the roesky working group: facilities, collaborations, · pdf filethe roesky working group:...

The Roesky Working Group:

Facilities, Collaborations, and Science

P W Roesky Institut für Anorganische ChemieP. W. Roesky, Institut für Anorganische Chemie

KIT – Universität des Landes Baden-Württemberg undnationales Großforschungszentrum in der Helmholtz-Gemeinschaft www.kit.edu

TeamTeam

Institut für Anorganische ChemieP. W. Roesky

Invited Speakers

Polly Arnold, University of Edinburgh, UK

Isabelle Billard, IPHC/DRS, Strasbourg, France, , g,

William J. Evans, UC Irvine, USA

Sophie M. Guillaume, Université de Rennes, France

Peter C. Junk, Monash University, Clayton, Australia

Arndt Simon, MPI, Stuttgart, Germany

33 O h L33 Other Lectures

150 Participants


Research BackgroundExpertise:Expertise:

Strong background in the synthesis of organometallic and coordination compounds.

Catalysis:y

• Hydroamination

• Polymerization

We do not handle radioactive material but we cooperate with the INE and the ITU in K l hKarlsruhe.


FacilitiesEquipment

State of the art equipment for handling air stable to highly air sensitive compoundsState of the art equipment for handling air stable to highly air sensitive compounds

• Different kinds of Schlenk lines

• Glove boxes


FacilitiesInstrumentation

• NMR• NMR

• Single Crystal X-ray diffraction



IR and Raman Spectroscopy• IR and Raman Spectroscopy

• Elemental Analysis



• Mass spectroscopy (EI and ESI)

• HPLC


Collaborations

Collaborations with French Groups

Long term collaboration in the field of polymerization

Dr. Sophie Guillaume: Université de Rennes 1 Polymerization

Prof. Laurent Maron: Université Paul Sabatier TheoryTheory

4 Joint Publications since 2007 + 1 submitted4 Joint Publications since 2007 1 submitted


CollaborationsCollaborations in the field of Nuclear Waste Disposal

Collaboration with the Institut für Nukleare Entsorgung, KIT

and the Universität Heidelbergg

Dr. Melissa A. DeneckeEXAFS

Dr. Andreas Geist Actinide(III) / lanthanide(III) separation 02NUK012

Prof. Dr. Petra J. PanakTRLFS

1 Joint Publication since 2010 + 1 submitted


Science

Sc

Y

La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu


Science: An Overview

Lanthanides

Homogenous catalysis: HydroaminationPolymerization

Cluster und porous strucrtures (MOF): MagnetismCluster und porous strucrtures (MOF): MagnetismLuminescens

M t l t t l b dMetal-to-metal-bonds

Nuclear waste disposalp


Science

Ca

Sr

Ba



Alkaline Earth Metals

H t l i H d i tiHomogenous catalysis: Hydroamination

Metal-to-metal-bonds


Science

Zn



Zinc

Homogenous catalysis: HydroaminationPolymerization

M t l t t l b dMetal-to-metal-bonds


Science

Au



GoldGold

Heterogenous catalysis

Metal-to-metal-bonds

L minescensLuminescens


The First Main-Group-Lanthanide Metal-to-Metal bonds

1/4 [(5 C5Me5)Al]4 + [(5 C5Me5)2Eu] Eu Al1/4 [( -C5Me5)Al]4 + [( -C5Me5)2Eu] Eu Al

d: Al-Eu 3.3652(10) Å

space group P1R1 = 0.0237 wR2 = 0.0659

M T Gamer P W Roesky S N Konchenko P Nava R Ahlrichs


M. T. Gamer, P. W. Roesky, S. N. Konchenko, P. Nava, R. Ahlrichs Angew. Chem., Int. Ed. 2006, 45, 4447-4451.

The first Molecular Polyphosphide of the Rare-Earth Elements

P

Sm + 2

P

P P4

S N Konchenko N A Pushkarevsky M T Gamer R Köppe H Schnöckel P W Roesky


S. N. Konchenko, N. A. Pushkarevsky, M. T. Gamer, R. Köppe, H. Schnöckel, P. W. Roesky J. Am. Chem. Soc. 2009, 131, 5740–5741.

The first Polyphosphide Triple-decker Complexes of the Rare-Earth Elements p

PP

Fe

PPP

P P

DIPSmTHF THFIII

N DIPDIP

NN

T Li J Wiecko N A Pushkarevsky M T Gamer R Köppe S N Konchenko M Scheer An

First mixed d /f metals triple-decker complex


T. Li, J. Wiecko, N. A. Pushkarevsky, M. T. Gamer, R. Köppe, S. N. Konchenko, M. Scheer, AnAngew. Chem. Int. Ed. 2011, 50, 9491-9495.

the roesky working group: facilities, collaborations, · pdf filethe roesky working group:...

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