1, PRODUCT AND COMPANY INFORMATION

Product ldentity: Nature's Element@ Web Out@

Recommended use ofthe chemical and restr¡ctions on use: Useto kill spiders, prevent spider webs on any surface. This product canalso be used as a contact pesticide to kill pest insects and othergeneral pests.

Manufacturer: Nisus Corporation100 Nisus Drive

' Rockford, TN 37853

Telephone: . Phone: (800) 264-0870Fax: (865) 577-5825

Emergency Phone: 800-424-9300 (CHEMTREC)

SDS Date of Preparation: 4/28115

2. HAZARDS IDENTIFICATION

GHS Classification:

GHS Label Elements

Signal Word: Warning

Statements of HazardH316 Causes mild skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye initation.H4'12 Harmful to aquatic life with long lasting effects.

Precaut¡onary StatementsP261 Avoid breathing mists or spray.P264 Wash hands thoroughly after handling.P273 Avoid release to the environment.P280 Wear protective gloves and eye protection.P305 + P351 + P338 lF lN EYES: Rinse cautiousty with water forseveral minutes. Rêmove contact lenses, if present and easy to do.Continue rinsing.P302 + P352 lF ON SKIN: Wash with plenty of soap and water.P333 + P313 lf skin irritation or rash occurs: Get medical attention,P362 Take off contaminated clothing and wash before reuse.P501 Dispose of contents and container in accordance with local andnational regulations.

Physical Health Environment

Not Hazardous

Eye Damage Category 2Skin lrritant Category 2Skin SensitizationCatesory 3

Aquatic ChronicCategory 3

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SAFETY DATA SHEET

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WEBOUTHealth Emergencies: CHEMTREC@ (S00) 424-ggOO

3, COMPOSITION/INFORMATION ON INGREDIENTS

Gomponent CAS No. AmountWater 7732-18-5 30-40o/o

Vinegar/DiluteAcet¡c Acid 8028-52-2 30-40!o

lsopropanol 67-63-0 <1Oo/ø

Sodium lauryl sulfate 151-21-3 <4.5o/o

Citronella Oil 8000-29-1 <3o/o

Lemongrass Oil 8007-02-1 <3o/o

Thyme Oil 8007-46-3 <3o/o

The exact formulation is being withheld as a trade secret.

4. FIRST AID MEASURES

Eye: lmmediately flush victim's eyes with large quantities of water forat least 15-20 minutes, while holding the eyelids apart. Removecontact lenses if easy to do so. Continue rinsing. Get immediatemedical advice/attention.Skin: Remove contaminated clothing and shoes. Flush thoroughly withwater for several minutes. Get med¡cal attention if irritation or rashoccurs. Launder clothing before re-use.lngestion: Do not induce vomiting unless directed to do so by medicalpersonnel. Get medical attention if you feel unwell.lnhalation: Move victim to fresh air. Get medical attention if irritationdevelops.

Most lmportant Symptoms: Direct contact with eyes may causemoderate to severe irritation or burns with possible eye damage. Maycause moderate skin irritation. May cause skin sensitization. lnhalationof mist or vapors may cause respiratory tract irritation.

lndication of ¡mmediate medical attention/special treatment:lmmediate medical attention is required for eye contact.

5. FIRE FIGHTING MEASURES

Suitable (and Unsuitable) Extinguishing Med¡a: Use mediaappropr¡ate for surrounding fire. Cool fire exposed containers andstructures with water.Specific hazards arising from the chem¡cal: This product is notflammable or combustible. A sol¡d stream of water or foam directedinto hot, burning liquids can cause frothing. Burning may produceoxides of carbon.Spec¡al Protective Equipment and Precautions for Fire-Fight¡nglnstructions: Firef¡ghters should wear positive pressure self-containedbreathing apparatus and full protective cloth¡ng. Contain all runoff.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment, and EmergencyProcedures: Evacuate spill area and keep unprotected personnelaway. Avoid contact w¡th the eyes, skin and clothing. Avoid breathingmists. Wear appropriate protective clothing as described in Section 8.Avoid releases to the environment.

Methods and Materials for Containment and Cleaning Up: Dikeand collect liquid or absorb with an inert absorbent and place inappropriate containers for disposal. Prevent spill from entering sewersand water courses. Report releases as required by local, state andfederal authorities.

7. HANDLING AND STORAGE

Precautions for Safe Handling: Avoid contact with the eyes, skin andclothing. Avoid breathing mists. Wear protective clothing andequipment as described in Section 8. Use with adequate ventilation.Wash thoroughly with soap and water after handling. Removecontaminated clothing and wash before reuse. Keep containers closedwhen not in use.

Nonrefillable container. Do not reuse containers. Product residues inempty containers can be hazardous. Follow all SDS precautions whenhandling empty containers.

Cond¡t¡ons for Safe Storage, lncluding Any lncompatibÍl¡t¡es:Store in a cool, dry, well-ventilated area away from incompatiblematerials. Keep out of reach of children and pets. Do not store in directsunlight. Keep containers tightly closed. Protect from physicaldamage. Keep in locked storage.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Acet¡c Acid 10 ppm TWA, 15 ppm STEL ACGIH TLV10 ppm TWA OSHA PEL

lsopropanol200 ppm TWA, 400 ppm STEL ACGIH TLV400 ppm TWA OSHA PEL

Citronella Oil None EstablishedLemonqrass Oil None EstablishedThyme Oil None Established

Engineering Controls: Use with adequate general or local exhaustventilation to maintain exposure levels below the occupationalexposure limits.Respiratory Protection: ln operations where exposure levels areexceeded, a NIOSH approved respirator with dusvmist cartridges orsupplied air respirator appropr¡ate for the form and concentration of thecontaminants should be used. Select¡on and use of respiratoryequipment must be ¡n accordance with OSHA 1910.134 and goodindustrial hygiene practice. Refer to the product label for additionalinformation.Skin Protect¡on: Wear nitrile or latex gloves.Eye Protect¡on: Wear safety goggles where splashing is possible.Other: Wear long-sleeve shirts, long pants, socks and shoes whenusing this product. Suitable washing facilities should be available in thework area.

9, PHYSICAL AND.CHEMICAL PROPERTIES

Appearance And Odor: Clear to tan liquid, opaque when mixed with alemon & vinegar odorPhysical State: Liquid Odor Threshold: Not establishedVapor Density: Not determinedlnitial Boiling PoinURange: 212"F (100"C)Solub¡l¡g ln Water: 100% forms emulsionVapor Pressure: Not determinedRelative Density: Not determined Evaporation Rate: Not determinedMelting/Freezing Point: Not determined pH: 6.0Percent Volatile: -15% as alcohol, acetic acid and essential oils,-75% as waterOctanol/WaterCoefficientl Notdetermined Solub¡l¡ty: WaterDecomposit¡on Temperature: Not determinedViscosity: Not determined Flammability (solid, gas): NiAFlashpoint: >220'F (>104.4"C) TCCAutoignit¡on Temperature: NoneFlammable Limits: LEL: Not determined UEL: Not determined

IO. STABILITY AND REACTIVITY

Reactivity: Not normally reactiveChemical Stability: Stable under normal storage and handlingconditions.Possibility of Hazardous Reactions: Material is not known topolymerize.Conditions to Avoid: Exposure to strong oxidizing agents.lncompat¡ble Mater¡als: Avoid strong oxidizing agents and strongacids.Hazardous Decomposition Products: When heated todecomposition emits oxides of carbon.

1 I, TOXICOLOGICAL ¡NFORMATION

HEALTH HAZARDS:lngestion: lngestion may cause gastrointestinal irritation, nausea andvomiting.lnhalation: lnhalation of mists may cause irritation of the nose, throatand upper respiratory tract.Eye: Causes serious irritat¡on and burns with redness, pain andtearing. May cause permanent eye damage.Skin: May cause moderate skin irritation. May cause an allergic skinreaction (sensitization)Chronic: None known.

Sensitization: This material may cause sensitization.Carcinogen¡c¡ty: None of the components is listed as a carcinogen orsuspected carcinogen by IARC, NTP or OSHA.Germ Cell Mutagenicity: Not expected to cause germ cellmutagenicity.Reproductive Toxicity: Not expected to cause reproductive toxic¡ty.

Numerical Measures of Toxicity:Product Toxicitv Data:Oral rat LDso: >5000 mg/kg (calculated)

Component Toxicitv Data:Acetic Acid: Oral rat LDso: 3310 mg/kglsopropanol: Oral rat LDs¡: 5840 mg/kgCitronella Oil: No tox¡city data availableLemongrass Oil: Oral rat LDso: >5000 mg/kg, Dermal rabbit LD5¡:>5000 mgikgThyme Oil: Oral rat LD50: 2840 mg/kg, Dermal rabbit LD5¡: >5000mg/kg

12. ECOLOGICAL INFORMATION

Ecotoxicity:Thyme Oil: 96 hr LCso Rainbow trout: 16.1 mg/L

This product is classified as harmful to the aquatic env¡ronment andharmful to the aquatic environment w¡th longlasting effects. Releasesto the environment should be avoided.

Persistence and Degradability: No data available for mixture.

Bioaccumulat¡ve Potential: No data available for mixture.

Mobility ¡n Soil: No data available for mixture.

Other Adverse Effects: No data available for mixture. \\

1 3. DISPOSAL CONSIDERATION

Dispose in accordance with local, state and federal environmentalregulations. The materials resulting from clean-up operations of a spillmay be hazardous and, therefore, subject to specific regulations.Package, store, transport and dispose of all clean-up materials andany contaminated equipment in accordance with all applicable federal,state, and local regulations. Shipments of waste materials may besubject to man¡festing requirements per applicable regulations.Appropriate disposal will depend on the nature of the waste and shouldbe performed by competent and properly permitted contractors.Ensure that all responsible federal, state and local agencies receiveproper not¡fication of spill and disposal methods. Spills or releasesshould be reported, if required, to the appropr¡ate local, state andfederal regulatory agencies.

1 4. TR.ANSPORTATION INFORMATION

DOT Hazardous Materials Descr¡ption: Not Regulated

I 5. REGULATORY INFORMATION

FIFRA: This product is a 25b exempt product.

CERCLA: This product has an RQ of 20,000 lbs (based on the RQ ofAcetic acid of 5,000 lbs present at 15-25%). Some states have morestringent reporting requirements. Report all spills in accordance withlocal, state, and federal regulations.

SARA Hazard Category (31113121t Acute Health

SARA 313: This product contains the following chemicals subject toAnnual Release Reporting Requirements Under SARA Title lll, Section313 (40 CFR 372): None

EPA TSCA lnventory: All of the ingredients in this product are listedon the EPA TSCA lnventory.

16. OTHER INFORMATION

NFPA Rating: Health = 0 Flammability = 0HMIS Rating: Health = 1 Flammability = Q

SDS Revision History: 02128115: New SDS04128115: Revised

lnstabil¡ty = 0Physical Hazard = 0

WARRANTY DISCLAIMERThe information, data and recommendations contained herein arebelieved to be accurate but may not be all inclusive and should only beused as a guide. The information is furnished upon the condition tñatthe person receiving ¡t shall make his own determination of thesuitability of the product for his particular use and on condition thatthey assume the risk of the use thereof. With respect to thispublication and the product related thereto, unless othenivise expresslyprovided by Manufacturer in writ¡ng, MANUFACTURER MAKES NOEXPRESS OR IMPLIED WARRANTY OF MERCHANTABILITY,FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHEREXPRESS OR IMPLIED WARRANTY.

Remedy/Liab¡tity Lim¡tsThe exclusive remedy for losses or damages resulting from thispublication or the related product (including claims based on contract,

negligence, sh¡ct liability or other legal theories) shall be limited to, atManufacturer's sole election, one of the following:

1, Refund of purchase pr¡ce paid by buyer or user for productbought, or

2. Replacement of amount of product used.Manufacturer shall not be liable for losses or damages resulting fromuse of this publication or handling or use of this product, lN NO CASESHALL MANUFACTURER BE LIABLE FOR CONSEQUENTIAL ORINCIDENTAL DAMAGES OR LOSSES, INCLUDING WITHOUTLIMIT, HEALTH RELATED DAMAGES OR INJURIES.

The terms of this Warranty Disclaimer and Remedy/Liab¡l¡ty Limitscannot be varied by any written or verbal statements or agreements.No employee or sales agent of Manufacturer or the seller is authorizedto vary or exceed the terms of this Warranty Disclaimer or Lim¡tationof Remedies in any manner.

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100 Nisus Drive . Rockford, TN 37853 USA. (800) 264-0970Web Out, Nature's Element and N¡sus Corporat¡on ar6 registêred trademarks of N¡sus Corporation. @2015 N¡sus Corporation . #WO-SDS-04281S

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