the 30th annual conference on thermal analysis … · the 30th annual conference on thermal...

PROCEEDINGS OF

The 30th Annual Conference on

Thermal Analysis and ApplicationsUNIVERS TATS&Bu

HANNOVER

TECHNISCHEINFQRMATiONSBIBUOTHEK

^September 23-25/2002Pittsburgh, Pennsylvania, U.S.A.

SPONSORED BY

UB/TIB Hannover123 324 866

89OO

Editor: Keith J. KocibaThe Lubrizol Corporation

Assistant Editor: Barbara J. KocibaB&K Publishing

THIRTBETH CONFERENCEOF THE

NORTH AMERICAN THERMAL ANALYSISSOCIETY

SEPTEMBER 23 - 25,2002The Pittsburgh City Center Marriott, Pittsburgh, Pennsylvania

MONDAY MORNING

September 23,2002

OPENING SESSION

SALONS 2 & 3

8:00 Opening Remarks

PLENARY LECTURE

8:20 Thermodynamics and Kinetics introduced throughCalorimetry, Anthony E Beezer, Andrew C.Moiris, KojiUrakami, Joseph A Connor, p. 27

9:20 Technical sessions begin

POROSIMETRY AND NANOMATERIALS

SALON 4; Dr. Richard A. Vaia presiding

9:20 Combinatorial Characterization of PolymericNanomaterials, Karim, Alamgir, Amis, Eric J.;p. 31

10:00 Nano-Cluster Size Distribution Determination of a PolymerElectrolyte Using DSC, Kazuhiko Ishikiriyama*, YukikoImaishi, Gen Katagiri, Koichi Takizawa, Akihusa Hagiwara;p. 32

10:20 Nanoporous Alumina Membrane Studied by ThermalAnalysis and XPS, Riko Ozao*, Hirohisa Yoshida, TakeshiInada, Moyuru Ochiai;/?. 37

10:40 Break

11:00 Study of Porous Materials Using TG with Automated GasMixing Capability, Dun Chen;/?. 42

11:20 The Study of Mesoporous Carbons Deposited with Silica byThermogravimetric Analysis (TGA), Doris Zimmerman,Mietiek Jaroniec, Roger K. Gilpin; p. 43

11:40 Session adjourns

NEW FRONTIERS IN THERMAL ANALYSIS

CITY CENTER A; Prof. James Seferis and Dr. R. Bruce Prime presiding

9:20 The Development of the Simultaneous Differential ScanningCalorimetry / Synchrotron Powder X-ray DiffractionMethod, Dusan Lexa;/?. 49

9:40 Extending Differential Scanning Calorimetry to IncludeNon-Contact Yibrational Spectroscopy and ThermalExpansion Analyses, Oana R. Dumitrescu, Crispin Doyle andGerard F. Fernando; p. 52

10:00 Thermally Assisted Nano-Sampling Combined with NearField FTIR Spectroscopy, L. Bozec, L. Gonon, A. Hammiche,F. Merrier, H. M. Pollock and M. Reading; p. 58

10:20 The Measurement of Dynamic Mechanical or RheologicalProperties on a Small Scale as a Function of TemperatureUsing Scanning Probe Microscopy, M. Reading and D.Grandy;/?. 62

10:40 Break

11:00 Thermal Analysis of Thin Film Materials UsingNanocalorimetry, Leslie H. Allen* and Eric A. Olson;/?. 64

11:40 Thermal Analysis of Nanogram Quantities Using aMicromechanical Cantilever Sensor, Rfldiger Berger* ,Jan-Henning Fabian;/?. 68


POLYMERS

CITY CENTER B; Dr. Manika Varma-Nair presiding

9:20 Kinetics of melting in polymers; different states of melt andits influence on physical properties, S. Rastogi and DR.Lippits;/?. 74

10:00 Morphological Studies of botactic Polypropylene* subjectto Isothermal Melting Kinetics, R. G. Alamo, I.L. Hosier, W.T.Huang;/?. 75

10:20 Break

10:40 Thermal Stability of Crystals during PolymerCrystallization, Andreas Wurm, Christoph Schick;/?. 76

11:00 Hard and Soft Confinement Effects on Nano-confinedPolymer Crystallization in Cylindrical Mesophases, Lei Zhu,Brion R. Mimnaugh, Ping Huang, William Y. Chen, Qing Ge,Roderic P. Quirk, and Stephen Z. D. Cheng, Edwin L. Thomas,Bernard Lotz, Benjamin S. Hsiao, Fengji Yeh, and Lizhi Liu;p. 77

11:20 Crystallization of a Nonracemic Chiral Main-Chain liquidCrystalline Polyester Confined by Its Smectk LayerStructure, Shi Tin, X3n Weng, Feng Bai, Frank W. Harris andStephenZ. D. Cheng;/?. 82

11:40 Estimating the Activation Energy for NonisothermalCrystallization of Polymer Melts, Sergey VyazovJrin, NicolasSbirrazzuoli;/?. 88

12:00 Effect of Compressed COt on Phase Behavior of IsotacticPolypropylene, Manika Varma-Nair, Paul Y. Handa, Aspy K.Mehta and Pawan Agarwal; p. 89


PHARMACEUTICALS AND BIOLOGICAL APPLICATIONS

MARQUIS A; Prof. Kenneth Alexander presiding

9:20 Methodology for Thermal Analysis of Excipients, R. BruceCassel, Alan T. Riga and Brian Biddlecom;/?. 90

9:40 Solvent Mediated Pharmaceutical Crystal Growth RateStudies, Imre M. Vitez*, Qi Gao, Mark Liu, Gary McGeorge,Larry Parker, Ray Scaringe, Shawn Yin; p. 96

10:00 Activity of Drugs in Transdermal Patches by DielectricThermal Analysis, Alan T. Riga and Kenneth S. Alexander;p.102

10:20 Break

10:40 Rheological Analysis of Human Biological Fluids:Application of Viscodastic Transformations, Steven R.Aubuchon, Fred A. Mazzeo, Bruce K. Rubin; p. 106

11:00 Dielectric, Shear and Heat Capacity Spectroscopy in theGlass Transition Range of Oligosaccharides, Dana Meissner,Dmytro Sukhorukov, Sergey Adamovsky, Andreas Wurm,Juergen Einfeldt, Christoph Schick;/?. 112

11:20 Determination of the glass transition temperature (Tg) forvarious grades of microcrystalline cellulose (mcc) and theeffect of absorbed moisture on this parameter, SumitMajumdar, Kenneth S. Alexander*, Alan T. Riga;/?. 118

11:40 Dielectric Thermal Analysis and DSC of Liquid and SolidPharmaceutical Excipients, Gene Pan, Alan T. Riga, Wei PingPan and Kenneth Alexander; p. 124


12:20 -1:20 Lunch

MONDAY AFTERNOONSeptember 23, 2002

POSTER SUMMARY PRESENTATIONS

SALONS 2& 3

1:20 - 2:30 During this time, all poster authors will present a brief summaryof their poster. Summaries will be 2-3 minutes each. Theobjective of this session is to give more publicity to each posterand simultaneously help conference attendees identify theposters they would most like to visit.

2:30 Technical sessions resume

POROSIMETRY AND NANOMATERIALS

SALON 4; Dr. Richard A. Vaia presiding

2:30 Biological Signal Transduction Using Composite Films,Lawrence L. Brott, Matthew Burke, Rajesh R. Naik, and MorleyO. Stone;/?. 130

3:10 An Investigation of Polymer Nanocomposite AblativesCharacterization, Joseph H. Koo, Joe T. Polidan, Marietta B.Fernandez, and Alan V. Bray;/?. 131

3:50 Break

4:10 Thermal Stability of Cationic Surfactants Modified LayeredSilicates, Wei Xie, Nathan Whitery, Wei-Ping Pan; p. 137

4:30 Crystallization of Polymers in Confined Environments:Structural Development of Semi-CrystallinePolymer-Layered Silicate Nanocomposites, Richard A. Vaia,Derek M. Lincoln, Zhi-Gang Wang, Benjamin S. Hsiao,RamananKrishnamoorti;/>. 143

4:50 Thermomechanical and Chemical Characterization ofAnhydride-Cured Epoxy/Clay Nanocomposites, HiroakiMryagawa, Michael J. Rich, Lawrence T. Drzal; p. 144

5:10 End of session

NEW FRONTIERS IN THERMAL ANALYSIS

CITY CENTER A; Prof. James Seferis and Dr. R. Bruce Prime presiding

2:30 Rapid Thermal Analysis, James Bennett; p. 150

3:10 A New Thermal Analysis Instrument with SimultaneousIsotropic Stress Measurement, G.B. McKenna, Williams

3:50 Break

4:10 A New Instrument for Measuring Isotropic StressDevelopment and Reaction Kinetics for ThermosettingResins, Mikhail Merzlyakov, Yan Meng, Sindee L. Simon,Gregory B. McKenna;/?. 151

4:30 Visualization of Polymeric Nanoscales ThroughThennoanarytical Techniques, E. Williams and J. C. Seferis,C. Whtman and G. Parker, p. 157


POLYMERS


2:30 Rheological Techniques for the Determination ofExtensional Viscosity of Polymers, Nafaa Mekhilef;/?. 158

3:10 Evolution of the Characteristic Relaxation Time for Volumeof Polystyrene, Paul Bernazzani and Sindee L. Simon;/?. 159

3:30 Break

3:50 New Development of Differential Scanning Calorimetry:HyperDSC™ and Its Applications, Lin Li, Tim Mann andSvenjaGoth;/?. 166

4:10 Effect of Entanglement Concentration on Tg in PolystyreneSamples, Paul Bernazzani 1, Sindee L. Simon, Don J. Plazek,KiaL.Ngai;/?. 772

4:30 Rheological Evaluation of Thermosetting Urethane Sealants,Steven R. Aubuchon and Fred A. Mazzeo;/?. 178

4:50 The Effect of Cure Conditions on Mechanical Properties ofa Rubber-Modified Epoxy Resin, Bobby Russell and RichardP.Chartoff;p. 183




2:30 TMDSC Study Of Phase Transformations in ShapeMemory and Superelastk Nickel-Titanium OrthodonticWires, William A. Brantley*, Masahiro Iijima and Thomas HGrentzer;/?. 184

2:50 Effects of Measurement Time and Viscosity on DynamicMechanical Analysis of Two Types of Dental ElastomericImpression Materials, William A. Brantley*, Jeannie M.Vickery and Thomas H. Grentzer, p. 190

3:10 The Investigation of Thermal Properties of Biphasic PorousCalcium Phosphate Ceramics as Bone Substitute, J.S. Lee;p. 196

3:30 Break

3:50 Concurrent Use of Thermal Analysis and X-ray PowderDiffraction to Characterize Hydration States, Michael L.Dicks, Donald M. Parsons, and Nancy L. Redman-Furey; p. 197

4:10 Thermoanalytkal Characterization of the Hydration Statesof Risedronate, Nancy L. Redman-Furey*. Wendy J. Collinsand Matthew A. Burgin; p. 733

4:30 Optimizing the Experimental Conditions and determiningthe Bound Water Associated with Commercially availablesuspensions of Milk of Magnesia, Pallabi Mitra, Kenneth S.Alexander, Alan T. Riga; p. 203

4:50 Evaluation of bound water in flocculated systems of pumiceusing DSC Experiments, Kavitha Bhasi, Kenneth S. Alexander,Alan T.Riga; p. 209


MONDAY EVENINGSeptember 23, 2002

5:15 - 6:15 NATAS BUSINESS MEETING - All are welcome to attendSalons 2 & 3

POSTER SESSION, 6:15-7:45

GRAND BALLROOM FOYER; Dr. Thomas Ramotowsld presiding

P-l Development of a TGA-Raman System, Corey D. DuBois, Wendy J.Collins, Matthew A. Burgin, R. Thomas Cambron and Nancy L.Redman-Furey;/?. 214

P-2 A Simultaneous TG-DTA Study of the Thermal Decomposition of2-Hydroxybenzoic Acid, 2-Carboxyphenyl Ester, O. Shulga and JeffreyDunn;/?. 220

P-3 Alkylthiol Monolayer Formation On gold; Gas Sorption In PolymerFilms; Water Uptake in Pharmaceutical Coatings: Some Applicationsof Quartz Crystal Microbalance/Heat Conduction Calorimetry, AllanL. Smith, S. Rose Mulligan, J. Tian, J. Riggs, and K. Thompson;/?. 227

P-4 Two glass transitions in sucrose/water glasses: the thermallystimulated current study, George Collins, Avani K. Patel, Renuka D.Reddy, Evgenyi Y. Shalaev;/>. 222

P-5 Effect of Isophthalate Copoly mer (IPA) on the Crystallization of Poly(Trimethylene Therephthalate), (PTT), Olvera, Juana-Maria; Chuah,Hoe H.; Grebowicz, Janusz S.;/?. 223

P-6 Thermal Behavior and Morphology of Liquid Crystalline Polymersusing Temperature Modulated DSC and AFM, William G. Kampert,Bryan B. Sauer, andR. Scott McLean;/?. 224

P-7 Phase Morphology and Crystal Orientation Changes inNano-Confined Lamellae of PEO-b-PS Block Copolymer, Ping Huang,Lei Zhu, Jiaokai Jing, Yan Chen, Stephen Z. D. Cheng,* Ya Guo, Qing Ge,and RodericP. Quirk;/?. 225

P-8 New NIST-traceable Standards for Calibration and Validation of DSC,Donald G. Archer,/?. 231

P-9 Magnetic Materials for Calibration of Temperature inThermogravimetry, Gallagher, PatrickK.; Blame, Roger;/?. 237

P-10 Cure Kinetics of Military coatings Using DMTA, Anthony T. Eng, LauraM. McGrath, Forrest D. Pilgrim, R. Bruce Prime;/?. 238

P-ll NaPO3 glass crystallization as observed by the Light TransmittanceThermal Analysis, Subhash C. Mojumdar, Milan Drabik, JozefChocholouSek, Vladimir Kovar, Jan Majling; p. 239

P-12 Thermal Properties of Co-Exchanged Montmorillonite with Pyridine,4-Methyl- and 4-Ethyipyridine, Eugen Jona, Miroslava Kopcova,KatarinaNemcekova, Subhash C. Mojumdar, Maria Kubranova;/?. 245

P-13 Thermophysical Properties of Blended Cements, Subhash C. Mojumdar,Ivan Janotka;/?. 251

P-14 Relationship between unisothermal an isothermal kinetics ofcrystallization of metallic glasses by DSC, Peter Simon, Emilia JJlekova,Subhash C. Mojumdar;/?. 257

P-15 Thermal Characterization of Hexaaluminate High TemperatureCombustion Catalysts, Tsao-Fa Yeh, Hsin-Gwo Lee, Chen-Bin Wang,Kuang-Shing Chu;/?. 263

P-16 Thermal Transitions ofHydrophylic Membranes by DSC and DMA,Leila F. Miranda; Leonardo G.ASilva; Ademar B. Lugao & Cheila G.Moth6;/?. 269

P-17 Isoconversional Kinetic Study of the T1iennaLD«composition of LDPEPacking in a Landfill, CheilaGMothe*, CarlaR. de Araj&jo, Ana C. Grisa,Mara Z. Andrade; p. 275

P-18 Thermal Characteristics of Poly-lactic acid / Wheaybluten Blends,Abdellatif A. Mohamed and Sherald H. Gordon;/*. 28

P-19 Use of DSC in Comparison of Ergocalciferol Lot/, Anna M. Wokovich*,Duckhee Y. Toler, Anjanette P. Smith, and Nick/Westenberger;/?. 288

P-20 Polymorphous structures and their phase relationships in amain-chain/side-chain liquid crystalline polyester, Jr-Jeng Ruan, Jason J.Ge, Anqiu Zhang, Jin Shi, Shy-Yeu Wang, Frank W. Harris, and Stephen Z.D. Cheng;/?. 294

P-21 A Novel Technique for Thin Film Mechanical Properties, IndiraAdhihetty, Dianne White, Joseph Vella and Alex Volinsky; p. 295

TUESDAY MORNING

September 24,2002

AWARD CEREMONY and PLENARY LECTURE

SALONS 2& 3

8:00 Award Ceremony

8:20 Mettler Award lectureThermal Analysis & Calorimetry Beyond 2000:

New Routes for Applications in Metastable Polymeric Systems;/?. 296

Mettler Award 2002 presented to

Vincent B. F. MathotManager, Polymer Characterization Laboratories

DSM ResearchThe Netherlands


CALORIMETRY AND MICROCALORIMETRY

SALON 4; Prof. A. E. Beezer presiding

9:20 Measuring Water Permeability Constants inPharmaceutical, Theodore D. Sokoloski* and Johannes ROpfermann; p. 297

10:00 CM-2 47 Quantitative Determination of Amorphous andCrystalline Drug in Polymer Microspheres, Leonard C.Thomas;/?. 303

10:20 CM-3 46 Characterization of Polymorphic Transitions in ;Pharmaceutical Drug by DSC and MDSOD, Leonard C.Thomas;/?. 308

10:40 Break

11:00 A comparison of DSC, TMDSC and DMA techniques forstudying the influence of production methods on spray driedparticles, John C Duncan 1, Laure Baladda, Paul Royall,Ching-ya Huang and Glynn Van-de-Velde;/?. 313

11:20 Influence of Moisture on the Glass Transition Determinedby the New IsoStep™ Method, Rudolf Riesen, Jurgen E.K.Schawe and Uwe Hess; p 314


THERMAL HAZARDS

CITY CENTER A; Dr. Sima Chervin presiding

9:20 How Calorimetry Can Help in the Evaluation of IndustrialProcess Safety, Ed Soliman and Luc A. Benoist;/?. 315

9:40 From calorimetric data via kinetics-based simulation topredicting reactivity and assessing reaction hazards(Methodology and Software), Arcady A. Kossoy*, Vasiliy M.Belokhvostov;/?. 316

10:20 Break

10:40 Rapid Screening of Exothermic Reaction Hazards, R.D.Mclntosh, S.P. Waldram, J.S. Singh, G. Etherington;/?. 322

11:00 Thermodynamics of Decomposition of Organic Compoundsof Phosphorous and Sulfur, T. Grewer and H.J. Kleiner;/?. 329

11:20 On the Use and Misuse of Detected Onset Temperature ofCalorimetric Experunetns for Reactive Chemicals, T.C.Hofelich and M.S. LaBarge;/?. 331

11:40 Applying kinetics-based approach for simulation of thermalexplosions and vent sizing, Arcady A. Kossoy*, Irina Ya.Sheinman, Nikha A. Podlevskikh;/?. 332


POLYMERS


2002 Perkin-Elmer Outstanding Student Award Lecture

9:20 Comparison of Isothermal and Dynamic Methods for theDeterminatino of Activation Energy

Mr. James Ray; p. 339

10:00 Rigid Amorphous Fraction in Poly(phenylene oxide)Detected by Temperature-modulated Calorimetry,Jeongihm Pak, Marek Pyda and Bernhard Wunderlich; p. 345

10:20 PO-16 62 Fractions of Different Mobility in SemicrystallinePolymers Revealed from Temperature Dependent HeatCapacity and NMR Measurements, Sergey Adamovsky, QunChen, Yan Chen, Alaa Mohammed, Ragab M. Soliman,Andreas Wurm, Christoph Schick; p. 351

10:40 Break

11:00 Measurement of the heat capacity ofpoly(a-methylstyrene)/oligomer mixtures: Implications forexperimental resolution of the Kauzmann paradox, DinghaiHuang, Sindee L. Simon and Gregory B. McKenna; p.357

11:20 Processing of intractable polymers using reactive solvents:the use of modulated DSC to follow structure development,J.G.P. Goossens, A. Saalbrink, H.E.H. Meijer, P.J. Lemstra;p364

11:40 Evaluation of Fiber Heatsetting by MDSC®, Els Verdonck,Valja Everaert, Myriam Vanneste, Luc Ruys, Roger L. Blaine;p. 365


GENERAL SESSION

MARQUIS A; Prof. Masangu Shabangi presiding

9:20 A History of NATAS, Gallagher, Patrick K.; Judovits, Larry;Vitez, Imre

9:40 Thermally Cured Water-Based Coatings: Effect of ComplexMorphology on Coating Performance, Brian K. Rearick andPeter Kamarchik, Ian R. Harrison;/?. 369

10:00 How Does It Fail: Understanding The Failure Modes ofCoatings, Lenore L. Dai, Ljiljana Maksimovic, PeterKamarchik;/?. 375

10:20 Break

10:40 DMA Modulus as a Screening Parameter for Compatibilityof Polymer Containment Materials with Various Solutionsfor Use in Space Shuttle Microgravity Protein CrystalGrowth (PCG) Experiments, Doug Wingard; p. 381

11:00 Recommendations for reporting thermal analysis data,Jeffrey G Dunn; /?. 387

11:20 Improved Technology for the Thermal Analysis of Foods, R.Bruce Cassel and Steve Aubuchon;/?. 393


12:00-1:30 Lunch

TUESDAY AFTERNOONSeptember 24,2002

1:30-2:30 New Frontiers in Thermal AnalysisPanel Discussion

SALONS 2 & 3; Prof. James Seferis and Dr. R. Bruce Prime presiding

230 Technical sessions resume

CALORIMETRY AND MICROCALORIMETRY

SALON 4; Prof. A. E. Beezer presiding2:30 An Investigation into the Subambient Behaviour of Aqueous

Mannitol Solutions using DSC and Cold Stage Microscopy,Vicky L. Kett,*, Shaun Fitzpatrick, Duncan Q.M. Craig;/?. 399

3:10 Thermodynamics and Calorimetry in Biology, Lee D.Hansen*, Richard S. Criddle, BruceN. Smith;/?. 405

3:50 Break

4:10 Determination of inactivation kinetic parameters of bacteriausing differential scanning calorimetry, Gonul Kaletunc;p. 411

4:30 Characterization of Reactivity of Multicomponent GlassFiber Surfaces via Perfusion (Flow) Microcalorimetry,Jon F.Bauer;/?. 412

5:10 End of Session

THERMAL HAZARDS


2:30 Consideration of Heat Accumulation Risks in Practice, BobVenugopal;/?. 418

2:50 Testing Strategy for Classifying Self-Heating Substances forTransport of Dangerous Goods, Sima Chervin, Glenn T.Bodman;/?. 427

3:10 Optimizing Thermal Safety for a Catalytic Hydrogenationof Aromatic Nitro Compounds, Olivier Ubrich*, FrancisStoessel;/?. 427

3:30 Break

3:50 Thermal hazard analysis of styrene monomer at Lowtemperature conditions during storage and transportation,Chin-Chuan Chen, Chi-Min Shu, Ron-Shin Chang, Mei-LingShyu, Shu-Ching Chen;/?. 433

4:10 Thermal hazard assessment on hydroperoxides examples oncumene hydroperoxide, Deng-Jr Peng, Chi-Min Shu, Jin-ZhiWei, Mei-Ling Shyu, Shu-Ching Chen;/?. 440

4:30 Thermal hazard analysis for cumene hydroperoxide by DSCand TAM, Tsu- Kaung Mao, Chi-Min Shu, Deng-Jr Peng,Mei-Ling Shyu, Shu-Ching Chen;/?. 448

4:50 Fire prevention study of wet bench cleaning stages insemiconductor manufacturing processes incompatibilitiesof hydrogen peroxide, Deng-Jr Peng, Chi-Min Shu, Huei-JiunChen, Mei-Ling Shyu, Shu-Ching Chen;/?. 455


POLYMERS


2:30 Morphology of Poly(Lactic acid) by AFM and Calorimetry,Marek Pyda, Alexander Buzin, Bemhard Wunderlich; p. 463

2:50 The monotropic phase transition behaviors in athermotropic main-chain liquid crystalline polyether,Alexander J. Jing, Orawan Taikum, Christopher Y. Li, Frank W.Harris, StephenZ. D. Cheng;/?. 469

3:10 DSC Step Annealing for Fingerprinting MolecularStructure in PVDF, Els Verdonck, Serge Heyez, Roger L.Blaine;/?. 475

3:30 Break

3:50 Characterization of Album Page Pressure SensitiveAdhesives Using Thermal Analysis, Joseph J. O'Shanka*,JohnH. Suwardie;/?. 481

4:10 Thermal Characterization of Overmolded UnderfillMaterials for Stacked Chip Scale Packages, Yi He;/?. 487

4:30 Thermal Degradation of VinylideneChloride/4-Vinylpyridine Copolymers, Bob A. Howell andPatrickB. Smith;/?. 493


THERMAL CONDUCTTVTrY

MARQUIS A; Ms. Daniela Stroe presiding

2:30 Rapid Thermal Conductivity Measurement with a Hot DiskSensor Part 1. Theoretical Considerations, Yi He;/?. 499

2:50 Rapid Thermal Conductivity Measurement with a Hot DiskSenson Part 2. Characterization of Thermal Greases forElectronic Packaging, Yi He; p. 505

3:10 Comparison of transient and steady state methods to testthermal conductivity, Daniela E. Stroe, Peter S. Gaal, Renee A.Jacobs - Fedore, Marc-Antoine Thermitus;/>. 577

3:30 Effects of Interface Resistance on Measurements ofThermal Conductivity of Composites and Polymers, AndrzejBrzezinski, Akhan Tleoubaev;/?. 512

3:50 Break

4:10 Thermal conductivity measurements using the flash method,Peter S. Gaal, Marc-Antoine Thermhus, Daniela E. Stroe;/?. 518

4:30 Thermal Conductivity Evaluation of Ceramic CoatingsUsing Flash Diffusivity and DSC Methods, Hsin Wang;p. 524

4:50 Thermal Effushity as a Non-Destructive Method toCharacterize Thin Films, Mark F. Fleszar,/?. 525


5:50 End of Technical Program for the day

WEDNESDAY MORNING

September 25,2002

PLENARY LECTURE

SALONS 2&3

8:00 Elastomers: The Other ThermosetsDonald J. Burlett;/?. 531


INORGANICSSpecial Session in honor of Prof. Patrick K. Gallagher

SALON 4; Dr. Keith J. Kociba presiding

9:00 Professor Patrick K. Gallagher: A Portrait, Keith J. Kociba

9:20 Kinetics of the Oxidation of Magnetite Using SimultaneousTG/DSC, Sanders, John P.; Gallagher, Patrick K.;/?. 537

9:40 Near eutectic Aluminum-Silicon alloys: Thermodynamicmodelling and DSC characterization, Duncan M. Price* andRachel C.;/?. 538

10:00 Characterisation of Hydrates Formation in Drilling MudsUsing High Pressure DSC, Pierre Le Parlouer, ChristineDalmazzone, Benjamin Herzhaft and Iggy Chan; p. 539

10:20 Macro-Defect-Free (MDF) Cements : Thermal Analysis,Moisture Resistance, Chemical, SEM and MagneticAnalyses, Subhash C. Mojumdar, Milan Drabik, Abhi Ray;p. 545

10:40 Break

11:00 Preparation, Thermoanarytical and Spectral Properties ofNi(D) Complexes with Furopyridines, Subhash C. Mojumdar,Jozef Miktovic, Alibeta KrutoSikova, Eugen J6na, BeataMitasova, Eugen J6na, DuSan Valigura;/?. 557

11:20 Recycling of Tires in Ceramic Material, Cheila G. Mothe" andHehorF. MotbiFilho;/?. 557

11:40 Simultaneous Characterizing Study of the Metallic Iron-Organic Coordination Compounds by TG-DSC-MSCoupling Techniques , Chang-Wei, Lu; Qun, Wang;Yun-Xian, Chen; Jian-Lin,Shi;/?. 563

12:00 From the Mine to the Building Site: Thermal Analysis ofBuilding Materials, Matthias Wagner, Rudolf Riesen andBlaineWeddle;/?. 569

12:20 End of session

THERMAL HAZARDS


9:00 Thermal Analysis and Intrinsic Activation EnergyEstimation to Predict Hazardous Chemical Pathways,Abdulrehman A. Aldeeb, William J. Rogers, and M. SamMannan;/?. 570

9:20 Predictive Techniques for Reactive Chemicals HazardEvaluation, Sanjeev R. Saraf, William J. Rogers, and M. SamMannan;/?. 576

9:40 Pinhole Control in Thermal Analysis for Thermal HazardStudies of Volatile Materials, R.J. Seyler,/?. 582

10:00 Challenges in Microthermal Detection of EnergeticMaterials, Chien-Chung Chen, Changshu Kuo, RamaswamyNagarajan, William Bannister, John W. Furry;/?. 592

10:20 Break

10:40 Smoldering Combustion of Biomass - Oxidation ofCellulose and Tobacco Chars, Bruce E Waymack;/?. 598

11:00 Use of DSC in Screening for Explosive Properties, Glenn T.Bodman;/?. 605

11:20 Thermal Hazard Assessment of Oxklizer Solutions andEmulsion Explosives Utilizing Accelerating Rate and DewarCalorimetry, David E.G. Jones, Philip D. Lightfoot and RobertC. Fouchard;/?. 611

11:40 The Investigation on Thermal Properties and WaterResistance of Primer Mixtures using Thermal Techniques,JinnshingLee;/?. 617


GENERAL SESSION

CITY CENTER B; Prof. Masangu Shabangi presiding

9:00 The Effect of Hair Treatments as Measured by DynamicMechanical Analysis, Steve Sauerbrunn and Jon Foreman;p618

9:20 Thermal Analysis Applications in Civil and Criminal LawCases, Alan T. Riga;/? 623

9:40 Advanced Thermal And Analytical Methods To MonitorEngine and Motor Oil Performance, Alan T. Riga and VadimLvovich;/? 624

10:00 How to Compare the Detection Limit of Different TG andTG/EGA?, Dun Chen;/?. 625

10:20 Weight Loss Determined from Mass Spectrometry TrendData in a Thermogravimetric/Mass Spectrometer System,Carlton G. Slough and Louis E. Waguespack;/?. 626

10:40 Break

11:00 Development and Application of an Instrument System forSimultaneous Thermogravimetric Analysis - MassSpectrometry, John J. Tria * and Frederick D. HUeman; p. 633

11:20 A New TG-MS Coupling: The Supersonic System, Pierre LEPARLOUER, Christophe MATHONAT, Iggy CHAN;/?. 639

11:40 Flash® Virtual Instruments for Rheology, Ian R. Harrison;p. 645

12:00 New Kinetics for Combined Dynamic and IsothermalExperiments, Rudolf Riesen, Ni Ting, Georg Widmann, UrsJ&rimann; p.646




9:00 The Characterization of Fully Formulated Pharmaceuticalsby Advanced Thermal Methods, Laura L. Wells, Wei-PingPan, Alan Riga/? 650

9:20 A Thermogravimetric Study of Peppermint Oil, PradyotNandi, Kenneth S. Alexander*, Alan T. Riga;/? 656

9:40 Determination Of The Kinetic Model Of Decomposition ForThe Commercially Available Form Of Sulfamerazine ByThermogravimetric Techniques, Sandipan Sinha, Kenneth S.Alexander*, Alan T. Riga;/? 662

10:00 Thermal Characterization Of Amiodarone HydrochlorideAnd Us Interactions With Excipients, Rajesh Vadlapatla,Nagarajan Thyagarajapuram, Kenneth S. Alexander, Alan T.Riga;/?. 668

10:20 Break

10:40 Thermal Properties and Drug Interactions of Excipients byDSC and TG, Alan T. Riga, Bryan Biddlecom, and Kenneth S.Alexander,/?. 674

11:00 A Differential Scanning Calorimetry Standard Test Methodbased on Statistical Experimental Design forPharmaceutical Preformulation Research and QualityControl., Alan T. Riga, Shouvik Roy, and Kenneth S.Alexander,/?. 675


12:20-1:30 Lunch

WEDNESDAY AFTERNOONSeptember 25, 2002

PLENARY LECTURE

SALONS 2 & 3

1:30 Assessing the Thermal Stability and Explosive Potential ofEnergetic Materials, Jimmie C. Oxley;/?. 676


POLYMERS

SALON 4; Dr. Manika Varma-Nair presiding

2:30 Recertification of the Polyethylene Oxidation InductionTime Reference Material, Roger L. Blaine and Alan T. Riga;p. 677

2:50 Thermal Degradation of Vinylidene Chloride/VinylChloride Coporymers in the Presence ofN-Substitutedmaleimides, Bob A. Howell and Jin Zhang;/?. 682

3:10 Using Thermal Techniques to Study Degradation ofSulfur-Crosslinked Elastomer Systems, Donald J. Burlett;p. 688

3:30 Break

3:50 Thermal Degradation of2,4,6-Tri(bromoxanilino)-l,3,5-triazines, Bob A. Howell andHuiWu;/?. 694

4:10 End of session

THERMAL HAZARDS


2:30 Kinetic Analysis of Explosives Using Multivariate NonlinearRegression and Critical Temperature Tests, Mary S.Campbell and Lloyd L. Davis;/?. 700

2:50 Thermal Experimental Design on Degradation forElectro-Explosive Devices, Jinn_shing Lee;/?. 706

3:10 End of session

GENERAL SESSION

CITY CENTER B; Prof. Masangu Shabangi presiding

2:30 Mettler Toledo HP DSC827e- A New Instrument forPressure DSC, Matthias Wagner, Rudolf Riesen, UrsJoerimann;/?. 707

2:50 A Review of Terms Concerning the Performance ofDifferential Scanning Calorimeters, Blaine Weddle, SteveSauerbrunn*, Rudolf Riesen and George Widmann; p. 708

3:10 Integrated Circuit Thermopile as a New Type ofTemperature Modulated Calorimeter, Mikhail Merzlyakov*and Christoph Schick;/?. 714

3:30 Break

3:50 New NIST-traceable Standards for Calibration andValidation of DSC, Donald G. Archer,/?. 237

4:10 Benefits of Using a Photocalorimetry Accessory (PCX) witha Tzero™ DSC, Louis E. Waguespack* and Carhon G. Slough;/?. 720

4:30 End of session

THERMAL CONDUCTIVITY

MARQUIS A; Ms. Daniela Stroe presiding

2:30 Thermal Conductivity Evolution of Powder MetallurgyParts During Initial Stage Sintering, Constance E. Schlaefer*,Randall M. German; p. 725

2:50 Improved Thermal Conductivity Measurement Capabilitiesthrough an Enhanced Algorithm and Instrument Design,Mathis, Nancy; Dixon, Craig; Canney, Brad; Montag, Sean;Musgrave, Dwight;/?. 726

3:10 Apparatus for Rapid Automated Measurement of LiquidThermal Conductivity by the Transient Hot-wire Method,John J. Tria, William A. Grote, Harold W. Luebke, Kevin L.Depperman and John Hackett; p. 727

3:30 TC-112 The Elimination of Calibration Requirements forThermal Conductivity Measurements with the TC Probe™,Mathis, Nancy; Dixon, Craig; Canney, Brad; p. 732

3:50 End of session

4:30 - 4:45 NAT AS ConferenceClosing remarks

Salons 2 & 3

the 30th annual conference on thermal analysis … · the 30th annual conference on thermal...

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