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Title Cover Author(s) Citation The Review of Physical Chemistry of Japan (1967), 37(1) Issue Date 1967-11-30 URL http://hdl.handle.net/2433/46889 Right Type Others Textversion publisher Kyoto University

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Page 1: Title Cover Issue Date URL ...repository.kulib.kyoto-u.ac.jp/dspace/bitstream/2433/46889/1/... · URL Right Type Others ... ANew Method of Determiningthe Transition Pressure of Mercury

Title Cover

Author(s)

Citation The Review of Physical Chemistry of Japan (1967), 37(1)

Issue Date 1967-11-30

URL http://hdl.handle.net/2433/46889

Right

Type Others

Textversion publisher

Kyoto University

Page 2: Title Cover Issue Date URL ...repository.kulib.kyoto-u.ac.jp/dspace/bitstream/2433/46889/1/... · URL Right Type Others ... ANew Method of Determiningthe Transition Pressure of Mercury

Vol. 37, 1967

The Review of Physical Chemist ~ ap

No.

(1967)

RFV'IEIYOR

THE

PflYS1CA~ OF JAPAN

C~E~IBTRI'Founded in 1926

CONTENTS

Kazuo Yasunaml : ANew Method of Determiningthe Transition Pressure of Mercury

at 0°C as a Fixed Point of. High Pressures :.:............................................:... 1

Jiro Osugi, Kiyoshi Shimiza, Kazuo Yaeunami and Akifami Onodera : Liquid-

Solid Transition at High Pressure (II), Monochlorobenzene and Toluene at 0°C......10

Ryozo Goto, Tsotomu Asano, Kiyoshi Matsnmoto and Alcira Sera : Orgauio Re-

ndions under High Pressure (I), Ptessure-and Solvent Effects on the Migratory

isyl Group ...............,...,.................................................16 Aptitude of o-Aa

I-Iironobu Knbota

to Butadiene (IJ

Hironobu Knbota:

Studies on the Kinetics of the Gas-phase Addition Reaction of.HI

ti

Studies on the Kinetics of the Gas-phase Addition Reacfionof HI

to Butadiene (II) 32

Jiro Onngi and Muaeo Sakakf : Kinetic Studies on Fast Reactions in Solulion (II),

The Reactioahetween t, 3, 5-Trinitrohenzene aril Diethylamine in Acetone...

Goro Morimoto: Physikochemische Untersuehung uber die 6-Substituierten 2,4-

Diamino-1, 3, 5; Triazine .....................................................................

43

54

ADDENDUM:

Tsunesake Doi: Physico-Chemical Properties of Sulfur (I),

sity of Liquid Sulfur

Pressure Effectr oa Visco-

62

THE PHYSICO-CHEMICAL SOCIETY OF JAPAN

Page 3: Title Cover Issue Date URL ...repository.kulib.kyoto-u.ac.jp/dspace/bitstream/2433/46889/1/... · URL Right Type Others ... ANew Method of Determiningthe Transition Pressure of Mercury

The Review of Physical Chemistry of Japan Vol. 37 No. 1 (1967)

THE REVIEWOF PHYSICAL CHEMISTRY OF JAPAN

(Butsuri-Ka.ga.ku no Shinpo)

1'resldeuh..Shinkichi Hori6a, Profeasod Emeritus, M. J. A. Members of Cona¢Il

Azuma Okuda (Chief)

J. Osugi --R. Rodera

R. Goto

T. Yamamoto

T, Fujinaga

E. Suito

Board of F.ditore

j. Oshgi (Chief)

S. Kachi

H. Takagi

H: Hatano

W, Jono R Goto

%yolo.U~riversity

I. Tsujikawa

A: ISeji

A. Saika -

W. Jono (Associate) Or¢ka Aefulwbf Woman-College

R. Goto ( o ) Byoto University

E. Suito ( a ) Ryoto University

3ecretssry :

S. Shida

T. Ritagawa

M. Tamura

H. Matsuyama

T. Makita

R. Susuki

R. Hirota

S. Ski

T. Ishino

T. Imoto

R. Fujishirv

O. Toyema

S. Ono

S. Tsuchihashi

S, Hasegawa

H. Togawa

R. Sbimiau

T. Fujivrara

Tokyo Institute of Te¢hnolo`y

Yokohmna University

Ayolo University

Doshisha University

Kyuto Teekaicol University

Ritsnmeikan University

U¢iiiersiry of Osaka

University of Osaka

Himeji lnstitate. of Technology

MunicfQo! University aJ Oroka.

dfuniiipal UniversityoJ Os¢k¢

PreJulura! Universiy of Omko

Prejutar¢l University of Otak¢

University of Kahe

Okayama Dnfverrily

Dotkish¢ University

M..Sasaki

Page 4: Title Cover Issue Date URL ...repository.kulib.kyoto-u.ac.jp/dspace/bitstream/2433/46889/1/... · URL Right Type Others ... ANew Method of Determiningthe Transition Pressure of Mercury

The Review of Physical Chemistry of Japan Vol. 37 No. 1 (1967)

November 30, 1967

Communications to-the Editor should br addressed. to Hoard of Fditors, The Physico-Chemical Society

of Japno,CoUege of Science, gyoto University, Byoto, Japan.

Buaiaeas Correspondeaeee should 6e addraaed to: Secretary, The Physico~Chemicel-Saciery of Japan,

College of Science, Ryoto University, Ryoto, Japan

Pssrehssse Order should be addressed to: Maroon Co.,. Ltd., Nihonbuhi, Chuo-ku, Tokyo, Japan.

THB

Publiabed by

PHYSICO•CHBMICAL SOCIETY OF JAPAN

(Nippoa Butsuri-Rsgaku Reakyu Ra{)

College of Seiena, Ryoto University, Ryoto, Japm

Printed by EAWARITA INSATSU CO., [yoto, Japan

Page 5: Title Cover Issue Date URL ...repository.kulib.kyoto-u.ac.jp/dspace/bitstream/2433/46889/1/... · URL Right Type Others ... ANew Method of Determiningthe Transition Pressure of Mercury

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. 37 No. 1 (1967)

Page 6: Title Cover Issue Date URL ...repository.kulib.kyoto-u.ac.jp/dspace/bitstream/2433/46889/1/... · URL Right Type Others ... ANew Method of Determiningthe Transition Pressure of Mercury

The Review of Physical Chemistry of Japan Vol. 37 No. 1 (1967)

il6'b~~:SERVING ALL INDUSTRIES THROUGH CHEMICALS

NISSO HI-CHLON, Granule, Tablet

(Calcium Hypochlorite 70°'o up) HIGH BLEACHING POWDER

(Calcium Hypochlorite 60..°a up) SODIUM CYANIDE 97°'o min.

Ball, Granule, Powder

POTASSIUM CYANIDE 98,,°o min. Ball, Granule, Powder

SODIUM HYDROSULFITE 85.°a or 90..°o min.

CAUSTIC SODA, Flake 97°0 or 98°o min.

CAUSTIC POTASH, Solid, Flake 98°o min.

;/Visso NIPPON

Head Office Ohte

Cable Address : "SO

• POTASSIUM CARBONATE, Granule

99.5°.o min. - WHITEX (Benzole Peroxide 22-25°b)

Flour Bleach • TDI 2, 4-TDI 80°.0

(Tolylene Diisocyanate) •POLYPROPYLENE GLYCOL

• ORTHO-TOLUNENE-SULFONAMIDE

• SULFAISOXAZOLE (SULPHAFURAZOLE)

U. 5. Pharmacopeia XVII B. Pharmacopeia 1963

• HYDROXY PROPYL CELLULOSE

SODA CO., LTD. machi, Tokyo, Japan

DANIPPON" TOKYO

Page 7: Title Cover Issue Date URL ...repository.kulib.kyoto-u.ac.jp/dspace/bitstream/2433/46889/1/... · URL Right Type Others ... ANew Method of Determiningthe Transition Pressure of Mercury

The Review of Physical Chemistry of Japan Vol. 37 No. 1 (1967)

ASAHI CHEMICAL INDUSTRY CO., LTD.

Caplml: ~ 20.000.000.000 President: KAGAYAKI NIYAZAKI

Head Office: 25. 1-chome, Dojima-hamadori, Kita-ku, Osaka. Japan

Tokyo Office: tt, t-chome, Yurakucho, Chiyoda-ku, Tokyo, Japan

Other Branch Offices: Nobeoka, Fuji, Fukuoka, Sapporo, Nagoya, Fukvi, Knaazawa, New York, etc.

Plants: Nobeoka, Fuji, Kawasaki, Sakanoichi, Wakayama, Jiatsudo

Laboratories: Tokyo (Technical Research Laboratory) Takatsuki (Textile Research Laboratory)

Asahi's history dates as far hack as 1923 when the late VIr. Jun Noguchi, who was the first

president of the company-. erected a synthetic ammonia plant in Nobeoka. present site of the

company's major plants. This is a memorable -plant in [hat the first commercial production of

synthetic ammonia in the world by the Casale

process was successfully started at this plant. Thereafter Asahi's production activity contin-

ued to expand, with [he exception of the war

yeazs, into great many fields. Using ample elec [ric power from its own power plants and stand-ing on the firmly established basis that primary

raw materials are available within the company,

Asahi has been producing chemical fibers, sym

thetic resin, explosives, chemical fertilizers, chemical seasoning, industrial nitrocellulose and

several scores of chemicals of ammonia, soda and rlilorine derivatives.

This fact points up to Asahi's special feature

as a chemical company. Asahi ranks 5rst in the

production of viscose rayon in Japan and its cuprammonium rayon capacity is largest in the world, using acrylonitrile monomer produced

by Sohio process at its Kawasaki plant, Asahi

produces polyacrylic fiber "Cashimilon" by its own process. Production acrylonitrile monomer

and of polyacrylic fiber is also the largest in

Japan. Asahi's chemical seasoning (monosodium

glutamate) Asahi Aji, ranks second in output of similar chemical seasonings. Sun-Nitro, Asahi's

unique chemical fertilizer, is building up for it-

self aspectacular sales. Asahi's industrial vitro-

cellulose and electrolytic soda production is the

largest in Japan. Asahi is also at the top in pro-duction volume of all the explosives manufac-

turers in Japan. Recently Asahi launched into

three new fields of operation, i.e. nylon 6, syn-

thetic rubber polybutadiene "ASADENE" and new building material '`HEBEL".

At present, Asahi's products are exported to

50 different countries. Export of the process is

also making headway. \Vorthy of mention fn

[his connection is the esport of viscose rayon

manufacturing techniques to the Baroda Rayon

Corporation. India. and Dawood Industries Lim-ited, Pakistan, and of polyatrylic fiber manufa-

cturing techniques to ANIC S. p. A, Italy.

Through all these activities, the excellence of

Asahi's techniques is highly evaluated.

Asahi now has many powerful affiliates,

including Asahi-Dow Limited and Shin Nihon

Chemical Industry Co., Ltd. and is proceeding on the road to further growth as a multiple-

purpose chemical company.

Page 8: Title Cover Issue Date URL ...repository.kulib.kyoto-u.ac.jp/dspace/bitstream/2433/46889/1/... · URL Right Type Others ... ANew Method of Determiningthe Transition Pressure of Mercury

The Review of Physical Chemistry of Japan Vol. 37 No. 1 (1967)

Single aystals of HORIBA INSTRUMESTS, INC., offered as complete products ready to use which are free from impurity absorption, have aquired worldwide reputatio¢s.

Our scintillators, such as NaI (Tl), CsI (TI) or CaIz are also credited and used internationally by the nuclear scientists, for the established qualities.

NaCI KC1 KBr KI LiF ARCI KRS-5` KRS-fi• Cs7

Limit of [ransparancy (microns)

Refractive index:

Salubility:••

Specific gravity gdrm'

3fe1[iog point: 'C '.lfaximum diameter:

mm Jfaximum height:

mm

-15 ~2I ---27 -31

1.555 1.498 1.559 1.667

35.] 28.5 53.5 117.5

1. Ifi 159 2.75 3.I3

SOI 7ifi i30 680

1t0 110 t20 120

100 100 100 i0

-s

1.394

0.27

2.64

-30

2.07 t

-40 X34

2.fi29 1.33fi

-70

1.987

8.9 x 10_5

5.56

0.02

7.2

0.32

7.19

44

4.53

843 455 415 424 621

ioo

60

0

0

6

0

60

60

60

t00

60

100

s KRSS is a compound single crpstxl of TII and TIBr, and KRS-6 is a compound single crystal of TICI

and TIBr. .. g/100 gr water at normal temperature.

HORIBA' I N S T R U M E N T S, I N C.

Head office & Factory: \liyanohiRashi•machi, Rissyoin, \liaami•Ku, &yoto

Tel: (Oi5) 313-8121 Tokyo brunch office: No. 1-18, Nishihatchobori, Chuo-ku,

Tokyo Tel: (03)552-7661

Page 9: Title Cover Issue Date URL ...repository.kulib.kyoto-u.ac.jp/dspace/bitstream/2433/46889/1/... · URL Right Type Others ... ANew Method of Determiningthe Transition Pressure of Mercury

II

The Review of Physical Chemistry of Japan Vol. 37 No 1 (1967)

VERY HIGH

..

r:~~~ ~:

~.~,

PRESSURE --

..~.,

..

EQUIPMENT{

~_! _..:

s M! ~-~ b?'

>+

"DlA" Equlpmsnl~ Cu67r Type Very Nlgh Prorwro Fqulpmenf~ Anvil Face IOmmX/Omm~ total Wsigirf 8 fen

~e Q ~6

.~

(.1

1 ~~

,,. _

J ~~

t

9 4. R Q ~ 9.

/1

t

S.H.P. Mearuremen/ Gauge, Electrical Resistance Slraln Gauge Type, falihraled whh the Master Free-Pis/on Govgs In Kobe Sfeol. (Japanese PAT. Ne.z94 i 53)

~ KOBE STEEL• MACHINERY DIVISION F[EAD OFFICE: 36, 1-chome, Wakinohame-cho, Fukiai-ku,

Kobe, Japaa OVERSE AS OFFICES: New York, Dusseldorf, New Delbi TOKYO OFFICE: Yanagiya Hldg., No. 2-1, Tori 2-Chome,

Chuo-ku, Tokyo, Japan

Liquid Pressure up to l 5,000kg fcml

Solid Pressure up to 1 OO,000kg/cm2

for Production and Research Purposes

Super High Pressure Generator Unlt Super High Pressure Reaction Vessel Super High Pressure Measurement Gauge Super High Pressure Equipment

Other Malor Products:

Fertilizer Plant, Cement Plant, Oxygen Plant, Rolled Steel Products, Steel

Castings &Forgings, General Industrial

Machinery, Light Metal Alloy Cas. flogs 8c Forgings, Titanium Products,

Arc Welding Electrodes, Small Tools, Non Ferrous Metals & Their Products,

Sugar Cane Milling Plant and others.

Page 10: Title Cover Issue Date URL ...repository.kulib.kyoto-u.ac.jp/dspace/bitstream/2433/46889/1/... · URL Right Type Others ... ANew Method of Determiningthe Transition Pressure of Mercury

The Review of Physical Chemistry of Japan Vol. 37 No. 1 (1967)

As specialists we have contributed to the world industries since 2924.

DA/K/N FLUOROCHEMICAL PRODUCTS

FLUOROCARBON REFRIGERANTS DAIFLON-11 CCI,F DAIFLON-12 CCI,F, DAIFLON-13 CC1F, DAIFLON-21 CHC1,F DAIFLON-22 CHC1F, DAIFLON-11? CCI,F-CCI,F DAIFLON-113 CCI,F-CC1F: DAIFLON-114 CC1F,-CC1F, DAIFLON-115 CC1F; CFe DAIFLON-152 CH,-CHF_DAIFLON-500 12/152 (73.8/26.2°owt.) DAIFLON-502 22/115 (48.8/51.5g'owt.)

FLUOROCARBON SOLVENTS DAIFLON SOLVENT S-1, S-3, S-3

AEROSOL PROPELLENiS DAIFLON Aerosol 50/50, DAIFLON Aerosol 85/15

FLUOROCARBON POLYMERS POLYFLON Polytetrafluoroethylene NEOFLON Copolymer of tetrafluoro-

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propylene DAIFLON Polymonochlorotrifluoro-

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trifluoroethylene

FLUOROCHEMICALS Anhydrous Hydrofluoric Acid Aqueous Hydrofluoric Acid Benzotrifluoride and its derivatives Tributyltinfluoride (Antifouling paint) FRATOL CH..F000Na (Rondenticide) FIISSOL CH,F000NH, (Agricultural chemical) Other Fluorides

For imformation about products write below address.

DA/KlN KOGYO CO., LTD. Head Office: Shin-Flonkyu Bldg., 8, Umodo, Kifa-ku, Osoka, Japan.

Tel: Osako 312-1201 Coble Address : DAIKINOKAY

Tokyo Branch s Fuji Bldg., 5, 2-chome, Yaesu, Chuo-ku, Tokyo, Jopon. Tel : Tokyo 272-3211

Cable Address: TKYDAIKINOKAY