1TBTAK - MAM, 2Yldz Teknik University, 3ALTACA ENERJ
Production of Biocrude Oil by Waste Biomass CatLiq Process and Characterization of Oils Parvana Aksoy1, Mehmet nsal1, Haydar Livatyali2 H. Alper nolu3 1TBTAK - MAM, 2Yldz Teknik University, 3ALTACA ENERJ International Congress and Expo onBiofuels & Bioenergy August 25-27, 2015 Valencia, Spain TUBITAK MRC TBTAK GEBZE CAMPUS 8 km2 ZMT BAY GEBZE
Environment and Clean Production Energy Food Genetic Engineering & Biotechnology Materials Chemistry Earth and Marine Sciences GEBZE TURKISH INSTITUTE OF INDUSTRIAL MANAGEMENT INFORMATICS AND INFORMATION SECURITY ADVANCED TECHNOLOGIES RESEARCH CENTER 8 km2 ZMT BAY MARMARA TECHNOPARC INC. NATIONAL METROLOGY INSTITUTE CATLQ Pilot and Demo Scale Systems Process Scheme Catalytic Liquefaction (CatLiq) Catalytic Liquefaction
Sample before separation Catalytic Liquefaction
Separation from ash, minerals and water by centrifugation Extraction with solvent to separate from ash and minerals Filtration Properties of Feedstock
Parameter Original (bark) Dry (bark) Original (sawdust) (sawdust) Original (sewage sludge) Dry (sewage sludge) Original (papermill sludge) (papermill sludge) Analysis Method Moisture (%) 16,79 - 57,79 93,28 77,7 - ASTM D Ash (%) 7,13 8,56 0,15 0,34 3,1 46,2 1,75 7,84 ASTM E (Reapp.2007) Volatile Matter (%) 56,37 67,74 35,01 82,94 3,33 49,58 18,79 84,24 Fixed Carbon (%) 19,72 23,69 7,05 16,71 0,29 4,22 1,77 7,92 ASTM D a Total Sulphur (%) 0,06 0,07 0,01 0,02 0,08 1,16 0,04 0,16 ASTM D Lower Heating Value (kcal/kg) 3597 4434 1558 4445 -331 2720 396 3692 ASTM D Higher Heating Value (kcal/kg) 3910 4699 2006 4753 196 2916 890 3989 ISO Properties of Feedstock
C H N S O* Ash Bark 56,67 4,94 0,21 0,07 31,55 8,56 Saw dust 54,32 5,99 0,10 0,02 39,23 0,34 Sewage sludge 25,3 3,09 4,34 1,16 19,91 46,2 Paper mill sludge 44,06 5,74 0,44 0,16 41,76 7,84 Method ASTM D ASTM D ASTM D 3176 ASTM E (Reapp.2007) Properties of Biocrude Oil
Parameter bark Saw dust Sewage sludge Paper mill sludge Method Density (gr/cm3) (15C) 1,0722 1,1204 - 1,0942 ASTM D 4052 Water content 5,2 22,2 ASTM D 95 Looks/smell Dark black Heating value (kcal/kg) 8204 7715 8845 8359 ASTM D 240 Properties of Water Fraction
Parameter Results Analysis Method Looks/smell Lightyellow/odorous Bark 6459 mg/L SM 5310 B Saw dust 13110 mg/L Sewage sludge 1069 mg/L Paper mill sludge 10430 mg/L Analysis of Gases Gases Concentration Bark Saw Dust Sewage Sludge
Paper mill sludge Hydrogen (wt %) 11,06 15,05 16,20 11,21 Methane (wt %) 1,57 1,92 4,62 0,93 Ethane (wt %) 0,48 0,11 0,62 0,04 Ethylene (wt %) 0,16 0,13 0,65 0,15 Propane (wt %) 0,02 0,35 Cyclo-propane (wt %) 0,22 - 0,00 0,38 Carbon monoxide (wt %) 2,18 1,64 0,59 0,91 Carbon dioxide (wt %) 84,31 81,11 76,98 86,37 Total Sulphur (ppm) 410 333 473 Boiling Point Distribution of Biocrude and Crude Oil
Result 204 CatLiq (waste of biogas system) 207 CatLiq (vinasse) API 27 nitial B. P. (C) 35,5 84,0 93,0 TBP %10(C) 178,5 139,0 183,5 TBP %20 (C) 264,5 198,5 243,0 TBP %30 (C) 294,0 224,5 297,0 TBP %40 (C) 296,0 251,5 343,5 TBP %50nin (C) 288,0 366,0 TBP %60 (C) 322,0 366,5 TBP %70 (C) 296,5 361,0 - Decomposition Temp.(C) 365,5 Comparision with Crude Oil
C H N S O* Ash Sewage Sludge as a feedstock 25,3 3,09 4,34 1,16 19,91 46,2 CATLIQ OIL 72,34 9,34 0,39 5,20 12,73 Crude Oil 84-87 11-14 0 - 1 0 - 6 0 - 2 Parafinic Hydrocarbons Naphthenic Hydrocarbons Aromatic Hydrocarbons Oxygenated Compounds Sulfur compounds CATLIQ OIL %13,957 %45,61 %14,623 %25,81 < % 0,5 Crude Oil %28 %45 %15 %3 %6 On-going Studies On-going Studies Start up studies of demo scale CatLiq system
Upgrading of Biocrude Acknowledgements TUBTAK TEYDEB Program for support Demo Scale Plant COLLABORATION OPTIONS
HORIZON 2020 InFO DAY The EU Framework Programme for Research and Innovation THANK YOU