thin film and thin wafer pv: challenges for bipv applications [pv 2009]
DESCRIPTION
- Flexible PV modules for BIPV - Potential for cost reductions and aesthetic integration - Challenges for processing thin silicon wafer Dr. Andrew Skumanich, SolarVision ConsultingTRANSCRIPT
SVC 2009 PV Summit Conference Page 1
Thin Films and Thin Wafers: Thin Films and Thin Wafers: Challenges and Challenges and
Opportunities with BIPV Opportunities with BIPV
PV SummitJune 3rd 2009
Andy Skumanich, Ph.D.SolarVision Consulting
SVC 2009 PV Summit Conference Page 2
Outline
Opportunities and challenges
• Market potential for BIPV– Flexible PV modules
• Challenges– Potential for cost reduction and aesthetic integration
• Thin film trajectory: CE and cost– Various types including CIGS
• Ultra-thin wafer trajectory: thickness, CE, and cost– PV processing sequence– Handling considerations
• Conclusions
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Market Opportunities
• General PV forecast: 6-9 GW in 2010
• Demand for glass: 2010 – 1Billion m2 WW– Take 1/10% as BIPV, 10% CE1GW of PV glass
• Roof-tops residential: coverage by PV– 7 million new houses in typical year– If 1/10% have BIPV roof, 10%CE1GW of rooftop PV for residential
• BIPV could potentially be a major market driver
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BIPV Market Requirements
• Aesthetics, cost• Customizability• Product availability• Product features: Flexibility, Shape, etc.
• Market opportunity for flexible TF, and c-Si foils
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Challenges
• Thin Film: – Improved efficiency– Flexible substrate extends applications – maintain CE– Viability of materials without exchange
• Wafer based c-Si:– Foils which are flexible and robust– Improved efficiency for ultra-thin wafers – recover CE– Processing of wafers-to-cells
• Common– Customizability in design– Product range
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Turn-key Landscape: TF & c-Si
a-Si and Tandem
CIGS CdTe c-Si
• Oerlikon (11)• AMAT (14)• Ulvac (3)• Other misc
• Centrotherm • (Roth & Rau) Full chain:• Centrotherm• Schmid
Multiple sub-lines
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Thin Film CE gains
• CIGS starting to show promise– Turnkey line from Centrotherm
• a-Si needs to achieve >10% capability• CdTe needs to confirm reliability
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Centrotherm CIGS Turn-key
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Value of thin wafers for c-Si PV
• Potential benefits– Improved theoretical conversion efficiency– Potentially improved flexibility below 100um
S. Schoenfelder EuroSim, 2006
??Post-
degradation
CZ P-type (w/ B-O)
!!
Strength vs ThicknessC.E. vs Thickness (R&D data)
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11
Cell Efficiency vs. Thickness
10
12
14
16
18
20
22
24
350 300 250 200 150 100
SunPowerSolar Cell
ConventionalSolar Cell
ConversionEfficiency %
Cell Thickness (microns)
Cost reduction
Solar cell thickness reduction is a key cost reduction path. SunPower solar cell efficiency improves as wafer thickness decreases versus conventional solar cells
which become less efficient on thinner wafers.
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Wafer Thickness Roadmap
0
50
100
150
200
250
300
350
2002 2004 2006 2008 2010 2012
Waf
er T
hic
knes
s (u
m)
150120
(Source: NREL Silicon Strategy, Dick Swanson – SunPower, SVC)
Multi -crystalline
Mono -crystalline
SunPowermono c-Si, (125mm)
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Cell Efficiency Roadmap
13
0
5
10
15
20
25
2002 2004 2006 2008 2010 2012
Cell Efficiency History and NREL PlanConversion Efficiency
Multi -crystalline
Mono -crystalline
SunPowermono c-Si,
CE
(%)
(Source: NREL Silicon Strategy, Dick Swanson – SunPower, SVC)
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Ultra-thin wafer processing
• Aggressive activities world wide
– EU: Fraunhofer Institute– Japan: NEDO– USA: various including commercial companies
• Key developments: e.g. back surface treatment– Example is GIT – Dr. Ajeet Rohatgi
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14
15
16
17
18
19
20
21
0 100 200 300 400 500Solar Cell Thickness (um)
Eff
icie
ncy
(%)
lifetime=100us, BSRV=50cm/s, BSR=97%
lifetime=100us, BSRV=400cm/s, BSR=65%
lifetime=25us, BSRV=50cm/s, BSR=97%
lifetime=25us, BSRV=400cm/s, BSR=65%
Current Status
Our Goal
GIT modeling for sub 100um wafers
• Bulk lifetime, thickness, BSRV and BSR targets for achieving 19-20% efficiency cells with screen printed front contacts
GIT Dr. Ajeet
Rohatgi
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Roadmap to 20%-efficient c-Si solar cells with screen printed contacts
17.0%
18.2%
19.3%
20.1% 20.0%
10%
12%
14%
16%
18%
20%
22%
Current SolarCell
Improved Text,AR & SP
(Ref=1.04%FF=79.1%M.C.=5.0)
BSR (97%)BSRV
(100cm/s)
High Sheet Res.Emitter (R=100
ohm/sq)
Reduce CellThickness (100
µm)
Eff
icie
ncy
GIT Dr. Ajeet
Rohatgi
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New Process Vs Full Al BSF IQE & RetroRefl
0
10
20
30
40
50
60
70
80
90
100
300 400 500 600 700 800 900 1000 1100 1200Wavelength (nm)
IQE
(%)
0
10
20
30
40
50
60
70
80
90
100
Ref
lect
ance
(%)
New Process
Full Al BSF
New Process
Full Al BSF
Voc(mV) 652 639
Jsc(mA/cm2) 39.4 37.9
FF(%) 78.1 78.9
Eff (%) 20.1 19.1
GIT Dr. Ajeet
Rohatgi
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IV-curve for the best Screen Printed New Process cell
0.00
0.02
0.04
0.06
0.08
0.10
0.12
0.14
0.16
0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700Voc (mV)
Isc
(A) ? : 20.1 %
VOC : 652 m VJSC : 39.4 mA/cm2FF : 78.1 %
Dielectric passivated rear LBSF raised the efficiency from 19.1 to 20.1%
GIT Dr. Ajeet
Rohatgi
SVC 2009 PV Summit Conference Page 19
Handling issues
• Breakage– Of course the major concern for module manufacturers
• Warped wafers cause issues– Ultra thin may have benefits and drawbacks
• Start-stop needs to be abrupt for high tpt– Wafers act like “wings” during motion
• Multiple challenges for handling
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Alternative Companies for Handling
• Equipment: Automation Technology Inc:– Bernoulli grippers– But still not developed
• Researchers at the Texas Manufacturing Assistance Center (University of Texas, Arlington)
– prototype air system able to both acquire wafers from a stack and move them along a track with no moving components
– contrasts with Bernoulli grippers which only acquire wafers and must use manipulators and robotic elements to move wafers
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Summary
• Decreasing thickness still moving forward– Market leaders driving to wafers 150um and then below– New improvements for thin films (CIGS specifically)
• Market forces will be pushing prices down– Foreseeable future: more pressure on cost reduction– Companies with tech advantages will survive
• Thin Film are steadily developing improved CE with CIGS leading in CE, (not in market)– Multiple challenges: higher CE >10% at low cost production
• Thin, and ultra-thin wafers now are driving processing– Mulitple challenges: maintain CE below 100um, breakage
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Conclusions
• Industry needs to drive metrics and dimensions– BOS may be substantially lower for frame and labor– May be closer to “grid parity” with lower BOS
• Increased focus on BIPV is also required
• Also, product portfolio needs to be expanded– Flexible, multi-dimensional, etc.
• Current development capabilities can open up the BIPV market in increase the demand for TF and ultra-thin c-Si
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TF BIPV