the fascination of crystals and symmetry...if not otherwise stated pictures, images, sketches, clip...
TRANSCRIPT
![Page 1: The Fascination of Crystals and Symmetry...If not otherwise stated pictures, images, sketches, clip arts are • self-taken/self-drawn or • public domain Rob Lavinsky, iRocks.com](https://reader033.vdocument.in/reader033/viewer/2022050209/5f5c0f921790423f9a099ee6/html5/thumbnails/1.jpg)
The Fascination of Crystals and Symmetry
Unit 5.4
by Frank Hoffmann & Michael Sartor
![Page 2: The Fascination of Crystals and Symmetry...If not otherwise stated pictures, images, sketches, clip arts are • self-taken/self-drawn or • public domain Rob Lavinsky, iRocks.com](https://reader033.vdocument.in/reader033/viewer/2022050209/5f5c0f921790423f9a099ee6/html5/thumbnails/2.jpg)
NaCl
− a simple-complicated structure
![Page 3: The Fascination of Crystals and Symmetry...If not otherwise stated pictures, images, sketches, clip arts are • self-taken/self-drawn or • public domain Rob Lavinsky, iRocks.com](https://reader033.vdocument.in/reader033/viewer/2022050209/5f5c0f921790423f9a099ee6/html5/thumbnails/3.jpg)
NaCl (Halite, Rock salt)
Space group
Crystal class
Crystal system
F m 3 m (# 225)
m 3 m
cubic
the sodium cations are surrounded by six
chloride anions, and vice versa
octahedral coordination spheres
CN = 6:6
Na+ Cl-
Lattice parameter
a = b = c = 5.625 Å
= 90 °, = 90 °, = 90 °
each ion type forms a fcc (sub-)lattice
![Page 4: The Fascination of Crystals and Symmetry...If not otherwise stated pictures, images, sketches, clip arts are • self-taken/self-drawn or • public domain Rob Lavinsky, iRocks.com](https://reader033.vdocument.in/reader033/viewer/2022050209/5f5c0f921790423f9a099ee6/html5/thumbnails/4.jpg)
NaCl (Halite, Rock salt) – Fragility
+ -
+-+ -
+-
+ -
+-
+
-+
-
+
-
-
+
+ -
+--
+
+ -
+-
-
+
+ -
+-forceCleavage
tendency of crystals to split along definite crystallographic planes
perfect along {001}
+ -
+ +
- -
electrostatic attraction
electrostatic repulsion
6.7 x 1.9 x 1.7 cm
![Page 5: The Fascination of Crystals and Symmetry...If not otherwise stated pictures, images, sketches, clip arts are • self-taken/self-drawn or • public domain Rob Lavinsky, iRocks.com](https://reader033.vdocument.in/reader033/viewer/2022050209/5f5c0f921790423f9a099ee6/html5/thumbnails/5.jpg)
NaCl (Halite, Rock salt) – the three viewing directions
F m 3 m (# 225)Space group
[001]4/m [111]
3
Full symbol F 4/m 3 2/m
[110]2/m
3D structure (Vesta)
reproduce this with the
![Page 6: The Fascination of Crystals and Symmetry...If not otherwise stated pictures, images, sketches, clip arts are • self-taken/self-drawn or • public domain Rob Lavinsky, iRocks.com](https://reader033.vdocument.in/reader033/viewer/2022050209/5f5c0f921790423f9a099ee6/html5/thumbnails/6.jpg)
NaCl (Halite, Rock salt) – International Tables
![Page 7: The Fascination of Crystals and Symmetry...If not otherwise stated pictures, images, sketches, clip arts are • self-taken/self-drawn or • public domain Rob Lavinsky, iRocks.com](https://reader033.vdocument.in/reader033/viewer/2022050209/5f5c0f921790423f9a099ee6/html5/thumbnails/7.jpg)
NaCl (Halite, Rock salt) – multiplicity of 192…
…
Positions
Na4Cl4
Add an atom at a general position in VESTA
![Page 8: The Fascination of Crystals and Symmetry...If not otherwise stated pictures, images, sketches, clip arts are • self-taken/self-drawn or • public domain Rob Lavinsky, iRocks.com](https://reader033.vdocument.in/reader033/viewer/2022050209/5f5c0f921790423f9a099ee6/html5/thumbnails/8.jpg)
NaCl (Halite, Rock salt) – simply beautiful..
![Page 9: The Fascination of Crystals and Symmetry...If not otherwise stated pictures, images, sketches, clip arts are • self-taken/self-drawn or • public domain Rob Lavinsky, iRocks.com](https://reader033.vdocument.in/reader033/viewer/2022050209/5f5c0f921790423f9a099ee6/html5/thumbnails/9.jpg)
Picture Credits
If not otherwise stated pictures, images, sketches, clip arts are • self-taken/self-drawn or• public domain
Rob Lavinsky, iRocks.com | CC-BY-SA-3.0 Dubravko Sorić SoraZG on Flickr | CC-BY-SA-2.0