforPSDisdefinedas:> Anysourceinoneofthelistedsourcecategoriesinthedefinitionof“majorstationarysource”per45CSR14‐2.43

withthepotential‐to‐emit(PTE)of100tonsperyear(tpy)ormoreoftraditionallyregulatedpollutants,or> AnysourcenotinoneofthelistedsourcecategorieswithaPTEof250tpyormoreofanytraditionallyregulated

pollutant.AreviewofthelegislativebackgroundandPSDregulationsdoesnotclearlyindicateSICasthedefiningfactorforcategorizationofafacilityasachemicalprocessplant.However,EPAhashistoricallyinterpretedthecategory“chemicalprocessplants”asincludinganyactivitylistedunderSICmajorgrouping28(witharecentspecificexceptionforethanolproductionfacilities).SIC28hasabroaderscopethansiteswherechemicalprocessesareoccurring,asSIC28isdefinedasChemicalsandAlliedProducts,andnotsimplychemicals.TheAlliedProductsportionofSIC28includesmultipleactivitieswherethereisnochemicalprocessingatall,suchasphysicalblendingofingredientstomakefinishedchemicalproductstobeusedforultimateconsumptionsuchasdrugs,cosmetics,andsoaps[citedfromSIC28definition].MostoftheproposedsitewouldbeclassifiedunderSIC284,SOAP,DETERGENTS,ANDCLEANINGPREPARATIONS,PERFUMES,COSMETICS,ANDOTHERTOILETPREPARATIONS


FollowingEPA’shistoricdetermination,thesenon‐chemicalprocessareaswouldbeconsideredtobechemicalprocessplants,andthusthefacilityfallsintothegroupofsourcecategoriessubjecttoa100tpymajorsourcethreshold.Becausethefacility‐widePTEforeachpollutantislessthan100tpy,theTablerStationfacilitywillbeanewminorsourceunderPSD.Assuch,PSDpermittingisnottriggeredbythisconstructionactivity. TheTablerStationfacilityisanticipatedtoincludeadditionalprocessareasaspartoftheoverallscopeoftheTablerStationproject.Anyadditionalprocessareasrelatedtotheprojectwhicharecurrentlyundergoingdetaileddesignwillbepermittedatalaterdate.Itisanticipatedthatallphasesofthisprojectwillbepermitted,installed,andoperationalwithin5yearsofbeginningconstruction.AthoroughanalysisofthecurrentscopeoftheentirefacilityandplannedoperationsindicatesthatallphasestogetherdonottriggerPSDpermitting.

Minor New Source Review Source Classification

Theminor(orstate)NSRprogramiscodifiedin45CSR13,andistypicallyknownasanR‐13permit.TheproposedTablerStationfacilitydoesnotqualifyforanycategoricalexemptions,andthusthepotentialemissionrateforthefacilityiscomparedagainsttheemissionthresholdin45CSR13‐2.24(b)and45CSR13‐2.24(b).AscalculatedinAttachmentN,theproposedprojecttriggersminorNSRforPM,PM10,PM2.5,VOC,NOX,CO,andHAP.IncompliancewithR‐13,P&GissubmittingtheattachedpermitapplicationfortheinstallationofaconsumerproductsfacilityatTablerStation,WestVirginia.

Title V Operating Permit Program

Title40oftheCodeofFederalRegulationsPart70(40CFR70)establishesthefederalTitleVoperatingpermitprogram.WestVirginiahasincorporatedtheprovisionsofthisfederalprograminitsTitleVoperatingpermitprogramin45CSR30.ThemajorsourcethresholdswithrespecttotheWestVirginiaTitleVoperatingpermitprogramregulationsare10tonsperyear(tpy)ofasingleHAP,25tpyofanycombinationofHAPs,and100tpyofallotherregulatedpollutants.1ThepotentialemissionsofVOCarebelowthe100tpythresholdatthisfacility.Therefore,theTablerStationfacilityisnotamajorsourceforTitleVpurposes.

New Source Performance Standards

NSPSrequirenew,reconfigured,orreconstructedsourcestocontrolemissionstothelevelachievablebythebestdemonstratedtechnologyasspecifiedintheapplicableprovisions.Moreover,anysourcesubjecttoanNSPSisalsosubjecttothegeneralprovisionsofNSPSSubpartA,unlessspecificallyexcluded.FollowingisadiscussionofpotentiallyapplicablesubpartsfortheproposedemissionsourcesattheTablerStationfacility.

NSPS Subpart A – General Provisions

AnysourcesubjecttoaNSPSisalsosubjecttothegeneralprovisionsofNSPSSubpartA,unlessspecificallyexcluded.

NSPS Subpart H – Sulfuric Acid Plants

NSPSSubpartHappliestosulfuricacidproductionunits,whicharedefinedas(emphasisadded):

1EPA’sTailoringRulehadestablishedaTitleVmajorsourcethresholdof100,000tpyofgreenhousegaspollutantsorGHGs(onacarbondioxideequivalent[CO2e]basis).However,onJune23,2014,theU.S.SupremeCourtissueditsdecisioninUtilityAirRegulatoryGroupv.EPA,wherebytheCourtsaidthatEPAmaynottreatGHGsasanairpollutantforpurposesofdeterminingwhetherasourceisamajorsourcerequiredtoobtainaPSDorTitleVpermit.CaseNo.12‐1146,decidedJune23,2014.http://www.supremecourt.gov/opinions/13pdf/12‐1146_4g18.pdf.


(a) Sulfuricacidproductionunitmeansanyfacilityproducingsulfuricacidbythecontactprocessbyburningelementalsulfur,alkylationacid,hydrogensulfide,organicsulfidesandmercaptans,oracidsludge,butdoesnotincludefacilitieswhereconversiontosulfuricacidisutilizedprimarilyasameansofpreventingemissionstotheatmosphereofsulfurdioxideorothersulfurcompounds.2

ProcterandGambleintendstousethereactorsprimarilytoproducesurfactantforuseintheirproducts.ThesurfactantmakingprocessatTablerStationproducessulfuricacidtopreventsulfurdioxideemissionstotheatmosphere.Sulfuricacidistypicallyproducedduringtransitionperiodssuchasstartup,shutdown,orwhenareactorischangingovertoproduceadifferenttypeofsurfactant.However,becauseofthephasedstartupofthefacilityasawhole,ProcterandGambleanticipatesthattheremaybeperiodswhen,inordertofullyutilizetheequipment,areactormaybededicatedtosulfuricacidproduction.ThoughProcterandGamblehopestofindaninterestedbuyerforthesulfuricacid,thesulfuricacidwillnotbeproducedastheprimaryproductofthesurfactantmakingsystem.Sulfuricacidsalesarenotthefinancialobjectiveofthereactorinstallation.ThoughtheTablerStationfacilitywillproducesulfuricacid,itisnottheprimarypurposeofthesurfactantmakingoperation.Thesulfuricacidmakingisusedprimarilyasameansofpreventingsulfurdioxideemissionsfromenteringtheatmosphere,andwillnotgenerallybeproducedasastand‐aloneproduct.Therefore,theTablerStationfacilityisexemptfromSubpartH.

NSPS Subpart Dc – Steam Generating Units

TheNSPSSubpartDcapplicabilitydefinitionprovides:

(a) …theaffectedfacilitytowhichthissubpartappliesiseachsteamgeneratingunitforwhichconstruction,modification,orreconstructioniscommencedafterJune9,1989andthathasamaximumdesignheatinputcapacityof29megawatts(MW)(100millionBtuperhour(Btu/hr))orless,butgreaterthanorequalto2.6MW(10millionBtu/hr)3

Thethreemainboilersatthesitehavearatedheatinputcapacityof62MMBtu/hr,62MMBtu/hr,and31MMBtu/hrandaresubjecttothisrule.Inaddition,the11MMBtu/hrtemporaryboilerisalsosubjecttothisrule.Theboilerswillonlycombustnaturalgas.Therequirementsthatapplyfornaturalgasboilersaretorecordandmaintainrecordsoftheamountoffuelcombustedduringeachcalendarmonthandmaintaincertificationsfromthenaturalgassupplierguaranteeingsulfurcontentofthefuel.

NSPS Subpart Kb – Storage Tanks

NSPSSubpartKb,StandardsofPerformanceforVolatileOrganicLiquidStorageVessels,regulatesstoragevesselswithadesigncapacitygreaterthanorequalto75cubicmeters(m3)thatstorevolatileorganicliquids. Thestandardsareeffectiveforallfacilitiesforwhichconstruction,reconstruction,ormodificationcommencedafterJuly23,1984.Storagevesselswithacapacitygreaterthanorequalto151cubicmeters(m3) storingaliquidwithamaximumtruevaporpressure,excludingwater,lessthan3.5kilopascals(kPa)orwithacapacitygreaterthanorequalto75m3 butlessthan151m3 storingaliquidwithamaximumtruevaporpressurelessthan15.0kPaareexemptfromtherequirementsofthisrule. ThetanksattheTablerStationfacilitymeettheexemptionrequirementsofthisrule.Therefore,theTablerStationfacilityisexemptfromNSPSKb.

240CFR60.81340CFR§60.40c(a)


NSPS VVa – SOCMI Equipment Leaks

Per40CFR60.480a(b),NSPSVVaappliestoanyaffectedfacilitythatcommencesconstruction,reconstruction,ormodificationafterNovember7,2006,whereanaffectedfacilityisthegroupofallequipmentwithinaprocess.Thedefinitionof“processunit”and“equipment”areasfollowsper40CFR60.480a(f)(2):

Processunitmeanscomponentsassembledtoproduce,asintermediateorfinalproducts,oneormoreofthechemicalslistedin§60.489ofthispart.Aprocessunitcanoperateindependentlyifsuppliedwithsufficientfeedorrawmaterialsandsufficientstoragefacilitiesfortheproduct.Equipmentmeanseachpump,compressor,pressurereliefdevice,samplingconnectionsystem,open‐endedvalveorline,valve,andflangeorotherconnectorinVOCserviceandanydevicesorsystemsrequiredbythissubpart.

Theonlychemicalproducedeitherasafinalproductorasanintermediatefromthelistgivenin§60.489ofthispartattheTablerStationfacilityisdioxane(CAS#123‐91‐1),anunintendedbyproductproducedduringthesurfactantmakingprocessataverylowconcentration.Therefore,P&Ghasapotential“processunit”asdefinedunderNSPSVVa.ForpurposesofcompliancewithNSPSVVa,the“affectedfacility”isthegroupofallequipmentwithinthesurfactantsprocessunit.ThisprocessunitwillbeconstructedafterNovember7,2006.Assuch,thegroupofallequipmentinthesurfactantsprocessunitissubjecttotherequirementscodifiedinNSPSVVa.Per40CFR60.480a(d),thefollowingexemptionsareavailableunderNSPSVVa:

> Anyaffectedfacilitythathasthedesigncapacitytoproducelessthan1,000Mg/yr(1,102ton/yr)ofachemicallistedin§60.489isexemptfrom§§60.482–1athrough60.482–11a.

> Ifanaffectedfacilityproducesheavyliquidchemicalsonlyfromheavyliquidfeedorrawmaterials,thenitisexemptfrom§§60.482–1athrough60.482–11a.

> Anyaffectedfacilitythatproducesbeveragealcoholisexemptfrom§§60.482–1athrough60.482–11a.> AnyaffectedfacilitythathasnoequipmentinVOCserviceisexemptfrom§§60.482–1athrough60.482–11a.

TheP&Gsurfactantmakingprocessproducesdioxaneinextremelysmallquantitiesasanunintendedbyproduct.Lessthan1,000Mg/yearofdioxaneisproduced;thereforetheTablerStationfacilityqualifiesforthefirstexemption.Assuch,P&Gdoesnotoperatean“affectedfacility”underNSPSVVaand,assuch,P&Gisnotsubjecttotherequirementslistedin§§60.482−1athrough60.482–11a.However,P&Gisrequiredtokeeprecordsonsitetodocumenttheexemption.

NSPS III – SOCMI Air Oxidation Reactor

Per40CFR60.610(a),NSPSIIIappliestoeachaffectedfacilitythatispartofaprocessunitthatproducesanyofthechemicalslistedin40CFR60.617asaproduct,co‐product,by‐product,orintermediate.Anaffectedfacilityisanyofthefollowingforwhichconstruction,modification,orreconstructioncommencedafterOctober21,1983:4

> Eachairoxidationreactornotdischargingitsventstreamintoarecoverystream;> Eachcombinationofanairoxidationreactorandtherecoverysystemintowhichitsventstreamis

discharged;or> Eachcombinationoftwoormoreairoxidationreactorsandthecommonrecoverysystemintowhichtheir

ventstreamsaredischarged.

“Airoxidationreactor”and“processunit”aredefinedin40CFR60.611asfollows:

440CFR60.610(b)


AirOxidationReactormeansanydeviceorprocessvesselinwhichoneormoreorganicreactantsarecombinedwithair,oracombinationofairandoxygen,toproduceoneormoreorganiccompounds.Ammoxidationandoxychlorinationreactionsareincludedinthisdefinition.ProcessUnitmeansequipmentassembledandconnectedbypipesorductstoproduce,asintermediatesorfinalproducts,oneormoreofthechemicalsin§60.617.Aprocessunitcanoperateindependentlyifsuppliedwithsufficientfuelorrawmaterialsandsufficientproductstoragefacilities.

TablerStationoperationsdonotincludeanairoxidationreactorasdefinedabove,nordotheyproduceachemicallistedin40CFR60.610.Therefore,P&Gdoesnotoperatean“affectedfacility”underNSPSIIIand,assuch,TablerStationisnotsubjecttotherequirementstherein.

NSPS RRR – SOCMI Reactors

Per40CFR60.700(a),NSPSRRRappliestoeachaffectedfacilitythatispartofaprocessunitthatproducesanyofthechemicalslistedin40CFR60.707asaproduct,co‐product,by‐product,orintermediate.Anaffectedfacilityisanyofthefollowingforwhichconstruction,modification,orreconstructioncommencedafterJune29,1990:5

> Eachreactorprocessnotdischargingitsventstreamintoarecoverystream;> Eachcombinationofareactorprocessandtherecoverysystemintowhichitsventstreamisdischarged;or> Eachcombinationoftwoormorereactorprocessesandthecommonrecoverysystemintowhichtheirvent

streamsaredischarged.

“Reactorprocesses”and“processunit”aredefinedin40CFR60.701asfollows:

Reactorprocessesareunitoperationsinwhichoneormorechemicals,orreactantsotherthanair,arecombinedordecomposedinsuchawaythattheirmolecularstructuresarealteredandoneormoreneworganiccompoundsareformed.

Processunitmeansequipmentassembledandconnectedbypipesorductstoproduce,asintermediatesorfinalproducts,oneormoreofthechemicalsin§60.707.Aprocessunitcanoperateindependentlyifsuppliedwithsufficientfeedorrawmaterialsandsufficientproductstoragefacilities.

TheTablerStationfacilitywillcontainareactorprocessconstructedafterJune29,1990.Therefore,thereactorprocessmeetsthedefinitionof“affectedfacility”underNSPSRRR.However,thisreactorprocessdoesnotproduceanyoftheaffectedchemicalslistedin40CFR60.707.Assuch,theP&GreactorprocessisnotsubjectNSPSRRR.

NSPS IIII – Stationary Compression Ignition Internal Combustion Engines

Thissubpartisapplicabletoownersandoperatorsofstationarycompressionignitioninternalcombustionengines(CIICE).TherewillbefiveCIICEonsite,threeforbackup/standbyuseonly(350kilowatt[kW])andtwofirepumpengines(311horsepower[hp]).Thebackup/standbygeneratorenginesaresubjecttotheemissionstandardsinTable1ofthesubpart,whilethefirepumpenginesaresubjecttoemissionstandardsinTable4ofthesubpart.Bothkindsofenginesarerequiredtouselow‐sulfurdiesel.Thebackup/standbygeneratorengineswillonlybeusedundermaintenanceconditionsorduringalossofpowertothesite;theywillhavealimitof100hoursperyear(each)foroperationinnon‐emergencysituations.Thehoursthebackup/standbygeneratorenginesareoperatedwillbetrackedwithanon‐resettablehourmeter.Recordkeepingandmonitoringrequirementsmayapplytothebackup/standbygeneratorenginesandthefirepumpengine.

540CFR60.700(b)


NSPS JJJJ – Stationary Spark Ignition Internal Combustion Engines

Thissubpartisapplicabletoownersandoperatorsofstationarysparkignitioninternalcombustionengines(SIICE).TherewillbeoneSIICEonsiteforbackup/standbyuseonlywhichpowersa70kilowatt[kW]generator.Thebackup/standbygeneratorengineissubjecttotheemissionstandardsin40CFR1054.Thebackup/standbygeneratorenginewillonlybeusedundermaintenanceconditionsorduringalossofpowertothesite;itwillhavealimitof100hoursperyearforoperationinnon‐emergencysituations.Thehoursthebackup/standbygeneratorengineisoperatedwillbetrackedwithanon‐resettablehourmeter.Recordkeepingandmonitoringrequirementsmayapplytothebackup/standbygeneratorengine.

Non-Applicability of All Other NSPS

NSPSaredevelopedforparticularindustrialsourcecategories.AllotherNSPSarecategoricallynotapplicabletotheproposedchange.

National Emission Standards for Hazardous Air Pollutants (NEHSAP)

NationalEmissionsStandardsforHazardousAirPollutants(NESHAP),federalregulationsfoundinTitle40Part61and63oftheCFR,areemissionstandardsforHAP.NESHAPareapplicabletobothmajorsourcesofHAP(facilitiesthatexceedthemajorsourcethresholdsof10tpyofasingleHAPand25tpyofanycombinationofHAPfromstationarysources)aswellasnon‐majorsources(termed“areasources”).NESHAPapplytosourcesinspecificallyregulatedindustrialsourceclassifications(CleanAirActSection112(d))oronacase‐by‐casebasis(CleanAirActSection112(g))forfacilitiesnotregulatedasaspecificindustrialsourcetype.TheTablerStationfacilityisanareasourceofHAP.Assuch,thisdocumentonlyaddressesregulatoryapplicabilityforareasourcesanddoesnotincludeMACTstandardsformajorsources(e.g.,40CFRPart63SubpartFFFF,ortheMON).

NESHAP 4Z – Reciprocating Internal Combustion Engines

NESHAP4ZestablishesemissionlimitationsandoperatinglimitationsforHAPemittedfromstationaryreciprocatinginternalcombustionengines(RICE)locatedatmajorandareasourcesofHAP.Per40CFR6590(c)(1),newstationaryRICElocatedatanareasourcemayshowcompliancewithNESHAP4ZbybeingincompliancewithNSPS4IorNSPS4J.AllstationaryRICEP&GarenewandlocatedatanareasourceofHAPemissions.Therefore,bymaintainingcompliancewithNSPS4IorNSPS4J,P&GcandemonstratecompliancewithNESHAP4Z.

NESHAP 6J – Area Source Boilers

TheareasourceboilerNESHAPregulatesindustrial,commercial,andinstitutionalboilersthatburnsolidfossilfuel,biomass,orliquidfuel.ThefourboilersattheTablerStationfacilitywillburnnaturalgas.Per40CFR63.11237,alloftheboilersattheTablerStationfacilityqualifyasgas‐firedboilers.

Gaseousfuelsincludes,butisnotlimitedto,naturalgas,processgas,landfillgas,coalderivedgas,refinerygas,hydrogen,andbiogas.

Gas‐firedboilerincludesanyboilerthatburnsgaseousfuelsnotcombinedwithanysolidfuelsandburnsliquidfuelonlyduringperiodsofgascurtailment,gassupplyinterruption,startups,orperiodictestingonliquidfuel.Periodictestingofliquidfuelshallnotexceedacombinedtotalof48hoursduringanycalendaryear.

Gas‐firedboilersareexemptfromrequirementscontainedinthisregulation,per40CFR63.11195(e).Therefore,thefacilityisnotsubjecttoNESHAP6J.


NESHAP 6V – Chemical Manufacturing Area Sources (CMAS)

Per40CFR63.11494(a),theCMASappliesachemicalmanufacturingprocessunit(CMPU)thatmeetsthefollowingcriteria:

> TheCMPUislocatedatanareasourceofHAPemissions;and> HAPlistedinTable1oftheCMASarepresentintheCMPUasfollows:

TheCMPUusesasfeedstock,anymaterialthatcontainsquinoline,manganese,and/ortrivalentchromiumatanindividualconcentrationgreaterthan1.0percentbyweight,oranyotherTable1HAPatanindividualconcentrationgreaterthan0.1percentbyweight.TodeterminetheTable1HAPcontentoffeedstocks,youmayrelyonformulationdataprovidedbythemanufacturerorsupplier,suchastheMaterialSafetyDataSheet(MSDS)forthematerial.IftheconcentrationinanMSDSispresentedasarange,usetheupperboundoftherange.

Quinolineisgeneratedasby‐productandispresentintheCMPUinanyliquidstream(processorwaste)ataconcentrationgreaterthan1.0percentbyweight.

Hydrazineand/orTable1organicHAPotherthanquinolinearegeneratedasby‐productandarepresentintheCMPUinanyliquidstream(processorwaste),continuousprocessvent,orbatchprocessventatanindividualconcentrationgreaterthan0.1percentbyweight.

HydrazineoranyTable1HAPisproducedasaproductoftheCMPU.

TheTablerStationfacilityisanareasourceofHAPemissions.However,therearenoTable1HAPspresentinanyoftheTablerStationfacilityoperations.Therefore,thefacilityisnotsubjecttotheCMAS.

NESHAP 7B – Chemical Preparations Area Sources

Per40CFR63.11579(a),NESHAP7Bappliesifallofthefollowingconditionsaremet:

> Operateachemicalpreparationsfacility;> ThechemicalpreparationsfacilityisastationaryareasourceofHAP;and> ThechemicalpreparationsfacilityhasatleastonechemicalpreparationsoperationintargetHAPservice.

“IntargetHAPservice”isdefinedunder40CFR63.11588asfollows:

IntargetHAPservicemeansthatequipmentinthechemicalpreparationoperationeithercontains,contacts,orisprocessingtargetHAP‐containingmaterials.

Additionally,“targetHAP”aredefinedasmetalcompoundsforchromium,lead,manganese,andnickel.TheTablerStationfacilitydoesnothaveachemicalpreparationoperationthatcontains,contacts,orprocessesanymetalcompoundsforchromium,lead,manganese,and/ornickel.Therefore,theTablerStationfacilityisnotsubjecttoNESHAP7B.

Non-Applicability of All Other NESHAP

SimilartoNSPS,NESHAParedevelopedforparticularindustrialsourcecategories.AllotherNESHAParecategoricallynotapplicabletotheproposedchange.


West Virginia SIP Regulations

TheproposedprojectattheTablerStationfacilityispotentiallysubjecttoregulationscontainedintheWestVirginiaCodeofStateRegulations,Chapter45(CodeofStateRegulations).WestVirginiaregulationspotentiallyapplicabletotheproposedprojectarediscussedbelow.

45 CSR 2: Particulate Air Pollution from Combustion of Fuel in Indirect Heat Exchangers

45CSR2appliestofuelburningunits,definedasequipmentburningfuel“fortheprimarypurposeofproducingheatorpowerbyindirectheattransfer”.TheboilersattheTablerStationfacilitymeetsthisdefinitionandarethereforesubjectto45CSR2.Per45CSR2‐3,opacityofemissionsfromtheboilersshallnotexceed10percentarebasedonasixminuteblockaverage.Per45CSR2‐4,theparticulateemissionslimitforType‘b’fuelburningunits6istheproductof0.09andthetotaldesignheatinput(62MMBtu/hrand31MMBtu/hr),whichis5.58poundsperhour(lb/hr)and2.79lb/hr,respectively.

45 CSR 4: To Prevent Objectionable Odors

45CSR4‐2.01specifiesthat:

Nopersonshallcause,suffer,alloworpermitthedischargeofairpollutantswhichcauseorcontributetoanobjectionableodoratanylocationoccupiedbythepublic.

P&Gtakesprecautionstoassurecompliancewiththisrule.Accidentalorotherinfrequentemissionsofodorarenotprovisionsofthisrule.Thisregulationisnotfederallyenforceable.

45 CSR 6: To Prevent and Control Air Pollution from Combustion of Refuse

45CSR6setsforthrequirementsforlimitingemissionsfromincinerationwhichisdefinedas“thedestructionofcombustiblerefusebyburninginafurnacedesignedforthatpurpose.Forthepurposesofthisrule,thedestructionofanycombustibleliquidorgaseousmaterialbyburninginaflareorflarestack,thermaloxidizer,orthermalcatalyticoxidizerstackshallbeconsideredincineration.”Theproposedregenerativethermaloxidizermeetsthisdefinitionandisthereforesubjecttothisregulation.TheregenerativethermaloxidizerwillbesubjecttothePMemissionlimitsin45CSR6‐4.1.Inaddition,opacityfromtheregenerativethermaloxidizerwillbelimitedto20%per45CSR6‐4.3exceptasprovidedin45CFR6‐4.4.

45 CSR 7: To Prevent and Control Particulate Matter from Manufacturing Processes

45CSR7regulatesPMemissionsfrommanufacturingprocessesandassociatedoperations.45CSR7‐3,requiresa20%opacitylimitfromallprocesssourceoperations.Section45CSR7‐4andTable45‐7Asetparticulateemissionslimitsbasedonthetotalweightofallmaterialsusedbythefacility,alsoknownastheprocessweight.ThedifferentprocessareasattheTablerStationfacilityqualifyunderdifferentclassificationsaspartoftherule.Thesurfactantsareaisamineralacidproducingarea,7subjecttolimitsinTable45‐7B.Theliquidsoap,dryconsumerlaundryandcleaningproducts,andplasticsmoldingareasqualifyasType‘a’facilities.8Theutilitiesareaiscoveredunder45CSR2,andisexemptfromthisrule,accordingto45CSR5‐10.1.ThemaximumallowabletotalstackemissionrateforeachareaareshowninTableD‐1.

6Per40CSR2‐10(b):“Type'b'meansanyfuelburningunitnotclassifiedasaType'a'orType'c'unitsuchasindustrialpulverized‐fuel‐firedfurnaces,cyclonefurnaces,gas‐firedandliquid‐fuel‐firedunits.”7Themineralacid,sulfuricacid,isanincidentalbyproductofsurfactantmanufacturing.8Per45CSR7‐2.39(a),“Type‘a’meansanymanufacturingprocesssourceoperationinvolvingglassmelting,calcination,orphysicalchangeexceptasnotedintype‘c’below.”(emphasisadded)


TableD‐1.ProcessWeightRuleLimits

ProcessArea ProcessWeightRate MaxStackEmissionRate

Surfactants “MineralAcid”–Table45‐7B 35mg/m3

LiquidSoapAandB >600,000lb/hr 50lb/hr

DryConsumerLaundryandCleaningProducts

>600,000lb/hr 50lb/hr

PlasticsMaking >20,000lb/hr 16mg/m3

Utilities Exempt‐CoveredUnder45CSR2

PlasticsMakingUtilities Exempt‐CoveredUnder45CSR2

45 CSR 10: To Prevent and Control Air Pollution from the Emission of Sulfur Oxides

45CSR10appliestofuelburningunits,definedasequipmentburningfuel“fortheprimarypurposeofproducingheatorpowerbyindirectheattransfer”.TheboilersattheTablerStationfacilitymeetsthisdefinitionandisthereforesubjectto45CSR10.SinceBerkeleyCountyisinaPriorityIIIregion,per45CSR10‐3.1(e),thesulfurdioxideweightemissionsstandardistheproductof3.2andthetotaldesignheatinput(166MMBtu/hr),or531lb/hr.

45 CSR 16: Standards of Performance for New Stationary Sources

Thisruleadoptsthestandardsofperformancefornewstationarysourcessetforthin40CFRPart60byreference.PotentiallyapplicableNSPSarediscussedabove.

45 CSR 21: To Prevent and Control Air Pollution from the Emission of Volatile Organic Compounds

45CSR21isintendedtorequirereasonablyavailablecontroltechnologyforVOCsourcesinPutnam,Kanawha,Cabell,Wayne,andWoodCounties.Assuch,theserequirementsdonotapplytoVOCsourcesinBerkeleyCounty.

45 CSR 27: To Prevent and Control the Emissions of Toxic Air Pollutants

WestVirginiaregulatestheemissionsoftoxicairpollutantemissionsthrough45CSR27.Afacilitythatdischarges,ormaydischarge,atoxicpollutantintotheopenatmosphereinquantitiesgreaterthanthosedelineatedinTableAofthisruleisrequiredtoemployBestAvailableTechnology(BAT)onallchemicalprocessingequipmentemittingthepollutant.TheequipmentattheTablerStationfacilitydischargestraceamountsofbenzeneandformaldehydeduringnaturalgascombustion.However,theTablerStationfacilitydoesnotdischargebenzeneandformaldehydeinaquantitygreaterthanlistedinTableA,asshowninTableD‐2.Assuch,thisregulationdoesnotapplytotheprojectattheTablerStationfacility.


TableD‐2.EvaluationofToxicAirPollutants

Pollutant1 45CSR27EmissionRate

Threshold1(lb/yr)TablerStationEmission

Rate(lb/yr)Is45CSR27Applicable?

Acrylonitrile 500 0 NoAllylChloride 10,000 0 NoBenzene 1,000 <1 No

1,3Butadiene 500 0 NoCarbonTetrachloride 1,000 0 No

Chloroform 1,000 0 NoEthyleneDichloride 1,000 0 NoEthyleneOxide 500 0 NoFormaldehyde 1,000 <1 No

MethyleneChloride 5,000 0 NoPropyleneOxide 5,000 0 NoTrichloroethylene 10,000 0 NoVinylChloride 1,000 0 No

VinylideneChloride 2,000 0 No1From40CSR27,TableA

45 CSR 31 Confidential Information

45CSR31describestherequirementsforclaimingconfidentialinformation,andtheproceduresfordeterminationsofconfidentiality.ConfidentialitymaybeclaimediftheDirectordeterminesthatthefacilitymeetsthecriteriadetailedin45CSR31‐4.1(a‐e).P&GhasdeterminedthattheTablerStationR‐13applicationdoesnotmeetthecriteriaforconfidentialsubmittal.

45 CSR 34: Emission Standards for Hazardous Air Pollutants

ThisruleadoptstheNationalEmissionsStandardsforHazardousAirPollutants(NESHAPs)byreference.PotentiallyapplicableNESHAParediscussedabove.


ATTACHMENT E

Plot Plan

C4

C3

C5

INTERSTATE 81(VARIABLE WIDTH)

℄

℄



BU

SIN

ES

S P

AR

K D

RI V

E - R

T. 32

( VA

RIA

BLE

WID

TH

)

DB

. 916 PG

. 142

DB

. 916 PG

. 150

BU

SIN

ES

S P

AR

K D

RIV

E - R

T. 32

(VA

RIA

BLE

WI D

TH

)

DB

. 9 16 P

G. 14

2

DB

. 9 16 P

G. 15

0

℄

℄


15' BUILDING SETBACK

50' B

UIL

DI N

G S

ET

BA

CK


15' B

UILD

ING

SE

TB

AC

K


5' BUILDING SETBACK


50' B

UILD

ING

SE

TB

AC

K



100'

BU

ILD

ING

SE

TB

AC

K


25' B

UILD

ING

SE

TB

AC

K





L35

L33

L31

L30

L27

L26

L23

N 36°12'10" E 769.27'

N 04°07'56" W

361.48'

S 67°0 9

'38" E 12

73.64 ' (TO

TAL)

S 16°43'52" W 2659.34'

L21

L22

L19

C1

L18L17

L15

L14

L13

L11

L9L8

L5

L3

L2

L37

L36

L34

L29

L32

L28

L25

L20

L24

N 04°19'02" W

613.84'

C2

L16

L10

L12

L7

L6

L1

L4

N/F GILBERT S. &LINDA K. BARNEYDB. 355 PG. 733TAX MAP A14

PARCEL 9USE: RESIDENTIAL

N/F PHILIP A. &BETTY M. BARNEY

DB. 378 PG. 81TAX MAP A14PARCEL 9.7

N/F PHILIP A. &BETTY M. BARNEY

DB. 378 PG. 79TAX MAP A14PARCEL 9.6

N/F STEVE &BONITA B. BEALDB. 378 PG. 77TAX MAP A14PARCEL 9.4

PARCEL BBERKELEY COUNTY

DEVELOPMENT AUTHORITYTAX MAP A10 PARCEL 1.2

45.0180 ACRES(ADJUSTED)

USE: VACANT

N/F ALLMINE PAVING LLCDB. 952 PG. 642P.C. 15, SL. 28

TAX MAP A15 PARCEL 32USE: COMMERCIAL

N/FA&S WAREHOUSE INC.

DB. 777 PG. 376TAX MAP 14-12

DB. 508 P

GR

EEN

B

MA


BERKELEY COUNTYDEVELOPMENT AUTHORITY

TAX MAP A15 PARCEL 2"WEST PORTION"

10.6925 ACRES(ADJUSTED)

BER

KELEY C

OU

NTY

DE

VELO

PM

ENT AU

THO

RITY

TAX

MA

P A10 P

ARC

EL 1.5

US

E: VAC

AN

T

PIK

EVIE

W W

ES

T SUBD

IVISIO

N


DB

. 508 PG

. 127 TAX M

AP

A10 P

ARC

EL 2.2 N/F N

AN

CY

P. BU

RKH

AR

T

USE: RESIDENTIAL PLATCABINET 9 SLOT 189

CRESTFIELD SUBDIVISION

N/F CLARENCE LEE RIDGELYDB. 483 PG. 188

TAX MAP A10 PARCEL 116.1USE: COMMERCIAL

N/F JAMES P. & SHARON A. GARVINDB. 420 PG. 569

TAX MAP A10 PARCEL 4USE: RESIDENTIAL

N/F

CLA

RE

NC

E LEE

RID

GE

LY

DB. 596 PG

. 3

TAX

MA

P A10 PA

RC

EL 116

WINCHESTER & WESTERN RAILROAD ( DB. 409 PG. 125)

PARCEL BBERKELEY COUNTY


LOT

28

SECTIO

N 3C

PLAT CA

BIN

ET 2 SLOT 161

LOT

30

SECTIO

N 3B

PLAT CA

BIN

ET 1 SLOT 51A

LOT

25

LOT

26

LOT

27

LOT

29

LOT

124

N/F

ALB

ERT D

ARLIN

GTO

N

DB. 241 PG

. 118

DB. 436 PG

. 690

TAX

MA

P A10 PA

RC

EL 5.1

SANITARY SEWER ESMT.P.C. 14 SL. 104P.C. 15 SL. 28P.C. 112-124

75' BUFFER YARD

25' BUFFER YARD

5' BUFFER YARD

25' BU

FF

ER

YA

RD

PARCEL CBERKELEY COUNTY


USE: COMMUNICATION TOWER

ST

OR

M D

RA

INA

GE

ES

MT

.

P.C

. 14 S

L. 104

P.C

. 15 S

L. 28

P.C

. 112-1

24

100' BUFFER YARD

IRS

IRF

25' BUFFER YARD

N/FY SCOTT AND WRIGHT-MILLER JUDITH L.

DB. 555 PG. 275TAX MAP 14-11

25' BUFFER YARD

N/F

BAR

BAR

A FU

DB. 524 P

G

TAX

MA

P A10 PA

DEVELOPMENT DRIVEPRIVATE RIGHT-OF-WAY

P.C. 14, SL. 104-110

DEVELOPMENT DRIVEPRIVATE RIGHT-OF-WAY

P.C. 14, SL. 104-110

BERKELEY COUNTY DEVELOPMENT AUTHORITY"WEST PORTION"DB. 754 PG. 123

TAX MAP A15 PARCEL 2USE: VACANT

BERKELEY COUNTYDEVELOPMENT AUTHORITY

DB. 1026 PG. 26TAX MAP A10 PARCEL 1.3

USE: VACANT

WINCHESTER & WESTERN RAILROAD ( DB. 409 PG. 125)

"UNECONOMIC REMNANT" NOTED ON RIGHT OF WAY

PLANS FOR STATE PROJECTNO. X302-81/8-0.00 00

LOT

24 SEC

TIO

N 3D

PLAT CA

BIN

ET 2 SLOT 198

LOT

23

BERKELEY COUNTY DEVELOPMENT AUTHORITY"WEST PORTION"DB. 754 PG. 123

TAX MAP A15 PARCEL 2

WATERLINE ESMT.P.C. 14 SL. 104P.C. 15 SL. 28P.C. 112-124

SANITARY SEWER ESMT.P.C. 14 SL. 104P.C. 15 SL. 28P.C. 112-124

ST

OR

M D

RA

INA

GE

ES

MT

.P

.C. 14

SL

. 104

P.C

. 15 S

L. 2

8P

.C. 11

2-124

D.B

. 952 P

G. 64

2

PA

CKH

OR

SE R

OA

D

PR

ESC

RIP

TIVE R

IGH

T-OF-W

AY

PC

. 14 SL. 47

POWER LINES & POLES COVEREDBY RIGHT-OF-WAY AGREEMENT WITH

POTOMAC EDISON CO. OF WV.DB. 238 PG. 531

PC. 14 SL. 47

75' BUFFER YARD

75' BUFFER YARD

100' B

UF

FE

R Y

AR

D

50' SETBACK FROM WWRR

25' BUFFER YARD

50' SETBACKFROM WWRR

25' BUFFER YARD

UDITH L.

N/F JAMES P. & SHARON A. GARVINDB. 420 PG. 569

TAX MAP A10 PARCEL 4USE: RESIDENTIAL

100' BUFFER YARD

TANK

TEMPORARY STAGE ICONTRACTOR YARD

FUTURE BUILDING

PROPOSEDRELOCATED

CELLTOWER

LOCATION

TRAILER DROP 250 SPACES

FUELING(INTERNAL USE ONLY)

PHASE 2 CONSTRUCTION FACILITIES

PROP ACCESS ROADBY WVDOH

80' ROWADT = 2480 VPD

VEHICULAR ACCESS

RAIL YARD

PHASE 2BUILDING

CONSTRUCTIONOPERATIONS

CONSTRUCTIO

N OPERATIO

N ACCESS

RAIL YARD

PHASE ICONTRACTOR

PARKING396

SPACES(REMOVED IN

PHASE II)

PH

AS

E I

RO

AD

FU

TU

RE

TR

UC

K D

OC

KA

ND

MIS

C.

IMP

ER

VIO

US

ST

RU

CT

UR

ES

INTERSTATE 81

EX. DEVELOPMENT DRIVE

EX

. ST

EW

AR

T A

VE

EX

. MA

RT

HA

DR

IVE

BU

SIN

ES

S P

AR

K D

RIV

E C

R 8

1/8

WWRR

WWRR

PROP TRUCK

ENTRANCE ROAD

BY WVDOH

80' ROW

ADT=530 VPD

WAITINGAREA

GUARDHOUSE

TRUCKSCALES

END OFPUBLICACCESS

END OFPUBLICACCESS

GUARDHOUSE

PROP ROUNDABOUTEND OF PUBLIC

ACCESS

PROPOSEDSIDEWALK

EMERGENCYACCESS

PONDACCESSROAD

EXISTING MARTHA DRIVETO BE VACATED BEYOND

WWRR ROW

PROPOSED ACCESS BYWVDOH TO ROUTE 11ENTRANCE TRIP GENERATIONESTIMATED AT 1120 VPD

EXISTING STEWART AVE.TO BE VACATED BEYONDWWRR ROW

PHASE I PARKING427 SPACES



COURTYARD DECK

EN

TR

AN

CE

24 X 60

24 X 60

24 X 60

8 X

40

8 X

40

GUARDSHACK

STAIR

S STAIR

S LIGHT

LIGHT

ROUTE 11CONNECTORBY WVDOH

PROPOSED 10'ELECTRIC ESMT




SCALE

TAIL TRACK

CANOPY

CANOPY

POINT OFCONNECTION

POINT OFCONNECTION

MS-1A

MS-1A

PROPOSEDSIDEWALK

PROPOSEDSIDEWALK

PROPOSEDSIDEWALK

PHASE 2 CONSTRUCTION FACILITIES


CLASS 3A CONCRETEJACK PAD (TYP.)



POND ACCESS ROAD

PONDACCESSROAD

PHASE II TRAILER DROP LOT (444 SAPCES)

PROPOSEDCROSSWALK

SIGN (TYP)

PROPSTOPSIGN(TYP)

PROP STOPSIGN (TYP)

PROPSTOPSIGN(TYP)

PROPSTOPSIGN(TYP)

PROP STOPSIGN (TYP)

CG-12A

PROPOSEDWVDOH ROW

MS-1A

PROP 10' SIDEWALK

FUTURE ROAD

FUTURE BUILDING

PR

OP

10'

SID

EW

ALK

ROCK CRUSHINGOPERATIONS

BATCH PLANTOPERATIONS




FU

TU

RE

TR

UC

K D

OC

KA

ND

MIS

C.

IMP

ER

VIO

US

ST

RU

CT

UR

ES

FUTURE BUILDING

FUTURE PARKING

LIMITS OF TEMPORARYSTOCKPILE AREA




24 X 60

24 X 60

PROP 20' WL ESMT

PROP 20' WL ESMT

5 30

PROCESS WASTEWATER TANK FARM

FUTURE

FUTURE

FUTURE


ATTACHMENT F

Detailed Process Flow Diagram

Process Flow Diagram F-1: General Process

October 2016141801.0078

P&G Tabler Station WV

Utilities

Raw Materials

Surfactant Making Liquid Soap

Consumer Products (Mixing and Filling)

Dry Consumer Laundry and

Cleaning Products (Mixing and Coating)

Shipping

Plastics Molding

Plastics Molding Utilities

Neutralization Process

Finished Product Handling, Storage

and Transfer

For Onsite and Offsite Use

Raw MaterialUnloading Raw Materials

Handling, Storage and Transfer

Surfactant Making Process

Process Flow Diagram F-2: Surfactants Process

P&G Tabler Station WV

October 2016

Prepared by:Project: 141801.0078

During Startup/ShutdownChangeover

Sulfur Trioxide Absorber

Incidental By Product:

Sulfuric Acid Handling, Storage,

and Transfer

Incidental By Product: Precipitated

Acid Mix Handling, Storage, and Transfer

Sulfuric Acid and PAM Loading

Legend

Emissions

Process Flow

Sulfur Dioxide Scrubber

Fugitive

Fugitive

Fugitive

Process Flow Diagram F-3: Liquid Soap A and B Making

Process

October 2016141801.0078

P&G – WV Tabler Station

Process Flow

Legend

Air Emissions Rotoclone

Thermal Oxidizer

Bulk Material Unloading

Bulk Liquid Storage, Handling &

Transfer

Tote and Drum Unloading

Dry Unloading

Liquid Soap A Mix Tanks

Finished Product Warehouse

Finished Product Shipping

Packaging Lines

Packaging Supply

Surfactant Process Tank

Surfactants

Finished Product Tanks

Central Preweigh

From

Che

mica

ls Ar

ea

Tank

Far

ms

H2O

During Volatile Material Use

H2O

Day Process Tanks

Liquid Soap B Mix Tanks

H2O

Liquid Soap Making Process

Wastewater Flow

FugitiveFugitive

Fugitive

Fugitive

Fugitive

Fugitive

Fugitive

Process Flow Diagram F-4: Simple Dry Consumer Products A

P&G – Tabler Station WV

Solid Material Unloading

Liquids Unloading

Raw Material Addition and Preparation for

Packaging

Packaging

Process Flow

Legend

Emissions Baghouse

Solid Material Storage, Handling & Transfer Intermediate Mixing

Liquids Storage, Handling & Transfer

Packaging Supply

Finished Product to Warehouse and Shipping

Substrate

October 2016

Prepared by:Project: 141801.0078Filter

Fugitive

Fugitive

Tote and Drum UnloadingDay

Process Tanks

Fugitive

Process Flow Diagram F-5: Utilities

October 2016141801.0078


Engine ULSD Tanks

(<500 gallon)

Vehicle Refueling

ULSD Tank(5,000 gallons)

Boilers (2) – 62 MMBtu/hr, eachBoiler (1) – 31 MMBtu/hr

Temp Boiler (1) – 11 MMBtu/hr

Cooling Towers (3) – 5,117 gallons/min

13,200 gallons/min3,533 gallons/min

Fire Pump Engine311 hp

Fire Pump Engine311 hp

Backup/Standby

Generator350 kW

Backup/Standby

Generator350 kW

Backup/Standby

Generator350 kW

Warehouse Heating

14-20 MMBtu/hr (total)

TEMP

Water PretreatmentWastewater Pretreatment

Emissions

Fugitive

Fugitive

Fugitive

Fugitive

Fugitive Fugitive Fugitive

Legend

Process Flow Diagram F-6: Plastics Molding Supplier

October 2016141801.0078


Cooling Tower

Backup/Standby

Generator

Surge BinsStorage Silos

Pressing and Molding

OperationsTransport to

Production Area

Process Flow

Legend

EmissionsCyclone

Space Heating

Parts Washing

Railcar Unloading

Fugitive

General Process Cleaning

Plastic Regrind


ATTACHMENT G

Process Description

P&G|AttachmentGTrinityConsultants 1

ATTACHMENT G – PROCESS DESCRIPTION

Aspartofthisproject,P&Gproposestoinstallequipmentinthefollowingdifferentbusinessareas:> SurfactantManufacturing;> LiquidSoapMakingAandB;> DryConsumerProductsA;> PlasticsMolding;and> Utilities.Eachofthesebusinessareasarediscussedingreaterdetailinthereport.


ATTACHMENT H

Materials Safety Data Sheets

Attachment HTabler Station

TablerStationSiteMaterialListing

MaterialNameProcessAreas18MMSiliconeALSAMTriquatAmodimethicone(10TAS)AXSBeautyCare(HairCare,BodyWash)Perfumes(multiple)BeautyCareFinishedProducts(multiple)BentoniteClayBenzylAlcoholBetaineBetzdearbornIEC2C24AE1AlcoholEthoxylateC24AE3AlcoholEthoxylateCaustic,50%CetylAlcoholCO1214CorrshieldMD4103CuttingOilThreadCuttingLubricantDADMACDC‐1865DC‐1872DCMCDiethyleneglycol(heattransferfluid)Dimethicone(10,000cSt)Dimethicone(15‐85)DM5500PolydimethylSiloxaneEmulsionEDDSEjectorPinEthanol,denaturedFattyAcidFlogardPOT6183FoodGradeSiliconeFormoleneHB5502FFormoleneHighDensityPolyethylene‐HexaneCopolymerGengardGN7112GlycerinGlydantHydrochloricAcidHydroForceFoamingCitrusAllPurposeCleanerIMSPaintableMistInhibitorAZ8101KathonKRALaureth‐4L‐GlutamicAcidLinoleMarlexKN226PolyethyleneMarlexKN226PolyethyleneMiramod‐BulkPerfumeNalco1720Nalco1820Nalco3DT265

1 of 6Trinity Consultants

141801.0078



MaterialNameNalco7320Nalco7330NalcoNexguard22310NeolonePanthenolPantylPerfumeMicroCapsulesPerfumes(multiple)PetrolatumPhenoxyethanolPolyethyleneResinPolypropyleneHomopolymerPolyquaterium‐10PQASPrecipatedAcidMix(PAM)PropyleneGlycol(heattransferfluid)S2TSSteolTD402‐65SAPDMASimpleGreenAll‐PurposeCleanerSlideMoldCleanerPlusDegreaser4SlideMoldShieldCylinderSlideResinRemoverAerosolSlideSuperGreaseSodiumHypochloriteSolutionSodiumLaurethSulfateSLE1SSodiumLaurethSulfateSLE3SSodiumLaurylSulfateSLSSpectrusNX1100StearylAlcoholStepTwoRustStopperSulfuricAcidSuperGreaseAerosolSXSTDA‐3UltimateUV390‐1UltraLowSulfurDieselFuelWhiteSilver‐3

LabChemicals(Deminimis)0.01NHydrochloricAcid0.01NIodineSolution0.01NSodiumHydroxide0.01NSodiumThiosulfate0.025MSodiumSulfate0.04NIodineSolution0.04NIodineSolution0.05NSodiumHydroxide0.1NEDTADisodiumSalt0.1NHydrochloricAcid0.1NHydrochloricAcidinIPA0.1NIodineSolution0.1NPerchloricAcidinAceticAcid0.1NSilverNitrate


141801.0078



MaterialName0.1NSodiumHydroxide0.1NSodiumThiosulfate0.1NSulfuricAcid0.25NSodiumHydroxide0.2MHydrochloricAcid0.5NHydrochloricAcid0.5NPotassiumHydroxide1%HydrochloricAcid1,3‐dioxane1,3‐Butanediol(butyleneglycol)1,4‐dioxane10%SodiumHydroxide1000mg/LFestandard1000ppmIronindiluteacid1‐Chlorodocosane(C22‐Cl)1‐Chloroeicosane(C20‐Cl)1‐Chlorohexadecane1‐Chlorooctadecane1‐Docosanol1‐Dodecanol1‐Eicosanol1‐Hexadecanol1NHydrochloricAcid1NSodiumHydroxide1NSulfuricAcid1‐Nonadecanol1‐Octadecanol1‐Pentadecanol1‐Tetracosanol1‐Tetradecanol25%ActiveAE3S28‐30%StrongAmmoniaSolution2‐Phenoxyethanol37%FormaldehydeSolution50%SodiumHydroxide6mLx1000mgSAXSPEcartridge7.5%HydrogenPeroxide90%LA‐7AEAbsoluteEthanolAcc‐FluorReagentKitAceticAcidAceticAcid(HPLCGrade)AcetoneAcetonitrile(HPLCGrade)AcetylacetoneAcetyleneGasAE3SAmberliteMB‐1IonExchangeResinAmmoniumAcetateAmmoniumChlorideAmmoniumHydroxideAmmoniumXyleneSulphonateAquamerckFormaldydeTestKit(0.1ppm)


141801.0078



MaterialNameBenzoicAcidBenzylAlcoholBenzylaldehydeBF3/MethanolBromocresolGreenIndicatorBromothymolBlueIndicatorButan‐2‐olButylAlcoholButylParabenCaffeine,anhydrousCalciumChlorideDihydateCalibrationStdCanonOilStandardN140CanonOilStandardN250ChloroformChromotropicAcidCitricAcidMonohydrateComposite5VolumetricCoulomatAGD6CylcomethiconeDecamethylpentasiloxane(D5Cyclomethicone)DecanoicAcidDiethyleneGlycolDiethyleneGlycolDimidiumBromideDiphenyloxideDipropyleneGlycolDishwashingDetergentDisodiumDihydrogenEthyleneDiamineTetraAcetateDihydrateDisodiumHydrogenPhosphateAnhydrousDisodiumHydrogenPhosphateHeptahydrateDisperseRed17ReferenceStdDisulfineBlueVNDNPHDodecanolD‐PanthenolD‐PanthenylEthylEtherDryMethanolEicosanoicAcidElaidicAcidElectrodeReferenceSolutionEriochromeBlackErythorbicAcidEthoxylatedAlcoholEthyleneGlycolEthyleneGlycolEthyleneGlycolDistearateFerricAmmoniumSulfateFerricChlorideHexahydrateFerroVerIronReagentPowderPillowsFIDCheckSampleFilterPaperFinishedPerfumeOil


141801.0078



MaterialNameFlavorStandardFluorenoneFormicAcidGlycerinGlycineHeptadecanoicAcidHexadecanolHexadecylHexadecanoateHexamethyltrisiloxane(D3Cyclomethicone)HexaneHyamine1622HydrochloricAcidHydrogenPeroxide(30%)HydroxylamineHydrochlorideIodineIPBCStandardIsooctaneIsopropylAlcoholKathonCG/ICPII®(CG/ICPII)StandardLauricAcidLaurinaldehydeLeadNitrateLinoleicAcidMerckoquantFormaldehydeTestKit(10ppm)MethanolMethanol(HPLCGrade)MethylIsobutylKetoneMethylOrangeIndicatorSolutionMethylParabenMethylRedIndicatorMethyleneChlorideMethyleneChloride(HPLCGrade)MineralOil,NujolMyristicAcidN,N‐Dimethyl‐n‐hexadecylamine(C16DMA)N,N‐Dimethyl‐n‐octadecylamine(C18DMA)NeoloneRMn‐HeptaneNicotinamideNitricAcidNitrousOxideGasn‐Pentacosanen‐TricosaneOctamethyltetrasiloxane(D4Cyclomethicone)OctanoicAcidOleicAcido‐PhenanthrolinePalmiticAcidPalmitoleicAcidPapersamplecupswithlidsPentadecanolPerfumeBlottersPerfumeMaterialStandard


141801.0078



MaterialNamePerfumeRawMaterialsPetrolatumPetroleumEtherpH10BufferpH4BufferpH7BufferPhenolphthaleinSolutionPhosphateSpectroquantKitPhosphoricAcidPhosphoricAcid(HPLCGrade)Plasticsamplecupswithlidsp‐Nitrophenol,indicatorPotassiumBiphthalatePotassiumBromidePowderPotassiumChloratePotassiumChromateIndicatorPotassiumDihydrogenPhosphatePotassiumhexacyanoferrate(II)Potassiumhexacyanoferrate(III)PotassiumHydrogenPhthalatePotassiumHydroxide(pellets)PotassiumIodidePropylParabenSalicylAlcoholsiliconeanti‐foamSodiumChlorideSodiumDihydrogenPhosphateMonohydrateSodiumLaurylSulfateSodiumSulfateSodiumThiosulfateSPBrandMICROSqualaneStarchIndicatorStearicAcidSulfuricAcidSulfuricAcid(<0.1ppmChloride)SylonBFTTargetAppearanceStdTargetOdorStandardsTetradecanolTetrahydrofuranTolueneTridecanoicAcidTridecanolTrisodiumCitrateDihydrateTritonX‐100TrizmaBaseWaterStandard


141801.0078


ATTACHMENT I

Emission Units Table

Attachment ITabler Station

EmissionUnitID1

EmissionPointID2

EmissionUnitDescriptionYear

Installed/Modified

DesignCapacityType3anddateofChange

ControlDevice4

1S 1E SurfactantMakingProcess 2017 3,000gal/hr New 1C

2S 2E SurfactantMakingProcess 2017 3,000gal/hr New 2C

3S 3E SurfactantTanks 2017 120,762gal New ‐‐4S 4E SurfactantTanks 2017 48,345gal New ‐‐5S 5E SurfactantTanks 2017 40,109gal New ‐‐6S 6E SurfactantTanks 2017 40,109gal New ‐‐7S 7E SurfactantTanks 2017 15,125gal New ‐‐8S 8E SurfactantTanks 2017 15,125gal New ‐‐9S 9E SurfactantTanks 2017 15,125gal New ‐‐10S 10E SurfactantTanks 2017 72,475gal New ‐‐11S 11E SurfactantTanks 2017 72,475gal New ‐‐12S 12E SurfactantTanks 2017 72,475gal New ‐‐13S 13E SurfactantTanks 2017 72,475gal New ‐‐14S 14E SurfactantTanks 2017 72,475gal New ‐‐15S 15E SurfactantTanks 2017 72,475gal New ‐‐16S 16E SurfactantTanks 2017 26,083gal New ‐‐17S 17E SurfactantTanks 2017 15,125gal New ‐‐18S 18E SurfactantTanks 2017 15,125gal New ‐‐19S 19E SurfactantBulkLiquidTransfer 2017 17,150,000gal/yr New ‐‐20S 20E LiquidSoapAandBTanks 2017 39,626gal New ‐‐21S 21E LiquidSoapAandBTanks 2017 39,626gal New ‐‐22S 22E LiquidSoapAandBTanks 2017 39,626gal New ‐‐23S 23E LiquidSoapAandBTanks 2017 7,925gal New ‐‐24S 24E LiquidSoapAandBTanks 2017 7,925gal New ‐‐25S 25E LiquidSoapAandBTanks 2017 39,626gal New ‐‐26S 26E LiquidSoapAandBTanks 2017 15,850gal New ‐‐27S 27E LiquidSoapAandBTanks 2017 39,626gal New ‐‐28S 28E LiquidSoapAandBTanks 2017 26,417gal New ‐‐29S 29E LiquidSoapAandBTanks 2017 15,850gal New ‐‐30S 30E LiquidSoapAandBTanks 2017 26,417gal New ‐‐31S 31E LiquidSoapAandBTanks 2017 15,850gal New ‐‐32S 32E LiquidSoapAandBTanks 2017 15,850gal New ‐‐33S 33E LiquidSoapAandBTanks 2017 7,925gal New ‐‐34S 34E LiquidSoapAandBTanks 2017 7,925gal New ‐‐35S 35E LiquidSoapAandBTanks 2017 7,925gal New ‐‐36S 36E LiquidSoapAandBTanks 2017 7,925gal New ‐‐37S 37E LiquidSoapAandBTanks 2017 7,925gal New ‐‐50S 50E LiquidSoapAandBTanks 2017 7,925gal New ‐‐56S 56E LiquidSoapAandBTanks 2017 7,275gal New ‐‐53S 53E LiquidSoapAandBTanks 2017 7,925gal New ‐‐38S 38E LiquidSoapAandBTanks 2017 396gal New ‐‐40S 40E LiquidSoapAandBTanks 2017 396gal New ‐‐41S 41E LiquidSoapAandBTanks 2017 396gal New ‐‐42S 42E LiquidSoapAandBTanks 2017 396gal New ‐‐43S 43E LiquidSoapAandBTanks 2017 396gal New ‐‐44S 44E LiquidSoapAandBTanks 2017 396gal New ‐‐45S 45E LiquidSoapAandBTanks 2017 396gal New ‐‐46S 46E LiquidSoapAandBTanks 2017 396gal New ‐‐47S 47E LiquidSoapAandBTanks 2017 396gal New ‐‐51S 51E LiquidSoapAandBTanks 2017 396gal New ‐‐52S 52E LiquidSoapAandBTanks 2017 396gal New ‐‐54S 54E LiquidSoapAandBTanks 2017 660gal New ‐‐55S 55E LiquidSoapAandBTanks 2017 396gal New ‐‐57S 57E LiquidSoapAandBTanks 2017 1,057gal New ‐‐59S 59E LiquidSoapAandBTanks 2017 396gal New ‐‐60S 60E LiquidSoapAandBTanks 2017 132gal New ‐‐61S 61E LiquidSoapAandBTanks 2017 396gal New ‐‐63S 63E LiquidSoapAandBTanks 2017 396gal New ‐‐64S 64E LiquidSoapAandBTanks 2017 396gal New ‐‐65S 65E LiquidSoapAandBTanks 2017 396gal New ‐‐66S 66E LiquidSoapAandBTanks 2017 396gal New ‐‐67S 67E LiquidSoapAandBTanks 2017 396gal New ‐‐68S 68E LiquidSoapAandBTanks 2017 396gal New ‐‐69S 69E LiquidSoapAandBTanks 2017 396gal New ‐‐70S 70E LiquidSoapAandBTanks 2017 396gal New ‐‐71S 71E LiquidSoapAandBTanks 2017 396gal New ‐‐72S 72E LiquidSoapAandBTanks 2017 396gal New ‐‐73S 73E LiquidSoapAandBTanks 2017 396gal New ‐‐74S 74E LiquidSoapAandBTanks 2017 396gal New ‐‐75S 75E LiquidSoapAandBTanks 2017 396gal New ‐‐76S 76E LiquidSoapAandBTanks 2017 396gal New ‐‐77S 77E LiquidSoapAandBTanks 2017 396gal New ‐‐87S 87E LiquidSoapAandBTanks 2017 1,585gal New ‐‐88S 88E LiquidSoapAandBTanks 2017 1,585gal New ‐‐89S 89E LiquidSoapAandBTanks 2017 1,585gal New ‐‐90S 90E LiquidSoapAandBTanks 2017 1,585gal New ‐‐91S 91E LiquidSoapAandBTanks 2017 1,585gal New ‐‐92S 92E LiquidSoapAandBTanks 2017 1,585gal New ‐‐93S 93E LiquidSoapAandBTanks 2017 1,585gal New ‐‐94S 94E LiquidSoapAandBTanks 2017 1,585gal New ‐‐94bS 94bE LiquidSoapAandBTanks 2017 1,585gal New ‐‐94cS 94cE LiquidSoapAandBTanks 2017 1,585gal New ‐‐94dS 94dE LiquidSoapAandBTanks 2017 1,585gal New ‐‐94eS 94eE LiquidSoapAandBTanks 2017 1,585gal New ‐‐95S 95E LiquidSoapAandBTanks 2017 1,585gal New ‐‐96S 96E LiquidSoapAandBTanks 2017 1,585gal New ‐‐97S 97E LiquidSoapAandBTanks 2017 1,585gal New ‐‐98S 98E LiquidSoapAandBTanks 2017 1,585gal New ‐‐99S 99E LiquidSoapAandBTanks 2017 1,585gal New ‐‐100S 100E LiquidSoapAandBTanks 2017 1,585gal New ‐‐101S 101E LiquidSoapAandBTanks 2017 1,585gal New ‐‐102S 102E LiquidSoapAandBTanks 2017 1,585gal New ‐‐103S 103E LiquidSoapAandBTanks 2017 1,585gal New ‐‐104S 104E LiquidSoapAandBTanks 2017 1,585gal New ‐‐105S 105E LiquidSoapAandBTanks 2017 1,585gal New ‐‐106S 106E LiquidSoapAandBTanks 2017 1,585gal New ‐‐

AttachmentIEmissionUnitsTable

(includesallemissionunitsandairpollutioncontroldevicesthatwillbepartofthispermitapplicationreview,regardlessofpermittingstatus)


141801.0078


EmissionUnitID1

EmissionPointID2


Installed/Modified


ControlDevice4



107S 107E LiquidSoapAandBTanks 2017 1,585gal New ‐‐108S 108E LiquidSoapAandBTanks 2017 1,585gal New ‐‐109S 109E LiquidSoapAandBTanks 2017 1,585gal New ‐‐110S 110E LiquidSoapAandBTanks 2017 1,585gal New ‐‐111S 111E LiquidSoapAandBTanks 2017 1,585gal New ‐‐112S 112E LiquidSoapAandBTanks 2017 1,585gal New ‐‐113S 113E LiquidSoapAandBTanks 2017 1,585gal New ‐‐114S 114E LiquidSoapAandBTanks 2017 1,585gal New ‐‐115S 115E LiquidSoapAandBTanks 2017 1,585gal New ‐‐116S 116E LiquidSoapAandBTanks 2017 1,585gal New ‐‐117S 117E LiquidSoapAandBTanks 2017 1,585gal New ‐‐118S 118E LiquidSoapAandBTanks 2017 1,585gal New ‐‐119S 119E LiquidSoapAandBPacking/Filling 2017 139,798,617gal/yr New ‐‐120S Mixer1forPremixProcess1 2017 New121S Mixer2forPremixProcess1 2017 New122S PremixTank1forPremixProcess1 2017 New123S PremixTank2forPremixProcess1 2017 New124S Mixer1forLiquidSoapBProcess1 2017 New125S ProcessTank1forLiquidSoapBProcess1 2017 New126S ProcessTank2forLiquidSoapBProcess1 2017 New127S ProcessTank3forLiquidSoapBProcess1 2017 New128S Mixer1forLiquidSoapBProcess2 2017 New129S ProcessTank1forLiquidSoapBProcess2 2017 New130S ProcessTank2forLiquidSoapBProcess2 2017 New131S ProcessTank3forLiquidSoapBProcess2 2017 New132S Mixer1forLiquidSoapBProcess3 2017 New133S ProcessTank1forLiquidSoapBProcess3 2017 New134S ProcessTank2forLiquidSoapBProcess3 2017 New135S ProcessTank3forLiquidSoapBProcess3 2017 New136S PreweighStation1 2017 New137S PreweighStation2 2017 New138S PreweighStation3 2017 New139S PreweighStation4 2017 New140S PreweighStation5 2017 New141S PreweighStation6 2017 New142S PreweighStation7 2017 New143S PreweighStation8 2017 New144S SamplingStation 2017 New145S 126E HotMixTankforLiquidSoapAProcess1 2017 20,611,765cf/year New 14C146S Mixer1forLiquidSoapAProcess1 2017 New147S ProcessTank1forLiquidSoapAProcess1 2017 New148S ProcessTank2forLiquidSoapAProcess1 2017 New149S 126E HotMixTankforLiquidSoapAProcess2 2017 20,611,765cf/year New 14C150S Mixer1forLiquidSoapAProcess2 2017 New151S ProcessTank1forLiquidSoapAProcess2 2017 New152S ProcessTank2forLiquidSoapAProcess2 2017 New153S 126E HotMixTankforLiquidSoapAProcess3 2017 20,611,765cf/year New 14C154S Mixer1forLiquidSoapAProcess3 2017 New155S ProcessTank1forLiquidSoapAProcess3 2017 New156S ProcessTank2forLiquidSoapAProcess3 2017 New157S 126E HotMixTankforLiquidSoapAProcess4 2017 20,611,765cf/year New 14C158S Mixer1forLiquidSoapAProcess4 2017 New159S ProcessTank1forLiquidSoapAProcess4 2017 New160S ProcessTank2forLiquidSoapAProcess4 2017 New161S ProcessTank1forLiquidSoapBProcess4 2017 New162S ProcessTank2forLiquidSoapBProcess4 2017 New163S 132E DryConsumerLaundryandCleaningProductsATanks 2017 42,879gal New ‐‐164S 133E DryConsumerLaundryandCleaningProductsATanks 2017 37,641gal New ‐‐165S 134E DryConsumerLaundryandCleaningProductsATanks 2017 6,809gal New ‐‐166S 135E DryConsumerLaundryandCleaningProductsATanks 2017 396gal New ‐‐167S 136E DryConsumerLaundryandCleaningProductsATanks 2017 396gal New ‐‐168S 137E DryConsumerLaundryandCleaningProductsATanks 2017 396gal New ‐‐169S 138E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐170S 139E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐171S 140E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐172S 141E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐173S 142E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐174S 143E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐175S 144E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐176S 145E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐177S 146E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐178S 147E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐179S 148E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐180S 149E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐181S 150E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐182S 151E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐183S 152E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐184S 153E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐185S 154E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐186S 155E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐187S 156E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐188S 157E DryConsumerLaundryandCleaningProductsATanks 2017 181gal New ‐‐189S 158E DryConsumerLaundryandCleaningProductsAParticulateControl1 2017 17,450scfm New 15C190S 159E DryConsumerLaundryandCleaningProductsAParticulateControl2 2017 17,450scfm New 16C191S 160E DryConsumerLaundryandCleaningProductsAParticulateControl3 2017 17,450scfm New 17C192S 161E DryConsumerLaundryandCleaningProductsAParticulateControl4 2017 17,450scfm New 18C193S 162E DryConsumerLaundryandCleaningProductsAParticulateControl5 2017 17,450scfm New 19C194S 163E DryConsumerLaundryandCleaningProductsAParticulateControl6 2017 8,000scfm New 20C195S 164E DryConsumerLaundryandCleaningProductsAAdditive1 2017 109ft/s New ‐‐196S 165E Boiler1 2017 62MMBtu/hr New ‐‐197S 166E Boiler2 2017 62MMBtu/hr New ‐‐198S 167E Boiler3 2017 31MMBtu/hr New ‐‐199S 168E TemporaryBoiler 2017 11MMBtu/hr New ‐‐200S 169E CoolingTower 2017 331Mgal/hr New ‐‐201S 170E CoolingTower 2017 792Mgal/hr New ‐‐202S 171E CoolingTower 2017 212Mgal/hr New ‐‐

127E

128E

129E

130E

131E

9C

10C

11C

12C

13C

1,655,640,000scf/yr

919,800,000scf/yr

3C

121E

122E

123E

4C

5C

6C

124E

125E

525,600,000scf/yr

525,600,000scf/yr

120E

8C

7C

919,800,000scf/yr

919,800,000scf/yr

1,603,080,000scf/yr

735,840,000scf/yr

1,182,600,000scf/yr

2,496,600,000scf/yr

2,496,600,000scf/yr


141801.0078


EmissionUnitID1

EmissionPointID2


Installed/Modified


ControlDevice4



203S 172E FirePumpEngine 2017 311hp New ‐‐204S 173E FirePumpEngine 2017 311hp New ‐‐205S 174E Backup/StandbyPowerGenerator 2017 350kW New ‐‐206S 175E Backup/StandbyPowerGenerator 2017 350kW New ‐‐207S 176E Backup/StandbyPowerGenerator 2017 350kW New ‐‐208S 177E FuelTanks 2017 5,000gal New ‐‐210S 179E WarehouseHeater 2017 3.05MMBtu/hr New ‐‐211S 180E WarehouseHeater 2017 3.05MMBtu/hr New ‐‐212S 181E WarehouseHeater 2017 3.05MMBtu/hr New ‐‐213S 182E WarehouseHeater 2017 3.05MMBtu/hr New ‐‐214S 183E WarehouseHeater 2017 3.05MMBtu/hr New ‐‐215S 184E WarehouseHeater 2017 3.05MMBtu/hr New ‐‐216S 185E WaterPretreatmentChemicals 2017 174,928kg/yr New ‐‐217S 186E RailcarUnloading1 2017 New 21C218S 187E RailcarUnloading2 2017 New 22C219S 188E RailcarUnloading3 2017 New 23C220S 189E RailcarUnloading4 2017 New 24C221S 190E RailcarUnloading5 2017 New 25C222S 191E StorageSilo1 2017 New ‐‐223S 192E StorageSilo2 2017 New ‐‐224S 193E StorageSilo3 2017 New ‐‐225S 194E StorageSilo4 2017 New ‐‐226S 195E StorageSilo5 2017 New ‐‐227S 196E StorageSilo6 2017 New ‐‐228S 197E StorageSilo7 2017 New ‐‐229S 198E StorageSilo8 2017 New ‐‐230S 199E StorageSilo9 2017 New ‐‐231S 200E StorageSilo10 2017 New ‐‐232S 201E StorageSilo11 2017 New ‐‐233S 202E StorageSilo12 2017 New ‐‐234S 203E StorageSilo13 2017 New ‐‐235S 204E StorageSilo14 2017 New ‐‐236S 205E StorageSilo15 2017 New ‐‐237S 206E StorageSilo16 2017 New ‐‐238S 207E StorageSilo17 2017 New ‐‐239S 208E StorageSilo18 2017 New ‐‐240S 209E StorageSilo19 2017 New ‐‐241S 210E StorageSilo20 2017 New ‐‐242S 211E StorageSilo21 2017 New ‐‐243S 212E StorageSilo22 2017 New ‐‐244S 213E StorageSilo23 2017 New ‐‐245S 214E StorageSilo24 2017 New ‐‐246S 215E PlasticRegrind 2017 32,000tons/year New 26C247S 216E FormingVOC 2017 100,000tons/year New ‐‐248S 217E PartsWashing/ProcessCleaning 2017 6tons/year New ‐‐249S 218E SpaceHeater1 2017 5MMBtu/hr New ‐‐250S 219E SpaceHeater2 2017 5MMBtu/hr New ‐‐251S 220E SpaceHeater3 2017 2.5MMBtu/hr New ‐‐252S 221E SpaceHeater4 2017 2.5MMBtu/hr New ‐‐253S 222E SpaceHeater5 2017 1MMBtu/hr New ‐‐254S 223E SpaceHeater6 2017 1MMBtu/hr New ‐‐255S 224E CoolingTower 2017 7,000gpm New ‐‐256S 225E BackupGenerator 2017 0.2MMBtu/hr New ‐‐257S 226E PrintingInk 2017 3,430lb/year New258S 227E CasePackingGlue 2017 690,080lb/year New

100,000tons/year

100,000tons/year

4)ForControlDevicesusethefollowingnumberingsystem:1C,2C,3C,...orotherappropriatedesignation.

1)ForEmissionUnits(orSources)usethefollowingnumberingsystem:1S,2S,3S,...orotherappropriatedesignation2)ForEmissionPointsusethefollowingnumberingsystem:1E,2E,3E,...orotherappropriatedesignation.3)New,modification,removal


141801.0078


EmissionUnitID1

EmissionPointID2 EmissionUnitDescription

3S‐5S 3E‐5E SurfactantTanks7S‐18S 7E‐18E SurfactantTanks19S 19E SurfactantBulkLiquidTransfer

20S‐31S 20E‐31E LiquidSoapAandBTanks33S‐37S 33E‐37E LiquidSoapAandBTanks38S‐118S 38E‐118E LiquidSoapAandBTanks119S 119E LiquidSoapAandBPacking/Filling161S 131E ProcessTank1forLiquidSoapBProcess4162S 131E ProcessTank2forLiquidSoapBProcess4

163S‐188S 163E‐188E DryConsumerLaundryandCleaningProductsATanks189S 189E DryConsumerLaundryandCleaningProductsAParticulateControl1190S 190E DryConsumerLaundryandCleaningProductsAParticulateControl2191S 191E DryConsumerLaundryandCleaningProductsAParticulateControl3208S 177E FuelTanksn/a n/a HaulRoadsn/a n/a SteamVentingSystemforSanitizationofEquipmentforLiquidSoapAandBn/a n/a PMemissionsfromformingoperations‐occurinsidebuilding,noaccesstoopenair(45CSR7)n/a n/a PMemissionsfromtransportationoperations‐occurinsidebuilding,noaccesstoopenair(45CSR7)n/a n/a PrintingInkn/a n/a CasePackingGluen/a n/a Additionaldeminimissourcesfrom45CSR13,Table45‐13b

AttachmentISourcesofMinorSignificanceEmissionUnitsTable(<0.5tpy)


141801.0078


ATTACHMENT J

Emission Points Data Summary Sheet

Attachment JTabler Station

IDNo. Source IDNo. DeviceType ShortTerm2 Max(hr/yr) lb/hr ton/yr lb/hr ton/yr

NOX 1.6 2.3CO 6.6E‐01 2.4E‐02SO2 2.1 8.2E‐01VOC 1.8 2.1PM 2.7 1.4E+01

PM10/PM2.5 2.7 13.8H2SO4 8.5 11.7HAP 5.3E‐04 5.3E‐04NOX 1.6 2.3

CO 6.6E‐01 2.4E‐02SO2 2.1 8.2E‐01

VOC 1.8 2.0

PM 2.7 9.8PM10/PM2.5 2.7 9.8H2SO4 8.5 7.8

HAP 5.3E‐04 5.3E‐04

VOC 2.8E‐01 1.2 2.8E‐01 1.2 GasO‐EPATanks

H2SO4 3.5E‐04 1.5E‐03 3.5E‐04 1.5E‐03 GasO‐EPATanks

HAP 2.1E‐02 9.1E‐02 2.1E‐02 9.1E‐02 Gas EEVOC 1.2E‐02 5.2E‐02 1.2E‐02 5.2E‐02 Gas O‐AP‐42H2SO4 5.5E‐04 2.4E‐03 5.5E‐04 2.4E‐03 Gas O‐AP‐42

20E‐118EUpward

VerticalStackN/A

LiquidSoapAandBTanks

N/A N/A N/A N/A VOC 4.26E‐01 2.6 4.26E‐01 2.6 GasO‐EPATanks

119EUpward

VerticalStackN/A

LiquidSoapAandBPacking/Filling

N/A N/A N/A N/A VOC 2.5E‐04 1.1E‐03 2.5E‐04 1.1E‐03 Gas O‐AP‐42

PM/PM10/PM2.5 3.9E‐01 1.69 Gas EE

VOC 2.0E‐01 8.59E‐01 Gas EE

PM/PM10/PM2.5 8.1E‐01 3.6 Gas EE

VOC 3.64E‐01 1.6 Gas EE

PM/PM10/PM2.5 8.1E‐01 3.6 Gas EE

VOC 4.40E‐01 1.9 Gas EE

PM/PM10/PM2.5 5.4E‐01 2.4 Gas EE

VOC 3.64E‐01 1.6 Gas EE

PM/PM10/PM2.5 1.7E‐01 7.51E‐01 Gas EEVOC ‐‐ ‐‐ Gas EE

PM/PM10/PM2.5 1.7E‐01 7.51E‐01 Gas EEVOC ‐‐ ‐‐ Gas EE

PM/PM10/PM2.5 1.42 6.2 Gas EE

VOC 6.26 27.4 Gas MB

125EUpward

VerticalStack8C PreweighGroup2 N/A N/A N/A N/A

N/A N/A N/A Gas

AttachmentJEMISSIONPOINTSSUMMARYSHEET

Table1:EmissionsData

EmissionPointIDNo.(MustmatchEmission

UnitsTable&PlotPlan)

EmissionPointType1

EmissionUnitVentedThroughThisPoint(MustmatchEmissionUnits

Table&PlotPlan)

AirPollutionControlDevice(MustmatchEmissionUnits

Table&PlotPlan)

VentTimeforEmissionUnit(ChemicalProcessesonly)

AllRegulatedPollutants‐Chemical

Name/CAS3(SpeciateVOCsandHAPS)

MaximumPotentialUncontrolledEmissions4

MaximumPotentialControlledEmissions5

EmissionFormorPhase(At

exitconditions,Solid,LiquidorGas/Vapor)

Est.MethodUsed6

EmissionConcentration7(ppmvormg/m4)

3E‐18EUpward

VerticalStackN/A SurfactantTanks N/A N/A N/A N/A

O‐VendorandAP‐42

2EUpward

VerticalStack2C

SurfactantMakingProcess

N/A N/A N/A N/A GasO‐VendorandAP‐42

1EUpward

VerticalStack1C

SurfactantMakingProcess

N/A

120EUpward

VerticalStack3C PremixProcess1 N/A N/A N/A N/A

19EUpward

VerticalStackN/A

SurfactantBulkLiquidTransfer

N/A N/A N/A N/A

N/A N/A

122EUpward

VerticalStack5C

LiquidSoapBProcess2

N/A N/A N/A N/A

121EUpward

VerticalStack4C

LiquidSoapBProcess1

N/A N/A

N/A N/A

124EUpward

VerticalStack7C PreweighGroup1 N/A N/A N/A N/A

123EUpward

VerticalStack6C

LiquidSoapBProcess3

N/A N/A

N/A N/A127E‐130EUpward

VerticalStack9C‐12C

LiquidSoapAProcess1‐4

N/A N/A


141801.0078







EmissionPointType1


Table&PlotPlan)


Table&PlotPlan)








Est.MethodUsed6


PM/PM10/PM2.5 2.4E‐01 1.05 Gas EE

VOC 9.9E‐03 4.3E‐02 Gas EE

PM10/PM2.5 1.5E‐02 6.5E‐02 Gas O‐AP‐42SO2 1.4E‐03 6.2E‐03 Gas O‐AP‐42NOX 2.4E‐01 1.1 Gas O‐VendorVOC 1.24 5.4 Gas MBCO 1.33 5.8 Gas O‐VendorLead 1.2E‐06 5.2E‐06 Gas O‐AP‐42

132E‐157EUpward

VerticalStackN/A

DryConsumerLaundryand

CleaningProductsATanks

N/A N/A N/A N/A VOC 1.51E‐01 6.63E‐01 1.5E‐01 6.6E‐01 Gas EE

158EUpward

VerticalStack15C


CleaningProductsAParticulateControl1

N/A N/A N/A N/A PM/PM10/PM2.5 6.9E‐02 3.0E‐01 Gas EE

159EUpward

VerticalStack16C




160EUpward

VerticalStack17C




161EUpward

VerticalStack18C



N/A N/A N/A N/A PM/PM10/PM2.7 1.54E+00 6.8 Gas EE

162EUpward

VerticalStack19C



N/A N/A N/A N/A PM/PM10/PM2.5 1.54E+00 6.8 Gas EE

163EUpward

VerticalStack20C



N/A N/A N/A N/A PM/PM10/PM2.5 5.57E‐01 2.4 Gas EE

164EUpward

VerticalStackN/A


CleaningProductsAAdditive1

N/A N/A N/A N/A VOC 3.6E‐01 1.6 2.0 8.7 Gas EE

N/A N/A

126EUpward

VerticalStack14C

HotMixTanksforLiquidSoapA,Process1‐4

N/A N/A N/A N/A

131EUpward

VerticalStack13C

LiquidSoapBProcess4

N/A N/A


141801.0078







EmissionPointType1


Table&PlotPlan)


Table&PlotPlan)








Est.MethodUsed6


NOX 4.5 19.8 4.5 19.8

CO 2.3 10.0 2.3 10.0SO2 3.7E‐02 0.2 3.7E‐02 1.6E‐01VOC 2.2E‐01 1.0 2.2E‐01 9.8E‐01PM 2.4E‐01 1.0 2.4E‐01 1.03PM10 4.7E‐01 2.0 4.7E‐01 2.04PM2.5 4.7E‐01 2.0 4.7E‐01 2.04H2SO4 4.0E‐04 0.0 4.0E‐04 1.8E‐03HAP 1.1E‐01 0.5 1.1E‐01 5.0E‐01NOX 4.5 19.8 4.5 19.8CO 2.3 10.0 2.3 10.0SO2 3.7E‐02 1.6E‐01 3.7E‐02 1.6E‐01VOC 2.2E‐01 1.0 2.2E‐01 1.0PM 2.4E‐01 1.0 2.4E‐01 1.0PM10 4.7E‐01 2.0 4.7E‐01 2.0PM2.5 4.7E‐01 2.0 4.7E‐01 2.0H2SO4 4.0E‐04 1.8E‐03 4.0E‐04 1.8E‐03HAP 1.1E‐01 5.0E‐01 1.1E‐01 5.0E‐01

NOX 2.3 9.9 2.3 9.9

CO 1.1 5.0 1.1 5.0SO2 1.9E‐02 8.1E‐02 1.9E‐02 8.1E‐02VOC 1.1E‐01 4.9E‐01 1.1E‐01 4.9E‐01PM 1.2E‐01 0.5 1.2E‐01 0.5PM10 2.3E‐01 1.0 2.3E‐01 1.0PM2.5 2.3E‐01 1.0 2.3E‐01 1.0H2SO4 2.0E‐04 8.8E‐04 2.0E‐04 8.8E‐04HAP 5.7E‐02 2.5E‐01 5.7E‐02 2.5E‐01

168EUpward

VerticalStackN/A TemporaryBoiler N/A N/A N/A N/A N/A N/A N/A N/A N/A Gas N/A

169E‐171EUpward

VerticalStackN/A CoolingTower N/A N/A N/A N/A PM/PM10/PM2.5 8.91E‐01 3.9 8.91E‐01 3.9 Gas O‐AP‐42

NOX 3.6 8.9E‐01 3.6 8.9E‐01

CO 1.1 2.7E‐01 1.1 2.7E‐01SO2 1.9E‐03 4.8E‐04 1.9E‐03 4.8E‐04VOC 1.4E‐01 3.4E‐02 1.4E‐01 3.4E‐02PM 1.4E‐01 3.4E‐02 1.4E‐01 3.4E‐02PM10 1.4E‐01 3.4E‐02 1.4E‐01 3.4E‐02PM2.5 1.4E‐01 3.4E‐02 1.4E‐01 3.4E‐02HAP 2.8E‐02 7.0E‐03 2.8E‐02 7.0E‐03

NOX 10.5 2.6 10.5 2.6

CO 1.7 4.2E‐01 1.7 4.2E‐01SO2 4.4E‐03 1.1E‐03 4.37E‐03 1.1E‐03VOC 1.3E‐01 3.3E‐02 1.31E‐01 3.3E‐02PM 1.4E‐01 3.6E‐02 1.44E‐01 3.6E‐02PM10 1.4E‐01 3.5E‐02 1.38E‐01 3.5E‐02PM2.5 1.4E‐01 3.5E‐02 1.38E‐01 3.5E‐02HAP 6.4E‐02 1.6E‐02 6.38E‐02 1.6E‐02

177EUpward

VerticalStackN/A FuelTanks N/A N/A N/A N/A VOC 5.2E‐04 2.3E‐03 5.2E‐04 2.3E‐03 Gas

O‐EPATanks

O‐AP‐42166EUpward

VerticalStackN/A Boiler2 N/A Gas

O‐Vendor

O‐AP‐42

Gas O‐AP‐42

Gas O‐Vendor

Gas

Gas

172E‐173EUpward

VerticalStackN/A FirePumpEngine N/A N/A N/A N/A

174E‐176EUpward

VerticalStackN/A

Backup/StandbyPowerGenerator

N/A N/A N/A N/A

N/A Boiler3 N/A N/A N/A N/A

N/A N/A N/A

UpwardVerticalStack

N/A Boiler1 N/A N/A N/A N/A

167EUpward

VerticalStack

165E


141801.0078







EmissionPointType1


Table&PlotPlan)


Table&PlotPlan)








Est.MethodUsed6


NOX 9.0E‐01 3.93 9.0E‐01 3.9

CO 1.51 6.60 1.51 6.60SO2 1.1E‐02 4.7E‐02 1.1E‐02 4.7E‐02VOC 9.9E‐02 4.3E‐01 9.9E‐02 4.3E‐01PM 1.4E‐01 6.0E‐01 1.4E‐01 6.0E‐01PM10 1.4E‐01 6.0E‐01 1.4E‐01 6.0E‐01PM2.5 1.4E‐01 6.0E‐01 1.4E‐01 6.0E‐01H2SO4 1.2E‐04 5.1E‐04 1.2E‐04 5.1E‐04HAP 3.4E‐02 1.5E‐01 3.4E‐02 1.5E‐01VOC 3.0 13.0 3.0 13.0HAP 9.1E‐04 4.0E‐03 9.1E‐04 4.0E‐03PM 7.99E‐01 3.50 7.99E‐02 3.50E‐01PM10 7.99E‐01 3.50 7.99E‐02 3.50E‐01PM2.5 7.99E‐01 3.50 7.99E‐02 3.50E‐01PM 7.99E‐01 3.50 7.99E‐01 3.5PM10 7.99E‐01 3.50 7.99E‐01 3.5PM2.5 7.99E‐01 3.50 7.99E‐01 3.5PM 7.67E‐01 3.36 3.84E‐02 1.68E‐01PM10 7.67E‐01 3.36 3.84E‐02 1.68E‐01PM2.5 7.67E‐01 3.36 3.84E‐02 1.68E‐01

216EUpward

VerticalStackN/A FormingVOC N/A N/A N/A N/A VOC 7.01E‐01 3.07 7.01E‐01 3.1 Gas O‐Vendor

217EUpward

VerticalStackN/A

PartsWashing/Process

CleaningN/A N/A N/A N/A VOC 1.4E+00 6.00 1.4 6.0 Gas O‐Vendor

NOX 8.33E‐01 3.7 8.33E‐01 3.7CO 1.4 6.1 1.4 6.1SO2 1.0E‐02 4.4E‐02 1.00E‐02 4.38E‐02VOC 9.2E‐02 4.0E‐01 9.17E‐02 4.02E‐01PM 1.3E‐01 5.5E‐01 1.27E‐01 5.55E‐01PM10 1.3E‐01 5.5E‐01 1.27E‐01 5.55E‐01PM2.5 1.3E‐01 5.5E‐01 1.27E‐01 5.55E‐01H2SO4 1.1E‐04 4.7E‐04 1.08E‐04 4.75E‐04HAP 3.1E‐02 1.3E‐01 3.15E‐02 1.30E‐01PM 2.8E‐01 1.2 2.80E‐01 1.2PM10 2.8E‐01 1.2 2.80E‐01 1.2PM2.5 2.8E‐01 1.2 2.80E‐01 1.2NOX 4.17E‐01 1.04E‐01 4.17E‐01 1.04E‐01CO 8.33E‐01 2.08E‐01 8.33E‐01 2.08E‐01SO2 1.18E‐04 2.94E‐05 1.18E‐04 2.94E‐05VOC 2.01E‐01 5.02E‐02 2.01E‐01 5.02E‐02PM 1.90E‐03 4.75E‐04 1.90E‐03 4.75E‐04PM10 3.88E‐03 9.71E‐04 3.88E‐03 9.71E‐04PM2.5 3.88E‐03 9.71E‐04 3.88E‐03 9.71E‐04HAP 6.48E‐03 1.62E‐03 6.48E‐03 1.62E‐03VOC 8.65E‐02 3.79E‐01 8.7E‐02 3.79E‐01 Gas EEHAP 3.65E‐02 1.60E‐01 3.7E‐02 1.60E‐01 Gas EEVOC 4.73E‐02 2.07E‐01 4.7E‐02 2.07E‐01 Gas EEHAP 1.58E‐03 6.90E‐03 1.6E‐03 6.90E‐03 Gas EE

EE185E Fugitive N/AWaterPretreatment

ChemicalsN/A N/A N/A N/A Gas

Gas O‐AP‐42179E‐184EUpward

VerticalStackN/A WarehouseHeater N/A N/A N/A N/A

Gas

UpwardVerticalStack

21C‐25C RailcarUnloading N/A

N/A

N/A

O‐Vendor215EUpward

VerticalStackN/A PlasticRegrind N/A

186E‐190E

O‐Vendor

N/A N/A Gas O‐Vendor

191E‐214EUpward

VerticalStackN/A StorageSilo N/A

N/A

N/A N/A Gas

Gas O‐AP‐42

224EUpward

VerticalStackN/A CoolingTower N/A N/A N/A N/A

218E‐223EUpward

VerticalStackN/A SpaceHeater N/A N/A N/A

N/A N/A N/A

Gas O‐AP‐42

Gas O‐AP‐42

225EUpward

VerticalStackN/A BackupGenerator N/A N/A N/A N/A

226E Fugitive N/A PrintingInk N/A N/A N/A N/A

227E Fugitive N/A CasePackingGlue N/A N/A N/A N/A


141801.0078


Temp.(of)

VolumetricFlow1(acfm)atoperatingconditions

Velocity(fps)

GroundLevel(Height

abovemeansealevel)

StackHeight2

(Releaseheightofemissionsabovegroundlevel)

Northing Easting

1E TBD TBD TBD TBD TBD TBD 4,366 7572E TBD TBD TBD TBD TBD TBD 4,366 757

3E‐18E N/A N/A N/A N/A N/A N/A N/A N/A19E N/A N/A N/A N/A N/A N/A N/A N/A

20E‐118E N/A N/A N/A N/A N/A N/A N/A N/A119E N/A N/A N/A N/A N/A N/A N/A N/A120E TBD TBD TBD TBD TBD TBD 4,366 757121E TBD TBD TBD TBD TBD TBD 4,366 757122E TBD TBD TBD TBD TBD TBD 4,366 757123E TBD TBD TBD TBD TBD TBD 4,366 757124E TBD TBD TBD TBD TBD TBD 4,366 757125E TBD TBD TBD TBD TBD TBD 4,366 757

127E‐130E TBD TBD TBD TBD TBD TBD 4,366 757131E TBD TBD TBD TBD TBD TBD 4,366 757126E TBD TBD TBD TBD TBD TBD 4,366 757

132E‐157E N/A N/A N/A N/A N/A N/A N/A N/A158E TBD TBD TBD TBD TBD TBD 4,366 757159E TBD TBD TBD TBD TBD TBD 4,366 757160E TBD TBD TBD TBD TBD TBD 4,366 757161E TBD TBD TBD TBD TBD TBD 4,366 757162E TBD TBD TBD TBD TBD TBD 4,366 757163E TBD TBD TBD TBD TBD TBD 4,366 757164E N/A N/A N/A N/A N/A N/A N/A N/A165E TBD TBD TBD TBD TBD TBD 4,366 757166E TBD TBD TBD TBD TBD TBD 4,366 757167E TBD TBD TBD TBD TBD TBD 4,366 757168E TBD TBD TBD TBD TBD TBD 4,366 757

169E‐171E TBD TBD TBD TBD TBD TBD 4,366 757172E‐173E N/A N/A N/A N/A N/A N/A N/A N/A174E‐176E N/A N/A N/A N/A N/A N/A N/A N/A

177E N/A N/A N/A N/A N/A N/A N/A N/A179E‐184E N/A N/A N/A N/A N/A N/A N/A N/A

185E N/A N/A N/A N/A N/A N/A N/A N/A186E‐190E TBD TBD TBD TBD TBD TBD 4,366 757191E‐214E TBD TBD TBD TBD TBD TBD 4,366 757

215E TBD TBD TBD TBD TBD TBD 4,366 757216E N/A N/A N/A N/A N/A N/A N/A N/A217E N/A N/A N/A N/A N/A N/A N/A N/A

218E‐223E N/A N/A N/A N/A N/A N/A N/A N/A224E TBD TBD TBD TBD TBD TBD 4,366 757225E N/A N/A N/A N/A N/A N/A N/A N/A226E N/A N/A N/A N/A N/A N/A N/A N/A227E N/A N/A N/A N/A N/A N/A N/A N/A

AttachmentJ

EMISSIONPOINTSSUMMARYSHEET

Table2:ReleaseParameterData


UnitsTable)

InnerDiameter(ft.)

ExitGas EmissionPointElevation(ft) UTMCoordinates(km)


141801.0078


ATTACHMENT K

Fugitive Emissions Data Summary Sheet

Attachment KTabler Station

Question YES/NO ifYES:

1 Willtherebehaulroadactivities? Yes Completehaulroademissionsunitdatasheet

2 Willtherebestoragepiles? NoCompleteTable1ofnonmetallicmineralsprocessingemissionsunitdatasheet

3 Willtherebeliquidloading/unloadingoperations? YesCompletebulkliquidtransferoperations

emissionsunitdatasheet

4Willtherebeemissionsofairpollutantsfromwastewater

treatmentevaporation?Yes Completegeneralemissionsunitdatasheet

5

Willtherebeequipmentleaks(e.g.leaksfrompumps,compressors,in‐lineprocessvalves,pressurereliefdevices,open‐endedvalves,samplingconnections,flanges,agitators,

coolingtowers,etc.)?

NoCompleteleaksourcedatasheetsectionofthechemicalprocessesemissionsunitdatasheet

6 WilltherebeGeneralClean‐upVOCOperations? Yes Completethegeneralemissionsunitdatasheet

7Willtherebeanyotheractivitiesthatgeneratefugitive

emissions?Yes

Completethegeneralemissionsunitdatasheetormostappropriateform

AttachmentKFUGITIVEEMISSIONSDATASUMMARYSHEET


141801.0078

Attachment KTabler Station

lb/hr ton/yr lb/hr ton/yrHaulRoad/RoadDustEmissions NA NA NA NA NA NA

PavedHaulRoads PM 5.0E‐04 2.2E‐03 N/A N/A O‐AP‐42UnpavedHaulRoads NA NA NA NA NA NAStoragePileEmissions NA NA NA NA NA NA

VOC 1.2E‐02 5.2E‐02 1.2E‐02 5.2E‐02H2SO4 5.5E‐04 2.4E‐03 5.5E‐04 2.4E‐03

VOC 3.0 13.0 3.0 13.0EE‐

EngineeringEstimate

HAP 9.1E‐04 4.0E‐03 9.1E‐04 4.0E‐03EE‐

EngineeringEstimate

EquipmentLeaks NA NA NA NA NA NA

GeneralClean‐upVOCEmissions67‐63‐0,and

others1.37 6.00 1.37 6.00

EE‐EngineeringEstimate

VOC 8.7E‐02 3.79E‐01 8.65E‐02 3.79E‐01

GlycolEther 3.7E‐02 1.60E‐01 3.65E‐02 1.60E‐01

VOC 4.7E‐02 2.07E‐01 4.73E‐02 2.07E‐01

108‐05‐4 1.6E‐03 6.90E‐03 1.58E‐03 6.90E‐03Other NA‐FugitiveemissionsfromtanksarecalculatedinAttachmentL

WastewaterTreatmentEvaporation&Operations

Loading/UnloadingOperations O‐AP‐42

AttachmentKFUGITIVEEMISSIONSDATASUMMARYSHEET

FUGITIVEEMISSIONSSUMMARY

AllRegulatedPollutants‐

ChemicalName/CAS

MaximumPotentialUncontrolledEmissions

MaximumPotentialControlledEmissions Est.Method

Used

InkPrinters

CasePackingGlue




141801.0078


ATTACHMENT L

Emission Unit Data Sheet

Attachment LTabler Station

1 3 4 6 8 9A 9B 10A 13A 18 20 22A 22B 22C 27 38B 39C 39D 40

BulkStorageAreaName

TankEquipmentIdentificationNumber

EmissionPointIdentificationNumber

TypeofChange

Capacity(gallons)

InternalDiameter

(ft)

InternalHeight(ft)

MaxLiquidHeight

MaxAnnualThroughput(gal/yr)

TypeofTankShell

Color/RoofColor

AretheTanksHeated?

Providetheoperating

temperature(F)

Describehowheatisprovidedtothetank

City/StateforTANKS

calculations

MaxVaporPressure(psi)

LiquidDensity(lb/gal)

LiquidMolecularWeight

(lb/lb‐mol)

EmissionControlDevices

MaterialClassification

AnnualLoss

(lb/year)

MaterialClassificati

on

AnnualLoss

(lb/year)

EstimationMethod

SurfactantTanks 3S 3E NewConst. 120,762 21.3 45.5 41.6 20,327,735VerticalFixed

RoofAboveground

Grey/Grey Yes 90.5SteamorHotWater

DullesAirport,

WashingtonDC

3.50E‐03 6.84 197Doesnotapply

VOC 109.6 HAP n/a EPA


RoofAboveground


DullesAirport,

WashingtonDC


VOC 44.6 HAP 44.6 EPA


RoofAboveground

Grey/Grey Yes 95SteamorHotWater

DullesAirport,

WashingtonDC




RoofAboveground

Grey/Grey Yes Ambient N/A

DullesAirport,

WashingtonDC

8.62E‐01 6.58 46.07Doesnotapply



RoofAboveground


DullesAirport,

WashingtonDC




RoofAboveground


DullesAirport,

WashingtonDC




RoofAboveground


DullesAirport,

WashingtonDC




RoofAboveground


DullesAirport,

WashingtonDC




RoofAboveground


DullesAirport,

WashingtonDC




RoofAboveground


DullesAirport,

WashingtonDC




RoofAboveground


DullesAirport,

WashingtonDC




RoofAboveground


DullesAirport,

WashingtonDC




RoofAboveground


DullesAirport,

WashingtonDC



SurfactantTanks 16S 16E NewConst. 26,083 11.8 31.8 30.6 115,491VerticalFixed

RoofAboveground


DullesAirport,

WashingtonDC


VOC 1.3 HAP n/a EPA


RoofAboveground


DullesAirport,

WashingtonDC


H2SO4 3.0 HAP n/a EPA

SurfactantTanks 18S 18E NewConst. 15,125 9.8 26.6 26.5 150,000VerticalFixed

RoofAboveground


DullesAirport,

WashingtonDC


VOC 0.6 HAP n/a EPA


20S 20E NewConst. 39,626 13.5 36.1 23.8 13,431,682VerticalFixed

RoofAboveground


DullesAirport,

WashingtonDC



41

AttachmentLEMISSIONSUNITDATASHEET‐STORAGETANKS


141801.0078


1 3 4 6 8 9A 9B 10A 13A 18 20 22A 22B 22C 27 38B 39C 39D 40

BulkStorageAreaName



TypeofChange

Capacity(gallons)

InternalDiameter

(ft)

InternalHeight(ft)

MaxLiquidHeight


TypeofTankShell

Color/RoofColor

AretheTanksHeated?

Providetheoperating

temperature(F)


City/StateforTANKS

calculations




(lb/lb‐mol)



AnnualLoss

(lb/year)


on

AnnualLoss

(lb/year)

EstimationMethod

41




RoofAboveground


DullesAirport,

WashingtonDC





RoofAboveground


DullesAirport,

WashingtonDC




23S 23E NewConst. 7,925 7.9 21.0 13.9 291,058VerticalFixed

RoofAboveground


DullesAirport,

WashingtonDC


VOC 2.4 HAP 2.4 EPA



RoofAboveground


DullesAirport,

WashingtonDC


VOC n/a HAP 37.0 EPA



RoofAboveground


DullesAirport,

WashingtonDC


VOC 6.10E‐12 HAP n/a EPA



RoofAboveground


DullesAirport,

WashingtonDC

n/a 7.51 503Doesnotapply

VOC 0.00E+00 HAP n/a EPA



RoofAboveground


DullesAirport,

WashingtonDC





RoofAboveground


DullesAirport,

WashingtonDC


VOC 1.3 HAP n/a EPA



RoofAboveground


DullesAirport,

WashingtonDC





RoofAboveground


DullesAirport,

WashingtonDC





RoofAboveground


DullesAirport,

WashingtonDC





RoofAboveground


DullesAirport,

WashingtonDC





RoofAboveground

Grey/Grey No 77SteamorHotWater

DullesAirport,

WashingtonDC





RoofAboveground

Grey/Grey No Ambient N/A

DullesAirport,

WashingtonDC





RoofAboveground


DullesAirport,

WashingtonDC





RoofAboveground


DullesAirport,

WashingtonDC





RoofAboveground

Grey/Grey Yes Ambient N/A

DullesAirport,

WashingtonDC




141801.0078


1 3 4 6 8 9A 9B 10A 13A 18 20 22A 22B 22C 27 38B 39C 39D 40

BulkStorageAreaName



TypeofChange

Capacity(gallons)

InternalDiameter

(ft)

InternalHeight(ft)

MaxLiquidHeight


TypeofTankShell

Color/RoofColor

AretheTanksHeated?

Providetheoperating

temperature(F)


City/StateforTANKS

calculations




(lb/lb‐mol)



AnnualLoss

(lb/year)


on

AnnualLoss

(lb/year)

EstimationMethod

41




RoofAboveground

Grey/Grey Yes 77SteamorHot

Water

DullesAirport,

WashingtonDC


VOC 4.2 HAP n/a EPA



RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 1.05E+00 HAP n/a EPA


38S 38E NewConst. 396 3.3 8.58 5.6628 37,808VerticalFixed

RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 6.4 HAP n/a EPA



RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC




51S 51E NewConst. 396 3.3 8.58 5.6628 n/aVerticalFixed

RoofAboveground


Water

DullesAirport,

WashingtonDC

n/a n/a n/aDoesnotapply

VOC n/a HAP n/a EPA


52S 52E NewConst. 396 3.3 8.58 5.6628 990VerticalFixed

RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC




55S 55E NewConst. 396 3.3 8.58 5.6628 75VerticalFixed

RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC




141801.0078


1 3 4 6 8 9A 9B 10A 13A 18 20 22A 22B 22C 27 38B 39C 39D 40

BulkStorageAreaName



TypeofChange

Capacity(gallons)

InternalDiameter

(ft)

InternalHeight(ft)

MaxLiquidHeight


TypeofTankShell

Color/RoofColor

AretheTanksHeated?

Providetheoperating

temperature(F)


City/StateforTANKS

calculations




(lb/lb‐mol)



AnnualLoss

(lb/year)


on

AnnualLoss

(lb/year)

EstimationMethod

41




RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 3.63E‐03 HAP 0.0 EPA



RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 8.7 HAP 4.34E‐02 EPA



RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC




141801.0078


1 3 4 6 8 9A 9B 10A 13A 18 20 22A 22B 22C 27 38B 39C 39D 40

BulkStorageAreaName



TypeofChange

Capacity(gallons)

InternalDiameter

(ft)

InternalHeight(ft)

MaxLiquidHeight


TypeofTankShell

Color/RoofColor

AretheTanksHeated?

Providetheoperating

temperature(F)


City/StateforTANKS

calculations




(lb/lb‐mol)



AnnualLoss

(lb/year)


on

AnnualLoss

(lb/year)

EstimationMethod

41




RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 3.5 HAP n/a EPA



RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 3.0 HAP n/a EPA



RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 3.0 HAP n/a EPA



RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 3.0 HAP n/a EPA



RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 3.0 HAP n/a EPA



RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 3.0 HAP n/a EPA



RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 3.0 HAP n/a EPA



RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 3.0 HAP n/a EPA


94bS 94bE NewConst. 1,585 5.3 13.78 9.0948 2,048,433VerticalFixed

RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 2.0 HAP n/a EPA


94cS 94cE NewConst. 1,585 5.3 13.78 9.0948 2,048,433VerticalFixed

RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 1.8 HAP n/a EPA


94dS 94dE NewConst. 1,585 5.3 13.78 9.0948 2,048,433VerticalFixed

RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 1.8 HAP n/a EPA


94eS 94eE NewConst. 1,585 5.3 13.78 9.0948 2,048,433VerticalFixed

RoofAboveground


Water

DullesAirport,

WashingtonDC


VOC 1.8 HAP n/a EPA



RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC




141801.0078


1 3 4 6 8 9A 9B 10A 13A 18 20 22A 22B 22C 27 38B 39C 39D 40

BulkStorageAreaName



TypeofChange

Capacity(gallons)

InternalDiameter

(ft)

InternalHeight(ft)

MaxLiquidHeight


TypeofTankShell

Color/RoofColor

AretheTanksHeated?

Providetheoperating

temperature(F)


City/StateforTANKS

calculations




(lb/lb‐mol)



AnnualLoss

(lb/year)


on

AnnualLoss

(lb/year)

EstimationMethod

41




RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC




141801.0078


1 3 4 6 8 9A 9B 10A 13A 18 20 22A 22B 22C 27 38B 39C 39D 40

BulkStorageAreaName



TypeofChange

Capacity(gallons)

InternalDiameter

(ft)

InternalHeight(ft)

MaxLiquidHeight


TypeofTankShell

Color/RoofColor

AretheTanksHeated?

Providetheoperating

temperature(F)


City/StateforTANKS

calculations




(lb/lb‐mol)



AnnualLoss

(lb/year)


on

AnnualLoss

(lb/year)

EstimationMethod

41




RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC





RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC

0.50 8.81 200Doesnotapply





RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC




141801.0078


1 3 4 6 8 9A 9B 10A 13A 18 20 22A 22B 22C 27 38B 39C 39D 40

BulkStorageAreaName



TypeofChange

Capacity(gallons)

InternalDiameter

(ft)

InternalHeight(ft)

MaxLiquidHeight


TypeofTankShell

Color/RoofColor

AretheTanksHeated?

Providetheoperating

temperature(F)


City/StateforTANKS

calculations




(lb/lb‐mol)



AnnualLoss

(lb/year)


on

AnnualLoss

(lb/year)

EstimationMethod

41





RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC






RoofAboveground


Water

DullesAirport,

WashingtonDC



FuelTanks 208S 177E NewConst. 5,162 8.0 20.8 13.73 70,000VerticalFixed

RoofAboveground


DullesAirport,

WashingtonDC


VOC 4.6 HAP n/a EPA


141801.0078


Number: Question: Notes:Sheetversion:

0 IdentificationNumber

1 LoadingAreaName

2TypeofCargoVessels

AccommodatedatthisTransferPoint

Choose:Drums,MarineVessels,RailTankCars,andTankTrucks

7ProjectedMaximumOperating

ScheduleBulkLiquidDataLiquidName PAM Surfactant SulfuricAcidAnnualthroughput(Mgal/yr) 150 15,000 2,000Max.BulkLiquidTemp(F) 69 69 69Truevaporpressure(psia) 1.69E‐03 1.50E‐03 1.69E‐03Filltype Submerged Submerged SubmergedVOCEmissionRate(lb/yr) 3.5E‐01 60.1 ‐‐H2SO4EmissionRate(lb/yr) 1.1E‐01 ‐‐ 4.7ControlEquipment N/A N/A N/A

RailTankCarsandTankTrucks

24/7/365

8

AttachmentLEMISSIONSUNITDATASHEET‐BULKLIQUIDTRANSFEROPERATIONS

Response:BulkLiquidTransfer

19S

SurfactantBulkLiquidTransfer


141801.0078


Utilities‐Road‐ConstantsParameter Value UnitIndustrialaugmentationfactor 1 dimensionlessNumberoftrafficlanes 2Surfacematerialsiltcontent1 3.3% %Surfacedustloading 125 lb/mile

Utilities‐Road‐Parameters

DescriptionAverage Weight2

MilesperTrip2

MaximumTripsperHour

Maximum Trips per

YearControl

Device IDControl

Efficiency(tons) %

DeliveryTrucks 40 0.04167 30.8 365 -- --EmployeeVehicles 2 0.04167 0.5 365 -- --

Utilities‐Road‐Emissions

(lb/hr) (tpy) (lb/hr) (tpy)DeliveryTrucks 5.0E‐04 2.2E‐03 -- --EmployeeVehicles 1.0E‐06 4.4E‐06 -- --

TOTAL 5.0E‐04 2.2E‐03 -- --

2.ConservativeassumptionbasedonProcterandGambledesigndata.

AttachmentLEMISSIONSUNITDATASHEET‐PAVEDHAULROADS

3.FromEmissionFactorDocumentationforAP‐42Section13.2.1,PavedRoads, Equation2‐2,assitedinWVDEPR‐13PermitFormAttachmentLforHaulRoads

PollutantUncontrolledTSPEmissions3 ControlledTSPEmissions

1.ConservativelyassumedtobeequaltoaveragefactorforAsphaltBatching,AP‐42Section13.2.1PavedRoads ,Table13.2.1‐3


141801.0078


Number: Question: Response: Notes:Sheetversion: IndirectHeatExchanger

0 ControlDeviceIDNo. 165Eand166E1 Manufacturer Cleaver‐Brooks

2ModelNumber:SerialNumber:

TBD

3 NumberofUnits 24 Use Plantsteam7 DateConstructed November2016

9Maximumdesignheatinputperunit 62 MMBtu/hr

10 Peakheatinputperunit

11Steamproducedatmaximumdesign

output 50,267each pph12 ProjectedOperatingSchedule 24/7/365

13TypeofFiringEquipmenttobeUsed

NaturalGasBurners Choosefrompulverizedcoal,spreaderstoker,oilburners,naturalgasburners,orother.

Fuel NaturalGasQuantityofFuelUsed(ft3/hr) 62,000eachQuantityofFuelUsedAnnually

(MMft3/hr) 4,757,731each

BTUContent(BTU/ft3) 1,000Emissionsaftercontrol(lb/hr)

CO 4.6NOX 9.0Pb 1.2E‐04PM10 9.3E‐01

SO2 7.4E‐02VOC 4.5E‐01

AttachmentLEMISSIONSUNITDATASHEET‐INDIRECTHEATEXCHANGER

25

38


141801.0078



0 ControlDeviceIDNo. 167E1 Manufacturer Cleaver‐Brooks


TBD





output 25,134 pph12 ProjectedOperatingSchedule 24/7/365


NaturalGasBurnersChoosefrompulverizedcoal,spreaderstoker,oilburners,naturalgasburners,orother.

Fuel NaturalGasQuantityofFuelUsed(ft3/hr) 31,000QuantityofFuelUsedAnnually

(MMft3/hr) 2,378,866

BTUContent(BTU/ft3) 1,000Emissionsaftercontrol(lb/hr)

CO 1.1NOX 2.3Pb 1.5E‐05PM10 2.3E‐01

SO2 1.9E‐02VOC 1.1E‐01


25

38


141801.0078



0 ControlDeviceIDNo. 168E1 Manufacturer Cleaver‐Brooks


TBD





output 8,918 pph12 ProjectedOperatingSchedule AsNeeded


NaturalGasBurnersChoosefrompulverizedcoal,spreaderstoker,oilburners,naturalgasburners,orother.

Fuel NaturalGasQuantityofFuelUsed(ft3/hr) 11,000QuantityofFuelUsedAnnually

(MMft3/hr) 844,114

BTUContent(BTU/ft3) 1,000


25


141801.0078


REVISED

Number: Question: Response: Notes:Sheetversion: General

0 IdentificationNumber 1Sand2S asassignedonEquipmentListForm

1Nameortypeandmodelofproposed

affectedsourceSurfactantMakingProcess

4Namesandmaximumamountof

proposedprocessmaterialsproducedperhour

6,000gal/hr gal/hroffinishedproduct

5Givechemicalreactions,ifapplicable,thatwillbeinvolvedinthegeneration

ofairpollutants

1.CombustionofliquidStoSO2'2.OxidationofSO2toSO3

2.SO3reactedwithorganicfattyalcohol

6 CombustiondataSulfurwillbeburned.Naturalgas

burnedduringstartup7 Projectedoperatingschedule 24/7/365

Pollutant NOXEmissionRate(lb/hr) 1.8

Pollutant COEmissionRate(lb/hr) 0.1

Pollutant SO2EmissionRate(lb/hr) 2.1

Pollutant VOCEmissionRate(lb/hr) 1.9

Pollutant PM10

EmissionRate(lb/hr) 7.0Pollutant CO

EmissionRate(lb/hr) 1.3

Pollutant H2SO4EmissionRate(lb/hr) 5.1EmissionRate(lb/hr) Lead

Pollutant 7.8E‐06Pollutant HAP

EmissionRate(lb/hr) 3.0E‐02

9Recordkeeping

NSPSVVa:Recordkeepingtoshowthatfacilityisexempt.


0 IdentificationNumber 119S asassignedonEquipmentListForm


affectedsourceLiquidSoapAandBPacking/Filling



15,959 gal/houroffinishedproduct


ofairpollutants N/A7 Projectedoperatingschedule 24/7/365

Pollutant VOCEmissionRate(lb/hr) 2.5E‐04

AttachmentLEMISSIONSUNITDATASHEET‐GENERAL

8


8


141801.0078


REVISED




affectedsourceDryConsumerLaundryandCleaning

ProductsAAdditive1



393,701 ft/hroffinishedproduct



Pollutant VOCEmissionRate(lb/hr) 2.0




affectedsourceWaterPretreatmentChemicals



44lb/hr(ofmaterialsthatcontainVOCand/or

HAP)


ofairpollutantsN/A

7 Projectedoperatingschedule 24/7/365Pollutant VOC

EmissionRate(lb/hr) 3.0Pollutant HAP





affectedsourceForming



100,000 tons/year



Pollutant VOCEmissionRate(lb/hr) 7.0E‐01




affectedsourcePartsWashing/ProcessCleaning



6 tons/year


ofairpollutantsN/A


EmissionRate(lb/hr) 1.4

EMISSIONSUNITDATASHEET‐GENERAL

8


8

AttachmentL

AttachmentL

EMISSIONSUNITDATASHEET‐GENERALAttachmentL


8

8


141801.0078


REVISED




affectedsourcePrintingInk



0.39lb/hrlb/hr(ofmaterialsthatcontainVOCand/or

HAP)


ofairpollutantsN/A


EmissionRate(lb/hr) 8.65E‐02Pollutant HAP





affectedsourceCasePackingGlue



79lb/hrlb/hr(ofmaterialsthatcontainVOCand/or

HAP)


ofairpollutantsN/A


EmissionRate(lb/hr) 4.73E‐02Pollutant HAP



8


8

AttachmentL


141801.0078


ATTACHMENT M

Air Pollution Control Device Sheet

Attachment MTabler Station

Number: Question: Response: Notes:Sheetversion: WetCollectingSystem‐Scrubber

EquipmentDescription SurfactantMakingProcess0 ControlDeviceIDNo.: 1C MustmatchEmissionUnitsTable

2 Method: PackedBedChoices:Packedbed,spraytower,mechanical,venturi,

cycle,orifice,other(specify)10 ScrubbingLiquor: Water Compositionandweight%13 Pressuredropthroughscrubber: ~6 inchesH2O15 Liquorflowratestoscrubber: ~572 Designmaximum,gal/min23 Gasflowrate: ~14,000scfm Designmaximum,acfm26 Typeofpollutant(s)Controlled SOx ChooseSOx,Odor,Particulate,Other

Number: Question: Response: Notes:Sheetversion: WetCollectingSystem‐Scrubber

EquipmentDescription SurfactantMakingProcess0 ControlDeviceIDNo.: 2C MustmatchEmissionUnitsTable

2 Method: PackedBedChoices:Packedbed,spraytower,mechanical,venturi,

cycle,orifice,other(specify)10 ScrubbingLiquor: Water Compositionandweight%13 Pressuredropthroughscrubber: ~6 inchesH2O15 Liquorflowratestoscrubber: ~572 Designmaximum,gal/min23 Gasflowrate: ~14,000scfm Designmaximum,acfm26 Typeofpollutant(s)Controlled SOx ChooseSOx,Odor,Particulate,Other

Number: Question: Response: Notes:Sheetversion: MechanicalCollector‐Cyclone

EquipmentDescription Rotoclone0 ControlDeviceIDNo.: 3C MustmatchEmissionUnitsTable

2 Method: WetChoices:Wet,Single‐stage,dry,multiple(number?),in

series(number)5 PressureDrop(inH2O) ~11.29 Guaranteedcollectionefficiency: 96% Alsoincludeminimum%13 Totalflowrate ~3000acfm15 GasFlowRateintoCollector ~2250scfm






















EquipmentDescription Rotoclone0 ControlDeviceIDNo.: 9C MustmatchEmissionUnitsTable5 PressureDrop(inH2O) ~11.2


series(number)9 Guaranteedcollectionefficiency: 98% Alsoincludeminimum%13 Totalflowrate ~5500acfm15 GasFlowRateintoCollector ~1750scfm









AttachmentMAIRPOLLUTIONCONTROLDEVICESHEET


141801.0078

Attachment MTabler Station

AttachmentMAIRPOLLUTIONCONTROLDEVICESHEET


EquipmentDescription Rotoclones0 ControlDeviceIDNo.: 12C MustmatchEmissionUnitsTable







Number: Question: Response: Notes:Sheetversion: Flaresystem

EquipmentDescription RegenerativeThermalOxidizer0 ControlDeviceIDNo.: 14C MustmatchEmissionUnitsTable5 Maxcapacityofflare: 75 scf/min7 Estimatedcombustionefficiency: 97% Estimated%8 FuelUsed NaturalGas9 BurnerRating ~2MMBtu/hr

30 Maximummassflowrateofwastegas: ~6146 scf.Estimatedtotalcombustibletoflare.

31Estimatedtotalflowratetoflareincluding

materialtobeburned,carriergases,auxiliaryfuel,etc.:

~158.6 lb/hr

Temperatureofemissionstream(inlet) ~104‐184 DegreesF

Temperatureofemissionstream(outlet) ~1500 DegreesF

Number: Question: Response: Notes:Sheetversion: Baghouse

EquipmentDescription BinVentFilter0 ControldeviceIDNo.: 15C MustmatchEmissionUnitsTable16 Gasflowrateintocollector: ~400scfm ACFM21 ParticulateLoading(outlet): ~0.02 grain/scf


EquipmentDescription Baghouse0 ControldeviceIDNo.: 16C MustmatchEmissionUnitsTable16 Gasflowrateintocollector: ~275scfm ACFM21 ParticulateLoading(outlet): ~0.02 grain/scf










EquipmentDescription Cyclone0 ControlDeviceIDNo.: 21C MustmatchEmissionUnitsTable

2 Method: DryChoices:Wet,Single‐stage,dry,multiple(number?),in

series(number)9 Guaranteedcollectionefficiency: 90% Alsoincludeminimum%13 Totalflowrate ~1298cfm


















EquipmentDescription BinVentFilter0 ControldeviceIDNo.: 26C MustmatchEmissionUnitsTable16 Gasflowrateintocollector: TBD ACFM21 ParticulateLoading(outlet): TBD grain/scf

33


141801.0078


ATTACHMENT N

Supporting Emission Calculations

Attachment NTabler Station

TableN‐0a.EmissionsSummary

BusinessUnit/Process PM PM10 PM2.5 VOC HAPs NOx CO SO2 H2SO4Chemicals 23.6 23.6 23.6 5.5 9.2E‐02 4.7 2.9E‐01 1.6 19.4

Tanks ‐‐ ‐‐ ‐‐ 1.2 9.1E‐02 ‐‐ ‐‐ ‐‐ 1.5E‐03TruckLoading ‐‐ ‐‐ ‐‐ 5.2E‐02 ‐‐ ‐‐ ‐‐ ‐‐ 2.4E‐03SO2Scrubber 23.6 23.6 23.6 4.2 1.1E‐03 4.7 2.9E‐01 1.6 19.4

SoapMakingA&B 20.0 20.0 20.0 44.1 3.4E‐02 1.1 5.8 6.2E‐03 0.0Tanks ‐‐ ‐‐ ‐‐ 2.6 3.4E‐02 ‐‐ ‐‐ ‐‐ ‐‐RTO 6.5E‐02 6.5E‐02 6.5E‐02 8.0 5.2E‐06 1.1 5.8 6.2E‐03 ‐‐

DustControl 20.0 20.0 20.0 33.4 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐Packing/Filling ‐‐ ‐‐ ‐‐ 1.11E‐03 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

DryConsumerProductsA 16.7 16.7 16.7 9.3 3.3E‐03 0.0 0.0 0.0 0.0Tanks ‐‐ ‐‐ ‐‐ 0.7 3.3E‐03 ‐‐ ‐‐ ‐‐ ‐‐

Converting 16.7 16.7 16.7 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐Additive ‐‐ ‐‐ ‐‐ 8.7 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

Utilities 7.2 9.7 9.7 16.0 1.4 56.9 32.4 4.6E‐01 4.9E‐03Boilers 2.6 5.1 5.1 2.4 1.3E+00 49.4 25.1 4.1E‐01 4.4E‐03Engines 7.0E‐02 6.9E‐02 6.9E‐02 6.7E‐02 2.3E‐02 3.5 0.7 1.6E‐03 ‐‐

CoolingTowers 3.9 3.9 3.9 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐Heaters 6.0E‐01 6.0E‐01 6.0E‐01 4.3E‐01 1.5E‐01 3.9 6.6 4.7E‐02 5.1E‐04

FuelTanks ‐‐ ‐‐ ‐‐ 2.3E‐03 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐WaterTreatmentChemicals ‐‐ ‐‐ ‐‐ 13.0 4.0E‐03 ‐‐ ‐‐ ‐‐ ‐‐

AuxiliaryActivities 5.8E+00 5.8E+00 5.8E+00 10.11 2.99E‐01 3.8E+00 6.3E+00 4.4E‐02 4.7E‐04GlueUsage ‐‐ ‐‐ ‐‐ 2.07E‐01 6.90E‐03 ‐‐ ‐‐ ‐‐ ‐‐Printing ‐‐ ‐‐ ‐‐ 3.79E‐01 1.60E‐01 ‐‐ ‐‐ ‐‐ ‐‐

PavedRoads 2.2E‐03 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐PlasticsMolding 5.80 5.80 5.80 9.52 1.3E‐01 3.75 6.34 4.4E‐02 4.7E‐04

Total 73.3 75.8 75.8 84.9 1.9 66.4 44.8 2.2 19.4

PotentialtoEmit(tpy)


141801.0078


TableN‐0b.HAP‐EmissionsSummary

HAPEmissions Hexane EthyleneOxide Formaldehyde VinylAcetate 1,4Dioxane HydrogenChloride Acetophenone Propylene Chloroform Lead GlycolEther OtherCombustionHAP1

Total(tpy) 1.46 4.8E‐02 6.0E‐02 6.9E‐03 5.4E‐02 1.8E‐02 7.9E‐05 9.2E‐03 4.0E‐03 4.1E‐04 1.7E‐01 2.1E‐02

PotentialtoEmit

1.Includes:2‐methylnaphthalene,3‐methylchloranthrene,7,12‐Dimethylbenz(a)anthracene,acetaldehyde,acenaphthene,acenaphthylene,acrolein,anthracene,benz(a)anthracene,benzene,benzo(a)pyrene,bezo(b)fluoranthene,benzo(g,h,i)perylene,benzo(k)fluoranthene,chrysene,dibenzo(a,h)anthracene,dichlorobenzene,ethylbenzene,fluoranthene,fluorene,indeno(1,2,3‐cd)pyrene,naphthalene,OCDD,PAH,phenanathrene,pyrene,toluene,1,1,1‐Trichloroethane,o‐xylene,xylenes,arsenic,antimony,beryllium,cadmium,chloride,chromium,chromiumVI,cobalt,fluoride,manganese,mercury,nickel,phosphorus,selenium.


141801.0078


TableN‐1.SurfactantMaking‐OutdoorTankEmissions

Throughput1 VaporPressure1 MolecularWeight1 BulkLiquidTemperature1,2 LiquidDensity1 TankCapacity1

EUID (gal/yr) (psia) (lb/lb‐mol) (°F) (lb/gal) (gal) (lb/hr) (tpy) HAPName (lb/hr) (tpy) (lb/hr) (tpy)3 20,327,735 3.50E‐03 197 90.5 6.84 120,762 1.3E‐02 5.5E‐02 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐4 8,805,475 3.42E‐03 197 89.6 7.18 48,345 5.1E‐03 2.2E‐02 EthyleneOxide 5.1E‐03 2.2E‐02 ‐‐ ‐‐5 9,481,192 3.92E‐03 197 95 7.68 40,109 5.5E‐03 2.4E‐02 EthyleneOxide 5.5E‐03 2.4E‐02 ‐‐ ‐‐6 1,917,922 8.62E‐01 46 Ambient 6.58 40,109 2.0E‐01 8.6E‐01 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7 7,823,046 1.50E‐03 323 99.5 8.69 15,125 2.2E‐03 9.5E‐03 1,4Dioxane 4.6E‐04 2.0E‐03 ‐‐ ‐‐8 7,823,046 1.50E‐03 323 95 8.69 15,125 2.2E‐03 9.6E‐03 1,4Dioxane 4.6E‐04 2.0E‐03 ‐‐ ‐‐9 6,841,173 1.50E‐03 323 95 8.69 15,125 2.0E‐03 8.7E‐03 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐10 39,115,231 1.32E‐03 323 99.5 8.35 72,475 9.4E‐03 4.1E‐02 1,4Dioxane 2.3E‐03 1.0E‐02 ‐‐ ‐‐11 39,115,231 1.32E‐03 323 99.5 8.35 72,475 9.4E‐03 4.1E‐02 1,4Dioxane 2.3E‐03 1.0E‐02 ‐‐ ‐‐12 39,115,231 1.24E‐03 323 95 8.35 72,475 9.0E‐03 3.9E‐02 1,4Dioxane 2.3E‐03 1.0E‐02 ‐‐ ‐‐13 39,115,231 1.24E‐03 323 95 8.35 72,475 9.0E‐03 3.9E‐02 1,4Dioxane 2.3E‐03 1.0E‐02 ‐‐ ‐‐14 34,205,863 1.24E‐03 323 95 8.35 72,475 8.1E‐03 3.6E‐02 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐15 34,205,863 1.24E‐03 323 95 8.35 72,475 8.1E‐03 3.6E‐02 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐16 115,491 1.50E‐03 323 95 8.69 26,083 1.4E‐04 6.3E‐04 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐17 2,000,000 1.69E‐03 98 77 15.36 15,125 ‐‐ -- -- -- -- 3.5E‐04 1.5E‐0318 150,000 1.69E‐03 98 77 15.36 15,125 6.6E‐05 2.9E‐04 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

2.8E‐01 1.2 ‐‐ 2.1E‐02 9.1E‐02 3.5E‐04 1.5E‐031.ChemicaldataandtankparametersfromProcterandGamble.

3.EmissionscalculatedperAP‐42,Section7.1(OrganicLiquidStorageTanks )andTrinitycalculationsspreadsheets.Specifically,equationscontainedinSection7.1.3.1( TotalLossesfromFixedRoofTanks )areutilized.

4.TraceamountsofHAPbyproductinsurfactant.

VOCPotentialtoEmit3

Total

H2SO4 Potential to Emit3

2.Alltankswillbetemperaturecontrolled(heatedandinsulated)exceptfortheambienttank.Unheatedtankemissionsforcoldmonths(Dec‐Feb)conservativelyassumedtobeequaltomaxwarmmonthemissions.

HAPPotentialtoEmit4


141801.0078


TableN‐2.SurfactantMaking‐TruckLoadingEmissions

AmountLoaded

FrequencyLoaded

VaporPressure

MolecularWeight Temp. VOC1 H2SO4

EUID Description (gal/truck) (trucks/yr) (psia) (lb/lb‐mol) R (wt%) wt% VOC H2SO4 VOC H2SO4 VOC H2SO4

PAMTruckLoadout 11,600 13 1.69E‐03 98 528 0.6 100% 30% 2.35E‐03 7.06E‐04 4.0E‐05 1.2E‐05 1.8E‐04 5.3E‐05SurfactantFinalProductTruckLoadout 11,600 1,293 1.50E‐03 323 528 0.6 100% 0% 6.86E‐03 ‐‐ 1.2E‐02 ‐‐ 5.1E‐02 ‐‐

SulfuricAcidTruckLoadout 11,600 172 1.69E‐03 98 528 0.6 0% 100% ‐‐ 2.35E‐03 ‐‐ 5.4E‐04 ‐‐ 2.4E‐03

Total 5.2E‐02 2.4E‐03

1.ConservativelyassumedthatVOCcontentofPAMandsurfactantfinishedproductis100%.

2.LoadinglossemissionfactorscalculatedperAP‐42,Chapter5.2(TransportationandMarketingofPetroleumLiquids ),Equation1.Assumessubmergedfilling.

EmissionFactor(lb/10³gal)2

AnnualEmissions(tpy)

HourlyEmissions(lb/hr)Saturation

Factor

19


141801.0078


TableN‐3.SurfactantMaking‐ScrubberStack

EmissionsUnit Operation1

EstimatedHoursofOperationfor

System Flowrate2

PollutantConcentration

(ppm)2

PollutantConcentration(mg/m³)

(scfm) NOX NOX NOx CO SO2 VOC PM10/PM2.53 H2SO4 NOx CO SO2 VOC PM10/PM2.5

3 H2SO4

Normal 8,760 5 10.13 5.3E‐01 ‐‐ 1.3E‐01 4.51E‐01 2.1 1.7 2.3 ‐‐ 5.6E‐01 2.0 9.4 7.4

ChangeOver 365 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 9.02E‐01 2.59 1.69 ‐‐ ‐‐ ‐‐ 1.65E‐01 4.73E‐01 3.08E‐01

SulfuricAcidProduction 8,760 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 8.5E‐01 8.5E‐01 ‐‐ ‐‐ ‐‐ ‐‐ 3.7 3.7

Start‐Up 288 ‐‐ ‐‐ ‐‐ ‐‐ 1.8 ‐‐ 1.7 1.7 ‐‐ ‐‐ 2.60E‐01 ‐‐ 2.43E‐01 2.43E‐01

Normal 8,760 5 10.13 5.3E‐01 ‐‐ 1.3E‐01 4.5E‐01 2.1 1.7 2.3 ‐‐ 5.6E‐01 2.0 9.4 7.4

ChangeOver 156 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 9.0E‐01 2.6 1.7 ‐‐ ‐‐ ‐‐ 7.0E‐02 2.0E‐01 1.3E‐01

SulfuricAcidProduction 0 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 8.5E‐01 8.5E‐01 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

Start‐Up 288 ‐‐ ‐‐ ‐‐ ‐‐ 1.8 ‐‐ 1.7 1.7 ‐‐ ‐‐ 2.6E‐01 ‐‐ 2.4E‐01 2.4E‐01

Total 4.7 0.2 1.6 4.2 23.6 19.4

EmissionsUnit Operation1

PollutantConcentration

(ppm)2

PollutantConcentration(mg/m³)

NOX NOX NOx CO SO2 VOC PM10/PM2.53 H2SO4

Normal 5 10.13 5.3E‐01 ‐‐ 1.3E‐01 4.5E‐01 2.1 1.7

ChangeOver ‐‐ ‐‐ 5.3E‐01 ‐‐ ‐‐ 1.4 4.7 3.4

Start‐Up ‐‐ ‐‐ 5.3E‐01 ‐‐ 1.9 ‐‐ 3.4 3.4

Total4 1.1 0.1 2.1 1.80 6.9 5.1

1.Assumesprocessisrunningnormally8,760hoursperyear.ChangeOver/Start‐Up/SulfuricAcidProductionisaddedasadditionalemissionsbeyondthebaseline.

2.Pervendor‐providedspecificationsandemissionsdata.

3.ConservativelyassumesPM10=PM2.5.

4.Maximumhourlyemissionsarecalculatedasthemaximumofthestart‐upandchangeoveremissionsaddedtothenormalemissionsperstack.


1Cor2CMaximumHour

14,000

14,0001C

2C

Worst‐CaseHourlyEmissionsPerStack(lb/hr)

NormalHourlyEmissions(lb/hr)


141801.0078


TableN‐4.ScrubberPreheaters‐Start‐upOperations 1

NumberofHeaters HeaterRatedCapacityAnnualOperating

HoursNaturalGasHeating

Value(HHV) EmissionFactor(MMBtu/hr) (hr/yr) (Btu/scf) Pollutant (lb/MMscf) Reference (lb/hr) (tpy)

NOx 50 2 7.8E‐01 2.8E‐02CO 84 2 1.3E+00 4.7E‐02PM 7.60 2 1.2E‐01 4.3E‐03PM10 7.60 2 1.2E‐01 4.3E‐03PM2.5 7.60 2 1.2E‐01 4.3E‐03SO2 0.60 2 9.4E‐03 3.4E‐04VOC 5.50 2 8.6E‐02 3.1E‐03H2SO4 6.50E‐03 3 1.0E‐04 3.7E‐06Lead 5.00E‐04 2 7.8E‐06 2.8E‐07

2‐Methylnaphthalene 2.40E‐05 4 3.8E‐07 1.4E‐083‐Methylchloranthrene 1.80E‐06 4 2.8E‐08 1.0E‐09

7,12‐Dimethylbenz(a)anthracene 1.60E‐05 4 2.5E‐07 9.0E‐09

Acenaphthene 1.80E‐06 4 2.8E‐08 1.0E‐09Acenaphthylene 1.80E‐06 4 2.8E‐08 1.0E‐09Anthracene 2.40E‐06 4 3.8E‐08 1.4E‐09

Benz(a)anthracene 1.80E‐06 4 2.8E‐08 1.0E‐09Benzene 2.10E‐03 4 3.3E‐05 1.2E‐06

Benzo(a)pyrene 1.20E‐06 4 1.9E‐08 6.8E‐10Benzo(b)fluoranthene 1.80E‐06 4 2.8E‐08 1.0E‐09Benzo(g,h,i)perylene 1.20E‐06 4 1.9E‐08 6.8E‐10Benzo(k)fluoranthene 1.80E‐06 4 2.8E‐08 1.0E‐09

Chrysene 1.80E‐06 4 2.8E‐08 1.0E‐09Dibenzo(a,h)anthracene 1.20E‐06 4 1.9E‐08 6.8E‐10

Dichlorobenzene 1.20E‐03 4 1.9E‐05 6.8E‐07Fluoranthene 3.00E‐06 4 4.7E‐08 1.7E‐09Fluorene 2.80E‐06 4 4.4E‐08 1.6E‐09

Formaldehyde 7.50E‐02 4 1.2E‐03 4.2E‐05Hexane 1.80E+00 4 2.8E‐02 1.0E‐03

Indeno(1,2,3‐cd)pyrene 1.80E‐06 4 2.8E‐08 1.0E‐09Naphthalene 6.10E‐04 4 9.6E‐06 3.4E‐07Phenanathrene 1.70E‐05 4 2.7E‐07 9.6E‐09

Pyrene 5.00E‐06 4 7.8E‐08 2.8E‐09Toluene 3.40E‐03 4 5.3E‐05 1.9E‐06Arsenic 2.00E‐04 4 3.1E‐06 1.1E‐07Beryllium 1.20E‐05 4 1.9E‐07 6.8E‐09Cadmium 1.10E‐03 4 1.7E‐05 6.2E‐07Chromium 1.40E‐03 4 2.2E‐05 7.9E‐07Cobalt 8.40E‐05 4 1.3E‐06 4.7E‐08Lead 5.00E‐04 4 7.8E‐06 2.8E‐07

Manganese 3.80E‐04 4 6.0E‐06 2.1E‐07Mercury 2.60E‐04 4 4.1E‐06 1.5E‐07Nickel 2.10E‐03 4 3.3E‐05 1.2E‐06

Selenium 2.40E‐05 4 3.8E‐07 1.4E‐082.8E-02 1.0E-033.0E-02 1.1E-03

4.NaturalgasemissionfactorsfromAP‐42,Tables1.4‐3and1.4‐4.

Emissions

4 72 1,020

MaxHAPTotalHAPs

4

1.Duringstartup,combustionemissionsfromthecatalystbedareexhaustedthroughtheSO2scrubber.

2.NaturalgasemissionfactorsfromAP‐42Section1.4.PMassumedtoequalPM10.

3.Naturalgasfactorcalculatedassuming1%ofsulfurbecomesH2SO4.


141801.0078


TableN‐5.LiquidSoapAandBMaking‐OutdoorTankEmissions

EUID DescriptionThroughput1

VaporPressure

MolecularWeight

LiquidDensity

BulkLiquidTemperature2

TankCapacity1

(gal/yr) (psia) (lb/lb‐mol) (lb/gal) (°F) (gal) (lb/hr) (tpy) HAPName (lb/hr) (tpy)20 RawMaterial 13,431,682 1.32E‐03 323 8.35 113 39,626 3.6E‐03 1.6E‐02 1,4Dioxane 7.9E‐04 3.5E‐0321 RawMaterial 24,833,180 1.24E‐03 323 8.35 113 39,626 5.3E‐03 2.3E‐02 1,4Dioxane 1.5E‐03 6.4E‐0322 RawMaterial 18,189,304 1.24E‐03 323 8.35 113 39,626 4.2E‐03 1.8E‐02 ‐‐ ‐‐ ‐‐23 RawMaterial 291,058 1.24E‐03 323 8.35 113 7,925 2.8E‐04 1.2E‐03 EthyleneOxide 2.8E‐04 1.2E‐0324 RawMaterial 229,500 2.03E‐01 36 9.16 113 7,925 ‐‐ ‐‐ HydrogenChloride 4.2E‐03 1.8E‐0225 RawMaterial 46,050,900 9.28E‐17 343 0.88 113 39,626 7.0E‐16 3.1E‐15 ‐‐ ‐‐ ‐‐26 RawMaterial 685,694 n/a 503 7.51 113 15,850 n/a 0.0E+00 ‐‐ ‐‐ ‐‐27 RawMaterial 2,317,226 1.60E‐03 388 8.97 113 39,626 2.4E‐03 1.0E‐02 ‐‐ ‐‐ ‐‐28 RawMaterial 2,012,364 1.93E‐04 270 6.78 113 26,417 1.5E‐04 6.4E‐04 ‐‐ ‐‐ ‐‐29 RawMaterial 1,039,693 1.16E‐07 242 6.77 113 15,850 4.4E‐08 1.9E‐07 ‐‐ ‐‐ ‐‐30 RawMaterial 1,646,085 7.25E‐05 503 8.35 113 26,417 9.6E‐05 4.2E‐04 ‐‐ ‐‐ ‐‐31 RawMaterial 1,691,510 3.30E‐02 503 8.35 113 15,850 3.0E‐02 1.3E‐01 ‐‐ ‐‐ ‐‐32 RawMaterial 240,216 8.13E‐01 368 7.93 113 15,850 n/a 7.8E‐01 ‐‐ ‐‐ ‐‐33 RawMaterial 282,057 4.83E‐05 92 10.52 77 7,925 5.6E‐07 1.4E‐05 ‐‐ ‐‐ ‐‐34 RawMaterial 146,204 5.00E‐01 200 8.71 Ambient 7,925 7.2E‐02 3.2E‐01 SeeNote4 3.6E‐04 1.6E‐0335 RawMaterial 47,372 5.00E‐01 200 8.71 Ambient 7,925 4.5E‐02 2.0E‐01 SeeNote4 2.3E‐04 9.9E‐0436 RawMaterial 38,244 5.00E‐01 200 8.71 Ambient 7,925 4.3E‐02 1.9E‐01 SeeNote4 2.1E‐04 9.3E‐0437 RawMaterial 7,552 5.00E‐01 200 8.71 Ambient 7,925 3.4E‐02 1.5E‐01 SeeNote4 1.7E‐04 7.4E‐0450 RawMaterial 696,309 1.24E‐03 323 8.35 77 7,925 4.8E‐04 2.1E‐03 ‐‐ ‐‐ ‐‐56 RawMaterial 287,453 1.59E‐03 76 9.09 77 7,275 9.2E‐05 4.0E‐04 ‐‐ ‐‐ ‐‐53 RawMaterial 112,722 1.24E‐03 323 8.35 77 7,925 1.2E‐04 5.26E‐04 ‐‐ ‐‐ ‐‐

2.4E‐01 1.8 ‐‐ 7.7E‐03 3.4E‐02

2.EmissionscalculatedperAP‐42,Section7.1(OrganicLiquidStorageTanks )andTrinitycalculationsspreadsheets.Specifically,equationscontainedinSection7.1.3.1(TotalLossesfromFixedRoofTanks )areutilized.

3.HAPEmissionsfromperfumesassumedtobe0.5%ofVOCemissions.TraceamountofbyproductHAPinsurfactant.

4.Baseduponassessmentofrawmaterialcomposition,HAPspeciationdeterminedtobe99%glycoletherand1%acetophenone.

HAPPotentialtoEmit3VOCPotentialtoEmit2

Total1.TankcapacitiesandthroughputsperProcterandGambledesigndatasheets.


141801.0078


TableN‐6.LiquidSoapAandBMaking‐IndoorTankEmissions


VaporPressure2

MolecularWeight2

LiquidDensity2


TankCapacity1

(gal/yr) (psia) (lb/lb‐mol) (lb/gal) (°F) (gal) (lb/hr) (tpy) (lb/hr) (tpy)38 RawMaterial 37,808 8.13E‐01 503 8.50 77 396 2.5E‐02 1.1E‐01 ‐‐ ‐‐40 RawMaterial 16,874 5.61E‐02 292 12.02 77 396 7.3E‐04 3.2E‐03 ‐‐ ‐‐41 RawMaterial 12,883 2.90E‐10 205 10.01 77 396 2.0E‐12 8.9E‐12 ‐‐ ‐‐42 RawMaterial 8,007 8.13E‐01 233 8.96 77 396 4.0E‐03 1.8E‐02 ‐‐ ‐‐43 RawMaterial 147,994 8.13E‐01 503 7.93 77 396 4.5E‐02 2.0E‐01 ‐‐ ‐‐44 RawMaterial 11,983 8.13E‐01 503 8.68 77 396 1.3E‐02 5.7E‐02 ‐‐ ‐‐45 RawMaterial 121,569 1.82E‐03 108 8.71 77 396 1.9E‐05 8.4E‐05 ‐‐ ‐‐46 RawMaterial 14,581 4.50E‐01 503 8.31 77 396 8.7E‐03 3.8E‐02 ‐‐ ‐‐47 RawMaterial 8,418 8.13E‐01 503 8.35 77 396 9.1E‐03 4.0E‐02 ‐‐ ‐‐51 RawMaterial n/a n/a n/a n/a 77 396 n/a n/a ‐‐ ‐‐52 RawMaterial 990 1.24E‐03 323 8.35 77 396 1.1E‐06 4.6E‐06 ‐‐ ‐‐54 RawMaterial 267,217 1.24E‐03 323 8.35 77 660 6.5E‐05 2.8E‐04 ‐‐ ‐‐55 RawMaterial 75 8.13E‐01 503 8.50 77 396 8.1E‐05 3.5E‐04 ‐‐ ‐‐57 RawMaterial 24,591 1.59E‐03 76 9.09 77 1,057 6.6E‐06 2.9E‐05 ‐‐ ‐‐59 RawMaterial 2,260 1.59E‐03 76 9.09 77 396 7.2E‐07 3.2E‐06 ‐‐ ‐‐60 RawMaterial 1,953 5.80E‐04 138 8.41 77 132 4.1E‐07 1.8E‐06 4.1E‐07 1.8E‐0661 RawMaterial 175,632 8.13E‐01 503 8.31 77 396 5.0E‐02 2.2E‐01 ‐‐ ‐‐63 RawMaterial 38,430 3.40E‐01 503 7.59 77 396 1.0E‐02 4.5E‐02 ‐‐ ‐‐64 RawMaterial 15,482 0.12 200 8.71 74 396 9.9E‐04 4.3E‐03 4.9E‐06 2.2E‐0565 RawMaterial 14,619 0.12 200 8.71 74 396 9.3E‐04 4.1E‐03 4.7E‐06 2.0E‐0566 RawMaterial 24,900 0.12 200 8.71 74 396 1.3E‐03 5.8E‐03 6.6E‐06 2.9E‐0567 RawMaterial 48,605 0.12 200 8.71 74 396 1.6E‐03 6.9E‐03 7.9E‐06 3.4E‐0568 RawMaterial 26,366 0.12 200 8.71 74 396 1.3E‐03 5.8E‐03 6.7E‐06 2.9E‐0569 RawMaterial 13,652 0.12 200 8.71 74 396 8.7E‐04 3.8E‐03 4.4E‐06 1.9E‐0570 RawMaterial 6,427 0.12 200 8.71 74 396 4.1E‐04 1.8E‐03 2.1E‐06 9.0E‐0671 RawMaterial 12,577 0.12 200 8.71 74 396 8.0E‐04 3.5E‐03 4.0E‐06 1.8E‐0572 RawMaterial 31,508 0.12 200 8.71 74 396 1.4E‐03 6.1E‐03 6.9E‐06 3.0E‐0573 RawMaterial 15,126 0.12 200 8.71 74 396 9.7E‐04 4.2E‐03 4.8E‐06 2.1E‐0574 RawMaterial 64,637 0.12 200 8.71 74 396 1.7E‐03 7.6E‐03 8.7E‐06 3.8E‐0575 RawMaterial 18,314 0.12 200 8.71 74 396 1.2E‐03 5.1E‐03 5.9E‐06 2.6E‐0576 RawMaterial 29,347 0.12 200 8.71 74 396 1.4E‐03 6.0E‐03 6.8E‐06 3.0E‐0577 RawMaterial 43,353 0.12 200 8.71 74 396 1.5E‐03 6.6E‐03 7.6E‐06 3.3E‐05

HAPPotentialtoEmit4VOCPotentialtoEmit2,3


141801.0078


TableN‐6.LiquidSoapAandBMaking‐IndoorTankEmissions


VaporPressure2

MolecularWeight2

LiquidDensity2


TankCapacity1

(gal/yr) (psia) (lb/lb‐mol) (lb/gal) (°F) (gal) (lb/hr) (tpy) (lb/hr) (tpy)HAPPotentialtoEmit4VOCPotentialtoEmit2,3

87 FinishedProduct 3,799,073 0.0011 200 8.71 90 1,585 4.0E‐04 1.7E‐03 ‐‐ ‐‐88 FinishedProduct 3,799,073 0.0011 200 8.71 90 1,585 3.4E‐04 1.5E‐03 ‐‐ ‐‐89 FinishedProduct 3,799,073 0.0011 200 8.71 90 1,585 3.4E‐04 1.5E‐03 ‐‐ ‐‐90 FinishedProduct 3,799,073 0.0011 200 8.71 90 1,585 3.4E‐04 1.5E‐03 ‐‐ ‐‐91 FinishedProduct 3,799,073 0.0011 200 8.71 90 1,585 3.4E‐04 1.5E‐03 ‐‐ ‐‐92 FinishedProduct 3,799,073 0.0011 200 8.71 90 1,585 3.4E‐04 1.5E‐03 ‐‐ ‐‐93 FinishedProduct 3,799,073 0.0011 200 8.71 90 1,585 3.4E‐04 1.5E‐03 ‐‐ ‐‐94 FinishedProduct 3,799,073 0.0011 200 8.71 90 1,585 3.4E‐04 1.5E‐03 ‐‐ ‐‐94b FinishedProduct 2,048,433 0.0011 200 8.71 90 1,585 2.3E‐04 1.0E‐03 ‐‐ ‐‐94c FinishedProduct 2,048,433 0.0011 200 8.71 90 1,585 2.0E‐04 8.8E‐04 ‐‐ ‐‐94d FinishedProduct 2,048,433 0.0011 200 8.71 90 1,585 2.0E‐04 8.8E‐04 ‐‐ ‐‐94e FinishedProduct 2,048,433 0.0011 200 8.71 90 1,585 2.0E‐04 8.8E‐04 ‐‐ ‐‐95 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 6.5E‐05 2.8E‐04 ‐‐ ‐‐96 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐97 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐98 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐99 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐100 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐101 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐102 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐103 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐104 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐105 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐106 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐107 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐108 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐109 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐110 FinishedProduct 3,973,279 0.0002 200 8.71 90 1,585 5.5E‐05 2.4E‐04 ‐‐ ‐‐111 FinishedProduct 2,048,433 0.0002 200 8.71 90 1,585 3.6E‐05 1.6E‐04 ‐‐ ‐‐112 FinishedProduct 2,048,433 0.0002 200 8.71 90 1,585 3.1E‐05 1.4E‐04 ‐‐ ‐‐113 FinishedProduct 2,048,433 0.0002 200 8.71 90 1,585 3.1E‐05 1.4E‐04 ‐‐ ‐‐114 FinishedProduct 2,048,433 0.0002 200 8.71 90 1,585 3.1E‐05 1.4E‐04 ‐‐ ‐‐115 FinishedProduct 7,786 0.0002 200 8.71 90 1,585 6.9E‐07 3.0E‐06 ‐‐ ‐‐116 FinishedProduct 7,786 0.0002 200 8.71 90 1,585 5.8E‐07 2.5E‐06 ‐‐ ‐‐117 FinishedProduct 7,786 0.0002 200 8.71 90 1,585 5.8E‐07 2.5E‐06 ‐‐ ‐‐118 FinishedProduct 7,786 0.0002 200 8.71 90 1,585 5.8E‐07 2.5E‐06 ‐‐ ‐‐

Total 0.2 0.8 8.2E‐05 3.6E‐04


4.HAPEmissionsfromperfumesassumedtobe0.5%ofVOCemissions.Baseduponassessmentofrawmaterialcomposition,HAPspeciationdeterminedtobe99%glycoletherand1%acetophenone.

1.TankcapacitiesandthroughputsperProcterandGambledesigndatasheets.

2.Finishedproducttanksassumedtocontainafractionalamountofvolatilematerials.


141801.0078


TableN‐7.SoapMakingBusinessAandB‐FinishedProductPackingandCappingEmissions

Temperature VaporPressure1 Mol.Wt.1 ThroughputEUID Description (°F) (psia) (lb/lb‐mol) (gal/yr) (lb/hr) (tpy)

119SoapMakingBusinessAandBPackingand

CappingLine90 0.0011 200 139,798,617 0.20 2.5E‐04 1.1E‐03

1.Conservativeestimateofproductformulation.

2.KNcalculatedassuminginfinitelymanyturnovers,N,peryear(i.e.,largematerialthroughputandsmallbottlevolume).

3.EmissionscalculatedperAP‐42,Chapter7.1(OrganicLiquidStorageTanks ),Equation1‐29.

Kn2VOCPotentialtoEmit3


141801.0078


TableN‐8.LiquidSoapAandB‐RotocloneParticulateEmissions

ProcessUnitNumbers

RotocloneNumber1

RotocloneNamePM/PM10/PM2.5

EstimatedControlEfficiency

EmissionFactor1

EmissionFactorUnits

AnnualThroughput2

AnnualThroughput

Units

PM/PM10/PM2.5

Emissions(tons/yr)

120S‐123S 3C PremixRotoclone1 96% 2.00E‐02 gr/dscf 1,182,600,000 scf/yr 1.7124S‐127S 4C LiquidSoapBRotoclone1 96% 2.00E‐02 gr/dscf 2,496,600,000 scf/yr 3.6128S‐131S 5C LiquidSoapBRotoclone2 96% 2.00E‐02 gr/dscf 2,496,600,000 scf/yr 3.6132S‐135S 6C LiquidSoapBRotoclone3 96% 2.00E‐02 gr/dscf 1,655,640,000 scf/yr 2.4

136S‐139S 7C ScaleandLabRotoclone14 96% 2.00E‐02 gr/dscf 525,600,000 scf/yr 0.8

140S‐144S 8C ScaleandLabRotoclone24 96% 2.00E‐02 gr/dscf 525,600,000 scf/yr 0.8146S‐148S 9C LiquidSoapARotoclone1 98% 2.00E‐02 gr/dscf 919,800,000 scf/yr 1.3150S‐152S 10C LiquidSoapARotoclone2 98% 2.00E‐02 gr/dscf 919,800,000 scf/yr 1.3154S‐156S 11C LiquidSoapARotoclone3 98% 2.00E‐02 gr/dscf 919,800,000 scf/yr 1.3158S‐160S 12C LiquidSoapARotoclone4 98% 2.00E‐02 gr/dscf 1,603,080,000 scf/yr 2.3161S‐162S 13C LiquidSoapBRotoclone4 96% 2.00E‐02 gr/dscf 735,840,000 scf/yr 1.1

20.0

2.ConservativeassumptionsbasedonP&GprocessknowledgeforLiquidSoapAandB.ConservativelyassumesPM=PM 10 =PM 2.5

3.Annualthroughputsbasedonmaximumanticipatedproductionvolumes.

Total

1.Controlincludesdustpickuppointsassociatedwithidentifiedprocessunits.Controlonlyoperateswhenpowdersarebeingadded.OthervolatilelossesfrommakingventthroughfugitiveandgeneralprocessventpointsareincludedinoverallVOCemissions.


141801.0078


TableN‐9.LiquidSoapAandB‐RotocloneandFugitiveVOCEmissions

ProcessUnitNumbers RotocloneNumber1 RotocloneName VOCControlEfficiency EmissionFactor2 EmissionFactorUnits

AnnualThroughput3

(lb/yr)

VOCEmissions(ton/yr)

120S‐123S 3C PremixRotoclone1 0% 1.61E‐02 lb/1000lbs 106,407,288 0.86124S‐127S 4C LiquidSoapBRotoclone1 0% 1.61E‐02 lb/1000lbs 197,299,946 1.59128S‐131S 5C LiquidSoapBRotoclone2 0% 1.61E‐02 lb/1000lbs 238,595,283 1.93132S‐135S 6C LiquidSoapBRotoclone3 0% 1.61E‐02 lb/1000lbs 197,299,946 1.59

136S‐139S 7C ScaleandLabRotoclone14 0% ‐‐ ‐‐ ‐‐ ‐‐

140S‐144S 8C ScaleandLabRotoclone24 0% ‐‐ ‐‐ ‐‐ ‐‐

146S‐148S,150S‐152S,154S‐156S,158S‐160S

9C,10C,11C,12C LiquidSoapAPerfumeLoss 0% 2.60E‐02 lb/1000lbs 179,183,246 2.33

146S‐148S 9C LiquidSoapARotoclone1 0% 1.00E+00 lb/1000lbs150S‐152S 10C LiquidSoapARotoclone2 0% 1.00E+00 lb/1000lbs154S‐156S 11C LiquidSoapARotoclone3 0% 1.00E+00 lb/1000lbs158S‐160S 12C LiquidSoapARotoclone4 0% 1.00E+00 lb/1000lbs161S‐162S 13C LiquidSoapBRotoclone4 0% 1.61E‐02 lb/1000lbs 5,383,423 0.04

33.43

2.EmissionfactorbasedonP&Gprocessknowledge.

3.ThroughputlistedforLiquidSoapAnon‐perfumeVOCisthatwhichcontainsthevolatileprocessingaid.

4.ScaleandLabRotocloneisnotusedformeasuringvolatilematerials.

1.VolatilelossesfrommakingventthroughfugitiveandgeneralprocessventpointsareincludedinoverallVOCemissions.

50,171,309 25.09

TOTAL


141801.0078


TableN‐10.LiquidSoapA‐RegenerativeThermalOxidizerEmissionsParameter Value Unit

ControlDeviceNumber 14C

EmissionUnitNumbers 145S,149S,153S,157SThroughputofLiquid

SoapA(Total)171,673 tpy

TotalHeatInput 2.4 MMBtu/hrPotentialThroughput 2.35E‐03 MMCF/hr

Pollutant EmissionFactor Units Source

UncontrolledEmissions(lb/hr)

ControlEfficiency(%)

ControlledEmissions(lb/hr)

PTE(tpy)

PM10/PM2.5 7.6 lb/MMCF AP‐42 0.01 0 1.5E‐02 6.5E‐02SO2 6.00E‐01 lb/MMCF AP‐42 1.41E‐03 0 1.4E‐03 6.2E‐03NOX 1.00E‐01 lb/MMBtu Vendor 2.40E‐01 0 2.4E‐01 1.1

VOC‐controlled1,2 5.04 lb/ton MassBalance 213.5 97 6.4 5.4

VOC‐uncontrolled3 5.04 lb/ton MassBalance 213.5 0 213.5 2.6CO 1.33 lb/hr Vendor 1.33 0 1.3 5.8Lead 5.00E‐04 lb/MMCF AP‐42 1.18E‐06 0 1.2E‐06 5.2E‐06

Ammonia 3.2 lb/MMCF FIRE 0.01 0 7.5E‐03 3.30E‐021.BaseduponmaximumthroughputofLiquidSoapAcontainingavolatileprocessingaid.

2.RTOwilloperateonlywhenaHotMixTankforLiquidSoapAwithvolatileprocessingaidisbeingused.

3.Assumes24hours(12‐monthrolling)ofuncontrolledemissionsatmaximumshort‐termsystemcapacity .


141801.0078


TableN‐11.DryConsumerProductA‐OutdoorTankEmissions

Throughput1 VaporPressureMolecularWeight

BulkLiquidTemperature

LiquidDensity TankCapacity1

EUID (gal/yr) (psia) (lb/lb‐mol) (°F) (lb/gal) (gal) (lb/hr) (tpy) (lb/hr) (tpy)163 7,751,090 7.35E‐09 282 160 7.00 42,879 1.2E‐08 5.1E‐08 ‐‐ ‐‐164 13,608,386 7.35E‐09 282 160 7.97 37,641 1.6E‐08 7.1E‐08 ‐‐ ‐‐165 378,689 0.50 200 77 8.81 6,809 7.0E‐02 3.1E‐01 3.5E‐04 1.5E‐03

7.0E‐02 3.1E‐01 3.5E‐04 1.5E‐03

3.HAPemissionsfromperfumesassumedtobe0.5%ofVOCemissions.Basedonknowledgeofrawmaterials,HAPsare99%glycoletherand1%acetophenone.


VOCPotentialtoEmit2

Total

HAPPotentialtoEmit3

1.TankcapacitiesandthroughputsperProcterandGambledesigndatasheets.ThroughputsaretimeaveragedthroughputsbasedonplannedproductionlinesforothersimilarProcterandGamblefacilitiesandbusinessunits,scaledaccordingtoratioofplannedproductionlinesforthefacility.


141801.0078


TableN‐12.DryConsumerProductA‐IndoorTankEmissions

Throughput1Vapor

PressureMolecularWeight

BulkLiquidTemperature LiquidDensity TankCapacity1

EUID (gal/yr) (psia) (lb/lb‐mol) (°F) (lb/gal) (gal) (lb/hr) (tpy) (lb/hr) (tpy)166 78,893 0.50 200 77 8.81 396 5.4E‐03 2.4E‐02 2.7E‐05 1.2E‐04167 78,893 0.50 200 77 8.81 396 5.4E‐03 2.4E‐02 2.7E‐05 1.2E‐04168 78,893 0.50 200 77 8.81 396 5.4E‐03 2.4E‐02 2.7E‐05 1.2E‐04169 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05170 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05171 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05172 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05173 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05174 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05175 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05176 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05177 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05178 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05179 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05180 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05181 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05182 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05183 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05184 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05185 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05186 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05187 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05188 39,447 0.50 200 77 8.81 181 3.3E‐03 1.4E‐02 1.6E‐05 7.2E‐05

8.1E‐02 3.6E‐01 4.1E‐04 1.8E‐03


3.HAPemissionsfromperfumesassumedtobe0.5%ofVOCemissions.Basedonknowledgeofrawmaterials,HAPsare99%glycoletherand1%acetophenone.

VOCPotentialtoEmit2

Total

HAPPotentialtoEmit3

1.TankcapacitiesandthroughputsperProcterandGambledesigndatasheets.ThroughputsaretimeaveragedthroughputsbasedonplannedproductionlinesforothersimilarProcterandGamblefacilitiesandbusinessunits,scaledaccordingtoratioofplannedproductionlinesforthefacility.


141801.0078


TableN‐13.DryConsumerProductsA‐ParticulateControlDeviceEmissions

FabricFilterEfficiency1 AirFlowrate2

EUID ControlDeviceID Description ControlType (gr/scf) (scfm) (lb/hr) (tpy)189 15C DryConsumerProductsA‐ClaySilo‐Loading BinVentFilter 8,760 0.02 400 6.9E‐02 3.0E‐01190 16C DryConsumerProductsA‐ClayFRLExhaust Baghouse 8,760 0.02 275 4.7E‐02 2.1E‐01191 17C DryConsumerProductsA‐Feeder/MixerVent Baghouse 8,760 0.02 260 4.5E‐02 2.0E‐01192 18C DryConsumerProductsA‐Line11 Baghouse 8,760 0.010 18,000 1.54E+00 6.8193 19C DryConsumerProductsA‐Line13 Baghouse 8,760 0.010 18,000 1.54E+00 6.8194 20C CVC Baghouse 8,760 0.010 6,500 5.6E‐01 2.4

3.8 16.7

1.ConservativeassumptionsbasedonP&GprocessknowledgeforDryConsumerProductsA

2.PerP&GprocessknowledgeforDryConsumerProductsA

PM/PM10/PM2.5PotentialtoEmitHours/YearUtilized

Total


141801.0078


TableN‐14.DryConsumerProductsA‐AdditiveEmissionsSubstrateCoated

Area1 TemperatureVaporPressure MolecularWeight

MassTransferCoefficient2

ApplicationFrequency

NumberofLines CoatingMix VOCContent PMCContent

EUID Description (ft²) (°F) (psia) (lb/lb‐mol) (ft/hr) (%) (%) (%) (%) (lb/hr) (tpy)DryConsumerProductsA‐Additive 1,050 50 7.35E‐09 282 39.18 100 2 95 100 n/a 3.1E‐05 1.3E‐04DryConsumerProductsA‐Perfume 1,050 50 1.50E‐02 200 43.93 100 2 5 100 25 2.0 8.7

2.0 8.71.TheproductionlinesaredesignedbasedonthefollowingProcterandGambledesignspecifications.Substratelinespecifications

Substratelength: 2,100 inches2.MassTransferCoefficient(MTC)calculatedusingwater(H2O)asreferencecompound.H2OMTC: 98.03 ft/hrH2OMol.Wt.: 18 lb/lb‐mol

VOCEmissions

195

Total


141801.0078


TableN‐15.Utilities‐OverallUtilityInventory

Value Units2 50,267 pphsteam1 25,134 pphsteam1 8,918 pphsteam1 331 Mgal/hr1 792 Mgal/hr1 212 Mgal/hr

FirePumpEngine 2 311 hpBackup/StandbyPowerGenerator 3 350 kW

EngineULSDTanks 5 <500 gallonVehicleRefuelingULSDTank 1 5,000 gallon

WarehouseHeaters 6 3.05 MMBtu/hr

WeightedHeatofVaporization1

Value Units (Btu/lb) Value Units2 50,267 pphsteam 1,048.4 85% 62 MMBtu/hr1 25,134 pphsteam 1,048.4 85% 31 MMBtu/hr1 8,918 pphsteam 1,048.4 85% 11 MMBtu/hr

1.Steamparameters:

H2Oheatofvaporization(non‐condensatereturn): 1,178 Btu/lb

H2Oheatofvaporization(condensatereturn): 1,016 Btu/lb

Condensatereturn: 80%

Boilers

DesignSize BoilerEfficiency(HHV)

CalculatedSize

DesignSize

CoolingTowers

EquipmentType Quantity

QuantityEquipmentType

Boilers


141801.0078


TableN‐16.Utilities‐BoilerNos.1and2‐CriteriaPollutants

Value6225438,7601,000

HourlyEmissions(lb/hr)


NOX 60 ppm 2 4.5 19.8 39.5

CO 50 ppm 2 2.3 10.0 20.1

PM 3.80E‐03 lb/MMBtu 2 2.4E‐01 1.0 2.1

PM10 7.50E‐03 lb/MMBtu 2 4.7E‐01 2.0 4.1

PM2.5 7.50E‐03 lb/MMBtu 2 4.7E‐01 2.0 4.1

SO2 6.00E‐04 lb/MMBtu 2 3.7E‐02 1.6E‐01 3.3E‐01

VOC 3.60E‐03 lb/MMBtu 2 2.2E‐01 1.0 2.0

H2SO4 6.50E‐03 lb/MMscf 3 4.0E‐04 1.8E‐03 3.5E‐03

Parameter UnitNewBoilerHeatInput: MMBtu/hrNumberofNewBoilers:AnnualGasUsage: MMscf/yr

EquivalentGasHours: Hoursat100%LoadNaturalGasHeatingValue(HHV): Btu/scf

EmissionsforBoilers1and

2(tpy)

1.Naturalgasfactorsbasedonmanufacturer'sppmspecificationsforunitswithLNBandconvertedtolb/MMBtuusinganFfactorof8,710dscf/MMBtufornaturalgas.

2.Guaranteesfromboilervendor.


PollutantNaturalGasEmissionFactor

Units Reference

EmissionsPerBoiler


141801.0078


TableN‐17.Utilities‐BoilerNos.1and2‐HAPValue Unit62 MMBtu/hr2

8,760 hr/yr1,020 Btu/scf

lb/hr tpy lb/hr tpy

2‐Methylnaphthalene 2.4E‐05 lb/MMscf 1.5E‐06 6.4E‐06 2.9E‐06 1.3E‐053‐Methylchloranthrene 1.8E‐06 lb/MMscf 1.1E‐07 4.8E‐07 2.2E‐07 9.6E‐07

7,12‐Dimethylbenz(a)anthracene 1.6E‐05 lb/MMscf 9.7E‐07 4.3E‐06 1.9E‐06 8.5E‐06Acenaphthene 1.8E‐06 lb/MMscf 1.1E‐07 4.8E‐07 2.2E‐07 9.6E‐07Acenaphthylene 1.8E‐06 lb/MMscf 1.1E‐07 4.8E‐07 2.2E‐07 9.6E‐07Anthracene 2.4E‐06 lb/MMscf 1.5E‐07 6.4E‐07 2.9E‐07 1.3E‐06

Benz(a)anthracene 1.8E‐06 lb/MMscf 1.1E‐07 4.8E‐07 2.2E‐07 9.6E‐07Benzene 2.1E‐03 lb/MMscf 1.3E‐04 5.6E‐04 2.6E‐04 1.1E‐03

Benzo(a)pyrene 1.2E‐06 lb/MMscf 7.3E‐08 3.2E‐07 1.5E‐07 6.4E‐07Benzo(b)fluoranthene 1.8E‐06 lb/MMscf 1.1E‐07 4.8E‐07 2.2E‐07 9.6E‐07Benzo(g,h,i)perylene 1.2E‐06 lb/MMscf 7.3E‐08 3.2E‐07 1.5E‐07 6.4E‐07Benzo(k)fluoranthene 1.8E‐06 lb/MMscf 1.1E‐07 4.8E‐07 2.2E‐07 9.6E‐07

Chrysene 1.8E‐06 lb/MMscf 1.1E‐07 4.8E‐07 2.2E‐07 9.6E‐07Dibenzo(a,h)anthracene 1.2E‐06 lb/MMscf 7.3E‐08 3.2E‐07 1.5E‐07 6.4E‐07

Dichlorobenzene 1.2E‐03 lb/MMscf 7.3E‐05 3.2E‐04 1.5E‐04 6.4E‐04Fluoranthene 3.0E‐06 lb/MMscf 1.8E‐07 8.0E‐07 3.6E‐07 1.6E‐06Fluorene 2.8E‐06 lb/MMscf 1.7E‐07 7.5E‐07 3.4E‐07 1.5E‐06

Formaldehyde 7.5E‐02 lb/MMscf 4.6E‐03 2.0E‐02 9.1E‐03 4.0E‐02Hexane 1.8E+00 lb/MMscf 1.1E‐01 4.8E‐01 2.2E‐01 9.6E‐01

Indeno(1,2,3‐cd)pyrene 1.8E‐06 lb/MMscf 1.1E‐07 4.8E‐07 2.2E‐07 9.6E‐07Naphthalene 6.1E‐04 lb/MMscf 3.7E‐05 1.6E‐04 7.4E‐05 3.2E‐04Phenanathrene 1.7E‐05 lb/MMscf 1.0E‐06 4.5E‐06 2.1E‐06 9.1E‐06

Pyrene 5.0E‐06 lb/MMscf 3.0E‐07 1.3E‐06 6.1E‐07 2.7E‐06Toulene 3.4E‐03 lb/MMscf 2.1E‐04 9.1E‐04 4.1E‐04 1.8E‐03Arsenic 2.0E‐04 lb/MMscf 1.2E‐05 5.3E‐05 2.4E‐05 1.1E‐04Beryllium 1.2E‐05 lb/MMscf 7.3E‐07 3.2E‐06 1.5E‐06 6.4E‐06Cadmium 1.1E‐03 lb/MMscf 6.7E‐05 2.9E‐04 1.3E‐04 5.9E‐04Chromium 1.4E‐03 lb/MMscf 8.5E‐05 3.7E‐04 1.7E‐04 7.5E‐04Cobalt 8.4E‐05 lb/MMscf 5.1E‐06 2.2E‐05 1.0E‐05 4.5E‐05Lead 5.0E‐04 lb/MMscf 3.0E‐05 1.3E‐04 6.1E‐05 2.7E‐04

Manganese 3.8E‐04 lb/MMscf 2.3E‐05 1.0E‐04 4.6E‐05 2.0E‐04Mercury 2.6E‐04 lb/MMscf 1.6E‐05 6.9E‐05 3.2E‐05 1.4E‐04Nickel 2.1E‐03 lb/MMscf 1.3E‐04 5.6E‐04 2.6E‐04 1.1E‐03

Selenium 2.40E‐05 lb/MMscf 1.5E‐06 6.4E‐06 2.9E‐06 1.3E‐05TotalHAP 2.3E‐01 1.0E+00

1.NaturalgasemissionfactorsfromAP‐42,Tables1.4‐3and1.4‐4

Units

EmissionsforBoilers1and2

ParameterNewBoilerHeatInput:NumberofNewBoilers:

HoursofOperationonNaturalGas:NaturalGasHeatingValue(HHV):

PollutantNaturalGas

EmissionFactor1EmissionsPerBoiler


141801.0078


TableN‐18.Utilities‐BoilerNos.3‐Parameters

Value3112728,7601,000

NOX 60 ppm 2 2.3 9.9 9.9

CO 50 ppm 2 1.1 5.0 5.0

PM 3.80E‐03 lb/MMBtu 2 1.2E‐01 0.5 0.5

PM10 7.50E‐03 lb/MMBtu 2 2.3E‐01 1.0 1.0

PM2.5 7.50E‐03 lb/MMBtu 2 2.3E‐01 1.0 1.0

SO2 6.00E‐04 lb/MMBtu 2 1.9E‐02 8.1E‐02 8.1E‐02

VOC 3.60E‐03 lb/MMBtu 2 1.1E‐01 4.9E‐01 4.9E‐01

H2SO4 6.50E‐03 lb/MMscf 3 2.0E‐04 8.8E‐04 8.8E‐04

1.Naturalgasemissionfactorsbasedonmanufacturer'sppmspecificationsforunitswithLNBandconvertedtolb/MMBtuusinganFfactorof8,710dscf/MMBtufornaturalgas.

3.Naturalgasfactorcalculatedassuming1%ofsulfurbecomesH 2SO4.

2.Guaranteesfromboilervendor.

NaturalGasHourly

Emissions(lb/hr)

NaturalGasAnnual

Emissions(tpy)

Emissionsfor

Boiler3

(tpy)

PollutantNaturalGasEmissionFactor

Units Reference

NaturalGasHeatingValue(HHV): Btu/scfEquivalentGasHours: Hoursat100%LoadAnnualGasUsage: MMscf/yr

Parameter UnitNewBoilerHeatInput: MMBtu/hrNumberofNewBoilers:


141801.0078


TableN‐19.Utilities‐BoilerNos.3‐ParametersValue Unit31 MMBtu/hr1


lb/hr tpy

2‐Methylnaphthalene 2.4E‐05 lb/MMscf 7.3E‐07 3.2E‐063‐Methylchloranthrene 1.8E‐06 lb/MMscf 5.5E‐08 2.4E‐07

7,12‐Dimethylbenz(a)anthracene 1.6E‐05 lb/MMscf 4.9E‐07 2.1E‐06Acenaphthene 1.8E‐06 lb/MMscf 5.5E‐08 2.4E‐07Acenaphthylene 1.8E‐06 lb/MMscf 5.5E‐08 2.4E‐07Anthracene 2.4E‐06 lb/MMscf 7.3E‐08 3.2E‐07

Benz(a)anthracene 1.8E‐06 lb/MMscf 5.5E‐08 2.4E‐07Benzene 2.1E‐03 lb/MMscf 6.4E‐05 2.8E‐04

Benzo(a)pyrene 1.2E‐06 lb/MMscf 3.6E‐08 1.6E‐07Benzo(b)fluoranthene 1.8E‐06 lb/MMscf 5.5E‐08 2.4E‐07Benzo(g,h,i)perylene 1.2E‐06 lb/MMscf 3.6E‐08 1.6E‐07Benzo(k)fluoranthene 1.8E‐06 lb/MMscf 5.5E‐08 2.4E‐07

Chrysene 1.8E‐06 lb/MMscf 5.5E‐08 2.4E‐07Dibenzo(a,h)anthracene 1.2E‐06 lb/MMscf 3.6E‐08 1.6E‐07

Dichlorobenzene 1.2E‐03 lb/MMscf 3.6E‐05 1.6E‐04Fluoranthene 3.0E‐06 lb/MMscf 9.1E‐08 4.0E‐07Fluorene 2.8E‐06 lb/MMscf 8.5E‐08 3.7E‐07

Formaldehyde 7.5E‐02 lb/MMscf 2.3E‐03 1.0E‐02Hexane 1.8E+00 lb/MMscf 5.5E‐02 2.4E‐01

Indeno(1,2,3‐cd)pyrene 1.8E‐06 lb/MMscf 5.5E‐08 2.4E‐07Naphthalene 6.1E‐04 lb/MMscf 1.9E‐05 8.1E‐05Phenanathrene 1.7E‐05 lb/MMscf 5.2E‐07 2.3E‐06

Pyrene 5.0E‐06 lb/MMscf 1.5E‐07 6.7E‐07Toulene 3.4E‐03 lb/MMscf 1.0E‐04 4.5E‐04Arsenic 2.0E‐04 lb/MMscf 6.1E‐06 2.7E‐05Beryllium 1.2E‐05 lb/MMscf 3.6E‐07 1.6E‐06Cadmium 1.1E‐03 lb/MMscf 3.3E‐05 1.5E‐04Chromium 1.4E‐03 lb/MMscf 4.3E‐05 1.9E‐04Cobalt 8.4E‐05 lb/MMscf 2.6E‐06 1.1E‐05Lead 5.0E‐04 lb/MMscf 1.5E‐05 6.7E‐05

Manganese 3.8E‐04 lb/MMscf 1.2E‐05 5.1E‐05Mercury 2.6E‐04 lb/MMscf 7.9E‐06 3.5E‐05Nickel 2.1E‐03 lb/MMscf 6.4E‐05 2.8E‐04

Selenium 2.40E‐05 lb/MMscf 7.3E‐07 3.2E‐06TotalHAP 5.7E‐02 2.5E‐01

Emissions


PollutantNaturalGas

EmissionFactor1Units

ParameterNewBoilerHeatInput:NumberofNewBoilers:



141801.0078


TableN‐20.Utilities‐CoolingTowers‐Emissions

Parameter Unit1 Unit2 Unit3 EmissionsTotal

Location1 Surfactants CentralUtilities LiquidSoapAandB ‐‐

FlowRate(gpm)1 5,517 13,200 3,533 ‐‐

FlowRate(Mgal/hr) 331 792 212 ‐‐

FlowRate(Mgal/yr) 2,899,560 6,937,920 1,857,120 ‐‐

OperatingHours(hr/yr) 8,760 8,760 8,760 ‐‐

DensityofWater(lb/gal) 8.35 8.35 8.35 ‐‐

TotalDissolvedSolids,TDS(ppm) 1,600 1,600 1,600 ‐‐

Drift(%)2 5.00E‐03 5.00E‐03 5.00E‐03 ‐‐

Drift(gpm) 0.28 0.66 0.18 ‐‐

PM/PM10/PM2.5(lb/gal)3 6.7E‐07 6.7E‐07 6.7E‐07 ‐‐

PM/PM10/PM2.5(lb/hr) 2.2E‐01 5.3E‐01 1.4E‐01 0.9

PM/PM10/PM2.5(tpy) 1.0 2.3 0.6 3.9

3.PM10areconservativelyoverestimatedby(TDS,ppm)x(TotalDriftRate,lb/gal)/106,basedonAP‐42Section13.4‐3.

1.Clientspecification.

2.DriftPercentageforInducedDraftCoolerspecifiedinemailfromBrianMensinger(TrinityConsultants)toAllisonCole(TrinityConsultants)onJuly22,2015.


141801.0078


TableN‐21.Utilities‐Engines‐InventorySummaryEngineModel Type Number Size UnitCaterpillarC15 Backup/StandbyPowerGenerator 3 350 kW

ClarkeJW6H‐UFADF0 FirePump 2 311 hp

PollutantPotentialEmissionsperEngine,

CaterpillarC15(tpy)

PotentialEmissionsperEngine,Clarke

(tpy)

Emissions(tpy)

CO 1.4E‐01 1.4E‐01 6.9E‐01NOX 8.7E‐01 4.5E‐01 3.5VOC 1.1E‐02 1.7E‐02 6.7E‐02SO2 3.6E‐04 2.4E‐04 1.6E‐03PM 1.2E‐02 1.7E‐02 7.0E‐02PM10 1.2E‐02 1.7E‐02 6.9E‐02PM2.5 1.2E‐02 1.7E‐02 6.9E‐02

PollutantPotentialEmissionsperEngine,

CaterpillarC15(tpy)

PotentialEmissionsperEngine,Clarke

(tpy)

Emissions(tpy)

Benzene 7.7E‐04 5.1E‐04 3.3E‐03Toluene 3.4E‐04 2.2E‐04 1.5E‐03Xylenes 2.4E‐04 1.6E‐04 1.0E‐03Propylene 2.1E‐03 1.4E‐03 9.2E‐03

Formaldehyde 9.8E‐04 6.4E‐04 4.2E‐03Acetaldehyde 6.4E‐04 4.2E‐04 2.7E‐03Acrolein 7.7E‐05 5.0E‐05 3.3E‐04

PolycyclicAromaticHydrocarbons(PAH) 1.4E‐04 9.1E‐05 6.0E‐04MaxHAP 2.1E‐03 1.4E‐03 9.2E‐03TotalHAPs 5.3E‐03 3.5E‐03 2.3E‐02


141801.0078


TableN‐22.Utilities‐Engines‐Caterpillar350kWSourceDesignation Engine GeneratorDateManufactured TBD TBD

Manufacturer1 Caterpillar Caterpillar

ModelNo.2 C15 C15

StrokeCycle2 4‐Stroke ‐‐

FuelUsed2 Diesel ‐‐

FuelSulfurContent(%)3 0.0015 ‐‐

RatedCapacity(eKW)2 350.00 ‐‐

CalculatedHorsepower(bhp)4 473.69 ‐‐

GeneratingCapacity(kW)1 ‐‐ 350.00

MaximumFuelConsumptionat100%Load(gal/hr)2 28.60 ‐‐

HeatInput(MMBtu/hr)5 3.32 ‐‐

OperationalDetail ValuePotentialAnnualHoursofOperation(hr/yr): 500.00

PotentialFuelConsumption(Mgal/yr): 14.30

Pollutant EmissionFactors Units NotesCO 5.30E‐01 g/hp‐hr 2NOX 3.34 g/hp‐hr 2HC 4.18E‐02 g/hp‐hr 2,6SO2 3.08E‐06 lb/hp‐hr 7PM 4.60E‐02 g/hp‐hr 2,8PM10 4.60E‐02 g/hp‐hr 2,8PM2.5 4.60E‐02 g/hp‐hr 2,8

TableN‐24.Utilities‐Engines‐Caterpillar350kW

PotentialEmissions PotentialEmissions

(lb/hr)11 (tpy)CO 5.5E‐01 1.4E‐01NOx 3.5E+00 8.7E‐01VOC 4.4E‐02 1.1E‐02SO2 1.5E‐03 3.6E‐04PM 4.8E‐02 1.2E‐02PM10 4.6E‐02 1.2E‐02PM2.5 4.6E‐02 1.2E‐02

EmissionFactor PotentialEmissions PotentialEmissions

(lb/MMBtu)10 (lb/hr)9 (tpy)Benzene 9.33E‐04 3.1E‐03 7.7E‐04Toluene 4.09E‐04 1.4E‐03 3.4E‐04Xylenes 2.85E‐04 9.5E‐04 2.4E‐04Propylene 2.58E‐03 8.6E‐03 2.1E‐03


PolycyclicAromaticHydrocarbons(PAH) 1.68E‐04 5.6E‐04 1.4E‐048.6E‐03 2.1E‐032.1E‐02 5.3E‐03

Pollutant

Pollutant

MaxHAPTotalHAPs


2.Valuescomefromtheunit'sspecsheet"CaterpillarC15ATAACDieselEngine."Foundathttp://s7d2.scene7.com/is/content/caterpillar/C10059394.

3.Per40CFR80SubpartI,maximumsulfurcontentofULSDis15ppm(i.e.0.0015%).

4.Dieselgeneratorhorsepower(BHP)backcalculatedfromelectricgeneratorratedoutput(ekW).Aninefficiencyof1%wasincludedtoaccountforlossesfromshaftworktoelectricity.

5.ToconvertfrombhptoMMBtu/hr,anaveragebrake‐specificfuelconsumptionof7,000Btu/hp‐hrwasusedperAP‐42P‐42Section3.3,Table3.3‐1"EmissionFactorsforUncontrolledGasolineandDieselIndustrialEngines,"SupplementB,October1996.

6.Allhydrocarbon(HC)emissionsareconservativelyassumedtobeVOC.

7.SO2emissionfactorfromAP‐42Section3.3,Table3.3‐1"EmissionFactorsforUncontrolledGasolineandDieselIndustrialEngines,"SupplementB,October1996.

9.EmissionRate(lb/hr)=RatedCapacity(MMBtu/hrorbhp)×EmissionFactor(lb/MMBtuorlb/bhp‐hr).

10.EmissionfactorsfromAP‐42Section3.3,Table3.3‐2"SpeciatedOrganicCompoundEmissionFactorsforUncontrolledDieselEngines."

8.Allparticulatesareassumedtobe<1microninsize,wherePM,PM 10,andPM2.5 areassumedtobeequivalent,consistentwithAP‐42Section3.3,Table3.3‐1"EmissionFactorsforUncontrolledGasolineandDieselIndustrialEngines,"SupplementB,October1996.


141801.0078


TableN‐23.Utilities‐Engines‐ClarkeSourceDesignation EngineDateManufactured TBD

Manufacturer1 Clarke

ModelNo.2 JW6H‐UFADF0

StrokeCycle2 4‐Stroke

FuelUsed1 Diesel

FuelSulfurContent(%)3 0.0015

RatedHorsepower(bhp)2 311.00

MaximumFuelConsumptionat100%Load(gal/hr)4 16.13

HeatInput(MMBtu/hr)5 2.18

OperationalDetail ValuePotentialAnnualHoursofOperation(hr/yr): 500.00

PotentialFuelConsumption(Mgal/yr): 8.06

Pollutant EmissionFactors Units NotesCO 8.00E‐01 g/hp‐hr 6

NOX 2.61 g/hp‐hr 6

HC 1.00E‐01 g/hp‐hr 6,7

SO2 3.08E‐06 lb/hp‐hr 8

PM 1.00E‐01 g/hp‐hr 6,9

PM10 1.00E‐01 g/hp‐hr 6,9

PM2.5 1.00E‐01 g/hp‐hr 6,9

TableN‐26.Utilities‐Engines‐ClarkePotentialEmissions PotentialEmissions

(lb/hr)10 (tpy)CO 5.5E‐01 1.4E‐01

NOX 1.8 4.5E‐01

VOC 6.9E‐02 1.7E‐02

SO2 9.6E‐04 2.4E‐04

PM 6.9E‐02 1.7E‐02

PM10 6.9E‐02 1.7E‐02

PM2.5 6.9E‐02 1.7E‐02

EmissionFactor PotentialEmissions PotentialEmissions

(lb/MMBtu)11 (lb/hr)10 (tpy)Benzene 9.33E‐04 2.0E‐03 5.1E‐04Toluene 4.09E‐04 8.9E‐04 2.2E‐04Xylenes 2.85E‐04 6.2E‐04 1.6E‐04Propylene 2.58E‐03 5.6E‐03 1.4E‐03


PolycyclicAromaticHydrocarbons(PAH) 1.68E‐04 3.7E‐04 9.1E‐055.6E‐03 1.4E‐031.4E‐02 3.5E‐03

Pollutant

Pollutant

MaxHAPTotalHAPs


8.SO2emissionfactorfromAP‐42Section3.3,Table3.3‐1"EmissionFactorsforUncontrolledGasolineandDieselIndustrialEngines,"SupplementB,October1996.

2.Valuescomefromtheunit'sspecsheet"ClarkeJW6H‐UFADJ0FireEngineSpecifications."Foundathttp://www.clarkefire.com/Libraries/PDF/Spec_Sheet_JW6H‐UFAA‐AD_C133422.sflb.ashx

3.Per40CFR80SubpartI,maximumsulfurcontentofULSDis15ppm(i.e.0.0015%).

4.Maximumfuelconsumptioncalculatedastheheatinputfortheengine(MMBtu)dividedbytheenergydensityofdieselfuel(0.135MMBtu/gal).

5.ToconvertfrombhptoMMBtu/hr,anaveragebrake‐specificfuelconsumptionof7,000Btu/hp‐hrwasusedperAP‐42P‐42Section3.3,Table3.3‐1"EmissionFactorsforUncontrolledGasolineandDieselIndustrialEngines,"SupplementB,October1996.

6.NOX,HC,CO,andPMemissionfactorsfromJohnDeere"RatingSpecificEmissionsData."Foundathttp://www.clarkefire.com/Libraries/PDF/Emissions_JW6H‐UFADF0_6090HFC47A_1760rpm_2009.sflb.ashx

7.Toconservativelyover‐estimateemissions,allhydrocarbon(HC)emissionsareassumedtobeVOC.

10.EmissionRate(lb/hr)=RatedCapacity(MMBtu/hrorbhp)×EmissionFactor(lb/MMBtuorlb/bhp‐hr).

11.EmissionfactorsfromAP‐42Section3.3,Table3.3‐2"SpeciatedOrganicCompoundEmissionFactorsforUncontrolledDieselEngines."

9.Allparticulatesareassumedtobe<1microninsize,wherePM,PM 10,andPM2.5areassumedtobeequivalent,consistentwithAP‐42Section3.3,Table3.3‐1"EmissionFactorsforUncontrolledGasolineandDieselIndustrialEngines,"SupplementB,October1996.


141801.0078


TableN‐24.Utilities‐DieselTank‐Emissions

ThroughputVapor

Pressure1MolecularWeight1

BulkLiquidTemperature LiquidDensity1 TotalCapacity

EUID Description (gal/yr) (psia) (lb/lb‐mol) (°F) (lb/gal) (gal) (lb/hr) (tpy)

208 Diesel(DistillateFuelOilNo.2) 70,000 2.20E‐02 130 Ambient 7.1 5,162 5.2E‐04 2.3E‐035.2E‐04 2.3E‐03

1.ChemicalpropertiesperEPATANKS4.09ddatabasefordistillatefueloilno.2.

VOCEmissions2

Total



141801.0078


TableN‐25.Utilities‐Heaters

Value Unit

3.05 MMBtu/hr

8,760 hr/yr

1,020 Btu/scf

26.18 MMscf/yr

6

NOX 50.00 lb/MMscf 1 1.49E‐01 6.5E‐01 3.9

CO 84.00 lb/MMscf 1 2.51E‐01 1.1 6.6

PM 7.60 lb/MMscf 1 2.27E‐02 9.9E‐02 6.0E‐01

PM10 7.60 lb/MMscf 1 2.27E‐02 9.9E‐02 6.0E‐01

PM2.5 7.60 lb/MMscf 1 2.27E‐02 9.9E‐02 6.0E‐01

SO2 0.60 lb/MMscf 1 1.79E‐03 7.9E‐03 4.7E‐02

VOC 5.50 lb/MMscf 1 1.64E‐02 7.2E‐02 4.3E‐01

H2SO4 6.50E‐03 lb/MMscf 2 1.94E‐05 8.5E‐05 5.1E‐04

NumberofHeaters:

Parameter


HeaterSize:

OperatingHours:

NaturalGasHeatingValue(HHV):

AnnualGasUsage:


Units Reference

HourlyEmissionsperHeater(lb/hr)

AnnualEmissionsperHeater(tpy)

AnnualEmissionsforAllHeaters

(tpy)

PollutantNaturalGas

EmissionFactor


141801.0078


TableN‐26.Utilities‐HeatersParameter Value UnitHeaterSize: 3.05 MMBtu/hr

NumberofHeaters: 6HoursofOperation: 8,760 hr/yr

NaturalGasHeatingValue(HHV): 1,020 Btu/scf

lb/hr tpy lb/hr tpy

2‐Methylnaphthalene 2.40E‐05 lb/MMscf 7.2E‐08 3.1E‐07 4.3E‐07 1.9E‐063‐Methylchloranthrene 1.80E‐06 lb/MMscf 5.4E‐09 2.4E‐08 3.2E‐08 1.4E‐07

7,12‐Dimethylbenz(a)anthracene 1.60E‐05 lb/MMscf 4.8E‐08 2.1E‐07 2.9E‐07 1.3E‐06Acenaphthene 1.80E‐06 lb/MMscf 5.4E‐09 2.4E‐08 3.2E‐08 1.4E‐07Acenaphthylene 1.80E‐06 lb/MMscf 5.4E‐09 2.4E‐08 3.2E‐08 1.4E‐07Anthracene 2.40E‐06 lb/MMscf 7.2E‐09 3.1E‐08 4.3E‐08 1.9E‐07

Benz(a)anthracene 1.80E‐06 lb/MMscf 5.4E‐09 2.4E‐08 3.2E‐08 1.4E‐07Benzene 2.10E‐03 lb/MMscf 6.3E‐06 2.7E‐05 3.8E‐05 1.6E‐04

Benzo(a)pyrene 1.20E‐06 lb/MMscf 3.6E‐09 1.6E‐08 2.2E‐08 9.4E‐08Benzo(b)fluoranthene 1.80E‐06 lb/MMscf 5.4E‐09 2.4E‐08 3.2E‐08 1.4E‐07Benzo(g,h,i)perylene 1.20E‐06 lb/MMscf 3.6E‐09 1.6E‐08 2.2E‐08 9.4E‐08Benzo(k)fluoranthene 1.80E‐06 lb/MMscf 5.4E‐09 2.4E‐08 3.2E‐08 1.4E‐07

Chrysene 1.80E‐06 lb/MMscf 5.4E‐09 2.4E‐08 3.2E‐08 1.4E‐07Dibenzo(a,h)anthracene 1.20E‐06 lb/MMscf 3.6E‐09 1.6E‐08 2.2E‐08 9.4E‐08

Dichlorobenzene 1.20E‐03 lb/MMscf 3.6E‐06 1.6E‐05 2.2E‐05 9.4E‐05Fluoranthene 3.00E‐06 lb/MMscf 9.0E‐09 3.9E‐08 5.4E‐08 2.4E‐07Fluorene 2.80E‐06 lb/MMscf 8.4E‐09 3.7E‐08 5.0E‐08 2.2E‐07

Formaldehyde 7.50E‐02 lb/MMscf 2.2E‐04 9.8E‐04 1.3E‐03 5.9E‐03Hexane 1.80E+00 lb/MMscf 5.4E‐03 2.4E‐02 3.2E‐02 1.4E‐01

Indeno(1,2,3‐cd)pyrene 1.80E‐06 lb/MMscf 5.4E‐09 2.4E‐08 3.2E‐08 1.4E‐07Naphthalene 6.10E‐04 lb/MMscf 1.8E‐06 8.0E‐06 1.1E‐05 4.8E‐05Phenanathrene 1.70E‐05 lb/MMscf 5.1E‐08 2.2E‐07 3.0E‐07 1.3E‐06

Pyrene 5.00E‐06 lb/MMscf 1.5E‐08 6.5E‐08 9.0E‐08 3.9E‐07Toulene 3.40E‐03 lb/MMscf 1.0E‐05 4.5E‐05 6.1E‐05 2.7E‐04Arsenic 2.00E‐04 lb/MMscf 6.0E‐07 2.6E‐06 3.6E‐06 1.6E‐05Beryllium 1.20E‐05 lb/MMscf 3.6E‐08 1.6E‐07 2.2E‐07 9.4E‐07Cadmium 1.10E‐03 lb/MMscf 3.3E‐06 1.4E‐05 2.0E‐05 8.6E‐05Chromium 1.40E‐03 lb/MMscf 4.2E‐06 1.8E‐05 2.5E‐05 1.1E‐04Cobalt 8.40E‐05 lb/MMscf 2.5E‐07 1.1E‐06 1.5E‐06 6.6E‐06Lead 5.00E‐04 lb/MMscf 1.5E‐06 6.5E‐06 9.0E‐06 3.9E‐05

Manganese 3.80E‐04 lb/MMscf 1.1E‐06 5.0E‐06 6.8E‐06 3.0E‐05Mercury 2.60E‐04 lb/MMscf 7.8E‐07 3.4E‐06 4.7E‐06 2.0E‐05Nickel 2.10E‐03 lb/MMscf 6.3E‐06 2.7E‐05 3.8E‐05 1.6E‐04

Selenium 2.40E‐05 lb/MMscf 7.2E‐08 3.1E‐07 4.3E‐07 1.9E‐06TotalHAP 5.6E‐03 2.5E‐02 3.4E‐02 1.5E‐01


PollutantNaturalGasEmissionFactor1

Units

EmissionsperHeaterEmissionsforAll

Heaters


141801.0078


TableN‐27.CoolingTower/BoilerFeedwater/WastewaterPretreatmentEmissions

Material Projected Usage (kg /year) Volatile Content Potential VOC emissions Potential HAP emissions(tpy) (tpy)

Nalco 3DT 265 49,932 0% 0.0 --Nalco 7320 112,347 10% 12.4 --Nalco 7330 57,921 1% 5.1E-01 --

Nalco Stabrex ST70 500 0% 0.0 --

Nalco Nexguard 22310 17,100 0% 0.0 --Nalco 1720 4,100 0% 0.0 --Nalco 1820 280 40% 1.2E-01 --

Sodium hypochlorite 4,380 N/A 4.0E-03 4.0E-0313.0 4.0E-03

Cooling Tower Water

Boiler Feedwater

Recycle Water Disinfection

Total


141801.0078


TableN‐28.Utilities‐InkUsage‐Emissions

AnnualInkUsage1 VOCContent2 AnnualInkUsage1 VOCContent2 HAPContent3

(lb/yr) (%) (lb/yr) (%) (%) (lb/hr) (tpy) (lb/hr) (tpy)SoapMakingBusinessA&B 0 35 1,000 16 16 1.8E‐02 8.0E‐02 1.8E‐02 8.0E‐02DryConsumerProductsA 1,100 35 1,000 16 16 6.2E‐02 2.7E‐01 1.8E‐02 8.0E‐02Customization 330 16 ‐‐ ‐‐ ‐‐ 6.0E‐03 2.6E‐02 ‐‐ ‐‐Total 0.09 0.38 0.04 0.16

3.AssumesallVOCinthecodedaterinkisHAP.HAPisaglycolether.

VOCEmissions2 HAPEmissions3


2.Conservativelyassumedthattheinkcompositionis100%VOCandthatallinkislosttotheatmosphereduringusage.

BusinessUnit

CasePrintingInk CodeDaterInk


141801.0078


TableN‐29.FinishedProductPackingEmissionsfromHotMeltGlue

AnnualGlueUsage1 VOCEmissionFactor HAPEmissionFactor(lb/year) (lb/lb) (lb/lb) (lb/hr) (tpy) (lb/hr) (tpy)

Soap Making Business A&B 438,000 3.0E‐02 1.3E‐01 1.0E‐03 4.4E‐03DryConsumerProductsA 250,080 1.7E‐02 7.5E‐02 5.7E‐04 2.5E‐03

Customization 2,000 1.4E‐04 6.0E‐04 4.6E‐06 2.0E‐054.7E‐02 2.1E‐01 1.6E‐03 6.9E‐03


2.ConservativelyassumedthatalloftheVOCinthehotmeltglueisvinylacetate.

BusinessUnitVOCEmissions HAPEmissions2

6.00E‐04 2.00E‐05

Total:


141801.0078


TableN‐30.Utilities‐RoadParameter Value UnitIndustrialaugmentationfactor 1 dimensionlessNumberoftrafficlanes 2Surfacematerialsiltcontent1 3.3% %Surfacedustloading 125 lb/mile

DescriptionAverage Weight2 MilesperTrip2

MaximumTripsperHour

Maximum Trips per

Year(tons)

DeliveryTrucks 40 0.0417 30.8 365EmployeeVehicles 2 0.0417 0.5 365

(lb/hr) (tpy)DeliveryTrucks 5.0E‐04 2.2E‐03EmployeeVehicles 1.0E‐06 4.4E‐06

TOTAL 5.0E‐04 2.2E‐03

3.FromEmissionFactorDocumentationforAP‐42Section13.2.1, PavedRoads, Equation2‐2,assitedinWVDEPR‐13PermitFormAttachmentLforHaulRoads

PollutantUncontrolledTSPEmissions3


1.ConservativelyassumedtobeequaltoaveragefactorforAsphaltBatching,AP‐42Section13.2.1 PavedRoads ,Table13.2.1‐3


141801.0078


TableN‐31.PlasticsMoldingSupplier‐EmissionsSummary

PM PM10 PM2.5 VOC HAPs NOX CO SO2 H2SO4RailCarUnloading 3.50E‐01 3.50E‐01 3.50E‐01 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐StorageSilos 3.50 3.50 3.50 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐PlasticRegrind 1.68E‐01 1.68E‐01 1.68E‐01 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐FugitiveVOCEmissions ‐‐ ‐‐ ‐‐ 9.07 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐SpaceHeaters 5.55E‐01 5.55E‐01 5.55E‐01 4.02E‐01 1.30E‐01 3.65 6.13 4.38E‐02 4.75E‐04CoolingTower 1.23 1.23 1.23 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐Back‐UpGenerator 4.75E‐04 9.71E‐04 9.71E‐04 5.02E‐02 1.62E‐03 1.04E‐01 2.08E‐01 2.94E‐05 ‐‐

ProcessTotal 5.80 5.80 5.80 9.52 1.32E‐01 3.75 6.34 4.38E‐02 4.75E‐04

ActivityAnnualEmissions(tpy)


141801.0078


EmissionFactors1

(lb/tonmaterial)

PM 7.00E‐02PM10 7.00E‐02PM2.5 7.00E‐02

(ton/yr) % (lb/hr) (tpy) (lb/hr) (tpy) (lb/hr) (tpy) (lb/hr) (tpy) (lb/hr) (tpy) (lb/hr) (tpy)21C RailcarUnload122C RailcarUnload223C RailcarUnload324C RailcarUnload425C RailcarUnload5

3.50 3.50 3.50 0.35 0.35 0.351.ConservativeProcterandGambleapproximation.Accountsforfiveunloadingpointsforrailcarswhichcanfeedanyof24storagesilos.

TOTAL

PM10 PM2.5

ControlEfficiencyControlDevice

Number

100,000 90% 0.80 3.50 0.80 3.50 0.80 3.50

TableN‐32.PlasticsMoldingSupplier‐RailcarUnloadingtoSilo‐EmissionFactors

TableN‐33.PlasticsMoldingSupplier‐RailcarUnloadingtoSilo‐Emissions

EmissionDescription

1.EstimatedusingaveragedustingfactorforalltypesofpelletstorageidentifiedbyEPA.ConservativelyassumesPM=PM10=PM2.5.

Operation

UnloadThroughput1

ControlledEmissionsPM PM10 PM2.5

UncontrolledEmissionsPM

0.357.99E‐02 0.35 7.99E‐02 0.35 7.99E‐02


141801.0078


EmissionFactors1

(lb/tonmaterial)

PM 7.00E‐02PM10 7.00E‐02PM2.5 7.00E‐02

(ton/yr) % (lb/hr) (tpy) (lb/hr) (tpy) (lb/hr) (tpy)222S PelletStorage1223S PelletStorage2224S PelletStorage3225S PelletStorage4226S PelletStorage5227S PelletStorage6228S PelletStorage7229S PelletStorage8230S PelletStorage9231S PelletStorage10232S PelletStorage11233S PelletStorage12234S PelletStorage13235S PelletStorage14236S PelletStorage15237S PelletStorage16238S PelletStorage17239S PelletStorage18240S PelletStorage19241S PelletStorage20242S PelletStorage21243S PelletStorage22244S PelletStorage23245S PelletStorage24

3.5 3.5 3.51.ConservativeProcterandGambleapproximation.Storagesilosmaybefedfromanyoffiverailcarunloadingpoints.

TOTAL

PM PM10 PM2.5

100,000 0% 7.99E‐01 3.50 7.99E‐01 3.50 7.99E‐01 3.50

TableN‐34.PlasticsMoldingSupplier‐SiloStorage‐EmissionFactors

EmissionDescription

1.EstimatedusingaveragedustingfactorforalltypesofpelletstorageidentifiedbyEPA.ConservativelyassumesPM=PM10=PM2.5.

TableN‐35.PlasticsMoldingSupplier‐SiloStorage‐Emissions

EmissionUnit Operation

UnloadThroughput1

ControlEfficiency

UncontrolledEmissions


141801.0078


EmissionFactors1

(lb/tonmaterial)

PM 2.10E‐01PM10 2.10E‐01PM2.5 2.10E‐01

(ton/yr) % (lb/hr) (tpy) (lb/hr) (tpy) (lb/hr) (tpy) (lb/hr) (tpy) (lb/hr) (tpy) (lb/hr) (tpy)246 PlasticRegrind 32,000 95% 0.77 3.36 0.77 3.36 0.77 3.36 3.84E‐02 1.68E‐01 3.84E‐02 1.68E‐01 3.84E‐02 1.68E‐01

3.36 3.36 3.36 1.68E‐01 1.68E‐01 1.68E‐011.ConservativeProcterandGambleapproximationof32%oftotalplasticthroughput.

TOTAL

ControlledEmissionsPM PM10 PM2.5 PM PM10 PM2.5

TableN‐36.PlasticsMoldingSupplier‐PlasticRegrind‐EmissionFactors

EmissionDescription

1.EstimatedusingaveragedustingfactorforalltypesofpelletstorageidentifiedbyEPA,multipliedby3xtoaccountforregrindprocess.ConservativelyassumesPM=PM10=PM2.5.

TableN‐37.PlasticsMoldingSupplier‐PlasticRegrind‐Emissions

EmissionUnit OperationThroughput1

ControlEfficiency


CONFIDENTIAL Page 37 of 42Trinity Consultants

141801.0078


VOCEmissionFactors(lb/tonmaterial)

Forming1 0.0614

IsopropylAlcohol2 2000PartsWashing

CleaningSolvent2 2000

(ton/yr) (lb/hr) (tpy)247S Forming 100,000 0.70 3.07248S PartsWashing/ProcessCleaning 6 1.37 6.00

TOTAL 2.07 9.071.ConservativeProcterandGambleapproximation.

TableN‐38.PlasticsMoldingSupplier‐Cleaning‐EmissionFactorsEmissionDescription

2.Assumes100%lossrate.

TableN‐39.PlasticsMoldingSupplier‐Cleaning‐Emissions

EmissionUnit OperationUnloadThroughput1


VOC

1.MichiganDepartmentofEnvironmentalQuality,"PlasticsProductionandProductsManufacturing"factsheet,emissionfactorformoldingmachine.


141801.0078


TableN‐40.Utilities‐PMSHeaters‐Parameters

Value249S SpaceHeater1 5250S SpaceHeater2 5251S SpaceHeater3 2.5252S SpaceHeater4 2.5253S SpaceHeater5 1254S SpaceHeater6 1

171468,7601,020

TableN‐41.Utilities‐PMSHeaters‐CriteriaEmissions

NOX 50 lb/MMscf 1 0.83 3.65

CO 84.00 lb/MMscf 1 1.40 6.13

PM 7.60 lb/MMscf 1 1.27E‐01 5.55E‐01

PM10 7.60 lb/MMscf 1 1.27E‐01 5.55E‐01

PM2.5 7.60 lb/MMscf 1 1.27E‐01 5.55E‐01

SO2 0.60 lb/MMscf 1 1.00E‐02 4.38E‐02

VOC 5.50 lb/MMscf 1 9.17E‐02 4.02E‐01

H2SO4 6.50E‐03 lb/MMscf 2 1.08E‐04 4.75E‐04

EquivalentGasHours: Hoursat100%LoadNaturalGasHeatingValue(HHV):

Parameter Unit

TotalHeatInput: MMBtu/hrAnnualGasUsage: MMscf/yr

MMBtu/hrMMBtu/hrMMBtu/hrMMBtu/hrMMBtu/hrMMBtu/hr

Btu/scf


2.Naturalgasfactorcalculatedassuming1%ofsulfurbecomesH2SO4.FueloilemissionfactorfromEmergencyPlanningandCommunityRight‐To‐KnowAct,EPCRA‐Section313:GuidanceforReportingSulfuricAcid(acidaerosolsincludingmists,vapors,gas,fog,andotherairborneformsofanyparticlesize).(March1998)EPA‐745‐R‐97‐007.

PollutantNaturalGas

EmissionFactorUnits Reference

NaturalGasHourly

Emissions(lb/hr)

NaturalGasAnnual

Emissions(tpy)


141801.0078


TableN‐42.Utilities‐PMSHeaters‐ParametersValue Unit17 MMBtu/hr


TableN‐43.Utilities‐PMSHeaters‐HAPEmissions

lb/hr tpy

2‐Methylnaphthalene 2.4E‐05 lb/MMscf 4.00E‐07 1.65E‐063‐Methylchloranthrene 1.8E‐06 lb/MMscf 3.00E‐08 1.24E‐07

7,12‐Dimethylbenz(a)anthracene 1.6E‐05 lb/MMscf 2.67E‐07 1.10E‐06Acenaphthene 1.8E‐06 lb/MMscf 3.00E‐08 1.24E‐07Acenaphthylene 1.8E‐06 lb/MMscf 3.00E‐08 1.24E‐07Anthracene 2.4E‐06 lb/MMscf 4.00E‐08 1.65E‐07

Benz(a)anthracene 1.8E‐06 lb/MMscf 3.00E‐08 1.24E‐07Benzene 2.1E‐03 lb/MMscf 3.50E‐05 1.45E‐04

Benzo(a)pyrene 1.2E‐06 lb/MMscf 2.00E‐08 8.26E‐08Benzo(b)fluoranthene 1.8E‐06 lb/MMscf 3.00E‐08 1.24E‐07Benzo(g,h,i)perylene 1.2E‐06 lb/MMscf 2.00E‐08 8.26E‐08Benzo(k)fluoranthene 1.8E‐06 lb/MMscf 3.00E‐08 1.24E‐07

Chrysene 1.8E‐06 lb/MMscf 3.00E‐08 1.24E‐07Dibenzo(a,h)anthracene 1.2E‐06 lb/MMscf 2.00E‐08 8.26E‐08

Dichlorobenzene 1.2E‐03 lb/MMscf 2.00E‐05 8.26E‐05Fluoranthene 3.0E‐06 lb/MMscf 5.00E‐08 2.07E‐07Fluorene 2.8E‐06 lb/MMscf 4.67E‐08 1.93E‐07

Formaldehyde 7.5E‐02 lb/MMscf 1.25E‐03 5.16E‐03Hexane 1.8E+00 lb/MMscf 3.00E‐02 1.24E‐01

Indeno(1,2,3‐cd)pyrene 1.8E‐06 lb/MMscf 3.00E‐08 1.24E‐07Naphthalene 6.1E‐04 lb/MMscf 1.02E‐05 4.20E‐05Phenanathrene 1.7E‐05 lb/MMscf 2.83E‐07 1.17E‐06

Pyrene 5.0E‐06 lb/MMscf 8.33E‐08 3.44E‐07Toulene 3.4E‐03 lb/MMscf 5.67E‐05 2.34E‐04Arsenic 2.0E‐04 lb/MMscf 3.33E‐06 1.38E‐05Beryllium 1.2E‐05 lb/MMscf 2.00E‐07 8.26E‐07Cadmium 1.1E‐03 lb/MMscf 1.83E‐05 7.57E‐05Chromium 1.4E‐03 lb/MMscf 2.33E‐05 9.64E‐05Cobalt 8.4E‐05 lb/MMscf 1.40E‐06 5.78E‐06Lead 5.0E‐04 lb/MMscf 8.33E‐06 3.44E‐05

Manganese 3.8E‐04 lb/MMscf 6.33E‐06 2.62E‐05Mercury 2.6E‐04 lb/MMscf 4.33E‐06 1.79E‐05Nickel 2.1E‐03 lb/MMscf 3.50E‐05 1.45E‐04

Selenium 2.40E‐05 lb/MMscf 4.00E‐07 1.65E‐06TotalHAP 3.15E‐02 1.30E‐01

ParameterHeatInput:


EmissionsperHeater


PollutantNaturalGas

EmissionFactor1Units


141801.0078


TableN‐44.Utilities‐PMSCoolingTower‐Emissions

Parameter Value

EmissionUnit 255S

Location1 BBS

FlowRate(gpm) 7,000

OperatingHours(hr/yr) 8,760

DensityofWater(lb/gal) 8.35

TotalDissolvedSolids,TDS(ppm) 1,600

Drift(%)2 5.00E‐03

Drift(gpm) 0.35

PM/PM10/PM2.5(lb/gal)3 6.68E‐07

PM/PM10/PM2.5(lb/hr) 2.80E‐01

PM/PM10/PM2.5(tpy) 1.23


2.DriftPercentageforInducedDraftCoolerspecifiedinemailfromBrianMensinger(TrinityConsultants)toAllisonCole(TrinityConsultants)onJuly22,2015.3.PM10areconservativelyoverestimatedby(TDS,ppm)x(TotalDriftRate,

lb/gal)/106,basedonAP‐42Section13.4‐3.


141801.0078


TableN‐45.PlasticsMolding‐Back‐UpGenerator

SourceDesignation: Engine Generator

EmissionUnit: 256S ‐‐

Manufacturer:1 ‐‐ Generac

StrokeCycle: 4‐stroke ‐‐

TypeofBurn:1 Rich ‐‐

FuelUsed: NaturalGas ‐‐

HigherHeatingValue(HHV)(Btu/scf): 1,020 ‐‐

PowerGenerated@2,300rpm(KW) ‐‐ 70

MaximumFuelConsumptionat100%Load(scf/hr):1 196 ‐‐

HeatInput(HHV)(MMBtu/hr):1 0.20 ‐‐

EmissionControls: None ‐‐

OperationalDetail Value

PotentialAnnualHoursofOperation(hr/yr): 500

PotentialFuelConsumption(MMscf/yr): 0.10

Pollutant EmissionFactors Units

NOX1 2.70 g/kw‐hr

CO1 5.40 g/kw‐hr

SO22 5.88E‐04 lb/MMBtu

PM(filterableonly)2 9.50E‐03 lb/MMBtu

PM10(filterable+condensable)2 1.94E‐02 lb/MMBtu

PM2.5(filterable+condensable)2 1.94E‐02 lb/MMBtu

VOC1 1.30 g/kw‐hr

Pollutant (lb/hr)3 (tpy)4

NOx 4.17E‐01 1.04E‐01

CO 8.33E‐01 2.08E‐01

SO2 1.18E‐04 2.94E‐05

PM 1.90E‐03 4.75E‐04

PM10 3.88E‐03 9.71E‐04

PM2.5 3.88E‐03 9.71E‐04

VOC 2.01E‐01 5.02E‐02

TableN‐45.PlasticsMolding‐Back‐UpGenerator

EmissionFactor

Pollutant (lb/MMBtu)2 (lb/hr)3 (tpy)4

Acetaldehyde 2.79E‐03 5.58E‐04 1.40E‐04

Acrolein 2.63E‐03 5.26E‐04 1.32E‐04

Benzene 1.58E‐03 3.16E‐04 7.90E‐05

1,3‐Butadiene 6.63E‐04 1.33E‐04 3.32E‐05

CarbonTetrachloride 1.77E‐05 3.54E‐06 8.85E‐07

Chlorobenzene 1.29E‐05 2.58E‐06 6.45E‐07

Chloroform 1.37E‐05 2.74E‐06 6.85E‐07

1,3‐Dichloropropene 1.27E‐05 2.54E‐06 6.35E‐07

Ethylbenzene 2.48E‐05 4.96E‐06 1.24E‐06

EthyleneDibromide 2.13E‐05 4.26E‐06 1.07E‐06

Formaldehyde 2.05E‐02 4.10E‐03 1.03E‐03

Methanol 3.06E‐03 6.12E‐04 1.53E‐04

MethyleneChloride 4.12E‐05 8.24E‐06 2.06E‐06

Naphthalene 9.71E‐05 1.94E‐05 4.86E‐06

PAH 1.41E‐04 2.82E‐05 7.05E‐06

Styrene 1.19E‐05 2.38E‐06 5.95E‐07

Toluene 5.58E‐04 1.12E‐04 2.79E‐05

1,1,2,2‐Tetrachloroethane 2.53E‐05 5.06E‐06 1.27E‐06

1,1,2‐Trichloroethane 1.53E‐05 3.06E‐06 7.65E‐07

VinylChloride 7.18E‐06 1.44E‐06 3.59E‐07

Xylenes 1.95E‐04 3.90E‐05 9.75E‐06

TotalHAP 6.48E‐03 1.62E‐03

1 EmissionfactorsfromCertificateofConformityGGNXB06.82C1‐043.Factorsfrom40CFR60,SubpartJJJJ,Table1.2

3

4 AnnualEmissions(tons/yr)=EmissionRate(lb/hr)×(MaximumAllowableOperatingHours,500hr/yr)×(1ton/2000lb).

EmissionRate(lb/hr)=RatedCapacity(MMBtu/hr)×EmissionFactor(lb/MMBtu)EmissionRate(lb/hr)=EmissionFactor(g/kw‐hr)*Capacity(KW)*ConversionFactor(lb/g)

PotentialEmissions

PotentialEmissions

EmissionfactorsfromAP‐42Section3.2,Table3.2‐3"UncontrolledEmissionFactorsfor4‐stroke,Rich‐burnEngines,"SupplementF,August2000.


141801.0078


ATTACHMENT O

Monitoring/Recordkeeping/Reporting/Testing Plans

Attachment OTabler Station

PlanTypeEmissionunit

Pollutant Requirements FrequencyMethodof

MeasurementRegulatoryReference

TBD 1C SO2/H2SO4 MonitorpH Hourly TBD TBD

TBD 2C SO2/H2SO4 MonitorpH Hourly TBD TBD

TBD 3C PM/PM10/PM2.5 Monitorpressuredrop Weekly TBD TBD







TBD 10 PM/PM10/PM2.5 Monitorpressuredrop Weekly TBD TBD




TBD 14C AllPollutantsInitialComplianceDemonstration

TBD TBD TBD

TBD 14C HAP/VOCMonitorinternaltemperature

Hourly TBD TBD

TBD 14C HAP/VOCOperateRTOwhenLiquid

SoapAHotMixTankisbeingused.1

TBD TBD TBD













TBD 256S AllPollutants Non‐ResettableHourMeter Monthly TBD NSPSJJJJ

TBD 249S‐254S AllPollutants FuelUsage Monthly TBD TBDTBD 1S‐2S Dioxane Maintainrecords Monthly TBD NSPSVVa

TBD 196S‐199S AllPollutantsFuelRecords,including%

SulfurMonthly TBD NSPSDc

TBD 203S‐207S AllPollutantsFuelRecords,including%

SulfurMonthly TBD NSPSIIII

TBD 203S‐207S AllPollutants Non‐ResettableHourMeter Monthly TBD NSPSIIII

TBD 210S‐215S AllPollutants FuelUsage Monthly TBD TBD

AttachmentOMONITORING,RECORDKEEPING,REPORTING,ANDTESTINGPLANS

Monitoring,Recordkeeping,ReportingandTestingPlans.Attachproposedmonitoring,recordkeeping,reportingandtestingplansinordertodemonstratecompliancewiththeproposedemissionslimitsandoperatingparametersinthispermitapplication.ProvidethisinformationasAttachmentO.

*Pleasebeawarethatallpermitsmustbepracticallyenforceablewhetherornottheapplicantchoosestoproposesuchmeasures.Additionally,theDAQmaynotbeabletoacceptallmeasuresproposedbytheapplicant.Ifnoneoftheseplansareproposedbytheapplicant,DAQwilldevelopsuchplansandincludetheminthepermit.

1.Assumes24hours(per12‐monthrollingperiod)ofuncontrolledoperation.


141801.0078

r13 permit applicationdep.wv.gov/daq/documents/october 2016 applications/003-00154_appl_13... ·...

Documents