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1 Qingshan Zhu Remediation of mining legacy sites: Chinese Practices Institute of Process Engineering Chinese Academy of Sciences

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11

Qingshan Zhu

Remediation of mining legacy

sites: Chinese Practices

Institute of Process Engineering

Chinese Academy of Sciences

2

1. Introduction

2. Use of mining legacy sites

3. Utilization of gangue and

tailings

Outlines

2

3

1. Introduction

2. Use of mining legacy sites

3. Utilization of gangue and

tailings

Outlines

3

4

(1) Chinese minerals: low grade

Coal: 50% are low-rank coal

1t coal discharges 0.15-0.2t coal gangue

Background

5

(1) Chinese minerals: low grade

Iron ore

1t iron ore concentrate: 2t waste rock+2t tailings

70 billion tons, 95% low grade iron ore

Average Fe 33%, 11% lower than world

average

4036 mines, large mine 28, medium mine

61, 97.8% are small scale mines

Need beneficiation before use

Background

6

(2) Large population, huge mineral consumption

Consumption Domestic production waste/tailings

Iron ore 1.43 0.41 0.87

Coal 3.66 3.40 0.59

Unit: billion ton

Total iron ore gangue/tailings: >10 billion tons, over 4000

iron ore waste rock piles or tailings dams

Total coal gangue:>5 billion tons, over 1600 coal gangue

piles

Occupied 4 million hectares land

increased 40,000 hectares per year

Background

7

(3) Small agricultural land per capital

Land area: 9.6

million km2; 0.78

hectare per capital,

1/3 of world average

Agricultural land:

0.11 hectare per

capital, 43% of

world average

Background

88

History of mined land reclamation

(1) First stage (1949-1980s)

Almost no land reclamation

(2) Second stage (1988-1998)

“Land reclamation provision (1988)”: government

promotes land reclamation; State investment on research

and demonstration

(3) Third stage (1998-present)

“Land management act” (1998): all damaged land must

be remediated

“Regulations on land reclamation monitoring”

(2007): report on land damage and reclamation plan

“Regulations on land reclamation” (2011): detailed

requirements on the implementation

99

National strategy on land reclamation

All the damaged land must be remediated

(1) New mines

Licence can be obtained before the land reclamation plan

was approved by government

Land reclamation fund must first be established before

issuing the licence

(2) Mines in use

Land reclamation plan and fund need to be established

before renewing the licence

(3) Closed mines

Government initiates to make land reclamation plan and

establish the reclamation fund

1010

Land reclamation in China

(1) Overall mines

9000 large mines, 260,000 medium and small mines

Over 7 billion tons of mining gangue

Over 10 billion tons of tailings, stored on over 3000 tailings

ponds

(2) Overall land reclamation

Land damage due to mining: 4 million hectares

Land reclamation of mining legacy sites: 860,000 hectares,

~20% damaged land was remediated

100,000 hectares land reclamation every year

11

1995 2000 2005 2010 2015

120

125

130

135

140

145

Agricultura

l la

nd (

mill

ion h

ecta

re)

Year

Change of agricultural land

2016

Decrease: 336 khm2

due to construction,

industrial and

mining

Increase: 293 khm2

due to reclamation

Decrease rate: from 500 khm2 to 40 khm

2 per year

Land reclamation in China

12

1. Introduction

2. Use of mining legacy sites

3. Utilization of gangue and

tailings

Outlines

12

13

(1) Huangshi national mine park

I. Mine park

Daye iron ore: high grade 54-60%

Start at 254 AC in Han dynasty;

Restart in 1890 for iron ore for

Hanyang Iron factory, provide 3000

t/m iron ore for the first modern iron

company

Up to 1938, produce 6.1 million

tons of iron ore

1938-1945: 9.2 million tons of iron

ore shipped to Japan

1960: 2.90 million t/a of iron ore

1971: 5.05 million t/a of iron ore

1958-2003: 112.61 million tons

iron ore in total

Daye iron ore mine 1930s

Hanyang iron factory 1930s

14

(1) Huangshi national mine park

444m

Closed in 2003

Revegetation area: 2.47106 m2

Total area: 30.2 km2

Open at April 22, 2007

I. Mine park

15

(2) Maoming mine park

Start in 1958, closed in

1992

Produce oil shale oil

100 million tons, which

produce shale oil 2.92

million tons

Mine area 6.8 km2, depth 70 meters, ecological environment deterioration

Ecological remediation started in 2014

I. Mine park

16

(2) Maoming mine park

Plant 13,000 trees, over 100 hectares, new road 25.2 km;

Capacity of reservoir 1600 million m3, irrigating farmland 600 hectares

I. Mine park

18

II. Revegetation of mining site

(1) Soil reconstruction

leveling

refilling

Topsoil

Isolation

layer

Vegetation

Gangue

19

(2) Plant selection

Festuca arundinacea Clover Vetiver grass

Erect milkvetchLucerne Bermuda grass

II. Revegetation of mining site

20

(3) Slop stabilization

II. Revegetation of mining site

21

Example 1: iron ore mine (Anshan steel)Established in 1948, produce crude steel 331.93 million tons in 2015

Has 6 iron ore mines, produce 65 million tons raw ore, get 18 million

tons iron ore concentrate

Formed 8 tailings dams (4 still in use) of 1669 hectares, and 8 waste rock

fields of 2094 hectares

II. Revegetation of mining site

22

Example 1: iron ore mine (Anshan steel)Reclamation and revegetation start in 2007

II. Revegetation of mining site

23

Example 1: iron ore mine (Anshan steel)Pant 6 million trees, 5.8 million bushes

II. Revegetation of mining site

24

Example 1: iron ore mine (Anshan steel)Reclamation area: 3000 hectares, reclamation rate 90%; revegetation

rate 95%

II. Revegetation of mining site

25

Example 1: iron ore mine (Anshan steel)Established 3 reclamation demonstration park

II. Revegetation of mining site

26

Example 1: iron ore mine (Anshan steel)

II. Revegetation of mining site

Established 3 reclamation demonstration park

27

Example 2: coal gangue hill (Luan coal Ltd.)

II. Revegetation of mining site

Over 200 coal gangue hills of ~1500 hectares were revegetated all over China

13 coal gangue “hills” (8 still in use), occupied land 67 hectares

5 coal gangue hills of 33.7 hectares revegetated

28

III. Photovoltaic power generation

(1)Xiaoyi subsided coal mine PV projectCapacity 100 MW: Sept. 2014 start to construction, capacity 30 MW,

finished August 2015; second phase 70 MW finished Nov. 2016

Subsided area: 200 hectares

Investment 1 billion RMB, electricity output 140 million kWh

29

(2)Linxiang copper ore tailings pond PV projectCapacity 20 MW: start in July 2015, connected to the grid in June 28,

2016

Covered area: 120 hectares

Investment 180 million RMB, electricity output 19.5 million kWh

III. Photovoltaic power generation

30

(3)Huainan coal mine subsided lake PV projectCapacity 40 MW, 165000 PV module in total, connected to the grid in

June 16, 2017

Subsided lake area: 400 hectares, PV module covered area: 87 hectares

Investment 320 million RMB, electricity output 33 million kWh

III. Photovoltaic power generation

31

(4)Others

Other 10 mine PV projects finished with capacity of 220 MW

Around 20 mine PV projects planned with capacity over 500 MW

III. Photovoltaic power generation

32

1. Introduction

2. Use of mining legacy sites

3. Utilization of gangue and

tailings

Outlines

32

33

I. Coal gangue utilization

1600 coal gangue “hills”, total amount 5 billion tons

increased by 150-200 million tons per year

Land occupation: 13,700 hectares

Utilization ratio increased year by year, currently utilization

ratio ~70%

34

Utilization technologies

(1) Thermal utilization (power generation, combustion)

carbon content >20%, calorific value >6200 kJ/kg

(2) Construction materials (bricks)

calorific value 2100-6200 kJ/kg

(3) Filling materials (mine, roads)

calorific value <2100 kJ/kg

(4) Pigments

Special compositionThermal

utilization

Construction

materials

Filling

materials

I. Coal gangue utilization

2013

35

(1) Coal gangue power generation plantsHuanglin mine Guolin power plant

Over 250 coal gangue power plant with total capacity 35

GW, the largest capacity 330 MW

Consume 150 million tons of coal gangue in 2013, 32% of

the total coal gangue discharged in 2013

I. Coal gangue utilization

36

(2) Make construction materials

Over 1000 coal gangue brick plants, produce 13 billion bricks

Consume 56 million tons of coal gangue in 2013, 12% of the

total coal gangue discharged in 2013

I. Coal gangue utilization

37

(3) Filling materials

260 million tons of coal gangue were used to filling and

remediating mines and in 2013, 56% of the total coal gangue

discharged in 2013

I. Coal gangue utilization

38

(4) White pigment from kaolinite coal gangue

Roasting

additives

product

Mixing

Established 30,000t/a kolin white

pigment in 2013

Whiteness 95,particle size: 0.1-5m

Hydrothermal

I. Coal gangue utilization

39

II. Iron ore tailings utilization

Over 2000 iron ore tailings dams, total amount 10 billion tons

increased by 400-600 million tons per year

Iron content (TFe) 10-18%

Low value utilization, most of them are not used

New technology to recovery iron ore concentrate

40

New utilization processIron ore tailings

TFe: 10-18% high gradient magnetic separator

Primary iron ore concentrate

TFe: 30-35%

Magnetizing roasting

Fe2O3+H2Fe3O4+H2O

II. Iron ore tailings utilization

41

New utilization process

Primary iron ore concentrate after roasting

Magnetic

separation

Secondary tailings

TFe 3.5%

Recovery concentrate

TFe 66.5%

Bright phase: Fe3O4; dark phase: silicates

II. Iron ore tailings utilization

42

New utilization processIron ore tailings

TFe: 10-18% high gradient magnetic separator

Primary Iron ore concentrate

TFe: 30-35%

magnetic separatorTFe: 60-66%

II. Iron ore tailings utilization

4343Yunnan Province, China

Shaft FB

(1966)

FB

(2009)

FB

(2013)

capacity(10kt/a) 10 3 5 10

T(C) 850 700 850 500

Time(h) 4 0.5 0.5 0.25

Fe recovery(%) 72 81 81 93

Energy

comsumption

(kgce)102 85 91 68

Fe2O3+H2Fe3O4+H2O

100kt/a technology demonstration plant

II. Iron ore tailings utilization

44

6 million (4*1.5 million) t/a plant (Anshan Steel)

28.5 m tons of tailings processed to produce 6.2 m tons primary

iron ore concentrate, after magnetizing roasting-magnetic separation,

2.5 m tons of iron ore concentrate with TFe 66.5%

II. Iron ore tailings utilization

空气

5660.4 Nm3/h, 823K

矿石 15.2 t/h

水 0.76t/h

4519.0 Nm3/h

高炉

煤气 5770 Nm3/h

5660.4 Nm3/h, 823K

1591K

24t H2O

923K

9596.5

Nm3/h

12138.3 Nm3/h

682K

10660.5

Nm3/h

373K

H2O 6 t/h

矿浆

1

2

5

7

8

9

10

17

16

15

13

11

12

14

19

20

21

6

3

4

18

矿石

Fe2O3.1.5H2O 8.9t/h

脉石 6.3 t/h

水 0.76t/h

Fe2O3.H2O 8.5 t/h

SiO2 6.3 t/h

Fe2O3 7.6 t/h

脉石 6.63 t/h

Fe3O4 7.4 t/h

脉石 6.3 t/h

Fe2O3 7.6 t/h

脉石 6.3 t/h

矿石 15.2 t/h

水 0.76t/h

823K

5770 Nm3/h

12138.3 Nm3/h

22

23

23

454K

45

Thank you for your

attention!

46

(1) Soil reconstruction

Acidic gangue

an isolation layer

II. Revegetation of mining site

47

Example 3: red mud tailings pond (Pingguo Alumina)

Area: 45 hectares, 5 million tons of red mud

II. Revegetation of mining site

48

Example 3: red mud tailings pond (Pingguo Alumina)

Revegetation area: 70 hectares

II. Revegetation of mining site

49

Example 3: red mud tailings pond (Pingguo Alumina)

II. Revegetation of mining site

Revegetation area: 70 hectares

50

(4)Chengde iron ore tailings pond PV project

Capacity 20 MW: closed in 2014, start to install PV module in June

2016, 77436 PV module in total, connected to the grid in June 29, 2017

Land area: 50.76 hectares

III. Photovoltaic power generation