tables · 2020. 12. 12. · table 2-1 hydraulic conductivity values tonolli corporation superfund...

TABLES

3R30I587

TABLE 1-1SUMMARY OF WASTE WATER SAMPLING

ANALYTICAL RESULTS

Valve 1/3 LeakingSample I.D. Tonolli Corp. from Tank Valve at

Sample T-1 TSL01 TSL02 Top of Tank Bottom Bottom_________________________4/30/84 9/27/84 6/3/87 6/3/87_____1987______1987______1987Parameter Unit

Aluminum ug/l 30,000Arsenic ufl/I 5,200 12,200 622 704 1,620 250 15Barium ug/l 1,300 LT 500 — — — • —Cadmium ug/l 7,600 15,300 603 605 1,180 7500 30Chromium ug/I 180 1,355 137 138 370 2,550 NDCopper ug/l — — 1060 1050Fluoride ug/l 1,250Total Iron ug/I 2,700 — — — — ———Dissoved Iron ug/l 350 — — —Lead ug/l 107,000 2,800 2,890 2,910 1,080 3,820 2,900Magnesium ug/l 38,500Mercury ug/l 4.9 2.1 — — — — —Niokel ug/l -- — -- - 810 5,500 100Selenium ug/l 25 99Silver ug/l LT 10 LT 200 — —Zinc ug/l — — — ~ 2,600 3,000 11,000Toluene ug/l 400Trichloroethene ug/l 1,1 OO1,1,1-Trichloethane ug/l 1,400Chloroform ug/l 500 — — —Methylene Chloride ug/I 9,400 — — — ~ —Benzene ug/l LT 100All Pesticides ug/I LT 5,000Phenols ug/l LT 20,000 — — — — ——-Fuoranthane ug/l 5,300 — — — —Bis-2-ethyl phthalate ug/l 47,000 — — — —Di-n-butyl phthalate ug/l 3,300 — — —Phenathracene/Anthracene ug/l 3,700 — — — _ - - -—-Pyrene ug/l 1,800 — — — —Benzedene ug/l LT 20,000Hexachlorocylopentadisne ug/l LT 20,000 —Total PCBs ug/l LT 50,000 — — — — ——sulfate mg/1 200 — _ _Nitrate mg/l 1.1 ~ — — ~ " ~Nitrite mg/l 0.007Ammonia mg/l 0.23 — — —Oil/Grease mg/l 0.41 — — — —Total Solids mg/l 2,145 — — — ._Settleable Solids mg/l 1,689.5Dissolved Solids mg/l 196.2Dissolved Oxygen mg/l 8.6 — —Acidity mg/l 322 — — — —pH - 1.0-1.1 - - _ • -Color - 4.3Turbidity FTU 230 — — — — • —Five Day BOD mg/l 1,200 — — — — —

NA - Not analyzedLT - Less than Detection LimitsNote: Referenced from E.S. Work Plan 1989 r~

Metals analysis beleived to be total metals.

"1R30/588

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TABLE 1-3SUMMARY OF GROUNDWATER MONITORING ANALYTICAL RESULTS

FROM THE PANTHER CREEK ENERGY, INC.BEDROCK MONITORING WELLS (a)

PARAMETER ____________ UNIT _____ 6 ______ 7 ______ 8 ______ 9 ______ 10Aluminum A*g/l 100 so/2oo(b) LT 100 20/190 LT 100

Arsenic jtg/1 LTS.O LTB.O LT B.O LT B.O LT B.OBeryllium Mg/i LT1.0 LT1_0 LT , 0 LT , 0 LT , 0Cadmium LT1.0 LT1.0 LT , 0 LT , 0 LT , 0Calcium g/1 27,000 1,120 83,aoo 251,000 7,230Chromium /ig/1 LTB.0 LTB.0 LTS-0 LT6.0 LTSOCOPper /ig/1 LT10 LT 10 LT10 LT10 LT10

'r°n MS/' 1,280 10/560 60/110 80/230 30

Lead /*9/l LT s.o LT 5.0 LT s.o LT B.O LT 5.0

Magnesium /*g/l 6io 370 17,100 ao 2,410Manganese /tg/l 80 10/19 LT 10/2.0 LTIO/B.O LT 10Mercury /tg/l LT0.5 LT0.6 LT0.S LT0.S LT0.S

3i720 820 3,080 68,600 420

Selenium ^g/l LTBt0 LT5.0 LT B-0 LT 5-0 LT s 0

fJ.Q/\ LT1.0 LT1.0 LT 1.0 LT1.0 LT 1 .0

M9/' 1,900 1,230 9,200 16,800 4,840

LT 10 10 540 LT 10 10

LT5.o 9.0 UT6.0 40 LT6.0

Chloride mg/l ,.0 1.0 4.0 4.0 s.oFlouride mg/l tre.o LTe.o LT e.o 0.37 LT B.O

Nitrate mg/l 0.24 0.1 0.27 I.M 3.42Nitrogen mg/l LTO.I LTO.I LTO.I O.B LTO.I

Sulfate mg/l s.o 7.0/15 225/340 12/48 2.0P" UnitS 7.2 9.6/11.7 8.8/11.7 3.6/11.5 8.7

Acidity mg/l 3.0 o.o 0.0/7.0 0.0/3.0 e.o

Alkalinity mg/l 22.0 34/232 43/224 ss/iao 25Specific Conductance mmhos 8i 74/1,340 379/1,510 144,700 104TSS mg/l 14 LT 1.0/4.0 1.0/38 2.0/4.0 4.0

TDS mg/l as 23/351 379/888 32/288 100

LT =Less than the detection limit indicated.(a) Source: Panther Creek Energy, Inc. Permit Application for Cogeneration Facility, May 1989

and Tonolli RI/FS Work Plan, April 1990.(b) Numbers to the left are lowest recorded values, while numbers to the right are the highest

recorded values.

\lonolli\ri\tibl-3.doc flR30/590

TABLE 1-4

SUMMARY OF PREVIOUSSURFACE WATER MONITORING ANALYTICAL RESULTS

TONOLLI CORPORATION SUPERFUND SITE

Upstream (a) Downstream (a) Upstream (b) Downstream (b)Parameter Unit S-1 S-2 029 028

Aluminum ug/l — — LT 20 LT 20Antimony ug/l LT1.0/2.0(c) LT1.0/47(c) LT 20 LT 20Arsenic ug/l LT 2.0/4.0 LT 2.0/108.3 3.0 5.0Barium ug/l 4.0/100 2.0/200Beryllium ug/l — — LT 5.0 LT 5.0Boron ug/l --- — LT 100 LT100Cadmium ug/l LT 1.0/9.0 2.0/38 LT 0.5 0.7Chromium ug/l LT 1.0/15 LT 1.0/21Copper ug/l 10/120 20/900 2.0 5.0Fluoride ug/l 15/155 23/250Iron ug/l 50/550 330/3,360 280 330Lead ug/l 1.6/20 2.0/170 1.6 2.8Manganese ug/l 9.0/200 23/2,020Mercury ug/l LT 0.2/1.6 LT 0.2/1.4Nickel ug/l — --- 5.0 11Nitrate ug/l 21/8,000 10/1,100Selenium ug/l LT 2.0/2.8 LT 2.0/30 LT 3.0 LT 3.0Silver ug/l LT 1.0/2.0 0.7/9.0 LT 0.5 LT 0.5Sodium ug/l 700/8000 700/51,500Tin ug/l — — LT 2.0 LTZinc ug/l 20/560 20/900 3.0 10Endrin ug/l LT 0.005 LT 0.005Lindane ug/l LT 0.01 LT 0.01Methoxychlor ug/l LT 0.02 LT 0.02Toxaphene ug/l LT 0.1 LT 0.12,4-D ug/l LT 0.02/1.5 LT 0.02/1.42,4,5-TPSiivex ug/l LT 0.002 LT 0.002Phenol ug/l LT 100 LT 100/60 LT1.0 8.0Chloride mg/l 1.0/13 1.0/39Sulfate mg/l 6.0/48 6.0/110Bicarbonate mg/l 3.0/23 3.0/26Oil/Grease mg/l 0.1/5.0 LT 1.0/3.0Radium pci/L LT1.0 LT 1.0Gross Alpha pci/L LT 0.4/5.6 LT 0.4/5.0Gross Beta pci/L LTD.9/1.5 LT 1.0/5.1Turbidity TU 0.1/5 0.0/20Coliform per 100 ml 0.0/115 0.0/50pH Units 5.64/6.63 4.05/6.61Specific Conductance umhos 38/54 50/390Total Organic Carbon mg/l 1.4/3.7 0.4/14Total Organic Halogens mg/l LT 0.01/0.027 LT 0.01/0.036Total Dissolved Solids mg/l 18/30 23/209Acidity mg/lAlkalinity mg/lFlow Rate gpm

LT = Less than indicated detection limit= Not Analyzed

(a) Tonolli Corporation, RCRA Part B - Vol. II, March 1985 (Quarterly Monitoring 1983-1985)(b) USEPA, 1989d (Sampled on July 3, 1989)(c) Numbers to the left are the lowest recorded values, while numbers to the right are the highest recorded values.

Metals analysis are believed to be total metals

3R3Q159I

TABLE 1-4(Continued)

SUMMARY OF PREVIOUSSURFACE WATER MONITORING ANALYTICAL RESULTS

TONOLLI CORPORATION SUPERFUND SITE

Parameter Unit 12 14 20 30 40

Aluminum ug/l LT 100/100 (c) LT 100/100 (c) 10/100 (c) LT 100/200 (c) 100/1 3,100 (c!Antimony ug/lArsenic ug/lBarium ug/lBeryllium ug/lBoron ug/lCadmium ug/lChromium ug/lCopper ug/lFluoride ug/lIron ug/l 40/220 LT 10/70 90/190 30/310 120/300Lead ug/lManganese ug/l LT 10/50 LT 10/10 50/100 20/280 210/4,300Mercury ug/lNickel ug/lNitrate ug/lSelenium ug/lSilver ug/lSodium ug/lTin ug/lZinc ug/lEndrin ug/lLindane ug/lMethoxychlor ug/lToxaphene ug/l2,4-D ug/l2,4,5-TPSilvex ug/lPhenol ug/l — — . — — — -~rChloride mg/lSulfate mg/l 7.0/9.0 3.0/4.0 10/16 17/32 27/239Bicarbonate mg/lOil/Grease mg/lRadium ' pci/lGross Alpha pci/l --- --- — — ;Gross Beta pci/lTurbidity TU — — — ...Coliform per 100 mlpH Units 6.0/6.9 5.9/6.4 5.4/6.1 5.2/6.3 3.5/5.7Specific Conductance umnos 41/48 18/21 46/64 90/98 84/460Total Organic Carbon mg/lTotal Organic Halogens mg/lTotal Dissolved Solids mg/lAcidity mg/l 3.0 2.0/3.0 3.0/5.0 1.0/5.0 5.0/91Alkalinity mg/l 3.0/6.0 2.0/5.0 4.0/5.0 2.0/7.0 0.0/3.0Flow Rate gpm 10,735 7,450 25,375

LT = Less than indicated detection limit- Not Analyzed

(a) Tonolli Corporation, RCRA Part B - Vol. II, March 1985 (Quarterly Monitoring 1983-1935)(b) USEPA, 1989d (Sampled on July 3, 1989)(c) Numbers to the left are the lowest recorded values, while numbers to the right are the highest recorded values.

Metals analysis are believed to be total metals

'flf?30/592

TABLE 2-1

Hydraulic Conductivity ValuesTonolli Corporation Superfund Site

Nesquehoning, Pennsylvania

HYDRAULIC HYDRAULICCONDUCTIVITY CONDUCTIVITY

WELL (cm/sec) WELL (cm/sec)

MW-10S 1.03x10-4 MW-10D 4.89 x 10'3MW-11S 1.54x10-2 MW-11D 7.39 x 10'4MW-12S 1.86x10-3 MW-12D 3.29 x 10'3MW-13S 7.98x10-2 MW-13D 6.61 x 10'3MW-14S 2.80x10-3 MW-14D (1)MW-15S 1.08x10-3 MW-15D 1.61x10'3MW-16S 2.60x10-3 MW-16D (2)MW-17S 9.67x10-4 MW-17D 1.08x1Q-3MW-18S 4.84x10-5 MW-18D 3.38 x 10'3MW-19S 5.73x10-3 MW-19D 2.83 x 10'4

Average k = 1.10 x 10'2 Average k = 2.74 x 10'3

Overall Average k = 7.35 x 10'3 cm/sec

(1) No response to slug, hydraulic conductivity value greater than limits of testprocedure.

(2) Monitoring well damaged, hydraulic conductivity testing could not beperformed.

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TABLE 4-8

ROUND 2 BYPRODUCT ANALYTICAL DATATONOLLI CORPORATION SUPERFUND SITE

NESQUEHONING, PENNSYLVANIA

WA-W12 WA-W13 WA-W14 WA-W15 WA-W16 WA-W17MATRIX DESCRIPTION RED-BROWN CRUSHER EXCAVATED SOLIDIFIED DEWATERED DUST

MATERIAL BUILDING SOIL SLUDGE SLUDGE FURNACEDUST AREA

General Chemistry

pH, s.u. 6.30 6.63 6.10 12.4 12.3 7.74TOC, mg/kg 9,500 4,600 3,800 4,200 4,100 8,000Moisture Content, % 1.7 2.8 6.2 27.5 24.5 1.5(as received)

Indicator Metals, mg/kg CRDL

Cadmium 1 —Copper SLead 0.6 2,570 192,000 5,290 19,100 41,300 221,000Zinc 4Arsenic 2 — — —

TCLP Extraction, mg/1

Mercury 0.005 LT 0.005 LT 0.005 LT 0.005 LT 0.005 LT 0.005 LTArsenic 0.5 LT 0.5 LT 0.5 LT 0.5 LT 0.5 LT 0.5 LTSelenium 0.5 LT 0.5 LT 0.5 LT 0.5 LT 0.5 LT 0.5 LTBarium 2 LT 2 LT 2 LT 2 LT 2 LT 2 LTCadmium 0.05 LT 144 1.16 0.05 LT 0.09 33.7Chromium 0.1 LT 0.1 LT 0.1 LT 0.1 LT 0.1 LT 0.1 LTLead 3 LT 57.7 ' 15.4 1.5 1'.5 15.5Silver 0.1 LT 0.1 LT 0.1 LT 0.1 LT 0.1 LT 0.1 LT

TABLE 4-9

ROUND 1 LANDFILL WASTE ANALYTICAL DATATONOLLI CORPORATION SUPERFUND SITE


LTP1-4 LTP2 LTP2 LTP2 LTP3-6.5WHITE BLACK-A BLACK-B

(Duplicate)

MATRIX DESCRIPTION Battery Battery Battery BatteryCasings Sludge Casings Casings Casings

General Chemistry

pH, S.U. 5.84 6.06 6.91 7.31 5.81TOC, mg/kg 2,400 2,900 5,600 3,200 2,700Moisture Content, % (as reo'd) 6.1 37.6 10.5 22.3 27.3Hexavalent Chromium, mg/kg — — — —

Indicator Metals, mg/kgCRDL

Cadmium 1 89.0 44.4 54.1 187 12.1Copper 5 1,920 L 778 L 960 L 4,790 L 146 LLead 0.6 51,100 K 11,200 K 68,300 K 62,800 K 18,500 KMercury 0.2 0.03 B 0.85 0.19 0.23 0.08Zinc 4 1,830 458 1,170 2,770 319Arsenic 2 440 192 1,070 1,140 99.1,Selenium 1 15.0 K 2.4 B 1.4 B 32.2 K 0.9

Additional TAL Metals, mg/kgCRDL

Aluminum 40 — — —Antimony 12 — —Barium 40Beryllium 1 — — —Calcium 1,000Chromium 2 —Cobalt 10Iron 20 — — — —Magnesium 1,000 — — — —Manganese 3 — — — —Nickel 8Potassium 1,000 — — —Silver 2 — — — _ -Sodium 1,000 — -- —Thallium 2 —Vanadium 10 — —Cyanide, Total 2 — — —

3R30I658

TABLE 4-9

ROUND 1 LANDFILL WASTE ANALYTICAL DATATONOLLI CORPORATION SUPERFUND SITE

NESOUEHONING, PENNSYLVANIA


(Duplicate)


TCL Volatiles, ug/kgCRQL

Acetone 10 — — — . —Chloroform 5 — — — : —Ethylbenzene 5 — — — ! —Methylene Chloride 5 — — — : — —Tetrachloroethene 5Toluene 5 — — — —2-Butanone 101,1,1-Trichloroethane 51,1-Dichloroetheno 5 — — — — —Xylenes, Total 5 — —

PAH's, mg/kgCRQL

Naphthalene 0.330 40 10 LT 2 LT 3 LT 30 LTAcenaphthylene 0.330 20 LT 20 LT 2 LT 3 LT 30 LTAcenaphthene 0.330 20 LT 6 LT 2 LT 3 LT 30 LTFluorene 0.330 10 LT 6 LT 2 LT 3 LT 30 LTPhenanthrene 0.330 31 37 0.6 LT 0.6 LT 12Anthracene 0.330 10 LT 2 LT 0.6 LT 0.6 LT 7 LTFluoranthene 0.330 17 60 LT 0.2 LT 0.3 LT 6Pyrene 0.330 15 30 LT 0.2 LT 3.9 7Benzo(a) anthracene 0.330 5.8 2.2 0.01 LT 0.6 LT 1.9Chrysene 0.330 5 LT 7 0.1 LT .0.1 LT 4 LTBenzo(b) fluoranthene 0.330 4 1.1 0.02 LT 0.03 LT 2Benzo(k) fluoranthane 0.330 2 0.51 0.02 LT 0.03 LT 1 LTBenzo(a) pyrene 0.330 3 LT 0.06 LT 0.02 LT 0.5 LT 1 LTDibenzo(a,h) anthracene 0.330 1 LT 0.06 LT 0.02 LT 0.5 LT 1 LTBenzo(g,h,i) perylene 0.330 4 0.5 LT 0.06 LT 1 LT 4 LTIndeno (1,2,3-cd) pyrene 0.330 4 0.2 LT 0.06 LT 1 LT 4 LT

Additional TCL Sorni-Volatiles, mg/kgCRQL

Phenol 0.330 — — — —bis (2-Chloroisopropyl) ether 0.3302-Methylphenol 0.3304-Methylphenoi 0.3302,4 - Dimethylphenol 0.330 -- -- — —2-Methylnaphthalene 0.330Dibenzofuran 0.330Benzoic acid 1.600Nitrobenzene 0.360 — — — — —N-Nitrosodiphenyiamine (1) 0.360 — — — -—Di-n-butylphthalate 0.330Butylbenzylphthalate 0.330 — — — — —bis (2-Ethylhexyl) phthalate 0.330Di-n-octylphthalate 0.330Diethylphthalate 0.3304-Nitrophenol 1.600

TABLE 4-9

ROUND 1 LANDFILL WASTE ANALYTICAL DATATONOLL! CORPORATION SUPERFUND SITE



(Duplicate)


TCL Pesticides/PCBs, ug/kg CRQL

Dieldrin 16 -- — -- — —alpha-Chlordane 80 — — — — —

TCLP Extraction, mg/l

Mercury 0.005 LT 0.005 LT 0.005 LT 0.005 LT 0.005 LTArsenic 0.5 LT J 0.5 LT J 0.6 J 0.5 LT J 0.5 LTSelenium 0.5 LT 0.5 LT 0.5 LT 0.5 LT 0.5 LTBarium 2 LT 2 LT 2 LT 2 LT 2 LTCadmium 0.42 0.22 0.92 0.83 0.25Chromium 0.5 LT 0.5 LT 0.5 LT 0.5 LT 0.5 LTLead 294 J 22.0 J 137 J 93.7 J 177 JSilver 0.1 LT 0.1 LT 0.1 LT 0.1 LT 0.1 LT

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TABLE 4-12

ROUND 1 SEEP AND LANDFILL LEACHATE ANALYTICAL DATATONOLLI CORPORATION SUPERFUND SITE


LI L2 L3 L4 LB L6SEEP LANDFILL SEEP SEEP LANDFILL (DUP. OF L3)

Field Parameters

pH, s.u. 3.04 7.5 3.8 3.96 5.92 3.8

Specific Conductance 429 633 600 393 339 600

Temperature, C 14.1 13.2 12.3 12.9 13.2 12.3Eh 470 142 376 422 54 376

General Chemistry, mg/l

Alkalinity to pH 8.3 1 LT 1 LT 1 LT 1 LT 1 LT 1 LT

Alkalinity to PH 4.5 1 LT 23 1 LT 1 LT 1 LT 1 LT

Acidity to pH 3.7 37 1 LT 2 1 LT 1 LT 1 LT

Acidity to pH 8.3 286 3 153 159 162 160

TSS 740 24 21 4 LT 40 78

TDS 3,080 550 430 3,640 1,930 450

Total Hardness 501 281 126 326 870 127

Chloride 160 5 18 130 55 18

Sulfate 1,800 330 270 2,200 1,300 240

TOC 3.5 6.0 2.2 2.0 3.8 2.2

Hexavalent Chromium . . — 0.005 LT — — — —

Indicator Metals, ug/lCRDL

Cadmium Total 5 61.0 61.4 71.3 34.6 79.1 74.2

Dissolved 5 59.0 37.1 74.7 32.9 72.7 69.9

Copper Total 25 128 7.6 B 23.8 25.2 151 36.5

Dissolved 25 93.6 2.5 U 26.0 30.7 2,5 U 24.3

Lead Total 3 1,380 2,180 71.4 7.5 U 640 87.7

Dissolved 3 83.5 J 316 J 67.3 J 7.5 U 572 J 70.3 J

Mercury Total 0.2 0.44 0.11 B 0.1 U 0.19 B 0.17 B 0.22

Dissolved 0.2 0.12 B» 0.16 B« 0.21 * 2.0 * 0.17 B* 0.11 B*

Zinc Total 20 761 213 606 441 742 620

Dissolved 20 687 105 631 431 1,760 564

Arsenic Total 10 635 39.1 16.1 42 B 49.9 24.3

Dissolved 10 13.4 15.8 4.7 B* 21.5 B 6.4 B* 5.1 B*

Selenium Total 5 23.4 L 1.9 UL 1.9 UL 9.5 UL 9.5 UL 3.1 BL

Dissolved 5 21.4 L 1.9 UL 1.9 UL 9.5 UL 3.1 BL 1.9 UL

TABLE 4-12



LI L2 L3 L4 L5 L6SEEP LANDFILL SEEP SEEP LANDFILL (DUP. OF L3)

Additional TAL Metals, ug/I

CRDL

Aluminum Total 200 — 39.5 BDissolved 200 — 12.0 U

Antimony Total 60 — 85.6

Dissolved 60 — 52.8

Barium Total 200 — 19.9 8Dissolved 200 — 18.7 B

Beryllium Total 5 -- 4.5 UDissolved 5 — 4.5 U

Calcium Total 5,OOO — 106,000 J

Dissolved 5,000 -- 99,100

Chromium Total 10 — 2.5 UDissolved 10 — 2.5 U

Cobalt Total 50 — 19.2 U

Dissolved 50 — 19.2 U

TABLE 4-12




Additional TAL Metals, ug/l

(continued)

CRDL

Iron Total 100 -- 2,120 J —

Dissolved 100 — 274 J

Magnesium Total 5,000 — 2,150 BJ — — — —

Dissolved 5,000 — 2,010 B — — — —

Manganese Total 15 — 2 1 9 J — — — —

Dissolved 15 — 199 — ~-

Nickel Total 40 — 45.6 — — —

Dissolved 40 ~- 36.7 — —Potassium Total 5,000 -- 12,000 — — — —

Dissolved 5,000 — 11,000 — — —

Silver Total 10 — 4.4 B

Dissolved 10 — 4.0 U — —

Sodium Total 5,000 — 20,800 — —

Dissolved 5,000 -- 19,200 — ' — -~

Thallium Total 10 — 2.0 U — — —

Dissolved 10 -- 2.0 U — — — '—

Vanadium Total 50 — 6.0 U — — — —

Dissolved 50 — 6.8 B — — — —

Cyanide, Total 10 — 5.0 U — — —

TCL Volatiles, ug/l

CRQL

Acetone 10 — 7J — — — -~Chloroform 5 — 5 U — — — —Ethylbenzene 5 — 5 U — — — —Methylene Chloride 5 — 5U— ~ —

Tetrachloroethene 5 — - - 5 U — — — —

Toluene 5 — 5 U — — — —

2-Butanone 10 — 10 U — — — ~

1,1,1 - Trichoroethane 5 — 5 U ~ — — —

1,1 - Dichloroethena 5 --- 5 U — — —Xylenes, Total 5 — 5 U — ~ —

1R3oi:683

TABLE 4-12



L1 L2 L3 L4 L5 L6SEEP LANDFILL SEEP SEEP LANDFILL (DUP. OF L3)

PAH's, ug/1

CRQL

Naphthalene 10 10 LT 10 U 10 LT 20 LT 50 LT 20

Acenaphthylene 10 20 LT 10 U 20 LT 40 LT 100 LT 40Acenaphthena 10 20 LT 10 U 20 LT 40 LT 100 LT 40

Fluorene 10 2 LT 10 U 2 LT 4 LT 10 LT 4

Phenanthrene 10 2 LT 10 U 2 LT 4 LT 10 LT 4

Anthracene 10 1 LT 10 U 1 LT 2 LT 5 LT 2

Fluoranthene 10 0.5 LT 10 U 0.5 LT 1 LT 2.5 LT 1

Pyrene 10 2 LT 10 U 2 LT 4 LT 10 LT 4Benzo(a) anthracene 10 0.1 LT 10 U 0.1 LT 0.2 LT 0.5 LT 0.2

Chrysene 10 1 LT 10 U 1 LT 2 LT 5 LT 2

Banzo(b) fluoranthano 10 0.2 LT 10 U 0.2 LT 0.4 LT 1 LT 0.4

Benzo(k) fluoranthene 10 0.1 LT 10 U 0.1 LT 0.2 LT 0.5 LT 0.2

Benzo(a) pyrene 10 0.2 LT 10 U 0.2 LT 0.4 LT 1 LT

Dibenzo(a,h) anthracene 10 0.2 LT 10 U 0.2 LT 0.4 LT 1 LT

Benzo(g,h,i) perylene 10 0.5 LT 10 U 0.5 LT 1 LT 2.5 LT

lndeno(1,2,3-cd)pyreno 10 0.5 LT 10 U 0.5 LT 1LT 2.5 LT

TABLE 4-12




Additional TCL Ssmi-Volatiles, ug/lCRQL

Phenol 10 — 10 U

bis (2-Chloroisopropyl) ether 10 — 10 U

2-Methylphenol 10 — 10 U

4-Methylphenol 10 — 10 U

2,4 - Dimethylphenol 10 — 10 U

2-Methylnaphthalane 10 — 10 U

Dibenzofuran 10 — 10 U

Benzole acid 50 — 50 U

Nitrobenzene 10 — 10 UN-Nitrosodiphenyfamine (1) 10 — 10 UDi-n-butylphthalata 10 — 10 UButylbenzylphthalate 10 — 10 U

bis (2-Ethylhexyl) phthalate 10 — 6 J

Di-n-octylphthalata 10 — 10 U

Diethylphalate 10 — 10 U

4-Nitrophenoi 50 — 50 U

TCL Pesticides/PCB's, ug/l

CRQL

Dieldrin 0.10 ~ 0.1 Ualpha-Chlordane 0.50 — 0.08 J

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TABLE 4-17

ROUND 1 SUMP SEDIMENT ANALYTICAL DATATONOLLI CORPORATION SUPERFUND SITE


SD-SUMP1 SD-SUMP2A SD-SUMP2B SD-SUMP3General Chemistry

pH, s.u. 8.14 6.43 6.38 6.46TOC, mg/kg 7,000 35,000 29,000 29,000Moisture Content, % (as reo'd) 40.1 48.3 43.9 66.0Hexavalent Chromium, mg/kg

Indicator Metals, mg/kgCRDL

Cadmium 1 53.4 247 218 83.7Copper 5 198 2,980 2,340 1,160Lead 0.6 19,000 311,000 243,000 92,000Mercury 0.2 0.37 1.80 1.5 0.82Zinc 4 643 J 1,260 J 974 J 796 JArsenic 2 101 824 694 536Selenium 1 2.1 BK 2.1 BK 2.0 BK 1.3 UK

Additional TAL Metals, mg/kgCRDL

Aluminum 40 — — — ,Antimony 12Barium 40Beryllium 1Calcium 1,000Chromium 2Cobalt 10Iron 20 — —Magnesium 1,000 — — — ._Manganese 3 — — — —Nickel 8Potassium 1,000Silver 2 — . — — :Sodium 1,000Thallium 2Vanadium 10Cyanide, Total 2

TCL Volatiles, mg/kgCRQL

Acetone 10 — —Chloroform 5 — — . — —Ethylbenzena 5 — _Methylene Chloride 5Tetrachloroothene 5Toluene 52-Butanone 101,1,1-Trichloroethane 51,1-Dichloroethene 5Xylenes, Total 5

TABLE 4-17

ROUND 1 SUMP SEDIMENT ANALYTICAL DATATONOLLI CORPORATION SUPERFUND SITE


SD-SUMP1 SD-SUMP2A SD-SUMP2B SD-SUMP3PAH's, mg/kg

CRQLNaphthalene 0.330 10 LT 10 LT 10 LT 20 LTAcenaphthylene 0.330 10 LT 10 LT 10 LT 20 LTAcenaphthene 0.330 10 LT 10 LT 10 LT 20 LTFluorene 0.330 10 LT 10 LT 10 LT 20 LTPhenanthrene 0.330 3 LT 4 LT 4 LT 6 LTAnthracene 0.330 3 LT 4 LT 4 LT 6 LTFluoranthene 0.330 1 1 LT 1 LT 2 LTPyrene 0.330 1 LT 6 LT 2 LT 2 LTBenzo(a) anthracene 0.330 0.1 LT 1.0 LT 0.2 LT 0.1 LTChrysene 0.330 2 LT 1 LT 1 LT 0.9 LTBenzo(b) fluoranthene 0.330 0.4 1.2 1.1 0.6 LTBenzo(k) fluoranthene 0.330 0.1 0.6 LT 0.2 0.2 LTBenzo(a) pyrene 0.330 0.1 LT 0.6 LT 0.2 LT 0.2 LTDibenzo(a.h) anthracene 0.330 0.1 LT 0.6 LT 0.5 LT 0.2 LTBenzo(g,h,i) perylene 0.330 0.3 LT 2 LT 1 LT 0.6 LTIndeno (1,2,3-cd) pyrene 0.330 0.3 LT 2 LT 1 LT 0.6 LT

Additional TCL Semi-Volatiles, mg/kgCRQL

Phenol 0.330bis (2-Chloroisopropyl) ether 0.3302-Methylphenol 0.330 —4-Methylphenol 0.330 — — —2,4 - Dimethylphenol 0.330 --- — — —2-Methylnaphthalene 0.330Dibenzofuran 0.330 . ... ..----— — — .—Benzoic acid 1.600 —Nitrobenzene 0.360 —N-Nitrosodiphenylamine (1) 0.360Di-n-butylphthalate 0.330 —Butylbenzylphtnalate 0.330 —bis (2-Ethylhexyl) phthalate 0.330Di-n-octylphthalate 0.330Diethylphthalata 0.330 — —4-Nitrophenol 1.600

TCL Pesticides/PCBs, ug/kgCRQL

Dieldrin 16alpha-Chlordane 80 — — — —

TCLP Extraction, mg/l

Mercury —ArsenicSelenium — — — —Barium — — ' — —CadmiumChromiumLeadSilver

&R3QI698

TABLE 4-18

RI AIR MONITORING ANALYTICAL DATATONOLLI CORPORATION SUPERFUND SITE


High Volume High Volumo High Volume High VolumeSampler #1 Sampler #2 Sampler #3 Sampler #4

TSP Lead TSP Lead TSP Lead TSP Leadug/M3 ug/M3 ug/M3 ug/M3 ug/M3 ug/M3 ug/M3 ug/M3

Week of:21-0ct-90 21-Oot-90 — — — — ~- — _ _ ;

22-Oct-90 — — ~ — _ _23-Oot-90 — — ~ — — _24-Oct-90 — ... ._ _ _ _ _25-Oct-90 ~ — — — _ _26-Gct-90 23.9 0.00506 15.9 0.20700 12.1 0.01750 12.1 0.0076327-Qct-90 23.0 0.01340 22.6 0.02050 23.9 0.02030 23.9 0.00959

28-Oct-90 23-Oct-90 7.76 0.00180 LT 9.13 0.02380 7.99 0.01190 9.27 0.0106029-Oot-90 11.1 0.00726 9.52 0.20100 16.1 0.02500 16.9 0.0267030-Oot-90 34.3 0.01470 52.9 0.16100 56.5 0.04330 44.5 0.5330031-Oct-90 38.1 0.01690 66.2 0.28500 56.0 0.04650 54.2 0.041701-Nov-90 39.2 0.01470 61.5 0.05710 51.7 0.04570 51.0 0.068102-NOV-90 29.1 0.00297 47.2 0.01260 39.0 0.02500 39.9 0.034003-Nov-90 33.0 0.00604 53.1 0.01950 49.5 0.00942 47.0 0.01470

4-Nov-SO 4-NOV-90 29.7 0.00807 39.9 0.10300 38.1 0.00973 38.0 0.011605-Nov-90 32.1 0.04260 69.6 1.83000 41.0 0.05300 4O.S 0.084106-NOV-90 7.77 0.00288 14.3 0.06720 12.2 0.02950 10.5 0.030007-Nov-90 13.1 0.00170 LT 31.3 0.13100 15.8 0.02300 33.9 0.02520S-Nov-90 17 0.01140 15.1 0.06770 14.2 0.00297 13.4 0.0018 LT9-Nov-90 20.0 0.00846 22.0 0.10400 18.2 0.00771 18.6 0.0076010-Nov-9O 186.0 0.00170 7.4 0.00780 6.19 0.00180 LT 6.19 0.00462

11-Nov-90 11-Nov-90 6.03 0.00170 LT 7.11 0.01750 4.97 0.02420 6.5O 0.0591012-Nov-90 6.08 0.00160 LT 8.34 0.07580 8.09 0.05900 8.08 0.0593013-Nov-90 15.2 0.01050 13.1 0.06090 9.95 0.05220 8.84 0.0567014-Nov-90 17.6 0.01110 25.9 0.07540 18.8 0.03780 19.1 0.0246015-Nov-90 25.3 0.02500 33.3 0.05320 36 0.21500 99.5 0.0995016-Nov-90 21.8 0.00291 30.7 0.04070 28.9 0.02030 27.5 0.0381017-Nov-.90 6.07 0.00486 7.08 0.04670 31.6 0.00503 9.15 0.00498

18-Nov-90 18-Nov-90 8.77 0.00279 10.40 0.02220 10.90 0.00584 12.70 0.0046919-Nov-90 12.5 0.00451 19.2 0.08330 15.1 0.01640 16.5 0.0117020-Nov-90 17.50 0.00449 28.60 0.16900 29.60 0.04110 31.6O 0.0257021-Nov-90 24.9 0.01280 35.8 0.04250 35.7 0.01790 31.3 0.1770022-Nov-90 46.30 0.00916 46.80 0.01590 49.00 0.00852 49.10 0.0083523-Nov-90 20.7 0.00180 LT 23.9 0.00704 25.8 0.00190 LT 25.6 0.0024524-Nov-90 12.80 0.00160 LT 15.80 0.00251 17.10 0.00170 LT 16.6O 0.00225

25-Nov-90 25-Nov-90 21.0 0.00180 LT 22.4 0.00180 LT 23.8 0.00369 23.7 0.0091226-Nov-90 31.70 0.01420 43.30 0.11900 35.60 0.01880 35.6O 0.0199027-Nov-90 36.6 0.00180 LT 43.8 0.02400 50.3 0.01330 45.7 0.0122028-Nov-SO 18.90 0.00347 20.70 0.01830 19.80 0.01320 20.0 0.0106029-Nov-90 10.7 0.00347 11.7 0.01240 10.9 0.00991 10.9 0.0075930-Nov-90 15.70 0.00277 20.60 0.00467 22.20 0.00350 471.00 0.002881-Dec-90 78.7 0.00287 31.3 0.00721 341.0 0.00415 31.3 0.00470

2-Oeo-90 2-Deo-90 13.00 0.01730 14.00 0.02340 15.20 0.00415 88.20 0.00294*3-Oec-90 96.00 0.00234 69.3 0.00693 67.3 0.00180 LT 63.4 0.00180 LT4-Oec-90 7.01 0.00170 LT 11.10 0.04180 8.50 0.03330 8.02 0.050505-Deo-90 11.0 0.00162 13.5 0.01010 — — 1.11 0.008326-Deo-90 16.5 0.00307 20.2 0.00509 21.7 0.00581 20.7 0.004987-Dec-90 20.5 0.00551 23.1 0.01160 24.7 0.01260 24.8 0.011308-Dec-90 14.0 0.00442 15.2 0.01160 16.2 0.00845 16.0 0.00847

9-Dec-90 g-Dsc-90 18.3 0.00467 20.7 0.01870 23.0 0.01980 22.4 0.0168010-Dec-90 12.6 0.00290 11.8 0.05970 13.1 0.01430 13.3 0.0116011-Deo-90 22.4 0.01110 25.6 0.01690 26.5 0.01000 25.4 0.0102012-Dec-90 — — 201 0.01510 45.8 0.01640 43.3 O.Olfbi? O H J13-D6C-90 --- «- 12.1 0.01250 12.6 0.00904 13.3 0.01400* U '

TABLE 4-18

Rl AIR MONITORING ANALYTICAL DATA, TONOLLI CORPORATION SUPERFUND SITE


High Volume High Volume High Volume High VolumeSampler #1 Sampler #2 Sampler #3 Sampler #4

TSP Lead TSP Lead TSP Lead TSP Leadug/M3 ug/M3 ug;M3 uq/M3 ug/M3 ug/M3 ug/M3 uq/M3

14-Dec-90 19.4 0.00883 23.2 0.01250 24.1 0.00223 22.1 0.0068315-Dec-90 12.1 0.00318 12.3 0.00482 13.0 0.00430 11.9 0.00219

16-Dec-90 16-Qec-90 11.2 0.00190 LT — — 12.1 0.00190 LT 11.7 0.00190 LT17-0ec-90 18.8 0.00364 — — 23.4 0.00680 22.0 0.0042718-Dec-90 10.9 0.00459 11.8 0.00576 11.7 0.00234 11.2 0.0017719-Dec-90 8.79 0.00180 LT 9.39 0.00432 11.6 0.00135 10.5 0.00180 LT20-Deo-90 14.3 0.00988 14.6 0.04470 14.1 0.00550 13.6 0.0045721-Dec-90 7.62 0.00280 8.22 0.0016 LT 9.05 0.00464 8.3 0.0029822-Deo-90 71.7 0.0017 LT 12.1 0.00257 12.8 0.00556 12.3 0.00171

23-Deo-90 23-Dec-90 5.95 0.0018 LT 5.29 0.0016 LT 5.64 0.0018 LT 5.72 0.0060224-Dec-90 10.7 0.0017 LT 10.7 0.00528 12.4 0.00598 12.3 0.0059525-Dec-90 15.4 0.00265 78.2 0.00620 20.1 0.01050 18.6 0.0079726-Deo-90 14.7 0.0017 LT 14.0 0.0016 LT 16.5 0.0017 LT 16.7 0.0017 LT27-Deo-90 10.9 0.00455 13.8 0.01660 17.4 0.00720 15.3 0.0057228-Dec-90 12.7 0.0018 LT 11.3 0.00202 12.5 0.00334 12.5 0.0017529-Oec-90 31.0 0.00297 33.4 0.00320 191 0.00475 30O 0.00545

30-Dao-90 30-0ec-90 7.62 0.0016 LT 8.03 0.00144 10.5 0.00420 9.51 0.0016331-Dec-90 8.29 0.0019 LT 8.36 0.0019 LT 10.1 0.0019 LT 9.65 0.0019 LT1-Jan-91 19.1 0.00290 20.5 0.00454 23.3 0.00292 22.4 0.00176 LT2-Jan-91 21.2 0.00487 22.9 0.00748 25.1 0.00435 24.3 0.006173-Jan-91 13.9 0.00177 14.8 0.00489 1S.9 0.00477 16.4 0.005494-Jan-91 17.5 0.00316 20.5 0.00759 23.7 0.00783 23.0 0.006335-Jan-91 25.5 0.00797 27.5 0.01230 32.3 0.00972 28.6 0.00828

6-Jan-91 6-Jan-91 18.8 0.00290 17.5 0.00428 18.9 0.00411 19.3 0.003007-Jan-91 14.6 0.01230 13.3 0.01470 14.3 0.00400 15.1 0.003528-Jan-91 19.6 0.02900 15.8 0.03260 19.0 0.00370 21.3 0.003779-Jan-91 15.1 0.00171 LT 16.2 0.00410 17.2 0.00448 18.0 0.0029310-Jan-91 29.1 0.05320 997 0.19600 384 0.00309 23.5 0.0031211-Jan-9.1 2080 0.02650 12.5 0.02220 14.1 0.00149 LT 13.2 O.OO15412-Jan-91 15.7 0.00274 14.1 0.00495 15.5 0.00275 15.3 0.00437

13-Jan-91 13-.Jan-91 12.1 0.00302 15.1 0.00452 18.9 0.00623 18.0 0.0050514-Jan-91 30.7 0.00533 32.8 0.00493 36.2 0.00542 35.1 0.0043915-Jan-91 103 0.01570 131 0.01690 203 0.01860 344 0.0173016-Jan-91 8.3 0.00233 10.7 0.00212 12.6 0.00292 11.4 0.0029817-Jan-91 11.8 0.00178 LT 12.7 0.03110 11.3 0.03280 14.3 0.0629018-Jan-91 14.9 0.00164 LT 16.6 0.02140 16.9 0.02400 17.6 0.0330019-Jan-91 17.4 0.00327 23.6 0.00512 23.7 0.00719 23.2 0.00573

20-Jan-91 20-Jan-91 16.6 0.00313 15.5 0.00158 16.7 0.00184 16.S 0.0031621-Jan-91 12.8 0.00231 15.0 0.00511 15.0 0.00571 13.9 0.0029022-Jan-91 20.6 0.00550 22.2 0.00732 25.2 0.00980 25.2 0.0084423-Jan-91 24.2 0.00255 25.8 0.00926 27.4 0.00760 29.0 0.0093924-Jan-91 13.3 0.00184 LT 13.7 0.00952 12.6 0.00870 13.1 0.0152025-Jan-91 18.8 0.00161 22.3 0.00497 22.7 0.00722 20.6 0.0070326-Jan-91 26.2 0.00250 28.3 0.00833 27.2 0.00513 — —

27-Jan-90 27-Jan-91 22.5 0.00176 22.7 0.00435 21.6 0.00294 20.7 0.003032S-Jan-91 15.6 0.00293 20.4 0.00709 22.4 0.00754 19.4 0.0049329-Jan-91 30.3 0.01480 34.8 0.01330 36.8 0.01490 34.0 0.0152030-Jan-91 21.2 0.00612 22.1 0.01680 24.0 0.02280 22.5 0.0303031-Jan-91 18.5 0.00169 LT 20.0 0.01970 18.3 0.01880 18.2 0.037101-Feb-91 25.3 0.00531 28.4 0.00492 29.6 0.00941 28.S 0.00828

TABLE 4-19

DATA QUALIFIER CODESFOR INORGANIC DATA VALIDATION

COOES RELATED TO IDENTIFICATION(confidence concerning presence or absence of analytes):

(NO CODE) * Confirmed identification.

U = Not detected. The associated number indicates approximatesample concentration necessary to be detected.

B = Reported value obtained from a reading that was less than theContract Required Detection Limit but greater than or equal to theInstrument Detection Limit.

Not detected substantially above the level reported in laboratoryor field blanks.

R = Unreliable result. Analyte may or may not be present in thesample.

CODES RELATED TO QUANTITATION(can be used for both positive results and sample quantitation limits):

J = Analyte Present. Reported value may not be accurate or precise.

K = Analyte present. Reported value may be biased high. Actualvalue is expected to be lower.

L = Analyte present. Reported value may be biased low. Actualvalue is expected to be higher.

UJ = Not detected, quantitation limit may be inaccurate or imprecise.

UL = Not detected, quantitation limit may be biased low.

LT = Less than quantitation limit.

TABLE 4-20

DATA QUALIFIER COOESFOR ORGANIC DATA VALIDATION

COOES RELATING TO IDENTIFICATION(confidence concerning presence or absence of compounds):

(NO CODE) = Confirmed identification.

U = Not detected. The associated number indicates approximatesample concentration necessary to be detected.

B « Compound was detected in laboratory or field blank.

= Not detected substantially above the level reported in laboratoryor field blanks.

R = Unreliable result. Analyte may or may not be present in thesample.

N = Tentative identification. Analyte is considered to be present.Special methods may be needed to confirm its presence orabsence in future sampling efforts.

CODES RELATED TO QUANTITATIOM(can be used for both positive results and sample quantitation limits):

J = Anaiyte present. Reported value may not be accurate or precise.

K = Analyte present. Reported value may be biased high. Actualvalue is expected to be lower.

L = Analyte present. Reported value may be biased low. Actualvalue is expected to be higher.

UJ = Not detected, quantitation limit may be inaccurate or imprecise.

UL = Not detected, quantitation limit may be biased low.

LT = Less than quantitation limit.

TABLE 5-1

Results of Cation Exchange Capacity AnalysisTonolli Corporation Superfund Site

Nesquehoning, Pennsylvania

Cation ExchangeSample No. Soil Type Capacity (mg/D* (mg/IOOg)4

TONO-SO-S2-6 Alluvium 32 3.5TONO-SO-S38-5 Alluvium 31 3.4TONO-SO-S39-5 Alluvium 46 5.0

TONO-SO-S36-9 Mine Spoil 22 2.4TONO-SO-S44-3 Mine Spoil 33 3.6TONO-SO-CEC6-2 Mine Spoil 34 3.7

* Method SW 846-9081, Detection Limit of 5 mg/l of Na +

** Calculated from laboratory data assuming 4 g of soil extracted for a Na +into a final volume of 100 mi.

flR30i703

TABLE 7-1

GENERAL LIST OF ARARS AND TBCsFOR TONOLLI CORPORATION SITE

RESOURCE CONSERVATION AND RECOVERY ACT WASTE REGULATIONS

• Generator Requirements• Transportation Requirements• Treatment, Storage and Disposal Requirements

Groundwater Protection- Closure and Post-Closure Action- Surface Impoundments- Waste Piles

Land TreatmentLandfills

- Incinerators• Land Disposal Restrictions

SAFE DRINKING WATER ACT

• Maximum Contaminant Levels• Maximum Contaminant Level Goals• Secondary Maximum Contaminant Levels• National Interim Primary Drinking Water

Standards• Injection Well Program

CLEAN WATER ACT

• Ambient Water Quality Criteria for theProtection of Aquatic Life

• Ambient Water Quality Criteria for theProtection of Human Health

• National Pollutant Discharge Elimination SystemRequirements

• Dredge and Fill Requirements

THE CLEAN AIR ACT

• National Ambient Air Quality Standards• National Emissions Standards for Hazardous Air

Pollutants• New Source Performance Standards

I of 2


STANDARDS FOR TOXICS AND PESTICIDES

• Toxic Substances Control Act• Federal Insecticide, Fungicide, And Rodenticide

Act

OTHER RESOURCE PROTECTION STATUTES

• National Historic Preservation Act• Archeological and Historic Preservation Act• Endangered Species Act• Wild and Scenic Rivers Act• Fish and Wildlife Coordination Act• Coastal Zone Management Act• Wilderness Act

OCCUPATIONAL HEALTH AND SAFETY ADMINISTRATION REQUIREMENTS

STATE ENVIRONMENTAL REQUIREMENTS

• Ground Water and Surface Water- Pennsylvania Clean Streams Law- Pennsylvania Safe Drinking Water Act- Pennsylvania Water Resources Regulations- Pennsylvania Discharge Eliminator System- Pennsylvania Water Quality Standards

• Solid Waste- Pennsylvania Solid Waste Management Act- Pennsylvania Solid Waste - Resource

Recovery Development Act- Pennsylvania Hazardous Sites Cleanup Act- Pennsylvania Solid Waste Regulations- Pennsylvania Hazardous Waste Regulations

• Air Pollutants- Pennsylvania Air Pollution Control Act- Pennsylvania Air Pollution Control

Regulations

2 of 2

TABLE 7-2

CHEMICAL-SPECIFIC ARARS AND TBCS FOR OTHER THANGROUNDWATER AND SURFACE WATER

Requirement/Criteria Constituent Medium Criteria

ARARs

RCRA Action Levels Arsenic Air 2.32 x 10'4 ug/m3Cadmium Air 4.50 x 10-4 ug/m3

RCRA ToxicityCharacteristic Arsenic Soil/Waste 5.0 mg/l

Cadmium Soil/Waste 1.0 mg/lLead Soil/Waste 5.0 mg/l

Clean Air Act NAAQS Lead Air 1.5 ug/m3

TB.Cs

Proposed RCRA Action Arsenic Soil 80 mg/kgLevel Air 7x10'5 mg/m3

Cadmium Soil 40 mg/kgAir 6x10'4 mg/m3

Proposed RCRA Arsenic Air 7x10'3 mg/m3MaximumProtection Standards

Cadmium Air 6x10'2 mg/m3

Clean Air Act NAAQS Lead Air 1.5 ug/m3RfD Arsenic 3 x 10'4 mg/kg/day

Cadmium 5 x 10'4 mg/kg/day

CSF (inhalation) Arsenic 50 (mg/kg/day)-1Cadmium 6.1 (mg/kg/day)-1

CDC Blood Lead Levelof Concern for YoungChildren Lead Blood 10-15ug/dl

OERR Cleanup Lead Soil 500-1,000 mg/kgRecommendation

Iof2flR30J706


TABLE 7-2 FOOTNOTES

OERR Cleanup Recommendation - Found in "Interim Guidance onEstablishing Soil Lead Cleanup Levels at Superfund Sites." Issued asOSWER Directive No. 9355.4-0.

RCRA Action Level - Level which may necessitate corrective action at aRCRA regulated unit. For arsenic and cadmium these levels are based oncarcinogenic effects due to exposure via the inhalation pathway. Source:RCRA Facility Investigation Guidance (USEPA, 1989)

RCRA Toxicity Characteristic - Based on concentrations resulting from theToxicity Characteristic Leachate Procedures (TCLP).

Proposed RCRA Action Level - Action levels are levels proposed by theUSEPA to be indicators for protection of human health and the environment.Exceedance of action levels can trigger a corrective measure study. Source:Proposed Rule 55 Federal Register 30798, July 27, 1990.

Proposed RCRA Maximum Protection Standards - The upper limit of therange of concentrations for establishing protection standards forcarcinogens. Source: Proposed Rule 55 Federal Register 30798, July 27,1990.

Clean Air Act NAAQS - Natural Ambient Air Quality Standards (40 CFR 50).

RfD - Chronic Reference Dose. Source: arsenic - IRIS; cadmium - HEAST.

CSF (inhalation) - Cancer Slope Factore. Source: HEAST.

CDC Blood Lead Level of Concern - Concentration of lead in the blood thathas been determined by the Centers for Disease Control to be ofneurological concern in young children.

2 of 2

TABLE 7-3

ARARS AND TBCS FOR GROUNDWATER AND SURFACE WATER

Requirement/Citation Arsenic Level Cadmium Lead Level(mg/l) Level (ma/I) (mg/l)

ARARs

MCL 0.05 0.005 0.015<a>

NIPDWR 0.05 0.01 0.05

AWQC Human Health 2.5 x 10'5 0.01 0.05(dw)AWQC Human Health 2.2 x 10'6 0.01 0.05(dw/ao)AWQC Aquatic Life 0.36 0.0039 0.082(acute)AWQC Aquatic Life 0.19 0.0011 0.0032(chronic)PA WQC Aquatic Life 0.19 0.0011 0.0032

PA WQC Human Health 0.05 0.01 0.05

Proposed MCL _ Jb> . _ _ 0.005

MCLG __ 0.005 0

Proposed MCLG 0.05

Drinking Water 0.015 0.018Equivalent Level

Drinking Water __ 0.005Health Advisories

OERR Cleanup __ __ 0.015Recommendation

Iof3


TABLE 7-3 FOOTNOTES

MCL - Maximum contaminant levels as listed in the National PrimaryDrinking Water Regulations. Sources: arsenic and lead - Integrated RiskInformation System (IRIS); cadmium - 56 Federal Register 3526.

Proposed MCL -Proposed by USEPA Office of Drinking Water, Criteria andStandards Division. Source: United States Environmental ProtectionAgency, Fact Sheet - Drinking Water Regulations Under the Safe DrinkingWater Act, Criteria and Standards Division, Office of Drinking Water,Washington, D.C., May 1990.

MCLG - Maximum Contaminant Level Goal. Source: IRIS.

Proposed MCLG - Proposed by USEPA Office of Drinking Water, Criteria andStandards Division. Source: IRIS.

NIPDWR - National Interim Primary Drinking Water Regulations promulgatedunder the SWDA. Source: United States Environmental Protection AgencyDrinking Water Regulations and Health Advisories, Office of Drinking Water,Washington, D.C., April 1990.

Drinking Water Equivalent Levels - A lifetime exposure concentrationprotective of adverse, non-cancer health effects, that assumes all of theexposure to a contaminant is from a drinking water source. Source: Sameas for NIPDWR.

Drinking Water Health Advisories - USEPA Office of Drinking Water HealthAdvisories. The various advisory levels include different exposure durationsand both child and adult receptors. No health advisory levels were availablefor arsenic or lead. The value of 0.005 mg/l is the longer-term healthadvisory for a 10 kg child and the lifetime health advisory for a 70 kg adult.The one-day and ten-day health advisory level for a child is 0.04 mg/l; thelonger-term health advisory for an adult is 0.02 mg/l. Source: Same as forNIPDWR.

AWQC Human Health - Clean Water Act Ambient Water Quality Criteriaprotective to human health. (DW): Based on exposure via ingestion ofdrinking water only. (DW/AO): Based on exposure via ingestion of drinkingwater and aquatic organisms. Source: 45 Federal Register 79318-79379.

2 of 3

AR30I709


AWQC Aquatic Life - Clean Water Act Ambient Water Quality Criteria.Concentration for protection of aquatic life to acute and chronic toxicity.Source: United States Environmental Protection Agency, 1988, Guidanceon Remedial Actions for Contaminated Ground Water at Superfund Sites,Office of Emergency and Remedial Response, Washington, D.C.,EPA/540/G-88/003.

OERR Cleanup Recommendation - Office of Emergency and RemedialResponse and Office of Waste Programs Enforcement cleanup level for leadin groundwater at Superfund Sites.

PA WQC Aquatic Life - Pennsylvania Water Quality Criteria concentration forprotection of aquatic life to chronic toxicity. This value supposes amaximum continuous concentration. Source: PA Code, Title 25, Chapter16.

PA WQC Human Health - Pennsylvania Water Quality Criteria concentrationsfor protection of human health. Source: PA code, Title 25, Chapter 16.

(a) USEPA is promulgating final rule NPDWRs for lead in drinking waterwhich require treatment technologies and an action level of 0.015 mg/lapplicable to small and medium-sized drinking water systems. The finalNPDWR states that no more than 10 percent of the samples collected fromone of these systems may exceed the action level (56 Federal Register26460).

(b) " " means not available.

3 of 3 ^30/7/0

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FIGURE DEPICTS ISOPLETHS OF MODELED MODELED AMBIENTAMBIENT LEAD CONCENTRATIONS (ug/M3) FOR LEAD CONCENTRATIONS

TONOLLI CORPORATION SUPERFUND SITENESQUEHONING, PENNSYLVANIA

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