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Upgrading the Value of Bitumen by Using Performance Grading Hussain U. Bahia Director of MARC, University of Wisconsin- Madison, USA May 2 nd , 2016, Dubai, UAE

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Page 1: Upgrading the Value of Bitumen by Using Performance Gradingmeb2016.weebly.com/uploads/6/1/0/3/61034471/12.dr_hussain_bahia.pdfD5546 99 99 99 99 10 Polymer Content , min, % by mass

Upgrading the Value of Bitumen by Using

Performance Grading

Hussain U. Bahia Director of MARC, University of Wisconsin- Madison, USA May 2nd , 2016, Dubai, UAE

Page 2: Upgrading the Value of Bitumen by Using Performance Gradingmeb2016.weebly.com/uploads/6/1/0/3/61034471/12.dr_hussain_bahia.pdfD5546 99 99 99 99 10 Polymer Content , min, % by mass

Bitumen and Pavement Life Cycle Cost (LCC)

• Pavement LCC depends on bitumen quality Better quality = reduce life cycle cost, and = less

environmental impact.. Sustainable roads

• Bitumen plays a big role in pavement life Bitumen value should be proportional to its role; Better

bitumen should be worth more

• Performance Grading system can define value The Pen 60/70 and VG grading systems could give inaccurate

definition of factual quality

• Modification allow upgrading bitumen value

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Deterioration of Asphalt Pavements Life Cycle Cost concepts

Ro

ad

Co

nd

itio

n

Pavement Age or Traffic

Min. Acceptable Rating

Resurfacing

Corrective Maint.

Reconstruction

Restoration

Preventive Maint.

New

Road

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Bitumen also affect Environmental Impact Embodied Carbon in Asphalt Most critical: Drying and Bitumen

Component CO2 eq/ Ton of Asphalt

Aggregate 4

Heating & Drying 21 (42%)

Bitumen 18 (36%)

Mixing 4

Delivery 3

Total 50

Source: Loveday 2009

82%

Page 5: Upgrading the Value of Bitumen by Using Performance Gradingmeb2016.weebly.com/uploads/6/1/0/3/61034471/12.dr_hussain_bahia.pdfD5546 99 99 99 99 10 Polymer Content , min, % by mass

Modified Bitumen = More durability = (Less cost , less CO2+Less Energy ) per year

Less Durable: Initial cost/

emissions spread on shorter life

More Durable: initial cost/CO2

emissions spread on longer life.

Time

Condition

life Cycle More important than Initial

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http://www.eurobitume.eu/bitumen/production-process

Bitumen cost is always a function of crude oil; but there is

no clear system/scale to upgrade value & increase profit

Page 7: Upgrading the Value of Bitumen by Using Performance Gradingmeb2016.weebly.com/uploads/6/1/0/3/61034471/12.dr_hussain_bahia.pdfD5546 99 99 99 99 10 Polymer Content , min, % by mass

The Performance Grading System allows defining Quality in terms of Pavement Condition Indictors (PCIs)

Thermal

Cracking

Fatigue

Cracking

Permanent

Deformation

(mixing &

compaction)

Performance Grade : PG 76-10

- 10 37 76 135

1. Workability:

Production/cons

truction

4. Thermal Cracking 3. Fatigue

Cracking

2. Rutting

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The New Grading System- AASHTO M332 1. Climate: xx-yy 2. Traffic conditions- Trucks (S,H,V,E) 3. Reliability , and 4. Modification

PG 76(V)-10 Performance

Grade Summer

Average 7-day

max pavement

design temp

Winter

Min pavement

design temp

Traffic

Volume &

Speed

Better Value/Price

Scale

Page 9: Upgrading the Value of Bitumen by Using Performance Gradingmeb2016.weebly.com/uploads/6/1/0/3/61034471/12.dr_hussain_bahia.pdfD5546 99 99 99 99 10 Polymer Content , min, % by mass

Example of PG Grading- Qatar-QCS

Item Property Test

Method

Criteria

PG76S-10

PG76H-10

PG76V -10

PG76E -10

1 Traffic Volume: 20–Year Design ESALs, millions

< 10 10 – 30 30-50 ≥ 50

2 If Traffic Speed is less than 20 km/hr (Standing/Intersections)

Use grade PG76H-10

Use grade PG76V-10

Use grade PG76E-10

Use grade PG76E-10

3 Flash Point, min, C ASTM D92

230 230 230 230

4 Viscosity @ 135C, max, Pa.s ASTM D4402

3.00 3.00 3.00 3.00

5 Dynamic Shear, G*/sinδ @

76C and 10 rad/s, min, kPa ASTM D7175

1.00 1.00 1.00 1.00

6

Separation Test: Absolute

Difference between G* @ 76C and 10 rad/s of Top and Bottom Specimens, max, %

ASTM D7173

20 20 20 20

7

Time Stability: Average of G*

values measured in Separation test (item 6) divided by the initial G* value measured in (item 5), range

0.8 - 1.2 0.8 - 1.2 0.8 - 1.2 0.8 - 1.2

8 Particulate Retained on Sieve Test, %

PWA 100 0 0 0 0

9 Solubility, min, % ASTM D5546

99 99 99 99

10 Polymer Content, min, % by mass

Supplier Certificat

e Required

2.0 2.0 3.0 3.0

Rolling Thin Film Oven (RTFO) Residue

11 Mass Change, max, % ASTM D2872

1.00 1.00 1.00 1.00

12 Dynamic Shear, G*/sinδ, @

76C and 10 rad/s, min, kPa ASTM D7175

2.20 2.20 2.20 2.20

13 MSCR, Jnr3.2 @ 76C, max, kPa-1

ASTM D7405

4.50 2.00 1.00 0.50

14 MSCR, Recovery R3.2 @ 76C and 3.2 kPa, %

Not applicable

Not applicable

Not applicable

Not applicable

MSCR, Jnr-diff @ 76C, % Not

applicable Not

applicable Not

applicable Not

applicable

Better Quality , Better Return

on Investment = Higher Price

Technical

Quality

Criteria

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Can better bitumens fetch higher price? Yes… example from the region

Product

Quality

Price per M. Ton

(QAR)

Percent Price

Increase

Pen 60/70 1,470 0.0

PMB (PG 76-22) 1,992 36%

PMB (PG82-22) 2,105 43%

PMB – Special Grade 2,223 51%

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Cost – Benefit Analysis of PMBs

Users:

Very high return on

Investment

Producer:

Specialty product=

Better profit margin

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Economics of Modified asphalts

12

NPV = Net Present Value

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The Production of Pen 60/70 Bitumen products not well defined

The final bitumen product can be produced to technical

specification either:

1. Directly in the refining process or by blending

bitumens with different physical properties.

2. Blending of higher and lower viscosity residues in

the required proportions.

3. The blending may take place at the refinery, at

terminals or at a third party facility.

Finished products can have very variable quality !!

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Risks to Quality .. and Real value Uncertainty drives price & profit down

• Blending from different sources could be a problem.

Not all chemistries are similar.

• Oxidation changes chemistry, molecular weight, and

could upset balance of bitumen.

• De-asphalted bitumen is not really a paving grade

material.

• It is very hard to tell when Pitch is used in bitumen

production

• Soft bitumen-Vacuum Tower Bottoms (VBTs) are

abundant.

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Examples of low cost VTB based feed stock in the GCC region

Property Source 1 Source 2 Source 3

Pen at 25 C, dmm 119 169 60

R&B Softening Pt, °C 43 34 51

Ductility, cm 84 >125 >125

Flash point , C 321 328 346

R. Vis at 135C 212 100 388

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The fair solution: Better Bitumen Grading System- PG 1. Climate 2. Traffic conditions- Trucks 3. Reliability , and 4. Cost/Modification

PG 76 (X)-10 Performance

Grade Summer

Average 7-day

max pavement

design temp

Winter

Min pavement

design temp

Traffic

Volume &

Speed

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The fair solution: Benefits of Bitumen Modifiers- Asphalt Institute

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1) Build more roads Pave more miles by reducing road

thickness, while maintaining road performance

OR

2) Build better roads Extend the maintenance cycle by 5 yrs

thereby reducing maintenance costs

Infrastructure dollars are extremely limited,

while demands to build & improve roads continues to grow

Stretch paving dollars with Modified Binders

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Type of

Highway

Approximate

Speed MPH

Not

Modified

7.5%

SBS

2.5 %

HON

% Increase in Service Pavement Life

Expressway 60- 80 0% 64% 107%

Intersections ~ 5 0% 173% 218%

% Reduction in Asphalt Layer Thickness

Expressway 60- 80 0% 9% 14%

Intersections ~ 5 0% 20% 22%

Benefits Quantified Using the Current AASHTO 1993 Design

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4 in.

6 in.

6 in.

Top Layer

Middle Layer

2.2 in.

6 in.

6 in. Base Layer

Savings 1.8 in.

Significant savings in cost & natural resources

by reducing pavement top layer Thickness

Polymer Additive

Aggregate Base

Subsoil

Average Road

Top Layer

Middle Layer

Base Layer

Aggregate Base

Subsoil

45%

Reduction

With

Specific

PMBs

Page 21: Upgrading the Value of Bitumen by Using Performance Gradingmeb2016.weebly.com/uploads/6/1/0/3/61034471/12.dr_hussain_bahia.pdfD5546 99 99 99 99 10 Polymer Content , min, % by mass

Build better roads and improve bitumen profit margin

• Reduce total road life costs by 35%

Extend the maintenance cycle by 5 yrs using specialty additives…

Today (4 in)

With Titan

Additive (4 in)

Desired Road Life 50 years 50 years

Initial road cost/mile $117K $126K

Maintenance cycle* (maintain <0.25 in rutting)

Every 7 yrs Every 12 yrs

Maintenance cycle cost/mile** $70K $75K

Total # of maintenance cycles 6 cycles 3 cycles

Total Road Life Cost $537K $351K

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Environmental Impact – Effect of Polymers on compaction effort of mixtures at 145 oC

Sample N92- 8 % air-voids

N96 – 4% air-voids

% Change in compaction effort

Control 36 111 0 Polymer 1: SBS* 32 100 -10 Polymer 2: Titan 26 86 -23

Hybrid 24 76 -41

• Titan and Hybrid can reduce compaction effort ( up to 40%)

• Or allow wider temperature range for compaction

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Concluding Remarks- Upgrading Bitumen Value and Profit Margin

• It could be a Win-Win for User and Producer

• Pen grading is a threat not only to pavement life, but also fair

value and profit margin

– Oxidation, rectification, de-asphalting and cracking are common

refinery practices that present risk to quality

• Measures to check and prevent poor quality bitumen should

be used. Performance grading (PG) is a ready solution

• Modification can reduce life cycle cost and Environmental

impact is a significant cost

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Thank You

•Organizers of the conference

•Sponsors /partners of MARC

Hussain U. Bahia, Ph.D. [email protected]

UWMARC.org

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