references - cds.cern.ch · references 775 32. w. götze, j. phys. condens. matter 11, a1–a45...

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References 1. R. Brown, Edinb. Phil. J. 5, 358 (1828); Philos. Mag. 4, 161 (1828); See also A. Fick, Poggendorff’s Annalen 94, 59 (1855), and (in English) Philos. Mag. S.4, 10, 30–39 (1855). 2. R. Kohlrausch, Theorie des elektrischen Rückstandes in der Leidener Flasche; von R. Kohlrausch, Pogg. Ann. Phys. Chem. 91, 179–214 (1854). For experimental data, see R. Kohlrausch, Pogg. Ann. Phys. Chem. 91, 56 (1854). 3. F. Kohlrausch, Ueber die elastische Nachwirkung bei der Torsion, Pogg. Ann. Phys. Chem. 119, 337–368 (1863). Beiträge zur Kenntniss der elastischen Nachwirkung, Pogg. Ann. Phys. Chem.128, 1–20, 207–228, 399–419 (1866). 4. F. Kohlrausch, Beiträge zur Kenntniss der elastischen Nachwirkung, Pogg. Ann. Phys. Chem. 128, 1–20, 207–228, 399–419 (1866). 5. J.C. Maxwell, Philos. Trans. R. Soc. (London) 157, 49 (1867). 6. J.P. Joule, Mem. Manchr Literary Philos. Soc., 3rd ser., 3, 292 (1867); The Scientific Papers of J. P. Joule, Vol. 1, Physical Society, London, p. 558 (1884). 7. S.V. Nemilov, G.P. Johari, Philos. Mag. 83, 3117 (2003). 8. A. Einstein, Investigations on the Theory of Brownian Movement, Dover, New York, NY (1956). 9. J. Stachel, Ed., The Collected Papers of Albert Einstein, Vol. 2, pp. 170–182, 206–222, Princeton University Press (1987). 10. G.G. Stokes, On the Effect of the Internal Friction of Fluid on the Motion of Pendulums, Proc. Camb. Philos. Soc. 9, 8–106 (1851). 11. A. Einstein, Ann. d. Physik 17, 549 (1905). 12. J. Perrin, Le Mouvement Brownien et la Réalité Moleculaire, Ann. Chim. Phys. (8 me Serie), 5–114 (1909); J. Phys. Radium 5, 497 (1934); Atoms, Constable, London (1916). See also R. Newburgh, J. Peidle, W. Rueckner, Einstein, Perrin, and the Reality of Atoms:1905 Revisited, Am. J. Phys. 74, 478 (2006). 13. M.V. Smoluchowski, Ann. d. Physik. 21, 756 (1906). 14. P. Langevin, Sur la Theorie du Mouvement Brownien, C. R. Acad. Sci. (Paris) 146, 530 (1908). In English, Am. J. Phys. 65(11), 1079 (1997). 15. R. Kubo, M. Toda, N. Hashitsumi, Statistical Physics II, Nonequilibrium Statistical Mechanics, Springer, Berlin (1985). 16. F. Perrin, J. Phys. Radium 5, 497 (1934). 17. A. Einstein, Ann. d. Physik 19, 371 (1906). 18. P. Debye, Physik. Z. 13n, 97 (1912). 19. P. Debye, Ber. Deut. Phys. Ges. 55, 777 (1913). 20. P. Debye, Polar Molecules, Dover, New York, NY (1929). 21. S. Chandrasekhar, Rev. Modern Phys. 15, 1 (1943). 22. J.K.G. Dhont, An Introduction to Dynamics of Colloids, Elsevier, Amsterdam (1996). 23. B.J. Berne, R. Percora, Dynamic Light Scattering, Wiley, New York, NY (1976). 773 K.L. Ngai, Relaxation and Diffusion in Complex Systems, Partially Ordered Systems, DOI 10.1007/978-1-4419-7649-9, C Springer Science+Business Media, LLC 2011

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Page 1: References - cds.cern.ch · References 775 32. W. Götze, J. Phys. Condens. Matter 11, A1–A45 (1999); W. Götze, Complex Dynamics of Glass-Forming Liquids, International Series

References

1. R. Brown, Edinb. Phil. J. 5, 358 (1828); Philos. Mag. 4, 161 (1828); See also A. Fick,Poggendorff’s Annalen 94, 59 (1855), and (in English) Philos. Mag. S.4, 10, 30–39(1855).

2. R. Kohlrausch, Theorie des elektrischen Rückstandes in der Leidener Flasche; vonR. Kohlrausch, Pogg. Ann. Phys. Chem. 91, 179–214 (1854). For experimental data,see R. Kohlrausch, Pogg. Ann. Phys. Chem. 91, 56 (1854).

3. F. Kohlrausch, Ueber die elastische Nachwirkung bei der Torsion, Pogg. Ann. Phys. Chem.119, 337–368 (1863). Beiträge zur Kenntniss der elastischen Nachwirkung, Pogg. Ann.Phys. Chem.128, 1–20, 207–228, 399–419 (1866).

4. F. Kohlrausch, Beiträge zur Kenntniss der elastischen Nachwirkung, Pogg. Ann. Phys.Chem. 128, 1–20, 207–228, 399–419 (1866).

5. J.C. Maxwell, Philos. Trans. R. Soc. (London) 157, 49 (1867).6. J.P. Joule, Mem. Manchr Literary Philos. Soc., 3rd ser., 3, 292 (1867); The Scientific Papers

of J. P. Joule, Vol. 1, Physical Society, London, p. 558 (1884).7. S.V. Nemilov, G.P. Johari, Philos. Mag. 83, 3117 (2003).8. A. Einstein, Investigations on the Theory of Brownian Movement, Dover, New York, NY

(1956).9. J. Stachel, Ed., The Collected Papers of Albert Einstein, Vol. 2, pp. 170–182, 206–222,

Princeton University Press (1987).10. G.G. Stokes, On the Effect of the Internal Friction of Fluid on the Motion of Pendulums,

Proc. Camb. Philos. Soc. 9, 8–106 (1851).11. A. Einstein, Ann. d. Physik 17, 549 (1905).12. J. Perrin, Le Mouvement Brownien et la Réalité Moleculaire, Ann. Chim. Phys. (8me Serie),

5–114 (1909); J. Phys. Radium 5, 497 (1934); Atoms, Constable, London (1916). See alsoR. Newburgh, J. Peidle, W. Rueckner, Einstein, Perrin, and the Reality of Atoms:1905Revisited, Am. J. Phys. 74, 478 (2006).

13. M.V. Smoluchowski, Ann. d. Physik. 21, 756 (1906).14. P. Langevin, Sur la Theorie du Mouvement Brownien, C. R. Acad. Sci. (Paris) 146, 530

(1908). In English, Am. J. Phys. 65(11), 1079 (1997).15. R. Kubo, M. Toda, N. Hashitsumi, Statistical Physics II, Nonequilibrium Statistical

Mechanics, Springer, Berlin (1985).16. F. Perrin, J. Phys. Radium 5, 497 (1934).17. A. Einstein, Ann. d. Physik 19, 371 (1906).18. P. Debye, Physik. Z. 13n, 97 (1912).19. P. Debye, Ber. Deut. Phys. Ges. 55, 777 (1913).20. P. Debye, Polar Molecules, Dover, New York, NY (1929).21. S. Chandrasekhar, Rev. Modern Phys. 15, 1 (1943).22. J.K.G. Dhont, An Introduction to Dynamics of Colloids, Elsevier, Amsterdam (1996).23. B.J. Berne, R. Percora, Dynamic Light Scattering, Wiley, New York, NY (1976).

773K.L. Ngai, Relaxation and Diffusion in Complex Systems, Partially Ordered Systems,DOI 10.1007/978-1-4419-7649-9, C© Springer Science+Business Media, LLC 2011

Page 2: References - cds.cern.ch · References 775 32. W. Götze, J. Phys. Condens. Matter 11, A1–A45 (1999); W. Götze, Complex Dynamics of Glass-Forming Liquids, International Series

774 References

24. K. Chang, The Nature of Glass Remains Anything but Clear (The New York Times,July 29, 2008). See a technical response to this New York Times article entitled The Natureof Glass: Somethings are Clear, by K.L. Ngai, S. Capaccioli, D. Prevosto, M. Paluch,published in Metastable Systems under Pressure, NATO Science for Peace and SecuritySeries-A: Chemistry and Biology, S. Rzoska, A. Drozd-Rzoska, V. Mazur, Eds., Springer,pp. 3–30 (2010).

25. (a) P.W. Anderson, Through the Glass Lightly, Science 267, 1616 (1995); (b) R.G. Palmer,D.L. Stein, E. Abrahams, P.W. Anderson, Phys. Rev. Lett. 53, 958 (1984); (c) M. Cardona,R.V. Chamberlin, W. Marx Ann. Phys. (Leipzig) 16(12), 842 (2007). These authors assertthat the original paper of Kohlrausch was forgotten until it was cited by Palmer et al. in1984 [25(b)]. They went on to say that unfortunately Palmer et al. [25(b)] did not refer tothe correct 1854 paper by R. Kohlrausch but to a wrong one his published in 1847 [Pogg.Ann. Phys. Chem. 72, 353 (1847)]. Actually I and my coworkers have to share the blamefor incorrectly citing the 1847 paper of Kohlrausch in our 1983 paper [K.L. Ngai et al.,Phys. Rev. B 28, 6073 (1983).]. This paper published one year earlier than Palmer et al.[25(b)], as well as our interaction with Palmer and Stein at the Workshop on Relaxationin Disordered Systems that I organized in 1983, might have misled Palmer et al. to followsuit in citing the wrong 1847 paper of Kohlrausch. Incidentally in their paper [25(b)],Palmer et al. did cite the Proceedings of the 1983 Workshop I organized as well as myfirst publication of the Coupling Model in 1979 [K.L. Ngai, Comment Solid State Phys. 9,127 (1979).].

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Index

AAcetaminophen, 426–427Acetyl salicylic acid, 285, 419, 421–422Adamantanone, 143, 389Adam–Gibbs model, 113, 124–126, 135, 137,

180, 247, 345Adiabatic calorimetry, 91, 134, 141, 287–288,

372, 375, 390, 445–446, 454, 457, 460,462, 464–466, 468, 470, 474, 490,492–494, 496, 501–502, 506, 517, 548,589

AFM probe of the surface layer, 7160.48(AgI)2–0.52Ag2SeO4, 662, 664, 667,

744–745, 7470.525Ag2S+0.475(B2S3:SiS2), 664Ag2S–GeS2, 670–671, 699Aggregating polymers solutions, 762AgI–AgPO3, 670–671, 699Alcohol dehydrogenase, 637Alkyl nanodomains, 62, 108–109, 111–112,

595–601Amino acids, 488, 600Amorphous solid water (ASW), 442, 461Anderson, P. W., 7–8, 10, 42–43, 45, 245Annealing, 209, 281, 297, 312, 399–403, 406,

408, 411, 413–414, 419, 424, 431, 461,597, 635, 711

Anomalies, 41–45, 47, 50–272, 358, 543, 675,698–699, 701, 708–710, 754–758

Anomalous properties, 11–12, 44, 46–47,75–76, 90, 358, 641, 707

Aqueous hyaluronic acid solutions, 675Aqueous mixture at elevated pressure, 369,

437, 618, 625Aqueous mixtures, 41, 277, 315, 368–369, 379,

396, 437, 444, 447–457, 459, 462–464,466–470, 474, 483–484, 487–491,494–495, 497, 502–507, 509–511, 515,

517, 521–522, 562, 613, 618, 625–628,674, 676–678

Aroclor, 71, 123–124, 243, 247, 305Aspirin, 277, 285, 419, 421–423, 577Associating polymers solutions, 194, 657–658,

762Asymmetric double-well potential, 312, 751Atactic PEMA (a-PEMA), 179, 363–364Atactic polypropylene (aPP), 262–263, 563,

691

BBackbone, 55, 62, 108, 144–145, 194, 237,

252, 267, 273, 298, 316, 356, 367, 398,409, 435, 441, 475, 484, 488, 543, 594,609–610, 615, 675, 699, 755

Backscattering spectrometer IN13, 476,513–514

Backscattering spectrometer IN16, 481–482Basalt, 282Bead-necklace model, 283–285, 336, 352Benzonitrile, 167

in PS, 340–343Benzophenone (BZP), 67, 281, 317, 322,

381–382, 387–389, 392, 412, 552,576–580, 584–585

3,3′,4,4′-Benzophenonetetracarboxylicdianhydride (BPTCDaH), 153,333–334

Benzoyn isobutylether (BIBE), 152, 154, 156,167, 276, 326–328, 335, 535–537, 614

Binary mixture, 65–66, 144, 166, 215, 227,232, 296, 335, 341, 344, 370, 376, 396,447–448, 457, 495, 502, 530, 534, 540,603, 614, 625, 627, 641, 723, 740, 743

Biomolecule, 9, 41, 379, 434, 462, 474, 478,481, 484, 488, 506, 508, 512–513, 550,765, 769

823

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824 Index

Biopharmaceutical, 400, 489, 628–629,635–636, 638, 765, 769

1,3-Bis(1-naphthyl)-5-(2-naphthyl)benzene(TNB), 72, 128, 171

Bis(2-ethylhexyl) phthalate, 71, 234Bis-5-hydroxypentylphthalate (BHPP), 62,

299, 400Bisphenol-A-propoxylate(1 PO/phenol)

diglycidylether) (1PODGE), 154, 3351,1′-Bis(p-methoxyphenyl)cyclohexane

(BMPC), 154, 243, 318, 333, 335, 408BKZ theory, 268Boron trioxide (B2O3), 119, 124–125, 128,

136, 172–173, 281, 411, 563, 567–569,573, 656, 659–660, 667, 683, 688, 729,731, 739–740, 743, 745–747, 750–752,754

Bovine serum albumin (BSA), 454–455, 457,492, 494, 498, 502, 517–518, 520

Bovine serum γ-globulin, 633Branched entangled polymers, 692–694Breakdown of Nernst–Einstein relation,

737–739Breakdown of Stokes–Einstein–Debye

relation, 5Breakdown of Stokes–Einstein relation, 100,

221, 271, 413–414, 473, 689, 694–695,737–739

Breakdown of thermorheological simplicity,44, 241, 251–267, 543, 602, 727,754–758

Breathers, 86–87Bromoethylbenzene (BrEBz), 237, 3613-Bromopentane (3BP), 55, 91, 136, 175Brownian motion, 2–3, 39, 68–70, 203, 610,

672Bulk compliance and modulus, 19–20Butylacetate, 382–383Butyl alcohol, 249–250Butyl-benzene, 1721-Butyl-1-methylpyrrolidinium

bis[oxalato]borate (BMP-BOB),161–162

2-Biphenylmethanol, 552, 577BZP, see Benzophenone (BZP)

CCaged dynamics, 66, 70, 105, 116, 202, 510,

526, 550, 552, 555–556, 573, 582,585–586, 597, 599, 634, 638, 644–646,648, 652, 654, 739–754, 769

Cage decay, 202, 550–551, 597, 648, 743, 751Cage fluctuation, 587

Caging, 486, 553, 571, 644, 7540.4Ca(NO3)2–0.6KNO3 (CKN), 68–69, 273,

380, 553, 576, 660, 740–741, 743–747Calorimetric detection of JG relaxation, 54845CaO–55SiO2, 28255CaO–45SiO2, 282Carbohydrate, 9, 41, 294, 420, 434–435Carbon monoxy myoglobin, 479Causality, 345, 531, 611, 768CDE, 141–143, 398Cellopentabiose, 441–442Cellotetrabiose, 441–442Cellotribiose, 441–442Cellulose, 294, 401, 435, 441–443Chalcogenide, 108, 129–132, 144Charge density wave, 759Chlorobenzene in cis-decalin, 396, 612–613CKN, see 0.4Ca(NO3)2–0.6KNO3 (CKN)Classical Chaos, 78, 766CM, see Coupling Model (CM)CODEX NMR, 364Co-invariance of n and (τα/τJG) at constant τα,

327–345Cole–Cole function, 297, 304, 361, 395, 401,

437, 460, 495, 576–577, 620–621Cole–Davidson function, 323, 388, 394, 420,

581–582, 620Collagen, 457, 483–484, 500–503, 506–507,

517Colloidal dispersions of magnetic

nanoparticles, 760–764Colloidal particles, 9, 41, 44, 55–56, 68–70,

99, 102–103, 105, 139, 147–148, 194,201, 286, 325, 560–562, 587, 605, 639,642–653, 661, 671, 740–741, 743

Colloidal suspension confined between rigidwalls, 605

Compliance, 13–21, 23, 130, 197–198, 204,213, 220, 223, 253–255, 257–258,261–265, 359, 409, 472, 568, 602, 607,758

Component dynamics, 165–166, 215, 233,235, 238, 243, 246–247, 341, 355, 379,457, 727

Concentration fluctuations, 62, 95, 124, 144,166, 232–238, 244, 341–344, 347, 352,642, 700–701, 727

Conductivity relaxation, 1, 10, 21, 52, 62,68, 146, 162, 229, 236, 553–555, 576,645–646, 653–656, 658–661, 663–665,667–671, 680–688, 694, 699, 710–712,714–716, 734, 739, 741, 743–746, 749

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Index 825

Configurational entropy, 9, 88–90, 92, 94, 120,124, 134–135, 138, 180, 248, 345

Confinement, 116, 248–249, 251, 354,370–372, 375–377, 413, 445–448, 455,463, 470, 487, 588–593, 595, 606,608–609, 613, 715

Confining wall, 587, 603, 733–734Confocal microscopy, 44, 56, 76, 99, 102–103,

146, 201, 286, 560–561, 605, 645,648–652, 740

Conformational fluctuations, 489, 491Conformational transition energy barrier, 722Constraint release, 10, 696, 725–727Cooperative length-scale, 115, 123, 318Cooperative rearranging region, 88, 94,

124, 180Cooperative shearing model (CSM), 416Cottrell atmosphere, 719Coupled protein–solvent structural relaxation,

484, 486Coupling Model (CM), 11, 47, 52–53, 59,

61–62, 73–88, 97–98, 103, 107, 130,137–138, 165, 170–171, 176, 192,200–201, 203, 213, 217, 221, 225, 233,249, 267, 271–272, 275–276, 280, 293,298–299, 303, 345–346, 375, 377, 382,390, 398, 412, 437, 440–441, 465, 497,502, 531, 549, 610, 614, 640, 643, 655,696–698, 700, 703–708, 711, 715, 733,741, 766

Coupling Model equation, 293, 440Coupling Model predictions, 610, 711Coupling parameter, 74, 80, 111, 145, 161,

166, 176, 180, 213, 216, 231, 233, 235,238, 245, 251, 266, 278–279, 296, 299,326, 340, 344, 346–347, 349, 352–353,356, 359, 362, 366, 390, 414, 426,439–440, 459–460, 462, 485, 487, 497,549, 559, 571, 585, 588, 594–596, 599,601–609, 619, 658, 661, 669, 673, 682,684–685, 688–690, 692–693, 695–697,700–703, 706–707, 710, 714, 716, 718,720–721, 723, 725, 728, 738, 747, 766

C-phycocyanin (C-PC), 479, 488, 500, 507,509, 517, 519, 521, 527

Creep, 13–18, 20, 55, 142, 197, 204–205, 213,220, 239, 253–255, 261–264, 266, 359,409, 568, 607, 727, 755

Cresolphthalein-dimethylether, KDE or CDE,152–153, 305, 318, 398, 408

Crick, 42, 238, 245Cross-linking, 319, 358–359, 403Crossover of correlation function, 63–70

CR-PBD, see 1,4-Polybutadiene (CR-PBD)Cryobiology, 434Cryoprotectant, 434Crystal embryo formation, 412Crystal growth rate, 207–209, 412–414, 420Crystalline ionic conductor, 62, 556, 653, 659,

661, 664, 686, 694, 712, 714, 729, 738,741–742

Crystallized bulk water, 4931-Cyanoadamantane (CNADM), 143, 390–394Cyanobenzene, 340Cyanocyclohexane (CNCH), 299, 390, 392Cyclohexanol, 286, 288, 299, 390, 548Cyclohexanol-cycloheptanol (CHXOL-

CHPOL), 390Cyclo-octanol, 143, 389, 566

DDebye function, 6Debye model, 5–6, 79, 210–211, 224, 227, 229Decahydroisoquinoline (DHIQ), 154, 299,

301, 335Decoupling, 215, 220–221, 223, 225, 227–228,

681, 685, 694, 757–758Defect diffusion model, 63Density fluctuation, 63, 124, 273, 404, 525,

557, 578, 601, 663, 727Deoxyribose, 452–453Depolarized light scattering, 34, 223, 226,

552–553, 567, 573, 577, 579, 581–582,585

Deuteron NMR, 220, 239–240, 275, 278, 355,358, 370, 398, 421, 454–455, 485, 493,496–502, 506–507

Deviatoric component, 271D-exchanged lysozyme, 476Dextran, 294, 435, 441–443, 633DHIQ, see Decahydroisoquinoline (DHIQ)Di(2-ethylhexyl) phthalate, 71, 154, 234Dialkyl phthalates, 317, 381, 383, 441Dielectric permittivity, 20–21, 576Dielectric spectroscopy, 110, 112–113, 151,

164, 166, 225, 240, 253–254, 262, 274,276, 285, 302, 346

Diethyl phthalate (DEP), 153, 276, 280, 306,333, 335, 383–384, 612

Differential scanning calorimetry (DSC), 23,113–115, 131, 198, 360, 371, 402, 421,424, 439, 448, 462, 471, 512

Difluorotetrachloroethane (CFCl2–CFCl2)plastic crystal, 65, 389

Diglycidyl ether of bisphenol A (DGEBA), 54,145, 154, 172, 192, 225–226, 306–307,

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826 Index

Diglycidyl ether of bisphenol A (cont.)312–313, 317, 319–320, 327, 329–330,332, 358, 397–398, 403, 530, 536, 569,614–615

Diglycidyl ether of bisphenol-A (EPON828),154, 319–320, 329–330, 335, 358–359

Diisobutyl phthalate (DiBP), 152, 154, 280,306, 328, 335, 381, 383, 400

Di-isooctal phthalate (DiOP), 153, 333, 335Dimethyl phthalate (DMP), 381, 383, 3861,1′-Di(4-methoxy-5-

methylphenyl)cyclohexane (BMMPC),153, 333, 335, 408

Di-n-butyl phthalate (DBP), 154, 276, 280,306, 322, 335, 381–382, 386, 406–407,410, 423, 564, 569, 577, 584

Dining Philosophers Problem, 76, 96–98Dioctalphthalate (DOP), 71, 306–308,

310–313, 360, 386, 410, 727–7281,2-Diphenylbenzene, 2501,2-Diphenylbenzene, ortho-terphenyl,

o-terphenyl, OTP, 55, 57, 95, 107,207–209, 250, 588

Diphenylvinylene carbonate (DPVC),154–156, 305–306, 317, 333, 535–537

Dipropylene glycol (2PG), 54, 187, 190,276–277, 280, 406, 410

Dipropyleneglycol dibenzoate (DPGDB), 152,154, 157, 276, 288, 296, 327, 335, 403,405, 431, 530

Dirac constraint dynamics, 60Disaccharide, 277, 294, 434–435, 437–443,

509–511, 629–630, 633–636Disorder–order transition, 4454D-NMR, 98Donth’s thermodynamic fluctuation theory,

95–96, 125–126DSC, see Differential scanning calorimetry

(DSC)Ductile, 418Ductility, 416–418Dy2Ti2−yZryO7, 711Dynamic correlation volume, 540–542Dynamic crossover, 182–183, 192, 467,

471–472, 476, 478, 499–501, 521–522Dynamic heterogeneity, 76, 96–108, 119, 123,

125–127, 148, 218, 231, 260, 541, 654,758

Dynamic lattice liquid model, 76Dynamic lattice liquid simulation, 643–644Dynamic light scattering, 33, 44, 55, 68, 70,

81, 102, 119, 139, 145–146, 175, 203,205, 223, 226, 262, 325, 381, 413, 473,

529, 557–559, 566–567, 574–576, 578,582, 586, 643–644, 649, 672, 674–675

Dynamic transition, 475–482, 486–488,499–500, 506–509, 511–513, 515–517,521–523, 526–528, 550

EE-glass, 282Einstein equation, 206, 653Elastin, 457, 483–484, 500–503, 506–507, 517Electric modulus, 13, 21–22, 143, 161–163,

290, 428, 553, 555, 558, 624, 657, 659,682, 688, 709–710, 713–714, 734–735,738, 742, 744–746, 752

Energy landscape, 9–10, 137–138, 273, 476,498

Entangled polymer, 9, 220–221, 253, 261,263–264, 544, 547, 609, 642, 654,656–657, 670–671, 673, 689, 691–692,694, 696, 706, 723, 726–728, 756

Entanglements, 150, 263, 656, 658, 724,726–728

Enthalpy relaxation, 59, 140, 162, 195–196,198, 281, 287, 391, 402, 465, 471, 489,492–496, 685

Enzyme, 474, 506Enzyme stability, 637EPON828, see Diglycidyl ether of bisphenol-A

(EPON828)Epoxide group, 319–320, 358, 615Epoxies, 145, 273, 320, 397Epoxy resin, 145, 192, 306, 312, 358Ethanol, 143, 389, 394Ethylbenzene (EBz), 91, 237, 288, 361Ethylcyclohexane, 298–299Ethylene glycol (EG), 247, 396, 444, 448, 450,

454, 459, 505, 518–519, 522–523, 626,675, 678

Ethylene glycol oligomers (EGO), 444, 448,626

Excess wing, 152, 154, 156, 285, 301–313,315, 317–324, 327, 331–335, 340, 346,361, 376, 379–381, 398, 406–408, 413,427–428, 530, 558–559, 575–580, 619,624, 741

Eyring’s approach, 267

FFabry–Perot interferometry, 34, 71, 669Fananserine, 277, 285, 419, 427Fast glassy ionic conductors, 658–659, 662,

664, 683(Fe, Co, Ni)75Si10B15, 281, 411Felodipine, 419

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Index 827

Fermi–Pasta–Ulam model, 86Fermi-stadium map, 83–86Floppy-to-rigid transition, 131Flopropione, 419–420Flory’s constrained junction model, 704–706,

708Fluctuation–dissipation theorem, 14, 39–40Food science, 1, 9, 49, 162, 294, 434Forced Rayleigh scattering, 209, 211, 240, 697Four-point correlation function, 118, 540, 542Four-point susceptibility, 118, 123, 126, 542Fox-Flory equation, 244Fragile glassformer, 120, 128–129, 423, 573,

582, 747Fragile-to-strong transition, 446, 468, 471–473,

500Fragility

index, 95, 107, 109, 117, 121, 127–150,159, 185, 234, 236, 282, 298, 300,344, 362, 367, 380, 393–395, 428, 439,535–536, 563–566, 568–569, 596, 600,622–623, 628, 635–636

thermodynamic, 134–137, 393, 635Free volume, 9–10, 88, 90, 94, 112, 124–125,

135, 142, 168, 179, 204, 271, 412, 569,573, 596, 639–640

Fructose, 162, 294–295, 396–397, 434–438,443, 450, 628–629

Furanose, 434–435

GGalactose, 162, 294, 434, 436–437, 443β-Galactosidase, 630, 632Gaussian approximation, 56, 202–203, 224Gaussian Orthogonal Ensemble (GOE), 73, 85Gaussian submolecule, 255, 258Gay-Berne ellipsoids of revolution, 227Germanium dioxide (GeO2), 120, 128–129,

136, 177, 282–283, 569, 657, 736, 747,752

Glarum defect diffusion model, 63, 316Glass

ionic conductors, 10, 61–62, 76, 229, 556,645–646, 653, 655–656, 658–659,661–664, 667, 670, 680–681, 683–687,689, 694, 699, 700, 708, 712, 728–729,738–739, 741–745

-rubber transition zone, 253Global chain dynamics, 723–728Glucose, 162, 273, 294, 431, 434–438,

440–441, 443, 451, 511–513Göttingen, 2, 4, 645Green–Kubo relation, 37–38, 60

HHard-sphere colloidal suspensions, 61Haven ratio, 653, 684, 736–740Havriliak–Negami equation, 299Havriliak–Negami function, 156, 361, 422Heat Capacity Spectroscopy, 22–23, 108, 110,

112, 426, 597Heavy water, 454–455, 481, 493, 496–497,

500–501, 507Hemoglobin, 475Heterodyne-detected optical Kerr effect

(OHD-OKE), 67, 322, 421, 423, 455,461, 552, 556–557, 573–582, 585, 600,740, 742

Heterogeneity lifetime, 98–99Heterogeneous relaxation, 102Heterostructure, 717–7181-Hexyl-3-methylimidazolium bromide, 163,

368–3691-Hexyl-3-methylimidazolium chloride, 162,

290Homogeneous relaxation, 96, 103, 217, 231H-polymer, 10, 657Human growth hormone, 630–631Hydrated palmitoyloleoyl phosphatidylcholine,

497Hydration shell, 368, 454–455, 457, 475–476,

491, 493, 495–498, 502, 523–525Hydration water, 457, 467, 475, 478, 480–483,

485, 487–489, 491, 494, 496–503, 505,507, 509, 511, 513–521, 525–528

Hydrodynamic regime, 215Hydrogel, 454, 466–470Hydrogenated polybutadiene (HPB), 221,

689–690, 693Hydrogen bond, 54, 107, 120, 130, 142, 145,

159, 161–162, 259–260, 273, 275, 294,306, 315, 332, 366, 396, 398, 404,408, 410–411, 423, 427, 431, 436, 445,447–448, 458, 461–462, 466–467, 470,474–475, 482, 484–485, 487, 492, 525

Hydrogen-bonding, 423, 431, 436, 466, 627Hydrophilic solute, 453, 466, 483, 488, 512Hydroxyl group, 434–435Hyperquenched glassy water (HGW), 442,

446, 461–462, 469

IIbuprofen, 277, 285, 313–314, 317, 419,

423–424, 584Immobilization, 729, 732–734, 736Immobilizing effect, 731Indomethacin, 162–163, 277, 282, 285,

402–403, 418–420, 422, 424–425

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828 Index

Inelastic ultraviolet scattering, 455, 461Inelastic X-ray scattering, 381, 568Interacting system, 3–4, 6, 8, 11–12, 34, 37,

41–45, 66, 68, 73, 78, 87–88, 96, 103,105, 193–195, 263, 322, 640–650, 653,655–656, 658–659, 661, 663, 670, 676,680, 689, 697–700, 710, 715, 720, 722,726, 730–731, 734, 738, 741, 743, 747,758–764

Interdisciplinary research, 44–46Intermediate power law (IPL), 322–323, 423,

533, 552, 557, 574, 578, 580, 672, 740Intermediate scattering function, 35, 37, 56,

58, 60, 63–66, 68–70, 101–103, 105,118–119, 122, 126, 139, 191, 193–194,202–203, 205, 221, 224, 227, 234, 325,344, 355, 460, 472, 525–527, 538–542,550, 600–601, 604, 610, 644, 649, 663,671–672, 731

Intermolecular coupling, 55, 59–60, 81, 83,145, 161, 180, 213, 232–237, 245, 249,251–253, 256–259, 266–267, 271, 279,346–347, 359, 363–364, 385, 392–393,404, 407, 418, 441, 520, 527, 534, 588,590–592, 594, 600–601, 607–608, 610,613, 619, 622–623, 627–628, 677, 723

Interstitial solute atoms, 718Invariance of dispersion, 152–154, 158, 160,

166, 334–335, 614Ion dynamics, 10, 62, 645–647, 652–653, 655,

664, 681, 688, 708–710, 713, 719, 730,738–739, 742, 748, 750–751

Ionic conductivity, 9, 68, 162, 576, 645–646,659, 671, 682, 710, 715–718, 733, 744

Ionic conductors, 9–10, 41, 61–62, 76, 229,325, 551, 556, 642, 645–650, 652–659,661–664, 666–667, 670, 680–689, 694,699–700, 708, 710–715, 728–736,738–739, 741–754

Ionic liquid, 41, 139, 161–163, 194, 210, 213,277, 290–301, 368–369, 504, 557, 624,694, 740

Ion-ion interaction, 10, 61, 642, 652–653, 664,684, 729–731, 734–739, 742

Islands of mobility, 273Isobaric fragility, 132, 159, 185, 535–538,

620–622, 624, 628Isochore, 183, 227, 586Isochoric condition, 132, 149, 184–185, 537Isochoric fragility, 185, 534, 536–537Isochronal dielectric loss, 354, 378, 392, 403,

422, 577Isocyanocyclohexane (ICNCH), 390, 392

Isoeugenol, 306–307, 309–311, 317–318, 406,410

Isopropylbenzene, 91, 382, 431, 548–549Isotactic PEMA (i-PEMA), 145, 363–364Isotope mass dependence, 42, 687–688, 690Isotropic phase, 702

JJG β-relaxation time of water, 459, 468–469,

483–484, 487, 633Johari–Goldstein β-relaxation, 275–638, 741,

768Jonscher’s expression, 749–750Junction dynamics, 658, 703–705, 707–708,

719–720

KKAHR model, 195, 200Kauzmann paradox, 88, 124–125KDE, 133, 141, 152–153, 181–182, 184, 192,

305, 318–319, 333, 379, 398, 408, 536Kirkwood–Fröhlich theory, 187, 584K0.3MoO3, 759–760Kob–Andersen model, 57, 122, 540, 542Kohlrausch exponent, 54–55, 75, 95, 107, 120,

123, 142, 145, 170, 177, 196, 200, 212,216, 223, 250, 269, 340, 394, 422,426, 433, 461, 465, 566, 604, 630–631,670–671, 673, 678–697, 713, 721, 735

Kohlrausch relaxation, 4, 64, 81, 102, 162,194–196, 322, 556, 675, 677, 734

Kohlrausch–Williams–Watts, 51, 54

LLa55Al25Ni20, 380Lactulose, 294, 437–439Langevin equation, 314, 528, 654–655Laponite, 70, 203, 205–206, 272, 408,

610–611, 672–673, 675–676, 698, 762Lattice φ4 model, 86LB-PBD, 238, 246–247, 283, 348–352, 354,

723Legendre polynomials, 32, 34, 59, 210, 213,

227, 763Length scale, 10, 13, 34, 52, 88–127, 130,

170, 176, 187, 191–192, 222, 241–242,247, 249, 251–267, 286, 303–304, 318,321, 327, 344, 413, 419, 446, 533–535,541–544, 584, 587–588, 591, 601–602,608–609, 650, 652, 670–671, 694–695,715, 724

Lennard–Jones potential, 283–284, 540, 731Leucrose, 294, 437–439, 443Lévy distributions, 53, 77, 743

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Index 829

Leyden jar, 2, 645LiAlSi2O6 (β-spodumene), 642, 7420.44LiBr–0.56Li20–B2O3, 659–660, 7430.6LiCl–0.7Li2O–B2O3, 683Li0.18La0.61TiO3 (LLTO), 642, 653, 712–713,

748, 7520.45Li2S+0.55GeS2, 686–6870.56Li2S–0.44SiS2, 686–687Li1.2Ti1.8Al0.2(PO4)3, 714–715Librational motions, 482Light scattering, 13, 19, 24, 33–34, 44, 51,

55–56, 59, 63, 68–70, 81, 102, 119,124, 139, 142–143, 145–146, 151,174–175, 203, 205, 213, 221, 223,225–226, 230, 248, 250, 252, 262,295, 325–326, 381, 413, 473, 529,552–553, 557–559, 566–567, 572–579,581–582, 585–587, 610, 643–644, 649,661, 668–669, 671–677, 679, 694–695,697–699

Li metasilicate glass (Li2SiO3), 286, 652, 655,733, 740, 743

LLTO, see Li0.18La0.61TiO3 (LLTO)Lodge–McLeish model, 247Longitudinal compliance and modulus, 19–20Low-density amorphous water (LDA), 442Lysozyme, 454–455, 457, 476–479, 482–484,

486–488, 499–502, 505–507, 509,511–513, 515–517, 600

MMagnetic nanoparticles, 760–764Maltose, 294, 435, 437–441, 443, 481–482,

485, 488, 509–510, 513, 515–516,526–527, 600

binding protein, 481–482, 485, 488, 513,515–516, 526–527, 600

Many-body cooperative dynamics, 587, 703Many-body effects, 6, 50, 94, 96, 181, 215,

534, 542, 545, 641, 643, 654, 670, 698Many-body interacting systems, 4, 12, 44, 68,

73, 640, 656, 698Many-body relaxation, 8–11, 40, 47, 60,

62–63, 73–88, 90, 93–94, 96, 100,103–104, 107, 121, 124–126, 129–130,133, 135–139, 141, 150, 187, 191–192,194, 205, 213, 215, 217–218, 222–224,227, 238, 241, 244, 248, 271–272,285–286, 303–304, 316, 318, 321–322,327, 394–395, 502, 543, 556, 591,618–619, 639–643, 655, 658, 661, 676,679–680, 694, 710, 715, 721, 726, 739,747, 758, 766, 769–770

Many-chain diffusion, 655

Many-molecule dynamics, 170, 535, 588,608–609, 652

Many-particle dynamics, 148–149Maxwell equation, 665, 690MCM-41, 446, 454–457, 463–468, 473, 490,

496, 506–507, 517MCT critical temperature, 553, 580Mean-squared displacement (MSD), 56, 60,

66–68, 87, 102–103, 139, 202, 224,325, 477, 480–481, 485, 498, 508, 514,516, 521–524, 526–527, 550, 556,560–564, 570, 572, 589, 599–600, 605,633–634, 636, 686, 727, 741, 743

Mechanical relaxation, 2, 13, 59–60, 131, 143,150, 172, 198, 220, 223, 225, 231, 359,443, 607, 610, 679, 704, 723

Merged α- and β-process, 451, 463, 491, 506Mesophases, 700–701Metallic glass, 41, 142, 210, 230, 275,

414–415, 417, 426, 504, 558Methyl-ended poly(oxybutylene), 5944′-Methylene bis(N, N-diglycidylaniline)

(MBDGA), 154, 3355-Methyl-2-hexanol, 293–294, 3952-Methyl tetrahydrofuran (MTHF), 98–99Meyer–Neldel rule, 670, 699, 720M-fluoroaniline, 159, 280, 319, 332, 396–398,

404, 612Microgels, 66, 146–148Mixed Alkali Effect, 728–736, 739, 750Mixture

Fructose, 628propylene glycol oligomer, 625–628of van der Waals liquids, 337, 339, 344,

349, 353, 396, 447, 451, 502, 530, 627MMA trimer, 329Mode coupling theory, 9, 66–67, 70, 88, 192,

203, 276, 525, 539–540, 573–574, 644,661, 768

Modulus, 2, 13–14, 16–17, 19–22, 51, 71,128, 139–140, 142–143, 161–163, 198,205, 220, 253–255, 267, 281, 290,317, 380–381, 409–411, 416–417, 426,428–429, 553–555, 558, 606, 624,656–657, 659, 682, 688, 690, 703,709–710, 713–714, 723, 727, 734–735,738, 742–746, 752

Molecular dynamics simulation, 13, 31, 41,57–59, 65–67, 73, 76, 99, 103–104,119, 122, 138–139, 146, 179, 193–194,213, 217, 223–224, 227, 229, 238, 246,279, 286, 325, 336, 347–353, 460, 462,484–485, 513–514, 526, 531–533, 538,

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830 Index

Molecular dynamics simulation (cont.)553, 568, 600, 603–604, 641, 643, 646,652, 685, 691, 709–711, 722, 730,732–733, 736–737, 743, 756

Molecular sieves, 315, 437, 446, 454, 462–466,468, 470–471, 490, 506, 517, 608

Molecular weight of entanglement, 544Molten salt, 68, 128, 130, 172, 273, 325, 380,

504, 581, 664, 740, 743Monohydroxyl alcohols, 293Monomeric friction coefficient, 241, 252, 544,

595, 602Monosaccharide, 162, 277, 294, 434–443Mössbauer spectroscopy, 506–507, 513–514,

517–519, 521–523, 527, 550Multidimensional NMR, 53, 101–102, 106,

125, 170, 541–542Multi-point dynamic susceptibility, 118–123,

540, 542Myoglobin, 454–455, 457, 467, 475–476,

479–482, 487–491, 493–498, 500–503,506–507, 509–510, 513–514, 517–528

NNa β-alumina, 642, 653, 660–661, 664–666,

681, 729, 742Na-β′′-alumina, 661Nanochannel of crystal, 474Nanoconfinement, 112–118, 247–251, 445,

447, 455, 463, 468, 473, 487–488, 548,562, 590, 595, 608–609, 613

Nanophase-separated side chain polymers,108–112

Nanoscience, 10, 50Nanotechnology, 10, 765Naphthenic mineral oil, 154Na–Rb alumino-germanate glasses, 736Na–Rb borate glasses, 736Na8[Si32O64(OH)8]·32H2O clay, 473–474Na-vermiculite clay, 463–464, 473Nearly constant loss (NCL), 64–65, 68, 286,

289, 292, 322–325, 380, 486–487, 510,526, 550, 564–565, 574, 578, 597, 639,644–645, 663, 672, 739–754

Nematic phase, 724–727Neopentanol-neopentylglycol (NPOL-

NPGOL), 390Nernst–Einstein relation, 737–739Neutron spin echo experiment, 655, 693, 727New York Times, 7, 46Nifedipine, 426NIST710a, 282–283N-methyl-ε-caprolactam (NMEC), 249, 323,

741

NMR measurements, 98, 106, 209, 219–221,240, 319, 427, 511–512, 610, 631, 658,691, 722, 755

N,N-diglycidyl-4-glycidyloxyaniline(DGGOA), 154, 335

N,N-diglycidylaniline (DGA), 154, 335, 401Nobel prize, 5Non-ergodicity parameter, 139–140, 568–569,

582Non-exponentiality, 52, 59, 76, 95, 111, 119,

121–122, 125, 130, 132, 136, 146–150,195, 200, 217–218, 222–223, 227,252–253, 274, 278, 283, 395, 426, 535,537, 566, 568–569, 584

Non-Gaussian parameter, 37, 100, 104, 561,644–647, 652–653

Non-JG secondary relaxation, 302, 304–306,319, 365, 380–395, 400, 441, 550

Non-linear deformation, 205, 267–272, 588,708

Nonlinear viscoelasticity, 271Normal mode, 157, 259–261, 266, 543–548,

594–595, 655, 658, 728N-propyl-3-methylpyridinium

bis(trifluoromethylsulfonyl)imide(PMPIm), 67, 557, 577

Nuclear Magnetic Resonance, 13, 34, 61, 209,631, 724

Nucleation, 207, 209, 412–420

OOldekop–Laughlin–Uhlmann–Angell plot, 83,

127–128Oligomers of ethylene glycol, 396, 459Onset time of NCL, 551–553Optical Kerr Effect, 67–68, 119, 322, 381, 421,

423, 455, 461, 552, 556–557, 573, 672,740

Ortho-terphenyl (OTP), 65, 71, 81, 88,90–91, 93–94, 98, 106–107, 119, 128,141–142, 154, 164, 175, 179, 182, 283,382, 390, 398, 413, 423, 577, 582, 585,588

o-TaS3, 759–760

PPd77.5Cu6Si16.5, 380Pd43Ni10Cu27P20, 380, 558Pd48Ni32P20, 281, 411P-doped molecular arsenic sulfide, 367–368Pearl necklace model of polymer, 283–285Pentachloronitrobenzene, 143, 389PEO in blends with PS, 240Peroxidase, 637

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Index 831

Perrin’s law, 3–4Pharmaceutical, 1, 9, 14, 41, 46, 49, 162–163,

277, 282, 285, 317, 400, 402, 411,418–430, 434, 489, 584, 628–629,635–636, 638, 765, 768–769

Phase-coupled oscillators, 78–80Phenylphthalein-dimethylether (PDE), 133,

141–143, 153, 164, 183–184, 187, 192,305, 318–319, 333, 336, 399–400, 408,529–530, 536, 612

1-Phenyl-1-propanol, 294Phenyl salicylate (salol), 153, 305, 333, 335,

423, 573Phosphate-silicate glass (0.243Na2O–

0.269CaO–0.026P2O5–0.462SiO2),273, 281

Photobleaching, 198, 210–211Photon correlation spectroscopy (PCS), 34, 59,

131, 147, 164, 210, 219–220, 250, 254,263, 266, 360, 472–473, 529, 548, 569,574, 591, 698, 754, 757

Physical aging, 111–112, 197–200, 268, 271,281, 296, 304–305, 307, 310–311, 318,404, 406, 408–411, 414, 431–432, 596,619

2-Picoline, 166, 168, 337–339, 343, 347,353–354, 365–366, 575–576

2-Picoline in tri-styrene, 337–339, 347, 353,366

Plastic crystalline materials, plastic crystals,143, 280

Plasticity, 416–418P(nBMA-stat-S) random copolymers, 2791,2-Polybutadiene, 55, 157–158, 243, 277,

400, 407–408, 433, 5691,4-Polybutadiene (CR-PBD), 55, 123, 238,

246, 277, 290, 347–352, 354, 563, 569,768

1,2-Polybutadiene (1,2-PBD), 55, 157–158,243, 277, 400–401, 403, 407–408, 433,569

Poly(α-methylstyrene) (PαMS), 166–167Poly(2,4-difluorobenzyl methacrylate)

(P24FM), 297–298Poly(2,6-dichloro-1,4-phenylene oxide)

(PDCPO), 658Poly(2-chlorosytrene) (P2CS), 165, 167, 247Poly(2-hydroxyethyl methacrylate) (PHEMA),

454–455, 466, 468–470, 507, 517Poly(3-chlorobenzyl methacrylate) (P3CM),

297–298Poly(3-fluorobenzyl methacrylate) (P3FM),

297–298

1,4-Polyisoprene (PI), 157, 289–290, 543, 574Poly(3-methylbenzyl methacrylate) (P3MM),

297Polyalcohols, 145, 275, 279, 292, 368, 504,

613, 622, 627Poly(aryl ether ether ketone), 55, 610Poly(aryl ether sulfone), 610Poly(butylene isophthalate) (PBI), 367Polychlorinated biphenyl (PCB62), 133,

152–153, 183–184, 188, 192, 243, 305,333, 377–378, 536

Poly(cyclohexyl methacrylate) (PCHMA),166–167, 530, 727–728

Poly(dimethyl siloxane) (PDMS), 113–118,194, 248, 251, 448, 588–590, 592,689–691, 699, 715, 722

Poly(ethylene-co-vinyl acetate), 157Poly(ethylene isophthalate) (PEI), 367, 506Polyethylene-like glass transition, 108–109,

112, 595–598Poly(ethylene naphthalene dicarboxylate)

(PEN), 367, 576Poly(ethylene oxide) (PEO), 64, 194, 234,

238–242, 247, 254, 355–358, 360,370–372, 375, 592–594, 675–676, 715,723

Polyethylene (PE), 108–109, 111–112, 221,223–224, 227, 576, 595–598, 654,689–691, 693, 755–756

Poly(ethylene terephthalate) (PET), 367, 431,525, 568–569, 576

Poly(ethyl methacrylate) (PEMA), 145, 166,179, 355, 363–364, 398, 598, 612–613,615–618

Polyisobutylene (PIB), 55, 64, 141, 194, 212,252–259, 264, 266–267, 325, 344, 356,551, 559, 563, 568, 571, 574, 582,586–587, 590, 594, 603, 740, 754, 758

Poly(isobutyl vinylether) (PiBVE), 157, 159Polyisoprene, 64–65, 105, 123, 157, 240, 242,

253, 259, 266, 277, 289–290, 304,325–327, 371, 431, 543, 574, 723, 728

Polymer blend, 165–166, 234–235, 238,240–241, 243, 246–247, 337, 347,352–358, 360, 370, 447, 451, 599,723–728

Polymer chain dynamics, 654–656, 696, 726Polymeric cluster solutions, 673–674Polymerization, 110, 320, 329, 654, 656Polymer surface mobile layer, 606–608Polymer viscoelasticity, 44, 76, 241, 755–756Poly(methylacrylate) (PMA), 164, 258

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832 Index

Poly(methyl methacrylate) (PMMA), 55, 62,64, 68, 95, 99, 125, 145–146, 166, 191,194, 201, 203, 234, 237–242, 247, 251,254, 269–270, 276, 298, 329, 355–360,363–364, 370–372, 375–376, 398,400–401, 407, 409–411, 431, 530, 563,568–569, 572, 575–576, 578, 590, 606,723

Polymethylphenylsiloxane (PMPS), 113–118,157, 243–244, 247, 265–267, 448, 530,536, 543, 548, 588–590, 592–594, 715

Poly(methyltolylsiloxane) (PMTS), 153, 157,530, 536

Poly(n-alkyl acrylates), 108, 596, 598, 600Poly(n-alkyl methacrylates), 62, 95, 279, 596,

615Poly(n-decyl methacrylate), 62, 111–112, 596,

601Poly(n-heptyl methacrylate), 111, 596–597,

601Poly(oxybutylene) (POB), 153, 157, 530, 543,

546–547, 594–595, 601Poly(phenylene sulfide), 610Polyphenyl ether, 154Poly(phenylglycidylether) (PPGE), 145, 153,

157, 172, 276–277, 280, 306–308,312–314, 317, 320, 330–331, 397–401,530, 536, 614–615

Poly(propylene glycol), 54, 157–158, 187,190, 259, 569

Poly(propylene oxide), 164, 400, 407Polysaccharide, 277, 294, 434–435, 441–443,

508, 633, 675Polystyrene (PS), 55, 95, 132, 140–142, 150,

164–165, 167, 198–199, 204–205, 212,220, 222, 234, 237, 251–252, 254–255,261–262, 266–267, 281, 298, 375–377,382, 386–387, 398, 407–408, 410–411,434, 525, 563, 576, 590, 592, 606, 608,694, 696–697, 708, 716, 758

Polytetrahydrofuran networks, 703, 706Poly(vinyl acetate) (PVAc), 53, 91, 98,

106–108, 124, 126, 132, 153, 157, 172,176, 187, 190, 194–195, 240–242, 247,254, 261, 264, 331, 333, 424, 530, 536,568, 584, 614, 756

Poly(vinyl alcohol), 455, 493, 496, 498, 507,517

Poly(vinylchloride) (PVC), 64, 132, 194,236–237, 277, 359, 409, 568, 576

Polyvinylethylene (PVE), 157, 194, 239–240,242–243, 247, 407, 433–434, 530, 536

Poly(vinylmethylether) (PVME), 157,165–167, 194, 234, 237, 239–240, 247,353–354, 372–377, 448, 454–455, 463,468, 489–491, 506, 517, 530, 536, 697,723

Poly(vinylpyrrolidone) (PVP), 282, 402, 420,425, 448, 454–455, 457, 460, 468,489–490, 506–507, 517

Positronium annihilation lifetime spectroscopy(PALS), 88, 179, 244, 569–572

Potassium ferrocyanide (K457Fe(CN)6),

523–524Potential energy landscape models, 9–10, 273PPG400, 157, 159, 306–307, 312–315, 317,

369, 399–400, 547, 618, 625–628, 633PPG4000, 157–159, 307, 309, 312–313Precipitates, 721–722Pre-exponential factor, 196, 474, 528, 581,

700, 703, 706–708, 718, 740Primitive relaxation

frequency, 163, 281, 287–290, 292–293,295, 302, 306, 321, 329, 331, 333,341, 424, 428–429, 551, 554–555, 625,741–742

time, 73–88, 92, 103–104, 121, 166–167,178, 181, 190, 213, 233, 240, 244–245,248, 275, 278, 280, 285–291, 298, 301,303, 307, 310–311, 314, 331–332, 344,358, 367, 377, 381–382, 388, 390, 408,421–422, 424, 430, 437, 440, 477, 479,505, 534, 541, 543–548, 564–565, 587,591–592, 603, 607, 610, 614, 621, 627,634, 636, 641, 645, 649, 652, 654, 660,675, 680, 684–687, 690, 698, 700–701,703, 710, 712, 715–716, 741, 749, 754,760, 766

Probe molecule, 193, 211, 2351-Propanol, 91, 293–295, 448, 455–457,

506–507, 517Propylbenzene (PBZ), 73, 173, 175Propylene carbonate (PC), 88, 91, 93–94, 128,

136, 141–143, 152–153, 174, 176,178–179, 182, 187, 190, 286, 302–305,322, 324, 333, 376, 379, 406–408, 426,428, 530, 548–549, 551, 561, 566, 570,575–576, 582–584, 740

Propylene glycol (PG), 54, 81–82, 88, 119,157–159, 161, 177, 179, 187, 190, 244,249, 250, 259, 265–266, 276–277, 280,286, 302–306, 314, 379, 406–407, 410,448, 460, 535, 543, 569–570, 575–576,582–584, 625–628

Protein denaturation, 480

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Index 833

Protein dynamics, 475, 478–486, 489, 498,526, 638

Protein unfolding, 480P-T superposition, 151, 153–154, 156–157,

159, 333Pullulan, 294, 442–443PVME in blends with PS, 240, 353Pyranose, 435Pyrochlores (Gd2Ti2−yZryO7), 653, 709–711

QQuasielastic neutron scattering (QENS), 113,

191–194, 234, 240, 325, 350, 355, 455,460, 464–465, 467, 471, 499, 501, 513,528–529, 550, 562–566, 570, 572, 581,661, 670–671, 675, 703, 744

Quinaldine (QN), 144, 166–168, 233, 276,280, 339–344, 346, 348, 353–354, 366,375–377, 382, 385, 396, 449, 530,612–613

Quinaldine in tri-styrene, 353, 366

RRadius of gyration, 124, 260, 601, 606, 693Random energy barrier model, 10, 742RbAg4I5, 660–661, 667ν-Relaxation, 369–370, 452, 455, 458–459,

527–528, 625, 627–629γ-Relaxation, 244, 280–281, 287, 290,

295–297, 306–320, 327–330, 332–333,335–336, 358, 369, 372, 381–385,387–393, 397–398, 402–403, 406, 409,423–426, 428–430, 436–438, 440–443,480, 511, 565, 593–594, 609–610, 615,625, 635, 637, 699, 701–702

γ-Relaxation in bisphenol A polycarbonate(BPA-PC), 244, 609–610, 701–702

Reptation, 9–10, 87, 241, 654–656, 691, 696,725–727, 756

Reptation model, 241, 654, 656, 696, 725–727Repulsive inverse power potential (IPP), 528,

541Retardation spectrum L, 258Reverse Monte Carlo method, 729Ribonuclease A, 484Ribose, 162–163, 294, 333, 435–437, 440–441,

452–453Rigidity percolation, 131RNA, 435, 478, 488Rotational diffusion, 4–5, 200, 206, 210–211,

217–219, 221–232, 679Rotational-translational coupling, 558,

577–579Rouse dynamics, 242, 258–259, 670–673

Rouse modes, 221, 253–256, 258–260, 263,265–267, 543, 594–595, 601–603,608–609, 692, 758

Rubber elasticity, 703–704Rubbery plateau, 253

SSaccharides, 162–163, 434, 441, 628–631Scattering vector dependence, 44, 639, 696Secondary alcohols, 293Segmental relaxation, 63, 65, 129–130, 132,

142, 157, 165–167, 191, 205, 221,223–224, 236–237, 239–243, 246,251–254, 256–257, 259–268, 352, 356,358–360, 543–545, 548, 592–594,601–602, 607–609, 691, 722, 727,755–757

Selenium (Se), 108, 116, 120, 136, 144,264–267, 563, 569

Self-diffusion coefficient, 38, 60, 207–209,217, 221, 467, 689, 692, 722, 757

Self intermediate scattering function, 58, 64,66, 122, 191, 202, 227, 472, 538–540,542, 604

Semidilute polymer solutions, 9, 194, 657–658,673, 694–697

Shear rate, 205–206, 272, 610–611Shear transformation zone (STZ), 416–418Side-chain, 55, 62, 95–96, 108–112, 194,

278–279, 297, 398, 475, 484, 595–596,598–600, 699–703, 707, 710, 719–720

Side chain liquid crystal polymers (SCLCPs),699–703, 707–708, 710, 719–720

Silanized glass pores, 251, 413, 448, 588–592Silanol group, 470Silica

gel, 437, 445–446, 454, 462, 466–471, 494,496, 506, 509–510, 608

SiO2, 128–130, 667, 736, 746Smectic phase, 700Smoluchowski equation, 5–6Snoek–Köster relaxation, 718–721Snoek peak, 718–719Sodium vermiculite, 447–448, 473Soft colloidal particles, 149Softening dispersion, 239, 242, 253–261, 263Solvent dynamics, 478–486Sorbitol, 54, 107, 126, 145, 159, 161, 238,

275, 278–279, 292–293, 304, 322, 332,352, 361–362, 365–366, 368, 395,398, 400–401, 404–408, 441, 448–449,504–505, 530, 535–536, 564, 576,612–614, 619, 622, 627–628

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834 Index

Sorbose, 162, 294, 434, 436–437Space-time pictures, 650–653, 743Spin-lattice relaxation, 61, 229, 237, 261, 275,

365, 398, 422, 457, 484, 558, 631, 633,636, 681–684, 687, 703–704, 706, 714

Spin-lattice relaxation weighted stimulated-echo experiment, 365, 484

Stabilization of biopharmaceuticals, 636Steepness of the effective repulsive potential,

540–541Steepness index, 120, 130, 137, 145, 147,

175, 216–217, 234, 236, 238, 300, 344,359, 362, 367, 422–423, 426–428, 537,566–567, 594, 596, 620

Stickel function, 182–183Stokes–Einstein–Debye relation, 5, 61, 127,

198–200, 206–232, 640, 680Stokes–Einstein relation, 3, 61, 100, 198–200,

206–232, 271, 413–414, 473, 684, 689,694–695, 737–739

Stress relaxation, 13–16, 60, 193, 197, 225,255, 263, 268, 725

Stretched exponential correlation function, 3,642–656, 678, 695, 706

Strong electrolyte, 730–731Strong glassformer, 120, 129, 194, 568, 747Structural recovery, 195, 197Sub-Rouse (sR) modes, 253–256, 258–259,

262–263, 603, 758Sucrose, 212, 214, 217, 220, 225, 230–231,

294, 419–420, 435, 437–439, 443,489, 509–511, 514, 518–519, 521–524,629–636, 638, 757

Sucrose benzoate, 212, 214, 217, 220, 225,230–231, 757

Sugar, 162, 362, 434, 438, 441, 452, 480, 489,628–638

Susceptibilityminimum, 526, 573, 582, 585–587, 653,

661–663, 740, 747spectrum, 64, 68, 226, 286, 552, 567–568,

574–575, 582, 653Syndiotactic PEMA (s-PEMA), 363–364

TTacticity, 145, 363–364ργ/T-dependence, 534–536, 542Telmisartan, 429, 434Temperature modulated differential scanning

calorimetry (TMDCS), 114–115, 117,371, 439

Tensile compliance and modulus, 19–20Terminal relaxation, 142, 239–241, 251,

261–264, 286, 544, 689–692

Tert-butylpyridine (TBP), 144, 233, 323,339–340, 346–348, 353, 375–377, 382,385, 396, 449–450, 575–576, 612

4-Tert-butylpyridine (4-TBP), 321, 575–576Tert-butylpyridine in tri-styrene, 339–340Tetrahydrofuran (THF), 236, 359Tetramethyl-bisphenol-A-polycarbonate

(TMBPA-PC), 244–245Thermal history, 195–196, 396, 399–405,

430–431Thermodynamic fragility, 134–137, 393–394,

635Thermodynamic path, 399–400, 404, 425Thermorheological simplicity, 44, 241,

251–267, 543–544, 602, 727, 754–758Thin films of Yttria stabilized Zirconia,

715–718Three-point function, 118Threitol, 54, 145, 159–160, 275, 279, 322,

332, 368, 441, 504–505, 551, 567, 613,619–622, 627, 740, 745

Time correlation function, 5–6, 14, 24, 30,32–33, 37–39, 51–88, 97–98, 106,118–119, 126, 169, 210, 212, 223, 227,232, 262, 293, 321, 603, 642, 727

Time–temperature–pressure superposition,164, 585

Time–temperature superposition, 220, 254,257–258, 262–263, 757

TNM model, 195–196, 198, 200–201Toluene, 71, 91, 98, 175, 181, 224, 368,

375–379, 395–396, 400, 407, 412,431–432, 503–504

Torsional autocorrelation function (TACF),284–285, 336–337, 351–353

Tracer diffusion, 208–209, 240, 242, 653, 684,696–697, 729, 738–739

Tramadol hydrochloride, 428–429Tramadol monohydrate, 428–429Translational diffusion, 3–5, 39, 60, 97, 193,

198–201, 208–209, 211, 217–219,221–232, 273, 427, 679, 685

Trehalose, 294, 419, 435, 437–441, 443, 458,479–481, 488–489, 509–511, 629–638

Tricresyl phosphate, 154Tri-epoxy triphenylolmethane triglycidylether

(TPMTGE), 145, 320Tri-m-cresyl phosphate (TCP), 99, 237,

256–257, 266–267, 569Trimethyl phosphate, 319Tri-m-tolyl phosphate, 266

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Index 835

Tri-naphthal benzene (TNB), 71–73, 120,127–128, 144, 171–172, 207–209,212–215, 217, 219–221, 230–231, 737

Tri-propylene glycol (3PG), 54, 159, 276,306–310, 312–318, 332, 448, 460

Tris(2-ethyl-hexyl) phosphate (TOP), 244–245Tris-naphthylbenzene, 207, 213Tri-styrene, 144, 166, 168, 251, 276, 280,

337–341, 344, 346–347, 353–354,366–367, 375–377, 382, 385, 396,449–450, 530, 585, 612–613

TVγ-dependence, 408, 433, 528–543,546–548, 572, 614, 768

Two-correlator MCT model, 557–558,578–580, 585

Tylenol, 426–430

UUltrathin films in nanocomposites, 592Ultrathin polystyrene film, 590, 606Uncrystallized water (UCW), 445–447, 494,

613Unentangled polymer, 221, 264, 547, 654, 656,

671, 756Universal properties, 10, 43, 45–46, 77, 556,

639–764, 770Unresolved JG relaxation, 297, 307, 319, 324,

331–336, 344, 353, 379, 408, 596, 624Ursodeoxycholic acid (UDA), 282, 402, 425

VVan der Waals liquid, 72, 108, 130, 132, 164,

288, 306, 337–344, 349, 353, 396, 447,451, 494, 530, 551, 627

Velocity–velocity correlation function, 221,684, 686

Viscoelastic properties, 9, 251–252, 671, 756Viscosity, 2, 4, 15, 38–39, 52, 61, 70–73, 90,

94, 105, 128–129, 137, 142, 147, 161,171–173, 175–177, 181–183, 186, 189,205, 207–211, 213, 215–217, 219–222,224–232, 259, 261–265, 282, 317, 472,514, 518–519, 521, 523–525, 529, 544,569, 621, 663, 680–681, 684–685,689–695, 722, 726–727, 739, 755,757–758, 761, 766

Vitrification, 7, 49, 135, 272, 354, 385–386,389, 399–400, 406, 453, 470, 629, 755,766

Vogel–Fulcher–Tammann–Hesse (VFTH)equation, 89, 114, 132, 171, 190, 246,255, 259, 262, 340, 472, 518–519, 521,612, 617, 627

Vogel–Fulcher–Tammann–Hesse (VFTH)temperature dependence, 69, 111–112,117, 171, 370, 373, 375, 380, 446, 452,469, 531, 593, 600, 639

Vogel–Fulcher temperature dependence, 8Von Schweidler law, 68, 574, 582

WWater

-glycerol mixtures, 483, 495-specific secondary relaxation, 503, 516,

518–519Wide Angle X-ray Scattering, 178–179Width of dispersion, 63, 126, 271, 348, 750Wigner’s statistical theory of energy levels, 73Williams ansatz, 274, 369–370, 616–618Williams–Landel–Ferry (WLF) equation, 255,

262

XXylitol, 54, 145, 159, 275, 279–280, 292, 322,

352, 365–366, 368, 406, 441, 448–449,504, 551, 567, 576–577, 613–614, 622,627–628, 745, 747

YY2Ti2−yZryO7, 711Yttria stabilized zirconia (YSZ), 642, 653,

664–665, 667–669, 699, 709, 715–718,742

ZZBLAN glass, 682Zinc chloride (ZnCl2), 136, 566–568, 573,

590, 745, 747Zn-substituted Mb, 490Zr65Al7.5Cu27.5, 380–381, 411, 504, 558, 740Zr46.75Ti8.25Cu7.5Ni10Be27.5 (Vit4), 380Zr46.7Ti8.3Cu7.5Ni10Be27.5, 210, 230