ISPITIVANJE KONTAMINIRANIH ISPITIVANJE KONTAMINIRANIH PODZEMNIH VODA U SLOŽENIM PODZEMNIH VODA U SLOŽENIM

PROCESNIM SISTEMIMAPROCESNIM SISTEMIMA

SONJA STEFANOVSONJA STEFANOV, , MIRJANA VOJINOVIĆ MILORADOVMIRJANA VOJINOVIĆ MILORADOV, ,

RADOMIR BIOČANIN, RADOMIR BIOČANIN, SLOBODAN STANICSLOBODAN STANIC, , ŠIMON ŠIMON BANČOVBANČOV

Asocijacija geofizičara Srbije

ZAŠTITA ŽIVOTNE SREDINEU ENERGETICI, RUDARSTVU I PRATEĆOJ INDUSTRIJI

21 - 23. 9. 2010. Divčibare

LokacijaLokacija

EksperimentEksperiment

EksperimentEksperiment ► LocatioLocation number 1n number 1 is located some is located some 100 m100 m from the fence of the complex process systems (exemple 1). On location 1 the from the fence of the complex process systems (exemple 1). On location 1 the

project anticipated construction of project anticipated construction of 4 piezometers4 piezometers, depths: , depths: 45 m, 25 m, 15 m 45 m, 25 m, 15 m andand 7 m 7 m. . HDPE pipes, 160mm in diameter, HDPE pipes, 160mm in diameter, were build-in the piezometer. Around the filter part quartz granulate 1-3 mm was poured in. Above it, a clay tampon was were build-in the piezometer. Around the filter part quartz granulate 1-3 mm was poured in. Above it, a clay tampon was made and the space between the pipes and walls of the hole above the clay tampon was filled with drilled material. made and the space between the pipes and walls of the hole above the clay tampon was filled with drilled material. All All piezometers were washed with pure water by a pump followed by air-lift piezometer compression until the water was piezometers were washed with pure water by a pump followed by air-lift piezometer compression until the water was completely clear. Also piezometers were secured by protective metal caps and locks.completely clear. Also piezometers were secured by protective metal caps and locks.

► Location number 2Location number 2 is located is located 30m30m from the fence of the complex process systems (exemple 1) near the road towards from the fence of the complex process systems (exemple 1) near the road towards Starcevo village. On location 1 the project anticipated construction of Starcevo village. On location 1 the project anticipated construction of 4 piezometers, depths: 45 m, 25 m, 15 m and 7 4 piezometers, depths: 45 m, 25 m, 15 m and 7 m.m. HDPE pipes, 160mm in diameter, were build-in the piezometer. Around the filter part quartz granulate 1-3 mm was poured HDPE pipes, 160mm in diameter, were build-in the piezometer. Around the filter part quartz granulate 1-3 mm was poured in. Above it, a clay tampon was made and the space between the pipes and walls of the hole above the clay tampon was filled in. Above it, a clay tampon was made and the space between the pipes and walls of the hole above the clay tampon was filled with drilled material. All piezometers were washed with pure water by a pump followed by air-lift piezometer compression with drilled material. All piezometers were washed with pure water by a pump followed by air-lift piezometer compression until the water was completely clear. Also piezometers were secured by protective metal caps and locksuntil the water was completely clear. Also piezometers were secured by protective metal caps and locks

► Location number 3Location number 3 is located is located 250 m250 m from the complex process systems (exemple 2), next to the road leading towards the from the complex process systems (exemple 2), next to the road leading towards the Danube. On location 3 the project anticipated construction of Danube. On location 3 the project anticipated construction of 4 piezometers, depths: 45 m, 25 m, 15 m and 7 m.4 piezometers, depths: 45 m, 25 m, 15 m and 7 m. HDPE HDPE pipes, 160mm in diameter, were build-in the piezometer. Around the filter part quartz granulate 1-3 mm was poured in. Above pipes, 160mm in diameter, were build-in the piezometer. Around the filter part quartz granulate 1-3 mm was poured in. Above it, a clay tampon was made and the space between the pipes and walls of the hole above the clay tampon was filled with it, a clay tampon was made and the space between the pipes and walls of the hole above the clay tampon was filled with drilled material. All piezometers were washed with pure water by a pump followed by air-lift piezometer compression until the drilled material. All piezometers were washed with pure water by a pump followed by air-lift piezometer compression until the water was completely clear. Also piezometers were secured by protective metal caps and locks.water was completely clear. Also piezometers were secured by protective metal caps and locks.

► Location number 4Location number 4 is located is located 700 m700 m from the complex process systems (exemple 2), next to Danube river. On location 4 from the complex process systems (exemple 2), next to Danube river. On location 4 the project anticipated construction of the project anticipated construction of 4 piezometers, depths: 35 m,4 piezometers, depths: 35 m, 25 m, 15 m and 7 m.25 m, 15 m and 7 m. HDPE pipes, 140mm in HDPE pipes, 140mm in diameter, were build-in the piezometer. Around the filter part quartz granulate 1-3 mm was poured in. Above it, a clay tampon diameter, were build-in the piezometer. Around the filter part quartz granulate 1-3 mm was poured in. Above it, a clay tampon was made and the space between the pipes and walls of the hole above the clay tampon was filled with drilled material. All was made and the space between the pipes and walls of the hole above the clay tampon was filled with drilled material. All piezometers were washed with pure water by a pump followed by air-lift piezometer compression until the water was piezometers were washed with pure water by a pump followed by air-lift piezometer compression until the water was completely clear.completely clear.

Rezultati i diskusijaRezultati i diskusija Rezultati hemijske analize na lokaciji 1

KMnO4 DEMAND COMPARATIVE CHARTBY DEPTH ON LOCATION NO. 1

0 20 40 60 80 100 120 140 160 180 200 220 240 260

7

15

25

45

depth

(m

)

mg/L

KMnO4 demand - I samplingKMnO4 demand - II samplingKMnO4 demand - III sampling

PCB CONCENTRATION COMPARATIVE CHART BY DEPTH ON LOCATION NO. 1

0 0.002 0.004 0.006 0.008 0.01 0.012 0.014 0.016 0.018 0.02

7

15

25

45

depth

(m

)

mg/L

PCB - I samplingPCB - II samplingPCB - III sampling

TOTAL HYDROCARBONS CONCENTRATION COMPARATIVE CHART BY DEPTH ON LOCATION NO. 1

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1 1.2

7

15

25

45

de

pth

(m

)

mg/L

Total hydrocarbons - I samplingTotal hydrocarbons - II samplingTotal hydrocarbons - III sampling

PHENOL CONCENTRATION COMPARATIVE CHART BY DEPTH ON LOCATION NO. 1

0 0.0005 0.001 0.0015 0.002 0.0025 0.003 0.0035 0.004 0.0045

7

15

25

45

de

pth

(m

)

mg/L

Phenol - I samplingPhenol - II samplingPhenol - III sampling

KM

nO

4

PCB

hlorfenol

Ukupni ugljovodonici

Rezultati I diskusijaRezultati I diskusijaRezultati hemijske analize na lokaciji 2

KMnO4 DEMAND COMPARATIVE CHARTBY DEPTH ON LOCATION NO. 2

0 25 50 75 100 125 150 175 200 225 250 275 300 325 350 375

7

15

25

45

depth

(m

)

mg/L

KMnO4 demand - I samplingKMnO4 demand - II samplingKMnO4 demand - III sampling

TOTAL HYDROCARBONS CONCENTRATION COMPARATIVE CHART BY DEPTH ON LOCATION NO. 2

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7

7

15

25

45

depth

(m

)

mg/L

Total hydrocarbons - I samplingTotal hydrocarbons - II samplingTotal hydrocarbons - III sampling

KMnO4Ukupni ugljovodonici

Rezultati i diskusijaRezultati i diskusijaRezultati hemisje analize na lokaciji 3

KMnO4 DEMAND COMPARATIVE CHARTBY DEPTH ON LOCATION NO. 3

0 10 20 30 40 50 60 70 80

7

15

25

45

de

pth

(m

)

mg/L

KMnO4 demnad - I samplingKMnO4 demand - II samplingKMnO4 demand - III sampling

PCB CONCENTRATION COMPARATIVE CHART BY DEPTH ON LOCATION NO. 3

0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.1

7

15

25

45

de

pth

(m

)

mg/L

PCB - I samplingPCB - II samplingPCB - III sampling

1,2-DICHLORETHANE COMPARATIVE CHART BY DEPTH ON LOCATION NO. 3

0 25 50 75 100 125 150 175 200 225 250 275 300

7

15

25

45

dep

th (m

)

mg/L

1,2-dichloethane - I sampling1,2-dichloethane - II sampling1,2-dichloethane - III sampling

CHCl3 COMPARATIVE CHART BY DEPTH ON LOCATION NO. 3

0 50 100 150 200 250 300 350 400 450 500 550 600 650 700

7

15

25

45

dep

th (m

)

mg/L

Chloroform - I samplingChloroform - II samplingChloroform - III sampling

KMnO4 PCB

EDC CHCl3

Rezultati i diskusijaRezultati i diskusijaAnalize na nekim loakcijama u blizini naseljenih mesta

KMnO4 DEMAND COMPARATIVE CHART ON CHOSEN LOCATION IN THE DIRECTION OF STARCEVO

0 5 10 15 20 25 30 35 40 45 50 55 60 65

P-738

P-739

esma

Lo

ca

tio

n

mg/L

KMnO4 demand - I samplingKMnO4 demand- II sampling

TOTAL HYDROCARBONS (C5-C20) COMPARATIVE CHART ON CHOSEN LOCATION IN THE DIRECTION OF STARCEVO

0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16

P-738

P-739

esma

Location

mg/L

Total hydrocarbons - I samplingTotal hydrocarbons - II sampling

PHENOL COMPARATIVE CHART ON CHOSEN LOCATION IN THE DIRECTION OF STARCEVO

0 0.001 0.002 0.003 0.004 0.005

P-738

P-739

esma

Location

mg/L

Phenol - I samplingPhenol - II sampling

CHCl3 COMPARATIVE CHART ON CHOSEN LOCATION IN THE DIRECTION OF STARCEVO

0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40

P-738

P-739

esma

Location

g/L

Chloroform - I samplingChloroform - II sampling

KMnO4 PCB

EDC CHCl3

ZaključciZaključci► Prečišćavanje kontaminaranih područja je složen

proces, pošto je izvesna količina iscurelih toksičnih supstanci transformisana ili su poslužili kao reagens za nastajanje drugih jedinjenja.

► Prečišćavanje velikog lokaliteta je neizvesan posao. U medjuvremenu zagađenje se širi i uništava podzemne vode i izvore odakle tako ili kroz lanac ishrane negativno utice na zdravlje ljudi.

► Projekat za lokalizaciju zagađenja treba da uradi hidrološke barijere sa postojećim piezometrima I bunara I na keraju I bušenje novih bunara