waterborne uv curable resins - lux 250 - pharos … · • p s g d e • y) y s y t l. n g sm •...
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New waterbased UV curing PUD‘s for industrial wood finishing
Laurie MorrisScientist – Technical ServiceAlberdingk Boley, Inc.
Why use UV Curable Coatings?
Benefits• Little-no solvent emissions• Excellent performance• Smooth finish
Challenges• High initial equipment
costs• Difficult to cure thick • Smooth finish
• Rapid production• Less floor space • Extended open time
during use (recyclable)• Low cost per finished sq/ft
• Difficult to cure thick coatings
• Complex geometries can be difficult
• Some components are skin/eye irritant
Why Waterborne UV?
Benefits• Low viscosity w/o reactive
diluents • Zero VOC capable• Low build appearance• Water clean up
Challenges• Some grain raising• Drying ovens required• Humidity dependence• Finish defects (incomplete dry)• Water clean up
• High hardness & flexibility• Little/no shrinkage - use of
high MW resins• Excellent adhesion • Resoluble / reclaim
overspray• Easier equipment retrofit• Gloss & viscosity control
• Finish defects (incomplete dry)
Radical Polymerization
• Ultraviolet (UV) curing is a photochemical process where intense UV light is used to cure coating
• Photopolymerization is achieved through a free radical mechanism
• A photoinitiator is the “catalyst” for the free radical • A photoinitiator is the “catalyst” for the free radical mechanism
• UV light splits the photoinitiator into free radicals• The radicals react with the double-bonds of the UV-
dispersion• This produces more free radicals and the reaction
process continues until terminated
Polymerization Reaction
Photoinitiation IN R* initiator radicals
Start R* + M R-M*
UV Light
Start R* + M R-M*radical resin intermediate
Growth R-M* + M R-M-M*
Termination R-M* + *M-R R-M-M-R
Alberdingk ® LUX 250 VP
• Solvent free aliphatic UV curable polyester polyurethane dispersion
• Excellent flexibility• Very fast water release• Very fast water release• Excellent chemical and
stain resistance• Excellent scratch
resistance• Excellent boiling water
resistance as measured by NEMA test
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ALBERDINGK® LUX 250 VP
• High blocking resistance• Low wood grain raising• Very good wood warmth• Very good wood warmth• Good wetting of pigments
and matting agents• Dual curing possible• Easy to recycle
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ALBERDINGK® LUX 250 VP
Physical Properties
Solids (%) 39 - 41pH 6.5 – 8.0
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pH 6.5 – 8.0Viscosity (cps) 10 - 500MFFT(oC) approx. 0Koenig Hardness prior to UV cure (sec) 20Koenig Hardness after UV cure (sec) 160
ALBERDINGK® LUX 250 VP
Applications include:- Clear and pigmented KCMA coatings- Clear and pigmented Furniture coatings- Cure on site parquet coatings- Clear plastic coatings (ABS, PC, PVC, PET)- General metal coatings
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Starting Point Formulation – Transparent, Matt Topcoat
Raw Material Amount Type Supplier
ALBERDINGK® LUX 250 94.60 UV resin Alberdingk Boley, Inc.
BYK 028 0.40 Defoamer BYK Chemie BYK 346 0.30 Surfactant BYK Chemie
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BYK 346 0.30 Surfactant BYK Chemie Ultralube D 816 1.50 Wax Keim Additec Acematt TS-100 2.00 Matting Agent Evonik Irgacure 500 1.00 Photoinitiator BASF DSX 1514 0.20 Rheology Modifier Cognis
Curing Conditions:
Pre-drying: 5 – 10 minutes @ 50o C, convection dryer Feed: 15 – 20 feet/minute UV Curing: 1 Hg lamp, 80W/cm
Chemical Resistances:
Test Chemicals Test Duration Test Results
(0 – 5 5 = Best) Ethanol (48%) 1 hour 5
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Ethanol (48%) 1 hour 5
NH4OH (10%) 1 minute 5
Water 16 hours 5
Coffee (4%) 16 hours 5 Tea (1%) 16 hours 5 Red Wine 5 hours 5 Coke 16 hours 5
Starting Point Formulation – White Topcoat
Raw Material Amount Type Supplier
ALBERDINGK® LUX 250 61.2 UV resin Alberdingk Boley, Inc.
Foamex 822 0.60 Defoamer Evonik BYK 094 0.20 Defoamer BYK Chemie BYK 346 0.30 Surfactant BYK Chemie Pigment paste 24.5 18% TiO2
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Pigment paste 24.5 18% TiO2 Glycol Ether DPM 2.90 Solvent Water 7.80 Water Irgacure 500 1.00 Photoinitiator BASF Irgacure 819 DW 1.20 Photoinitiator BASF DSX 1514 0.30 Rheology Modifier Cognis
Curing Conditions:
Pre-drying: 5 – 10 minutes @ 50o C, convection dryer Feed: 15 – 20 feet/minute UV Curing: 1 Ga-doped lamp, 120W/cm 1 Ga-doped + Hg-doped lamp, each 120 W/cm For additional crosslinking we suggest to add 10%of the following blend of polyisocyanates on total formulation weight: Bahydur XP 2487/1 in MPA (80/20). Pot life after addition = approximately 6 hours
Test Chemicals Test Duration
Test Results UV cure only
(0 - 5 5 = best)
Test Results Dual Cure
(0 - 5 5 = best) Ethanol 48% 1 hour 5 5
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Ethanol 48% 1 hour 5 5
NH4OH (10%) 1 minute 5 5 Water 16 hours 5 5 Coffee (4%) 16 hours 4 5 Tea (1%) 16 hours 5 5 Red wine 5 hours 4 5 Coke 16 hours 5 5
Flash off time
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Flash off time
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Flash off time
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Flash off time
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Flash off time
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Flash off time
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Flash off time
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Flash off time
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Flash off time
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Flash off time
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Flash off time
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Flash off time
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Flash off time
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Flash off time
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Chemical resistance (clear)
3
4
5
ratin
gLUX 250LUX 399
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0
1
2
ratin
g
1 h Etha
nol (4
8%)
5 h Etha
nol (4
8%)
1 h N
H3 (10
%)
16 h
Coffee
16 h
Water
test agent
LUX 399competitor 1
Conclusion
• ALBERDINGK® LUX 250 offers:- fast flash off - almost like ALBERDINGK® LUX 399- very high chemical resistance- superior mechanical resistances
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- superior mechanical resistances- excellent wood warming ( Anfeuerung )- very easy matting without sedimentation- highly pH stable
Thank you for your attention !!
want to know more ??
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want to know more ??visit us in booth 2841