2015 annual report overburden groundwater …
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2015 ANNUAL REPORT OVERBURDEN GROUNDWATER EXTRACTION AND TREATMENT SYSTEM
Southeastern Area – East Side Shoreham Facility Minneapolis, Minnesota (VIC Program Site ID VP5080)
Soo Line Shoreham Yard (SF) (SR380) Submitted To: Minnesota Pollution Control Agency 520 Lafayette Road North St. Paul, Minnesota 55155 Submitted By: Golder Associates Inc. 200 Century Parkway, Suite C Mt. Laurel, NJ 08054 USA Distribution: 1 E-copy Minnesota Pollution Control Agency 1 Copy/1 E-copy Canadian Pacific 1 CD Ashland, Inc. 1 E-copy Stinson Leonard Street 1 E-Copy Integral Consulting Inc. 1 E-copy Shoreham Area Advisory Committee 1 Copy Golder Associates Inc. April 2016 Project No. 023-6105
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Table of Contents 1.0 INTRODUCTION .............................................................................................................................. 1 2.0 OVERVIEW ...................................................................................................................................... 2 3.0 SYSTEM OPERATION .................................................................................................................... 4 4.0 PERFORMANCE EVALUATION ..................................................................................................... 6
4.1 Hydraulic Performance ....................................................................................................... 6 4.2 Groundwater Quality ........................................................................................................... 7 4.3 System Performance........................................................................................................... 9
5.0 CONCLUSIONS ............................................................................................................................. 11 6.0 REFERENCES ............................................................................................................................... 12
List of Tables Table 1 Well Construction Information Table 2 VOC Concentrations in Groundwater Extraction Wells Table 3 Total VOC Mass Removed
List of Figures Figure 1 Southeastern Area Well Location Map Figure 2 Groundwater Level Monitoring in Shallow Zone Wells Figure 3 Groundwater Level Monitoring in Intermediate Zone Wells Figure 4 Groundwater Level Monitoring in Deep Zone and OPD Wells Figure 5 Groundwater Potentiometric Contours – March 2015 Figure 6 Groundwater Potentiometric Contours – May 2015 Figure 7 Groundwater Potentiometric Contours – August 2015 Figure 8 Groundwater Potentiometric Contours – October 2015 Figure 9 Groundwater Potentiometric Contours Cross Section –March 2015 Figure 10 Groundwater Potentiometric Contours Cross Section –August 2015 Figure 11 Total cVOC Isoconcentration Contours – October 2015 Figure 12 Cumulative cVOC Mass Removal
List of Appendices Appendix A Time-History Concentration Graphs Appendix B Laboratory Results
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ABBREVIATIONS cVOCs chlorinated volatile organic compounds (sum of PCE, TCE, cis-1,2-DCE, 1,1,1-TCA, 1,1-DCA, 1,1-DCE and vinyl chloride) DCA dichloroethane DCE dichloroethene gpm gallons per minute L liter PCE tetrachloroethene TCA trichloroethane TCE trichloroethene µg micrograms VOCs volatile organic compounds
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1.0 INTRODUCTION This 2015 Annual Report has been prepared by Golder Associates Inc. (Golder) on behalf of the Soo Line
Railroad Company doing business as Canadian Pacific (CP). The purpose of this report is to document
the operation of the overburden groundwater remedial system in the southeastern area of the East Side
Shoreham Facility in Minneapolis, Minnesota (Facility). The design of the system was presented in the
Overburden Groundwater Remedial Design Report (Golder, 2007) (Design Report) submitted to the
Minnesota Pollution Control Agency (MPCA) in April 2007 and approved by MPCA on April 30, 2007. The
construction of the system was documented in the Response Action Implementation and Monitoring
Report (Golder, 2009) (RAIR) submitted to MPCA in April 2009 and subsequently approved. As detailed
in the Design Report and the RAIR, the purpose of the system is to address groundwater contamination in
shallow overburden near the Roundhouse and deep overburden between the Roundhouse and the
intersection of Central Avenue and 28th Avenue, NE. The RAIR documented system operation from
startup (November 8, 2007) through September 2008. Annual Reports have documented system
operations from October 2008 to 2014 (Golder, 2010, 2011, 2012, 2013, 2014a, 2015a). This 2015
Annual Report documents system operation from January 2015 through December 2015. This report has
been prepared in accordance with MPCA Voluntary Investigation and Cleanup (VIC) Guidance Document
#18 (MPCA, 2002).
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2.0 OVERVIEW As stated in the Design Report and consistent with MPCA guidance, the overburden groundwater
pumping system was designed to contain contaminated groundwater on an interim basis during
upgradient source removal activities until it could be demonstrated that the groundwater plume was stable
or decreasing in size, and would remain so without further pumping. The remainder of this section is a
general overview, as presented in the RAIR, of the geologic setting, contaminant profile prior to pumping
operation, system construction, and remedial goals.
As previously described in VIC Site reports, the geology in the vicinity of the Facility is comprised of
overburden units including surficial alluvium, till, outwash, and lacustrine clay. Bedrock units include the
loosely cemented St. Peter sandstone, St. Peter mudstone, and Prairie du Chien limestone (OPD), any of
which can directly underlie the overburden depending on location. For the purposes of remedial design,
groundwater has been assigned to the shallow overburden, intermediate overburden, deep overburden,
and OPD bedrock. Shallow wells are screened between 793 and 823 feet above mean sea level (ft
amsl), in near surface lithologies including glacial till, outwash, and St. Peter Sandstone. Deep wells are
screened between 659 and 699 ft amsl (approximately 70 feet to 150 feet beneath the water table) and
correspond primarily to deep outwash in the bedrock valley or equivalent depth in the mudstone unit of
the St. Peter Sandstone outside of the bedrock valley. Intermediate wells generally fall between these two
designations and are screened between 728 and 805 ft amsl, primarily in outwash and St. Peter
Sandstone. Shakopee wells are screened between 614 and 636 ft amsl (approximately 50 feet beneath
the top of the OPD). Wells monitored in these four zones are further detailed in Section 4.1.
The most significant impacts, prior to remediation, in overburden groundwater in the southeastern area at
shallow and intermediate depths were located beneath a portion of the Roundhouse footprint at
elevations generally greater than 775 ft msl. Geologically, glacial till, shallow outwash, and St. Peter
Sandstone units are present within the area of influence of the intermediate depth pumping wells. Active
soil source removal by soil excavation (Golder, 2015b) and soil vapor extraction (SVE) has been
completed in the Southeastern Facility area by CP (Golder, 2014b), and together with the pumping
system is expected to reduce the concentrations in shallow/intermediate overburden groundwater and
contain the migration of chlorinated volatile organic compounds (cVOCs) from the Roundhouse area.
The most significant impacts in deep overburden in the southeastern area prior to system operation were
located between the Roundhouse and the intersection of 28th Avenue and Central Avenue at elevations
generally below 775 ft msl. Geologically, the middle and deep outwash are present within the area of
influence of the deep overburden pumping system. Combined with the completed source removal by
SVE and with the operation of the intermediate depth pumping wells, the deep pumping wells are
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expected to reduce the concentrations in the deep overburden groundwater and contain the migration of
the cVOC plume.
The approved Design Report defined the performance goals for the pumping system, which included the
demonstration of hydraulic capture, plume stability, and attenuation. The Design Report also included the
results of pumping tests and groundwater modeling used to design the capture zones for the system,
based on addressing groundwater containing contaminant levels exceeding 100 ug/L of cVOCs. Plume
stability was defined as a steady state condition where the plume is no longer increasing in extent, and
can be demonstrated by overall stable concentration trends over time in wells located within and
surrounding the plume. Attenuation was defined as an overall decrease in plume mass over time and can
be demonstrated by decreasing concentration trends, particularly in wells located within the “core” of the
plume, where impacts are highest. The three pumping systems were designed to be operated throughout
source removal activities until the associated (shallow/intermediate overburden or deep overburden)
groundwater plume was stable or decreasing in size and would continue to do so without further pumping.
The southeastern area groundwater extraction and treatment system design includes the following
primary elements:
Five (5) extraction wells, each equipped with an electric, submersible groundwater pump.
Two (2) below-grade, double-walled force mains for conveyance of deep overburden groundwater to the treatment building.
Three (3) above-grade, heat-traced and insulated force mains for conveyance of intermediate overburden groundwater to the treatment building.
Treatment building with secondary containment. A below-grade, gravity discharge pipeline runs from the treatment building to an on-facility manhole located southeast of the treatment building. The manhole links to the city sanitary sewer, conveying the effluent to the Metropolitan Council Environmental Services (MCES) treatment plant. In December 2009, the system was modified to bypass the pre-treatment system and discharge directly to the sanitary sewer system (as detailed in the 2009 Annual Report) as MCES discharge limitations were satisfied without pre-treatment.
The layout of the system is shown in Figure 1 and construction of the southeastern area groundwater
extraction and treatment system was documented in the RAIR (Golder, 2009). Construction details of all
pumping and monitoring wells associated with the ES Extraction and Treatment system are summarized
in Table 1.
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3.0 SYSTEM OPERATION The southeastern area pump and treat system has been operating since November 9, 2007. During the
current reporting period (January 2015 to December 2015), the following operation and maintenance
issues were addressed:
Equipment Repairs and Maintenance
March 23-25: A scheduled well rehabilitation (see below for description) of RW06-28-I, RW07-39-SP, RW07-40-SP, and RW07-38-I was conducted by Stevens Drilling and Environmental (SDE).
August 3-6: A scheduled well rehabilitation (see below for description) of RW06-28-I, RW07-39-SP, RW07-40-SP, and RW07-38-I was conducted by SDE.
August 20: A new overload protector for the pump motor starter on RW07-38-I was installed by H2K Technologies Inc. During this repair, the pump in RW07-38-I was de-energized, but all other well pumps continued operating.
August 25: Following continuing intermittent pump stoppages, the pump motor electrical lead on RW07-38-I was believed to have failed, causing an electrical short. The electrical lead was replaced by SDE. During this repair, the pump in RW07-38-I was de-energized, but all other well pumps continued operating.
September 18: A replacement pump, motor, and electrical lead were installed in RW07-38-I
by Stevens Drilling and Environmental. It was suspected that during the electrical lead replacement on August 25, the pump and motor were accidentally damaged, and this work was performed by SDE. During this repair, the pump in RW07-38-I was de-energized, but all other well pumps continued operating.
Well Rehabilitation
The process of well rehabilitation, which includes mechanical and chemical treatments, included the
following steps. First, the drop pipes, pumps and motors were removed from each well for mechanical
cleaning, followed by the introduction of a chemical solution comprised of Aquaclear® AE and
Aquaclear® MGA into the wells. Aquaclear® AE is a liquid blend of acids and acid enhancers used to
remove biological and bacterial fouling. Aquaclear® MGA is a dry blend of granular acid and additives for
the removal of mineral scaling including from iron, manganese, and carbonate. The acid treatment was
surged mechanically within the wells using surge blocks, and the wells were then left undisturbed for 24
hours. At the conclusion of the 24-hour period, each well was redeveloped.
The process of redevelopment consisted of alternately pressurizing and depressurizing the water in each
well via vertical movement of a surge block to break loose particulates within the screen and well packing,
and then using a pump to purge the well water into an aboveground container until the groundwater was
observed to be clear.
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Containerized water from redevelopment is tested with a calibrated pH meter, and as necessary, sodium
bicarbonate is slowly added until the pH is within permitted limitations. The water is then discharged from
the holding tank to the East Side treatment building sump, and the sump pump conveys water to coalesce
with the treatment stream, the effluent stream of which is routed to the MCES sanitary sewer for disposal.
Based on the positive yields following rehabilitation, it is planned to continue performing rehabilitation
events through 2016 and the foreseeable future. This is scheduled to occur three times annually, every
four (4) months on wells RW06-28-I, RW07-38-I, RW07-39-SP and RW07-40-SP1.
1 RW06-27-BR continues to perform as designed and is not currently scheduled for rehabilitation.
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4.0 PERFORMANCE EVALUATION
4.1 Hydraulic Performance The hydraulic performance of the pumping system is assessed based on the groundwater levels
measured in monitoring wells within four monitoring zones previously defined for the VIC Site (i.e. Shallow
zone, Intermediate zone, Deep zone and OPD2). Groundwater elevations were measured quarterly by
the Site data collection and data management consultant (AMEC Foster Wheeler) (March 5, May 14-15,
August 6-7 and October 1-2) during the reporting period for the Site, including the following wells of the
Southeastern Area groundwater extraction system monitoring network:
Shallow zone: MW-406D, MW-407D, MW00-41-T, MW00-42-T, MW00-43-T, MW02-46-T, MW04-155-T, MW04-24-T, MW04-25-T, MW04-26-T, MW04-27-T, MW04-28-T, MW04-31-T, MW04-33-T, MW04-95-T and MW06-01-T
Intermediate zone: MW-403D, MW02-46-I, MW04-28-I, MW04-31-SP, MW04-33-SP, MW06-01-I, MW06-248-I, MW06-29-I, MW07-41-I, MW07-42-I, RW07-39-SP, RW07-40-SP, RW06-28-I and RW07-38-I
Deep zone: MW00-42-MS, MW00-43-BR, MW02-46-BR, MW03-56-BR, MW04-26-BR, MW04-29-BR, MW04-30-BR, MW06-01-BR and RW06-27-BR
OPD3: MW02-01-OPD, MW03-61-OPD, MW04-28-OPD and MW05-01-OPSH
Figure 1 shows the monitoring and extraction well locations in plan view. Hydrographs beginning in
March 2007 are shown in Figures 2 to 4 for the monitoring and extraction wells in each of the four
monitoring zones. From 2007 to 2010, water levels were generally stable from year to year, with
seasonal variations evident during the year, particularly during August which typically exhibited low water
levels. In 2011, water levels rose several feet on average and have remained at the higher levels, and
the typical seasonal variations are less evident. During 2015 the higher water levels persisted, and
notably in October the highest water levels for the year were observed. The same trends are exhibited
from Shallow to Deep zone with minor variations, as the Shallow zone (Figure 2) exhibits a wider range in
water level than the deeper zones (Figures 3 and 4), which generally vary over a smaller range and
exhibit less variability from well to well within the zone.
Contours of groundwater levels were developed as one line of evidence in evaluating the capture zone,
based on synoptic groundwater elevations. Figures 5 to 8 depict the groundwater equipotentials for each
of the four quarters in 2015 in the three overburden monitoring zones. The groundwater contours indicate
similar flow patterns and zones of pumping influences as have been observed since start up and reported
in the RAIR and the subsequent Annual Reports (Golder, 2010, 2011, 2012, 2013, 2014a, 2015).
2 Refer to AMEC (2015) for a complete discussion of the monitoring zones. 3 Select OPD wells are included for downgradient hydraulic monitoring control. No pumping is conducted in the OPD.
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Shallow zone figures show limited influences of the pumping system. However, the use of continuously
recording pressure transducers with dataloggers during startup (presented in the RAIR) showed greater
drawdown in Shallow zone wells close to the three Intermediate zone pumping wells compared with
shallow wells distal to the pumping wells. Intermediate zone contours in Figures 5 to 8 continue to show
a zone of influence around RW07-39-SP, RW07-40-SP, and RW06-28-I in the upper outwash and St.
Peter Sandstone. Groundwater flow converges horizontally and is directed downward towards RW07-38-
I, screened slightly deeper in the outwash. Deep zone figures indicate that a capture zone is developed
in the deep outwash around RW06-27-BR. Note that the plan view of the groundwater elevation contours
were developed in conjunction with cross-sectional interpretations (Figures 9 and 10 for the 1st quarter
and 3rd quarter 2015, respectively). This approach facilitates interpretation of the distribution of hydraulic
head contours in areas where no intermediate depth monitoring wells are located (i.e., MW00-42, MW00-
43, MW04-26 and MW04-29). The cross sectional view indicates that upward gradients between the
OPD wells and the deep pumping well exist proximal to the deep pumping well.
As shown by the groundwater equipotentials, the pumping wells RW06-28-I, RW07-39-SP, RW07-40-SP,
RW07-38-I and RW06-27-BR have developed a three-dimensional capture zone in the Shallow,
Intermediate, and Deep monitoring zones similar to those developed during the pumping tests and
system startup. The design takes advantage of the natural downward gradients from shallow to deep
overburden in the buried valley, whereby pumping wells RW07-38-I and RW06-27-BR also capture
groundwater flow from the shallow stratigraphic unit.
The groundwater flow model developed for designing the groundwater extraction system (Geomega and
Golder, 2007) revealed the progression of groundwater flow from shallow and intermediate units to deep
units. The model results indicated that vertical flow predominates, water is collected from below the deep
pumping well, and flow is reversed at the base of the outwash and within the shallow OPD. The details of
the model-simulated capture were presented in the RAIR (Golder, 2009).
In summary, the hydraulic performance data for 2015 show that the pumping systems are operating as
designed. Groundwater equipotentials indicate the monitoring zones in which pumping is conducted
achieve capture zones as designed.
4.2 Groundwater Quality Groundwater sampling events were conducted semi-annually for the Site by the data collection and data
management consultant (AMEC Foster Wheeler) on May 18-22 and October 5-9 during 2015. The data
are reported annually (AMEC, 2016).
Isopleths of cVOCs are presented for each monitoring zone in Figure 11. In the Shallow zone, cVOCs
were less than 100 ug/L in all network monitoring wells. In the Intermediate zone, two discrete areas
above 100 ug/L are present with maximum concentrations of 289 ug/L and 542 ug/L, respectively. In the
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deep zone, a discrete area above 100 ug/L is present with a maximum concentration of 303 ug/L. This
compares with pre-pumping conditions in which significant areas above 1,000 ug/L were present, and
maximum concentrations in the Shallow, Intermediate and Deep zones were 3,890 ug/L (MW04-95-T),
13,250 ug/L (MW04-28-I), and 14,090 ug/L (MW04-30-BR), respectively.
Additional indications of contaminant mass capture are provided by the changes in contaminant levels on
a well-by-well basis. Concentration-time graphs of the southeastern area monitoring well network are
presented in Appendix A, which includes the historical data and the data collected during this reporting
period. The data show that key monitoring wells in the vicinity of pumping wells have exhibited
substantial declines in contaminant levels, of between 96% and 99%, since pumping was initiated.
Monitoring wells MW07-42-I and MW07-41-I, proximal to pumping wells RW06-28-I, RW07-39-SP and RW07-40-SP, have shown decreases in cVOCs from 3,875 ug/L to 74.7 ug/L (98%) and from 5,800 ug/L to 30.1 ug/L (>99%), respectively, since pumping was initiated. In the monitoring well installed proximal to these pumping wells but slightly deeper, MW06-29-I, cVOCs were 193 ug/L prior to pumping, and concentrations have been variable under pumping conditions while remaining below pre-pumping concentrations; concentration was 9.8 ug/L in the 4th quarter 2015.
Monitoring well MW04-28-I, proximal to the Intermediate zone pumping well RW07-38-I, has also exhibited substantial reductions under pumping conditions. Prior to pumping, the contamination levels were as high as 13,300 ug/L. Over the last 4 years in particular, cVOCs have been decreasing, and was 109 ug/L in 2015, representing a decrease of approximately two orders of magnitude.
Monitoring wells proximal to the Deep zone pumping well have also exhibited substantial reductions under pumping conditions. Prior to pumping, the contamination levels of deep outwash well MW04-30-BR were generally greater than 6,000 ug/L, and as high as 14,190 ug/L. Under pumping conditions, cVOCs have generally been in the range of a few hundred ug/L since the third quarter of 2009, and were most recently 303 ug/L in October 2015, a decrease of 99% from the average concentration prior to startup. Deep outwash well MW00-43-BR, which most recently (October 2015) had a total cVOC concentration of 9.5 ug/L, shows a significant reduction from the 346 ug/L to 900 ug/L observed prior to the system start up, a 98% decrease from the average concentration prior to startup (excluding an anomalously low value in 2000).
Bedrock OPD monitoring well MW02-01-OPD, located near RW06-27-BR but with a deeper well screen (within the Shakopee), has declined to 19.8 ug/L from the 400 ug/l to 908 ug/L observed under pre-pumping conditions, a decrease of 97% from the average concentration prior to startup.
These results from wells within the plume “core”, the areas of highest concentration, indicate that
significant reductions (from 96% to >99%) are occurring, consistent with achieving the system
performance goals.
A few peripheral wells in the monitoring network have exhibited more variable trends in cVOC
concentrations:
A relatively small zone of contaminated groundwater between the area north of the Roundhouse and the former Waste Reclamation Area is currently monitored by wells
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MW04-24-T, MW06-01-I, and MW-403D (See Figure 1). This area was not designed for active remediation due to the presence of naturally declining concentrations. For example, monitoring well MW-21A had declined from 435 µg/L in 1993 to 83 µg/L in October 2012 (a 81% decrease since 1993) and was decommissioned in 2012 (MPCA, 2012). MW04-24-T has also maintained a downward trend in concentration. Well MW-403D has exhibited relatively stable concentrations since system startup, and has decreased 38% in cVOCs compared to the average pre-pumping concentration. The trend graphs are included in Appendix A.
Monitoring well MW06-01-I is part of a three well cluster than includes a shallower well (MW06-01-T) and a deeper well (MW06-01-BR). MW06-01-T has always been non-detect for cVOCs, and concentration trends in the deeper well, MW06-01-BR, have been variable but less than 30 µg/L in a majority of monitoring events in the last five years. Under pumping conditions, concentrations in MW06-01-I have been variable but exhibit a downward trend overall, particularly in the last four years. From 2008-2010 concentrations were 436-570 µg/L, substantially lower during 2010-2011 (53-312 µg/L), increased slightly in 2012-2014 (around 311-540 µg/L), and since then have decreased to around 290 µg/L in 2015. Overall, concentrations remain lower than the pre-pumping concentrations of October 2007 (749 µg/L).
A localized area south of the intermediate pumping wells in the vicinity of the MW00-42-T/MS well nest had shown higher concentrations under pumping conditions. However, from 2013 onwards, cVOC concentrations in both wells were maintained at relatively low levels (MW00-42-T was 23-24 ug/L and MW00-42-MS was 22-32 ug/L in 2015). As discussed in the 2012 Annual Report, the pumping rate of RW06-28-I appeared to impact the cVOC levels at MW00-42-MS, and the analysis indicated a minimum flow rate of approximately 3.5 gpm was a positive influence. As discussed in section 4.3, the pumping rate of RW06-28-I was maintained at 3.5 gpm on average in 2015.
Monitoring well MW04-26-BR has exhibited a slight increasing trend in total cVOCs in recent years, due to increasing concentrations of cis-1,2-DCE and 1,1-DCA. These compounds are biologically-facilitated breakdown products of PCE/TCE and 1,1,1-TCA, respectively. These degradation products are not observed elsewhere in the Southeastern facility area at these levels (average concentrations of cis-1,2-DCE and 1,1-DCA of 129 ug/L and 99 ug/L in 2015, respectively). Adjacent monitoring well MW04-30-BR also exhibited an increase in cVOCs in 2014-2015, due to increases in the concentrations of cis-1,2-DCE and 1,1-DCA. These wells will continue to be monitored and the trends will be evaluated as appropriate in future reports.
Given the substantial reductions in groundwater concentrations (thousands of ug/L) throughout the plume
core as a result of pumping, variability in concentrations on the order of a few hundred ug/L on the fringes
of the plume are not significant with respect to the overall reductions achieved in plume mass.
4.3 System Performance Total volumes of water extracted from each well during the reporting period, together with annualized flow
rates are as follows:
RW07-39-SP: 864,771 gallons (1.65 gpm average)
RW07-40-SP: 972,220 gallons (1.85 gpm average)
RW06-28-I: 1,861,576 gallons (3.54 gpm average)
RW07-38-I: 4,468,777 gallons (8.50 gpm average)
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RW06-27-BR: 7,004,033 gallons (13.33 gpm average)
The total volume extracted from all five wells during 2015 was 15,171,376 gallons. Table 2 presents the
VOC concentrations detected in the influent stream for each sampling event. Table 3 presents the mass
removed quarterly and total mass removed through December 2015. Mass removal calculations were
based on the average of concentrations determined at the beginning and end of each sampling period
and the volume extracted during that time. Complete laboratory data for the influent and effluent samples
are provided in Appendix B. VOCs detected in the groundwater stream include 1,1-DCA, 1,1-DCE, cis-
1,2-DCE, PCE, 1,1,1-TCA, and TCE. A total of 12.5 pounds of VOCs were removed from the
groundwater during the reporting period and a cumulative total of 363 pounds has been removed since
commissioning the system on November 8, 2007 through December 15, 2015. The cumulative mass
removal of cVOCs since startup through the current reporting period is shown on Figure 12. During the
reporting period, PCE constituted the largest mass of contaminants removed (6.31 pounds), followed by
1,1,1-TCA (1.86 pounds), and then 1,1-DCA, cis-1,2 DCE, TCE, and 1,1-DCE (between 0.65 and 1.73
pounds each).
During each year of operation the mass removed has decreased, recently from 18.4 pounds in 2013, to
16.2 pounds in 2014, and 12.5 pounds during 2015. Since the volume of water extracted has not varied
appreciably, the mass removed per volume of water extracted has declined in similar proportion,
specifically, 1.24 lb/Mgal, 1.09 lb/Mgal, and 0.813 lb/Mgal in 2013 through 2015, respectively. This
compares with 10.1 lb/Mgal removed during the first 10 months of operation.
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5.0 CONCLUSIONS The overburden groundwater remedial system in the southeastern area of the East Side Shoreham
Facility was successfully operated and maintained in 2015, and continues to operate as intended and
detailed in the approved Design Report. Groundwater capture zones established are consistent with
those anticipated in design, and 363 pounds of VOCs have been removed from the groundwater since the
startup of the system, with 12.5 pounds being removed in 2015. Wells within the plume core, monitoring
the most contaminated areas prior to operation, have exhibited cVOC decreases of 96% to 99% since the
start of system operation. Extraction wells RW06-27-BR, RW07-38-I, RW06-28-I, and RW07-40-SP
continue to exhibit decreases of total cVOCs between December 2014 and December 2015. Semi-
annual monitoring of groundwater quality is proposed to continue, along with monthly effluent monitoring,
during continued operations in 2016.
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6.0 REFERENCES AMEC Environmental and Infrastructure, Inc., 2014. 2013 Annual Groundwater Monitoring Report, East
Side Shoreham Facility, (MPCA Superfund Program No. SR380, MPCA VIC Site No. 5080), Canadian Pacific, Minneapolis, Minnesota.
AMEC Environmental and Infrastructure, Inc., 2016. 2015 Annual Groundwater Monitoring Report, East Side Shoreham Facility, (MPCA Superfund Program No. SR380, MPCA VIC Site No. 5080), Canadian Pacific, Minneapolis, Minnesota.
Geomega and Golder Associates Inc., 2007. Summary and Users Guide for Joint Outwash Remediation Model, and Source Files. March 14, 2007.
Golder Associates, 2005. Voluntary Investigation and Cleanup Program, Response Action Plan for the East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA August 2005.
Golder Associates, 2006. Groundwater Pumping Test Report, Southeastern Pumping Tests, East Side Shoreham Facility, VIC Program Site Id VP5080, Minneapolis, Minnesota.
Golder Associates, 2007. Overburden Groundwater Remedial Design, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA April 2007.
Golder Associates, 2009. Response Action Implementation and Monitoring Report, Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA April 2009.
Golder Associates, 2010. 2009 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA August 2010.
Golder Associates, 2011. 2010 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA August 2011.
Golder Associates, 2012. 2011 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA June 2012.
Golder Associates, 2013. 2012 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA May 2013.
Golder Associates, 2014a. 2013 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA May 2014.
Golder Associates, 2014b. Response Action Implementation Report, Soil Vapor Extraction Systems, Former Waste Reclamation Area and Roundhouse/Shops Areas, East Side Shoreham Yard Facility, Minneapolis, Minnesota. Submitted to MPCA May 2014.
Golder Associates, 2015a. 2014 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA April 2015.
g:\projects\2002 projects\023-6105 cpr\east side groundwater 2015 annual rpt\text\2015 east side annual (041516).docx
April 2016 13 023-6105
Golder Associates, 2015b. Soil Response Action Completion Report, Former Waste Reclamation Area,
Roundhouse/Shops Area, East Side Shoreham Yard Facility, Minneapolis, Minnesota. Submitted to MPCA June 2015.
Minnesota Pollution Control Agency, 2002. Guidance Document #18, Response Action Plan/Response Action Implementation Report, 17 pp, revised February 2002.
Minnesota Pollution Control Agency, 2012. Electronic mail communication from Andrew Nichols, MPCA to Claire Mackler, Golder Associates, cc to Tom Frame, City of Minneapolis, LeeAnn Thomas, CP, James Vondracek, Ashland, Steve Helgen, Integral, Steve Finn, Golder, July 31, 2012.
g:\projects\2002 projects\023-6105 cpr\east side groundwater 2015 annual rpt\text\2015 east side annual (041516).docx
Table 1 Well Construction Information
2015 Annual Report Overburden Groundwater Extraction and Treatment System Southeast Area - East Side Shoreham Facility, Minneapolis, MN
023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\tables\Table 1 Well Construction.xlsx Page 1 of 1
Site Well ID*
[ft amsl] [inches] [ft amsl] [depth bgs] [ft amsl] [depth bgs] [ft amsl]RW06-27-BR* 854.1 6 Stainless Steel 856.53 155 699.1 195 659.1 OutwashRW06-28-I* 855.1 4 Stainless Steel 857.89 70 785.1 90 765.1 OutwashRW07-38-I* 854.08 6 Stainless Steel 856.44 90 764.1 110 744.1 OutwashRW07-39-SP* 854.76 4 Stainless Steel 857.69 45.1 809.7 65.1 789.7 St. Peter SandstoneRW07-40-SP* 854.85 4 Stainless Steel 857.71 45.2 809.7 65.2 789.7 St. Peter SandstoneMW00-41-T 853.4 2 Stainless Steel 857.67 39 814.4 49 804.4 St. Peter SandstoneMW00-42-MS 854.6 2 Stainless Steel 856.88 140 714.6 150 704.6 Outwash/St. Peter MudstoneMW00-42-T 854.4 2 Stainless Steel 857.31 37 817.4 47 807.4 OutwashMW00-43-BR 854.3 2 Stainless Steel 856.27 160 694.3 170 684.3 OutwashMW00-43-T 854.3 2 Stainless Steel 856.85 37 817.3 47 807.3 Glacial Till/OutwashMW02-01-OPD 854.8 2 Stainless Steel 857.26 220 634.8 240 614.8 ShakopeeMW02-46-BR 853.5 2 Stainless Steel 853.33 155 698.5 190 663.5 OutwashMW02-46-I 853.6 2 Stainless Steel 853.32 100 753.6 110 743.6 OutwashMW02-46-T 853.6 2 Stainless Steel 853.41 40 813.6 50 803.6 OutwashMW03-56-BR 852.78 2 Stainless Steel 852.26 179 673.8 189 663.8 St. Peter MudstoneMW03-61-OPD 854.1 2 Stainless Steel 856.55 220 634.1 240 614.1 ShakopeeMW04-155-T 853.6 2 Stainless Steel 855.53 33 820.6 43 810.6 Till Sand/St Peter SandstoneMW04-24-T 854.57 2 Stainless Steel 856.43 33 821.6 43 811.6 Glacial TillMW04-25-T 854.3 2 Stainless Steel 856.57 33 821.3 43 811.3 Till SiltMW04-26-BR 854.6 2 Stainless Steel 855.94 184 670.6 194 660.6 OutwashMW04-26-T** 854.6 2 Stainless Steel 856.50 34 820.6 44 810.6 Glacial TillMW04-27-T 854.69 2 Stainless Steel 856.49 34 820.7 44 810.7 Glacial Till/OutwashMW04-28-I 854.0 2 Stainless Steel 856.16 95 759.0 105 749.0 OutwashMW04-28-OPD 853.9 2 Stainless Steel 856.65 220 633.9 240 613.9 ShakopeeMW04-28-T 854.1 2 Stainless Steel 856.19 33 821.1 43 811.1 Outwash/Lacustrine/OutwashMW04-29-BR 854.0 2 Stainless Steel 855.66 187 667.0 197 657.0 OutwashMW04-30-BR 854.0 2 Stainless Steel 855.70 186 668.0 196 658.0 OutwashMW04-31-SP 855.6 2 Stainless Steel 858.25 60 795.6 70 785.6 St. Peter SandstoneMW04-31-T 855.2 2 Stainless Steel 857.91 34 821.2 44 811.2 St. Peter SandstoneMW04-33-SP 853.8 2 Stainless Steel 855.21 52 801.8 62 791.8 St. Peter SandstoneMW04-33-T 853.8 2 Stainless Steel 855.38 33.5 820.3 43.5 810.3 Glacial TillMW04-95-T 854.95 2 Stainless Steel 857.47 36 819.0 46 809.0 Glacial Till/OutwashMW05-01-OPSH 855.1 2 Stainless Steel 855.30 219 636.1 239 616.1 ShakopeeMW05-15-BR 854.31 2 Stainless Steel 856.27 164 690.3 174 680.3 OutwashMW06-01-BR 854.01 2 Stainless Steel 855.47 176 678.0 180 674.0 St Peter Mudstone/OutwashMW06-01-I 853.97 2 Stainless Steel 855.53 110.5 743.5 125.5 728.5 OutwashMW06-01-T 853.92 2 Stainless Steel 855.43 31 822.9 41 812.9 Glacial TillMW06-248-I 853.93 2 Stainless Steel 856.24 50 803.9 60 793.9 OutwashMW06-29-I 854.5 2 Stainless Steel 857.23 80 774.5 90 764.5 OutwashMW07-41-I 854.84 2 Stainless Steel 857.24 50.3 804.5 60.3 794.5 Glacial Till/OutwashMW07-42-I 855.02 2 Stainless Steel 857.35 52.8 802.2 62.8 792.2 OutwashMW-301 853.8 2 Stainless Steel 855.56 37 816.8 47 806.8 Till Silt/St Peter SandstoneMW-403D 853.8 2 Stainless Steel 856.51 49 804.8 59 794.8 OutwashMW-406D 856.0 2 Stainless Steel 855.94 53 803.0 63 793.0 OutwashMW-407D** 858.4 2 Stainless Steel 858.38 52 806.4 62 796.4 Outwash* Groundwater Recovery Well** Well abandonment completed in 2015. Checked by: APN
Ground Surface
Well Diameter Screen Material
Screened Unit
Screened Interval
Top of Well Screen Bottom of Well Screen
Top of Riser
Elevation
023-6105April 2016
Tables 2 and 3 and Fig 12.xlsx Page 1 of 1
Well Identification Date 1,1,1 TCA 1,1 DCA 1,1 DCE cis-1,2 DCE PCE TCE
[m/d/y] [µg/l] [µg/l] [µg/l] [µg/l] [µg/l] [µg/l]3/13/15 8.8 11.5 4.4 13.5 31.1 5.46/15/15 7.3 10.2 4.6 13.2 31.3 5.49/15/15 6.6 14.6 4.2 16.7 32.7 6.2
12/15/15 7.3 12.9 4.2 16.6 30.1 5.83/13/15 10.6 15.5 4.7 5.7 44.7 4.86/15/15 9.2 12.9 4.8 5.6 42.0 4.89/15/15 8.9 14.1 3.6 6.5 56.8 5.3
12/15/15 7.3 13.2 3.9 5.1 35.8 4.63/13/15 4.2 4.5 1.2 1.3 8.2 0.96/15/15 10.1 5.7 3.1 3.2 16.1 1.89/15/15 6.6 9.3 1.9 2.6 13.2 1.4
12/15/15 5.7 6.8 1.7 1.9 10.0 1.03/13/15 110.0 40.8 13.2 29.4 261.0 12.86/15/15 102.0 41.3 19.6 19.5 252.0 13.69/15/15 145.0 60.7 24.5 33.6 264.0 14.4
12/15/15 106.0 48.8 20.2 28.4 232.0 12.23/13/15 13.5 2.4 2.2 1.5 60.6 3.36/15/15 11.0 2.1 2.4 1.6 58.6 3.09/15/15 8.2 2.5 1.6 1.6 52.0 2.6
12/15/15 9.3 2.5 1.5 1.3 47.5 2.6Checked by: APN
RW07-40-SP
Table 2VOC Concentrations in Groundwater Extraction Wells
2015 Annual Report Overburden Groundwater Extraction and Treatment SystemSoutheast Area - East Side Shoreham Facility, Minneapolis, MN
RW06-27-BR
RW07-38-I
RW06-28-I
RW07-39-SP
023-6105April 2016
Tables 2 and 3 and Fig 12.xlsx Page 1 of 1
Well Identification Date 1,1,1 TCA 1,1 DCA 1,1 DCE cis-1,2 DCE PCE TCE
[lbs] [lbs] [lbs] [lbs] [lbs] [lbs]3/13/15 0.131 0.176 0.083 0.210 0.500 0.0866/15/15 0.120 0.162 0.067 0.200 0.467 0.0819/15/15 0.098 0.175 0.062 0.211 0.451 0.08212/15/15 0.104 0.206 0.063 0.250 0.471 0.0903/13/15 0.123 0.174 0.063 0.062 0.534 0.0506/15/15 0.103 0.148 0.049 0.059 0.451 0.0509/15/15 0.062 0.092 0.029 0.041 0.338 0.03512/15/15 0.081 0.136 0.037 0.058 0.461 0.0493/13/15 0.023 0.025 0.008 0.007 0.046 0.0046/15/15 0.036 0.026 0.011 0.011 0.061 0.0079/15/15 0.034 0.030 0.010 0.012 0.059 0.00612/15/15 0.012 0.016 0.004 0.004 0.023 0.0023/13/15 0.184 0.068 0.031 0.046 0.549 0.0226/15/15 0.207 0.080 0.032 0.048 0.501 0.0269/15/15 0.263 0.109 0.047 0.057 0.549 0.03012/15/15 0.192 0.084 0.034 0.048 0.380 0.0203/13/15 0.027 0.005 0.005 0.003 0.138 0.0076/15/15 0.025 0.005 0.005 0.003 0.120 0.0069/15/15 0.019 0.004 0.004 0.003 0.107 0.00512/15/15 0.018 0.005 0.003 0.003 0.102 0.005
1.861 1.726 0.648 1.334 6.309 0.664 12.5 lbs total0.813 lbs/Mgal
Checked by: APN
Table 3Total VOC Mass Removed
2015 Annual Report Overburden Groundwater Extraction and Treatment SystemSoutheast Area - East Side Shoreham Facility, Minneapolis, MN
RW07-40-SP
Total Removed [lbs]
RW06-27-BR
RW07-38-I
RW06-28-I
RW07-39-SP
----8 MW04-25-T
MW-4080
8 MW-4070
,....-,....-~~~~~~~~~~~+--~~~~~~~~~
E 0
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cXi
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0 0 0 II) Oo
0 0 8._MWTJ5--01-0PSH
LEGEND
~---- CROSS SECTION DESIGNATION
0
8 ®
REFERENCES
FACILITY BOUNDARY
RAILROAD TRACKS
ROAD
DRIVEWAY
TRAIL
FENCE
WALL
SIDEWALK
FOUNDATION OR SLAB
WOODS OUTLINE
TREE
MONITORING WELL
EXTRACTION WELL
1.) BASE MAP NORTH OF 27th AVENUE NE FROM DIGIT AL CAD FILE NEW_BASE_2_2001.dwg, TITLED "PORTIONS OF SECTIONS 2 & 11 T29N, R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
2.) PROPERTY LINE AND ROW FROM DIGITAL CAD FILE NEW_BASE_B_OO-property llne.dwg PROVIDED BY AMEC EARTH AND ENVIRONMENTAL., INC.
3.) EAST SIDE SHOREHAM SITE AREAS FROM FIGURE 2, "AREA AND LEAKSITE LOCATION MAP", STATUS OF RECOGNIZED ENVIRONMENTAL CONDITIONS REPORT, EAST SIDE SHOREHAM FACILITY, AMEC EARTH AND ENVIRONMENTAL, INC. APRIL 2004. AREA G, PROPOSED IN THAT REPORT, IS MODIFIED AND INCLUDED HERE. AREA A SUBDIVIDED AS SHOWN IN FIGURE 2-1 OF PHASE II SUPPLEMENTAL REMEDIAL INVESTIGATION REPORT, IT CORPORATION, MAY 2001. NOTE THAT THE AREA BOUNDARIES ARE APPROXIMATE ONLY, ARE SHOWN FOR ILLUSTRATIVE PURPOSES ONLY, AND DO NOT NECESSARILY REPRESENT AN INTERPRETATION OF THE EXTENT OF POTENTIAL ENVIRONMENTAL IMPACTS OR KNOWN CONTAMINATION.
4.) LOCATION OF WELLS PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
5.) RAILROAD TRACK LOCATED EAST OF ROUNDHOUSE AREA DIGITIZED FROM FIGURE 1, TITLED "TRACK LAYOUT AND EXCAVATION AREA," PROVIDED BY IT CORPORATION, DATED MAY 2001.
150 0 150 - ----SCALE FEET
RE.V llAlE DES RE.VISION DESCRIPTION CAllD CHK rMI
PROJECT
TITLE
SOO LINE SHOREHAM FACILITY MINNEAPOLIS, MINNESOTA
SOUTHEAST AREA WELL LOCATION MAP
ca;;;;:-· PROJECT No. 023-6105 FILE No. 02361 05BU49
DESIGN ACK 04/15/16 SCM..E 1'S SHOWN REV. 0
CADll ,,. 04/15/16
1\SsOclates CHECK ACK 04/1 5/16 FIGURE 1 Mt. l..clurel. New Jaraey REVIEW ACK 04/15/16
023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\figures\Figures 2, 3, and 4 (2015).xlsx
Checked by: APN
814
816
818
820
822
824
826
2007 2008 2009 2010 2011 2012 2013 2014 2015 2016
Elev
atio
n (ft
msl
)Figure 2
Groundwater Level Monitoring in Shallow Zone Wells2015 Annual Report, Southeast Area
MW-406D MW-407D MW00-41-T MW00-42-T MW00-43-T MW02-46-T MW04-155-T MW04-24-T
MW04-25-T MW04-26-T MW04-27-T MW04-28-T MW04-31-T MW04-33-T MW04-95-T MW06-01-T
023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\figures\Figures 2, 3, and 4 (2015).xlsx
Checked by: APN
790
830
870
910
810
815
820
825
2007 2008 2009 2010 2011 2012 2013 2014 2015 2016
RW
Ele
vatio
n (ft
msl
)MW
Ele
vatio
n (ft
msl
)Figure 3
Groundwater Level Monitoring in Intermediate Zone Wells2015 Annual Report, Southeast Area
MW-403D MW02-46-I MW04-28-I MW04-31-SP MW04-33-SP MW06-01-I MW06-248-I
MW06-29-I MW07-41-I MW07-42-I RW07-39-SP* RW07-40-SP* RW06-28-I* RW07-38-I*
Note: Water levels in extraction wells are as measured.
023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\figures\Figures 2, 3, and 4 (2015).xlsx
Checked by: APN
805
810
815
820
825
830
835
810
812
814
816
818
820
822
2007 2008 2009 2010 2011 2012 2013 2014 2015 2016
RW
Ele
vatio
n (ft
msl
)
MW
Ele
vatio
n (ft
msl
)Figure 4
Groundwater Level Monitoring In Deep Zone and OPD Wells2015 Annual Report, Southeast Area
MW00-42-MS MW00-43-BR MW02-46-BR MW03-56-BR MW04-26-BR MW04-29-BR MW04-30-BR
MW06-01-BR MW02-01-OPD MW03-61-OPD MW04-28-OPD MW05-01-OPSH RW06-27-BR*
Note: Water levels in extraction wells are as measured.
E c ~ cXi
C1 LL 0 II) ::::> CD II) 0
co ~ 0
Qj ~
C1 c: 'i ~
LEGEND
0
RAILROAD TRACKS
ROAD
DRIVEWAY
TRAIL
DRAIN OR SHORELINE
FENCE
WALL
SIDEWALK
FOUNDATION OR SLAB
WOODS OUTLINE
TREE
8. @
-820-
(820.74)
MONITORING WELL
EXTRACTION WELL
A MW05-08-T
821.40
,8.MW-407D 821.21
GROUNDWATER CONTOUR
GROUNDWATER ELEVATION (FTAMSL)
NOT MEASURED DURING SYNOPTIC (SEENOTE3)
NOTES 1.) GROUNDWATER LEVELS MEASURED MARCH 27-28, 2015.
2.) CONTOURS AT 1-FT INTERVAL (ONLY) PROVIDED BY AMEC, AS SHOWN IN 2015 VIC ANNUAL GROUNDWATER MONITORING REPORT.
3.) GROUNDWATER ELEVATIONS IN PUMPING WELLS NOT USED FOR GROUNDWATER CONTOUR DEVELOPMENT. APPROXIMATE ELEVATIONS IN PUMPING WELLS: RW07~9-SP: 813.65, RW07-40-SP: 819.01, RW06-26-I: 817.66, RW07~6-I: 819.9, RW06-27-BR: 810.72.
REFERENCES 1.) BASE MAP NORTH OF 271h AVENUE NE FROM DIGITAL CAD FILE NEW_BASE_2_2001.dwg, TITLED "PORTIONS OF SECTIONS 2 & 11 T29N, R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC. ROADS SOUTH OF 27TH AVENUE NE PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
2.) PROPERTY LINE AND ROW FROM DIGITAL CAD FILE NEW_BASE_8_0().property line.dwg PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
3.) LOCATION OF WELLS PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
4.) RAILROAD TRACK LOCATED EAST OF ROUNDHOUSE AREA DIGITIZED FROM FIGURE 1, TITLED "TRACK LAYOUT AND EXCAVATION AREA," PROVIDED BY IT CORPORATION, DATED MAY 2001.
RE.V llAlE DES
PROJECT
TTTLE
300 0 300 - ----SCALE FEET
RE.VISION DESCRIPTION
SOO LINE SHOREHAM FACILITY MINNEAPOLIS, MINNESOTA
CAllD CHK rMI
GROUNDWATER POTENTIOMETRIC CONTOURS MARCH 2015
- NJ Authorl:zotfon f?4GA2802'9100 PROJECT No. 023-6105 FILE No. 0236105BU50
<P~ DESIGN ACK 04/15/16 SCl>J...E 1'S SHOWN REV. 0
CADll IW 04/15/16
CHECK RMW 04/15/16 FIGURE 5 REVIEW ACK
0 ... --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------.... --------------
Ut. Lourel, New Jeraey 04/15/16
E c
iO cXi
~
c. <
C1 c: "i ~
LEGEND
, 'f ......... 'f ••
RAILROAD TRACKS
ROAD
DRIVEWAY
TRAIL
DRAIN OR SHORELINE
FENCE
WALL
SIDEWALK
FOUNDATION OR SLAB
WOODS OUTLINE
TREE
MONITORING WELL
MW"'407D 8 820.92
@ EXTRACTION WELL
--820-- GROUNDWATER CONTOUR
(820.76) GROUNDWATER ELEVATION (FTAMSL)
NOT MEASURED DURING SYNOPTIC (SEENOTE3)
NOTES 1.) GROUNDWATER LEVELS MEASURED MAY 15-16, 2015.
2.) CONTOURS AT 1-FT INTERVAL (ONLY) PROVIDED BY AMEC, AS SHOWN IN 2015 VIC ANNUAL GROUNDWATER MONITORING REPORT.
3.) GROUNDWATER ELEVATIONS IN PUMPING WELLS NOT USED FOR GROUNDWATER CONTOUR DEVELOPMENT. APPROXIMATE ELEVATIONS IN PUMPING WELLS: RW07-39-SP: 814.22, RW07-4G-SP: 819.85, RW06-28-I: 818.23, RW07-38-I: 820.14, RW06-27-BR: 811.19.
REFERENCES 1.) BASE MAP NORTH OF 27th AVENUE NE FROM DIGITAL CAD FILE NEW_BASE_2_2001.dwg, TITLED "PORTIONS OF SECTIONS 2 & 11 T29N, R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC. ROADS SOUTH OF 27TH AVENUE NE PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
2.) PROPERTY LINE AND ROW FROM DIGIT AL CAD FILE NEW_BASE_B_OG-property llne.dwg PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
3.) LOCATION OF WELLS PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
4.) RAILROAD TRACK LOCATED EAST OF ROUNDHOUSE AREA DIGITIZED FROM FIGURE 1, TITLED "TRACK LAYOUT AND EXCAVATION AREA," PROVIDED BY IT CORPORATION, DATED MAY 2001.
RE.V llAlE DES
PROJECT
TTTLE
300 0 300 - ----SCALE FEET
RE.VISION DESCRIPTION
SOO LINE SHOREHAM FACILITY MINNEAPOLIS, MINNESOTA
f
CAllD CHK rMI
GROUNDWATER POTENTIOMETRIC CONTOURS MAY2015
- NJ Authorl:zotfon f?4GA2802'9100 PROJECT No. 023-6105 FILE No. 0236105BU51
<P~ DESIGN ACK 04/15/16 SCl>J...E 1'S SHOWN REV. 0
CADll IW 04/15/16
CHECK RMW 04/15/16 FIGURE 6 REVIEW ACK
0 ... --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------.... --------------
Ut. Lourel, New Jeraey 04/15/16
E c
"' I(")
cXi
~
c. <
C1 LL N I(") ::::> CD I(") 0
co ~ 0
Qj ~
C1 c: "i ~
LEGEND
0
RAILROAD TRACKS
ROAD
DRIVEWAY
TRAIL
DRAIN OR SHORELINE
FENCE
WALL
SIDEWALK
FOUNDATION OR SL.AB
WOODS OUTLINE
TREE
8 @
-819-
(818.02)
MONITORING WELL
EXTRACTION WELL
A MW0!>-06-T
1121.28
GROUNDWATER CONTOUR
GROUNDWATER ELEVATION (FTAMSL)
NOT MEASURED DURING SYNOPTIC (SEENOTE3)
NOTES 1.) GROUNDWATER LEVELS MEASURED AUGUST 6-7, 2015.
2.) CONTOURS AT 1-FT INTERVAL (ONLY) PROVIDED BY AMEC, AS SHOWN IN 2015 VIC ANNUAL GROUNDWATER MONITORING REPORT.
3.) GROUNDWATER ELEVATIONS IN PUMPING WELLS NOT USED FOR GROUNDWATER CONTOUR DEVELOPMENT. APPROXIMATE ELEVATIONS IN PUMPING WELLS: RW07~9-SP: 811.36, RW07-40-SP: 819.76, RW06-26-I: 819.38, RW07~1: 820.29, RW0&-27-BR: 810.67.
4.) ANOMALOUS MEASUREMENT NOT USED IN CONTOURING.
REFERENCES 1.) BASE MAP NORTH OF 27th AVENUE NE FROM DIGITAL CAD FILE NEW_BASE_2_2001.dwg, TITLED "PORTIONS OF SECTIONS 2 & 11 T29N, R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC. ROADS SOUTH OF 27TH AVENUE NE PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
2.) PROPERTY LINE AND ROW FROM DIGITAL CAD FILE NEW_BASE_8_0().property line.dwg PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
3.) LOCATION OF WELLS PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
4.) RAILROAD TRACK LOCATED EAST OF ROUNDHOUSE AREA DIGITIZED FROM FIGURE 1, TITLED "TRACK LAYOUT AND EXCAVATION AREA," PROVIDED BY IT CORPORATION, DATED MAY 2001.
RE.V llAlE DES
PROJECT
TTTLE
300 0 300 - ----SCALE FEET
RE.VISION DESCRIPTION
SOO LINE SHOREHAM FACILITY MINNEAPOLIS, MINNESOTA
f
CAllD CHK rMI
GROUNDWATER POTENTIOMETRIC CONTOURS AUGUST2015
- NJ Authorl:zotfon f?4GA2802'9100 PROJECT No. 023-6105 FILE No. 0236105BU52
<P~ DESIGN ACK 04/15/16 SC1'J...E 1'S SHOWN REV. 0
CADll ,,. 04/15/16
CHECK RMW 04/1 5/16 FIGURE 7 REVIEW ACK
0 ... --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------.... --------------
Ut. Lourel, New Jeraey 04/15/16
E c ~ cXi
~
a. <
C1 c: "i ~
LEGEND
0
RAILROAD TRACKS
ROAD
DRIVEWAY
TRAIL
DRAIN OR SHORELINE
FENCE
WALL
SIDEWALK
FOUNDATION OR SL.AB
WOODS OUTLINE
TREE
MONITORING WELL
MWD5-0&-T 822.50
A MW05.00.T
821.49
@ EXTRACTION WELL
-819- GROUNDWATERCONTOUR
(818.98) GROUNDWATER ELEVATION (FTAMSL)
NOT MEASURED DURING SYNOPTIC (SEENOTE3)
NOTES 1.) GROUNDWATER LEVELS MEASURED OCTOBER 9-10, 2015.
2.) CONTOURS AT 1-FT INTERVAL (ONLY) PROVIDED BY AMEC, AS SHOWN IN 2015 VIC ANNUAL GROUNDWATER MONITORING REPORT.
3.) GROUNDWATER ELEVATIONS IN PUMPING WELLS NOT USED FOR GROUNDWATER CONTOUR DEVELOPMENT. APPROXIMATE ELEVATIONS IN PUMPING WELLS: RW07~9-SP: 812.84, RW07-40-SP: 820.38, RW06-26-I: 820.45, RW07~1: 820.31, RW0&-27-BR: 810.38.
REFERENCES 1.) BASE MAP NORTH OF 27th AVENUE NE FROM DIGITAL CAD FILE NEW_BASE_2_2001.dwg, TITT.ED "PORTIONS OF SECTIONS 2 & 11 T29N, R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC. ROADS SOUTH OF 2TTH AVENUE NE PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
2.) PROPERTY LINE AND ROW FROM DIGITAL CAD FILE NEW_BASE_8_0().property line.dwg PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
3.) LOCATION OF WELLS PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
4.) RAILROAD TRACK LOCATED EAST OF ROUNDHOUSE AREA DIGITIZED FROM FIGURE 1, TITT.ED "TRACK LAYOUT AND EXCAVATION AREA," PROVIDED BY IT CORPORATION, DATED MAY 2001.
RE.V llAlE DES
PROJECT
TITLE
300 0 300 - ----SCALE FEET
RE.VISION DESCRIPTION
SOO LINE SHOREHAM FACILITY MINNEAPOLIS, MINNESOTA
CAllD CHK rMI
GROUNDWATER POTENTIOMETRIC CONTOURS OCTOBER 2015
- NJ Authorl:zotfon f?4GA2802'9100 PROJECT No. 023-6105 FILE No. 0236105BU53
<P~ DESIGN ACK 04/15/16 SCl>J...E 1'S SHOWN REV. 0
CADll ,,. 04/15/16
CHECK RMW 04/1 5/16 FIGURE 8 REVIEW ACK
0 ... --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------.... --------------
Ut. Lourel, New Jeraey 04/15/16
w 900
800
..-. ...I UJ ::!!:
I
I-!::;. z 0 ~
~ ...I w
700
650
600
STRATIGRAPHIC LABELS
MW04-95-T
ROUND HOUSE
MW06-29-I PROJECTED 19 ft. SW
RW06-28-I
PROJECTED 42 ft. NE
RW07-40-SP
RW07-39-SP
PROJECTED 38 ft. SW
LEGEND
MW04-28-I
PROJECTED 8 ft. NE
MW04-28-T MW04-28-0PD
PROJECTED 5 ft. SW PROJECTED 2 ft. SW
RW07-38-I
MW04-29-BR PROJECTED 27 ft. NE
PROJECTED 46 ft. NE
MW07-41-I PROJECTED 1 ft. SW
MW07-42-I MW04-30-BR
PROJECTED 19 ft. SW
NOTES
RW06-27-BR
MW02-01-0PD
PROJECTED 11 ft. SW
MW00-43-T
PROJECTED 5 ft. SW
MW00-43-BR
PROJECTED 2 ft. NE
A' E
900
850
800
750
700
650
600
..-.
...I Cl)
::!!:
I-!::;. z 0 ~
~ ...I w
MW00-45-T _.,. _____ WELL IDENTIFICATION 1.) ALL GEOLOGIC CONTACTS INTERPOLATED BETWEEN BOREHOLES.
2.) DASHED GEOLOGIC CONTACTS ARE INFERRED.
GLACIAL TILL
. < : ow·<;·.>: . OUTWASH DEPOSITS
~-::~~"""·~ ... ~t-,,t--- GLACIO-LACUSTRINE CLAY
~ ST PETER SANDSTONE n~D . \\1<>. .. WJ __ ~~~l __ OUTWASH DEPOSITS "' (SANDSTONE AND · ·~ ~ MUDSTONE MEMBERS) ~· (REWORKED SANDSTONE) ~ 1;;;;;------.,,,,~~:l"I _...1._ I ~ t::l"'~·~-~:::::E!::fr-- PRAIRIE DU CHIEN
,.....I,_.__ __ TOP OF BOREHOLE
..-...---- SCREEN INTERVAL
......... _____ BOTIOM OF BOREHOLE
816.5 ----- GROUNDWATER EQUIPOTENTIAL (FT AMSL)
3.) GROUNDWATER LEVELS MEASURED MARCH 5, 2015.
4.) WATER LEVELS IN PUMPING WELLS (RW) ARE NOT USED IN CONTOURING.
s~ AS SHOWN TllU:
70 0
HORIZONTAL SCALE
50 0 - -70
FEET
50 ---VERTICAL SCALE FEET
VERTICAL EXAGGERATION= 1.4X
GROUNDWATER ~~.~-·· '2fFAssodates
DATE 04/15116 POTENTIOMETRIC CONTOURS DESIGN ACK CROSS SECTION
Mt. Laurel, New Jeniey CADD AM MARCH 2015
FILE No. CHECK 0236105BU44 ACK
SOO LINE SHOREHAM FACILITY FIGURE
9 REVIEW ACK f._ ______________________________________________________________________________________________________________ P_ROJ __ ECT __ N~ _________ o_2_3-_6_1_os ..... _REV __ . __ o __ .... ____________________________________________________ .......... __________ ~
900
..-. ...I UJ ::!!:
I
I-!::;. z 0 ~
~ ...I w
STRATIGRAPHIC LABELS
OUTWASH DEPOSITS
. < : ow·<;·.>: .
w
MW04-95-T
GLACIAL TILL
ROUND HOUSE
MW06-29-I
PROJECTED 19 ft. SW
RW06-28-I
PROJECTED 42 ft. NE
RW07-40-SP
RW07-39-SP
PROJECTED 38 ft. SW
LEGEND
MW04-28-T
PROJECTED 5 ft. SW
MW04-29-BR
PROJECTED 46 ft. NE MW07-41-I
PROJECTED 1 ft. SW MW07-42-I
'
MW00-45-T _.,. _____ WELL IDENTIFICATION
,....I,_.__ __ TOP OF BOREHOLE
.-...---- SCREEN INTERVAL
......... _____ BOTIOM OF BOREHOLE
816.5----- GROUNDWATER EQUIPOTENTIAL (FT AMSL)
MW04-28-I
PROJECTED 8 ft. NE
MW04-28-0PD
PROJECTED 2 ft. SW
RW07-38-I
PROJECTED 27 ft. NE
MW04-30-BR
PROJECTED 19 ft. SW
NOTES
RW06-27-BR
MW02-01-0PD
PROJECTED 11 ft. SW MW00-43-T
PROJECTED 5 ft. SW
MW00-43-BR
PROJECTED 2 ft. NE
1.) ALL GEOLOGIC CONTACTS INTERPOLATED BETWEEN BOREHOLES.
2.) DASHED GEOLOGIC CONTACTS ARE INFERRED.
3.) GROUNDWATER LEVELS MEASURED AUGUST 6 - 7, 2015.
4.) WATER LEVELS IN PUMPING WELLS (RW) ARE NOT USED IN CONTOURING.
A' E
900
850
800
750
700
650
600
70
..-.
...I Cl)
::!!:
I-!::;. z 0 ~
~ ...I w
0
HORIZONTAL SCALE
50 0 - -70
FEET
50 ---VERTICAL SCALE FEET
VERTICAL EXAGGERATION= 1.4X
~~.~-·· '2fFAssodates
~-::~~'""'·~ ... ~t-,,t--- GLACIO-LACUSTRINE CLAY
~ ST PETER SANDSTONE n~D . \\1<>. .. WJ __ ~~~l __ OUTWASH DEPOSITS "' (SANDSTONE AND · ·~ ~ MUDSTONE MEMBERS) ~· (REWORKED SANDSTONE)
s~ AS SHOWN TllU:
GROUNDWATER DATE 04/15116 POTENTIOMETRIC CONTOURS DESIGN ACK CROSS SECTION
Mt. Laurel, New Jeniey ~ 1;;;;;------.,,,,~~:l"I _...1._ I ~ t::l"'~·~-~:::::E!::fr-- PRAIRIE DU CHIEN 0236105BU46
CADD AM AUGUST 2015 CHECK ACK
SOO LINE SHOREHAM FACILITY FIGURE
10 REVIEW ACK
FILE No. f._ ______________________________________________________________________________________________________________ P_ROJ __ ECT __ N~ _________ o_2_3-_6_1_05 ..... _REV __ . __ o __ .... ____________________________________________________ .......... __________ ~
E 0
~ cXi
co 0 N
LEGEND
0
RAILROAD TRACKS
ROAD
DRIVEWAY
TRAIL
DRAIN OR SHORELINE
FENCE
WALL
SIDEWALK
FOUNDATION OR SLAB
WOODS OUTLINE
TREE
MW-4070 A ND
2'mf ~NE~----i.·----t
8. @
-100-
54
ND
MONITORING WELL
EXTRACTION WELL
CVOC CONTOUR (ugll)
TOT AL CVOC CONCENTRATION (ug/L)
NOT DETECTED
NOTES 1.) TOTAL CVOC DATA FOR MONITORING WELLS IS FROM OCTOBER f>.9, 2015 SAMPLING EVENT.
2.) TOTAL CVOC DATA FOR PUMPING WELLS IS FROM SEPTEMBER 15, 2015 SAMPLING EVENT.
3.) AREA ADJACENT TO FORMER ASHLAND LEASE AREA IS NOT CONTOURED.
REFERENCES 1.) BASE MAP NORTH OF 27th AVENUE NE FROM DIGITAL CAD FILE NEW_BASE_2_2001.dwg, TITLED "PORTIONS OF SECTIONS 2 & 11 T29N, R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL. INC. ROADS SOUTH OF 27TH AVENUE NE PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
2.) PROPERTY LINE AND ROW FROM DIGITAL CAD FILE NEW_BASE_8_00-properfy llne.dwg PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
3.) LOCATION OF WELLS PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.
4.) RAILROAD TRACK LOCATED EAST OF ROUNDHOUSE AREA DIGITIZED FROM FIGURE 1, TITLED "TRACK LAYOUT AND EXCAVATION AREA," PROVIDED BY IT CORPORATION, DATED MAY 2001.
f
300 0 300 - ----SCALE FEET
RE.V llAlE DES RE.VISION DESCRIPTION CAllD CHK rMI
PROJECT
TITLE
SOO LINE SHOREHAM FACILITY MINNEAPOLIS, MINNESOTA
TOTALCVOC ISOCONCENTRATION CONTOURS
OCTOBER2015 - NJ Autllorl:zotron f?4GA28D2'9loo PROJECT No. 023-6105 FILE No. 02361058~
DESIGN ACK 04/15/16 SCl>J...E 1'S SHOWN REV. 0
01 - c ... ~~-- CADll ,,. 04/15/16 ·i ~UILAI CHECK RMW 04/1 5/16 FIGURE 11 ~ ... ____________________________________________________________________________________________________________________________________________________________ ..... _______ u_t._~_u_~_1._N_•w_J_·~-~ ........ RE.Vl_EW...., __ AC_K __ 0_4/_15_/_16 ______________ ....
Figure 12 0236105April 2016
By: Christopher MunsonChecked: APN
0
50
100
150
200
250
300
350
400
Nov-07 Nov-08 Nov-09 Nov-10 Nov-11 Nov-12 Nov-13 Nov-14 Nov-15 Nov-16
Mas
s Rem
oved
[lbs]
Cumulative cVOC Mass RemovalEast Side Shoreham Overburden Groundwater Extraction and Treatment System
Total cVOC Removal = 363.4 lbs
APPENDIX A TIME-HISTORY CONCENTRATION GRAPHS
Figure A-1 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 1 of 33
Checked by: APN
CP PUMPING
0
1
2
3
4
5
6
7
8
9
10
2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2016
CON
CEN
TRAT
ION
(UG
/L)
TIME
MW00-41-T
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-2 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 2 of 33
Checked by: APN
CP PUMPING
0
20
40
60
80
100
120
140
160
180
2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW00-42-MS
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-3 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 3 of 33
Checked by: APN
CP PUMPING
0
5
10
15
20
25
30
35
2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW00-42-T
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-4 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 4 of 33
Checked by: APN
CP PUMPING
0
100
200
300
400
500
600
700
800
900
1000
2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW00-43-BR
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-5 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 5 of 33
Checked by: APN
CP PUMPING
000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
MW00-43-T
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-6 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 6 of 33
Checked by: APN
CP PUMPING
002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
MW02-01-OPD
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-7 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 7 of 33
Checked by: APN
004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016
MW03-56-BR
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-8 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 8 of 33
Checked by: APN
CP PUMPING
003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
MW03-61-OPD
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-9 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 9 of 33
Checked by: APN
CP PUMPING
005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
MW04-155-T
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-10 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 10 of 33
Checked by: APN
CP PUMPING
004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
MW04-24-T
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-11 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 11 of 33
Checked by: APN
CP PUMPING
004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
MW04-25-T
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-12 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 12 of 33
Checked by: APN
CP PUMPING
004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
MW04-26-BR
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-13 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 13 of 33
Checked by: APN
CP PUMPING
004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
MW04-26-T
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-14 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 14 of 33
Checked by: APN
CP PUMPING
004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
MW04-28-I
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-15 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 15 of 33
Checked by: APN
CP PUMPING
004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
MW04-28-OPD
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-16 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 16 of 33
Checked by: APN
CP PUMPING
004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
MW04-28-T
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-17 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 17 of 33
Checked by: APN
CP PUMPING
0
100
200
300
400
500
600
700
800
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW04-29-BR
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-18 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 18 of 33
Checked by: APN
CP PUMPING
0
2000
4000
6000
8000
10000
12000
14000
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW04-30-BR
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-19 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 19 of 33
Checked by: APN
CP PUMPING
0
10
20
30
40
50
60
70
80
90
100
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW04-31-SP
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-20 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 20 of 33
Checked by: APN
CP PUMPING
004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
MW04-31-T
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-21 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 21 of 33
Checked by: APN
CP PUMPING
0
20
40
60
80
100
120
140
160
180
200
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW04-33-SP
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-22 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 22 of 33
Checked by: APN
CP PUMPING
0
20
40
60
80
100
120
140
160
180
200
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW04-33-T
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-23 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 23 of 33
Checked by: APN
CP PUMPING
0
500
1000
1500
2000
2500
3000
3500
4000
4500
5000
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW04-95-T
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-24 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 24 of 33
Checked by: APN
CP PUMPING
0
100
200
300
400
500
600
700
800
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW05-01-OPSH
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-25 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 25 of 33
Checked by: APN
CP PUMPING
0
20
40
60
80
100
120
2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW06-01-BR
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-26 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 26 of 33
Checked by: APN
CP PUMPING
0
100
200
300
400
500
600
700
800
2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW06-01-I
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-27 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 27 of 33
Checked by: APN
CP PUMPING
0
5
10
15
20
25
2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW06-01-T
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-28 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 28 of 33
Checked by: APN
CP PUMPING
0
50
100
150
200
250
300
2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW06-29-I
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-29 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 29 of 33
Checked by: APN
CP PUMPING
0
20
40
60
80
100
120
140
2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW06-248-I
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-30 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 30 of 33
Checked by: APN
CP PUMPING
0
1000
2000
3000
4000
5000
6000
7000
8000
2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW07-41-I
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-31 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 31 of 33
Checked by: APN
CP PUMPING
0
1000
2000
3000
4000
5000
6000
7000
8000
2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
CON
CEN
TRAT
ION
(UG
/L)
MW07-42-I
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-32 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 32 of 33
Checked by: APN
0
20
40
60
80
100
120
1997 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016
CON
CEN
TRAT
ION
(UG
/L)
MW-403D
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
Figure A-33 023-6105April 2016
G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 33 of 33
Checked by: APN
0
20
40
60
80
100
120
1997 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016
CON
CEN
TRAT
ION
(UG
/L)
MW-407D
Total CVOC
1,1,1-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
CIS-1,2-DICHLOROETHENE
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
CP PUMPING
Total CVOC_ND_only
1,1,1-TRICHLOROETHANE_ND_only
1,1-DICHLOROETHANE_ND_only
1,1-DICHLOROETHENE_ND_only
CIS-1,2-DICHLOROETHENE_ND_only
TETRACHLOROETHENE_ND_only
TRICHLOROETHENE_ND_only
VINYL CHLORIDE_ND_only
Non-detects are plotted at the reporting limit
APPENDIX B LABORATORY RESULTS
#=CL#
January 27, 2015
LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40109651
40109651Project:Pace Project No.:
RE:
Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102
023-6105-015 CP-SHOREHAM YARD
Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on January 22, 2015.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Laurie [email protected] Manager
Enclosures
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:Project:
40109651023-6105-015 CP-SHOREHAM YARD
Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334
New York Certification #: 11888North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Wisconsin Certification #: 405132750
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:Project:
40109651023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID Matrix Date Collected Date Received
40109651001 012115-0800-200 Water 01/21/15 08:00 01/22/15 08:35
40109651002 SE EFFLUENT Water 01/21/15 15:25 01/22/15 08:35
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 3 of 16
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:Project:
40109651023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts
40109651001 012115-0800-200 EPA 8260 71 PASI-GAMN
40109651002 SE EFFLUENT EPA 8260 71 PASI-GAMN
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 4 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40109651023-6105-015 CP-SHOREHAM YARD
Sample: 012115-0800-200 Lab ID: 40109651001 Collected: 01/21/15 08:00 Received: 01/22/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 01/26/15 14:24 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 01/26/15 14:24 107-05-120.0 2.2 1Benzene <0.50 ug/L 01/26/15 14:24 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 01/26/15 14:24 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 01/26/15 14:24 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 01/26/15 14:24 75-27-41.0 0.50 1Bromoform <0.50 ug/L 01/26/15 14:24 75-25-220.0 0.50 1Bromomethane <2.4 ug/L 01/26/15 14:24 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 01/26/15 14:24 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 01/26/15 14:24 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 01/26/15 14:24 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 01/26/15 14:24 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 01/26/15 14:24 56-23-520.0 0.50 1Chlorobenzene <0.50 ug/L 01/26/15 14:24 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 01/26/15 14:24 75-00-31.0 0.37 1Chloroform <2.5 ug/L 01/26/15 14:24 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 01/26/15 14:24 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 01/26/15 14:24 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 01/26/15 14:24 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 01/26/15 14:24 96-12-820.0 2.2 1Dibromochloromethane <0.50 ug/L 01/26/15 14:24 124-48-15.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 01/26/15 14:24 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 01/26/15 14:24 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 01/26/15 14:24 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 01/26/15 14:24 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 01/26/15 14:24 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 01/26/15 14:24 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 01/26/15 14:24 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 01/26/15 14:24 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 01/26/15 14:24 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 01/26/15 14:24 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 01/26/15 14:24 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 01/26/15 14:24 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 01/26/15 14:24 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 01/26/15 14:24 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 01/26/15 14:24 594-20-720.0 0.48 11,1-Dichloropropene <0.44 ug/L 01/26/15 14:24 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 01/26/15 14:24 10061-01-520.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 01/26/15 14:24 10061-02-620.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 01/26/15 14:24 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 01/26/15 14:24 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 01/26/15 14:24 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 01/26/15 14:24 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 01/26/15 14:24 99-87-61.0 0.50 1Methylene Chloride 0.34J ug/L 01/26/15 14:24 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 01/26/15 14:24 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2015 02:14 PM
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Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40109651023-6105-015 CP-SHOREHAM YARD
Sample: 012115-0800-200 Lab ID: 40109651001 Collected: 01/21/15 08:00 Received: 01/22/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 01/26/15 14:24 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 01/26/15 14:24 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 01/26/15 14:24 103-65-11.0 0.50 1Styrene <0.50 ug/L 01/26/15 14:24 100-42-55.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 01/26/15 14:24 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 01/26/15 14:24 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 01/26/15 14:24 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 01/26/15 14:24 109-99-95.0 2.0 1Toluene <0.50 ug/L 01/26/15 14:24 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 01/26/15 14:24 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 01/26/15 14:24 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 01/26/15 14:24 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 01/26/15 14:24 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 01/26/15 14:24 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 01/26/15 14:24 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 01/26/15 14:24 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 01/26/15 14:24 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 01/26/15 14:24 95-63-65.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 01/26/15 14:24 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 01/26/15 14:24 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 01/26/15 14:24 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 01/26/15 14:24 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 96 % 01/26/15 14:24 460-00-459-130 1Dibromofluoromethane (S) 101 % 01/26/15 14:24 1868-53-7 HS70-130 1Toluene-d8 (S) 99 % 01/26/15 14:24 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2015 02:14 PM
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Page 6 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40109651023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40109651002 Collected: 01/21/15 15:25 Received: 01/22/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 01/26/15 14:47 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 01/26/15 14:47 107-05-120.0 2.2 1Benzene <0.50 ug/L 01/26/15 14:47 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 01/26/15 14:47 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 01/26/15 14:47 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 01/26/15 14:47 75-27-41.0 0.50 1Bromoform <0.50 ug/L 01/26/15 14:47 75-25-220.0 0.50 1Bromomethane <2.4 ug/L 01/26/15 14:47 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 01/26/15 14:47 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 01/26/15 14:47 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 01/26/15 14:47 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 01/26/15 14:47 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 01/26/15 14:47 56-23-520.0 0.50 1Chlorobenzene <0.50 ug/L 01/26/15 14:47 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 01/26/15 14:47 75-00-31.0 0.37 1Chloroform <2.5 ug/L 01/26/15 14:47 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 01/26/15 14:47 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 01/26/15 14:47 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 01/26/15 14:47 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 01/26/15 14:47 96-12-820.0 2.2 1Dibromochloromethane <0.50 ug/L 01/26/15 14:47 124-48-15.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 01/26/15 14:47 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 01/26/15 14:47 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 01/26/15 14:47 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 01/26/15 14:47 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 01/26/15 14:47 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 01/26/15 14:47 75-71-81.0 0.22 11,1-Dichloroethane 13.9 ug/L 01/26/15 14:47 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 01/26/15 14:47 107-06-21.0 0.17 11,1-Dichloroethene 5.4 ug/L 01/26/15 14:47 75-35-41.0 0.41 1cis-1,2-Dichloroethene 9.7 ug/L 01/26/15 14:47 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 01/26/15 14:47 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 01/26/15 14:47 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 01/26/15 14:47 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 01/26/15 14:47 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 01/26/15 14:47 594-20-720.0 0.48 11,1-Dichloropropene <0.44 ug/L 01/26/15 14:47 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 01/26/15 14:47 10061-01-520.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 01/26/15 14:47 10061-02-620.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 01/26/15 14:47 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 01/26/15 14:47 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 01/26/15 14:47 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 01/26/15 14:47 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 01/26/15 14:47 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 01/26/15 14:47 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 01/26/15 14:47 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2015 02:14 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 7 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40109651023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40109651002 Collected: 01/21/15 15:25 Received: 01/22/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 01/26/15 14:47 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 01/26/15 14:47 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 01/26/15 14:47 103-65-11.0 0.50 1Styrene <0.50 ug/L 01/26/15 14:47 100-42-55.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 01/26/15 14:47 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 01/26/15 14:47 79-34-51.0 0.25 1Tetrachloroethene 47.5 ug/L 01/26/15 14:47 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 01/26/15 14:47 109-99-95.0 2.0 1Toluene <0.50 ug/L 01/26/15 14:47 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 01/26/15 14:47 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 01/26/15 14:47 120-82-15.0 2.2 11,1,1-Trichloroethane 13.0 ug/L 01/26/15 14:47 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 01/26/15 14:47 79-00-51.0 0.20 1Trichloroethene 5.2 ug/L 01/26/15 14:47 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 01/26/15 14:47 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 01/26/15 14:47 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 01/26/15 14:47 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 01/26/15 14:47 95-63-65.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 01/26/15 14:47 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 01/26/15 14:47 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 01/26/15 14:47 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 01/26/15 14:47 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 95 % 01/26/15 14:47 460-00-459-130 1Dibromofluoromethane (S) 101 % 01/26/15 14:47 1868-53-770-130 1Toluene-d8 (S) 99 % 01/26/15 14:47 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2015 02:14 PM
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Page 8 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40109651023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
MSV/27255EPA 8260
EPA 82608260 MSV
Associated Lab Samples: 40109651001, 40109651002
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1110668Associated Lab Samples: 40109651001, 40109651002
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 01/26/15 09:241,1,1-Trichloroethane ug/L <0.50 1.0 01/26/15 09:241,1,2,2-Tetrachloroethane ug/L <0.25 1.0 01/26/15 09:241,1,2-Trichloroethane ug/L <0.20 1.0 01/26/15 09:241,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 01/26/15 09:241,1-Dichloroethane ug/L <0.24 1.0 01/26/15 09:241,1-Dichloroethene ug/L <0.41 1.0 01/26/15 09:241,1-Dichloropropene ug/L <0.44 1.0 01/26/15 09:241,2,3-Trichlorobenzene ug/L <2.1 5.0 01/26/15 09:241,2,3-Trichloropropane ug/L <0.50 1.0 01/26/15 09:241,2,4-Trichlorobenzene ug/L <2.2 5.0 01/26/15 09:241,2,4-Trimethylbenzene ug/L <0.50 1.0 01/26/15 09:241,2-Dibromo-3-chloropropane ug/L <2.2 5.0 01/26/15 09:241,2-Dibromoethane (EDB) ug/L <0.18 1.0 01/26/15 09:241,2-Dichlorobenzene ug/L <0.50 1.0 01/26/15 09:241,2-Dichloroethane ug/L <0.17 1.0 01/26/15 09:241,2-Dichloropropane ug/L <0.23 1.0 01/26/15 09:241,3,5-Trimethylbenzene ug/L <0.50 1.0 01/26/15 09:241,3-Dichlorobenzene ug/L <0.50 1.0 01/26/15 09:241,3-Dichloropropane ug/L <0.50 1.0 01/26/15 09:241,4-Dichlorobenzene ug/L <0.50 1.0 01/26/15 09:242,2-Dichloropropane ug/L <0.48 1.0 01/26/15 09:242-Butanone (MEK) ug/L <3.0 20.0 01/26/15 09:242-Chlorotoluene ug/L <0.50 1.0 01/26/15 09:244-Chlorotoluene ug/L <0.21 1.0 01/26/15 09:244-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 01/26/15 09:24Acetone ug/L <3.0 20.0 01/26/15 09:24Allyl chloride ug/L <2.2 5.0 01/26/15 09:24Benzene ug/L <0.50 1.0 01/26/15 09:24Bromobenzene ug/L <0.23 1.0 01/26/15 09:24Bromochloromethane ug/L <0.34 1.0 01/26/15 09:24Bromodichloromethane ug/L <0.50 1.0 01/26/15 09:24Bromoform ug/L <0.50 1.0 01/26/15 09:24Bromomethane ug/L <2.4 5.0 01/26/15 09:24Carbon tetrachloride ug/L <0.50 1.0 01/26/15 09:24Chlorobenzene ug/L <0.50 1.0 01/26/15 09:24Chloroethane ug/L <0.37 1.0 01/26/15 09:24Chloroform ug/L <2.5 5.0 01/26/15 09:24Chloromethane ug/L <0.50 1.0 01/26/15 09:24cis-1,2-Dichloroethene ug/L <0.26 1.0 01/26/15 09:24cis-1,3-Dichloropropene ug/L <0.50 1.0 01/26/15 09:24
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2015 02:14 PM
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Page 9 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40109651023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1110668Associated Lab Samples: 40109651001, 40109651002
Matrix: Water
Analyzed
Dibromochloromethane ug/L <0.50 1.0 01/26/15 09:24Dibromomethane ug/L <0.43 1.0 01/26/15 09:24Dichlorodifluoromethane ug/L <0.22 1.0 01/26/15 09:24Dichlorofluoromethane ug/L <0.21 1.0 01/26/15 09:24Diethyl ether (Ethyl ether) ug/L <2.2 5.0 01/26/15 09:24Ethylbenzene ug/L <0.50 1.0 01/26/15 09:24Hexachloro-1,3-butadiene ug/L <2.1 5.0 01/26/15 09:24Isopropylbenzene (Cumene) ug/L <0.14 1.0 01/26/15 09:24m&p-Xylene ug/L <1.0 2.0 01/26/15 09:24Methyl-tert-butyl ether ug/L <0.17 1.0 01/26/15 09:24Methylene Chloride ug/L <0.23 1.0 01/26/15 09:24n-Butylbenzene ug/L <0.50 1.0 01/26/15 09:24n-Propylbenzene ug/L <0.50 1.0 01/26/15 09:24Naphthalene ug/L <2.5 5.0 01/26/15 09:24o-Xylene ug/L <0.50 1.0 01/26/15 09:24p-Isopropyltoluene ug/L <0.50 1.0 01/26/15 09:24sec-Butylbenzene ug/L <2.2 5.0 01/26/15 09:24Styrene ug/L <0.50 1.0 01/26/15 09:24tert-Butylbenzene ug/L <0.18 1.0 01/26/15 09:24Tetrachloroethene ug/L <0.50 1.0 01/26/15 09:24Tetrahydrofuran ug/L <2.0 5.0 01/26/15 09:24Toluene ug/L <0.50 1.0 01/26/15 09:24trans-1,2-Dichloroethene ug/L <0.26 1.0 01/26/15 09:24trans-1,3-Dichloropropene ug/L <0.23 1.0 01/26/15 09:24Trichloroethene ug/L <0.33 1.0 01/26/15 09:24Trichlorofluoromethane ug/L <0.18 1.0 01/26/15 09:24Vinyl chloride ug/L <0.18 1.0 01/26/15 09:244-Bromofluorobenzene (S) % 95 59-130 01/26/15 09:24Dibromofluoromethane (S) % 100 70-130 01/26/15 09:24Toluene-d8 (S) % 98 70-130 01/26/15 09:24
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1110669LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1110670
1,1,1-Trichloroethane ug/L 52.450 105 70-13010652.9 1 201,1,2,2-Tetrachloroethane ug/L 48.850 98 70-1309849.1 1 201,1,2-Trichloroethane ug/L 48.950 98 70-1309949.3 1 201,1,2-Trichlorotrifluoroethane ug/L 58.850 118 50-15011758.3 1 201,1-Dichloroethane ug/L 53.150 106 70-13010552.7 1 201,1-Dichloroethene ug/L 54.950 110 70-13211055.1 0 201,2,4-Trichlorobenzene ug/L 53.350 107 70-13010552.5 1 201,2-Dibromo-3-chloropropane ug/L 43.650 87 50-1508743.7 0 201,2-Dibromoethane (EDB) ug/L 49.250 98 70-13010150.3 2 201,2-Dichlorobenzene ug/L 49.650 99 70-1309849.0 1 20
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2015 02:14 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
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Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40109651023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1110669LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1110670
1,2-Dichloroethane ug/L 49.250 98 70-13010150.3 2 201,2-Dichloropropane ug/L 50.150 100 70-13010150.6 1 201,3-Dichlorobenzene ug/L 51.250 102 70-13010250.9 1 201,4-Dichlorobenzene ug/L 49.850 100 70-1309849.1 1 20Benzene ug/L 52.850 106 70-13010753.3 1 20Bromodichloromethane ug/L 50.450 101 70-13010150.6 1 20Bromoform ug/L 44.350 89 70-1309145.5 3 20Bromomethane ug/L 54.650 109 34-15711155.4 2 20Carbon tetrachloride ug/L 53.750 107 70-13210954.5 1 20Chlorobenzene ug/L 50.950 102 70-13010150.7 0 20Chloroethane ug/L 55.650 111 60-14310954.3 2 20Chloroform ug/L 49.250 98 70-1309748.7 1 20Chloromethane ug/L 58.250 116 43-14811557.6 1 20cis-1,2-Dichloroethene ug/L 51.550 103 51-13310250.8 1 20cis-1,3-Dichloropropene ug/L 44.050 88 70-1308844.2 0 20Dibromochloromethane ug/L 46.150 92 70-1309446.9 2 20Dichlorodifluoromethane ug/L 62.150 124 10-17412361.4 1 20Ethylbenzene ug/L 52.550 105 70-13010552.3 0 20Isopropylbenzene (Cumene) ug/L 53.850 108 70-13610854.1 1 20m&p-Xylene ug/L 106100 106 70-131106106 0 20Methyl-tert-butyl ether ug/L 50.250 100 54-13910150.4 0 20Methylene Chloride ug/L 50.950 102 70-13010250.9 0 20o-Xylene ug/L 53.650 107 70-13010753.7 0 20Styrene ug/L 48.950 98 70-1309849.0 0 20Tetrachloroethene ug/L 52.350 105 70-13010351.5 2 20Toluene ug/L 52.150 104 70-13010452.0 0 20trans-1,2-Dichloroethene ug/L 54.150 108 70-13010753.3 2 20trans-1,3-Dichloropropene ug/L 42.050 84 70-1308542.7 2 20Trichloroethene ug/L 52.850 106 70-13010753.3 1 20Trichlorofluoromethane ug/L 56.650 113 50-15010853.9 5 20Vinyl chloride ug/L 59.750 119 59-15711658.0 3 204-Bromofluorobenzene (S) % 100 59-130102Dibromofluoromethane (S) % 98 70-13099Toluene-d8 (S) % 98 70-13099
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1110671MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40109651002
1110672
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 50 111 70-130107 2 205013.0 68.3 66.71,1,2,2-Tetrachloroethane ug/L 50 100 70-13097 3 2050<0.25 50.0 48.51,1,2-Trichloroethane ug/L 50 100 70-13096 4 2050<0.20 50.2 48.21,1,2-Trichlorotrifluoroethane ug/L 50 116 50-154116 1 2050<0.81 58.2 57.91,1-Dichloroethane ug/L 50 104 70-130105 0 205013.9 66.2 66.21,1-Dichloroethene ug/L 50 106 70-138107 1 20505.4 58.2 58.9
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 11 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40109651023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1110671MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40109651002
1110672
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,2,4-Trichlorobenzene ug/L 50 106 70-130104 2 2050<2.2 53.2 51.91,2-Dibromo-3-chloropropane
ug/L 50 90 50-15087 4 2050<2.2 45.0 43.3
1,2-Dibromoethane (EDB) ug/L 50 100 70-13096 4 2050<0.18 50.1 48.11,2-Dichlorobenzene ug/L 50 100 70-13098 2 2050<0.50 50.1 49.11,2-Dichloroethane ug/L 50 100 70-13099 1 2050<0.17 49.8 49.31,2-Dichloropropane ug/L 50 102 70-130100 2 2050<0.23 51.0 50.11,3-Dichlorobenzene ug/L 50 102 70-130101 1 2050<0.50 51.1 50.41,4-Dichlorobenzene ug/L 50 101 70-130100 1 2050<0.50 50.5 49.9Benzene ug/L 50 107 70-130105 1 2050<0.50 53.6 52.9Bromodichloromethane ug/L 50 102 70-130101 1 2050<0.50 51.2 50.5Bromoform ug/L 50 92 70-13087 6 2050<0.50 46.2 43.7Bromomethane ug/L 50 111 34-159111 0 2050<2.4 55.6 55.5Carbon tetrachloride ug/L 50 109 70-132109 0 2050<0.50 54.4 54.4Chlorobenzene ug/L 50 102 70-130100 2 2050<0.50 50.9 50.1Chloroethane ug/L 50 108 60-143109 1 2050<0.37 54.0 54.6Chloroform ug/L 50 101 70-13096 4 2050<2.5 50.3 48.1Chloromethane ug/L 50 115 43-149112 3 2050<0.50 57.5 56.0cis-1,2-Dichloroethene ug/L 50 101 48-13799 1 33509.7 60.1 59.3cis-1,3-Dichloropropene ug/L 50 89 70-13087 2 2050<0.50 44.4 43.6Dibromochloromethane ug/L 50 95 70-13091 4 2050<0.50 47.4 45.7Dichlorodifluoromethane ug/L 50 123 10-174122 0 2050<0.22 61.3 61.0Ethylbenzene ug/L 50 106 70-130104 2 2050<0.50 53.1 51.8Isopropylbenzene (Cumene) ug/L 50 108 70-136107 2 2050<0.14 54.2 53.3m&p-Xylene ug/L 100 107 70-135104 3 20100<1.0 107 104Methyl-tert-butyl ether ug/L 50 102 54-13999 2 2050<0.17 50.9 49.7Methylene Chloride ug/L 50 102 70-133101 1 2050<0.23 50.8 50.3o-Xylene ug/L 50 109 70-130106 3 2050<0.50 54.4 53.0Styrene ug/L 50 99 70-13097 2 2050<0.50 49.4 48.5Tetrachloroethene ug/L 50 106 70-130102 2 205047.5 100 98.6Toluene ug/L 50 105 70-130103 1 2050<0.50 52.7 51.9trans-1,2-Dichloroethene ug/L 50 109 70-130108 1 2050<0.26 54.3 53.9trans-1,3-Dichloropropene ug/L 50 86 70-13085 1 2050<0.23 42.8 42.3Trichloroethene ug/L 50 107 70-130106 1 20505.2 58.8 58.0Trichlorofluoromethane ug/L 50 107 50-150106 1 2050<0.18 53.7 53.1Vinyl chloride ug/L 50 114 59-158115 1 2050<0.18 57.2 57.64-Bromofluorobenzene (S) % 100 59-130102Dibromofluoromethane (S) % 97 70-13099Toluene-d8 (S) % 98 70-13098
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2015 02:14 PM
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Page 12 of 16
#=QL#
QUALIFIERS
Pace Project No.:Project:
40109651023-6105-015 CP-SHOREHAM YARD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Green BayPASI-G
ANALYTE QUALIFIERS
Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter).HS
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 13 of 16
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:Project:
40109651023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch
40109651001 MSV/27255012115-0800-200 EPA 826040109651002 MSV/27255SE EFFLUENT EPA 8260
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2015 02:14 PM
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Page 14 of 16
Pag
e 15
of 1
6
Company Name:
Branch/Location:
~ Page UPPER MIDWEST REGION
612-607-1700 WI: 920-469-24 C'ree•1 ~vt 1
Quote#:
Phone: '{ 7 3 - b lf.S- - /C( 2. L CHAIN OF CUSTODY Mail To Contact:
*Preservation Codes Project Number: 0 2... '3- 6 { 0 S -C) /.) A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH
Project Name: . S'"-b re_ l.\'I ""1 ~ rel... H=Sodium Bisulfate Solution
Project State:
Sampled By (Print):
Sampled By (Sign):
PO#: L-12-0 z_ Data Package Options
(billable)
0 EPA Level Ill
0 EPA Level IV
MS/MSD 0 On your sample
(billable) 0 NOT needed on
your sample
PACE LAB# CLIENT FIELD ID
Regulatory Program:
FILTERED? (YES/NO)
PRESERVATION (CODE)*
Matrix Codes A= Air W:;: Water B = Biota OW = Drinking Water C = Charcoal GW = Ground Water 0 = Oil SW= Surface Water S = Soil WW= Waste Water Sl=Slud e WP=Wi
COLLECTION
DATE
!=Sodium Thiosulfate J=Other
Mail To Company:
Mail To Address:
Invoice To Contact:
Invoice To Company
Invoice To Address:
Invoice To Phone:
CLIENT COMMENTS
LAB COMMENTS (Lab Use Only)
of
Profile#
Rush Turnaround Time Requested - Prelims (Rush TAT subject to approval/surcharge)
Date Needed:
PACE Project No.
Transmit Prelim Rush Results by (complete what you want):
Emai1#1:
Emall#2:
Telephone:
ax:
Samples on HOLD are subject to
special pricing and release of liability
C019a(27 Jun2006)
Daterrime: eceived By: Datefrime:
Datemme: ived By: Datemme:
Page 16 of 16
Sample Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9
Green Bay, WI 54302
aceAnalyticat Project#:' WOl:40109651
Courier: r Fed Ex r UPS r Client r Pace Other: 1111111111111111111111 Tracking#: =t \2 4 9 b 40109651 Custody Seal on Cooler/Sox Present: [!)(yes - no Seals intact:(R"yes r no ..__
Custody Seal on Samples Present: ~ y~s (!)(no Seals intact: r yes - no
Packing Material: Bubble Wrap lb( Bubble Bags r None r Other
Thermometer Use f£ -Lf ~ Type of Ice:~ Blue Dry None 05( Samples on ice, cooling process has begun
Cooler Temperature Uncorr: I /Corr: I ~ogical Tissue is Frozen: r yes
Temp Blank Present: r yes f55{no r no Person examining contents: Date: I-~- ~1~ Initials: ;& I Temp should be above freezing to e•c for all sample except Biota.
Frozen Biota Samples should be received" o•c. Comments:
Samples Arrived within Hold Time: ON/A 5.
Sufficient Volume:
Correct Containers Used:
-Pace Containers Used:
-Pace IR Containers Used:
Containers Intact:
Filtered volume received for Dissolved tests
Sample Labels match COC:
-Includes date/time/ID/Anal sis Matrix:
0Yes 0No Date/Time:
0 ON/A 7.
ON/A 8.
{J(ies ONo ON/A 9.
{.)fyes 0No ON/A
10.
All containers needing preservation have been checked. ('~ (No~-9~~~a~i:;_ '!oted_i~ ~·l _____________ DY~~~~~ !:::\NJ_A 13. r HN03 r H2S04 r NaOH r NaOH +ZnAct
All contain.ers needing preservation are found to be in f\./ compliance with EPA recommendation. OYes ONo ~NIA <t!tl9~·~-~~ ~Qljgrt'-£~9.1. !:-laOf:! ~W- ____________ _ exceptions V A conform, TOC, TOX. TOH, ' O&G, WIDR , Phenolics, OTHER: Yes 0No
Heads ce in VOA Vials >6mm :
Trip Blank Present:
Trip Blank Custody Seals Present
ON/A 14.
ON/A 15.
ON/A
Person Contacted: Date/Time: If checked, see attached form for additional comments D
------------~ ---------Comm en ls/ Resolution: _____________________________________ _
Project Manager Review: U<.J Date: ij z.vl 1 '5
F-GB-C-031-Rev.02 (280ct2013) SCUR Form
#=CL#
February 17, 2015
LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40110554
40110554Project:Pace Project No.:
RE:
Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102
023-6105-015 CP-SHOREHAM YARD
Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on February 13, 2015.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Laurie [email protected] Manager
Enclosures
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:Project:
40110554023-6105-015 CP-SHOREHAM YARD
Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334
New York Certification #: 11888North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Wisconsin Certification #: 405132750
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:Project:
40110554023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID Matrix Date Collected Date Received
40110554001 021215-0800-200 Water 02/12/15 08:00 02/13/15 08:45
40110554002 SE EFFLUENT Water 02/12/15 15:00 02/13/15 08:45
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 3 of 16
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:Project:
40110554023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts
40110554001 021215-0800-200 EPA 8260 71 PASI-GLAP
40110554002 SE EFFLUENT EPA 8260 71 PASI-GLAP
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 4 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40110554023-6105-015 CP-SHOREHAM YARD
Sample: 021215-0800-200 Lab ID: 40110554001 Collected: 02/12/15 08:00 Received: 02/13/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone 7.9J ug/L 02/16/15 14:52 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 02/16/15 14:52 107-05-15.0 2.2 1Benzene <0.50 ug/L 02/16/15 14:52 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 02/16/15 14:52 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 02/16/15 14:52 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 02/16/15 14:52 75-27-41.0 0.50 1Bromoform <0.50 ug/L 02/16/15 14:52 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 02/16/15 14:52 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 02/16/15 14:52 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 02/16/15 14:52 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 02/16/15 14:52 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 02/16/15 14:52 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 02/16/15 14:52 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 02/16/15 14:52 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 02/16/15 14:52 75-00-31.0 0.37 1Chloroform <2.5 ug/L 02/16/15 14:52 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 02/16/15 14:52 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 02/16/15 14:52 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 02/16/15 14:52 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 02/16/15 14:52 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 02/16/15 14:52 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 02/16/15 14:52 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 02/16/15 14:52 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 02/16/15 14:52 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 02/16/15 14:52 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 02/16/15 14:52 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 02/16/15 14:52 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 02/16/15 14:52 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 02/16/15 14:52 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 02/16/15 14:52 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 02/16/15 14:52 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 02/16/15 14:52 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 02/16/15 14:52 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 02/16/15 14:52 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 02/16/15 14:52 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 02/16/15 14:52 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 02/16/15 14:52 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 02/16/15 14:52 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 02/16/15 14:52 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 02/16/15 14:52 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 02/16/15 14:52 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 02/16/15 14:52 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 02/16/15 14:52 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 02/16/15 14:52 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 02/16/15 14:52 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 02/16/15 14:52 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40110554023-6105-015 CP-SHOREHAM YARD
Sample: 021215-0800-200 Lab ID: 40110554001 Collected: 02/12/15 08:00 Received: 02/13/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 02/16/15 14:52 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 02/16/15 14:52 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 02/16/15 14:52 103-65-11.0 0.50 1Styrene <0.50 ug/L 02/16/15 14:52 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 02/16/15 14:52 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 02/16/15 14:52 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 02/16/15 14:52 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 02/16/15 14:52 109-99-95.0 2.0 1Toluene <0.50 ug/L 02/16/15 14:52 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 02/16/15 14:52 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 02/16/15 14:52 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 02/16/15 14:52 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 02/16/15 14:52 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 02/16/15 14:52 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 02/16/15 14:52 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 02/16/15 14:52 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 02/16/15 14:52 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 02/16/15 14:52 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 02/16/15 14:52 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 02/16/15 14:52 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 02/16/15 14:52 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 02/16/15 14:52 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 93 % 02/16/15 14:52 460-00-459-130 1Dibromofluoromethane (S) 110 % 02/16/15 14:52 1868-53-770-130 1Toluene-d8 (S) 100 % 02/16/15 14:52 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 6 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40110554023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40110554002 Collected: 02/12/15 15:00 Received: 02/13/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 02/16/15 15:14 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 02/16/15 15:14 107-05-15.0 2.2 1Benzene <0.50 ug/L 02/16/15 15:14 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 02/16/15 15:14 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 02/16/15 15:14 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 02/16/15 15:14 75-27-41.0 0.50 1Bromoform <0.50 ug/L 02/16/15 15:14 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 02/16/15 15:14 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 02/16/15 15:14 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 02/16/15 15:14 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 02/16/15 15:14 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 02/16/15 15:14 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 02/16/15 15:14 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 02/16/15 15:14 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 02/16/15 15:14 75-00-31.0 0.37 1Chloroform <2.5 ug/L 02/16/15 15:14 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 02/16/15 15:14 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 02/16/15 15:14 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 02/16/15 15:14 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 02/16/15 15:14 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 02/16/15 15:14 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 02/16/15 15:14 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 02/16/15 15:14 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 02/16/15 15:14 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 02/16/15 15:14 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 02/16/15 15:14 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 02/16/15 15:14 75-71-81.0 0.22 11,1-Dichloroethane 14.5 ug/L 02/16/15 15:14 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 02/16/15 15:14 107-06-21.0 0.17 11,1-Dichloroethene 5.6 ug/L 02/16/15 15:14 75-35-41.0 0.41 1cis-1,2-Dichloroethene 10.2 ug/L 02/16/15 15:14 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 02/16/15 15:14 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 02/16/15 15:14 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 02/16/15 15:14 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 02/16/15 15:14 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 02/16/15 15:14 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 02/16/15 15:14 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 02/16/15 15:14 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 02/16/15 15:14 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 02/16/15 15:14 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 02/16/15 15:14 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 02/16/15 15:14 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 02/16/15 15:14 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 02/16/15 15:14 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 02/16/15 15:14 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 02/16/15 15:14 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40110554023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40110554002 Collected: 02/12/15 15:00 Received: 02/13/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 02/16/15 15:14 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 02/16/15 15:14 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 02/16/15 15:14 103-65-11.0 0.50 1Styrene <0.50 ug/L 02/16/15 15:14 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 02/16/15 15:14 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 02/16/15 15:14 79-34-51.0 0.25 1Tetrachloroethene 48.5 ug/L 02/16/15 15:14 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 02/16/15 15:14 109-99-95.0 2.0 1Toluene <0.50 ug/L 02/16/15 15:14 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 02/16/15 15:14 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 02/16/15 15:14 120-82-15.0 2.2 11,1,1-Trichloroethane 15.6 ug/L 02/16/15 15:14 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 02/16/15 15:14 79-00-51.0 0.20 1Trichloroethene 5.4 ug/L 02/16/15 15:14 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 02/16/15 15:14 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 02/16/15 15:14 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 02/16/15 15:14 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 02/16/15 15:14 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 02/16/15 15:14 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 02/16/15 15:14 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 02/16/15 15:14 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 02/16/15 15:14 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 94 % 02/16/15 15:14 460-00-459-130 1Dibromofluoromethane (S) 110 % 02/16/15 15:14 1868-53-770-130 1Toluene-d8 (S) 101 % 02/16/15 15:14 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40110554023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
MSV/27465EPA 8260
EPA 82608260 MSV
Associated Lab Samples: 40110554001, 40110554002
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1117977Associated Lab Samples: 40110554001, 40110554002
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 02/16/15 09:161,1,1-Trichloroethane ug/L <0.50 1.0 02/16/15 09:161,1,2,2-Tetrachloroethane ug/L <0.25 1.0 02/16/15 09:161,1,2-Trichloroethane ug/L <0.20 1.0 02/16/15 09:161,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 02/16/15 09:161,1-Dichloroethane ug/L <0.24 1.0 02/16/15 09:161,1-Dichloroethene ug/L <0.41 1.0 02/16/15 09:161,1-Dichloropropene ug/L <0.44 1.0 02/16/15 09:161,2,3-Trichlorobenzene ug/L <2.1 5.0 02/16/15 09:161,2,3-Trichloropropane ug/L <0.50 1.0 02/16/15 09:161,2,4-Trichlorobenzene ug/L <2.2 5.0 02/16/15 09:161,2,4-Trimethylbenzene ug/L <0.50 1.0 02/16/15 09:161,2-Dibromo-3-chloropropane ug/L <2.2 5.0 02/16/15 09:161,2-Dibromoethane (EDB) ug/L <0.18 1.0 02/16/15 09:161,2-Dichlorobenzene ug/L <0.50 1.0 02/16/15 09:161,2-Dichloroethane ug/L <0.17 1.0 02/16/15 09:161,2-Dichloropropane ug/L <0.23 1.0 02/16/15 09:161,3,5-Trimethylbenzene ug/L <0.50 1.0 02/16/15 09:161,3-Dichlorobenzene ug/L <0.50 1.0 02/16/15 09:161,3-Dichloropropane ug/L <0.50 1.0 02/16/15 09:161,4-Dichlorobenzene ug/L <0.50 1.0 02/16/15 09:162,2-Dichloropropane ug/L <0.48 1.0 02/16/15 09:162-Butanone (MEK) ug/L <3.0 20.0 02/16/15 09:162-Chlorotoluene ug/L <0.50 1.0 02/16/15 09:164-Chlorotoluene ug/L <0.21 1.0 02/16/15 09:164-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 02/16/15 09:16Acetone ug/L <3.0 20.0 02/16/15 09:16Allyl chloride ug/L <2.2 5.0 02/16/15 09:16Benzene ug/L <0.50 1.0 02/16/15 09:16Bromobenzene ug/L <0.23 1.0 02/16/15 09:16Bromochloromethane ug/L <0.34 1.0 02/16/15 09:16Bromodichloromethane ug/L <0.50 1.0 02/16/15 09:16Bromoform ug/L <0.50 1.0 02/16/15 09:16Bromomethane ug/L <2.4 5.0 02/16/15 09:16Carbon tetrachloride ug/L <0.50 1.0 02/16/15 09:16Chlorobenzene ug/L <0.50 1.0 02/16/15 09:16Chloroethane ug/L <0.37 1.0 02/16/15 09:16Chloroform ug/L <2.5 5.0 02/16/15 09:16Chloromethane ug/L <0.50 1.0 02/16/15 09:16cis-1,2-Dichloroethene ug/L <0.26 1.0 02/16/15 09:16cis-1,3-Dichloropropene ug/L <0.50 1.0 02/16/15 09:16
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40110554023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1117977Associated Lab Samples: 40110554001, 40110554002
Matrix: Water
Analyzed
Dibromochloromethane ug/L <0.50 1.0 02/16/15 09:16Dibromomethane ug/L <0.43 1.0 02/16/15 09:16Dichlorodifluoromethane ug/L <0.22 1.0 02/16/15 09:16Dichlorofluoromethane ug/L <0.21 1.0 02/16/15 09:16Diethyl ether (Ethyl ether) ug/L <2.2 5.0 02/16/15 09:16Ethylbenzene ug/L <0.50 1.0 02/16/15 09:16Hexachloro-1,3-butadiene ug/L <2.1 5.0 02/16/15 09:16Isopropylbenzene (Cumene) ug/L <0.14 1.0 02/16/15 09:16m&p-Xylene ug/L <1.0 2.0 02/16/15 09:16Methyl-tert-butyl ether ug/L <0.17 1.0 02/16/15 09:16Methylene Chloride ug/L <0.23 1.0 02/16/15 09:16n-Butylbenzene ug/L <0.50 1.0 02/16/15 09:16n-Propylbenzene ug/L <0.50 1.0 02/16/15 09:16Naphthalene ug/L <2.5 5.0 02/16/15 09:16o-Xylene ug/L <0.50 1.0 02/16/15 09:16p-Isopropyltoluene ug/L <0.50 1.0 02/16/15 09:16sec-Butylbenzene ug/L <2.2 5.0 02/16/15 09:16Styrene ug/L <0.50 1.0 02/16/15 09:16tert-Butylbenzene ug/L <0.18 1.0 02/16/15 09:16Tetrachloroethene ug/L <0.50 1.0 02/16/15 09:16Tetrahydrofuran ug/L <2.0 5.0 02/16/15 09:16Toluene ug/L <0.50 1.0 02/16/15 09:16trans-1,2-Dichloroethene ug/L <0.26 1.0 02/16/15 09:16trans-1,3-Dichloropropene ug/L <0.23 1.0 02/16/15 09:16Trichloroethene ug/L <0.33 1.0 02/16/15 09:16Trichlorofluoromethane ug/L <0.18 1.0 02/16/15 09:16Vinyl chloride ug/L <0.18 1.0 02/16/15 09:164-Bromofluorobenzene (S) % 96 59-130 02/16/15 09:16Dibromofluoromethane (S) % 108 70-130 02/16/15 09:16Toluene-d8 (S) % 103 70-130 02/16/15 09:16
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1117978LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1117979
1,1,1-Trichloroethane ug/L 60.150 120 70-13012260.8 1 201,1,2,2-Tetrachloroethane ug/L 53.850 108 70-13010050.0 7 201,1,2-Trichloroethane ug/L 54.650 109 70-13010452.2 5 201,1,2-Trichlorotrifluoroethane ug/L 61.550 123 50-15012662.8 2 201,1-Dichloroethane ug/L 59.650 119 70-13012361.3 3 201,1-Dichloroethene ug/L 61.450 123 70-13212663.0 2 201,2,4-Trichlorobenzene ug/L 49.950 100 70-1309949.3 1 201,2-Dibromo-3-chloropropane ug/L 45.650 91 50-1508341.4 10 201,2-Dibromoethane (EDB) ug/L 55.350 111 70-13010552.3 6 201,2-Dichlorobenzene ug/L 53.050 106 70-13010552.6 1 20
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40110554023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1117978LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1117979
1,2-Dichloroethane ug/L 56.650 113 70-13011256.2 1 201,2-Dichloropropane ug/L 54.350 109 70-13011256.1 3 201,3-Dichlorobenzene ug/L 54.350 109 70-13010854.1 0 201,4-Dichlorobenzene ug/L 52.150 104 70-13010451.9 1 20Benzene ug/L 56.550 113 70-13011557.6 2 20Bromodichloromethane ug/L 55.050 110 70-13010954.6 1 20Bromoform ug/L 46.150 92 70-1308442.0 9 20Bromomethane ug/L 36.250 72 34-1578341.3 13 20Carbon tetrachloride ug/L 58.250 116 70-13211858.8 1 20Chlorobenzene ug/L 54.450 109 70-13010853.9 1 20Chloroethane ug/L 61.450 123 60-14312663.0 3 20Chloroform ug/L 59.550 119 70-13012160.5 2 20Chloromethane ug/L 48.850 98 43-14810552.5 7 20cis-1,2-Dichloroethene ug/L 57.450 115 51-13311858.9 2 20cis-1,3-Dichloropropene ug/L 52.750 105 70-13010452.1 1 20Dibromochloromethane ug/L 53.050 106 70-13010351.5 3 20Dichlorodifluoromethane ug/L 56.350 113 10-17412260.8 8 20Ethylbenzene ug/L 54.550 109 70-13010753.7 1 20Isopropylbenzene (Cumene) ug/L 53.750 107 70-13610753.6 0 20m&p-Xylene ug/L 111100 111 70-131109109 2 20Methyl-tert-butyl ether ug/L 57.050 114 54-13911055.2 3 20Methylene Chloride ug/L 57.150 114 70-13011758.7 3 20o-Xylene ug/L 54.750 109 70-13010954.6 0 20Styrene ug/L 53.550 107 70-13010552.7 1 20Tetrachloroethene ug/L 52.550 105 70-13010552.3 0 20Toluene ug/L 55.450 111 70-13011155.5 0 20trans-1,2-Dichloroethene ug/L 60.350 121 70-13012461.9 3 20trans-1,3-Dichloropropene ug/L 50.750 101 70-13010050.1 1 20Trichloroethene ug/L 57.050 114 70-13011557.3 1 20Trichlorofluoromethane ug/L 64.750 129 50-15013366.5 3 20Vinyl chloride ug/L 60.850 122 59-15712763.4 4 204-Bromofluorobenzene (S) % 98 59-13098Dibromofluoromethane (S) % 111 70-130111Toluene-d8 (S) % 100 70-13099
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1118417MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40110598019
1118418
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 50 120 70-130120 0 2050<0.50 60.2 60.11,1,2,2-Tetrachloroethane ug/L 50 101 70-130102 1 2050<0.25 50.3 50.81,1,2-Trichloroethane ug/L 50 104 70-130105 1 2050<0.20 52.0 52.41,1,2-Trichlorotrifluoroethane ug/L 50 125 50-154124 0 2050<0.81 62.4 62.21,1-Dichloroethane ug/L 50 119 70-130120 1 2050<0.24 59.7 60.01,1-Dichloroethene ug/L 50 123 70-138121 2 2050<0.41 61.7 60.5
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Page 11 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40110554023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1118417MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40110598019
1118418
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,2,4-Trichlorobenzene ug/L 50 96 70-13096 0 2050<2.2 48.7 49.01,2-Dibromo-3-chloropropane
ug/L 50 81 50-15087 7 2050<2.2 40.5 43.3
1,2-Dibromoethane (EDB) ug/L 50 104 70-130106 1 2050<0.18 52.1 52.81,2-Dichlorobenzene ug/L 50 105 70-130105 0 2050<0.50 52.3 52.31,2-Dichloroethane ug/L 50 111 70-130111 0 2050<0.17 55.6 55.71,2-Dichloropropane ug/L 50 110 70-130111 0 2050<0.23 55.1 55.41,3-Dichlorobenzene ug/L 50 108 70-130109 2 2050<0.50 53.8 54.61,4-Dichlorobenzene ug/L 50 104 70-130104 0 2050<0.50 51.8 51.9Benzene ug/L 50 113 70-130113 0 2050<0.50 56.7 56.5Bromodichloromethane ug/L 50 109 70-130108 0 2050<0.50 54.3 54.1Bromoform ug/L 50 86 70-13087 1 2050<0.50 42.9 43.3Bromomethane ug/L 50 80 34-15981 1 2050<2.4 40.2 40.6Carbon tetrachloride ug/L 50 116 70-132119 2 2050<0.50 58.2 59.5Chlorobenzene ug/L 50 108 70-130107 1 2050<0.50 54.1 53.7Chloroethane ug/L 50 125 60-143126 1 2050<0.37 62.3 63.0Chloroform ug/L 50 119 70-130119 0 2050<2.5 59.3 59.5Chloromethane ug/L 50 104 43-149103 1 2050<0.50 52.0 51.3cis-1,2-Dichloroethene ug/L 50 115 48-137115 1 3350<0.26 57.7 57.3cis-1,3-Dichloropropene ug/L 50 102 70-130102 0 2050<0.50 51.0 51.2Dibromochloromethane ug/L 50 102 70-130104 2 2050<0.50 50.8 52.0Dichlorodifluoromethane ug/L 50 117 10-174117 0 2050<0.22 58.6 58.7Ethylbenzene ug/L 50 107 70-130108 2 2050<0.50 53.3 54.1Isopropylbenzene (Cumene) ug/L 50 107 70-136108 1 2050<0.14 53.4 54.0m&p-Xylene ug/L 100 110 70-135110 0 20100<1.0 110 110Methyl-tert-butyl ether ug/L 50 109 54-139110 1 2050<0.17 54.6 55.2Methylene Chloride ug/L 50 115 70-133115 0 2050<0.23 57.5 57.3o-Xylene ug/L 50 109 70-130109 1 2050<0.50 54.3 54.7Styrene ug/L 50 104 70-130105 1 2050<0.50 51.9 52.6Tetrachloroethene ug/L 50 103 70-130103 0 2050<0.50 51.6 51.7Toluene ug/L 50 111 70-130110 1 2050<0.50 55.5 54.8trans-1,2-Dichloroethene ug/L 50 121 70-130121 0 2050<0.26 60.6 60.3trans-1,3-Dichloropropene ug/L 50 99 70-130100 1 2050<0.23 49.7 50.1Trichloroethene ug/L 50 112 70-130113 0 2050<0.33 56.0 56.3Trichlorofluoromethane ug/L 50 130 50-150132 2 2050<0.18 65.1 66.1Vinyl chloride ug/L 50 123 59-158123 0 2050<0.18 61.5 61.74-Bromofluorobenzene (S) % 96 59-13096Dibromofluoromethane (S) % 111 70-130110Toluene-d8 (S) % 99 70-130100
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#=QL#
QUALIFIERS
Pace Project No.:Project:
40110554023-6105-015 CP-SHOREHAM YARD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Green BayPASI-G
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2015 03:19 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 13 of 16
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:Project:
40110554023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch
40110554001 MSV/27465021215-0800-200 EPA 826040110554002 MSV/27465SE EFFLUENT EPA 8260
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2015 03:19 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 14 of 16
Pag
e 15
of 1
6(Please Print Clearly) UPPER MIDWEST REGION '-----'·--·~ Company Name: {JJ Cf1 (tie ;t"' .4-:5S"C1~ f'C~ Branch/Location: M +., 4vvc { N :r ce~·~ Project Contact: A-lrscV') 2:.."11
M•' 612-001-1100 wi, 920-4 ,_,.,.(;re~"" DUi~+:,l/
Quote#:
Phone: CHAIN OF CUSTODY Project Number:
Project Name:
Project State:
f
*Preservation Codes A=None B=HCL C=H2S04 D=HN03 E=DI Water
H=Sodium Bisulfate Solution !=Sodium Thlosulfate
FILTERED? (YES/NO)
Sampled By (Print): .A-l q '1 P~ ,' f / /IJ (,f-p) PRESERVATION (CODE)*
A'J_~(~
PACE LAB# CLIENT FIELD ID
Sampled By (Sign):
l=P=:=a=:=~=P=a=~=~=11~=a~===1=o=p==t=i~=:=:=/:;:. ~= ...... =0=~=s=1=1111=s=o==::::=A:::~::::~::.'=';:,=t=:cy=~=tr1=;===:=~=te=~=s==:::::I "J;_•. ,'")
0 0 On your sample B = Biota ow= Drinking Water 1· ~ EPA Level Ill (bi"llable) .• ·.· .. 11"'\. C = Charcoal GW = Ground Water -: - _ __ "-...)
0 EPA L I Iv 0 NOT d d O=Oil SW=SurfaceWater . > ll------.--e_v_e __ _._ ___ Y_o_u~-~-e_eP_le_
0
_"-=s'-=.Y:.So""il=-.......:.ww:.:....=...:W.:.:;ai:.::sc.,te_w_a_te_r ~ · .•..•. · SI = Sludoe WP = WiOA . . . . 1---C_OLLE_;:;;;.:.CTION_.;.;._.;.;.-1 MATRIX :i
DATE TIME
CJD\
F=Methanol
J=Other
G=NaOH
Mail To Contact:
Mail To Company:
Mail To Address:
Invoice To Contact:
Invoice To Company:
Invoice To Address:
Invoice To Phone:
CLIENT COMMENTS
LAB COMMENTS {lab Use Only)
Profile#
Rush Turnaround Time Requested - Prelims ~ ll
..._ __ <R-us_h_T_A_T_su_b-je_c_t-to_a_p_p_r_ov_a_l/_s_ur_c_ha_r_g_e_) -- l. -\-(mg)' 9 ) _ Date Needed: ' JJ!ll!_e: _1 f:27 ieceiv~ I f.&../ "L-Dr;~7l) 14 z.-/ JJ Bli~~-·) I·
Z~ifrFim~e: (!)~(-; ~6:ri),J J Ml K6 tf{3(l6 6Rl/S11----l_U_Jr_/--(--"-=ll Transmit Prelim Rush Results by (complete what you want):
Email #1: Relinquished By: 11-----t----------------;i Emall#2:
11-T_e_le..;.p_h_on_e_:_+-----------------!IRelinquished By: Fax:
Samples on HOLD are subject to
speclal pricing and release of llablllty
C019a(27 Jun2006)
Relinquished By:
Date/Time:
Datemme:
Datemme:
~eceived By:
Received By:
Received By:
-1
Receipt Temp = 9'I\ 1 C::::... •c 1 Datemme: U -J
Date/Time:
Dateffime:
Sample Receipt pH
OK I Adjusted Cooler Custodv Seal
rr~t I Not Present
Intact I Not Intact Versio .O 06 106
Page 16 of 16
· aceAnalytical n.
Sample Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9
Green Bay, WI 54302
roJect.#: W0#:40110554 111111 I II I 111111111111 40110554
Custody Seal on Cooler/Box Present: es - no Seals intact: es r no
cu~tody Seai on slrnY"I. ..• s Pr~sent: r~y· ~ ... 0 . Seals intact: r yes i no Packing Material: /IC)!lubble Wra~ ubble. Bags r None r Other ·
Thermometer Used CVJ.2 - . ~. Type of lce:@.9 Blue Ory None .x2Samples on ice, cooling process has begun
Cooler Temperature Uncorr: C. /Corr: , '? Biological Tissue is Frozen: r yes
Temp Blank Present: r yes r no :,on ~!i~~ents: Temp should be above freezing to e•c or all sample except Biota. Initials: _ p Frozen Biota Sam les should be received s o•c. Comments:
ON/A 1.
ONo ON/A 2.
0No ON/A 3.
Samples Arrived within Hold Time: ON/A 5.
OYes ONo Datemme:
Sufficient Volume:
Correct Containers Used:
-Pace Containers Used:
-Pace IR Containers Used:
Containers Intact:
Filtered volume received for Dissolved tests
Sample labels match COC:
-Includes date/time/ID/Anal sis Matrix: \N
ON/A 6.
ON/A 7.
ON/A 8.
ON/A 9.
ON/A
10.
0NtA 11.
ON/A 12.
All containers needing preservation have been checked. ~ (Non-Compliance noted in 13.) 0Yes 0No ..f_...._A 13. Ail c~~t;rr\;;;, ";;;;dl;g pr;~iVaii~ ;r; fou~d t;;" be-in • • - • - - -- Li)
r HN03 r H2S04 r NaOH r NaOH +ZnAct
compliance with EPA recommendation. OYes ONo ~A
(t!_Nfl~. ~s.2~ !::!!Ql:,l~l'!!\9~9.r. !:'l!Qlj~g}- ___ -~ _____ • -i.,....,..,...,.......,----...----------.....-....-------1 exceplions: coliform, TOC, TOX. TOH, Initial when Lab Sid #ID of O&G. WIOR • Phenollcs, OTHER: ONo completed preseivative
Heads ce in VOA Vials >6mm :
Trip Blank Present:
Trip Blank Custody Seals Present
ON/A 14.
ON/A 15.
ON/A
Person Contacted: _____________ Datemme: If checked, see attached form for additional comments D
Comments/ Resolution: _________________________________ _,__,___~
Project Manager Review:
F-GB-C-031-Rev.02 (280ct2013) SCUR Form
#=CL#
March 25, 2015
LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40111719
40111719Project:Pace Project No.:
RE:
Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102
023-6105-015 CP-SHOREHAM YARD
Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on March 14, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Laurie [email protected] Manager
Enclosures
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 1 of 33
#=CP#
CERTIFICATIONS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334
North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Wisconsin Certification #: 405132750
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 2 of 33
#=SS#
SAMPLE SUMMARY
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID Matrix Date Collected Date Received
40111719001 RW07-39-SP Water 03/13/15 16:05 03/14/15 08:05
40111719002 RW07-40-SP Water 03/13/15 16:10 03/14/15 08:05
40111719003 RW06-28-I Water 03/13/15 16:14 03/14/15 08:05
40111719004 RW07-38-I Water 03/13/15 16:17 03/14/15 08:05
40111719005 RW06-27-BR Water 03/13/15 16:20 03/14/15 08:05
40111719006 SE EFFLUENT Water 03/13/15 16:25 03/14/15 08:05
40111719007 031315-0800-200 Water 03/13/15 08:00 03/14/15 08:05
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 3 of 33
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts
40111719001 RW07-39-SP EPA 8260 71 PASI-GHNW
40111719002 RW07-40-SP EPA 8260 71 PASI-GHNW
40111719003 RW06-28-I EPA 8260 71 PASI-GHNW
40111719004 RW07-38-I EPA 8260 71 PASI-GHNW
40111719005 RW06-27-BR EPA 8260 71 PASI-GHNW
40111719006 SE EFFLUENT EPA 8260 71 PASI-GHNW
SM 2540D 1 PASI-GMLH
SM 4500-H+B 1 PASI-GDEY
EPA 410.4 1 PASI-GTJJ
40111719007 031315-0800-200 EPA 8260 71 PASI-GHNW
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 4 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: RW07-39-SP Lab ID: 40111719001 Collected: 03/13/15 16:05 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <14.8 ug/L 03/17/15 11:10 67-64-1100 14.8 5Allyl chloride <10.8 ug/L 03/17/15 11:10 107-05-125.0 10.8 5Benzene <2.5 ug/L 03/17/15 11:10 71-43-25.0 2.5 5Bromobenzene <1.2 ug/L 03/17/15 11:10 108-86-15.0 1.2 5Bromochloromethane <1.7 ug/L 03/17/15 11:10 74-97-55.0 1.7 5Bromodichloromethane <2.5 ug/L 03/17/15 11:10 75-27-45.0 2.5 5Bromoform <2.5 ug/L 03/17/15 11:10 75-25-25.0 2.5 5Bromomethane <12.2 ug/L 03/17/15 11:10 74-83-925.0 12.2 52-Butanone (MEK) <14.9 ug/L 03/17/15 11:10 78-93-3100 14.9 5n-Butylbenzene <2.5 ug/L 03/17/15 11:10 104-51-85.0 2.5 5sec-Butylbenzene <10.9 ug/L 03/17/15 11:10 135-98-825.0 10.9 5tert-Butylbenzene <0.90 ug/L 03/17/15 11:10 98-06-65.0 0.90 5Carbon tetrachloride <2.5 ug/L 03/17/15 11:10 56-23-55.0 2.5 5Chlorobenzene <2.5 ug/L 03/17/15 11:10 108-90-75.0 2.5 5Chloroethane <1.9 ug/L 03/17/15 11:10 75-00-35.0 1.9 5Chloroform <12.5 ug/L 03/17/15 11:10 67-66-325.0 12.5 5Chloromethane <2.5 ug/L 03/17/15 11:10 74-87-35.0 2.5 52-Chlorotoluene <2.5 ug/L 03/17/15 11:10 95-49-85.0 2.5 54-Chlorotoluene <1.1 ug/L 03/17/15 11:10 106-43-45.0 1.1 51,2-Dibromo-3-chloropropane <10.8 ug/L 03/17/15 11:10 96-12-825.0 10.8 5Dibromochloromethane <2.5 ug/L 03/17/15 11:10 124-48-15.0 2.5 51,2-Dibromoethane (EDB) <0.89 ug/L 03/17/15 11:10 106-93-45.0 0.89 5Dibromomethane <2.1 ug/L 03/17/15 11:10 74-95-35.0 2.1 51,2-Dichlorobenzene <2.5 ug/L 03/17/15 11:10 95-50-15.0 2.5 51,3-Dichlorobenzene <2.5 ug/L 03/17/15 11:10 541-73-15.0 2.5 51,4-Dichlorobenzene <2.5 ug/L 03/17/15 11:10 106-46-75.0 2.5 5Dichlorodifluoromethane <1.1 ug/L 03/17/15 11:10 75-71-85.0 1.1 51,1-Dichloroethane 40.8 ug/L 03/17/15 11:10 75-34-35.0 1.2 51,2-Dichloroethane <0.84 ug/L 03/17/15 11:10 107-06-25.0 0.84 51,1-Dichloroethene 13.2 ug/L 03/17/15 11:10 75-35-45.0 2.1 5cis-1,2-Dichloroethene 29.4 ug/L 03/17/15 11:10 156-59-25.0 1.3 5trans-1,2-Dichloroethene <1.3 ug/L 03/17/15 11:10 156-60-55.0 1.3 5Dichlorofluoromethane <1.1 ug/L 03/17/15 11:10 75-43-45.0 1.1 51,2-Dichloropropane <1.2 ug/L 03/17/15 11:10 78-87-55.0 1.2 51,3-Dichloropropane <2.5 ug/L 03/17/15 11:10 142-28-95.0 2.5 52,2-Dichloropropane <2.4 ug/L 03/17/15 11:10 594-20-75.0 2.4 51,1-Dichloropropene <2.2 ug/L 03/17/15 11:10 563-58-65.0 2.2 5cis-1,3-Dichloropropene <2.5 ug/L 03/17/15 11:10 10061-01-55.0 2.5 5trans-1,3-Dichloropropene <1.1 ug/L 03/17/15 11:10 10061-02-65.0 1.1 5Diethyl ether (Ethyl ether) <11.1 ug/L 03/17/15 11:10 60-29-725.0 11.1 5Ethylbenzene <2.5 ug/L 03/17/15 11:10 100-41-45.0 2.5 5Hexachloro-1,3-butadiene <10.5 ug/L 03/17/15 11:10 87-68-325.0 10.5 5Isopropylbenzene (Cumene) <0.72 ug/L 03/17/15 11:10 98-82-85.0 0.72 5p-Isopropyltoluene <2.5 ug/L 03/17/15 11:10 99-87-65.0 2.5 5Methylene Chloride <1.2 ug/L 03/17/15 11:10 75-09-25.0 1.2 54-Methyl-2-pentanone (MIBK) <10.7 ug/L 03/17/15 11:10 108-10-125.0 10.7 5
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 5 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: RW07-39-SP Lab ID: 40111719001 Collected: 03/13/15 16:05 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.87 ug/L 03/17/15 11:10 1634-04-45.0 0.87 5Naphthalene <12.5 ug/L 03/17/15 11:10 91-20-325.0 12.5 5n-Propylbenzene <2.5 ug/L 03/17/15 11:10 103-65-15.0 2.5 5Styrene <2.5 ug/L 03/17/15 11:10 100-42-55.0 2.5 51,1,1,2-Tetrachloroethane <0.90 ug/L 03/17/15 11:10 630-20-65.0 0.90 51,1,2,2-Tetrachloroethane <1.2 ug/L 03/17/15 11:10 79-34-55.0 1.2 5Tetrachloroethene 261 ug/L 03/17/15 11:10 127-18-45.0 2.5 5Tetrahydrofuran <10.2 ug/L 03/17/15 11:10 109-99-925.0 10.2 5Toluene <2.5 ug/L 03/17/15 11:10 108-88-35.0 2.5 51,2,3-Trichlorobenzene <10.7 ug/L 03/17/15 11:10 87-61-625.0 10.7 51,2,4-Trichlorobenzene <11.0 ug/L 03/17/15 11:10 120-82-125.0 11.0 51,1,1-Trichloroethane 110 ug/L 03/17/15 11:10 71-55-65.0 2.5 51,1,2-Trichloroethane <0.99 ug/L 03/17/15 11:10 79-00-55.0 0.99 5Trichloroethene 12.8 ug/L 03/17/15 11:10 79-01-65.0 1.7 5Trichlorofluoromethane <0.92 ug/L 03/17/15 11:10 75-69-45.0 0.92 51,2,3-Trichloropropane <2.5 ug/L 03/17/15 11:10 96-18-45.0 2.5 51,1,2-Trichlorotrifluoroethane <4.1 ug/L 03/17/15 11:10 76-13-125.0 4.1 51,2,4-Trimethylbenzene <2.5 ug/L 03/17/15 11:10 95-63-65.0 2.5 51,3,5-Trimethylbenzene <2.5 ug/L 03/17/15 11:10 108-67-85.0 2.5 5Vinyl chloride <0.88 ug/L 03/17/15 11:10 75-01-45.0 0.88 5m&p-Xylene <5.0 ug/L 03/17/15 11:10 179601-23-110.0 5.0 5o-Xylene <2.5 ug/L 03/17/15 11:10 95-47-65.0 2.5 5Surrogates4-Bromofluorobenzene (S) 90 % 03/17/15 11:10 460-00-470-130 5Dibromofluoromethane (S) 113 % 03/17/15 11:10 1868-53-770-130 5Toluene-d8 (S) 99 % 03/17/15 11:10 2037-26-570-130 5
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 6 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: RW07-40-SP Lab ID: 40111719002 Collected: 03/13/15 16:10 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 03/17/15 15:22 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 03/17/15 15:22 107-05-15.0 2.2 1Benzene <0.50 ug/L 03/17/15 15:22 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 03/17/15 15:22 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 03/17/15 15:22 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 03/17/15 15:22 75-27-41.0 0.50 1Bromoform <0.50 ug/L 03/17/15 15:22 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 03/17/15 15:22 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 03/17/15 15:22 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 03/17/15 15:22 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 03/17/15 15:22 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 03/17/15 15:22 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 03/17/15 15:22 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 03/17/15 15:22 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 03/17/15 15:22 75-00-31.0 0.37 1Chloroform <2.5 ug/L 03/17/15 15:22 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 03/17/15 15:22 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 03/17/15 15:22 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 03/17/15 15:22 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 03/17/15 15:22 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 03/17/15 15:22 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 03/17/15 15:22 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 03/17/15 15:22 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 03/17/15 15:22 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 03/17/15 15:22 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 03/17/15 15:22 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 03/17/15 15:22 75-71-81.0 0.22 11,1-Dichloroethane 2.4 ug/L 03/17/15 15:22 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 03/17/15 15:22 107-06-21.0 0.17 11,1-Dichloroethene 2.2 ug/L 03/17/15 15:22 75-35-41.0 0.41 1cis-1,2-Dichloroethene 1.5 ug/L 03/17/15 15:22 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 03/17/15 15:22 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 03/17/15 15:22 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 03/17/15 15:22 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 03/17/15 15:22 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 03/17/15 15:22 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 03/17/15 15:22 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 03/17/15 15:22 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 03/17/15 15:22 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 03/17/15 15:22 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 03/17/15 15:22 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 03/17/15 15:22 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 03/17/15 15:22 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 03/17/15 15:22 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 03/17/15 15:22 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 03/17/15 15:22 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 7 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: RW07-40-SP Lab ID: 40111719002 Collected: 03/13/15 16:10 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 03/17/15 15:22 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 03/17/15 15:22 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 03/17/15 15:22 103-65-11.0 0.50 1Styrene <0.50 ug/L 03/17/15 15:22 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 03/17/15 15:22 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 03/17/15 15:22 79-34-51.0 0.25 1Tetrachloroethene 60.6 ug/L 03/17/15 15:22 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 03/17/15 15:22 109-99-95.0 2.0 1Toluene <0.50 ug/L 03/17/15 15:22 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 03/17/15 15:22 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 03/17/15 15:22 120-82-15.0 2.2 11,1,1-Trichloroethane 13.5 ug/L 03/17/15 15:22 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 03/17/15 15:22 79-00-51.0 0.20 1Trichloroethene 3.3 ug/L 03/17/15 15:22 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 03/17/15 15:22 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 03/17/15 15:22 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 03/17/15 15:22 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 03/17/15 15:22 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 03/17/15 15:22 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 03/17/15 15:22 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 03/17/15 15:22 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 03/17/15 15:22 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 91 % 03/17/15 15:22 460-00-470-130 1Dibromofluoromethane (S) 114 % 03/17/15 15:22 1868-53-770-130 1Toluene-d8 (S) 100 % 03/17/15 15:22 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 8 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: RW06-28-I Lab ID: 40111719003 Collected: 03/13/15 16:14 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 03/17/15 15:45 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 03/17/15 15:45 107-05-15.0 2.2 1Benzene <0.50 ug/L 03/17/15 15:45 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 03/17/15 15:45 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 03/17/15 15:45 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 03/17/15 15:45 75-27-41.0 0.50 1Bromoform <0.50 ug/L 03/17/15 15:45 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 03/17/15 15:45 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 03/17/15 15:45 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 03/17/15 15:45 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 03/17/15 15:45 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 03/17/15 15:45 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 03/17/15 15:45 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 03/17/15 15:45 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 03/17/15 15:45 75-00-31.0 0.37 1Chloroform <2.5 ug/L 03/17/15 15:45 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 03/17/15 15:45 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 03/17/15 15:45 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 03/17/15 15:45 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 03/17/15 15:45 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 03/17/15 15:45 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 03/17/15 15:45 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 03/17/15 15:45 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 03/17/15 15:45 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 03/17/15 15:45 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 03/17/15 15:45 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 03/17/15 15:45 75-71-81.0 0.22 11,1-Dichloroethane 4.5 ug/L 03/17/15 15:45 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 03/17/15 15:45 107-06-21.0 0.17 11,1-Dichloroethene 1.2 ug/L 03/17/15 15:45 75-35-41.0 0.41 1cis-1,2-Dichloroethene 1.3 ug/L 03/17/15 15:45 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 03/17/15 15:45 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 03/17/15 15:45 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 03/17/15 15:45 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 03/17/15 15:45 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 03/17/15 15:45 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 03/17/15 15:45 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 03/17/15 15:45 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 03/17/15 15:45 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 03/17/15 15:45 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 03/17/15 15:45 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 03/17/15 15:45 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 03/17/15 15:45 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 03/17/15 15:45 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 03/17/15 15:45 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 03/17/15 15:45 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 9 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: RW06-28-I Lab ID: 40111719003 Collected: 03/13/15 16:14 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 03/17/15 15:45 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 03/17/15 15:45 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 03/17/15 15:45 103-65-11.0 0.50 1Styrene <0.50 ug/L 03/17/15 15:45 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 03/17/15 15:45 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 03/17/15 15:45 79-34-51.0 0.25 1Tetrachloroethene 8.2 ug/L 03/17/15 15:45 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 03/17/15 15:45 109-99-95.0 2.0 1Toluene <0.50 ug/L 03/17/15 15:45 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 03/17/15 15:45 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 03/17/15 15:45 120-82-15.0 2.2 11,1,1-Trichloroethane 4.2 ug/L 03/17/15 15:45 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 03/17/15 15:45 79-00-51.0 0.20 1Trichloroethene 0.85J ug/L 03/17/15 15:45 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 03/17/15 15:45 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 03/17/15 15:45 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 03/17/15 15:45 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 03/17/15 15:45 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 03/17/15 15:45 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 03/17/15 15:45 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 03/17/15 15:45 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 03/17/15 15:45 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 88 % 03/17/15 15:45 460-00-470-130 1Dibromofluoromethane (S) 111 % 03/17/15 15:45 1868-53-770-130 1Toluene-d8 (S) 98 % 03/17/15 15:45 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 10 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: RW07-38-I Lab ID: 40111719004 Collected: 03/13/15 16:17 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 03/17/15 16:08 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 03/17/15 16:08 107-05-15.0 2.2 1Benzene <0.50 ug/L 03/17/15 16:08 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 03/17/15 16:08 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 03/17/15 16:08 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 03/17/15 16:08 75-27-41.0 0.50 1Bromoform <0.50 ug/L 03/17/15 16:08 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 03/17/15 16:08 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 03/17/15 16:08 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 03/17/15 16:08 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 03/17/15 16:08 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 03/17/15 16:08 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 03/17/15 16:08 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 03/17/15 16:08 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 03/17/15 16:08 75-00-31.0 0.37 1Chloroform <2.5 ug/L 03/17/15 16:08 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 03/17/15 16:08 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 03/17/15 16:08 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 03/17/15 16:08 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 03/17/15 16:08 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 03/17/15 16:08 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 03/17/15 16:08 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 03/17/15 16:08 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 03/17/15 16:08 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 03/17/15 16:08 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 03/17/15 16:08 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 03/17/15 16:08 75-71-81.0 0.22 11,1-Dichloroethane 15.5 ug/L 03/17/15 16:08 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 03/17/15 16:08 107-06-21.0 0.17 11,1-Dichloroethene 4.7 ug/L 03/17/15 16:08 75-35-41.0 0.41 1cis-1,2-Dichloroethene 5.7 ug/L 03/17/15 16:08 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 03/17/15 16:08 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 03/17/15 16:08 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 03/17/15 16:08 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 03/17/15 16:08 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 03/17/15 16:08 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 03/17/15 16:08 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 03/17/15 16:08 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 03/17/15 16:08 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 03/17/15 16:08 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 03/17/15 16:08 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 03/17/15 16:08 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 03/17/15 16:08 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 03/17/15 16:08 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 03/17/15 16:08 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 03/17/15 16:08 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 11 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: RW07-38-I Lab ID: 40111719004 Collected: 03/13/15 16:17 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 03/17/15 16:08 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 03/17/15 16:08 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 03/17/15 16:08 103-65-11.0 0.50 1Styrene <0.50 ug/L 03/17/15 16:08 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 03/17/15 16:08 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 03/17/15 16:08 79-34-51.0 0.25 1Tetrachloroethene 44.7 ug/L 03/17/15 16:08 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 03/17/15 16:08 109-99-95.0 2.0 1Toluene <0.50 ug/L 03/17/15 16:08 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 03/17/15 16:08 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 03/17/15 16:08 120-82-15.0 2.2 11,1,1-Trichloroethane 10.6 ug/L 03/17/15 16:08 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 03/17/15 16:08 79-00-51.0 0.20 1Trichloroethene 4.8 ug/L 03/17/15 16:08 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 03/17/15 16:08 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 03/17/15 16:08 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 03/17/15 16:08 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 03/17/15 16:08 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 03/17/15 16:08 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 03/17/15 16:08 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 03/17/15 16:08 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 03/17/15 16:08 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 89 % 03/17/15 16:08 460-00-470-130 1Dibromofluoromethane (S) 113 % 03/17/15 16:08 1868-53-770-130 1Toluene-d8 (S) 99 % 03/17/15 16:08 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 12 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: RW06-27-BR Lab ID: 40111719005 Collected: 03/13/15 16:20 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 03/17/15 16:31 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 03/17/15 16:31 107-05-15.0 2.2 1Benzene <0.50 ug/L 03/17/15 16:31 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 03/17/15 16:31 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 03/17/15 16:31 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 03/17/15 16:31 75-27-41.0 0.50 1Bromoform <0.50 ug/L 03/17/15 16:31 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 03/17/15 16:31 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 03/17/15 16:31 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 03/17/15 16:31 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 03/17/15 16:31 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 03/17/15 16:31 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 03/17/15 16:31 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 03/17/15 16:31 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 03/17/15 16:31 75-00-31.0 0.37 1Chloroform <2.5 ug/L 03/17/15 16:31 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 03/17/15 16:31 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 03/17/15 16:31 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 03/17/15 16:31 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 03/17/15 16:31 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 03/17/15 16:31 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 03/17/15 16:31 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 03/17/15 16:31 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 03/17/15 16:31 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 03/17/15 16:31 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 03/17/15 16:31 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 03/17/15 16:31 75-71-81.0 0.22 11,1-Dichloroethane 11.5 ug/L 03/17/15 16:31 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 03/17/15 16:31 107-06-21.0 0.17 11,1-Dichloroethene 4.4 ug/L 03/17/15 16:31 75-35-41.0 0.41 1cis-1,2-Dichloroethene 13.5 ug/L 03/17/15 16:31 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 03/17/15 16:31 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 03/17/15 16:31 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 03/17/15 16:31 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 03/17/15 16:31 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 03/17/15 16:31 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 03/17/15 16:31 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 03/17/15 16:31 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 03/17/15 16:31 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 03/17/15 16:31 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 03/17/15 16:31 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 03/17/15 16:31 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 03/17/15 16:31 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 03/17/15 16:31 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 03/17/15 16:31 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 03/17/15 16:31 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 13 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: RW06-27-BR Lab ID: 40111719005 Collected: 03/13/15 16:20 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 03/17/15 16:31 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 03/17/15 16:31 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 03/17/15 16:31 103-65-11.0 0.50 1Styrene <0.50 ug/L 03/17/15 16:31 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 03/17/15 16:31 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 03/17/15 16:31 79-34-51.0 0.25 1Tetrachloroethene 31.1 ug/L 03/17/15 16:31 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 03/17/15 16:31 109-99-95.0 2.0 1Toluene <0.50 ug/L 03/17/15 16:31 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 03/17/15 16:31 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 03/17/15 16:31 120-82-15.0 2.2 11,1,1-Trichloroethane 8.8 ug/L 03/17/15 16:31 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 03/17/15 16:31 79-00-51.0 0.20 1Trichloroethene 5.4 ug/L 03/17/15 16:31 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 03/17/15 16:31 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 03/17/15 16:31 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 03/17/15 16:31 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 03/17/15 16:31 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 03/17/15 16:31 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 03/17/15 16:31 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 03/17/15 16:31 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 03/17/15 16:31 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 89 % 03/17/15 16:31 460-00-470-130 1Dibromofluoromethane (S) 114 % 03/17/15 16:31 1868-53-770-130 1Toluene-d8 (S) 97 % 03/17/15 16:31 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 14 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40111719006 Collected: 03/13/15 16:25 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 03/17/15 16:54 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 03/17/15 16:54 107-05-15.0 2.2 1Benzene <0.50 ug/L 03/17/15 16:54 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 03/17/15 16:54 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 03/17/15 16:54 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 03/17/15 16:54 75-27-41.0 0.50 1Bromoform <0.50 ug/L 03/17/15 16:54 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 03/17/15 16:54 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 03/17/15 16:54 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 03/17/15 16:54 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 03/17/15 16:54 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 03/17/15 16:54 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 03/17/15 16:54 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 03/17/15 16:54 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 03/17/15 16:54 75-00-31.0 0.37 1Chloroform <2.5 ug/L 03/17/15 16:54 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 03/17/15 16:54 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 03/17/15 16:54 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 03/17/15 16:54 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 03/17/15 16:54 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 03/17/15 16:54 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 03/17/15 16:54 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 03/17/15 16:54 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 03/17/15 16:54 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 03/17/15 16:54 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 03/17/15 16:54 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 03/17/15 16:54 75-71-81.0 0.22 11,1-Dichloroethane 13.7 ug/L 03/17/15 16:54 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 03/17/15 16:54 107-06-21.0 0.17 11,1-Dichloroethene 4.7 ug/L 03/17/15 16:54 75-35-41.0 0.41 1cis-1,2-Dichloroethene 9.8 ug/L 03/17/15 16:54 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 03/17/15 16:54 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 03/17/15 16:54 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 03/17/15 16:54 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 03/17/15 16:54 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 03/17/15 16:54 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 03/17/15 16:54 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 03/17/15 16:54 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 03/17/15 16:54 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 03/17/15 16:54 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 03/17/15 16:54 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 03/17/15 16:54 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 03/17/15 16:54 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 03/17/15 16:54 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 03/17/15 16:54 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 03/17/15 16:54 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 15 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40111719006 Collected: 03/13/15 16:25 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 03/17/15 16:54 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 03/17/15 16:54 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 03/17/15 16:54 103-65-11.0 0.50 1Styrene <0.50 ug/L 03/17/15 16:54 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 03/17/15 16:54 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 03/17/15 16:54 79-34-51.0 0.25 1Tetrachloroethene 49.5 ug/L 03/17/15 16:54 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 03/17/15 16:54 109-99-95.0 2.0 1Toluene <0.50 ug/L 03/17/15 16:54 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 03/17/15 16:54 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 03/17/15 16:54 120-82-15.0 2.2 11,1,1-Trichloroethane 15.5 ug/L 03/17/15 16:54 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 03/17/15 16:54 79-00-51.0 0.20 1Trichloroethene 5.5 ug/L 03/17/15 16:54 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 03/17/15 16:54 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 03/17/15 16:54 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 03/17/15 16:54 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 03/17/15 16:54 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 03/17/15 16:54 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 03/17/15 16:54 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 03/17/15 16:54 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 03/17/15 16:54 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 89 % 03/17/15 16:54 460-00-470-130 1Dibromofluoromethane (S) 116 % 03/17/15 16:54 1868-53-770-130 1Toluene-d8 (S) 99 % 03/17/15 16:54 2037-26-570-130 1
Analytical Method: SM 2540D2540D Total Suspended Solids
Total Suspended Solids <0.95 mg/L 03/18/15 15:072.0 0.95 1
Analytical Method: SM 4500-H+B4500H+ pH, Electrometric
pH 7.1 Std. Units 03/16/15 16:05 H60.10 0.010 1
Analytical Method: EPA 410.4 Preparation Method: EPA 410.4410.4 COD
Chemical Oxygen Demand <11.6 mg/L 03/25/15 10:4103/25/15 07:4850.0 11.6 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 16 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: 031315-0800-200 Lab ID: 40111719007 Collected: 03/13/15 08:00 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 03/18/15 11:09 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 03/18/15 11:09 107-05-15.0 2.2 1Benzene <0.50 ug/L 03/18/15 11:09 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 03/18/15 11:09 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 03/18/15 11:09 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 03/18/15 11:09 75-27-41.0 0.50 1Bromoform <0.50 ug/L 03/18/15 11:09 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 03/18/15 11:09 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 03/18/15 11:09 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 03/18/15 11:09 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 03/18/15 11:09 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 03/18/15 11:09 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 03/18/15 11:09 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 03/18/15 11:09 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 03/18/15 11:09 75-00-31.0 0.37 1Chloroform <2.5 ug/L 03/18/15 11:09 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 03/18/15 11:09 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 03/18/15 11:09 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 03/18/15 11:09 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 03/18/15 11:09 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 03/18/15 11:09 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 03/18/15 11:09 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 03/18/15 11:09 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 03/18/15 11:09 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 03/18/15 11:09 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 03/18/15 11:09 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 03/18/15 11:09 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 03/18/15 11:09 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 03/18/15 11:09 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 03/18/15 11:09 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 03/18/15 11:09 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 03/18/15 11:09 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 03/18/15 11:09 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 03/18/15 11:09 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 03/18/15 11:09 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 03/18/15 11:09 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 03/18/15 11:09 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 03/18/15 11:09 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 03/18/15 11:09 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 03/18/15 11:09 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 03/18/15 11:09 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 03/18/15 11:09 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 03/18/15 11:09 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 03/18/15 11:09 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 03/18/15 11:09 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 03/18/15 11:09 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
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Page 17 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Sample: 031315-0800-200 Lab ID: 40111719007 Collected: 03/13/15 08:00 Received: 03/14/15 08:05 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 03/18/15 11:09 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 03/18/15 11:09 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 03/18/15 11:09 103-65-11.0 0.50 1Styrene <0.50 ug/L 03/18/15 11:09 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 03/18/15 11:09 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 03/18/15 11:09 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 03/18/15 11:09 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 03/18/15 11:09 109-99-95.0 2.0 1Toluene <0.50 ug/L 03/18/15 11:09 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 03/18/15 11:09 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 03/18/15 11:09 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 03/18/15 11:09 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 03/18/15 11:09 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 03/18/15 11:09 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 03/18/15 11:09 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 03/18/15 11:09 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 03/18/15 11:09 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 03/18/15 11:09 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 03/18/15 11:09 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 03/18/15 11:09 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 03/18/15 11:09 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 03/18/15 11:09 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 91 % 03/18/15 11:09 460-00-470-130 1Dibromofluoromethane (S) 107 % 03/18/15 11:09 1868-53-770-130 1Toluene-d8 (S) 100 % 03/18/15 11:09 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
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Page 18 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
MSV/27760EPA 8260
EPA 82608260 MSV
Associated Lab Samples: 40111719001, 40111719002, 40111719003, 40111719004, 40111719005, 40111719006
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1128174Associated Lab Samples: 40111719001, 40111719002, 40111719003, 40111719004, 40111719005, 40111719006
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 03/17/15 06:351,1,1-Trichloroethane ug/L <0.50 1.0 03/17/15 06:351,1,2,2-Tetrachloroethane ug/L <0.25 1.0 03/17/15 06:351,1,2-Trichloroethane ug/L <0.20 1.0 03/17/15 06:351,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 03/17/15 06:351,1-Dichloroethane ug/L <0.24 1.0 03/17/15 06:351,1-Dichloroethene ug/L <0.41 1.0 03/17/15 06:351,1-Dichloropropene ug/L <0.44 1.0 03/17/15 06:351,2,3-Trichlorobenzene ug/L <2.1 5.0 03/17/15 06:351,2,3-Trichloropropane ug/L <0.50 1.0 03/17/15 06:351,2,4-Trichlorobenzene ug/L <2.2 5.0 03/17/15 06:351,2,4-Trimethylbenzene ug/L <0.50 1.0 03/17/15 06:351,2-Dibromo-3-chloropropane ug/L <2.2 5.0 03/17/15 06:351,2-Dibromoethane (EDB) ug/L <0.18 1.0 03/17/15 06:351,2-Dichlorobenzene ug/L <0.50 1.0 03/17/15 06:351,2-Dichloroethane ug/L <0.17 1.0 03/17/15 06:351,2-Dichloropropane ug/L <0.23 1.0 03/17/15 06:351,3,5-Trimethylbenzene ug/L <0.50 1.0 03/17/15 06:351,3-Dichlorobenzene ug/L <0.50 1.0 03/17/15 06:351,3-Dichloropropane ug/L <0.50 1.0 03/17/15 06:351,4-Dichlorobenzene ug/L <0.50 1.0 03/17/15 06:352,2-Dichloropropane ug/L <0.48 1.0 03/17/15 06:352-Butanone (MEK) ug/L <3.0 20.0 03/17/15 06:352-Chlorotoluene ug/L <0.50 1.0 03/17/15 06:354-Chlorotoluene ug/L <0.21 1.0 03/17/15 06:354-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 03/17/15 06:35Acetone ug/L <3.0 20.0 03/17/15 06:35Allyl chloride ug/L <2.2 5.0 03/17/15 06:35Benzene ug/L <0.50 1.0 03/17/15 06:35Bromobenzene ug/L <0.23 1.0 03/17/15 06:35Bromochloromethane ug/L <0.34 1.0 03/17/15 06:35Bromodichloromethane ug/L <0.50 1.0 03/17/15 06:35Bromoform ug/L <0.50 1.0 03/17/15 06:35Bromomethane ug/L <2.4 5.0 03/17/15 06:35Carbon tetrachloride ug/L <0.50 1.0 03/17/15 06:35Chlorobenzene ug/L <0.50 1.0 03/17/15 06:35Chloroethane ug/L <0.37 1.0 03/17/15 06:35Chloroform ug/L <2.5 5.0 03/17/15 06:35Chloromethane ug/L <0.50 1.0 03/17/15 06:35cis-1,2-Dichloroethene ug/L <0.26 1.0 03/17/15 06:35cis-1,3-Dichloropropene ug/L <0.50 1.0 03/17/15 06:35
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
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Page 19 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1128174Associated Lab Samples: 40111719001, 40111719002, 40111719003, 40111719004, 40111719005, 40111719006
Matrix: Water
Analyzed
Dibromochloromethane ug/L <0.50 1.0 03/17/15 06:35Dibromomethane ug/L <0.43 1.0 03/17/15 06:35Dichlorodifluoromethane ug/L <0.22 1.0 03/17/15 06:35Dichlorofluoromethane ug/L <0.21 1.0 03/17/15 06:35Diethyl ether (Ethyl ether) ug/L <2.2 5.0 03/17/15 06:35Ethylbenzene ug/L <0.50 1.0 03/17/15 06:35Hexachloro-1,3-butadiene ug/L <2.1 5.0 03/17/15 06:35Isopropylbenzene (Cumene) ug/L <0.14 1.0 03/17/15 06:35m&p-Xylene ug/L <1.0 2.0 03/17/15 06:35Methyl-tert-butyl ether ug/L <0.17 1.0 03/17/15 06:35Methylene Chloride ug/L <0.23 1.0 03/17/15 06:35n-Butylbenzene ug/L <0.50 1.0 03/17/15 06:35n-Propylbenzene ug/L <0.50 1.0 03/17/15 06:35Naphthalene ug/L <2.5 5.0 03/17/15 06:35o-Xylene ug/L <0.50 1.0 03/17/15 06:35p-Isopropyltoluene ug/L <0.50 1.0 03/17/15 06:35sec-Butylbenzene ug/L <2.2 5.0 03/17/15 06:35Styrene ug/L <0.50 1.0 03/17/15 06:35tert-Butylbenzene ug/L <0.18 1.0 03/17/15 06:35Tetrachloroethene ug/L <0.50 1.0 03/17/15 06:35Tetrahydrofuran ug/L <2.0 5.0 03/17/15 06:35Toluene ug/L <0.50 1.0 03/17/15 06:35trans-1,2-Dichloroethene ug/L <0.26 1.0 03/17/15 06:35trans-1,3-Dichloropropene ug/L <0.23 1.0 03/17/15 06:35Trichloroethene ug/L <0.33 1.0 03/17/15 06:35Trichlorofluoromethane ug/L <0.18 1.0 03/17/15 06:35Vinyl chloride ug/L <0.18 1.0 03/17/15 06:354-Bromofluorobenzene (S) % 90 70-130 03/17/15 06:35Dibromofluoromethane (S) % 111 70-130 03/17/15 06:35Toluene-d8 (S) % 99 70-130 03/17/15 06:35
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1128175LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1128176
1,1,1-Trichloroethane ug/L 58.350 117 70-13012060.0 3 201,1,2,2-Tetrachloroethane ug/L 55.550 111 70-13011055.2 1 201,1,2-Trichloroethane ug/L 55.750 111 70-13011457.1 3 201,1,2-Trichlorotrifluoroethane ug/L 60.150 120 50-15012060.1 0 201,1-Dichloroethane ug/L 54.750 109 70-13011255.9 2 201,1-Dichloroethene ug/L 53.750 107 70-13010753.6 0 201,2,4-Trichlorobenzene ug/L 51.650 103 70-13010552.4 2 201,2-Dibromo-3-chloropropane ug/L 41.150 82 50-1507839.1 5 201,2-Dibromoethane (EDB) ug/L 53.850 108 70-13010854.2 1 201,2-Dichlorobenzene ug/L 54.150 108 70-13010753.3 1 20
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
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Page 20 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1128175LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1128176
1,2-Dichloroethane ug/L 60.650 121 70-13112060.0 1 201,2-Dichloropropane ug/L 61.450 123 70-13011959.7 3 201,3-Dichlorobenzene ug/L 53.750 107 70-13010753.6 0 201,4-Dichlorobenzene ug/L 55.050 110 70-13010954.3 1 20Benzene ug/L 54.350 109 70-13011255.8 3 20Bromodichloromethane ug/L 53.950 108 70-13011255.9 4 20Bromoform ug/L 43.550 87 68-1308844.2 2 20Bromomethane ug/L 20.250 40 38-1374824.2 18 20Carbon tetrachloride ug/L 57.350 115 70-13011457.0 1 20Chlorobenzene ug/L 55.350 111 70-13011256.2 2 20Chloroethane ug/L 51.150 102 70-13610251.2 0 20Chloroform ug/L 58.050 116 70-13011758.4 1 20Chloromethane ug/L 39.450 79 48-1447839.2 0 20cis-1,2-Dichloroethene ug/L 55.150 110 70-13010954.3 1 20cis-1,3-Dichloropropene ug/L 48.550 97 70-1309949.5 2 20Dibromochloromethane ug/L 45.450 91 70-1309447.1 4 20Dichlorodifluoromethane ug/L 32.750 65 33-1576331.7 3 20Ethylbenzene ug/L 55.150 110 70-13211256.2 2 20Isopropylbenzene (Cumene) ug/L 54.350 109 70-13011155.3 2 20m&p-Xylene ug/L 111100 111 70-131113113 2 20Methyl-tert-butyl ether ug/L 49.350 99 48-14110250.8 3 20Methylene Chloride ug/L 53.050 106 70-13010552.6 1 20o-Xylene ug/L 54.750 109 70-13111155.4 1 20Styrene ug/L 52.050 104 70-13010854.1 4 20Tetrachloroethene ug/L 54.150 108 70-13010853.9 0 20Toluene ug/L 56.350 113 70-13011457.1 1 20trans-1,2-Dichloroethene ug/L 55.050 110 70-13011155.5 1 20trans-1,3-Dichloropropene ug/L 44.750 89 70-1309447.0 5 20Trichloroethene ug/L 56.750 113 70-13011657.8 2 20Trichlorofluoromethane ug/L 57.850 116 50-15011658.1 0 20Vinyl chloride ug/L 45.550 91 65-1429045.0 1 204-Bromofluorobenzene (S) % 94 70-13097Dibromofluoromethane (S) % 112 70-130113Toluene-d8 (S) % 98 70-13099
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1128265MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40111729007
1128266
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 50 118 70-130118 0 2050<0.50 59.0 58.91,1,2,2-Tetrachloroethane ug/L 50 110 70-130112 1 2050<0.25 55.2 55.81,1,2-Trichloroethane ug/L 50 115 70-130114 0 2050<0.20 57.5 57.21,1,2-Trichlorotrifluoroethane ug/L 50 121 50-151122 1 2050<0.81 60.4 60.81,1-Dichloroethane ug/L 50 111 70-134109 2 2050<0.24 55.3 54.31,1-Dichloroethene ug/L 50 105 70-139106 0 2050<0.41 52.7 52.9
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
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Page 21 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1128265MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40111729007
1128266
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,2,4-Trichlorobenzene ug/L 50 106 70-130106 0 2050<2.2 53.2 53.01,2-Dibromo-3-chloropropane
ug/L 50 83 50-15077 7 2050<2.2 41.6 38.7
1,2-Dibromoethane (EDB) ug/L 50 106 70-130108 2 2050<0.18 53.1 54.11,2-Dichlorobenzene ug/L 50 108 70-130109 1 2050<0.50 54.0 54.41,2-Dichloroethane ug/L 50 121 70-132122 1 2050<0.17 60.5 61.11,2-Dichloropropane ug/L 50 122 70-130120 1 2050<0.23 60.9 60.11,3-Dichlorobenzene ug/L 50 109 70-130108 1 2050<0.50 54.7 54.01,4-Dichlorobenzene ug/L 50 111 70-130112 1 2050<0.50 55.3 55.9Benzene ug/L 50 109 70-130111 2 2050<0.50 54.5 55.5Bromodichloromethane ug/L 50 109 70-132110 1 2050<0.50 54.7 55.2Bromoform ug/L 50 89 68-13090 1 2050<0.50 44.5 44.8Bromomethane ug/L 50 55 38-14156 2 2050<2.4 27.6 28.1Carbon tetrachloride ug/L 50 117 70-130115 2 2050<0.50 58.6 57.6Chlorobenzene ug/L 50 111 70-130111 0 2050<0.50 55.7 55.7Chloroethane ug/L 50 105 66-152101 4 2050<0.37 52.5 50.4Chloroform ug/L 50 114 70-130115 1 2050<2.5 57.1 57.4Chloromethane ug/L 50 82 44-15178 4 20500.63J 41.6 39.8cis-1,2-Dichloroethene ug/L 50 110 70-130111 1 2050<0.26 55.0 55.7cis-1,3-Dichloropropene ug/L 50 100 70-130100 0 2050<0.50 50.0 49.9Dibromochloromethane ug/L 50 93 70-13094 1 2050<0.50 46.6 47.0Dichlorodifluoromethane ug/L 50 61 29-16061 0 2050<0.22 30.5 30.5Ethylbenzene ug/L 50 112 70-132112 0 2050<0.50 56.1 56.0Isopropylbenzene (Cumene) ug/L 50 111 70-130112 1 2050<0.14 55.5 56.0m&p-Xylene ug/L 100 113 70-131112 0 20100<1.0 113 112Methyl-tert-butyl ether ug/L 50 103 48-143103 0 2050<0.17 51.5 51.4Methylene Chloride ug/L 50 107 70-130106 1 2050<0.23 53.3 52.8o-Xylene ug/L 50 111 70-131111 0 2050<0.50 55.5 55.3Styrene ug/L 50 109 70-130109 0 2050<0.50 54.3 54.5Tetrachloroethene ug/L 50 110 70-130109 1 2050<0.50 55.1 54.7Toluene ug/L 50 113 70-130113 0 2050<0.50 56.5 56.6trans-1,2-Dichloroethene ug/L 50 111 70-132111 0 2050<0.26 55.5 55.3trans-1,3-Dichloropropene ug/L 50 95 70-13093 2 2050<0.23 47.4 46.6Trichloroethene ug/L 50 113 70-130114 0 2050<0.33 56.7 56.9Trichlorofluoromethane ug/L 50 118 50-153118 0 2050<0.18 58.8 58.9Vinyl chloride ug/L 50 93 60-15592 1 2050<0.18 46.3 46.04-Bromofluorobenzene (S) % 95 70-13096Dibromofluoromethane (S) % 113 70-130111Toluene-d8 (S) % 99 70-13099
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
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Page 22 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
MSV/27765EPA 8260
EPA 82608260 MSV
Associated Lab Samples: 40111719007
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1128344Associated Lab Samples: 40111719007
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 03/18/15 05:481,1,1-Trichloroethane ug/L <0.50 1.0 03/18/15 05:481,1,2,2-Tetrachloroethane ug/L <0.25 1.0 03/18/15 05:481,1,2-Trichloroethane ug/L <0.20 1.0 03/18/15 05:481,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 03/18/15 05:481,1-Dichloroethane ug/L <0.24 1.0 03/18/15 05:481,1-Dichloroethene ug/L <0.41 1.0 03/18/15 05:481,1-Dichloropropene ug/L <0.44 1.0 03/18/15 05:481,2,3-Trichlorobenzene ug/L <2.1 5.0 03/18/15 05:481,2,3-Trichloropropane ug/L <0.50 1.0 03/18/15 05:481,2,4-Trichlorobenzene ug/L <2.2 5.0 03/18/15 05:481,2,4-Trimethylbenzene ug/L <0.50 1.0 03/18/15 05:481,2-Dibromo-3-chloropropane ug/L <2.2 5.0 03/18/15 05:481,2-Dibromoethane (EDB) ug/L <0.18 1.0 03/18/15 05:481,2-Dichlorobenzene ug/L <0.50 1.0 03/18/15 05:481,2-Dichloroethane ug/L <0.17 1.0 03/18/15 05:481,2-Dichloropropane ug/L <0.23 1.0 03/18/15 05:481,3,5-Trimethylbenzene ug/L <0.50 1.0 03/18/15 05:481,3-Dichlorobenzene ug/L <0.50 1.0 03/18/15 05:481,3-Dichloropropane ug/L <0.50 1.0 03/18/15 05:481,4-Dichlorobenzene ug/L <0.50 1.0 03/18/15 05:482,2-Dichloropropane ug/L <0.48 1.0 03/18/15 05:482-Butanone (MEK) ug/L <3.0 20.0 03/18/15 05:482-Chlorotoluene ug/L <0.50 1.0 03/18/15 05:484-Chlorotoluene ug/L <0.21 1.0 03/18/15 05:484-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 03/18/15 05:48Acetone ug/L <3.0 20.0 03/18/15 05:48Allyl chloride ug/L <2.2 5.0 03/18/15 05:48Benzene ug/L <0.50 1.0 03/18/15 05:48Bromobenzene ug/L <0.23 1.0 03/18/15 05:48Bromochloromethane ug/L <0.34 1.0 03/18/15 05:48Bromodichloromethane ug/L <0.50 1.0 03/18/15 05:48Bromoform ug/L <0.50 1.0 03/18/15 05:48Bromomethane ug/L <2.4 5.0 03/18/15 05:48Carbon tetrachloride ug/L <0.50 1.0 03/18/15 05:48Chlorobenzene ug/L <0.50 1.0 03/18/15 05:48Chloroethane ug/L <0.37 1.0 03/18/15 05:48Chloroform ug/L <2.5 5.0 03/18/15 05:48Chloromethane ug/L <0.50 1.0 03/18/15 05:48cis-1,2-Dichloroethene ug/L <0.26 1.0 03/18/15 05:48cis-1,3-Dichloropropene ug/L <0.50 1.0 03/18/15 05:48
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
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Page 23 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1128344Associated Lab Samples: 40111719007
Matrix: Water
Analyzed
Dibromochloromethane ug/L <0.50 1.0 03/18/15 05:48Dibromomethane ug/L <0.43 1.0 03/18/15 05:48Dichlorodifluoromethane ug/L <0.22 1.0 03/18/15 05:48Dichlorofluoromethane ug/L <0.21 1.0 03/18/15 05:48Diethyl ether (Ethyl ether) ug/L <2.2 5.0 03/18/15 05:48Ethylbenzene ug/L <0.50 1.0 03/18/15 05:48Hexachloro-1,3-butadiene ug/L <2.1 5.0 03/18/15 05:48Isopropylbenzene (Cumene) ug/L <0.14 1.0 03/18/15 05:48m&p-Xylene ug/L <1.0 2.0 03/18/15 05:48Methyl-tert-butyl ether ug/L <0.17 1.0 03/18/15 05:48Methylene Chloride ug/L <0.23 1.0 03/18/15 05:48n-Butylbenzene ug/L <0.50 1.0 03/18/15 05:48n-Propylbenzene ug/L <0.50 1.0 03/18/15 05:48Naphthalene ug/L <2.5 5.0 03/18/15 05:48o-Xylene ug/L <0.50 1.0 03/18/15 05:48p-Isopropyltoluene ug/L <0.50 1.0 03/18/15 05:48sec-Butylbenzene ug/L <2.2 5.0 03/18/15 05:48Styrene ug/L <0.50 1.0 03/18/15 05:48tert-Butylbenzene ug/L <0.18 1.0 03/18/15 05:48Tetrachloroethene ug/L <0.50 1.0 03/18/15 05:48Tetrahydrofuran ug/L <2.0 5.0 03/18/15 05:48Toluene ug/L <0.50 1.0 03/18/15 05:48trans-1,2-Dichloroethene ug/L <0.26 1.0 03/18/15 05:48trans-1,3-Dichloropropene ug/L <0.23 1.0 03/18/15 05:48Trichloroethene ug/L <0.33 1.0 03/18/15 05:48Trichlorofluoromethane ug/L <0.18 1.0 03/18/15 05:48Vinyl chloride ug/L <0.18 1.0 03/18/15 05:484-Bromofluorobenzene (S) % 87 70-130 03/18/15 05:48Dibromofluoromethane (S) % 112 70-130 03/18/15 05:48Toluene-d8 (S) % 98 70-130 03/18/15 05:48
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1128345LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1128346
1,1,1-Trichloroethane ug/L 59.650 119 70-13012662.8 5 201,1,2,2-Tetrachloroethane ug/L 57.150 114 70-13011959.4 4 201,1,2-Trichloroethane ug/L 58.050 116 70-13012060.0 3 201,1,2-Trichlorotrifluoroethane ug/L 57.050 114 50-15012261.1 7 201,1-Dichloroethane ug/L 56.450 113 70-13011657.8 2 201,1-Dichloroethene ug/L 52.350 105 70-13010753.7 2 201,2,4-Trichlorobenzene ug/L 50.950 102 70-13010753.3 5 201,2-Dibromo-3-chloropropane ug/L 41.650 83 50-1508844.2 6 201,2-Dibromoethane (EDB) ug/L 54.150 108 70-13011557.4 6 201,2-Dichlorobenzene ug/L 53.750 107 70-13011256.0 4 20
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
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Page 24 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1128345LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1128346
1,2-Dichloroethane ug/L 62.650 125 70-13113165.5 5 201,2-Dichloropropane ug/L 59.350 119 70-13012261.0 3 201,3-Dichlorobenzene ug/L 54.850 110 70-13011356.3 3 201,4-Dichlorobenzene ug/L 56.050 112 70-13011356.4 1 20Benzene ug/L 56.050 112 70-13011859.0 5 20Bromodichloromethane ug/L 55.650 111 70-13011557.7 4 20Bromoform ug/L 46.050 92 68-1309547.6 3 20Bromomethane ug/L 31.650 63 38-1377236.2 14 20Carbon tetrachloride ug/L 59.150 118 70-13012562.5 5 20Chlorobenzene ug/L 55.250 110 70-13011456.8 3 20Chloroethane ug/L 50.250 100 70-13610652.8 5 20Chloroform ug/L 58.050 116 70-13012361.3 6 20Chloromethane ug/L 40.450 81 48-1449045.1 11 20cis-1,2-Dichloroethene ug/L 55.350 111 70-13011758.5 6 20cis-1,3-Dichloropropene ug/L 50.650 101 70-13010351.7 2 20Dibromochloromethane ug/L 47.050 94 70-1309949.7 6 20Dichlorodifluoromethane ug/L 25.550 51 33-1575527.6 8 20Ethylbenzene ug/L 55.150 110 70-13211456.8 3 20Isopropylbenzene (Cumene) ug/L 55.150 110 70-13011356.4 2 20m&p-Xylene ug/L 110100 110 70-131114114 3 20Methyl-tert-butyl ether ug/L 51.850 104 48-14111055.0 6 20Methylene Chloride ug/L 53.050 106 70-13011356.3 6 20o-Xylene ug/L 54.550 109 70-13111155.6 2 20Styrene ug/L 51.550 103 70-13010552.7 2 20Tetrachloroethene ug/L 52.450 105 70-13010954.5 4 20Toluene ug/L 55.450 111 70-13011356.6 2 20trans-1,2-Dichloroethene ug/L 55.450 111 70-13011758.4 5 20trans-1,3-Dichloropropene ug/L 47.850 96 70-1309648.2 1 20Trichloroethene ug/L 57.350 115 70-13011858.9 3 20Trichlorofluoromethane ug/L 57.050 114 50-15011959.7 5 20Vinyl chloride ug/L 44.450 89 65-1429547.5 7 204-Bromofluorobenzene (S) % 96 70-13095Dibromofluoromethane (S) % 117 70-130118Toluene-d8 (S) % 99 70-13099
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1128349MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40111725001
1128350
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 50 124 70-130123 0 2050<0.50 61.9 61.61,1,2,2-Tetrachloroethane ug/L 50 118 70-130117 1 2050<0.25 59.2 58.71,1,2-Trichloroethane ug/L 50 118 70-130118 0 2050<0.20 59.0 58.81,1,2-Trichlorotrifluoroethane ug/L 50 122 50-151121 1 2050<0.81 60.8 60.41,1-Dichloroethane ug/L 50 114 70-134113 1 2050<0.24 57.1 56.61,1-Dichloroethene ug/L 50 106 70-139105 1 2050<0.41 53.0 52.3
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
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Page 25 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1128349MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40111725001
1128350
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,2,4-Trichlorobenzene ug/L 50 111 70-130107 3 2050<2.2 55.5 53.61,2-Dibromo-3-chloropropane
ug/L 50 85 50-15082 3 2050<2.2 42.4 41.0
1,2-Dibromoethane (EDB) ug/L 50 113 70-130110 2 2050<0.18 56.5 55.21,2-Dichlorobenzene ug/L 50 113 70-130113 1 2050<0.50 56.7 56.41,2-Dichloroethane ug/L 50 132 70-132130 2 2050<0.17 65.9 64.91,2-Dichloropropane ug/L 50 128 70-130126 2 2050<0.23 64.0 63.01,3-Dichlorobenzene ug/L 50 113 70-130113 1 2050<0.50 56.3 56.61,4-Dichlorobenzene ug/L 50 117 70-130117 0 2050<0.50 58.5 58.3Benzene ug/L 50 116 70-130115 0 2050<0.50 57.8 57.6Bromodichloromethane ug/L 50 116 70-132115 1 2050<0.50 57.9 57.6Bromoform ug/L 50 96 68-13096 0 2050<0.50 48.0 47.9Bromomethane ug/L 50 67 38-14174 11 2050<2.4 33.5 37.2Carbon tetrachloride ug/L 50 124 70-130123 0 2050<0.50 61.8 61.5Chlorobenzene ug/L 50 114 70-130113 1 2050<0.50 57.2 56.6Chloroethane ug/L 50 100 66-15299 2 2050<0.37 50.2 49.3Chloroform ug/L 50 121 70-130120 0 2050<2.5 60.4 60.2Chloromethane ug/L 50 82 44-15189 7 2050<0.50 41.2 44.3cis-1,2-Dichloroethene ug/L 50 115 70-130113 2 2050<0.26 57.7 56.4cis-1,3-Dichloropropene ug/L 50 106 70-130105 1 2050<0.50 52.8 52.5Dibromochloromethane ug/L 50 99 70-13097 1 2050<0.50 49.3 48.7Dichlorodifluoromethane ug/L 50 47 29-16047 1 2050<0.22 23.3 23.5Ethylbenzene ug/L 50 116 70-132112 3 2050<0.50 57.8 55.8Isopropylbenzene (Cumene) ug/L 50 114 70-130111 3 2050<0.14 57.2 55.4m&p-Xylene ug/L 100 113 70-131112 1 20100<1.0 113 112Methyl-tert-butyl ether ug/L 50 109 48-143108 1 2050<0.17 54.5 53.9Methylene Chloride ug/L 50 110 70-130109 1 2050<0.23 54.8 54.5o-Xylene ug/L 50 112 70-131110 2 2050<0.50 56.2 55.2Styrene ug/L 50 109 70-130106 3 2050<0.50 54.3 52.9Tetrachloroethene ug/L 50 111 70-130109 2 2050<0.50 55.5 54.3Toluene ug/L 50 114 70-130111 2 2050<0.50 57.1 55.7trans-1,2-Dichloroethene ug/L 50 114 70-132112 2 2050<0.26 57.2 56.2trans-1,3-Dichloropropene ug/L 50 99 70-13098 0 2050<0.23 49.3 49.0Trichloroethene ug/L 50 120 70-130118 2 2050<0.33 60.2 58.9Trichlorofluoromethane ug/L 50 117 50-153117 0 2050<0.18 58.7 58.6Vinyl chloride ug/L 50 92 60-15593 1 2050<0.18 45.9 46.54-Bromofluorobenzene (S) % 96 70-13094Dibromofluoromethane (S) % 117 70-130117Toluene-d8 (S) % 98 70-13095
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
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Page 26 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
WET/21481SM 2540D
SM 2540D2540D Total Suspended Solids
Associated Lab Samples: 40111719006
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1129226Associated Lab Samples: 40111719006
Matrix: Water
Analyzed
Total Suspended Solids mg/L <0.48 1.0 03/18/15 15:05
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1129227LABORATORY CONTROL SAMPLE:LCSSpike
Total Suspended Solids mg/L 92.0100 92 80-120
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401116220011129228SAMPLE DUPLICATE:
Total Suspended Solids mg/L 3.3 0 103.3
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401117630011129229SAMPLE DUPLICATE:
Total Suspended Solids mg/L 13.0 0 1013.0
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
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Green Bay, WI 54302(920)469-2436
Page 27 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
WET/21459SM 4500-H+B
SM 4500-H+B4500H+B pH
Associated Lab Samples: 40111719006
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401117190061128348SAMPLE DUPLICATE:
pH Std. Units 7.1 H60 57.1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 28 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
WETA/27705EPA 410.4
EPA 410.4410.4 COD
Associated Lab Samples: 40111719006
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1131144Associated Lab Samples: 40111719006
Matrix: Water
Analyzed
Chemical Oxygen Demand mg/L <11.6 50.0 03/25/15 10:41
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1131145LABORATORY CONTROL SAMPLE:LCSSpike
Chemical Oxygen Demand mg/L 507500 101 90-110
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1131146MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40111722001
1131147
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
Chemical Oxygen Demand mg/L 5000 100 90-11099 1 1050001400 6380 6340
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
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Page 29 of 33
#=QL#
QUALIFIERS
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Green BayPASI-G
ANALYTE QUALIFIERS
Analysis initiated outside of the 15 minute EPA recommended holding time.H6
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
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Page 30 of 33
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:Project:
40111719023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch
40111719001 MSV/27760RW07-39-SP EPA 826040111719002 MSV/27760RW07-40-SP EPA 826040111719003 MSV/27760RW06-28-I EPA 826040111719004 MSV/27760RW07-38-I EPA 826040111719005 MSV/27760RW06-27-BR EPA 826040111719006 MSV/27760SE EFFLUENT EPA 8260
40111719007 MSV/27765031315-0800-200 EPA 8260
40111719006 WET/21481SE EFFLUENT SM 2540D
40111719006 WET/21459SE EFFLUENT SM 4500-H+B
40111719006 WETA/27705 WETA/27722SE EFFLUENT EPA 410.4 EPA 410.4
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/25/2015 03:31 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 31 of 33
Pag
e 32
of 3
3UPPER MIDWEST REGION rG . "\ :b of (Please Print Clearly)
Company Name: G cl&l er A-ssdc1''l ~.s ~N= 612-607-1700 w1: 920-469 436 Grcc 111 J3:c Mt. kvve I ceAnalytical• ~ I J10fl/7 /Cf Branch/Location: Al "'S I www.pacelabs.com
Project Contact: ,4{ i'SIJVI C.olf Quote#:
Phone: "-'117 3-6'tS- JC(:L2.. CHAIN OF CUSTODY Mail To Contact:
Project Number: 02-3-610)-C'.>{5' I *Preservation Codes Mail To Company: A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH
Project Name: C /> ~ S~C?fe i.\1wi Yq~ H=Sodium Bisulfate Solution !=Sodium Thiosulfate J=Other
Mail To Address:
Project State: 11.tl ~-M ~/V N IV (YES/NO)
Sampled By (Print): AlCf>"l P~ (fl u; r (A-p PRESERVATION ~ c A Invoice To Contact: (CODE)*
Sampled By (Sign): ~2d~ I ; F Invoice To Company:
Regulatory .·
PO#: L-/2 ... o'L... •. Invoice To Address: Program: :•;; .::z: Data Package Oetions 11118/MSD Matrix Codes ,, ~ .. ·
~ ~
(billable) 0 On your sample A=Nr W=Water .. :
~ c ' DEPA Level Ill B =Biota OW= Drinking Water ....
(billable) C =Charcoal GW =Ground Water ;; 0 ;s Invoice To Phone:
D EPA level IV 0 NOT needed on O=Oil SW = Surface Water %£' • \) S=Soil WW= Waste Water > your sample SI= Sludoe WP=Wioe ~ CLIENT LAB COMMENTS Profile#
COLLECTION •·.· .• PACE LAB# CLIENT FIELD ID MATRIX
} . ..· .. COMMENTS (lab Use Only) DATE TIME
diilil l!ti 68~ a 15\!9 ., .. ~ - - - ,
:}';; - ,
lCXJ( f\W'c?7-3'f-SP VIW11 (605" Iv/ l3x ~~ 14Dt'rl { V B Q()Q., f-_W07·'1.~·· Sr Vrb11r. 6t0 w1 .: x f)(J ~ ~Vc'.96~ 2-'0 -I. 'J/1b/1 'i {6t'f '~ 3~ flnlf ~VO?- 3$' - I '3!1iJ17 l6l7 "'/' 3X OD~ fZ.. v ~6- 2-7- 5~ Mi,//1 (6U) \./ 3X \/ .i;,-1~ -1
.CJ il\I\ M-
()n L-·:; SE eftl "\Cl'\ f- ~hlr!t~ 162-S- 'vJ '/. " 1' ' -l
o fl I -:JS(}"' t:, lJ - v Otvi' vi'> ~ h·- 11 ~·
"I ·-(9()/ o 3 l 3 i)-~sco ~. 2Ao ~/(j/15 ~(CCI w 't • I 6' .
;i_. · 4DriA V { - i -A I ...., c '""'·- J ,... f'(1 fV\ . II ·I
I .../ ...
,.~i'~'i~ ':\. ; .. •··. ··:·
·•· .. ;,':' .. ;
\_· ....•. Rush Turnaround Time Requested - Prelims Relinq~;,,, P4i//,f)) 3//5i/f8 1157 ~~ °"V(o/1> ,r:, R'h
PACE Project No.
(Rush TAT subject to approval/surcharge) #0111719 Date Needed: Reli\r"rlB\ ~ J>
, 3·-i~t:'fs 6&05 Recel~JtA•.Wi "l!o(A .. J.at~'"lt-/'S ~ Transmit Prelim Rush Results by (complete what you want):
Receipt Temp =3. !:> •c mall#1: Relinquished By: Date/Time: Received By: '-.J Date/Time:
~~~e: Sample Receipt pH
Relinquished By: Date/Time; Received By: Date/Time: OK I Adjusted . Cooler Custodv Seal
Samples on HOLD are subject to Relinquished By: Date/Time: Received By: Date/Time: Present t(N'ot PresentJ
special pricing and release of liability Intact I Not Intact version 6.0 06114/06
C019a(27 Jun2006)
Page 33 of 33
Sample Condition Upon Receipt
'ace Analytical' 1 Project#:
G- D\occ u -sso. Courier: r Fed Ex r UPS i Client r p ce Other: wo...>..-\-C...Q Tracking#: \ 3 - /
Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9
Green Bay, Wt 54302
W0#:40111719 KmJ1~1111111111111
Custody Seal on Cooler/Box Present: r yes ~o Seals intact: r yes ref r/ Custody Seal on Sampl;if'Present: r Y¥'fV"no. Seals intact: r yes efno Packing Material: f\i"'Bubble Wrap .f\/ Bubble Bags r None r Other / Thermometer Used .. 6 R_, -0{. Type of Ice: ({iij) Blue Dry None--f\1---,""s_a_m_p_le_s_o_n-ice-, -co-o-lin_g_p-roc-e-ss_h_a_s_be-gu_n __
Cooler Temperature Uncorr: 3 /Corr: 3 (' 5 Biological Tissue is Frozen: r yes
Temp Blank Present: r yes ?no r no Date: 3 · I "--1 ·• ~ Person ~xam. injn9 ~!,ents:
Temp should be above freezing to e•c for all sample except Biota. Frozen Biota Samples should be received s o•c. Comments: Initials: iC\t\ . .
Chain of Custod Present: ON/A 1.
Chain of Custod Filled Out ON/A 2.
Chain of Custod Relin uished: ON/A 3.
sam ler Name & Si nature on coc: ON/A 4.
Samples Arrived within Hold Time: ONo ON/A 5.
0Yes 0No Datemme:
Rush Turn Around Time Re uested:
Sufficient Volume:
Correct Containers Used:
-Pace Containers Used:
-Pace IR Containers Used:
Containers Intact:
Filtered volume received for Dissolved tests
Sample Labels match COC:
-Includes date/time/ID/Anal sis
Heads ace in VOA Vials >6mm :
Trip Blank Present:
Matrix:
Trip Blank Custody Seals Present
Pace Tri Blank Lot# if urchased : 3 -;L ~ Client Notification/ Resolution:
OYes
es
0Yes
DYes
ON/A
ON/A
ON/A
0No ON/A
0No ON/A
0No ON/A
No ON/A
6.
7.
8.
9.
10.
11.
12. OO/p - ~'llfL S tt-r ~ h'l6 rn::s not-on COG·
r HN03 H2S04 r NaOH r NaOH +ZnAct
Initial when completed
14.
Lab Std #ID of preservative
ON/A 15.
0No ON/A
If checked, see attached form for additional comments 0 Person Contacted:--------------Datemme:
Comments/ Resolution: ---------------------------------------
Project Manager Review:
F-GB-C-031-Rev.02 (280ct2013) SCUR Form
#=CL#
April 21, 2015
LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40113336
40113336Project:Pace Project No.:
RE:
Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102
023-6105-015 CP-SHOREHAM YARD
Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on April 17, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Laurie [email protected] Manager
Enclosures
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:Project:
40113336023-6105-015 CP-SHOREHAM YARD
Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334
North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Wisconsin Certification #: 405132750
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:Project:
40113336023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID Matrix Date Collected Date Received
40113336001 041515-0800-200 Water 04/15/15 08:00 04/17/15 08:45
40113336002 SE EFFLUENT Water 04/15/15 08:55 04/17/15 08:45
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 3 of 16
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:Project:
40113336023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts
40113336001 041515-0800-200 EPA 8260 71 PASI-GLAP
40113336002 SE EFFLUENT EPA 8260 71 PASI-GLAP
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 4 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40113336023-6105-015 CP-SHOREHAM YARD
Sample: 041515-0800-200 Lab ID: 40113336001 Collected: 04/15/15 08:00 Received: 04/17/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 04/20/15 10:23 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 04/20/15 10:23 107-05-15.0 2.2 1Benzene <0.50 ug/L 04/20/15 10:23 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 04/20/15 10:23 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 04/20/15 10:23 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 04/20/15 10:23 75-27-41.0 0.50 1Bromoform <0.50 ug/L 04/20/15 10:23 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 04/20/15 10:23 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 04/20/15 10:23 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 04/20/15 10:23 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 04/20/15 10:23 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 04/20/15 10:23 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 04/20/15 10:23 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 04/20/15 10:23 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 04/20/15 10:23 75-00-31.0 0.37 1Chloroform <2.5 ug/L 04/20/15 10:23 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 04/20/15 10:23 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 04/20/15 10:23 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 04/20/15 10:23 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 04/20/15 10:23 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 04/20/15 10:23 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 04/20/15 10:23 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 04/20/15 10:23 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 04/20/15 10:23 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 04/20/15 10:23 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 04/20/15 10:23 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 04/20/15 10:23 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 04/20/15 10:23 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 04/20/15 10:23 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 04/20/15 10:23 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 04/20/15 10:23 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 04/20/15 10:23 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 04/20/15 10:23 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 04/20/15 10:23 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 04/20/15 10:23 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 04/20/15 10:23 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 04/20/15 10:23 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 04/20/15 10:23 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 04/20/15 10:23 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 04/20/15 10:23 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 04/20/15 10:23 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 04/20/15 10:23 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 04/20/15 10:23 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 04/20/15 10:23 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 04/20/15 10:23 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 04/20/15 10:23 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 03:23 PM
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Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40113336023-6105-015 CP-SHOREHAM YARD
Sample: 041515-0800-200 Lab ID: 40113336001 Collected: 04/15/15 08:00 Received: 04/17/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 04/20/15 10:23 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 04/20/15 10:23 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 04/20/15 10:23 103-65-11.0 0.50 1Styrene <0.50 ug/L 04/20/15 10:23 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 04/20/15 10:23 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 04/20/15 10:23 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 04/20/15 10:23 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 04/20/15 10:23 109-99-95.0 2.0 1Toluene <0.50 ug/L 04/20/15 10:23 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 04/20/15 10:23 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 04/20/15 10:23 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 04/20/15 10:23 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 04/20/15 10:23 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 04/20/15 10:23 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 04/20/15 10:23 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 04/20/15 10:23 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 04/20/15 10:23 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 04/20/15 10:23 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 04/20/15 10:23 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 04/20/15 10:23 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 04/20/15 10:23 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 04/20/15 10:23 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 99 % 04/20/15 10:23 460-00-470-130 1Dibromofluoromethane (S) 99 % 04/20/15 10:23 1868-53-770-130 1Toluene-d8 (S) 100 % 04/20/15 10:23 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 03:23 PM
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Page 6 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40113336023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40113336002 Collected: 04/15/15 08:55 Received: 04/17/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 04/20/15 10:01 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 04/20/15 10:01 107-05-15.0 2.2 1Benzene <0.50 ug/L 04/20/15 10:01 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 04/20/15 10:01 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 04/20/15 10:01 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 04/20/15 10:01 75-27-41.0 0.50 1Bromoform <0.50 ug/L 04/20/15 10:01 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 04/20/15 10:01 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 04/20/15 10:01 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 04/20/15 10:01 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 04/20/15 10:01 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 04/20/15 10:01 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 04/20/15 10:01 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 04/20/15 10:01 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 04/20/15 10:01 75-00-31.0 0.37 1Chloroform <2.5 ug/L 04/20/15 10:01 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 04/20/15 10:01 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 04/20/15 10:01 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 04/20/15 10:01 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 04/20/15 10:01 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 04/20/15 10:01 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 04/20/15 10:01 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 04/20/15 10:01 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 04/20/15 10:01 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 04/20/15 10:01 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 04/20/15 10:01 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 04/20/15 10:01 75-71-81.0 0.22 11,1-Dichloroethane 12.5 ug/L 04/20/15 10:01 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 04/20/15 10:01 107-06-21.0 0.17 11,1-Dichloroethene 5.4 ug/L 04/20/15 10:01 75-35-41.0 0.41 1cis-1,2-Dichloroethene 9.4 ug/L 04/20/15 10:01 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 04/20/15 10:01 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 04/20/15 10:01 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 04/20/15 10:01 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 04/20/15 10:01 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 04/20/15 10:01 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 04/20/15 10:01 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 04/20/15 10:01 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 04/20/15 10:01 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 04/20/15 10:01 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 04/20/15 10:01 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 04/20/15 10:01 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 04/20/15 10:01 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 04/20/15 10:01 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 04/20/15 10:01 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 04/20/15 10:01 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 03:23 PM
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Page 7 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40113336023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40113336002 Collected: 04/15/15 08:55 Received: 04/17/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 04/20/15 10:01 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 04/20/15 10:01 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 04/20/15 10:01 103-65-11.0 0.50 1Styrene <0.50 ug/L 04/20/15 10:01 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 04/20/15 10:01 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 04/20/15 10:01 79-34-51.0 0.25 1Tetrachloroethene 48.2 ug/L 04/20/15 10:01 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 04/20/15 10:01 109-99-95.0 2.0 1Toluene <0.50 ug/L 04/20/15 10:01 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 04/20/15 10:01 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 04/20/15 10:01 120-82-15.0 2.2 11,1,1-Trichloroethane 14.6 ug/L 04/20/15 10:01 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 04/20/15 10:01 79-00-51.0 0.20 1Trichloroethene 5.0 ug/L 04/20/15 10:01 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 04/20/15 10:01 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 04/20/15 10:01 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 04/20/15 10:01 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 04/20/15 10:01 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 04/20/15 10:01 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 04/20/15 10:01 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 04/20/15 10:01 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 04/20/15 10:01 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 99 % 04/20/15 10:01 460-00-470-130 1Dibromofluoromethane (S) 101 % 04/20/15 10:01 1868-53-770-130 1Toluene-d8 (S) 100 % 04/20/15 10:01 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 03:23 PM
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Page 8 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40113336023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
MSV/28105EPA 8260
EPA 82608260 MSV
Associated Lab Samples: 40113336001, 40113336002
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1143627Associated Lab Samples: 40113336001, 40113336002
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 04/20/15 07:221,1,1-Trichloroethane ug/L <0.50 1.0 04/20/15 07:221,1,2,2-Tetrachloroethane ug/L <0.25 1.0 04/20/15 07:221,1,2-Trichloroethane ug/L <0.20 1.0 04/20/15 07:221,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 04/20/15 07:221,1-Dichloroethane ug/L <0.24 1.0 04/20/15 07:221,1-Dichloroethene ug/L <0.41 1.0 04/20/15 07:221,1-Dichloropropene ug/L <0.44 1.0 04/20/15 07:221,2,3-Trichlorobenzene ug/L <2.1 5.0 04/20/15 07:221,2,3-Trichloropropane ug/L <0.50 1.0 04/20/15 07:221,2,4-Trichlorobenzene ug/L <2.2 5.0 04/20/15 07:221,2,4-Trimethylbenzene ug/L <0.50 1.0 04/20/15 07:221,2-Dibromo-3-chloropropane ug/L <2.2 5.0 04/20/15 07:221,2-Dibromoethane (EDB) ug/L <0.18 1.0 04/20/15 07:221,2-Dichlorobenzene ug/L <0.50 1.0 04/20/15 07:221,2-Dichloroethane ug/L <0.17 1.0 04/20/15 07:221,2-Dichloropropane ug/L <0.23 1.0 04/20/15 07:221,3,5-Trimethylbenzene ug/L <0.50 1.0 04/20/15 07:221,3-Dichlorobenzene ug/L <0.50 1.0 04/20/15 07:221,3-Dichloropropane ug/L <0.50 1.0 04/20/15 07:221,4-Dichlorobenzene ug/L <0.50 1.0 04/20/15 07:222,2-Dichloropropane ug/L <0.48 1.0 04/20/15 07:222-Butanone (MEK) ug/L <3.0 20.0 04/20/15 07:222-Chlorotoluene ug/L <0.50 1.0 04/20/15 07:224-Chlorotoluene ug/L <0.21 1.0 04/20/15 07:224-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 04/20/15 07:22Acetone ug/L <3.0 20.0 04/20/15 07:22Allyl chloride ug/L <2.2 5.0 04/20/15 07:22Benzene ug/L <0.50 1.0 04/20/15 07:22Bromobenzene ug/L <0.23 1.0 04/20/15 07:22Bromochloromethane ug/L <0.34 1.0 04/20/15 07:22Bromodichloromethane ug/L <0.50 1.0 04/20/15 07:22Bromoform ug/L <0.50 1.0 04/20/15 07:22Bromomethane ug/L <2.4 5.0 04/20/15 07:22Carbon tetrachloride ug/L <0.50 1.0 04/20/15 07:22Chlorobenzene ug/L <0.50 1.0 04/20/15 07:22Chloroethane ug/L <0.37 1.0 04/20/15 07:22Chloroform ug/L <2.5 5.0 04/20/15 07:22Chloromethane ug/L <0.50 1.0 04/20/15 07:22cis-1,2-Dichloroethene ug/L <0.26 1.0 04/20/15 07:22cis-1,3-Dichloropropene ug/L <0.50 1.0 04/20/15 07:22
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 03:23 PM
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Page 9 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40113336023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1143627Associated Lab Samples: 40113336001, 40113336002
Matrix: Water
Analyzed
Dibromochloromethane ug/L <0.50 1.0 04/20/15 07:22Dibromomethane ug/L <0.43 1.0 04/20/15 07:22Dichlorodifluoromethane ug/L <0.22 1.0 04/20/15 07:22Dichlorofluoromethane ug/L <0.21 1.0 04/20/15 07:22Diethyl ether (Ethyl ether) ug/L <2.2 5.0 04/20/15 07:22Ethylbenzene ug/L <0.50 1.0 04/20/15 07:22Hexachloro-1,3-butadiene ug/L <2.1 5.0 04/20/15 07:22Isopropylbenzene (Cumene) ug/L <0.14 1.0 04/20/15 07:22m&p-Xylene ug/L <1.0 2.0 04/20/15 07:22Methyl-tert-butyl ether ug/L <0.17 1.0 04/20/15 07:22Methylene Chloride ug/L <0.23 1.0 04/20/15 07:22n-Butylbenzene ug/L <0.50 1.0 04/20/15 07:22n-Propylbenzene ug/L <0.50 1.0 04/20/15 07:22Naphthalene ug/L <2.5 5.0 04/20/15 07:22o-Xylene ug/L <0.50 1.0 04/20/15 07:22p-Isopropyltoluene ug/L <0.50 1.0 04/20/15 07:22sec-Butylbenzene ug/L <2.2 5.0 04/20/15 07:22Styrene ug/L <0.50 1.0 04/20/15 07:22tert-Butylbenzene ug/L <0.18 1.0 04/20/15 07:22Tetrachloroethene ug/L <0.50 1.0 04/20/15 07:22Tetrahydrofuran ug/L <2.0 5.0 04/20/15 07:22Toluene ug/L <0.50 1.0 04/20/15 07:22trans-1,2-Dichloroethene ug/L <0.26 1.0 04/20/15 07:22trans-1,3-Dichloropropene ug/L <0.23 1.0 04/20/15 07:22Trichloroethene ug/L <0.33 1.0 04/20/15 07:22Trichlorofluoromethane ug/L <0.18 1.0 04/20/15 07:22Vinyl chloride ug/L <0.18 1.0 04/20/15 07:224-Bromofluorobenzene (S) % 97 70-130 04/20/15 07:22Dibromofluoromethane (S) % 98 70-130 04/20/15 07:22Toluene-d8 (S) % 100 70-130 04/20/15 07:22
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1143628LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1143629
1,1,1-Trichloroethane ug/L 55.550 111 70-13011255.9 1 201,1,2,2-Tetrachloroethane ug/L 50.350 101 70-13010251.0 1 201,1,2-Trichloroethane ug/L 52.950 106 70-13010753.4 1 201,1,2-Trichlorotrifluoroethane ug/L 60.450 121 50-15011959.4 2 201,1-Dichloroethane ug/L 54.350 109 70-13011055.1 1 201,1-Dichloroethene ug/L 57.750 115 70-13011758.6 1 201,2,4-Trichlorobenzene ug/L 48.450 97 70-1309748.7 0 201,2-Dibromo-3-chloropropane ug/L 50.350 101 50-15010351.7 3 201,2-Dibromoethane (EDB) ug/L 53.550 107 70-13010653.2 1 201,2-Dichlorobenzene ug/L 49.650 99 70-1309949.4 0 20
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 03:23 PM
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Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40113336023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1143628LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1143629
1,2-Dichloroethane ug/L 52.650 105 70-13110653.1 1 201,2-Dichloropropane ug/L 54.550 109 70-13010753.4 2 201,3-Dichlorobenzene ug/L 50.550 101 70-13010251.0 1 201,4-Dichlorobenzene ug/L 48.950 98 70-1309949.5 1 20Benzene ug/L 53.950 108 70-13010954.4 1 20Bromodichloromethane ug/L 52.750 105 70-13010653.0 1 20Bromoform ug/L 51.250 102 68-13010552.7 3 20Bromomethane ug/L 33.9 R150 68 38-1378441.9 21 20Carbon tetrachloride ug/L 55.150 110 70-13011255.8 1 20Chlorobenzene ug/L 51.350 103 70-13010451.8 1 20Chloroethane ug/L 55.050 110 70-13611155.3 1 20Chloroform ug/L 53.450 107 70-13010653.2 0 20Chloromethane ug/L 52.550 105 48-14410854.0 3 20cis-1,2-Dichloroethene ug/L 54.550 109 70-13011054.8 1 20cis-1,3-Dichloropropene ug/L 53.350 107 70-13010652.9 1 20Dibromochloromethane ug/L 51.550 103 70-13010351.7 1 20Dichlorodifluoromethane ug/L 58.350 117 33-15711658.0 1 20Ethylbenzene ug/L 53.150 106 70-13210753.7 1 20Isopropylbenzene (Cumene) ug/L 53.450 107 70-13010853.9 1 20m&p-Xylene ug/L 108100 108 70-131108108 1 20Methyl-tert-butyl ether ug/L 55.150 110 48-14111155.4 1 20Methylene Chloride ug/L 50.750 101 70-13010351.4 1 20o-Xylene ug/L 54.150 108 70-13110653.2 2 20Styrene ug/L 53.350 107 70-13010753.7 1 20Tetrachloroethene ug/L 53.150 106 70-13010451.8 3 20Toluene ug/L 53.650 107 70-13010753.5 0 20trans-1,2-Dichloroethene ug/L 56.950 114 70-13011457.1 0 20trans-1,3-Dichloropropene ug/L 51.050 102 70-13010451.8 1 20Trichloroethene ug/L 54.250 108 70-13010753.7 1 20Trichlorofluoromethane ug/L 57.450 115 50-15011557.3 0 20Vinyl chloride ug/L 57.950 116 65-14211859.2 2 204-Bromofluorobenzene (S) % 103 70-130102Dibromofluoromethane (S) % 101 70-130101Toluene-d8 (S) % 98 70-13097
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1143661MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40113336002
1143662
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 50 115 70-130113 1 205014.6 71.9 70.91,1,2,2-Tetrachloroethane ug/L 50 104 70-13099 4 2050<0.25 51.8 49.61,1,2-Trichloroethane ug/L 50 109 70-130105 4 2050<0.20 54.3 52.41,1,2-Trichlorotrifluoroethane ug/L 50 121 50-151120 1 2050<0.81 60.7 59.81,1-Dichloroethane ug/L 50 111 70-134111 0 205012.5 68.0 67.81,1-Dichloroethene ug/L 50 120 70-139116 3 20505.4 65.3 63.5
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 03:23 PM
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Page 11 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40113336023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1143661MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40113336002
1143662
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,2,4-Trichlorobenzene ug/L 50 100 70-13099 2 2050<2.2 50.5 49.81,2-Dibromo-3-chloropropane
ug/L 50 102 50-150104 1 2050<2.2 51.1 51.9
1,2-Dibromoethane (EDB) ug/L 50 108 70-130107 2 2050<0.18 54.1 53.31,2-Dichlorobenzene ug/L 50 100 70-130101 0 2050<0.50 50.2 50.31,2-Dichloroethane ug/L 50 109 70-132108 0 2050<0.17 54.3 54.21,2-Dichloropropane ug/L 50 111 70-130110 1 2050<0.23 55.7 55.11,3-Dichlorobenzene ug/L 50 103 70-13099 3 2050<0.50 51.3 49.71,4-Dichlorobenzene ug/L 50 99 70-13098 1 2050<0.50 49.6 49.2Benzene ug/L 50 111 70-130110 1 2050<0.50 55.7 54.9Bromodichloromethane ug/L 50 109 70-132107 2 2050<0.50 54.6 53.4Bromoform ug/L 50 107 68-130104 3 2050<0.50 53.7 52.2Bromomethane ug/L 50 87 38-14189 2 2050<2.4 43.7 44.6Carbon tetrachloride ug/L 50 114 70-130112 2 2050<0.50 57.1 56.1Chlorobenzene ug/L 50 107 70-130104 3 2050<0.50 53.4 51.8Chloroethane ug/L 50 113 66-152111 1 2050<0.37 56.3 55.6Chloroform ug/L 50 108 70-130106 2 2050<2.5 54.4 53.3Chloromethane ug/L 50 111 44-151109 2 2050<0.50 55.5 54.6cis-1,2-Dichloroethene ug/L 50 113 70-130110 2 20509.4 65.8 64.5cis-1,3-Dichloropropene ug/L 50 109 70-130107 1 2050<0.50 54.3 53.5Dibromochloromethane ug/L 50 107 70-130103 3 2050<0.50 53.5 51.7Dichlorodifluoromethane ug/L 50 114 29-160111 3 2050<0.22 56.9 55.3Ethylbenzene ug/L 50 112 70-132107 5 2050<0.50 56.2 53.4Isopropylbenzene (Cumene) ug/L 50 111 70-130108 3 2050<0.14 55.7 53.8m&p-Xylene ug/L 100 112 70-131108 4 20100<1.0 112 108Methyl-tert-butyl ether ug/L 50 112 48-143112 0 2050<0.17 56.0 55.8Methylene Chloride ug/L 50 105 70-130102 2 2050<0.23 52.5 51.2o-Xylene ug/L 50 110 70-131107 3 2050<0.50 54.9 53.3Styrene ug/L 50 112 70-130108 4 2050<0.50 56.0 53.9Tetrachloroethene ug/L 50 108 70-13098 5 205048.2 102 97.2Toluene ug/L 50 111 70-130106 4 2050<0.50 55.3 53.1trans-1,2-Dichloroethene ug/L 50 116 70-132114 1 2050<0.26 57.8 57.2trans-1,3-Dichloropropene ug/L 50 106 70-130103 3 2050<0.23 53.1 51.6Trichloroethene ug/L 50 113 70-130110 2 20505.0 61.5 60.1Trichlorofluoromethane ug/L 50 116 50-153113 3 2050<0.18 58.1 56.7Vinyl chloride ug/L 50 121 60-155118 2 2050<0.18 60.4 58.94-Bromofluorobenzene (S) % 104 70-130101Dibromofluoromethane (S) % 100 70-130101Toluene-d8 (S) % 100 70-13098
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 03:23 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 12 of 16
#=QL#
QUALIFIERS
Pace Project No.:Project:
40113336023-6105-015 CP-SHOREHAM YARD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Green BayPASI-G
ANALYTE QUALIFIERS
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 03:23 PM
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Page 13 of 16
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:Project:
40113336023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch
40113336001 MSV/28105041515-0800-200 EPA 826040113336002 MSV/28105SE EFFLUENT EPA 8260
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 03:23 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 14 of 16
Pag
e 15
of 1
6(Please Print Clearly)
Company Name:
Branch/Location: Mt.Lciuve.\, NT Project Contact:
Phone: CHAIN OF CUSTODY Project Number:
Project Name:
Project State: MAI
I *Preservation Codas
A=None B=HCL C=H2S04 D=HN03 E=DI Water
H=Sodium Bisulfate Solution !=Sodium Thiosulfate
FILTERED? (YES/NO)
Sampled By (Print): A-I q i"l Ph ; I/ ij) 5 (A p) PRESERVATION (CODE)*
Sampled By (Sign): ~ ~ (frtJJ PO#: L-1 LO'l...._
Data Package Options (blllable)
D EPA Level Ill
1. ,:
Regulatory , ', Program: , . ,
Matrix Codes ·• .. ·· ~~/ A=Alr W=Water : •. B =Biota OW= Drinking Water .; . , .. C = Charcoal GW = Ground Water i· ".,'
F=Methanol
J=Other
G=NaOH
JS~ ''"1
7 )L/011333 \_{:)
Quote#:
Mail To Contact:
Mail To Company:
Mail To Address:
Invoice To Contact:
Invoice To Company:
Invoice To Address:
Invoice To Phone: D EPA Level IV
MS/MSD D On your sample
(billable) D NOT needed on
your sample O = Oil SW = Surface Water ~i' S=Soil WW=WasteWater ·"d ,; LAB COMMENTS Sl=Sludoe WP=Wioe '' (i CLIENT Profile#
COL~ MATRIX ' ~ • ' COMMENTS ~P_A_c_E_LA_B~#l--~-C~l_IE_N_T~F_IE_L_D~•-D~~+-~DA~~.;:._~1--~-;-~1·_ .. .._...,_·-=--t-~--t-~-r~-r~-i-~--t---t~--1~~~~~~~+--(_L_a_b_U~se __ o_n_l_y~)__..__ __ ~--11 <9lftSls-<9~~-UJ<9 'fftfjrs <9ico V ... ·. )<'.L 2-'-IOYn/& 001
(j(yz_
11--~~~-+~~~~~~~~~~~~~+-~~-+-~~-1-~~-+~~·-,;'-~-t----t~~-t---i-~~-t-~--t--~+-~-+--~~~~~--+--~-~-~~-~~~~~----11
RushTurnaroundTimeRequested-Prelims !Relin~rB~ Niii <t Aiiioa:;r;,i';!nc ~ir-.u-'IY~~:tt.• t..lunt"t'Ac3E3PgJ~~No. (Rush TAT subject to approval/surcharge) ~, 1 rV\ fl J 111.1 ~ '!WI Ill .J 7 J UV 7U 't:";
....... ___ o_at_e_Ne_e_de_d_: -----....fi"eli~qujs~ed~L- I J i . 7 Dalt~/Time oa1 i e y:,1 \ / L1a1mme • { t.Jlril1"'S ~J u_~T~ra~n~s~m~lt~P~re~lim!!..!::R~us~h~R~e~s~ul~~~b~y~(co~m~pl~et~e~wh~at~y~o~u~w~an~t)~:--i~V.lL\~J~/l~A~,·Aol!...!(~·!.L()~~__:'-/:::z._·-~JLJ~~/~.~.2..~~.::::::.~()~'-{_!,.~~..L-J..L..:.::..L::'~A·J'.,::;a'~'~6 ~\/r~~,,/',tJ;:'..L<~/~''Jii.vtj~~:::..::~-l../~-1..!...7~1..!.:.S-.l..J··6L~~:r,,1'~~R T ·Y.,-:j - 0 r ecelpt amp= f( · v S C 1-E......,.m;a..,il..,#_1_: -~---------------!!Relinquished By: Date/Time: Received By: Date/Time: \
Emall #2: Sample Receipt pH
Telephone: Relinquished By: Date/Time: Received By: Date/Time: OK I Adjusted ~~-a-x:~-~-t-~~--~~-~~---~~~
Samples on HOLD are subject to
special pricing and release of llablllty
C019a(27 Jun2006)
Relinquished By: Date/Time: Received By: Date/Time:
Ve
Co"'' .. Custodv Seal
(IS"re~/ Not Present ?Tntact ft.lot Intact
Page 16 of 16
$ceAnalytical" :Client Name: Ge) [o{w
Sample Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9
Green Bay, WI 54302
Project#:
Courier: Fed Ex r UPS : Client r Pace )ther: l ;.... '.:JC&. ),:kC./:J Tracking#: "] lo:J(pgD Custody Seal on Cooler/Box Present: yr yes - no Seals intact: J?' yes r no
Custody Seal on Samples Present: r yes p:i no Seals intact: r yes : no
W0#:40113336 111111 11 ff I 11111111111 40113336
Packing Material: f Bubble Wrap pl Bubble Bags r None r Other
Thermometer Used 'R..- T~ of Ice~ Blue Dry None J7 Samples on ice, cooling process has begun
Cooler Temperature \ ~ /Corr: , ':::> Biological Tissue is Frozen: r yes
Temp Blank Present: yes Jf no rno Person r(m!ning contents:
Temp should be above freezing to 6°C for all sample except Biota. Date: -~-£S Frozen Biota Samples should be received ~ 0°C. Comments: Initials: = ii'
Chain of Custody Present: ¢Yes ONo ON/A 1.
Chain of Custody Filled Out: ~~es 0No ON/A 2.
Chain of Custody Relinquished: iv es ONo ON/A 3.
Sampler Name & Signature on COC: l:fYes ONo ON/A 4.
Samples Arrived within Hold Time: ¢'Yes ONo ON/A 5.
- VOA Samples frozen upon receipt 0Yes ONo Datemme:
Short Hold Time Analysis (<72hr): 0Yes ~o ON/A 6.
Rush Turn Around Time Requested: OYes ~o ON/A 7.
Sufficient Volume: JZ{Yes ONo ON/A 8.
Correct Containers Used: ~Yes ONo ON/A 9.
-Pace Containers Used: r;/Yes ONo ON/A
-Pace IR Containers Used: OYes ONo JdNIA Containers Intact: )'.iYes ONo ON/A 10.
Filtered volume received for Dissolved tests OYes 0No ~/A 11.
Sample Labels match COC: pYes DNo ON/A 12.
-Includes date/time/ID/Analysis Matrix: \._.]-) All containers needing preservation have been checked. ~
rHN03 r H2S04 r NaOH r NaOH +ZnAct (Non-Compliance noted in 13.) OYes ONo /A 13. ---- -- ------ --- -- -- -- -- - --- --- -- - - --All containers needing preservation are found to be in · compliance with EPA recommendation. OYes ONo c:;J'1A (~t-J03,_ ~2; ~~OH-t:~nAct_ ~_9~!!C?H 2!:l 2) ______________ exceptions V , coliform, TOC, TOX, TOH, ft Initial when llab Std #ID of luate/ O&G, WIDROW, Phenolics, OTHER: Yes 0No completed preservative Time:
Headspace in VOA Vials ( >6mm): OYes ~o ON/A 14 .
Trip Blank Present: ..i;z{ves ONo ON/A 15.
Trip Blank Custody Seals Present fes DNo ON/A
Pace Trip Blank Lot# (if purchased): Client Notification/ Resolution: If checked, see attached form for additional comments D
Person Contacted: Date/Time: ~~~~~~~~~~~~~-
Comments/ Resolution: ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~--
Project Manager Review: Date:
F-GB-C-031-Rev.03 (9April2015) SCURForm
#=CL#
May 19, 2015
LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40114839
40114839Project:Pace Project No.:
RE:
Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102
023-6105-015 CP-SHOREHAM YARD
Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on May 15, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Laurie [email protected] Manager
Enclosures
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:Project:
40114839023-6105-015 CP-SHOREHAM YARD
Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334
North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Wisconsin Certification #: 405132750
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:Project:
40114839023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID Matrix Date Collected Date Received
40114839001 051415-0800-200 Water 05/14/15 08:00 05/15/15 08:55
40114839002 SE EFFLUENT Water 05/14/15 13:25 05/15/15 08:55
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Green Bay, WI 54302(920)469-2436
Page 3 of 16
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:Project:
40114839023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts
40114839001 051415-0800-200 EPA 8260 71 PASI-GHNW
40114839002 SE EFFLUENT EPA 8260 71 PASI-GHNW
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 4 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40114839023-6105-015 CP-SHOREHAM YARD
Sample: 051415-0800-200 Lab ID: 40114839001 Collected: 05/14/15 08:00 Received: 05/15/15 08:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 05/16/15 17:34 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 05/16/15 17:34 107-05-15.0 2.2 1Benzene <0.50 ug/L 05/16/15 17:34 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 05/16/15 17:34 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 05/16/15 17:34 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 05/16/15 17:34 75-27-41.0 0.50 1Bromoform <0.50 ug/L 05/16/15 17:34 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 05/16/15 17:34 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 05/16/15 17:34 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 05/16/15 17:34 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 05/16/15 17:34 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 05/16/15 17:34 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 05/16/15 17:34 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 05/16/15 17:34 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 05/16/15 17:34 75-00-31.0 0.37 1Chloroform <2.5 ug/L 05/16/15 17:34 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 05/16/15 17:34 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 05/16/15 17:34 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 05/16/15 17:34 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 05/16/15 17:34 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 05/16/15 17:34 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 05/16/15 17:34 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 05/16/15 17:34 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 05/16/15 17:34 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 05/16/15 17:34 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 05/16/15 17:34 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 05/16/15 17:34 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 05/16/15 17:34 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 05/16/15 17:34 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 05/16/15 17:34 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 05/16/15 17:34 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 05/16/15 17:34 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 05/16/15 17:34 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 05/16/15 17:34 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 05/16/15 17:34 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 05/16/15 17:34 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 05/16/15 17:34 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 05/16/15 17:34 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 05/16/15 17:34 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 05/16/15 17:34 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 05/16/15 17:34 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 05/16/15 17:34 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 05/16/15 17:34 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 05/16/15 17:34 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 05/16/15 17:34 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 05/16/15 17:34 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/19/2015 03:56 PM
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Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40114839023-6105-015 CP-SHOREHAM YARD
Sample: 051415-0800-200 Lab ID: 40114839001 Collected: 05/14/15 08:00 Received: 05/15/15 08:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 05/16/15 17:34 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 05/16/15 17:34 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 05/16/15 17:34 103-65-11.0 0.50 1Styrene <0.50 ug/L 05/16/15 17:34 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 05/16/15 17:34 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 05/16/15 17:34 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 05/16/15 17:34 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 05/16/15 17:34 109-99-95.0 2.0 1Toluene <0.50 ug/L 05/16/15 17:34 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 05/16/15 17:34 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 05/16/15 17:34 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 05/16/15 17:34 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 05/16/15 17:34 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 05/16/15 17:34 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 05/16/15 17:34 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 05/16/15 17:34 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 05/16/15 17:34 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 05/16/15 17:34 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 05/16/15 17:34 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 05/16/15 17:34 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 05/16/15 17:34 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 05/16/15 17:34 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 92 % 05/16/15 17:34 460-00-4 HS70-130 1Dibromofluoromethane (S) 100 % 05/16/15 17:34 1868-53-770-130 1Toluene-d8 (S) 96 % 05/16/15 17:34 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/19/2015 03:56 PM
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Page 6 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40114839023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40114839002 Collected: 05/14/15 13:25 Received: 05/15/15 08:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 05/16/15 17:56 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 05/16/15 17:56 107-05-15.0 2.2 1Benzene <0.50 ug/L 05/16/15 17:56 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 05/16/15 17:56 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 05/16/15 17:56 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 05/16/15 17:56 75-27-41.0 0.50 1Bromoform <0.50 ug/L 05/16/15 17:56 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 05/16/15 17:56 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 05/16/15 17:56 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 05/16/15 17:56 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 05/16/15 17:56 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 05/16/15 17:56 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 05/16/15 17:56 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 05/16/15 17:56 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 05/16/15 17:56 75-00-31.0 0.37 1Chloroform <2.5 ug/L 05/16/15 17:56 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 05/16/15 17:56 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 05/16/15 17:56 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 05/16/15 17:56 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 05/16/15 17:56 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 05/16/15 17:56 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 05/16/15 17:56 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 05/16/15 17:56 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 05/16/15 17:56 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 05/16/15 17:56 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 05/16/15 17:56 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 05/16/15 17:56 75-71-81.0 0.22 11,1-Dichloroethane 12.0 ug/L 05/16/15 17:56 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 05/16/15 17:56 107-06-21.0 0.17 11,1-Dichloroethene 4.7 ug/L 05/16/15 17:56 75-35-41.0 0.41 1cis-1,2-Dichloroethene 9.0 ug/L 05/16/15 17:56 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 05/16/15 17:56 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 05/16/15 17:56 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 05/16/15 17:56 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 05/16/15 17:56 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 05/16/15 17:56 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 05/16/15 17:56 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 05/16/15 17:56 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 05/16/15 17:56 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 05/16/15 17:56 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 05/16/15 17:56 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 05/16/15 17:56 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 05/16/15 17:56 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 05/16/15 17:56 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 05/16/15 17:56 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 05/16/15 17:56 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 7 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40114839023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40114839002 Collected: 05/14/15 13:25 Received: 05/15/15 08:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 05/16/15 17:56 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 05/16/15 17:56 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 05/16/15 17:56 103-65-11.0 0.50 1Styrene <0.50 ug/L 05/16/15 17:56 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 05/16/15 17:56 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 05/16/15 17:56 79-34-51.0 0.25 1Tetrachloroethene 47.0 ug/L 05/16/15 17:56 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 05/16/15 17:56 109-99-95.0 2.0 1Toluene <0.50 ug/L 05/16/15 17:56 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 05/16/15 17:56 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 05/16/15 17:56 120-82-15.0 2.2 11,1,1-Trichloroethane 13.9 ug/L 05/16/15 17:56 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 05/16/15 17:56 79-00-51.0 0.20 1Trichloroethene 5.0 ug/L 05/16/15 17:56 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 05/16/15 17:56 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 05/16/15 17:56 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 05/16/15 17:56 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 05/16/15 17:56 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 05/16/15 17:56 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 05/16/15 17:56 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 05/16/15 17:56 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 05/16/15 17:56 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 92 % 05/16/15 17:56 460-00-470-130 1Dibromofluoromethane (S) 101 % 05/16/15 17:56 1868-53-770-130 1Toluene-d8 (S) 96 % 05/16/15 17:56 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 8 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40114839023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
MSV/28483EPA 8260
EPA 82608260 MSV
Associated Lab Samples: 40114839001, 40114839002
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1159272Associated Lab Samples: 40114839001, 40114839002
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 05/16/15 14:121,1,1-Trichloroethane ug/L <0.50 1.0 05/16/15 14:121,1,2,2-Tetrachloroethane ug/L <0.25 1.0 05/16/15 14:121,1,2-Trichloroethane ug/L <0.20 1.0 05/16/15 14:121,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 05/16/15 14:121,1-Dichloroethane ug/L <0.24 1.0 05/16/15 14:121,1-Dichloroethene ug/L <0.41 1.0 05/16/15 14:121,1-Dichloropropene ug/L <0.44 1.0 05/16/15 14:121,2,3-Trichlorobenzene ug/L <2.1 5.0 05/16/15 14:121,2,3-Trichloropropane ug/L <0.50 1.0 05/16/15 14:121,2,4-Trichlorobenzene ug/L <2.2 5.0 05/16/15 14:121,2,4-Trimethylbenzene ug/L <0.50 1.0 05/16/15 14:121,2-Dibromo-3-chloropropane ug/L <2.2 5.0 05/16/15 14:121,2-Dibromoethane (EDB) ug/L <0.18 1.0 05/16/15 14:121,2-Dichlorobenzene ug/L <0.50 1.0 05/16/15 14:121,2-Dichloroethane ug/L <0.17 1.0 05/16/15 14:121,2-Dichloropropane ug/L <0.23 1.0 05/16/15 14:121,3,5-Trimethylbenzene ug/L <0.50 1.0 05/16/15 14:121,3-Dichlorobenzene ug/L <0.50 1.0 05/16/15 14:121,3-Dichloropropane ug/L <0.50 1.0 05/16/15 14:121,4-Dichlorobenzene ug/L <0.50 1.0 05/16/15 14:122,2-Dichloropropane ug/L <0.48 1.0 05/16/15 14:122-Butanone (MEK) ug/L <3.0 20.0 05/16/15 14:122-Chlorotoluene ug/L <0.50 1.0 05/16/15 14:124-Chlorotoluene ug/L <0.21 1.0 05/16/15 14:124-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 05/16/15 14:12Acetone ug/L <3.0 20.0 05/16/15 14:12Allyl chloride ug/L <2.2 5.0 05/16/15 14:12Benzene ug/L <0.50 1.0 05/16/15 14:12Bromobenzene ug/L <0.23 1.0 05/16/15 14:12Bromochloromethane ug/L <0.34 1.0 05/16/15 14:12Bromodichloromethane ug/L <0.50 1.0 05/16/15 14:12Bromoform ug/L <0.50 1.0 05/16/15 14:12Bromomethane ug/L <2.4 5.0 05/16/15 14:12Carbon tetrachloride ug/L <0.50 1.0 05/16/15 14:12Chlorobenzene ug/L <0.50 1.0 05/16/15 14:12Chloroethane ug/L <0.37 1.0 05/16/15 14:12Chloroform ug/L <2.5 5.0 05/16/15 14:12Chloromethane ug/L <0.50 1.0 05/16/15 14:12cis-1,2-Dichloroethene ug/L <0.26 1.0 05/16/15 14:12cis-1,3-Dichloropropene ug/L <0.50 1.0 05/16/15 14:12
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/19/2015 03:56 PM
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Page 9 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40114839023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1159272Associated Lab Samples: 40114839001, 40114839002
Matrix: Water
Analyzed
Dibromochloromethane ug/L <0.50 1.0 05/16/15 14:12Dibromomethane ug/L <0.43 1.0 05/16/15 14:12Dichlorodifluoromethane ug/L <0.22 1.0 05/16/15 14:12Dichlorofluoromethane ug/L <0.21 1.0 05/16/15 14:12Diethyl ether (Ethyl ether) ug/L <2.2 5.0 05/16/15 14:12Ethylbenzene ug/L <0.50 1.0 05/16/15 14:12Hexachloro-1,3-butadiene ug/L <2.1 5.0 05/16/15 14:12Isopropylbenzene (Cumene) ug/L <0.14 1.0 05/16/15 14:12m&p-Xylene ug/L <1.0 2.0 05/16/15 14:12Methyl-tert-butyl ether ug/L <0.17 1.0 05/16/15 14:12Methylene Chloride ug/L <0.23 1.0 05/16/15 14:12n-Butylbenzene ug/L <0.50 1.0 05/16/15 14:12n-Propylbenzene ug/L <0.50 1.0 05/16/15 14:12Naphthalene ug/L <2.5 5.0 05/16/15 14:12o-Xylene ug/L <0.50 1.0 05/16/15 14:12p-Isopropyltoluene ug/L <0.50 1.0 05/16/15 14:12sec-Butylbenzene ug/L <2.2 5.0 05/16/15 14:12Styrene ug/L <0.50 1.0 05/16/15 14:12tert-Butylbenzene ug/L <0.18 1.0 05/16/15 14:12Tetrachloroethene ug/L <0.50 1.0 05/16/15 14:12Tetrahydrofuran ug/L <2.0 5.0 05/16/15 14:12Toluene ug/L <0.50 1.0 05/16/15 14:12trans-1,2-Dichloroethene ug/L <0.26 1.0 05/16/15 14:12trans-1,3-Dichloropropene ug/L <0.23 1.0 05/16/15 14:12Trichloroethene ug/L <0.33 1.0 05/16/15 14:12Trichlorofluoromethane ug/L <0.18 1.0 05/16/15 14:12Vinyl chloride ug/L <0.18 1.0 05/16/15 14:124-Bromofluorobenzene (S) % 92 70-130 05/16/15 14:12Dibromofluoromethane (S) % 101 70-130 05/16/15 14:12Toluene-d8 (S) % 97 70-130 05/16/15 14:12
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1159273LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1159274
1,1,1-Trichloroethane ug/L 56.650 113 70-13011055.1 3 201,1,2,2-Tetrachloroethane ug/L 47.950 96 70-1309346.5 3 201,1,2-Trichloroethane ug/L 55.950 112 70-13011155.6 1 201,1,2-Trichlorotrifluoroethane ug/L 53.350 107 50-15010351.5 4 201,1-Dichloroethane ug/L 48.850 98 70-1309547.5 3 201,1-Dichloroethene ug/L 45.650 91 70-1309145.6 0 201,2,4-Trichlorobenzene ug/L 50.550 101 70-13010050.2 1 201,2-Dibromo-3-chloropropane ug/L 44.250 88 50-1508944.5 1 201,2-Dibromoethane (EDB) ug/L 54.450 109 70-13010854.0 1 201,2-Dichlorobenzene ug/L 50.650 101 70-1309849.2 3 20
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40114839023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1159273LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1159274
1,2-Dichloroethane ug/L 54.750 109 70-13110753.7 2 201,2-Dichloropropane ug/L 52.450 105 70-13010351.7 1 201,3-Dichlorobenzene ug/L 48.850 98 70-1309648.0 2 201,4-Dichlorobenzene ug/L 51.050 102 70-1309949.5 3 20Benzene ug/L 50.050 100 70-13010049.8 1 20Bromodichloromethane ug/L 58.550 117 70-13011657.8 1 20Bromoform ug/L 52.050 104 68-13010250.8 2 20Bromomethane ug/L 45.450 91 38-13710150.3 10 20Carbon tetrachloride ug/L 58.050 116 70-13011356.5 3 20Chlorobenzene ug/L 55.950 112 70-13011255.9 0 20Chloroethane ug/L 42.850 86 70-1368542.4 1 20Chloroform ug/L 53.750 107 70-13010753.3 1 20Chloromethane ug/L 42.950 86 48-1448341.4 4 20cis-1,2-Dichloroethene ug/L 45.750 91 70-1309145.7 0 20cis-1,3-Dichloropropene ug/L 48.350 97 70-1309547.6 1 20Dibromochloromethane ug/L 52.250 104 70-13010351.4 2 20Dichlorodifluoromethane ug/L 37.650 75 33-1577235.9 5 20Ethylbenzene ug/L 57.050 114 70-13211356.4 1 20Isopropylbenzene (Cumene) ug/L 62.050 124 70-13012361.3 1 20m&p-Xylene ug/L 121100 121 70-131120120 1 20Methyl-tert-butyl ether ug/L 43.850 88 48-1418844.1 1 20Methylene Chloride ug/L 46.050 92 70-1309346.6 1 20o-Xylene ug/L 58.250 116 70-13111858.8 1 20Styrene ug/L 55.650 111 70-13010954.7 2 20Tetrachloroethene ug/L 58.150 116 70-13011557.4 1 20Toluene ug/L 56.350 113 70-13011255.9 1 20trans-1,2-Dichloroethene ug/L 47.850 96 70-1309748.5 2 20trans-1,3-Dichloropropene ug/L 48.750 97 70-1309748.5 1 20Trichloroethene ug/L 54.850 110 70-13010954.7 0 20Trichlorofluoromethane ug/L 51.050 102 50-1509849.0 4 20Vinyl chloride ug/L 47.850 96 65-1429446.9 2 204-Bromofluorobenzene (S) % 107 70-130107Dibromofluoromethane (S) % 98 70-13099Toluene-d8 (S) % 99 70-130100
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1159275MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40114839002
1159276
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 50 116 70-130116 0 205013.9 71.7 71.81,1,2,2-Tetrachloroethane ug/L 50 94 70-13096 2 2050<0.25 47.1 48.21,1,2-Trichloroethane ug/L 50 110 70-130110 0 2050<0.20 55.2 55.21,1,2-Trichlorotrifluoroethane ug/L 50 110 50-151107 2 2050<0.81 54.8 53.51,1-Dichloroethane ug/L 50 98 70-13499 1 205012.0 61.1 61.71,1-Dichloroethene ug/L 50 95 70-13993 2 20504.7 52.3 51.4
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 11 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40114839023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1159275MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40114839002
1159276
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,2,4-Trichlorobenzene ug/L 50 102 70-130102 0 2050<2.2 50.9 51.01,2-Dibromo-3-chloropropane
ug/L 50 91 50-15093 3 2050<2.2 45.4 46.7
1,2-Dibromoethane (EDB) ug/L 50 109 70-130109 0 2050<0.18 54.7 54.71,2-Dichlorobenzene ug/L 50 100 70-130101 1 2050<0.50 49.8 50.51,2-Dichloroethane ug/L 50 109 70-132110 2 2050<0.17 54.4 55.21,2-Dichloropropane ug/L 50 104 70-130106 1 2050<0.23 52.2 52.81,3-Dichlorobenzene ug/L 50 97 70-13097 1 2050<0.50 48.7 48.41,4-Dichlorobenzene ug/L 50 101 70-13099 1 2050<0.50 50.3 49.7Benzene ug/L 50 101 70-130102 0 2050<0.50 50.7 50.9Bromodichloromethane ug/L 50 116 70-132115 1 2050<0.50 58.1 57.7Bromoform ug/L 50 101 68-130102 1 2050<0.50 50.4 51.1Bromomethane ug/L 50 108 38-141107 1 2050<2.4 53.8 53.4Carbon tetrachloride ug/L 50 117 70-130116 1 2050<0.50 58.5 58.1Chlorobenzene ug/L 50 113 70-130111 1 2050<0.50 56.3 55.6Chloroethane ug/L 50 88 66-15289 1 2050<0.37 44.2 44.5Chloroform ug/L 50 108 70-130109 1 2050<2.5 54.3 54.7Chloromethane ug/L 50 85 44-15186 1 2050<0.50 42.5 43.1cis-1,2-Dichloroethene ug/L 50 88 70-13091 2 20509.0 53.3 54.4cis-1,3-Dichloropropene ug/L 50 96 70-13097 1 2050<0.50 48.2 48.6Dibromochloromethane ug/L 50 104 70-130103 1 2050<0.50 52.2 51.7Dichlorodifluoromethane ug/L 50 72 29-16071 2 2050<0.22 36.0 35.4Ethylbenzene ug/L 50 114 70-132114 0 2050<0.50 57.2 57.0Isopropylbenzene (Cumene) ug/L 50 124 70-130123 1 2050<0.14 61.8 61.4m&p-Xylene ug/L 100 120 70-131119 1 20100<1.0 120 119Methyl-tert-butyl ether ug/L 50 90 48-14393 3 2050<0.17 44.9 46.4Methylene Chloride ug/L 50 95 70-13092 2 2050<0.23 47.3 46.1o-Xylene ug/L 50 118 70-131114 3 2050<0.50 59.0 57.1Styrene ug/L 50 111 70-130110 1 2050<0.50 55.3 54.8Tetrachloroethene ug/L 50 121 70-130120 0 205047.0 107 107Toluene ug/L 50 114 70-130113 1 2050<0.50 56.9 56.3trans-1,2-Dichloroethene ug/L 50 98 70-132100 2 2050<0.26 48.8 49.9trans-1,3-Dichloropropene ug/L 50 97 70-13098 1 2050<0.23 48.6 48.8Trichloroethene ug/L 50 112 70-130111 1 20505.0 60.9 60.5Trichlorofluoromethane ug/L 50 101 50-153102 0 2050<0.18 50.7 50.9Vinyl chloride ug/L 50 96 60-15597 1 2050<0.18 47.8 48.34-Bromofluorobenzene (S) % 107 70-130106Dibromofluoromethane (S) % 99 70-130100Toluene-d8 (S) % 100 70-130100
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 12 of 16
#=QL#
QUALIFIERS
Pace Project No.:Project:
40114839023-6105-015 CP-SHOREHAM YARD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Green BayPASI-G
ANALYTE QUALIFIERS
Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter).HS
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/19/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 13 of 16
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:Project:
40114839023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch
40114839001 MSV/28483051415-0800-200 EPA 826040114839002 MSV/28483SE EFFLUENT EPA 8260
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/19/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 14 of 16
Pag
e 15
of 1
6
UPPER MIDWEST REGION ~\ 1 of
}o;;W 612~071700 w" ·C Cree'\ l)Ll CHAIN OF CUSTODY
*Preservation Codes A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH
H=Sodium Bisulfate Solution !=Sodium Thiosulfate J=Other
Project State: JI\ fV' Sampled By (Print): A-£ et V') P ~ 1' I( ,' Sampled By (Sign):
PO#:
Data Package Options (billable)
0 EPA Level Ill
0 EPA Level IV
PACE LAB#
MS/MSD 0 On your sample
(billable) 0 NOT needed on
your sample
Regulatory Program:
FILTERED? (YES/NO)
PRESERVATION (CODE)*
Matrix Codes Ao::: Air W=Water B = Biota OW = Drinking Water C = Charcoal GW = Ground Water 0 = Oil SW = Surface Water S =Soil WW= Waste Water Sl=Slud e WP=Wi
COLLECTION
Rush Turnaround Time Requested - Prelims (Rush TAT subject to approval/surcharge)
Date Needed:
Samples on HOLD are subject to
special pricing and release of llabllity
C019a(27 Jun2006)
Datemme:
DatefTime: Received By:
Quote#:
Mail To Contact:
Mail To Company:
Mail To Address:
Invoice To Contact:
Invoice To Company:
Invoice To Address:
Invoice To Phone:
CLIENT COMMENTS
Dateffime:
LAB COMMENTS (lab Use Only)
Profile#
PACE Project No.
Page 16 of 16
~eAnaJyticat" Sample Condition Upon Receipt Pace Analytical Services, Inc.
1241 Bellevue Street, Suite 9 Green Bay, WI 54302
Project#:
/Client Name: C:,-C)\C\'€)(' C\~SO · , I Courier: r Fed Ex r UPS r Client r Pace Jther: \l h >...~ c 0 Tracking #: :I ~ -:::i ~ 3'lo ..... \ ~ Custody Seal on Cooler/Box Present: r yes - no Seals intact: r yes r no
Custody Seal on Samples Present: r yes r no Seals intact: r yes ! no
W0#:40114839 1111111111111111111111 40114839
Packing Material: r Bubble Wrap Y Bubble Bags r None r Other • Thermometer Used 6 \L - S lo }ype of Ice: ~Blue Dry None--17'__,_..S_a_m_p_le_s_o_n-ic_e_, c-o-o-lin_g_p-ro_c_e_s_s-ha_s_b_eg-un __ _
Cooler Temperature Uncorr: ~ /Corr: 3 , 5 Biological Tissue is Frozen: r yes
Temp Blank Present: ryes J7no r no Person exami~g coSnts:
Temp should be above freezing to 6°C for all sample except Biota. Date: :2 - ~ _ -~ Frozen Biota Samples should be received s 0°C. Comments: Initials: 'f\CJno(\ -<
Chain of Custody Present: rlves ONo ON/A 1.
Chain of Custody Filled Out: 6Yes 0No ON/A 2.
Chain of Custody Relinquished: -d'Yes ONo ON/A 3 .
Sampler Name & Signature on COC: .efYes 0No ON/A 4.
Samples Arrived within Hold Time: ~Yes ONo ON/A 5.
- VOA Samples frozen upon receipt OYes ONo Date/Time:
Short Hold Time Analysis (<72hr): OYes d'No ON/A 6.
Rush Tum Around Time Requested: OYes B'No ON/A 7.
Sufficient Volume: 121)res ONo ON/A 8.
Correct Containers Used: dYes ONo ON/A 9.
-Pace Containers Used: tJves 0No ON/A
-Pace IR Containers Used: OYes ONo .f1N/A
Containers Intact: fues ONo ON/A 10.
Filtered volume received for Dissolved tests 0Yes ONo 6N/A 11.
Sample Labels match COC: Eifves ONo ON/A 12. tl{)\ - ~ \I ·w .... \. O '\\ \ '-\ \ :SO'ltv\~ \O~e\ , \k) -Includes date/time/ID/Analysis Matrix: \""" rv-.. ~ - \ ) -n -·
All containers needing preservation have been checked. ~/A ' (Non-Compliance noted in 13.) OYes 0No 13.
rHN03 r H2S04 r NaOH r NaOH +ZnAct -- - ---- -- ----- --- - -- -- ... - ----- ---- -- --All containers needing preservation are found to be in
~/A compliance with EPA recommendation. OYes ONo (!:i~03~ fi~2; t:::J~OH:_Z_nAct_<:_9~~<.?H :a:!_2J ___ -z-______ exceptions: VOA oliform, TOG, TOX, TOH, Initial when ILab Std #ID of luare1 O&G, WIDR W, Phenolics, OTHER: Ye; 0No completed preservative Time:
Headspace in VOA Vials ( >6mm): ~es ONo ON/A 14 .. ~ .+r-(\(') ~\o.n\<_c-:> l<.w S-- It;" -l 5"' ~es
I Trip Blank Present: ONo ON/A 15.
Trip Blank Custody Seals Present ~s ONo ON/A
Pace Trip Blank Lot# (if purchased):
Client Notification/ Resolution: If checked, see attached form for additional comments 0 Person Contacted: Date/Time: ------------------Comments/ Resolution: --------------------------------------------------------
Project Manager Review: Date: :?)0;< F-GB-C-031-Rev.03 (9April2015) SCUR Form
#=CL#
June 30, 2015
LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40116588
40116588Project:Pace Project No.:
RE:
Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102
023-6105-015 CP-SHOREHAM YARD
Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on June 16, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Laurie [email protected] Manager
Enclosures
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 1 of 29
#=CP#
CERTIFICATIONS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334
North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Wisconsin Certification #: 405132750
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 2 of 29
#=SS#
SAMPLE SUMMARY
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID Matrix Date Collected Date Received
40116588001 061515-0800-200 Water 06/15/15 08:00 06/16/15 08:40
40116588002 RW07-39-SP-0615-100 Water 06/15/15 15:04 06/16/15 08:40
40116588003 RW07-40-SP-0615-100 Water 06/15/15 15:08 06/16/15 08:40
40116588004 RW06-28-I-0615-100 Water 06/15/15 15:12 06/16/15 08:40
40116588005 RW07-38-I-0615-100 Water 06/15/15 15:15 06/16/15 08:40
40116588006 RW06-27-BR-0615-100 Water 06/15/15 15:19 06/16/15 08:40
40116588007 SE EFFLUENT Water 06/15/15 15:25 06/16/15 08:40
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Green Bay, WI 54302(920)469-2436
Page 3 of 29
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts
40116588001 061515-0800-200 EPA 8260 71 PASI-GHNW
40116588002 RW07-39-SP-0615-100 EPA 8260 71 PASI-GHNW
40116588003 RW07-40-SP-0615-100 EPA 8260 71 PASI-GHNW
40116588004 RW06-28-I-0615-100 EPA 8260 71 PASI-GHNW
40116588005 RW07-38-I-0615-100 EPA 8260 71 PASI-GHNW
40116588006 RW06-27-BR-0615-100 EPA 8260 71 PASI-GHNW
40116588007 SE EFFLUENT EPA 8260 71 PASI-GHNW
SM 2540D 1 PASI-GDDY
SM 4500-H+B 1 PASI-GSJR
EPA 410.4 1 PASI-GTJJ
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 4 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: 061515-0800-200 Lab ID: 40116588001 Collected: 06/15/15 08:00 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 06/18/15 15:37 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 06/18/15 15:37 107-05-15.0 2.2 1Benzene <0.50 ug/L 06/18/15 15:37 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 06/18/15 15:37 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 06/18/15 15:37 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 06/18/15 15:37 75-27-41.0 0.50 1Bromoform <0.50 ug/L 06/18/15 15:37 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 06/18/15 15:37 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 06/18/15 15:37 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 06/18/15 15:37 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 06/18/15 15:37 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 06/18/15 15:37 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 06/18/15 15:37 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 06/18/15 15:37 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 06/18/15 15:37 75-00-31.0 0.37 1Chloroform <2.5 ug/L 06/18/15 15:37 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 06/18/15 15:37 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 06/18/15 15:37 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 06/18/15 15:37 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 06/18/15 15:37 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 06/18/15 15:37 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 06/18/15 15:37 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 06/18/15 15:37 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 06/18/15 15:37 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 06/18/15 15:37 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 06/18/15 15:37 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 06/18/15 15:37 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 06/18/15 15:37 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 06/18/15 15:37 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 06/18/15 15:37 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 06/18/15 15:37 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 06/18/15 15:37 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 06/18/15 15:37 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 06/18/15 15:37 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 06/18/15 15:37 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 06/18/15 15:37 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 06/18/15 15:37 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 06/18/15 15:37 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 06/18/15 15:37 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 06/18/15 15:37 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 06/18/15 15:37 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 06/18/15 15:37 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 06/18/15 15:37 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 06/18/15 15:37 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 06/18/15 15:37 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 06/18/15 15:37 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
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Page 5 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: 061515-0800-200 Lab ID: 40116588001 Collected: 06/15/15 08:00 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 06/18/15 15:37 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 06/18/15 15:37 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 06/18/15 15:37 103-65-11.0 0.50 1Styrene <0.50 ug/L 06/18/15 15:37 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 06/18/15 15:37 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 06/18/15 15:37 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 06/18/15 15:37 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 06/18/15 15:37 109-99-95.0 2.0 1Toluene <0.50 ug/L 06/18/15 15:37 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 06/18/15 15:37 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 06/18/15 15:37 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 06/18/15 15:37 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 06/18/15 15:37 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 06/18/15 15:37 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 06/18/15 15:37 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 06/18/15 15:37 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 06/18/15 15:37 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 06/18/15 15:37 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 06/18/15 15:37 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 06/18/15 15:37 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 06/18/15 15:37 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 06/18/15 15:37 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 98 % 06/18/15 15:37 460-00-4 HS70-130 1Dibromofluoromethane (S) 94 % 06/18/15 15:37 1868-53-770-130 1Toluene-d8 (S) 94 % 06/18/15 15:37 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 6 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: RW07-39-SP-0615-100 Lab ID: 40116588002 Collected: 06/15/15 15:04 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <14.8 ug/L 06/18/15 10:23 67-64-1100 14.8 5Allyl chloride <10.8 ug/L 06/18/15 10:23 107-05-125.0 10.8 5Benzene <2.5 ug/L 06/18/15 10:23 71-43-25.0 2.5 5Bromobenzene <1.2 ug/L 06/18/15 10:23 108-86-15.0 1.2 5Bromochloromethane <1.7 ug/L 06/18/15 10:23 74-97-55.0 1.7 5Bromodichloromethane <2.5 ug/L 06/18/15 10:23 75-27-45.0 2.5 5Bromoform <2.5 ug/L 06/18/15 10:23 75-25-25.0 2.5 5Bromomethane <12.2 ug/L 06/18/15 10:23 74-83-925.0 12.2 52-Butanone (MEK) <14.9 ug/L 06/18/15 10:23 78-93-3100 14.9 5n-Butylbenzene <2.5 ug/L 06/18/15 10:23 104-51-85.0 2.5 5sec-Butylbenzene <10.9 ug/L 06/18/15 10:23 135-98-825.0 10.9 5tert-Butylbenzene <0.90 ug/L 06/18/15 10:23 98-06-65.0 0.90 5Carbon tetrachloride <2.5 ug/L 06/18/15 10:23 56-23-55.0 2.5 5Chlorobenzene <2.5 ug/L 06/18/15 10:23 108-90-75.0 2.5 5Chloroethane <1.9 ug/L 06/18/15 10:23 75-00-35.0 1.9 5Chloroform <12.5 ug/L 06/18/15 10:23 67-66-325.0 12.5 5Chloromethane <2.5 ug/L 06/18/15 10:23 74-87-35.0 2.5 52-Chlorotoluene <2.5 ug/L 06/18/15 10:23 95-49-85.0 2.5 54-Chlorotoluene <1.1 ug/L 06/18/15 10:23 106-43-45.0 1.1 51,2-Dibromo-3-chloropropane <10.8 ug/L 06/18/15 10:23 96-12-825.0 10.8 5Dibromochloromethane <2.5 ug/L 06/18/15 10:23 124-48-15.0 2.5 51,2-Dibromoethane (EDB) <0.89 ug/L 06/18/15 10:23 106-93-45.0 0.89 5Dibromomethane <2.1 ug/L 06/18/15 10:23 74-95-35.0 2.1 51,2-Dichlorobenzene <2.5 ug/L 06/18/15 10:23 95-50-15.0 2.5 51,3-Dichlorobenzene <2.5 ug/L 06/18/15 10:23 541-73-15.0 2.5 51,4-Dichlorobenzene <2.5 ug/L 06/18/15 10:23 106-46-75.0 2.5 5Dichlorodifluoromethane <1.1 ug/L 06/18/15 10:23 75-71-85.0 1.1 51,1-Dichloroethane 41.3 ug/L 06/18/15 10:23 75-34-35.0 1.2 51,2-Dichloroethane <0.84 ug/L 06/18/15 10:23 107-06-25.0 0.84 51,1-Dichloroethene 19.6 ug/L 06/18/15 10:23 75-35-45.0 2.1 5cis-1,2-Dichloroethene 19.5 ug/L 06/18/15 10:23 156-59-25.0 1.3 5trans-1,2-Dichloroethene <1.3 ug/L 06/18/15 10:23 156-60-55.0 1.3 5Dichlorofluoromethane <1.1 ug/L 06/18/15 10:23 75-43-45.0 1.1 51,2-Dichloropropane <1.2 ug/L 06/18/15 10:23 78-87-55.0 1.2 51,3-Dichloropropane <2.5 ug/L 06/18/15 10:23 142-28-95.0 2.5 52,2-Dichloropropane <2.4 ug/L 06/18/15 10:23 594-20-75.0 2.4 51,1-Dichloropropene <2.2 ug/L 06/18/15 10:23 563-58-65.0 2.2 5cis-1,3-Dichloropropene <2.5 ug/L 06/18/15 10:23 10061-01-55.0 2.5 5trans-1,3-Dichloropropene <1.1 ug/L 06/18/15 10:23 10061-02-65.0 1.1 5Diethyl ether (Ethyl ether) <11.1 ug/L 06/18/15 10:23 60-29-725.0 11.1 5Ethylbenzene <2.5 ug/L 06/18/15 10:23 100-41-45.0 2.5 5Hexachloro-1,3-butadiene <10.5 ug/L 06/18/15 10:23 87-68-325.0 10.5 5Isopropylbenzene (Cumene) <0.72 ug/L 06/18/15 10:23 98-82-85.0 0.72 5p-Isopropyltoluene <2.5 ug/L 06/18/15 10:23 99-87-65.0 2.5 5Methylene Chloride <1.2 ug/L 06/18/15 10:23 75-09-25.0 1.2 54-Methyl-2-pentanone (MIBK) <10.7 ug/L 06/18/15 10:23 108-10-125.0 10.7 5
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
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Green Bay, WI 54302(920)469-2436
Page 7 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: RW07-39-SP-0615-100 Lab ID: 40116588002 Collected: 06/15/15 15:04 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.87 ug/L 06/18/15 10:23 1634-04-45.0 0.87 5Naphthalene <12.5 ug/L 06/18/15 10:23 91-20-325.0 12.5 5n-Propylbenzene <2.5 ug/L 06/18/15 10:23 103-65-15.0 2.5 5Styrene <2.5 ug/L 06/18/15 10:23 100-42-55.0 2.5 51,1,1,2-Tetrachloroethane <0.90 ug/L 06/18/15 10:23 630-20-65.0 0.90 51,1,2,2-Tetrachloroethane <1.2 ug/L 06/18/15 10:23 79-34-55.0 1.2 5Tetrachloroethene 252 ug/L 06/18/15 10:23 127-18-45.0 2.5 5Tetrahydrofuran <10.2 ug/L 06/18/15 10:23 109-99-925.0 10.2 5Toluene <2.5 ug/L 06/18/15 10:23 108-88-35.0 2.5 51,2,3-Trichlorobenzene <10.7 ug/L 06/18/15 10:23 87-61-625.0 10.7 51,2,4-Trichlorobenzene <11.0 ug/L 06/18/15 10:23 120-82-125.0 11.0 51,1,1-Trichloroethane 102 ug/L 06/18/15 10:23 71-55-65.0 2.5 51,1,2-Trichloroethane <0.99 ug/L 06/18/15 10:23 79-00-55.0 0.99 5Trichloroethene 13.6 ug/L 06/18/15 10:23 79-01-65.0 1.7 5Trichlorofluoromethane <0.92 ug/L 06/18/15 10:23 75-69-45.0 0.92 51,2,3-Trichloropropane <2.5 ug/L 06/18/15 10:23 96-18-45.0 2.5 51,1,2-Trichlorotrifluoroethane <4.1 ug/L 06/18/15 10:23 76-13-125.0 4.1 51,2,4-Trimethylbenzene <2.5 ug/L 06/18/15 10:23 95-63-65.0 2.5 51,3,5-Trimethylbenzene <2.5 ug/L 06/18/15 10:23 108-67-85.0 2.5 5Vinyl chloride <0.88 ug/L 06/18/15 10:23 75-01-45.0 0.88 5m&p-Xylene <5.0 ug/L 06/18/15 10:23 179601-23-110.0 5.0 5o-Xylene <2.5 ug/L 06/18/15 10:23 95-47-65.0 2.5 5Surrogates4-Bromofluorobenzene (S) 95 % 06/18/15 10:23 460-00-470-130 5Dibromofluoromethane (S) 97 % 06/18/15 10:23 1868-53-770-130 5Toluene-d8 (S) 95 % 06/18/15 10:23 2037-26-570-130 5
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 8 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: RW07-40-SP-0615-100 Lab ID: 40116588003 Collected: 06/15/15 15:08 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 06/18/15 08:53 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 06/18/15 08:53 107-05-15.0 2.2 1Benzene <0.50 ug/L 06/18/15 08:53 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 06/18/15 08:53 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 06/18/15 08:53 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 06/18/15 08:53 75-27-41.0 0.50 1Bromoform <0.50 ug/L 06/18/15 08:53 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 06/18/15 08:53 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 06/18/15 08:53 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 06/18/15 08:53 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 06/18/15 08:53 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 06/18/15 08:53 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 06/18/15 08:53 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 06/18/15 08:53 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 06/18/15 08:53 75-00-31.0 0.37 1Chloroform <2.5 ug/L 06/18/15 08:53 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 06/18/15 08:53 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 06/18/15 08:53 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 06/18/15 08:53 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 06/18/15 08:53 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 06/18/15 08:53 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 06/18/15 08:53 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 06/18/15 08:53 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 06/18/15 08:53 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 06/18/15 08:53 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 06/18/15 08:53 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 06/18/15 08:53 75-71-81.0 0.22 11,1-Dichloroethane 2.1 ug/L 06/18/15 08:53 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 06/18/15 08:53 107-06-21.0 0.17 11,1-Dichloroethene 2.4 ug/L 06/18/15 08:53 75-35-41.0 0.41 1cis-1,2-Dichloroethene 1.6 ug/L 06/18/15 08:53 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 06/18/15 08:53 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 06/18/15 08:53 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 06/18/15 08:53 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 06/18/15 08:53 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 06/18/15 08:53 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 06/18/15 08:53 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 06/18/15 08:53 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 06/18/15 08:53 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 06/18/15 08:53 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 06/18/15 08:53 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 06/18/15 08:53 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 06/18/15 08:53 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 06/18/15 08:53 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 06/18/15 08:53 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 06/18/15 08:53 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 9 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: RW07-40-SP-0615-100 Lab ID: 40116588003 Collected: 06/15/15 15:08 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 06/18/15 08:53 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 06/18/15 08:53 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 06/18/15 08:53 103-65-11.0 0.50 1Styrene <0.50 ug/L 06/18/15 08:53 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 06/18/15 08:53 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 06/18/15 08:53 79-34-51.0 0.25 1Tetrachloroethene 58.6 ug/L 06/18/15 08:53 127-18-4 M11.0 0.50 1Tetrahydrofuran <2.0 ug/L 06/18/15 08:53 109-99-95.0 2.0 1Toluene <0.50 ug/L 06/18/15 08:53 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 06/18/15 08:53 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 06/18/15 08:53 120-82-15.0 2.2 11,1,1-Trichloroethane 11.0 ug/L 06/18/15 08:53 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 06/18/15 08:53 79-00-51.0 0.20 1Trichloroethene 3.0 ug/L 06/18/15 08:53 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 06/18/15 08:53 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 06/18/15 08:53 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 06/18/15 08:53 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 06/18/15 08:53 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 06/18/15 08:53 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 06/18/15 08:53 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 06/18/15 08:53 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 06/18/15 08:53 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 98 % 06/18/15 08:53 460-00-470-130 1Dibromofluoromethane (S) 95 % 06/18/15 08:53 1868-53-770-130 1Toluene-d8 (S) 95 % 06/18/15 08:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 10 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: RW06-28-I-0615-100 Lab ID: 40116588004 Collected: 06/15/15 15:12 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone 8.5J ug/L 06/18/15 11:08 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 06/18/15 11:08 107-05-15.0 2.2 1Benzene <0.50 ug/L 06/18/15 11:08 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 06/18/15 11:08 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 06/18/15 11:08 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 06/18/15 11:08 75-27-41.0 0.50 1Bromoform <0.50 ug/L 06/18/15 11:08 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 06/18/15 11:08 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 06/18/15 11:08 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 06/18/15 11:08 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 06/18/15 11:08 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 06/18/15 11:08 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 06/18/15 11:08 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 06/18/15 11:08 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 06/18/15 11:08 75-00-31.0 0.37 1Chloroform <2.5 ug/L 06/18/15 11:08 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 06/18/15 11:08 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 06/18/15 11:08 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 06/18/15 11:08 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 06/18/15 11:08 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 06/18/15 11:08 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 06/18/15 11:08 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 06/18/15 11:08 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 06/18/15 11:08 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 06/18/15 11:08 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 06/18/15 11:08 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 06/18/15 11:08 75-71-81.0 0.22 11,1-Dichloroethane 5.7 ug/L 06/18/15 11:08 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 06/18/15 11:08 107-06-21.0 0.17 11,1-Dichloroethene 3.1 ug/L 06/18/15 11:08 75-35-41.0 0.41 1cis-1,2-Dichloroethene 3.2 ug/L 06/18/15 11:08 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 06/18/15 11:08 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 06/18/15 11:08 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 06/18/15 11:08 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 06/18/15 11:08 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 06/18/15 11:08 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 06/18/15 11:08 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 06/18/15 11:08 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 06/18/15 11:08 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 06/18/15 11:08 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 06/18/15 11:08 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 06/18/15 11:08 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 06/18/15 11:08 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 06/18/15 11:08 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 06/18/15 11:08 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 06/18/15 11:08 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 11 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: RW06-28-I-0615-100 Lab ID: 40116588004 Collected: 06/15/15 15:12 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 06/18/15 11:08 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 06/18/15 11:08 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 06/18/15 11:08 103-65-11.0 0.50 1Styrene <0.50 ug/L 06/18/15 11:08 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 06/18/15 11:08 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 06/18/15 11:08 79-34-51.0 0.25 1Tetrachloroethene 16.1 ug/L 06/18/15 11:08 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 06/18/15 11:08 109-99-95.0 2.0 1Toluene <0.50 ug/L 06/18/15 11:08 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 06/18/15 11:08 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 06/18/15 11:08 120-82-15.0 2.2 11,1,1-Trichloroethane 10.1 ug/L 06/18/15 11:08 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 06/18/15 11:08 79-00-51.0 0.20 1Trichloroethene 1.8 ug/L 06/18/15 11:08 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 06/18/15 11:08 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 06/18/15 11:08 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 06/18/15 11:08 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 06/18/15 11:08 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 06/18/15 11:08 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 06/18/15 11:08 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 06/18/15 11:08 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 06/18/15 11:08 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 98 % 06/18/15 11:08 460-00-470-130 1Dibromofluoromethane (S) 94 % 06/18/15 11:08 1868-53-770-130 1Toluene-d8 (S) 95 % 06/18/15 11:08 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 12 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: RW07-38-I-0615-100 Lab ID: 40116588005 Collected: 06/15/15 15:15 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone 11.1J ug/L 06/18/15 11:30 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 06/18/15 11:30 107-05-15.0 2.2 1Benzene <0.50 ug/L 06/18/15 11:30 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 06/18/15 11:30 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 06/18/15 11:30 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 06/18/15 11:30 75-27-41.0 0.50 1Bromoform <0.50 ug/L 06/18/15 11:30 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 06/18/15 11:30 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 06/18/15 11:30 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 06/18/15 11:30 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 06/18/15 11:30 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 06/18/15 11:30 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 06/18/15 11:30 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 06/18/15 11:30 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 06/18/15 11:30 75-00-31.0 0.37 1Chloroform <2.5 ug/L 06/18/15 11:30 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 06/18/15 11:30 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 06/18/15 11:30 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 06/18/15 11:30 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 06/18/15 11:30 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 06/18/15 11:30 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 06/18/15 11:30 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 06/18/15 11:30 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 06/18/15 11:30 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 06/18/15 11:30 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 06/18/15 11:30 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 06/18/15 11:30 75-71-81.0 0.22 11,1-Dichloroethane 12.9 ug/L 06/18/15 11:30 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 06/18/15 11:30 107-06-21.0 0.17 11,1-Dichloroethene 4.8 ug/L 06/18/15 11:30 75-35-41.0 0.41 1cis-1,2-Dichloroethene 5.6 ug/L 06/18/15 11:30 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 06/18/15 11:30 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 06/18/15 11:30 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 06/18/15 11:30 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 06/18/15 11:30 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 06/18/15 11:30 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 06/18/15 11:30 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 06/18/15 11:30 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 06/18/15 11:30 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 06/18/15 11:30 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 06/18/15 11:30 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 06/18/15 11:30 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 06/18/15 11:30 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 06/18/15 11:30 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 06/18/15 11:30 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 06/18/15 11:30 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 13 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: RW07-38-I-0615-100 Lab ID: 40116588005 Collected: 06/15/15 15:15 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 06/18/15 11:30 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 06/18/15 11:30 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 06/18/15 11:30 103-65-11.0 0.50 1Styrene <0.50 ug/L 06/18/15 11:30 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 06/18/15 11:30 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 06/18/15 11:30 79-34-51.0 0.25 1Tetrachloroethene 42.0 ug/L 06/18/15 11:30 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 06/18/15 11:30 109-99-95.0 2.0 1Toluene <0.50 ug/L 06/18/15 11:30 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 06/18/15 11:30 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 06/18/15 11:30 120-82-15.0 2.2 11,1,1-Trichloroethane 9.2 ug/L 06/18/15 11:30 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 06/18/15 11:30 79-00-51.0 0.20 1Trichloroethene 4.8 ug/L 06/18/15 11:30 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 06/18/15 11:30 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 06/18/15 11:30 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 06/18/15 11:30 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 06/18/15 11:30 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 06/18/15 11:30 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 06/18/15 11:30 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 06/18/15 11:30 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 06/18/15 11:30 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 97 % 06/18/15 11:30 460-00-470-130 1Dibromofluoromethane (S) 95 % 06/18/15 11:30 1868-53-770-130 1Toluene-d8 (S) 95 % 06/18/15 11:30 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 14 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: RW06-27-BR-0615-100 Lab ID: 40116588006 Collected: 06/15/15 15:19 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 06/18/15 11:53 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 06/18/15 11:53 107-05-15.0 2.2 1Benzene <0.50 ug/L 06/18/15 11:53 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 06/18/15 11:53 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 06/18/15 11:53 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 06/18/15 11:53 75-27-41.0 0.50 1Bromoform <0.50 ug/L 06/18/15 11:53 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 06/18/15 11:53 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 06/18/15 11:53 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 06/18/15 11:53 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 06/18/15 11:53 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 06/18/15 11:53 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 06/18/15 11:53 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 06/18/15 11:53 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 06/18/15 11:53 75-00-31.0 0.37 1Chloroform <2.5 ug/L 06/18/15 11:53 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 06/18/15 11:53 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 06/18/15 11:53 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 06/18/15 11:53 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 06/18/15 11:53 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 06/18/15 11:53 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 06/18/15 11:53 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 06/18/15 11:53 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 06/18/15 11:53 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 06/18/15 11:53 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 06/18/15 11:53 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 06/18/15 11:53 75-71-81.0 0.22 11,1-Dichloroethane 10.2 ug/L 06/18/15 11:53 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 06/18/15 11:53 107-06-21.0 0.17 11,1-Dichloroethene 4.6 ug/L 06/18/15 11:53 75-35-41.0 0.41 1cis-1,2-Dichloroethene 13.2 ug/L 06/18/15 11:53 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 06/18/15 11:53 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 06/18/15 11:53 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 06/18/15 11:53 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 06/18/15 11:53 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 06/18/15 11:53 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 06/18/15 11:53 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 06/18/15 11:53 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 06/18/15 11:53 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 06/18/15 11:53 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 06/18/15 11:53 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 06/18/15 11:53 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 06/18/15 11:53 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 06/18/15 11:53 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 06/18/15 11:53 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 06/18/15 11:53 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 15 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: RW06-27-BR-0615-100 Lab ID: 40116588006 Collected: 06/15/15 15:19 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 06/18/15 11:53 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 06/18/15 11:53 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 06/18/15 11:53 103-65-11.0 0.50 1Styrene <0.50 ug/L 06/18/15 11:53 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 06/18/15 11:53 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 06/18/15 11:53 79-34-51.0 0.25 1Tetrachloroethene 31.3 ug/L 06/18/15 11:53 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 06/18/15 11:53 109-99-95.0 2.0 1Toluene <0.50 ug/L 06/18/15 11:53 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 06/18/15 11:53 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 06/18/15 11:53 120-82-15.0 2.2 11,1,1-Trichloroethane 7.3 ug/L 06/18/15 11:53 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 06/18/15 11:53 79-00-51.0 0.20 1Trichloroethene 5.4 ug/L 06/18/15 11:53 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 06/18/15 11:53 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 06/18/15 11:53 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 06/18/15 11:53 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 06/18/15 11:53 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 06/18/15 11:53 108-67-81.0 0.50 1Vinyl chloride 0.22J ug/L 06/18/15 11:53 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 06/18/15 11:53 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 06/18/15 11:53 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 98 % 06/18/15 11:53 460-00-470-130 1Dibromofluoromethane (S) 94 % 06/18/15 11:53 1868-53-770-130 1Toluene-d8 (S) 95 % 06/18/15 11:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 16 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40116588007 Collected: 06/15/15 15:25 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 06/18/15 12:15 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 06/18/15 12:15 107-05-15.0 2.2 1Benzene <0.50 ug/L 06/18/15 12:15 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 06/18/15 12:15 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 06/18/15 12:15 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 06/18/15 12:15 75-27-41.0 0.50 1Bromoform <0.50 ug/L 06/18/15 12:15 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 06/18/15 12:15 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 06/18/15 12:15 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 06/18/15 12:15 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 06/18/15 12:15 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 06/18/15 12:15 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 06/18/15 12:15 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 06/18/15 12:15 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 06/18/15 12:15 75-00-31.0 0.37 1Chloroform <2.5 ug/L 06/18/15 12:15 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 06/18/15 12:15 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 06/18/15 12:15 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 06/18/15 12:15 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 06/18/15 12:15 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 06/18/15 12:15 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 06/18/15 12:15 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 06/18/15 12:15 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 06/18/15 12:15 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 06/18/15 12:15 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 06/18/15 12:15 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 06/18/15 12:15 75-71-81.0 0.22 11,1-Dichloroethane 11.9 ug/L 06/18/15 12:15 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 06/18/15 12:15 107-06-21.0 0.17 11,1-Dichloroethene 5.1 ug/L 06/18/15 12:15 75-35-41.0 0.41 1cis-1,2-Dichloroethene 6.5 ug/L 06/18/15 12:15 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 06/18/15 12:15 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 06/18/15 12:15 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 06/18/15 12:15 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 06/18/15 12:15 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 06/18/15 12:15 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 06/18/15 12:15 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 06/18/15 12:15 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 06/18/15 12:15 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 06/18/15 12:15 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 06/18/15 12:15 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 06/18/15 12:15 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 06/18/15 12:15 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 06/18/15 12:15 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 06/18/15 12:15 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 06/18/15 12:15 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 17 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40116588007 Collected: 06/15/15 15:25 Received: 06/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 06/18/15 12:15 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 06/18/15 12:15 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 06/18/15 12:15 103-65-11.0 0.50 1Styrene <0.50 ug/L 06/18/15 12:15 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 06/18/15 12:15 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 06/18/15 12:15 79-34-51.0 0.25 1Tetrachloroethene 45.9 ug/L 06/18/15 12:15 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 06/18/15 12:15 109-99-95.0 2.0 1Toluene <0.50 ug/L 06/18/15 12:15 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 06/18/15 12:15 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 06/18/15 12:15 120-82-15.0 2.2 11,1,1-Trichloroethane 13.0 ug/L 06/18/15 12:15 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 06/18/15 12:15 79-00-51.0 0.20 1Trichloroethene 5.2 ug/L 06/18/15 12:15 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 06/18/15 12:15 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 06/18/15 12:15 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 06/18/15 12:15 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 06/18/15 12:15 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 06/18/15 12:15 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 06/18/15 12:15 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 06/18/15 12:15 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 06/18/15 12:15 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 98 % 06/18/15 12:15 460-00-470-130 1Dibromofluoromethane (S) 95 % 06/18/15 12:15 1868-53-770-130 1Toluene-d8 (S) 95 % 06/18/15 12:15 2037-26-570-130 1
Analytical Method: SM 2540D2540D Total Suspended Solids
Total Suspended Solids <0.95 mg/L 06/17/15 11:012.0 0.95 1
Analytical Method: SM 4500-H+B4500H+ pH, Electrometric
pH 7.1 Std. Units 06/16/15 17:20 H60.10 0.010 1
Analytical Method: EPA 410.4 Preparation Method: EPA 410.4410.4 COD
Chemical Oxygen Demand <11.6 mg/L 06/26/15 12:3406/26/15 08:4050.0 11.6 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 18 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
MSV/28962EPA 8260
EPA 82608260 MSV
Associated Lab Samples: 40116588001, 40116588002, 40116588003, 40116588004, 40116588005, 40116588006, 40116588007
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1177159Associated Lab Samples: 40116588001, 40116588002, 40116588003, 40116588004, 40116588005, 40116588006, 40116588007
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 06/18/15 06:311,1,1-Trichloroethane ug/L <0.50 1.0 06/18/15 06:311,1,2,2-Tetrachloroethane ug/L <0.25 1.0 06/18/15 06:311,1,2-Trichloroethane ug/L <0.20 1.0 06/18/15 06:311,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 06/18/15 06:311,1-Dichloroethane ug/L <0.24 1.0 06/18/15 06:311,1-Dichloroethene ug/L <0.41 1.0 06/18/15 06:311,1-Dichloropropene ug/L <0.44 1.0 06/18/15 06:311,2,3-Trichlorobenzene ug/L <2.1 5.0 06/18/15 06:311,2,3-Trichloropropane ug/L <0.50 1.0 06/18/15 06:311,2,4-Trichlorobenzene ug/L <2.2 5.0 06/18/15 06:311,2,4-Trimethylbenzene ug/L <0.50 1.0 06/18/15 06:311,2-Dibromo-3-chloropropane ug/L <2.2 5.0 06/18/15 06:311,2-Dibromoethane (EDB) ug/L <0.18 1.0 06/18/15 06:311,2-Dichlorobenzene ug/L <0.50 1.0 06/18/15 06:311,2-Dichloroethane ug/L <0.17 1.0 06/18/15 06:311,2-Dichloropropane ug/L <0.23 1.0 06/18/15 06:311,3,5-Trimethylbenzene ug/L <0.50 1.0 06/18/15 06:311,3-Dichlorobenzene ug/L <0.50 1.0 06/18/15 06:311,3-Dichloropropane ug/L <0.50 1.0 06/18/15 06:311,4-Dichlorobenzene ug/L <0.50 1.0 06/18/15 06:312,2-Dichloropropane ug/L <0.48 1.0 06/18/15 06:312-Butanone (MEK) ug/L <3.0 20.0 06/18/15 06:312-Chlorotoluene ug/L <0.50 1.0 06/18/15 06:314-Chlorotoluene ug/L <0.21 1.0 06/18/15 06:314-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 06/18/15 06:31Acetone ug/L <3.0 20.0 06/18/15 06:31Allyl chloride ug/L <2.2 5.0 06/18/15 06:31Benzene ug/L <0.50 1.0 06/18/15 06:31Bromobenzene ug/L <0.23 1.0 06/18/15 06:31Bromochloromethane ug/L <0.34 1.0 06/18/15 06:31Bromodichloromethane ug/L <0.50 1.0 06/18/15 06:31Bromoform ug/L <0.50 1.0 06/18/15 06:31Bromomethane ug/L <2.4 5.0 06/18/15 06:31Carbon tetrachloride ug/L <0.50 1.0 06/18/15 06:31Chlorobenzene ug/L <0.50 1.0 06/18/15 06:31Chloroethane ug/L <0.37 1.0 06/18/15 06:31Chloroform ug/L <2.5 5.0 06/18/15 06:31Chloromethane ug/L <0.50 1.0 06/18/15 06:31cis-1,2-Dichloroethene ug/L <0.26 1.0 06/18/15 06:31cis-1,3-Dichloropropene ug/L <0.50 1.0 06/18/15 06:31
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 19 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1177159Associated Lab Samples: 40116588001, 40116588002, 40116588003, 40116588004, 40116588005, 40116588006, 40116588007
Matrix: Water
Analyzed
Dibromochloromethane ug/L <0.50 1.0 06/18/15 06:31Dibromomethane ug/L <0.43 1.0 06/18/15 06:31Dichlorodifluoromethane ug/L <0.22 1.0 06/18/15 06:31Dichlorofluoromethane ug/L <0.21 1.0 06/18/15 06:31Diethyl ether (Ethyl ether) ug/L <2.2 5.0 06/18/15 06:31Ethylbenzene ug/L <0.50 1.0 06/18/15 06:31Hexachloro-1,3-butadiene ug/L <2.1 5.0 06/18/15 06:31Isopropylbenzene (Cumene) ug/L <0.14 1.0 06/18/15 06:31m&p-Xylene ug/L <1.0 2.0 06/18/15 06:31Methyl-tert-butyl ether ug/L <0.17 1.0 06/18/15 06:31Methylene Chloride ug/L <0.23 1.0 06/18/15 06:31n-Butylbenzene ug/L <0.50 1.0 06/18/15 06:31n-Propylbenzene ug/L <0.50 1.0 06/18/15 06:31Naphthalene ug/L <2.5 5.0 06/18/15 06:31o-Xylene ug/L <0.50 1.0 06/18/15 06:31p-Isopropyltoluene ug/L <0.50 1.0 06/18/15 06:31sec-Butylbenzene ug/L <2.2 5.0 06/18/15 06:31Styrene ug/L <0.50 1.0 06/18/15 06:31tert-Butylbenzene ug/L <0.18 1.0 06/18/15 06:31Tetrachloroethene ug/L <0.50 1.0 06/18/15 06:31Tetrahydrofuran ug/L <2.0 5.0 06/18/15 06:31Toluene ug/L <0.50 1.0 06/18/15 06:31trans-1,2-Dichloroethene ug/L <0.26 1.0 06/18/15 06:31trans-1,3-Dichloropropene ug/L <0.23 1.0 06/18/15 06:31Trichloroethene ug/L <0.33 1.0 06/18/15 06:31Trichlorofluoromethane ug/L <0.18 1.0 06/18/15 06:31Vinyl chloride ug/L <0.18 1.0 06/18/15 06:314-Bromofluorobenzene (S) % 97 70-130 06/18/15 06:31Dibromofluoromethane (S) % 94 70-130 06/18/15 06:31Toluene-d8 (S) % 94 70-130 06/18/15 06:31
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1177160LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1177161
1,1,1-Trichloroethane ug/L 51.550 103 70-13010853.9 5 201,1,2,2-Tetrachloroethane ug/L 42.450 85 70-1309045.1 6 201,1,2-Trichloroethane ug/L 45.950 92 70-1309748.5 5 201,1,2-Trichlorotrifluoroethane ug/L 57.350 115 50-15012160.7 6 201,1-Dichloroethane ug/L 46.150 92 70-1309949.6 7 201,1-Dichloroethene ug/L 50.950 102 70-13010753.6 5 201,2,4-Trichlorobenzene ug/L 47.550 95 70-13010452.1 9 201,2-Dibromo-3-chloropropane ug/L 40.950 82 50-1508844.0 7 201,2-Dibromoethane (EDB) ug/L 50.750 101 70-13010753.7 6 201,2-Dichlorobenzene ug/L 50.050 100 70-13010552.4 5 20
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
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Page 20 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1177160LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1177161
1,2-Dichloroethane ug/L 46.550 93 70-1319748.5 4 201,2-Dichloropropane ug/L 44.450 89 70-1309447.1 6 201,3-Dichlorobenzene ug/L 51.150 102 70-13010653.2 4 201,4-Dichlorobenzene ug/L 49.550 99 70-13010452.2 5 20Benzene ug/L 44.650 89 70-1309446.9 5 20Bromodichloromethane ug/L 50.550 101 70-13010954.5 8 20Bromoform ug/L 48.750 97 68-13010452.2 7 20Bromomethane ug/L 34.850 70 38-1377838.8 11 20Carbon tetrachloride ug/L 56.450 113 70-13012059.9 6 20Chlorobenzene ug/L 50.850 102 70-13010653.0 4 20Chloroethane ug/L 48.050 96 70-13610150.5 5 20Chloroform ug/L 45.650 91 70-1309547.7 5 20Chloromethane ug/L 39.550 79 48-1448241.2 4 20cis-1,2-Dichloroethene ug/L 50.150 100 70-13010250.9 1 20cis-1,3-Dichloropropene ug/L 46.750 93 70-1309949.6 6 20Dibromochloromethane ug/L 49.050 98 70-13010251.1 4 20Dichlorodifluoromethane ug/L 40.650 81 33-1578442.1 4 20Ethylbenzene ug/L 49.950 100 70-13210452.0 4 20Isopropylbenzene (Cumene) ug/L 52.650 105 70-13011054.8 4 20m&p-Xylene ug/L 104100 104 70-131109109 4 20Methyl-tert-butyl ether ug/L 45.750 91 48-1419748.7 6 20Methylene Chloride ug/L 48.950 98 70-13010250.9 4 20o-Xylene ug/L 51.350 103 70-13110753.7 5 20Styrene ug/L 51.250 102 70-13010954.5 6 20Tetrachloroethene ug/L 55.350 111 70-13011758.4 5 20Toluene ug/L 49.250 98 70-13010351.7 5 20trans-1,2-Dichloroethene ug/L 50.550 101 70-13010753.4 6 20trans-1,3-Dichloropropene ug/L 43.550 87 70-1309346.4 6 20Trichloroethene ug/L 51.250 102 70-13010854.0 5 20Trichlorofluoromethane ug/L 55.250 110 50-15011557.7 4 20Vinyl chloride ug/L 43.450 87 65-1429145.4 4 204-Bromofluorobenzene (S) % 99 70-13099Dibromofluoromethane (S) % 95 70-13096Toluene-d8 (S) % 97 70-13096
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1178412MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40116588003
1178413
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 50 106 70-130117 8 205011.0 63.8 69.31,1,2,2-Tetrachloroethane ug/L 50 86 70-13093 8 2050<0.25 43.0 46.71,1,2-Trichloroethane ug/L 50 93 70-130104 12 2050<0.20 46.3 52.01,1,2-Trichlorotrifluoroethane ug/L 50 117 50-151127 8 2050<0.81 58.6 63.71,1-Dichloroethane ug/L 50 95 70-134104 9 20502.1 49.7 54.11,1-Dichloroethene ug/L 50 103 70-139112 8 20502.4 53.7 58.4
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
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Page 21 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1178412MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40116588003
1178413
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,2,4-Trichlorobenzene ug/L 50 98 70-130108 10 2050<2.2 49.0 54.21,2-Dibromo-3-chloropropane
ug/L 50 84 50-15094 11 2050<2.2 41.9 46.9
1,2-Dibromoethane (EDB) ug/L 50 102 70-130114 11 2050<0.18 50.8 56.91,2-Dichlorobenzene ug/L 50 99 70-130109 10 2050<0.50 49.5 54.61,2-Dichloroethane ug/L 50 93 70-132102 10 2050<0.17 46.4 51.01,2-Dichloropropane ug/L 50 89 70-13097 8 2050<0.23 44.6 48.31,3-Dichlorobenzene ug/L 50 102 70-130111 8 2050<0.50 51.2 55.51,4-Dichlorobenzene ug/L 50 100 70-130108 8 2050<0.50 50.0 54.0Benzene ug/L 50 90 70-13098 9 2050<0.50 44.9 48.9Bromodichloromethane ug/L 50 104 70-132112 8 2050<0.50 51.8 56.2Bromoform ug/L 50 100 68-130110 10 2050<0.50 49.8 55.1Bromomethane ug/L 50 78 38-14186 10 2050<2.4 39.5 43.6Carbon tetrachloride ug/L 50 116 70-130126 8 2050<0.50 57.9 62.9Chlorobenzene ug/L 50 102 70-130112 9 2050<0.50 51.1 56.0Chloroethane ug/L 50 96 66-152105 9 2050<0.37 47.9 52.7Chloroform ug/L 50 93 70-130101 8 2050<2.5 47.2 51.1Chloromethane ug/L 50 79 44-15186 8 2050<0.50 39.9 43.4cis-1,2-Dichloroethene ug/L 50 97 70-130109 11 20501.6 50.0 56.1cis-1,3-Dichloropropene ug/L 50 94 70-130102 9 2050<0.50 46.9 51.2Dibromochloromethane ug/L 50 99 70-130108 9 2050<0.50 49.6 54.2Dichlorodifluoromethane ug/L 50 78 29-16084 8 2050<0.22 39.0 42.1Ethylbenzene ug/L 50 100 70-132110 9 2050<0.50 50.1 55.1Isopropylbenzene (Cumene) ug/L 50 107 70-130117 9 2050<0.14 53.5 58.5m&p-Xylene ug/L 100 106 70-131116 9 20100<1.0 106 116Methyl-tert-butyl ether ug/L 50 93 48-143103 10 2050<0.17 46.5 51.4Methylene Chloride ug/L 50 98 70-130107 9 2050<0.23 48.8 53.6o-Xylene ug/L 50 103 70-131114 10 2050<0.50 51.6 56.8Styrene ug/L 50 105 70-130115 9 2050<0.50 52.4 57.5Tetrachloroethene ug/L M150 116 70-130132 7 205058.6 116 125Toluene ug/L 50 100 70-130109 9 2050<0.50 49.8 54.5trans-1,2-Dichloroethene ug/L 50 103 70-132112 8 2050<0.26 51.8 56.3trans-1,3-Dichloropropene ug/L 50 88 70-13098 11 2050<0.23 44.0 48.9Trichloroethene ug/L 50 103 70-130113 9 20503.0 54.5 59.5Trichlorofluoromethane ug/L 50 112 50-153122 8 2050<0.18 56.2 61.1Vinyl chloride ug/L 50 87 60-15595 9 2050<0.18 43.6 47.54-Bromofluorobenzene (S) % 98 70-130100Dibromofluoromethane (S) % 97 70-13096Toluene-d8 (S) % 96 70-13097
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
WET/22383SM 2540D
SM 2540D2540D Total Suspended Solids
Associated Lab Samples: 40116588007
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1177619Associated Lab Samples: 40116588007
Matrix: Water
Analyzed
Total Suspended Solids mg/L <0.48 1.0 06/17/15 11:00
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1177620LABORATORY CONTROL SAMPLE:LCSSpike
Total Suspended Solids mg/L 90.0100 90 80-120
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401165350011177621SAMPLE DUPLICATE:
Total Suspended Solids mg/L 49.2 3 1047.7
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401165990011177622SAMPLE DUPLICATE:
Total Suspended Solids mg/L 45.2 2 1044.4
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
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Green Bay, WI 54302(920)469-2436
Page 23 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
WET/22379SM 4500-H+B
SM 4500-H+B4500H+B pH
Associated Lab Samples: 40116588007
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401165690011177403SAMPLE DUPLICATE:
pH Std. Units 8.5 H60 58.4
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 24 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
WETA/29234EPA 410.4
EPA 410.4410.4 COD
Associated Lab Samples: 40116588007
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1183683Associated Lab Samples: 40116588007
Matrix: Water
Analyzed
Chemical Oxygen Demand mg/L <11.6 50.0 06/26/15 12:32
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1183684LABORATORY CONTROL SAMPLE:LCSSpike
Chemical Oxygen Demand mg/L 486500 97 90-110
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1183685MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40116556001
1183686
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
Chemical Oxygen Demand mg/L 2000 104 90-110102 2 102000411 2490 2440
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1183687MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40116795001
1183688
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
Chemical Oxygen Demand mg/L 526 104 90-110104 0 1052618.3J 567 565
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
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Page 25 of 29
#=QL#
QUALIFIERS
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Green BayPASI-G
ANALYTE QUALIFIERS
Analysis initiated outside of the 15 minute EPA recommended holding time.H6Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter).HSMatrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
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Page 26 of 29
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:Project:
40116588023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch
40116588001 MSV/28962061515-0800-200 EPA 826040116588002 MSV/28962RW07-39-SP-0615-100 EPA 826040116588003 MSV/28962RW07-40-SP-0615-100 EPA 826040116588004 MSV/28962RW06-28-I-0615-100 EPA 826040116588005 MSV/28962RW07-38-I-0615-100 EPA 826040116588006 MSV/28962RW06-27-BR-0615-100 EPA 826040116588007 MSV/28962SE EFFLUENT EPA 8260
40116588007 WET/22383SE EFFLUENT SM 2540D
40116588007 WET/22379SE EFFLUENT SM 4500-H+B
40116588007 WETA/29234 WETA/29240SE EFFLUENT EPA 410.4 EPA 410.4
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/30/2015 03:56 PM
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Green Bay, WI 54302(920)469-2436
Page 27 of 29
Pag
e 28
of 2
9
(Please Print Clea fy)
Company Name:
Branch/Location: AA I l N J r\ f. L-t\,V ff_ ,
Project Contact:
Phone:
Project Number: (!) 2-'3 - b [OS-()(~ Project Name:
Project State:
I *Preservation Codes
A=None B=HCL C=H2S04 D=HN03 E=DI Water H=Sodium Bisulfate Solution l=Sodium Thiosulfate
FILTERED? (YES/NO) Ylf>J IV I\/
Sampled By (Print): A~ll p~ rl ~ PS (AP) Sampled By (Sign): ,,A-L .. _/[1~t -
PRESERVATION (CODE)"
Pick. ~
' . '('.
~ c. A
PO#: L-110'2... Data Package Options
(billable)
D EPA Level Ill
D EPA Level IV
PACE LAB#
11115/llll'lD D On your sample
(billa~le)
D NOT ne; dad on yours; mple
Regulatory Program:
Matrix Codes
1; h•;'.'.
·.
! '.
'• A= Air W =Water V\ B = Biota OW = Drinking Water s ~',:~, \. \ C =Charcoal GW =Ground Water ~
0 =Oil SW =Surface Water ll;•if ~ <:::'.) S =Soil WW= Waste Water > SI = Sludae WP = Wiae '. . • ,. . ·
COLLECTION ·· · .·.· · 1--~~.;.__~--1 MATRIX
UPPER MIDWEST REGION
MN: 612-607-1700 WI: 920-469-2436
F=Methanol J=Other
G=NaOH I
Quote#:
Mail To Contact:
Mail To Company:
Mail To Address:
Invoice To Contact:
Invoice To Company:
Invoice To Address:
Invoice To Phone:
1 of B:i?) \lo58'8
Profile#
rt) 2- (\.Wc97-3Cf-SP··&HS--ld1& tSOL.[ .'. • ~ j - L/OML/ i--->ci~o-?-~~w-~~1~--~e~,~sr~~~1,~ts~-~te-s+-l--'-t-,~~.-4--~ :3~~+--t--+--+~t---+--+--+~~~~~..,___:.:~~~~~~
oo L/ R.w~G-i.g-1-(QG s--t"1'Q 1s12. ..SI< 1'1.I <; It w~ 7 -~<&- I.-c'.9615-tOO ')/ f) '3 )( OCJG f(W~6-2.7·~~-@t 15-\~ l5ltf .~i< 007 SE ~«I \o\t".'.VI .i- .,_/ (5'"25 ..-/ 3,x h<
I I
1.\~.: Rush Turnaround Time Requeste I - Prelims Relinquished BYJ 1~·.--.....Jb.....-.L...-im_e..J: b.....-.L...-""11---1.-.......ll.--.I....--/l'V-t •. -."-~-.. a~-ty'9t -,!"imJ"-''...1.../-
1--/l_'__, ,.,......-..,,,.PA'"'c~E~P'""ro"'"lect~N~o-. -......a
(Rush TAT subject to approval/s llrcharge) ?'1f//~ 1 '1;' /IT f< i 7 Vile. Q l'.5/ I J v A t.i:DlUJ 7) >(f
~==T::::·i:P::r :D:Ra:te:h:~:e:ed:115e:db:: -i:~=~l-:!;:':'''h:-!..::::::t):":!,_R_el-inq_u..Ji~:.::~::::.;dd ""---,,, ___:.::...::.;:::.!:.:__~· "-..:.__.i.._. " _ __i.: • j (<t; Z,L Received By: oatefTime: ,..., n ..- ransm1 re 1m us esu y comp e e ., a you wan : · 1~ . f ------il--------------------l!Recelpt Temp= ::, ·1'7- •c
1-:-:-:-::-:-:--1---------+------11Re~i:q1i:rh-o (,J't,/;~e: okJ/0 R~BA1/!AM, J, !2~2{ /')ft/) S~leRec:i>tpH Telephone: Relinquished By: I o-;;\emme: Received By: batefnme: { ~~Adjusted ...------~-1--~~-~--~+--~----11 Fax: Coollfr custodv Seal
Samples on HOLD are subject to
special pricing and release of llablllty
C019a(27 Jun2006)
Relinquished By: DatefTime: Received By: DatefTime: P"'l@Jt I Not Present ~I Not Intact
VersiOn 6.0 05114106
Page 29 of 29
Sample Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9
Green Bay, WI 54302 ~eAnalytica( I
(Client Name: (;i 0 /J<7.c Acco c/6/ec Courier: r Fed Ex r UPS ! Client r Pace Jther:_....:\J~a~(fc.i...:::;.o ___ _
Tracking #: 0 7i
Project#: wott:40116588 1\1 ll\l l\ l\11\ \\I \11\1 40116588
Custody Seal on Cooler/Box Present: es - no Seals intact: ~s r no
Custody Seal on Samples Present: r yes,tz.no Seals intact: ryes ! no
Packing Material: F'8ubble Wrap r Bubble Bags r None r Other
Thermometer Used <:if2 /{ Type of Ice: e.)Blue Dry None p"\samples on ice, cooling process has begun
Cooler Temperature Uncorr: l/ /Corr: i.j Biological Tissue is Frozen: r yes
Temp Blank Present: ryes p..no r· no Person e?J;i~g contents:
Temp should be above freezing to 6°C for all sample except Biota. Date: '/ (, r_;( Initials: #V1 Frozen Biota Samples should be received s o·c. Comments:
Chain of Custody Present: ,.Ehes ONo ON/A 1. ,
Chain of Custody Filled Out: 0Ye~ ON/A 2. 11,,, 1hvo1le_ i!b-1 cft6/1>
Chain of Custody Relinquished: t91¥es ONo ON/A 3.
Sampler Name & Signature on COC: ~s ONo ON/A 4.
Samples Arrived within Hold Time: ~s ONo ON/A 5.
- VOA Samples frozen upon receipt 0Yes ONo Datemme:
Short Hold Time Analysis (<72hr): OYes 0No ON/A 6.
Rush Turn Around Time Requested: OYes~o ON/A 7. v
Sufficient Volume: 0Yes ONo ON/A 8.
Correct Containers Used: ~s ONo ON/A 9.
-Pace Containers Used: ~s ONo ON/A
-Pace IR Containers Used: 0Yes ONo ~ Containers Intact: i:ii&es ONo ON/A 10.
Filtered volume received for Dissolved tests 0Yes ONo fAiNiA 11.
Sample Labels match COC: ~s ONo ON/A 12.
-Includes date/time/ID/Analysis Matrix: vJ All containers needing preservation have been checked. . .
rHN03 ~2S04 r NaOH r NaOH + ZnAct {~~n-~~plia~:e~~:_d in 2~·L_ ___________ ~s _C:~ _~NIA_ 13. All containers needing preservation are found to be in compliance with EPA recommendation. tJ<ies ONo ON/A {HN03, H2S04 s2; NaOH+ZnAct <:9, NaOH <:12) e~c"°eptio~s~ @.-~t~~. roe: mi. rc5H. --- --- ---j;{;- -- --- -Initial when ifU ILab Std #.ID of ~ate/ O&G, WIDROW, Phenolics, OTHER: es ONo completed preservative ime:
Headspace in VOA Vials ( >6mm ): ~es ONo ON/A 14. 60 ( (I) ""'IAA 01c/J("
~s 71
Trip Blank Present: ONo ON/A 15.
Trip Blank Custody Seals Present Bilt:s ONo ON/A
Pace Trip Blank Lot# (if purchased): I 2. I 7 'J.... Lf Client Notification/ Resolution: If checked, see attached form for additional comments 0
Person Contacted: Date/Time: ------------------------ -------------Comments/ Resolution: -------------------------------------------------------------------
Project Manager Review: Date: _tti.....i.l ~ly"-ll~Ki.....-----
F-GB-C-031-Rev.03 (9April2015) SCUR Form
#=CL#
July 20, 2015
LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40118306
40118306Project:Pace Project No.:
RE:
Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102
023-6105-015 CP-SHOREHAM YD
Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on July 17, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Laurie [email protected] Manager
Enclosures
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:Project:
40118306023-6105-015 CP-SHOREHAM YD
Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334
North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Wisconsin Certification #: 405132750
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:Project:
40118306023-6105-015 CP-SHOREHAM YD
Lab ID Sample ID Matrix Date Collected Date Received
40118306001 071615-0700-200 Water 07/16/15 07:00 07/17/15 08:40
40118306002 SE EFFLUENT Water 07/16/15 07:15 07/17/15 08:40
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 3 of 16
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:Project:
40118306023-6105-015 CP-SHOREHAM YD
Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts
40118306001 071615-0700-200 EPA 8260 71 PASI-GLAP
40118306002 SE EFFLUENT EPA 8260 71 PASI-GLAP
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 4 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40118306023-6105-015 CP-SHOREHAM YD
Sample: 071615-0700-200 Lab ID: 40118306001 Collected: 07/16/15 07:00 Received: 07/17/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 07/18/15 17:48 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 07/18/15 17:48 107-05-15.0 2.2 1Benzene <0.50 ug/L 07/18/15 17:48 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 07/18/15 17:48 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 07/18/15 17:48 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 07/18/15 17:48 75-27-41.0 0.50 1Bromoform <0.50 ug/L 07/18/15 17:48 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 07/18/15 17:48 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 07/18/15 17:48 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 07/18/15 17:48 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 07/18/15 17:48 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 07/18/15 17:48 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 07/18/15 17:48 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 07/18/15 17:48 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 07/18/15 17:48 75-00-31.0 0.37 1Chloroform <2.5 ug/L 07/18/15 17:48 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 07/18/15 17:48 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 07/18/15 17:48 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 07/18/15 17:48 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 07/18/15 17:48 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 07/18/15 17:48 124-48-15.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 07/18/15 17:48 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 07/18/15 17:48 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 07/18/15 17:48 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 07/18/15 17:48 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 07/18/15 17:48 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 07/18/15 17:48 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 07/18/15 17:48 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 07/18/15 17:48 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 07/18/15 17:48 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 07/18/15 17:48 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 07/18/15 17:48 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 07/18/15 17:48 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 07/18/15 17:48 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 07/18/15 17:48 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 07/18/15 17:48 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 07/18/15 17:48 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 07/18/15 17:48 10061-01-55.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 07/18/15 17:48 10061-02-620.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 07/18/15 17:48 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 07/18/15 17:48 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 07/18/15 17:48 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 07/18/15 17:48 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 07/18/15 17:48 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 07/18/15 17:48 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 07/18/15 17:48 108-10-120.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/20/2015 04:28 PM
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Green Bay, WI 54302(920)469-2436
Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40118306023-6105-015 CP-SHOREHAM YD
Sample: 071615-0700-200 Lab ID: 40118306001 Collected: 07/16/15 07:00 Received: 07/17/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 07/18/15 17:48 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 07/18/15 17:48 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 07/18/15 17:48 103-65-11.0 0.50 1Styrene <0.50 ug/L 07/18/15 17:48 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 07/18/15 17:48 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 07/18/15 17:48 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 07/18/15 17:48 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 07/18/15 17:48 109-99-95.0 2.0 1Toluene <0.50 ug/L 07/18/15 17:48 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 07/18/15 17:48 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 07/18/15 17:48 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 07/18/15 17:48 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 07/18/15 17:48 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 07/18/15 17:48 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 07/18/15 17:48 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 07/18/15 17:48 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 07/18/15 17:48 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 07/18/15 17:48 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 07/18/15 17:48 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 07/18/15 17:48 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 07/18/15 17:48 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 07/18/15 17:48 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 98 % 07/18/15 17:48 460-00-470-130 1Dibromofluoromethane (S) 109 % 07/18/15 17:48 1868-53-770-130 1Toluene-d8 (S) 101 % 07/18/15 17:48 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/20/2015 04:28 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 6 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40118306023-6105-015 CP-SHOREHAM YD
Sample: SE EFFLUENT Lab ID: 40118306002 Collected: 07/16/15 07:15 Received: 07/17/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 07/18/15 22:17 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 07/18/15 22:17 107-05-15.0 2.2 1Benzene <0.50 ug/L 07/18/15 22:17 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 07/18/15 22:17 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 07/18/15 22:17 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 07/18/15 22:17 75-27-41.0 0.50 1Bromoform <0.50 ug/L 07/18/15 22:17 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 07/18/15 22:17 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 07/18/15 22:17 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 07/18/15 22:17 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 07/18/15 22:17 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 07/18/15 22:17 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 07/18/15 22:17 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 07/18/15 22:17 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 07/18/15 22:17 75-00-31.0 0.37 1Chloroform <2.5 ug/L 07/18/15 22:17 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 07/18/15 22:17 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 07/18/15 22:17 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 07/18/15 22:17 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 07/18/15 22:17 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 07/18/15 22:17 124-48-15.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 07/18/15 22:17 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 07/18/15 22:17 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 07/18/15 22:17 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 07/18/15 22:17 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 07/18/15 22:17 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 07/18/15 22:17 75-71-81.0 0.22 11,1-Dichloroethane 14.8 ug/L 07/18/15 22:17 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 07/18/15 22:17 107-06-21.0 0.17 11,1-Dichloroethene 5.4 ug/L 07/18/15 22:17 75-35-41.0 0.41 1cis-1,2-Dichloroethene 10.2 ug/L 07/18/15 22:17 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 07/18/15 22:17 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 07/18/15 22:17 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 07/18/15 22:17 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 07/18/15 22:17 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 07/18/15 22:17 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 07/18/15 22:17 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 07/18/15 22:17 10061-01-55.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 07/18/15 22:17 10061-02-620.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 07/18/15 22:17 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 07/18/15 22:17 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 07/18/15 22:17 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 07/18/15 22:17 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 07/18/15 22:17 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 07/18/15 22:17 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 07/18/15 22:17 108-10-120.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/20/2015 04:28 PM
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Green Bay, WI 54302(920)469-2436
Page 7 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40118306023-6105-015 CP-SHOREHAM YD
Sample: SE EFFLUENT Lab ID: 40118306002 Collected: 07/16/15 07:15 Received: 07/17/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 07/18/15 22:17 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 07/18/15 22:17 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 07/18/15 22:17 103-65-11.0 0.50 1Styrene <0.50 ug/L 07/18/15 22:17 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 07/18/15 22:17 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 07/18/15 22:17 79-34-51.0 0.25 1Tetrachloroethene 50.5 ug/L 07/18/15 22:17 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 07/18/15 22:17 109-99-95.0 2.0 1Toluene <0.50 ug/L 07/18/15 22:17 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 07/18/15 22:17 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 07/18/15 22:17 120-82-15.0 2.2 11,1,1-Trichloroethane 18.1 ug/L 07/18/15 22:17 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 07/18/15 22:17 79-00-51.0 0.20 1Trichloroethene 5.7 ug/L 07/18/15 22:17 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 07/18/15 22:17 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 07/18/15 22:17 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 07/18/15 22:17 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 07/18/15 22:17 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 07/18/15 22:17 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 07/18/15 22:17 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 07/18/15 22:17 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 07/18/15 22:17 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 95 % 07/18/15 22:17 460-00-470-130 1Dibromofluoromethane (S) 106 % 07/18/15 22:17 1868-53-770-130 1Toluene-d8 (S) 100 % 07/18/15 22:17 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/20/2015 04:28 PM
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Page 8 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40118306023-6105-015 CP-SHOREHAM YD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
MSV/29444EPA 8260
EPA 82608260 MSV
Associated Lab Samples: 40118306001, 40118306002
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1195032Associated Lab Samples: 40118306001, 40118306002
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 07/18/15 13:181,1,1-Trichloroethane ug/L <0.50 1.0 07/18/15 13:181,1,2,2-Tetrachloroethane ug/L <0.25 1.0 07/18/15 13:181,1,2-Trichloroethane ug/L <0.20 1.0 07/18/15 13:181,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 07/18/15 13:181,1-Dichloroethane ug/L <0.24 1.0 07/18/15 13:181,1-Dichloroethene ug/L <0.41 1.0 07/18/15 13:181,1-Dichloropropene ug/L <0.44 1.0 07/18/15 13:181,2,3-Trichlorobenzene ug/L <2.1 5.0 07/18/15 13:181,2,3-Trichloropropane ug/L <0.50 1.0 07/18/15 13:181,2,4-Trichlorobenzene ug/L <2.2 5.0 07/18/15 13:181,2,4-Trimethylbenzene ug/L <0.50 1.0 07/18/15 13:181,2-Dibromo-3-chloropropane ug/L <2.2 5.0 07/18/15 13:181,2-Dibromoethane (EDB) ug/L <0.18 1.0 07/18/15 13:181,2-Dichlorobenzene ug/L <0.50 1.0 07/18/15 13:181,2-Dichloroethane ug/L <0.17 1.0 07/18/15 13:181,2-Dichloropropane ug/L <0.23 1.0 07/18/15 13:181,3,5-Trimethylbenzene ug/L <0.50 1.0 07/18/15 13:181,3-Dichlorobenzene ug/L <0.50 1.0 07/18/15 13:181,3-Dichloropropane ug/L <0.50 1.0 07/18/15 13:181,4-Dichlorobenzene ug/L <0.50 1.0 07/18/15 13:182,2-Dichloropropane ug/L <0.48 1.0 07/18/15 13:182-Butanone (MEK) ug/L <3.0 20.0 07/18/15 13:182-Chlorotoluene ug/L <0.50 1.0 07/18/15 13:184-Chlorotoluene ug/L <0.21 1.0 07/18/15 13:184-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 07/18/15 13:18Acetone ug/L <3.0 20.0 07/18/15 13:18Allyl chloride ug/L <2.2 5.0 07/18/15 13:18Benzene ug/L <0.50 1.0 07/18/15 13:18Bromobenzene ug/L <0.23 1.0 07/18/15 13:18Bromochloromethane ug/L <0.34 1.0 07/18/15 13:18Bromodichloromethane ug/L <0.50 1.0 07/18/15 13:18Bromoform ug/L <0.50 1.0 07/18/15 13:18Bromomethane ug/L <2.4 5.0 07/18/15 13:18Carbon tetrachloride ug/L <0.50 1.0 07/18/15 13:18Chlorobenzene ug/L <0.50 1.0 07/18/15 13:18Chloroethane ug/L <0.37 1.0 07/18/15 13:18Chloroform ug/L <2.5 5.0 07/18/15 13:18Chloromethane ug/L <0.50 1.0 07/18/15 13:18cis-1,2-Dichloroethene ug/L <0.26 1.0 07/18/15 13:18cis-1,3-Dichloropropene ug/L <0.50 1.0 07/18/15 13:18
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/20/2015 04:28 PM
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Page 9 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40118306023-6105-015 CP-SHOREHAM YD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1195032Associated Lab Samples: 40118306001, 40118306002
Matrix: Water
Analyzed
Dibromochloromethane ug/L <0.50 1.0 07/18/15 13:18Dibromomethane ug/L <0.43 1.0 07/18/15 13:18Dichlorodifluoromethane ug/L <0.22 1.0 07/18/15 13:18Dichlorofluoromethane ug/L <0.21 1.0 07/18/15 13:18Diethyl ether (Ethyl ether) ug/L <2.2 5.0 07/18/15 13:18Ethylbenzene ug/L <0.50 1.0 07/18/15 13:18Hexachloro-1,3-butadiene ug/L <2.1 5.0 07/18/15 13:18Isopropylbenzene (Cumene) ug/L <0.14 1.0 07/18/15 13:18m&p-Xylene ug/L <1.0 2.0 07/18/15 13:18Methyl-tert-butyl ether ug/L <0.17 1.0 07/18/15 13:18Methylene Chloride ug/L <0.23 1.0 07/18/15 13:18n-Butylbenzene ug/L <0.50 1.0 07/18/15 13:18n-Propylbenzene ug/L <0.50 1.0 07/18/15 13:18Naphthalene ug/L <2.5 5.0 07/18/15 13:18o-Xylene ug/L <0.50 1.0 07/18/15 13:18p-Isopropyltoluene ug/L <0.50 1.0 07/18/15 13:18sec-Butylbenzene ug/L <2.2 5.0 07/18/15 13:18Styrene ug/L <0.50 1.0 07/18/15 13:18tert-Butylbenzene ug/L <0.18 1.0 07/18/15 13:18Tetrachloroethene ug/L <0.50 1.0 07/18/15 13:18Tetrahydrofuran ug/L <2.0 5.0 07/18/15 13:18Toluene ug/L <0.50 1.0 07/18/15 13:18trans-1,2-Dichloroethene ug/L <0.26 1.0 07/18/15 13:18trans-1,3-Dichloropropene ug/L <0.23 1.0 07/18/15 13:18Trichloroethene ug/L <0.33 1.0 07/18/15 13:18Trichlorofluoromethane ug/L <0.18 1.0 07/18/15 13:18Vinyl chloride ug/L <0.18 1.0 07/18/15 13:184-Bromofluorobenzene (S) % 97 70-130 07/18/15 13:18Dibromofluoromethane (S) % 109 70-130 07/18/15 13:18Toluene-d8 (S) % 102 70-130 07/18/15 13:18
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1195033LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1195034
1,1,1-Trichloroethane ug/L 59.650 119 70-13011758.6 2 201,1,2,2-Tetrachloroethane ug/L 41.850 84 70-1308542.4 2 201,1,2-Trichloroethane ug/L 49.850 100 70-13010251.2 3 201,1,2-Trichlorotrifluoroethane ug/L 56.750 113 50-15011055.0 3 201,1-Dichloroethane ug/L 51.450 103 70-13010050.0 3 201,1-Dichloroethene ug/L 52.550 105 70-13010150.7 4 201,2,4-Trichlorobenzene ug/L 50.750 101 70-13010251.0 1 201,2-Dibromo-3-chloropropane ug/L 40.650 81 50-1508140.5 0 201,2-Dibromoethane (EDB) ug/L 52.050 104 70-13010854.1 4 201,2-Dichlorobenzene ug/L 50.850 102 70-13010150.3 1 20
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/20/2015 04:28 PM
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Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40118306023-6105-015 CP-SHOREHAM YD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1195033LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1195034
1,2-Dichloroethane ug/L 59.150 118 70-13111456.9 4 201,2-Dichloropropane ug/L 49.350 99 70-13010351.4 4 201,3-Dichlorobenzene ug/L 48.550 97 70-1309949.3 2 201,4-Dichlorobenzene ug/L 51.750 103 70-13010351.5 0 20Benzene ug/L 48.250 96 70-1309648.0 0 20Bromodichloromethane ug/L 56.950 114 70-13011557.7 1 20Bromoform ug/L 44.550 89 68-1309547.7 7 20Bromomethane ug/L 59.550 119 38-13712663.0 6 20Carbon tetrachloride ug/L 62.150 124 70-13012462.0 0 20Chlorobenzene ug/L 56.350 113 70-13011155.3 2 20Chloroethane ug/L 49.250 98 70-1369647.9 3 20Chloroform ug/L 54.850 110 70-13010954.3 1 20Chloromethane ug/L 43.450 87 48-1448341.7 4 20cis-1,2-Dichloroethene ug/L 50.650 101 70-1309849.1 3 20cis-1,3-Dichloropropene ug/L 44.250 88 70-1308944.4 0 20Dibromochloromethane ug/L 49.150 98 70-1309949.5 1 20Dichlorodifluoromethane ug/L 43.750 87 33-1578441.9 4 20Ethylbenzene ug/L 59.250 118 70-13211758.7 1 20Isopropylbenzene (Cumene) ug/L 62.150 124 70-13012562.7 1 20m&p-Xylene ug/L 123100 123 70-131121121 2 20Methyl-tert-butyl ether ug/L 42.350 85 48-1418743.6 3 20Methylene Chloride ug/L 47.750 95 70-13010150.4 6 20o-Xylene ug/L 58.050 116 70-13111457.2 1 20Styrene ug/L 58.650 117 70-13011859.2 1 20Tetrachloroethene ug/L 57.750 115 70-13011356.7 2 20Toluene ug/L 57.150 114 70-13011356.5 1 20trans-1,2-Dichloroethene ug/L 50.650 101 70-13010150.4 0 20trans-1,3-Dichloropropene ug/L 48.050 96 70-1309748.7 1 20Trichloroethene ug/L 56.350 113 70-13011155.3 2 20Trichlorofluoromethane ug/L 55.950 112 50-15010954.4 3 20Vinyl chloride ug/L 45.850 92 65-1429044.8 2 204-Bromofluorobenzene (S) % 107 70-130110Dibromofluoromethane (S) % 101 70-130101Toluene-d8 (S) % 107 70-130106
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1195151MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40118260006
1195152
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 50 121 70-130122 1 2050<0.50 60.6 61.21,1,2,2-Tetrachloroethane ug/L 50 89 70-13088 2 2050<0.25 44.5 43.81,1,2-Trichloroethane ug/L 50 101 70-130104 3 2050<0.20 50.5 51.91,1,2-Trichlorotrifluoroethane ug/L 50 110 50-151114 3 2050<0.81 55.2 57.01,1-Dichloroethane ug/L 50 102 70-134102 0 2050<0.24 50.9 50.91,1-Dichloroethene ug/L 50 103 70-139104 1 2050<0.41 51.4 52.1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 11 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40118306023-6105-015 CP-SHOREHAM YD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1195151MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40118260006
1195152
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,2,4-Trichlorobenzene ug/L 50 102 70-130101 1 2050<2.2 51.2 50.71,2-Dibromo-3-chloropropane
ug/L 50 87 50-15097 11 2050<2.2 43.5 48.7
1,2-Dibromoethane (EDB) ug/L 50 110 70-130109 1 2050<0.18 54.9 54.41,2-Dichlorobenzene ug/L 50 101 70-130102 1 2050<0.50 50.5 51.01,2-Dichloroethane ug/L 50 118 70-132119 1 2050<0.17 58.8 59.31,2-Dichloropropane ug/L 50 100 70-130105 5 2050<0.23 50.0 52.51,3-Dichlorobenzene ug/L 50 96 70-13099 2 2050<0.50 48.1 49.31,4-Dichlorobenzene ug/L 50 100 70-130103 3 2050<0.50 50.0 51.6Benzene ug/L 50 99 70-130100 0 2050<0.50 49.7 49.8Bromodichloromethane ug/L 50 117 70-132119 1 2050<0.50 58.7 59.5Bromoform ug/L 50 94 68-13092 2 2050<0.50 46.8 45.8Bromomethane ug/L 50 127 38-141128 1 2050<2.4 63.4 64.0Carbon tetrachloride ug/L 50 130 70-130129 0 2050<0.50 64.8 64.6Chlorobenzene ug/L 50 114 70-130112 2 2050<0.50 56.8 55.8Chloroethane ug/L 50 99 66-15298 1 2050<0.37 49.4 48.9Chloroform ug/L 50 110 70-130111 1 2050<2.5 55.0 55.7Chloromethane ug/L 50 83 44-15184 1 2050<0.50 41.6 41.9cis-1,2-Dichloroethene ug/L 50 93 70-130102 9 2050<0.26 46.4 50.9cis-1,3-Dichloropropene ug/L 50 92 70-13089 3 2050<0.50 45.8 44.3Dibromochloromethane ug/L 50 105 70-130104 1 2050<0.50 52.3 51.9Dichlorodifluoromethane ug/L 50 85 29-16085 0 2050<0.22 42.4 42.4Ethylbenzene ug/L 50 119 70-132117 2 2050<0.50 59.6 58.5Isopropylbenzene (Cumene) ug/L 50 124 70-130125 1 2050<0.14 62.2 62.5m&p-Xylene ug/L 100 118 70-131119 0 20100<1.0 118 119Methyl-tert-butyl ether ug/L 50 94 48-14393 2 2050<0.17 47.2 46.3Methylene Chloride ug/L 50 97 70-130104 6 2050<0.23 48.7 51.8o-Xylene ug/L 50 113 70-131114 1 2050<0.50 56.4 56.9Styrene ug/L 50 107 70-130102 6 2050<0.50 53.7 50.8Tetrachloroethene ug/L 50 116 70-130115 0 2050<0.50 57.9 57.7Toluene ug/L 50 112 70-130113 1 2050<0.50 56.2 56.7trans-1,2-Dichloroethene ug/L 50 104 70-132101 3 2050<0.26 52.0 50.5trans-1,3-Dichloropropene ug/L 50 100 70-13094 7 2050<0.23 50.0 46.8Trichloroethene ug/L 50 114 70-130115 0 2050<0.33 57.1 57.3Trichlorofluoromethane ug/L 50 111 50-153115 3 2050<0.18 55.5 57.4Vinyl chloride ug/L 50 91 60-15592 1 2050<0.18 45.6 46.14-Bromofluorobenzene (S) % 109 70-130107Dibromofluoromethane (S) % 106 70-130102Toluene-d8 (S) % 105 70-130105
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/20/2015 04:28 PM
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Page 12 of 16
#=QL#
QUALIFIERS
Pace Project No.:Project:
40118306023-6105-015 CP-SHOREHAM YD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Green BayPASI-G
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/20/2015 04:28 PM
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Page 13 of 16
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:Project:
40118306023-6105-015 CP-SHOREHAM YD
Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch
40118306001 MSV/29444071615-0700-200 EPA 826040118306002 MSV/29444SE EFFLUENT EPA 8260
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/20/2015 04:28 PM
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Page 14 of 16
Pag
e 15
of 1
6
(Please Print Clearly)
Company Name: G:,w8L A-s s:o: / ~S
Project Contact:
Phone:
Project Number:
Project Name:
Project State:
Sampled By (Print):
Sampled By (Sign):
PO#:
So).) b.-<-
Regulatory Program:
UPPER MIDWEST REGION
MN: 612-607-1700 WI: 920-469-24
Quote#:
Mail To Contact:
*Preservation Codes A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH
Mail To Company:
H=Sodium Bisulfate Solution
FILTERED? (YES/NO)
PRESERVATION (CODE)*
N
B
!=Sodium Thiosulfate J=Other Mail To Address:
Invoice To Contact:
Invoice To Company:
Invoice To Address:
Data Package Options (billable)
MS/llllSD D On your sample
(billable) D NOT needed on
your sample
Matrix Codes
D EPALevellll
D EPA Level IV
PACE LAB# CLIENT FIELD ID
07/bJS°-0700- ;2'70
A=Nr B =Biota C =Charcoal O=Oil S =Soil Sl=Slud e
Rush Turnaround Time Requested - Prelims (Rush TAT subject to approval/surcharge)
W!;Water OW= Drinking Water GW = Ground Water SW = Surface Water WW= Waste Water WP=Wi
Invoice To Phone:
CLIENT COMMENTS
Date Needed: e:
LAB COMMENTS Profile#
PACE Project No.
D--T~r=an~s~m~it~P~rarl~im~R~u=s~h~R~e~su=l=m~b~y~(co::;:;.:m~p~le~re~w~h~a~tLyo=u~w~a~n~t)~:~i-=:...--..:..::......::..::::;__ _____ -f./...:_i.,.::::.:_ __ -=:__,.[......J~--i---=-:::....:.__,l-'---J..-------1:/-L..:!-l-~J~j;___():..::t'f:::...!C>c::._;Recel~Temp= 1-E_m_a_1_1 #_1_:_-1-----------------1Reiinquished By:
11----'--h-on_e_:_+----------------IRelinquished By:
Samples on HOLD are subject to speclal pricing and releaae of liability
C019a(27 Jun2006)
Relinquished By:
Dale/Time: Received By: Date/Time:
DatefTime: Received By: Date/Time:
ot Intact
Page 16 of 16
12re~· Sample Condition Upon Receipt Pace Analytical Services, Inc.
1241 Bellevue Street, Suite 9 Green Bay, WI 54302
Project#:
/Client Name: Go lclu-courier: r Fed E_x_r__..u......_P_S......,!..._C_li-en_t_r __ P_a_c_e_::>_th_e_r_:_ -.... \JJU.:=_\\c.e.....,""------Tracking #: fi 2$1i0 ~ "Z..
Custody Seal on Cooler/Box Present: ~es - no Seals intact: -'Oyes r no
Custody Seal on Samples Present: r yes ISC::1io Seals intact: r yes - no
Packing Material: r Bubble Wrap JOBubble Bags r None r Other
W0#:40118306 1111111111111111111111 40118306
Thermometer Used CS\'2.--Sl.A? Type of Ice: e.> Blue Dry None )( Samples on ice, cooling process has begun
Cooler Temperature Uncorr: l"'L /Corr: 2 °L Biological Tissue is Frozen: r yes
Temp Blank Present: ryes ~o rno Person examining contents:
Temp should be above freezing to 6°C for all sample except Biota. Date: 1/ l'i1t5 Initials: 'ct!. Frozen Biota Samples should be received s o·c. Comments:
Chain of Custody Present: )lar'es 0No ON/A 1.
Chain of Custody Filled Out: ~s 0No ON/A 2.
Chain of Custody Relinquished: ~es 0No ON/A 3.
Sampler Name & Signature on COC: ~es 0No ON/A 4.
Samples Arrived within Hold Time: ~es 0No ON/A 5.
- VOA Samples frozen upon receipt OYes -o Date/Time:
Short Hold Time Analysis {<72hrl: OYes ~o ON/A 6.
Rush Tum Around Time Requested: OYes EfNo ON/A 7.
Sufficient Volume: ~es 0No ONIA 8.
Correct Containers Used: ~es ONo ON/A 9.
-Pace Containers Used: ~es 0No ONIA
-Pace IR Containers Used: OYes ~o ON/A
Containers Intact: ~$ 0No ON/A 10.
Filtered volume received for Dissolved tests 0Yes ONo lMtA 11.
Sample Labels match COC: }ia9es ONo ON/A 12.
-Includes date/time/ID/Analysis Matrix: w All containers needing preservation have been checked.
rHN03 r H2S04 rNaOH r NaOH +ZnAct (Non-Compliance noted in 13.) OYes ONo ~A 13. AU c:OntBrne.:S needing preserV"ation ire fOund to be -i;- - - - - - - - - - ~- -compliance with EPA recommendation. OYes ONo /A
(~92· H~s_2_:.~Qlj+Zn!-9~9.:. !::1~1:'~12) _______ -------exceptions· , coliform, TOC, TOX, TOH, ~ Initial when llab Std #ID of l~tre1 O&G, WIDR W, Phenolics, OTHER: s 0No completed preservative 1me:
Headspace in VOA Vials ( >6mm): OYes •o ON/A 14.
Trip Blank Present: l!Qes ONo ON/A 15.
Trip Blank Custody Seals Present ~es 0No ON/A
Pace Trip Blank Lot# (if purchased): L4 l 1 I 'i-"f U. .. Client Notification/ Resolution: If checked, see attached form for additional comments LJ
Project Manager Review: LlJ
F-GB-C-031-Rev.03 (9April2015) SCUR Form
#=CL#
August 25, 2015
LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40119971
40119971Project:Pace Project No.:
RE:
Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102
023-6105-015 CP-SHOREHAM YARD
Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on August 21, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Laurie [email protected] Manager
Enclosures
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without the written consent of Pace Analytical Services, Inc..
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Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:Project:
40119971023-6105-015 CP-SHOREHAM YARD
Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334
North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Wisconsin Certification #: 405132750
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Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:Project:
40119971023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID Matrix Date Collected Date Received
40119971001 082015-0800-200 Water 08/20/15 08:00 08/21/15 09:10
40119971002 SE EFFLUENT Water 08/20/15 11:05 08/21/15 09:10
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:Project:
40119971023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts
40119971001 082015-0800-200 EPA 8260 71 PASI-GLAP
40119971002 SE EFFLUENT EPA 8260 71 PASI-GLAP
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40119971023-6105-015 CP-SHOREHAM YARD
Sample: 082015-0800-200 Lab ID: 40119971001 Collected: 08/20/15 08:00 Received: 08/21/15 09:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 08/24/15 17:52 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 08/24/15 17:52 107-05-15.0 2.2 1Benzene <0.50 ug/L 08/24/15 17:52 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 08/24/15 17:52 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 08/24/15 17:52 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 08/24/15 17:52 75-27-41.0 0.50 1Bromoform <0.50 ug/L 08/24/15 17:52 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 08/24/15 17:52 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 08/24/15 17:52 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 08/24/15 17:52 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 08/24/15 17:52 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 08/24/15 17:52 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 08/24/15 17:52 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 08/24/15 17:52 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 08/24/15 17:52 75-00-31.0 0.37 1Chloroform <2.5 ug/L 08/24/15 17:52 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 08/24/15 17:52 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 08/24/15 17:52 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 08/24/15 17:52 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 08/24/15 17:52 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 08/24/15 17:52 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 08/24/15 17:52 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 08/24/15 17:52 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 08/24/15 17:52 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 08/24/15 17:52 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 08/24/15 17:52 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 08/24/15 17:52 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 08/24/15 17:52 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 08/24/15 17:52 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 08/24/15 17:52 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 08/24/15 17:52 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 08/24/15 17:52 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 08/24/15 17:52 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 08/24/15 17:52 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 08/24/15 17:52 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 08/24/15 17:52 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 08/24/15 17:52 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 08/24/15 17:52 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 08/24/15 17:52 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 08/24/15 17:52 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 08/24/15 17:52 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 08/24/15 17:52 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 08/24/15 17:52 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 08/24/15 17:52 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 08/24/15 17:52 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 08/24/15 17:52 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2015 04:07 PM
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Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40119971023-6105-015 CP-SHOREHAM YARD
Sample: 082015-0800-200 Lab ID: 40119971001 Collected: 08/20/15 08:00 Received: 08/21/15 09:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 08/24/15 17:52 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 08/24/15 17:52 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 08/24/15 17:52 103-65-11.0 0.50 1Styrene <0.50 ug/L 08/24/15 17:52 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 08/24/15 17:52 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 08/24/15 17:52 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 08/24/15 17:52 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 08/24/15 17:52 109-99-95.0 2.0 1Toluene <0.50 ug/L 08/24/15 17:52 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 08/24/15 17:52 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 08/24/15 17:52 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 08/24/15 17:52 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 08/24/15 17:52 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 08/24/15 17:52 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 08/24/15 17:52 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 08/24/15 17:52 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 08/24/15 17:52 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 08/24/15 17:52 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 08/24/15 17:52 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 08/24/15 17:52 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 08/24/15 17:52 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 08/24/15 17:52 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 110 % 08/24/15 17:52 460-00-470-130 1Dibromofluoromethane (S) 94 % 08/24/15 17:52 1868-53-770-130 1Toluene-d8 (S) 102 % 08/24/15 17:52 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2015 04:07 PM
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Page 6 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40119971023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40119971002 Collected: 08/20/15 11:05 Received: 08/21/15 09:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 08/25/15 09:40 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 08/25/15 09:40 107-05-15.0 2.2 1Benzene <0.50 ug/L 08/25/15 09:40 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 08/25/15 09:40 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 08/25/15 09:40 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 08/25/15 09:40 75-27-41.0 0.50 1Bromoform <0.50 ug/L 08/25/15 09:40 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 08/25/15 09:40 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 08/25/15 09:40 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 08/25/15 09:40 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 08/25/15 09:40 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 08/25/15 09:40 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 08/25/15 09:40 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 08/25/15 09:40 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 08/25/15 09:40 75-00-31.0 0.37 1Chloroform <2.5 ug/L 08/25/15 09:40 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 08/25/15 09:40 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 08/25/15 09:40 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 08/25/15 09:40 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 08/25/15 09:40 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 08/25/15 09:40 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 08/25/15 09:40 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 08/25/15 09:40 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 08/25/15 09:40 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 08/25/15 09:40 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 08/25/15 09:40 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 08/25/15 09:40 75-71-81.0 0.22 11,1-Dichloroethane 16.9 ug/L 08/25/15 09:40 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 08/25/15 09:40 107-06-21.0 0.17 11,1-Dichloroethene 4.6 ug/L 08/25/15 09:40 75-35-41.0 0.41 1cis-1,2-Dichloroethene 9.7 ug/L 08/25/15 09:40 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 08/25/15 09:40 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 08/25/15 09:40 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 08/25/15 09:40 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 08/25/15 09:40 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 08/25/15 09:40 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 08/25/15 09:40 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 08/25/15 09:40 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 08/25/15 09:40 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 08/25/15 09:40 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 08/25/15 09:40 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 08/25/15 09:40 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 08/25/15 09:40 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 08/25/15 09:40 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 08/25/15 09:40 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 08/25/15 09:40 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2015 04:07 PM
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Green Bay, WI 54302(920)469-2436
Page 7 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40119971023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40119971002 Collected: 08/20/15 11:05 Received: 08/21/15 09:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 08/25/15 09:40 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 08/25/15 09:40 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 08/25/15 09:40 103-65-11.0 0.50 1Styrene <0.50 ug/L 08/25/15 09:40 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 08/25/15 09:40 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 08/25/15 09:40 79-34-51.0 0.25 1Tetrachloroethene 61.3 ug/L 08/25/15 09:40 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 08/25/15 09:40 109-99-95.0 2.0 1Toluene <0.50 ug/L 08/25/15 09:40 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 08/25/15 09:40 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 08/25/15 09:40 120-82-15.0 2.2 11,1,1-Trichloroethane 15.2 ug/L 08/25/15 09:40 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 08/25/15 09:40 79-00-51.0 0.20 1Trichloroethene 6.4 ug/L 08/25/15 09:40 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 08/25/15 09:40 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 08/25/15 09:40 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 08/25/15 09:40 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 08/25/15 09:40 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 08/25/15 09:40 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 08/25/15 09:40 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 08/25/15 09:40 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 08/25/15 09:40 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 110 % 08/25/15 09:40 460-00-470-130 1Dibromofluoromethane (S) 96 % 08/25/15 09:40 1868-53-770-130 1Toluene-d8 (S) 98 % 08/25/15 09:40 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2015 04:07 PM
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Page 8 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40119971023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
MSV/29884EPA 8260
EPA 82608260 MSV
Associated Lab Samples: 40119971001, 40119971002
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1210208Associated Lab Samples: 40119971001, 40119971002
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 08/24/15 14:121,1,1-Trichloroethane ug/L <0.50 1.0 08/24/15 14:121,1,2,2-Tetrachloroethane ug/L <0.25 1.0 08/24/15 14:121,1,2-Trichloroethane ug/L <0.20 1.0 08/24/15 14:121,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 08/24/15 14:121,1-Dichloroethane ug/L <0.24 1.0 08/24/15 14:121,1-Dichloroethene ug/L <0.41 1.0 08/24/15 14:121,1-Dichloropropene ug/L <0.44 1.0 08/24/15 14:121,2,3-Trichlorobenzene ug/L <2.1 5.0 08/24/15 14:121,2,3-Trichloropropane ug/L <0.50 1.0 08/24/15 14:121,2,4-Trichlorobenzene ug/L <2.2 5.0 08/24/15 14:121,2,4-Trimethylbenzene ug/L <0.50 1.0 08/24/15 14:121,2-Dibromo-3-chloropropane ug/L <2.2 5.0 08/24/15 14:121,2-Dibromoethane (EDB) ug/L <0.18 1.0 08/24/15 14:121,2-Dichlorobenzene ug/L <0.50 1.0 08/24/15 14:121,2-Dichloroethane ug/L <0.17 1.0 08/24/15 14:121,2-Dichloropropane ug/L <0.23 1.0 08/24/15 14:121,3,5-Trimethylbenzene ug/L <0.50 1.0 08/24/15 14:121,3-Dichlorobenzene ug/L <0.50 1.0 08/24/15 14:121,3-Dichloropropane ug/L <0.50 1.0 08/24/15 14:121,4-Dichlorobenzene ug/L <0.50 1.0 08/24/15 14:122,2-Dichloropropane ug/L <0.48 1.0 08/24/15 14:122-Butanone (MEK) ug/L <3.0 20.0 08/24/15 14:122-Chlorotoluene ug/L <0.50 1.0 08/24/15 14:124-Chlorotoluene ug/L <0.21 1.0 08/24/15 14:124-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 08/24/15 14:12Acetone ug/L <3.0 20.0 08/24/15 14:12Allyl chloride ug/L <2.2 5.0 08/24/15 14:12Benzene ug/L <0.50 1.0 08/24/15 14:12Bromobenzene ug/L <0.23 1.0 08/24/15 14:12Bromochloromethane ug/L <0.34 1.0 08/24/15 14:12Bromodichloromethane ug/L <0.50 1.0 08/24/15 14:12Bromoform ug/L <0.50 1.0 08/24/15 14:12Bromomethane ug/L <2.4 5.0 08/24/15 14:12Carbon tetrachloride ug/L <0.50 1.0 08/24/15 14:12Chlorobenzene ug/L <0.50 1.0 08/24/15 14:12Chloroethane ug/L <0.37 1.0 08/24/15 14:12Chloroform ug/L <2.5 5.0 08/24/15 14:12Chloromethane ug/L <0.50 1.0 08/24/15 14:12cis-1,2-Dichloroethene ug/L <0.26 1.0 08/24/15 14:12cis-1,3-Dichloropropene ug/L <0.50 1.0 08/24/15 14:12
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2015 04:07 PM
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Page 9 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40119971023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1210208Associated Lab Samples: 40119971001, 40119971002
Matrix: Water
Analyzed
Dibromochloromethane ug/L <0.50 1.0 08/24/15 14:12Dibromomethane ug/L <0.43 1.0 08/24/15 14:12Dichlorodifluoromethane ug/L <0.22 1.0 08/24/15 14:12Dichlorofluoromethane ug/L <0.21 1.0 08/24/15 14:12Diethyl ether (Ethyl ether) ug/L <2.2 5.0 08/24/15 14:12Ethylbenzene ug/L <0.50 1.0 08/24/15 14:12Hexachloro-1,3-butadiene ug/L <2.1 5.0 08/24/15 14:12Isopropylbenzene (Cumene) ug/L <0.14 1.0 08/24/15 14:12m&p-Xylene ug/L <1.0 2.0 08/24/15 14:12Methyl-tert-butyl ether ug/L <0.17 1.0 08/24/15 14:12Methylene Chloride ug/L <0.23 1.0 08/24/15 14:12n-Butylbenzene ug/L <0.50 1.0 08/24/15 14:12n-Propylbenzene ug/L <0.50 1.0 08/24/15 14:12Naphthalene ug/L <2.5 5.0 08/24/15 14:12o-Xylene ug/L <0.50 1.0 08/24/15 14:12p-Isopropyltoluene ug/L <0.50 1.0 08/24/15 14:12sec-Butylbenzene ug/L <2.2 5.0 08/24/15 14:12Styrene ug/L <0.50 1.0 08/24/15 14:12tert-Butylbenzene ug/L <0.18 1.0 08/24/15 14:12Tetrachloroethene ug/L <0.50 1.0 08/24/15 14:12Tetrahydrofuran ug/L <2.0 5.0 08/24/15 14:12Toluene ug/L <0.50 1.0 08/24/15 14:12trans-1,2-Dichloroethene ug/L <0.26 1.0 08/24/15 14:12trans-1,3-Dichloropropene ug/L <0.23 1.0 08/24/15 14:12Trichloroethene ug/L <0.33 1.0 08/24/15 14:12Trichlorofluoromethane ug/L <0.18 1.0 08/24/15 14:12Vinyl chloride ug/L <0.18 1.0 08/24/15 14:124-Bromofluorobenzene (S) % 113 70-130 08/24/15 14:12Dibromofluoromethane (S) % 93 70-130 08/24/15 14:12Toluene-d8 (S) % 101 70-130 08/24/15 14:12
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1210209LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1210210
1,1,1-Trichloroethane ug/L 57.150 114 70-13011155.3 3 201,1,2,2-Tetrachloroethane ug/L 49.550 99 70-13010050.0 1 201,1,2-Trichloroethane ug/L 56.550 113 70-13011055.2 2 201,1,2-Trichlorotrifluoroethane ug/L 56.550 113 50-15011457.0 1 201,1-Dichloroethane ug/L 54.550 109 70-13010853.9 1 201,1-Dichloroethene ug/L 49.350 99 70-1309547.6 4 201,2,4-Trichlorobenzene ug/L 53.550 107 70-13010753.4 0 201,2-Dibromo-3-chloropropane ug/L 49.450 99 50-15010251.1 3 201,2-Dibromoethane (EDB) ug/L 55.750 111 70-13010954.6 2 201,2-Dichlorobenzene ug/L 48.650 97 70-1309748.6 0 20
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2015 04:07 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40119971023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1210209LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD
% Rec RPDMaxRPD
LCSDResult
1210210
1,2-Dichloroethane ug/L 57.050 114 70-13111356.4 1 201,2-Dichloropropane ug/L 55.150 110 70-13010954.5 1 201,3-Dichlorobenzene ug/L 49.150 98 70-1309848.8 1 201,4-Dichlorobenzene ug/L 48.950 98 70-13010050.0 2 20Benzene ug/L 49.350 99 70-1309648.0 3 20Bromodichloromethane ug/L 60.250 120 70-13011758.3 3 20Bromoform ug/L 60.250 120 68-13011859.0 2 20Bromomethane ug/L 37.650 75 38-1377839.2 4 20Carbon tetrachloride ug/L 58.750 117 70-13011457.1 3 20Chlorobenzene ug/L 51.650 103 70-13010050.2 3 20Chloroethane ug/L 47.250 94 70-1369045.2 4 20Chloroform ug/L 53.850 108 70-13010552.6 2 20Chloromethane ug/L 47.750 95 48-1449145.4 5 20cis-1,2-Dichloroethene ug/L 48.950 98 70-1309447.2 4 20cis-1,3-Dichloropropene ug/L 51.650 103 70-13010050.0 3 20Dibromochloromethane ug/L 55.750 111 70-13011054.8 2 20Dichlorodifluoromethane ug/L 58.850 118 33-15711758.3 1 20Ethylbenzene ug/L 59.050 118 70-13211658.2 1 20Isopropylbenzene (Cumene) ug/L 56.550 113 70-13011255.9 1 20m&p-Xylene ug/L 109100 109 70-131107107 2 20Methyl-tert-butyl ether ug/L 52.750 105 48-14110150.4 4 20Methylene Chloride ug/L 48.850 98 70-1309547.4 3 20o-Xylene ug/L 53.450 107 70-13110452.2 2 20Styrene ug/L 54.950 110 70-13010753.7 2 20Tetrachloroethene ug/L 62.950 126 70-13012462.2 1 20Toluene ug/L 56.750 113 70-13011256.0 1 20trans-1,2-Dichloroethene ug/L 49.950 100 70-1309648.1 4 20trans-1,3-Dichloropropene ug/L 50.850 102 70-1309849.2 3 20Trichloroethene ug/L 60.150 120 70-13011959.3 1 20Trichlorofluoromethane ug/L 67.650 135 50-15013265.8 3 20Vinyl chloride ug/L 48.050 96 65-1429145.6 5 204-Bromofluorobenzene (S) % 121 70-130120Dibromofluoromethane (S) % 98 70-13099Toluene-d8 (S) % 101 70-130102
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1210302MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40119943004
1210303
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 50 101 70-130102 0 2050<0.50 50.7 50.91,1,2,2-Tetrachloroethane ug/L 50 94 70-13096 2 2050<0.25 47.1 47.91,1,2-Trichloroethane ug/L 50 104 70-130105 0 2050<0.20 52.1 52.31,1,2-Trichlorotrifluoroethane ug/L 50 92 50-15193 1 2050<0.81 45.9 46.31,1-Dichloroethane ug/L 50 103 70-134104 0 2050<0.24 51.7 51.91,1-Dichloroethene ug/L 50 86 70-13985 0 2050<0.41 42.8 42.6
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 11 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40119971023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1210302MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40119943004
1210303
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,2,4-Trichlorobenzene ug/L 50 100 70-13098 1 2050<2.2 50.3 49.71,2-Dibromo-3-chloropropane
ug/L 50 96 50-15094 2 2050<2.2 48.2 47.1
1,2-Dibromoethane (EDB) ug/L 50 106 70-130105 1 2050<0.18 52.8 52.41,2-Dichlorobenzene ug/L 50 93 70-13095 2 2050<0.50 46.7 47.61,2-Dichloroethane ug/L 50 111 70-132108 2 20500.61J 55.9 54.91,2-Dichloropropane ug/L 50 100 70-130104 4 2050<0.23 50.1 52.21,3-Dichlorobenzene ug/L 50 94 70-13095 1 2050<0.50 47.0 47.71,4-Dichlorobenzene ug/L 50 95 70-13094 2 2050<0.50 47.8 47.1Benzene ug/L 50 92 70-13092 0 20500.82J 46.9 47.0Bromodichloromethane ug/L 50 114 70-132113 1 2050<0.50 57.1 56.5Bromoform ug/L 50 111 68-130111 0 2050<0.50 55.3 55.3Bromomethane ug/L 50 76 38-14179 3 2050<2.4 38.0 39.4Carbon tetrachloride ug/L 50 102 70-130102 0 2050<0.50 50.8 51.0Chlorobenzene ug/L 50 96 70-13095 0 2050<0.50 47.9 47.7Chloroethane ug/L 50 85 66-15285 0 2050<0.37 42.4 42.3Chloroform ug/L 50 102 70-130102 0 2050<2.5 51.1 50.9Chloromethane ug/L 50 88 44-15189 2 2050<0.50 43.8 44.7cis-1,2-Dichloroethene ug/L 50 91 70-13092 1 2050<0.26 45.4 46.0cis-1,3-Dichloropropene ug/L 50 95 70-13097 1 2050<0.50 47.7 48.3Dibromochloromethane ug/L 50 104 70-130103 2 2050<0.50 52.2 51.4Dichlorodifluoromethane ug/L 50 91 29-16095 3 2050<0.22 45.7 47.3Ethylbenzene ug/L 50 108 70-132107 1 2050<0.50 54.1 53.5Isopropylbenzene (Cumene) ug/L 50 100 70-130102 1 20500.66J 50.8 51.4m&p-Xylene ug/L 100 98 70-131100 2 20100<1.0 98.6 100Methyl-tert-butyl ether ug/L 50 100 48-143100 0 2050<0.17 49.8 50.0Methylene Chloride ug/L 50 93 70-13092 1 2050<0.23 46.4 46.2o-Xylene ug/L 50 98 70-13198 0 2050<0.50 49.0 48.8Styrene ug/L 50 103 70-130102 1 2050<0.50 51.6 50.9Tetrachloroethene ug/L 50 107 70-130109 2 2050<0.50 53.6 54.5Toluene ug/L 50 103 70-130103 0 2050<0.50 51.6 51.8trans-1,2-Dichloroethene ug/L 50 90 70-13290 0 2050<0.26 45.2 45.2trans-1,3-Dichloropropene ug/L 50 91 70-13092 1 2050<0.23 45.6 45.9Trichloroethene ug/L 50 109 70-130111 2 2050<0.33 54.5 55.3Trichlorofluoromethane ug/L 50 113 50-153115 2 2050<0.18 56.6 57.5Vinyl chloride ug/L 50 81 60-15584 4 2050<0.18 40.4 42.04-Bromofluorobenzene (S) % pH123 70-130121Dibromofluoromethane (S) % 100 70-13099Toluene-d8 (S) % 99 70-130100
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2015 04:07 PM
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Page 12 of 16
#=QL#
QUALIFIERS
Pace Project No.:Project:
40119971023-6105-015 CP-SHOREHAM YARD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Green BayPASI-G
ANALYTE QUALIFIERS
Post-analysis pH measurement indicates insufficient VOA sample preservation.pH
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:Project:
40119971023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch
40119971001 MSV/29884082015-0800-200 EPA 826040119971002 MSV/29884SE EFFLUENT EPA 8260
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Page 14 of 16
Pag
e 15
of 1
6(Please Print Clearly) TREGIO_N~ / UPPER lllllDWES.. 0-469-243(_) /'(' evt of, '.". l:).)
'~ ... -Company Name: I I .:0 lo{ e r Ass Oct' q te Branch/Location: I /VI r ~vfe ( . tJ Project Contact: I ..41 l< b "") 2:.o l { Phone: I '\. 7 .) - 6 't 'J - l '\ l t.. Project Number: 10 L.3 - b ( () $ - 0 l 5 Project Name:
Project State:
Sampled By (Print):
Sampled By (Sign):
PO#: L-t 2-0"L Regulatory Program:
www.peoelabaoom
CHAIN OF CUSTODY •preservation Codes
A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH
H=Sodium Bisulfate Solution
FILTERED? (YES/NO)
PRESERVATION (CODE)*
!=Sodium Thiosulfate J=Other
Data Package Options (billable)
MS/MSD Matrix Codes
DEPA Level Ill
D EPA Level IV
A=!>jr B =Biota C =Charcoal O=OH
W=Water
C\Cfl' -Quote#:
Mail To Contact:
Mail To Company:
llllail To Address:
Invoice To Contact:
Invoice To Company:
Invoice To Address:
Invoice To Phone: D On your sample
(billable) D NOT needed on
your sample s =Soil Sl=SI
OW= Drinking Water GW = Ground Water SW = Surface Water WW= Waste Water WP=Wi CLIENT
COMMENTS LAB COMMENTS Profile#
PACE LAB# CLIENT FIELD ID
(9g~ 15" -&~e><9 -26>6Jl 9./11J/1 SG Eff-111 (111- 1'6/UV/' tW)I w
Rush Turnaround Time Requested - Prelims PACE Project No.
(Rush TAT subject to approval/surcharge) tJ 0t la1h Date Needed: 10\ \ <t'1 f $•
Transmit Prelim Rush Results by (complete what you want): 0 ~ Receipt Temp= C / Emall#1: • " Emall #2: Samp e Receipt pH
Telephone: Relinquished By: Date/Time: Received By: Date/Time: OK I Adjusted
Fax: Cooler Custody Seal
Samples on HOLD are subject to
special pricing and release of liability
C019a(27Jun2006)
Relinquished By: Date/Time: Received By: Date/Time: Present I Not Present Intact I Not Intact
Version GJ'f-06714/06
Page 16 of 16
Samp.le Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9
Green Bay, WI 54302
Project#:
Courier: r Fed Ex
Tracking#: __ ..lill:;.....,,__11--.,_~..c...-..,..--------Custody Seal on Cooler/Box Present: - no Seals intact: ~es r no
W0#:40119971 111111 1111111111111111 40119971
Custody Seal on Sa"fl~ Present: r yes. r-J4,o Seals intact: r yes - no
Packing Material: IJ'Babble Wrap ~bble Bags r None r Other .
Thermometer Used ~ q<J' Type of lce:{w;L Blue Dry None i1"$imples on ice, cooling process has begun
Cooler Temperature Uncorr: -q /Corr: Y ~gical Tissue is Frozen: r yes
Temp Blank Present: r yes rf{!to
Temp should be above freezing to 6°C for all sample except Biota. Frozen Biota Samples should be received s o•c. Comments:
Chain of Custody Present:
Chain of Custody Filled Out:
Chain of Custody Relinquished:
Samoler Name & Signature on COC:
Samples Arrived within Hold Time:
- VOA Samples frozen upon receipt
Short Hold Time Analvsls (<72hr):
Rush Turn Around Time Requested:
Sufficient Volume:
Correct Containers Used:
-Pace Containers Used:
-Pace IR Containers Used:
Containers Intact:
Filtered volume received for Dissolved tests
Sample Labels match COC:
-Includes date/time/ID/Analysis Matrix:
rb.._es ONo ON/A 1.
rl.ves ONo ON/A 2.
lrWes ONo ON/A 3.
~es ONo ON/A 4.
~es ONo ON/A 5.
OYes ONo Date/Time:
0Yes i;tJNo ON/A 6.
Oves !&No ON/A 7.
~es ONo ON/A 8.
ip¥es ONo ON/A 9.
~es ONo ON/A
0Yes ONo ~
~ ONo ON/A 10.
0Yes ONo $A 11.
ON/A 12.
r no Person wmining C9!JteAts: Date: Y--7--.r-7~ Initials: :-"'\
All conta.iners needing preservation have been checked. • ~ (Non-Compliance noted in 13.) 0Yes ONo NIA 13. r HN03 r H2S04 r NaOH r NaOH +ZnAct
--------------------------------- - -All containers needing preservation are found to be in compDance with EPA recommendation. Oves ONo 'fJi:uA (HN03, H~s2; NaOH+ZnAct ~. NaOH ~12) ;;Ptk>;;;~· ;;;,ilf~~ foC: -To>Uo.:i.- - - - --- --~ - - -- - - - initial when. O&G, WIDROW, Phenolics, OTHER: ~Yes 0No completed
Headsoace in VOA Vials ( >6mm): Ovc:is ~ ON/A 14.
Trip Blank Present: Oves ~ :1;:A 15.
Trip Blank Custody Seals Present OYes 0No · ~ -
Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution:
Person Contacted: Date!Time:
!Lab Std #ID of . preservative 1
1u;:ue1 Time:
If checked, see attached form for additional comments LJ
--------------------------- ------------------Comments/ Resolution: ----------------------------------------------------------------------------------
Proj~ct Manager Review: Date: __ 8'"")?Jl""\Plil1( ____ _
F-GB-C-031-Rev.03 (9April2015) SCUR Form
#=CL#
September 22, 2015
LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40121128
40121128Project:Pace Project No.:
RE:
Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102
023-6105-015 CP-SHOREHAM YARD
Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on September 16, 2015.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Laurie [email protected] Manager
Enclosures
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 1 of 29
#=CP#
CERTIFICATIONS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334
North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Wisconsin Certification #: 405132750
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 2 of 29
#=SS#
SAMPLE SUMMARY
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID Matrix Date Collected Date Received
40121128001 091515-0800-200 Water 09/15/15 08:00 09/16/15 08:50
40121128002 RW07-39-SP-0915-100 Water 09/15/15 16:20 09/16/15 08:50
40121128003 RW07-40-SP-0915-100 Water 09/15/15 16:25 09/16/15 08:50
40121128004 RW06-28-I-0915-100 Water 09/15/15 16:30 09/16/15 08:50
40121128005 RW07-38-I-0915-100 Water 09/15/15 16:15 09/16/15 08:50
40121128006 RW06-27-BR-0915-100 Water 09/15/15 16:35 09/16/15 08:50
40121128007 SE EFFLUENT Water 09/15/15 16:10 09/16/15 08:50
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 3 of 29
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts
40121128001 091515-0800-200 EPA 8260 71 PASI-GLAP
40121128002 RW07-39-SP-0915-100 EPA 8260 71 PASI-GLAP
40121128003 RW07-40-SP-0915-100 EPA 8260 71 PASI-GLAP
40121128004 RW06-28-I-0915-100 EPA 8260 71 PASI-GLAP
40121128005 RW07-38-I-0915-100 EPA 8260 71 PASI-GLAP
40121128006 RW06-27-BR-0915-100 EPA 8260 71 PASI-GLAP
40121128007 SE EFFLUENT EPA 8260 71 PASI-GLAP
SM 2540D 1 PASI-GDDY
SM 4500-H+B 1 PASI-GDEY
EPA 410.4 1 PASI-GTJJ
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 4 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: 091515-0800-200 Lab ID: 40121128001 Collected: 09/15/15 08:00 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 09/18/15 16:00 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 09/18/15 16:00 107-05-15.0 2.2 1Benzene <0.50 ug/L 09/18/15 16:00 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 09/18/15 16:00 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 09/18/15 16:00 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 09/18/15 16:00 75-27-41.0 0.50 1Bromoform <0.50 ug/L 09/18/15 16:00 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 09/18/15 16:00 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 09/18/15 16:00 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 09/18/15 16:00 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 09/18/15 16:00 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 09/18/15 16:00 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 09/18/15 16:00 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 09/18/15 16:00 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 09/18/15 16:00 75-00-31.0 0.37 1Chloroform <2.5 ug/L 09/18/15 16:00 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 09/18/15 16:00 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 09/18/15 16:00 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 09/18/15 16:00 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 09/18/15 16:00 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 09/18/15 16:00 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 09/18/15 16:00 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 09/18/15 16:00 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 09/18/15 16:00 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 09/18/15 16:00 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 09/18/15 16:00 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 09/18/15 16:00 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 09/18/15 16:00 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 09/18/15 16:00 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 09/18/15 16:00 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 09/18/15 16:00 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 09/18/15 16:00 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 09/18/15 16:00 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 09/18/15 16:00 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 09/18/15 16:00 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 09/18/15 16:00 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 09/18/15 16:00 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 09/18/15 16:00 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 09/18/15 16:00 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 09/18/15 16:00 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 09/18/15 16:00 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 09/18/15 16:00 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 09/18/15 16:00 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 09/18/15 16:00 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 09/18/15 16:00 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 09/18/15 16:00 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
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Page 5 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: 091515-0800-200 Lab ID: 40121128001 Collected: 09/15/15 08:00 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 09/18/15 16:00 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 09/18/15 16:00 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 09/18/15 16:00 103-65-11.0 0.50 1Styrene <0.50 ug/L 09/18/15 16:00 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 09/18/15 16:00 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 09/18/15 16:00 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 09/18/15 16:00 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 09/18/15 16:00 109-99-95.0 2.0 1Toluene <0.50 ug/L 09/18/15 16:00 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 09/18/15 16:00 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 09/18/15 16:00 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 09/18/15 16:00 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 09/18/15 16:00 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 09/18/15 16:00 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 09/18/15 16:00 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 09/18/15 16:00 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 09/18/15 16:00 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 09/18/15 16:00 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 09/18/15 16:00 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 09/18/15 16:00 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 09/18/15 16:00 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 09/18/15 16:00 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 103 % 09/18/15 16:00 460-00-470-130 1Dibromofluoromethane (S) 88 % 09/18/15 16:00 1868-53-770-130 1Toluene-d8 (S) 101 % 09/18/15 16:00 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 6 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: RW07-39-SP-0915-100 Lab ID: 40121128002 Collected: 09/15/15 16:20 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 09/18/15 09:05 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 09/18/15 09:05 107-05-15.0 2.2 1Benzene <0.50 ug/L 09/18/15 09:05 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 09/18/15 09:05 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 09/18/15 09:05 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 09/18/15 09:05 75-27-41.0 0.50 1Bromoform <0.50 ug/L 09/18/15 09:05 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 09/18/15 09:05 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 09/18/15 09:05 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 09/18/15 09:05 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 09/18/15 09:05 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 09/18/15 09:05 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 09/18/15 09:05 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 09/18/15 09:05 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 09/18/15 09:05 75-00-31.0 0.37 1Chloroform <2.5 ug/L 09/18/15 09:05 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 09/18/15 09:05 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 09/18/15 09:05 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 09/18/15 09:05 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 09/18/15 09:05 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 09/18/15 09:05 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 09/18/15 09:05 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 09/18/15 09:05 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 09/18/15 09:05 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 09/18/15 09:05 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 09/18/15 09:05 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 09/18/15 09:05 75-71-81.0 0.22 11,1-Dichloroethane 60.7 ug/L 09/18/15 09:05 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 09/18/15 09:05 107-06-21.0 0.17 11,1-Dichloroethene 24.5 ug/L 09/18/15 09:05 75-35-41.0 0.41 1cis-1,2-Dichloroethene 33.6 ug/L 09/18/15 09:05 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 09/18/15 09:05 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 09/18/15 09:05 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 09/18/15 09:05 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 09/18/15 09:05 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 09/18/15 09:05 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 09/18/15 09:05 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 09/18/15 09:05 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 09/18/15 09:05 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 09/18/15 09:05 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 09/18/15 09:05 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 09/18/15 09:05 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 09/18/15 09:05 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 09/18/15 09:05 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 09/18/15 09:05 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 09/18/15 09:05 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 7 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: RW07-39-SP-0915-100 Lab ID: 40121128002 Collected: 09/15/15 16:20 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 09/18/15 09:05 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 09/18/15 09:05 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 09/18/15 09:05 103-65-11.0 0.50 1Styrene <0.50 ug/L 09/18/15 09:05 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 09/18/15 09:05 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 09/18/15 09:05 79-34-51.0 0.25 1Tetrachloroethene 264 ug/L 09/18/15 09:05 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 09/18/15 09:05 109-99-95.0 2.0 1Toluene <0.50 ug/L 09/18/15 09:05 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 09/18/15 09:05 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 09/18/15 09:05 120-82-15.0 2.2 11,1,1-Trichloroethane 145 ug/L 09/18/15 09:05 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 09/18/15 09:05 79-00-51.0 0.20 1Trichloroethene 14.4 ug/L 09/18/15 09:05 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 09/18/15 09:05 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 09/18/15 09:05 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 09/18/15 09:05 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 09/18/15 09:05 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 09/18/15 09:05 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 09/18/15 09:05 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 09/18/15 09:05 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 09/18/15 09:05 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 104 % 09/18/15 09:05 460-00-470-130 1Dibromofluoromethane (S) 100 % 09/18/15 09:05 1868-53-770-130 1Toluene-d8 (S) 100 % 09/18/15 09:05 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 8 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: RW07-40-SP-0915-100 Lab ID: 40121128003 Collected: 09/15/15 16:25 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 09/18/15 09:27 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 09/18/15 09:27 107-05-15.0 2.2 1Benzene <0.50 ug/L 09/18/15 09:27 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 09/18/15 09:27 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 09/18/15 09:27 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 09/18/15 09:27 75-27-41.0 0.50 1Bromoform <0.50 ug/L 09/18/15 09:27 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 09/18/15 09:27 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 09/18/15 09:27 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 09/18/15 09:27 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 09/18/15 09:27 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 09/18/15 09:27 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 09/18/15 09:27 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 09/18/15 09:27 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 09/18/15 09:27 75-00-31.0 0.37 1Chloroform <2.5 ug/L 09/18/15 09:27 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 09/18/15 09:27 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 09/18/15 09:27 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 09/18/15 09:27 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 09/18/15 09:27 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 09/18/15 09:27 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 09/18/15 09:27 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 09/18/15 09:27 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 09/18/15 09:27 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 09/18/15 09:27 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 09/18/15 09:27 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 09/18/15 09:27 75-71-81.0 0.22 11,1-Dichloroethane 2.5 ug/L 09/18/15 09:27 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 09/18/15 09:27 107-06-21.0 0.17 11,1-Dichloroethene 1.6 ug/L 09/18/15 09:27 75-35-41.0 0.41 1cis-1,2-Dichloroethene 1.6 ug/L 09/18/15 09:27 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 09/18/15 09:27 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 09/18/15 09:27 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 09/18/15 09:27 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 09/18/15 09:27 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 09/18/15 09:27 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 09/18/15 09:27 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 09/18/15 09:27 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 09/18/15 09:27 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 09/18/15 09:27 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 09/18/15 09:27 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 09/18/15 09:27 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 09/18/15 09:27 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 09/18/15 09:27 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 09/18/15 09:27 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 09/18/15 09:27 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 9 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: RW07-40-SP-0915-100 Lab ID: 40121128003 Collected: 09/15/15 16:25 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 09/18/15 09:27 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 09/18/15 09:27 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 09/18/15 09:27 103-65-11.0 0.50 1Styrene <0.50 ug/L 09/18/15 09:27 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 09/18/15 09:27 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 09/18/15 09:27 79-34-51.0 0.25 1Tetrachloroethene 52.0 ug/L 09/18/15 09:27 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 09/18/15 09:27 109-99-95.0 2.0 1Toluene <0.50 ug/L 09/18/15 09:27 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 09/18/15 09:27 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 09/18/15 09:27 120-82-15.0 2.2 11,1,1-Trichloroethane 8.2 ug/L 09/18/15 09:27 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 09/18/15 09:27 79-00-51.0 0.20 1Trichloroethene 2.6 ug/L 09/18/15 09:27 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 09/18/15 09:27 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 09/18/15 09:27 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 09/18/15 09:27 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 09/18/15 09:27 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 09/18/15 09:27 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 09/18/15 09:27 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 09/18/15 09:27 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 09/18/15 09:27 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 103 % 09/18/15 09:27 460-00-470-130 1Dibromofluoromethane (S) 97 % 09/18/15 09:27 1868-53-770-130 1Toluene-d8 (S) 100 % 09/18/15 09:27 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 10 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: RW06-28-I-0915-100 Lab ID: 40121128004 Collected: 09/15/15 16:30 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone 19.7J ug/L 09/18/15 09:49 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 09/18/15 09:49 107-05-15.0 2.2 1Benzene <0.50 ug/L 09/18/15 09:49 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 09/18/15 09:49 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 09/18/15 09:49 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 09/18/15 09:49 75-27-41.0 0.50 1Bromoform <0.50 ug/L 09/18/15 09:49 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 09/18/15 09:49 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 09/18/15 09:49 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 09/18/15 09:49 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 09/18/15 09:49 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 09/18/15 09:49 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 09/18/15 09:49 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 09/18/15 09:49 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 09/18/15 09:49 75-00-31.0 0.37 1Chloroform <2.5 ug/L 09/18/15 09:49 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 09/18/15 09:49 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 09/18/15 09:49 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 09/18/15 09:49 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 09/18/15 09:49 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 09/18/15 09:49 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 09/18/15 09:49 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 09/18/15 09:49 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 09/18/15 09:49 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 09/18/15 09:49 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 09/18/15 09:49 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 09/18/15 09:49 75-71-81.0 0.22 11,1-Dichloroethane 9.3 ug/L 09/18/15 09:49 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 09/18/15 09:49 107-06-21.0 0.17 11,1-Dichloroethene 1.9 ug/L 09/18/15 09:49 75-35-41.0 0.41 1cis-1,2-Dichloroethene 2.6 ug/L 09/18/15 09:49 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 09/18/15 09:49 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 09/18/15 09:49 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 09/18/15 09:49 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 09/18/15 09:49 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 09/18/15 09:49 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 09/18/15 09:49 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 09/18/15 09:49 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 09/18/15 09:49 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 09/18/15 09:49 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 09/18/15 09:49 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 09/18/15 09:49 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 09/18/15 09:49 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 09/18/15 09:49 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 09/18/15 09:49 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 09/18/15 09:49 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 11 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: RW06-28-I-0915-100 Lab ID: 40121128004 Collected: 09/15/15 16:30 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 09/18/15 09:49 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 09/18/15 09:49 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 09/18/15 09:49 103-65-11.0 0.50 1Styrene <0.50 ug/L 09/18/15 09:49 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 09/18/15 09:49 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 09/18/15 09:49 79-34-51.0 0.25 1Tetrachloroethene 13.2 ug/L 09/18/15 09:49 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 09/18/15 09:49 109-99-95.0 2.0 1Toluene <0.50 ug/L 09/18/15 09:49 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 09/18/15 09:49 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 09/18/15 09:49 120-82-15.0 2.2 11,1,1-Trichloroethane 6.6 ug/L 09/18/15 09:49 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 09/18/15 09:49 79-00-51.0 0.20 1Trichloroethene 1.4 ug/L 09/18/15 09:49 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 09/18/15 09:49 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 09/18/15 09:49 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 09/18/15 09:49 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 09/18/15 09:49 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 09/18/15 09:49 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 09/18/15 09:49 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 09/18/15 09:49 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 09/18/15 09:49 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 102 % 09/18/15 09:49 460-00-470-130 1Dibromofluoromethane (S) 95 % 09/18/15 09:49 1868-53-770-130 1Toluene-d8 (S) 102 % 09/18/15 09:49 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 12 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: RW07-38-I-0915-100 Lab ID: 40121128005 Collected: 09/15/15 16:15 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 09/18/15 10:11 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 09/18/15 10:11 107-05-15.0 2.2 1Benzene <0.50 ug/L 09/18/15 10:11 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 09/18/15 10:11 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 09/18/15 10:11 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 09/18/15 10:11 75-27-41.0 0.50 1Bromoform <0.50 ug/L 09/18/15 10:11 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 09/18/15 10:11 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 09/18/15 10:11 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 09/18/15 10:11 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 09/18/15 10:11 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 09/18/15 10:11 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 09/18/15 10:11 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 09/18/15 10:11 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 09/18/15 10:11 75-00-31.0 0.37 1Chloroform <2.5 ug/L 09/18/15 10:11 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 09/18/15 10:11 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 09/18/15 10:11 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 09/18/15 10:11 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 09/18/15 10:11 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 09/18/15 10:11 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 09/18/15 10:11 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 09/18/15 10:11 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 09/18/15 10:11 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 09/18/15 10:11 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 09/18/15 10:11 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 09/18/15 10:11 75-71-81.0 0.22 11,1-Dichloroethane 14.1 ug/L 09/18/15 10:11 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 09/18/15 10:11 107-06-21.0 0.17 11,1-Dichloroethene 3.6 ug/L 09/18/15 10:11 75-35-41.0 0.41 1cis-1,2-Dichloroethene 6.5 ug/L 09/18/15 10:11 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 09/18/15 10:11 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 09/18/15 10:11 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 09/18/15 10:11 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 09/18/15 10:11 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 09/18/15 10:11 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 09/18/15 10:11 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 09/18/15 10:11 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 09/18/15 10:11 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 09/18/15 10:11 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 09/18/15 10:11 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 09/18/15 10:11 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 09/18/15 10:11 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 09/18/15 10:11 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 09/18/15 10:11 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 09/18/15 10:11 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 13 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: RW07-38-I-0915-100 Lab ID: 40121128005 Collected: 09/15/15 16:15 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 09/18/15 10:11 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 09/18/15 10:11 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 09/18/15 10:11 103-65-11.0 0.50 1Styrene <0.50 ug/L 09/18/15 10:11 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 09/18/15 10:11 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 09/18/15 10:11 79-34-51.0 0.25 1Tetrachloroethene 56.8 ug/L 09/18/15 10:11 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 09/18/15 10:11 109-99-95.0 2.0 1Toluene <0.50 ug/L 09/18/15 10:11 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 09/18/15 10:11 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 09/18/15 10:11 120-82-15.0 2.2 11,1,1-Trichloroethane 8.9 ug/L 09/18/15 10:11 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 09/18/15 10:11 79-00-51.0 0.20 1Trichloroethene 5.3 ug/L 09/18/15 10:11 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 09/18/15 10:11 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 09/18/15 10:11 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 09/18/15 10:11 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 09/18/15 10:11 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 09/18/15 10:11 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 09/18/15 10:11 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 09/18/15 10:11 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 09/18/15 10:11 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 103 % 09/18/15 10:11 460-00-470-130 1Dibromofluoromethane (S) 96 % 09/18/15 10:11 1868-53-770-130 1Toluene-d8 (S) 120 % 09/18/15 10:11 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 14 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: RW06-27-BR-0915-100 Lab ID: 40121128006 Collected: 09/15/15 16:35 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 09/18/15 10:32 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 09/18/15 10:32 107-05-15.0 2.2 1Benzene <0.50 ug/L 09/18/15 10:32 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 09/18/15 10:32 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 09/18/15 10:32 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 09/18/15 10:32 75-27-41.0 0.50 1Bromoform <0.50 ug/L 09/18/15 10:32 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 09/18/15 10:32 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 09/18/15 10:32 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 09/18/15 10:32 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 09/18/15 10:32 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 09/18/15 10:32 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 09/18/15 10:32 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 09/18/15 10:32 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 09/18/15 10:32 75-00-31.0 0.37 1Chloroform <2.5 ug/L 09/18/15 10:32 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 09/18/15 10:32 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 09/18/15 10:32 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 09/18/15 10:32 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 09/18/15 10:32 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 09/18/15 10:32 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 09/18/15 10:32 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 09/18/15 10:32 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 09/18/15 10:32 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 09/18/15 10:32 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 09/18/15 10:32 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 09/18/15 10:32 75-71-81.0 0.22 11,1-Dichloroethane 14.6 ug/L 09/18/15 10:32 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 09/18/15 10:32 107-06-21.0 0.17 11,1-Dichloroethene 4.2 ug/L 09/18/15 10:32 75-35-41.0 0.41 1cis-1,2-Dichloroethene 16.7 ug/L 09/18/15 10:32 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 09/18/15 10:32 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 09/18/15 10:32 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 09/18/15 10:32 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 09/18/15 10:32 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 09/18/15 10:32 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 09/18/15 10:32 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 09/18/15 10:32 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 09/18/15 10:32 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 09/18/15 10:32 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 09/18/15 10:32 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 09/18/15 10:32 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 09/18/15 10:32 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 09/18/15 10:32 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 09/18/15 10:32 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 09/18/15 10:32 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 15 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: RW06-27-BR-0915-100 Lab ID: 40121128006 Collected: 09/15/15 16:35 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 09/18/15 10:32 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 09/18/15 10:32 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 09/18/15 10:32 103-65-11.0 0.50 1Styrene <0.50 ug/L 09/18/15 10:32 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 09/18/15 10:32 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 09/18/15 10:32 79-34-51.0 0.25 1Tetrachloroethene 32.7 ug/L 09/18/15 10:32 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 09/18/15 10:32 109-99-95.0 2.0 1Toluene <0.50 ug/L 09/18/15 10:32 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 09/18/15 10:32 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 09/18/15 10:32 120-82-15.0 2.2 11,1,1-Trichloroethane 6.6 ug/L 09/18/15 10:32 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 09/18/15 10:32 79-00-51.0 0.20 1Trichloroethene 6.2 ug/L 09/18/15 10:32 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 09/18/15 10:32 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 09/18/15 10:32 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 09/18/15 10:32 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 09/18/15 10:32 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 09/18/15 10:32 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 09/18/15 10:32 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 09/18/15 10:32 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 09/18/15 10:32 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 103 % 09/18/15 10:32 460-00-470-130 1Dibromofluoromethane (S) 95 % 09/18/15 10:32 1868-53-770-130 1Toluene-d8 (S) 101 % 09/18/15 10:32 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 16 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40121128007 Collected: 09/15/15 16:10 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 09/18/15 10:54 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 09/18/15 10:54 107-05-15.0 2.2 1Benzene <0.50 ug/L 09/18/15 10:54 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 09/18/15 10:54 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 09/18/15 10:54 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 09/18/15 10:54 75-27-41.0 0.50 1Bromoform <0.50 ug/L 09/18/15 10:54 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 09/18/15 10:54 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 09/18/15 10:54 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 09/18/15 10:54 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 09/18/15 10:54 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 09/18/15 10:54 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 09/18/15 10:54 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 09/18/15 10:54 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 09/18/15 10:54 75-00-31.0 0.37 1Chloroform <2.5 ug/L 09/18/15 10:54 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 09/18/15 10:54 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 09/18/15 10:54 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 09/18/15 10:54 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 09/18/15 10:54 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 09/18/15 10:54 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 09/18/15 10:54 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 09/18/15 10:54 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 09/18/15 10:54 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 09/18/15 10:54 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 09/18/15 10:54 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 09/18/15 10:54 75-71-81.0 0.22 11,1-Dichloroethane 17.7 ug/L 09/18/15 10:54 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 09/18/15 10:54 107-06-21.0 0.17 11,1-Dichloroethene 5.8 ug/L 09/18/15 10:54 75-35-41.0 0.41 1cis-1,2-Dichloroethene 13.8 ug/L 09/18/15 10:54 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 09/18/15 10:54 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 09/18/15 10:54 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 09/18/15 10:54 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 09/18/15 10:54 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 09/18/15 10:54 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 09/18/15 10:54 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 09/18/15 10:54 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 09/18/15 10:54 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 09/18/15 10:54 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 09/18/15 10:54 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 09/18/15 10:54 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 09/18/15 10:54 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 09/18/15 10:54 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 09/18/15 10:54 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 09/18/15 10:54 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 17 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40121128007 Collected: 09/15/15 16:10 Received: 09/16/15 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 09/18/15 10:54 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 09/18/15 10:54 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 09/18/15 10:54 103-65-11.0 0.50 1Styrene <0.50 ug/L 09/18/15 10:54 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 09/18/15 10:54 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 09/18/15 10:54 79-34-51.0 0.25 1Tetrachloroethene 61.7 ug/L 09/18/15 10:54 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 09/18/15 10:54 109-99-95.0 2.0 1Toluene <0.50 ug/L 09/18/15 10:54 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 09/18/15 10:54 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 09/18/15 10:54 120-82-15.0 2.2 11,1,1-Trichloroethane 20.4 ug/L 09/18/15 10:54 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 09/18/15 10:54 79-00-51.0 0.20 1Trichloroethene 6.5 ug/L 09/18/15 10:54 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 09/18/15 10:54 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 09/18/15 10:54 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 09/18/15 10:54 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 09/18/15 10:54 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 09/18/15 10:54 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 09/18/15 10:54 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 09/18/15 10:54 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 09/18/15 10:54 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 105 % 09/18/15 10:54 460-00-470-130 1Dibromofluoromethane (S) 96 % 09/18/15 10:54 1868-53-770-130 1Toluene-d8 (S) 102 % 09/18/15 10:54 2037-26-570-130 1
Analytical Method: SM 2540D2540D Total Suspended Solids
Total Suspended Solids 1.0J mg/L 09/17/15 10:422.0 0.95 1
Analytical Method: SM 4500-H+B4500H+ pH, Electrometric
pH 7.1 Std. Units 09/17/15 10:45 H60.10 0.010 1
Analytical Method: EPA 410.4 Preparation Method: EPA 410.4410.4 COD
Chemical Oxygen Demand 17.5J mg/L 09/18/15 12:2509/18/15 07:3750.0 11.6 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 18 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
MSV/30185EPA 8260
EPA 82608260 MSV
Associated Lab Samples: 40121128001, 40121128002, 40121128003, 40121128004, 40121128005, 40121128006, 40121128007
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1222079Associated Lab Samples: 40121128001, 40121128002, 40121128003, 40121128004, 40121128005, 40121128006, 40121128007
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 09/18/15 07:161,1,1-Trichloroethane ug/L <0.50 1.0 09/18/15 07:161,1,2,2-Tetrachloroethane ug/L <0.25 1.0 09/18/15 07:161,1,2-Trichloroethane ug/L <0.20 1.0 09/18/15 07:161,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 09/18/15 07:161,1-Dichloroethane ug/L <0.24 1.0 09/18/15 07:161,1-Dichloroethene ug/L <0.41 1.0 09/18/15 07:161,1-Dichloropropene ug/L <0.44 1.0 09/18/15 07:161,2,3-Trichlorobenzene ug/L <2.1 5.0 09/18/15 07:161,2,3-Trichloropropane ug/L <0.50 1.0 09/18/15 07:161,2,4-Trichlorobenzene ug/L <2.2 5.0 09/18/15 07:161,2,4-Trimethylbenzene ug/L <0.50 1.0 09/18/15 07:161,2-Dibromo-3-chloropropane ug/L <2.2 5.0 09/18/15 07:161,2-Dibromoethane (EDB) ug/L <0.18 1.0 09/18/15 07:161,2-Dichlorobenzene ug/L <0.50 1.0 09/18/15 07:161,2-Dichloroethane ug/L <0.17 1.0 09/18/15 07:161,2-Dichloropropane ug/L <0.23 1.0 09/18/15 07:161,3,5-Trimethylbenzene ug/L <0.50 1.0 09/18/15 07:161,3-Dichlorobenzene ug/L <0.50 1.0 09/18/15 07:161,3-Dichloropropane ug/L <0.50 1.0 09/18/15 07:161,4-Dichlorobenzene ug/L <0.50 1.0 09/18/15 07:162,2-Dichloropropane ug/L <0.48 1.0 09/18/15 07:162-Butanone (MEK) ug/L <3.0 20.0 09/18/15 07:162-Chlorotoluene ug/L <0.50 1.0 09/18/15 07:164-Chlorotoluene ug/L <0.21 1.0 09/18/15 07:164-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 09/18/15 07:16Acetone ug/L <3.0 20.0 09/18/15 07:16Allyl chloride ug/L <2.2 5.0 09/18/15 07:16Benzene ug/L <0.50 1.0 09/18/15 07:16Bromobenzene ug/L <0.23 1.0 09/18/15 07:16Bromochloromethane ug/L <0.34 1.0 09/18/15 07:16Bromodichloromethane ug/L <0.50 1.0 09/18/15 07:16Bromoform ug/L <0.50 1.0 09/18/15 07:16Bromomethane ug/L <2.4 5.0 09/18/15 07:16Carbon tetrachloride ug/L <0.50 1.0 09/18/15 07:16Chlorobenzene ug/L <0.50 1.0 09/18/15 07:16Chloroethane ug/L <0.37 1.0 09/18/15 07:16Chloroform ug/L <2.5 5.0 09/18/15 07:16Chloromethane ug/L <0.50 1.0 09/18/15 07:16cis-1,2-Dichloroethene ug/L <0.26 1.0 09/18/15 07:16cis-1,3-Dichloropropene ug/L <0.50 1.0 09/18/15 07:16
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
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Page 19 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1222079Associated Lab Samples: 40121128001, 40121128002, 40121128003, 40121128004, 40121128005, 40121128006, 40121128007
Matrix: Water
Analyzed
Dibromochloromethane ug/L <0.50 1.0 09/18/15 07:16Dibromomethane ug/L <0.43 1.0 09/18/15 07:16Dichlorodifluoromethane ug/L <0.22 1.0 09/18/15 07:16Dichlorofluoromethane ug/L <0.21 1.0 09/18/15 07:16Diethyl ether (Ethyl ether) ug/L <2.2 5.0 09/18/15 07:16Ethylbenzene ug/L <0.50 1.0 09/18/15 07:16Hexachloro-1,3-butadiene ug/L <2.1 5.0 09/18/15 07:16Isopropylbenzene (Cumene) ug/L <0.14 1.0 09/18/15 07:16m&p-Xylene ug/L <1.0 2.0 09/18/15 07:16Methyl-tert-butyl ether ug/L <0.17 1.0 09/18/15 07:16Methylene Chloride ug/L <0.23 1.0 09/18/15 07:16n-Butylbenzene ug/L <0.50 1.0 09/18/15 07:16n-Propylbenzene ug/L <0.50 1.0 09/18/15 07:16Naphthalene ug/L <2.5 5.0 09/18/15 07:16o-Xylene ug/L <0.50 1.0 09/18/15 07:16p-Isopropyltoluene ug/L <0.50 1.0 09/18/15 07:16sec-Butylbenzene ug/L <2.2 5.0 09/18/15 07:16Styrene ug/L <0.50 1.0 09/18/15 07:16tert-Butylbenzene ug/L <0.18 1.0 09/18/15 07:16Tetrachloroethene ug/L <0.50 1.0 09/18/15 07:16Tetrahydrofuran ug/L <2.0 5.0 09/18/15 07:16Toluene ug/L <0.50 1.0 09/18/15 07:16trans-1,2-Dichloroethene ug/L <0.26 1.0 09/18/15 07:16trans-1,3-Dichloropropene ug/L <0.23 1.0 09/18/15 07:16Trichloroethene ug/L <0.33 1.0 09/18/15 07:16Trichlorofluoromethane ug/L <0.18 1.0 09/18/15 07:16Vinyl chloride ug/L <0.18 1.0 09/18/15 07:164-Bromofluorobenzene (S) % 105 70-130 09/18/15 07:16Dibromofluoromethane (S) % 91 70-130 09/18/15 07:16Toluene-d8 (S) % 102 70-130 09/18/15 07:16
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1222080LABORATORY CONTROL SAMPLE:LCSSpike
1,1,1-Trichloroethane ug/L 48.650 97 70-1301,1,2,2-Tetrachloroethane ug/L 47.250 94 70-1301,1,2-Trichloroethane ug/L 53.350 107 70-1301,1,2-Trichlorotrifluoroethane ug/L 54.550 109 50-1501,1-Dichloroethane ug/L 54.050 108 70-1301,1-Dichloroethene ug/L 44.750 89 70-1301,2,4-Trichlorobenzene ug/L 47.850 96 70-1301,2-Dibromo-3-chloropropane ug/L 39.250 78 50-1501,2-Dibromoethane (EDB) ug/L 52.350 105 70-1301,2-Dichlorobenzene ug/L 45.250 90 70-130
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
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Page 20 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1222080LABORATORY CONTROL SAMPLE:LCSSpike
1,2-Dichloroethane ug/L 57.550 115 70-1311,2-Dichloropropane ug/L 50.450 101 70-1301,3-Dichlorobenzene ug/L 45.050 90 70-1301,4-Dichlorobenzene ug/L 47.550 95 70-130Benzene ug/L 47.750 95 70-130Bromodichloromethane ug/L 56.850 114 70-130Bromoform ug/L 54.750 109 68-130Bromomethane ug/L 36.150 72 38-137Carbon tetrachloride ug/L 52.450 105 70-130Chlorobenzene ug/L 50.750 101 70-130Chloroethane ug/L 44.850 90 70-136Chloroform ug/L 51.050 102 70-130Chloromethane ug/L 42.350 85 48-144cis-1,2-Dichloroethene ug/L 49.750 99 70-130cis-1,3-Dichloropropene ug/L 44.650 89 70-130Dibromochloromethane ug/L 50.550 101 70-130Dichlorodifluoromethane ug/L 52.850 106 33-157Ethylbenzene ug/L 57.250 114 70-132Isopropylbenzene (Cumene) ug/L 54.450 109 70-130m&p-Xylene ug/L 109100 109 70-131Methyl-tert-butyl ether ug/L 43.350 87 48-141Methylene Chloride ug/L 46.250 92 70-130o-Xylene ug/L 51.450 103 70-131Styrene ug/L 54.150 108 70-130Tetrachloroethene ug/L 59.150 118 70-130Toluene ug/L 54.650 109 70-130trans-1,2-Dichloroethene ug/L 47.550 95 70-130trans-1,3-Dichloropropene ug/L 42.350 85 70-130Trichloroethene ug/L 56.450 113 70-130Trichlorofluoromethane ug/L 67.050 134 50-150Vinyl chloride ug/L 41.550 83 65-1424-Bromofluorobenzene (S) % 117 70-130Dibromofluoromethane (S) % 95 70-130Toluene-d8 (S) % 100 70-130
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1222218MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40121128002
1222219
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 50 121 70-13087 8 2050145 206 1891,1,2,2-Tetrachloroethane ug/L 50 92 70-13093 1 2050<0.25 46.1 46.61,1,2-Trichloroethane ug/L 50 110 70-130107 3 2050<0.20 54.9 53.41,1,2-Trichlorotrifluoroethane ug/L 50 110 50-151107 3 2050<0.81 55.2 53.61,1-Dichloroethane ug/L 50 95 70-134120 11 205060.7 108 1211,1-Dichloroethene ug/L 50 90 70-13981 7 205024.5 69.7 64.8
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 21 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1222218MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40121128002
1222219
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,2,4-Trichlorobenzene ug/L 50 99 70-130101 2 2050<2.2 50.0 50.81,2-Dibromo-3-chloropropane
ug/L 50 82 50-15081 2 2050<2.2 41.2 40.3
1,2-Dibromoethane (EDB) ug/L 50 107 70-130103 3 2050<0.18 53.5 51.71,2-Dichlorobenzene ug/L 50 89 70-13092 4 2050<0.50 44.3 45.91,2-Dichloroethane ug/L 50 113 70-132111 1 2050<0.17 56.4 55.51,2-Dichloropropane ug/L 50 99 70-130100 2 2050<0.23 49.4 50.21,3-Dichlorobenzene ug/L 50 88 70-13089 1 2050<0.50 44.0 44.61,4-Dichlorobenzene ug/L 50 92 70-13093 1 2050<0.50 45.9 46.5Benzene ug/L 50 93 70-13093 1 2050<0.50 46.7 46.4Bromodichloromethane ug/L 50 111 70-132111 0 2050<0.50 55.6 55.5Bromoform ug/L 50 108 68-130103 5 2050<0.50 54.1 51.5Bromomethane ug/L 50 75 38-14173 2 2050<2.4 37.3 36.6Carbon tetrachloride ug/L 50 105 70-130105 0 2050<0.50 52.7 52.7Chlorobenzene ug/L 50 99 70-13097 2 2050<0.50 49.5 48.5Chloroethane ug/L 50 88 66-15286 2 2050<0.37 44.0 43.0Chloroform ug/L 50 104 70-130101 3 2050<2.5 51.8 50.3Chloromethane ug/L 50 82 44-15180 3 2050<0.50 41.1 40.1cis-1,2-Dichloroethene ug/L 50 106 70-13092 8 205033.6 86.4 79.6cis-1,3-Dichloropropene ug/L 50 88 70-13090 2 2050<0.50 44.1 44.9Dibromochloromethane ug/L 50 102 70-13099 3 2050<0.50 51.0 49.7Dichlorodifluoromethane ug/L 50 99 29-16097 3 2050<0.22 49.7 48.5Ethylbenzene ug/L 50 111 70-132108 3 2050<0.50 55.9 54.2Isopropylbenzene (Cumene) ug/L 50 108 70-130105 3 2050<0.14 54.2 52.7m&p-Xylene ug/L 100 106 70-131104 2 20100<1.0 106 104Methyl-tert-butyl ether ug/L 50 87 48-14385 3 2050<0.17 43.7 42.6Methylene Chloride ug/L 50 94 70-13093 1 2050<0.23 47.0 46.5o-Xylene ug/L 50 101 70-131100 1 2050<0.50 50.8 50.4Styrene ug/L 50 108 70-130104 4 2050<0.50 54.2 52.0Toluene ug/L 50 106 70-130105 1 2050<0.50 53.3 52.8trans-1,2-Dichloroethene ug/L 50 93 70-13292 1 2050<0.26 46.7 46.1trans-1,3-Dichloropropene ug/L 50 85 70-13084 1 2050<0.23 42.6 42.2Trichloroethene ug/L 50 114 70-130116 1 205014.4 71.6 72.6Trichlorofluoromethane ug/L 50 134 50-153130 3 2050<0.18 67.0 65.1Vinyl chloride ug/L 50 79 60-15579 1 2050<0.18 39.6 39.34-Bromofluorobenzene (S) % 119 70-130112Dibromofluoromethane (S) % 100 70-13095Toluene-d8 (S) % 100 70-130101
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
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Page 22 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
WET/23199SM 2540D
SM 2540D2540D Total Suspended Solids
Associated Lab Samples: 40121128007
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1222317Associated Lab Samples: 40121128007
Matrix: Water
Analyzed
Total Suspended Solids mg/L <0.48 1.0 09/17/15 10:40
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1222318LABORATORY CONTROL SAMPLE:LCSSpike
Total Suspended Solids mg/L 100100 100 80-120
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401210770011222319SAMPLE DUPLICATE:
Total Suspended Solids mg/L 36.4 4 1034.8
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401211240031222320SAMPLE DUPLICATE:
Total Suspended Solids mg/L 260 5 10272
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 23 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
WET/23207SM 4500-H+B
SM 4500-H+B4500H+B pH
Associated Lab Samples: 40121128007
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401211830011223035SAMPLE DUPLICATE:
pH Std. Units 7.9 H60 57.9
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401212370011223036SAMPLE DUPLICATE:
pH Std. Units 8.1 H60 58.1
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401212580021223037SAMPLE DUPLICATE:
pH Std. Units 7.1 H61 57.1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 24 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
WETA/30289EPA 410.4
EPA 410.4410.4 COD
Associated Lab Samples: 40121128007
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1223045Associated Lab Samples: 40121128007
Matrix: Water
Analyzed
Chemical Oxygen Demand mg/L <11.6 50.0 09/18/15 12:23
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1223046LABORATORY CONTROL SAMPLE:LCSSpike
Chemical Oxygen Demand mg/L 509500 102 90-110
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1223047MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40121090001
1223048
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
Chemical Oxygen Demand mg/L 526 103 90-110101 2 10526<52.6 560 550
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1223049MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40121043002
1223050
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
Chemical Oxygen Demand mg/L 526 102 90-110101 1 10526<12.2 543 538
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 25 of 29
#=QL#
QUALIFIERS
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Green BayPASI-G
ANALYTE QUALIFIERS
Analysis initiated outside of the 15 minute EPA recommended holding time.H6
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 26 of 29
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:Project:
40121128023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch
40121128001 MSV/30185091515-0800-200 EPA 826040121128002 MSV/30185RW07-39-SP-0915-100 EPA 826040121128003 MSV/30185RW07-40-SP-0915-100 EPA 826040121128004 MSV/30185RW06-28-I-0915-100 EPA 826040121128005 MSV/30185RW07-38-I-0915-100 EPA 826040121128006 MSV/30185RW06-27-BR-0915-100 EPA 826040121128007 MSV/30185SE EFFLUENT EPA 8260
40121128007 WET/23199SE EFFLUENT SM 2540D
40121128007 WET/23207SE EFFLUENT SM 4500-H+B
40121128007 WETA/30289 WETA/30300SE EFFLUENT EPA 410.4 EPA 410.4
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/22/2015 03:00 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 27 of 29
Pag
e 28
of 2
9
{Please Print Clearly) of
Company Name:
UPPER MIDWEST REGION /
MN: 612-607-1700 WI: 920-469 ~36 (:)ree1-1
~ Branch/Location:
Project Contact:
Phone: CHAIN OF CUSTODY *Preservation Codes Project Number:
A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH
Project Name:
Project State:
Sampled By (Print):
Sampled By (Sign):
PO#:
Data Package Options (billable)
0 EPA Level Ill
0 EPA Level IV
MS/MSD 0 On your sample
(billable) 0 NOT needed on
your sample
PACE LAB# CLIENT FIELD ID
Regulatory Program:
H=Sodium Bisulfate Solution
FILTERED? (YES/NO)
PRESERVATION ccooer
Matrix Codes A= Air W =Water B = Biota OW = Ortnking Water
GW =Ground Water SW = Surface Water
Rush Turnaround Time Requested - Prelims (Rush TAT subject to approval/surcharge)
Date Needed: ransmit Prelim Rush Results by (complete what you want):
11-T_e_le.;..p_ho_n_e_: --1----------------l!Relinquished By:
Fax:
Samples on HOLD are subject to
special pricing and release of liability
C019a(27Jun2006)
elinquished By:
l=Sodium Thiosulfate J=Other
DatefTime:
DatefTime:
Quote#:
Mail To Contact:
Mail To Company:
Mail To Address:
Invoice To Contact:
Invoice To Company:
Invoice To Address:
Invoice To Phone:
LAB COMMENTS Profile#
PACE Project No.
Date/Time:
Date/Time:
Page 29 of 29
a Analytical. Sample Condition Upon Receipt Pace Analytical Services, Inc.
1241 Bellevue Street, Suite 9 Green Bay, WI 54302
/ /Client Name: c ncld.ec A.:s~'-a::ie_SJ Courier: r Fed Ex r UP~ - Client r Paco/'5ther: LOQ £ t(I 0
Project#:
Tracking #: 1)1 {19 30- CO Custody Seal on Cooler/Box Present: J/"' yes - no Seals intact: J/Yes r no
Custody Seal on Samples Present: f yesy no Seals intact: r yes - no
W0#"40121128 111111 1111111111 111111 40121128
Packing Material: ~Bubble Wrap )7'Bubble Bags r None r Other Thermometer Used $ e·- 5S<.p Type of Ice: @) Blue Dry None--J7"--=-s-a_m_p_le_s_o_n-ic_e_, -co-o-lin_g_p_r-oce_s_s -ha_s_b_e_g-un __ _
Cooler Temperature Uncorr- ~ /Corr: ~ Biological Tissue is Frozen: r yes ._
Temp Blank Present: ryes prio r no Person elf.r inin~ontents: Date: I ~I Cl C::-,
Temp should be above freezing to 6°C for all sample except Biota. Initials: ~ ~ Frozen Biota Samples should be received s o•c. Comments: ,,
~es £
Chain of Custody Present: ONo ON/A 1.
Chain of Custody Filled Out: r;Wes 0No ON/A 2.
Chain of Custody Relinquished: Jives 0No ON/A 3.
Sampler Name & Signature on COC: ¢es 0No ON/A 4.
Samples Arrived within Hold Time: ,ftres 0No ON/A 5.
- VOA Samples frozen upon receipt OYes 0No Date/Time:
Short Hold Time Analysis (<72hr): OYes )2i'No ON/A 6.
Rush Turn Around Time Requested: OYes j;ll(fo ON/A 7.
Sufficient Volume: ¢es 0No ON/A 8.
Correct Containers Used: ~es 0No ON/A 9.
-Pace Containers Used: &es 0No ON/A
-Pace IR Containers Used: OYes 0No ~A
Containers Intact: ¢'ves 0No ON/A 10.
Filtered volume received for Dissolved tests OYes 0No )a'f.ltA 11.
Sample Labels match COC: OYes 0No ON/A 12.
-Includes date/time/ID/Analysis Matrix: t1. ) All containers needing preservation have been checked. Jlfr (Non-Compliance noted in 13.) es ONo ON/A 13.
r HN03 p'H2S04 r NaOH r NaOH +ZnAct
---- ----- --- - -- - --- ---- ---- - ---- -- -- -All containers needing preservation are found to be in compliance with EPA recommendation. ¢es ONo ON/A (HN03, H~s2; NaOH+ZnAct ~9. NaOH <!12) e~pti;i;;; VOA, ~ttf~~ foC, TOX, TOH,- - -~~ ~~- -_;- - - -O&G, WIDR , Phenolics, OTHER: </, '/ fR. 5 '7" ;c-mv
Initial when ~lab Std #ID of completed preservative
1uare1 Time:
Headspace in VOA Vials ( >6mm): 0Yes ~o ON/A 14. ( Trip Blank Present: )ZJYes ONo ON/A 15.
Trip Blank Custody Seals Present }lfves 0No ON/A
Pace Trip Blank Lot# (if purchased):I" £'\\If rPr\ (.(A' <f/tu It~ Client Notification/ Resolution: If checked, see attached form for additional comments LJ
Person Contacted: Date/Time: --------~----~ Comments/ Resolution: -----~---~~~---~~-~------~--------~-~-~~-
Project Manager Review:
F-GB-C-031-Rev.03 (9April2015) SCUR Form
#=CL#
October 20, 2015
LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40123013
40123013Project:Pace Project No.:
RE:
Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102
023-6105-015 CP-SHOREHAM YARD
Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on October 16, 2015.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Laurie [email protected] Manager
Enclosures
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:Project:
40123013023-6105-015 CP-SHOREHAM YARD
Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334Virginia VELAP ID: 460263
North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Virginia VELAP ID: 460263Virginia VELAP Certification ID: 460263Wisconsin Certification #: 405132750
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:Project:
40123013023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID Matrix Date Collected Date Received
40123013001 101515-0800-200 Water 10/15/15 08:00 10/16/15 08:40
40123013002 SE EFFLUENT Water 10/15/15 13:20 10/16/15 08:40
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 3 of 16
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:Project:
40123013023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts
40123013001 101515-0800-200 EPA 8260 71 PASI-GAJP
40123013002 SE EFFLUENT EPA 8260 71 PASI-GAJP
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 4 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40123013023-6105-015 CP-SHOREHAM YARD
Sample: 101515-0800-200 Lab ID: 40123013001 Collected: 10/15/15 08:00 Received: 10/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 10/17/15 16:55 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 10/17/15 16:55 107-05-15.0 2.2 1Benzene <0.50 ug/L 10/17/15 16:55 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 10/17/15 16:55 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 10/17/15 16:55 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 10/17/15 16:55 75-27-41.0 0.50 1Bromoform <0.50 ug/L 10/17/15 16:55 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 10/17/15 16:55 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 10/17/15 16:55 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 10/17/15 16:55 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 10/17/15 16:55 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 10/17/15 16:55 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 10/17/15 16:55 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 10/17/15 16:55 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 10/17/15 16:55 75-00-31.0 0.37 1Chloroform <2.5 ug/L 10/17/15 16:55 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 10/17/15 16:55 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 10/17/15 16:55 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 10/17/15 16:55 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 10/17/15 16:55 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 10/17/15 16:55 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 10/17/15 16:55 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 10/17/15 16:55 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 10/17/15 16:55 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 10/17/15 16:55 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 10/17/15 16:55 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 10/17/15 16:55 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 10/17/15 16:55 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 10/17/15 16:55 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 10/17/15 16:55 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 10/17/15 16:55 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 10/17/15 16:55 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 10/17/15 16:55 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 10/17/15 16:55 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 10/17/15 16:55 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 10/17/15 16:55 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 10/17/15 16:55 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 10/17/15 16:55 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 10/17/15 16:55 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 10/17/15 16:55 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 10/17/15 16:55 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 10/17/15 16:55 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 10/17/15 16:55 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 10/17/15 16:55 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 10/17/15 16:55 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 10/17/15 16:55 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 10/20/2015 02:57 PM
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Green Bay, WI 54302(920)469-2436
Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40123013023-6105-015 CP-SHOREHAM YARD
Sample: 101515-0800-200 Lab ID: 40123013001 Collected: 10/15/15 08:00 Received: 10/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 10/17/15 16:55 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 10/17/15 16:55 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 10/17/15 16:55 103-65-11.0 0.50 1Styrene <0.50 ug/L 10/17/15 16:55 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 10/17/15 16:55 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 10/17/15 16:55 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 10/17/15 16:55 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 10/17/15 16:55 109-99-95.0 2.0 1Toluene <0.50 ug/L 10/17/15 16:55 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 10/17/15 16:55 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 10/17/15 16:55 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 10/17/15 16:55 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 10/17/15 16:55 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 10/17/15 16:55 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 10/17/15 16:55 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 10/17/15 16:55 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 10/17/15 16:55 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 10/17/15 16:55 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 10/17/15 16:55 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 10/17/15 16:55 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 10/17/15 16:55 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 10/17/15 16:55 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 90 % 10/17/15 16:55 460-00-470-130 1Dibromofluoromethane (S) 106 % 10/17/15 16:55 1868-53-770-130 1Toluene-d8 (S) 96 % 10/17/15 16:55 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 10/20/2015 02:57 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 6 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40123013023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40123013002 Collected: 10/15/15 13:20 Received: 10/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone 14.8J ug/L 10/17/15 18:47 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 10/17/15 18:47 107-05-15.0 2.2 1Benzene <0.50 ug/L 10/17/15 18:47 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 10/17/15 18:47 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 10/17/15 18:47 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 10/17/15 18:47 75-27-41.0 0.50 1Bromoform <0.50 ug/L 10/17/15 18:47 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 10/17/15 18:47 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 10/17/15 18:47 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 10/17/15 18:47 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 10/17/15 18:47 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 10/17/15 18:47 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 10/17/15 18:47 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 10/17/15 18:47 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 10/17/15 18:47 75-00-31.0 0.37 1Chloroform <2.5 ug/L 10/17/15 18:47 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 10/17/15 18:47 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 10/17/15 18:47 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 10/17/15 18:47 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 10/17/15 18:47 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 10/17/15 18:47 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 10/17/15 18:47 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 10/17/15 18:47 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 10/17/15 18:47 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 10/17/15 18:47 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 10/17/15 18:47 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 10/17/15 18:47 75-71-81.0 0.22 11,1-Dichloroethane 18.4 ug/L 10/17/15 18:47 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 10/17/15 18:47 107-06-21.0 0.17 11,1-Dichloroethene 6.2 ug/L 10/17/15 18:47 75-35-41.0 0.41 1cis-1,2-Dichloroethene 14.3 ug/L 10/17/15 18:47 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 10/17/15 18:47 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 10/17/15 18:47 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 10/17/15 18:47 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 10/17/15 18:47 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 10/17/15 18:47 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 10/17/15 18:47 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 10/17/15 18:47 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 10/17/15 18:47 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 10/17/15 18:47 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 10/17/15 18:47 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 10/17/15 18:47 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 10/17/15 18:47 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 10/17/15 18:47 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 10/17/15 18:47 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 10/17/15 18:47 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40123013023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40123013002 Collected: 10/15/15 13:20 Received: 10/16/15 08:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 10/17/15 18:47 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 10/17/15 18:47 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 10/17/15 18:47 103-65-11.0 0.50 1Styrene <0.50 ug/L 10/17/15 18:47 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 10/17/15 18:47 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 10/17/15 18:47 79-34-51.0 0.25 1Tetrachloroethene 49.3 ug/L 10/17/15 18:47 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 10/17/15 18:47 109-99-95.0 2.0 1Toluene <0.50 ug/L 10/17/15 18:47 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 10/17/15 18:47 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 10/17/15 18:47 120-82-15.0 2.2 11,1,1-Trichloroethane 19.3 ug/L 10/17/15 18:47 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 10/17/15 18:47 79-00-51.0 0.20 1Trichloroethene 5.7 ug/L 10/17/15 18:47 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 10/17/15 18:47 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 10/17/15 18:47 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 10/17/15 18:47 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 10/17/15 18:47 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 10/17/15 18:47 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 10/17/15 18:47 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 10/17/15 18:47 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 10/17/15 18:47 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 90 % 10/17/15 18:47 460-00-470-130 1Dibromofluoromethane (S) 104 % 10/17/15 18:47 1868-53-770-130 1Toluene-d8 (S) 96 % 10/17/15 18:47 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40123013023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
MSV/30735EPA 8260
EPA 82608260 MSV
Associated Lab Samples: 40123013001, 40123013002
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1241397Associated Lab Samples: 40123013001, 40123013002
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 10/17/15 10:010.181,1,1-Trichloroethane ug/L <0.50 1.0 10/17/15 10:010.501,1,2,2-Tetrachloroethane ug/L <0.25 1.0 10/17/15 10:010.251,1,2-Trichloroethane ug/L <0.20 1.0 10/17/15 10:010.201,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 10/17/15 10:010.811,1-Dichloroethane ug/L <0.24 1.0 10/17/15 10:010.241,1-Dichloroethene ug/L <0.41 1.0 10/17/15 10:010.411,1-Dichloropropene ug/L <0.44 1.0 10/17/15 10:010.441,2,3-Trichlorobenzene ug/L <2.1 5.0 10/17/15 10:012.11,2,3-Trichloropropane ug/L <0.50 1.0 10/17/15 10:010.501,2,4-Trichlorobenzene ug/L <2.2 5.0 10/17/15 10:012.21,2,4-Trimethylbenzene ug/L <0.50 1.0 10/17/15 10:010.501,2-Dibromo-3-chloropropane ug/L <2.2 5.0 10/17/15 10:012.21,2-Dibromoethane (EDB) ug/L <0.18 1.0 10/17/15 10:010.181,2-Dichlorobenzene ug/L <0.50 1.0 10/17/15 10:010.501,2-Dichloroethane ug/L <0.17 1.0 10/17/15 10:010.171,2-Dichloropropane ug/L <0.23 1.0 10/17/15 10:010.231,3,5-Trimethylbenzene ug/L <0.50 1.0 10/17/15 10:010.501,3-Dichlorobenzene ug/L <0.50 1.0 10/17/15 10:010.501,3-Dichloropropane ug/L <0.50 1.0 10/17/15 10:010.501,4-Dichlorobenzene ug/L <0.50 1.0 10/17/15 10:010.502,2-Dichloropropane ug/L <0.48 1.0 10/17/15 10:010.482-Butanone (MEK) ug/L <3.0 20.0 10/17/15 10:013.02-Chlorotoluene ug/L <0.50 1.0 10/17/15 10:010.504-Chlorotoluene ug/L <0.21 1.0 10/17/15 10:010.214-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 10/17/15 10:012.1Acetone ug/L <3.0 20.0 10/17/15 10:013.0Allyl chloride ug/L <2.2 5.0 10/17/15 10:012.2Benzene ug/L <0.50 1.0 10/17/15 10:010.50Bromobenzene ug/L <0.23 1.0 10/17/15 10:010.23Bromochloromethane ug/L <0.34 1.0 10/17/15 10:010.34Bromodichloromethane ug/L <0.50 1.0 10/17/15 10:010.50Bromoform ug/L <0.50 1.0 10/17/15 10:010.50Bromomethane ug/L <2.4 5.0 10/17/15 10:012.4Carbon tetrachloride ug/L <0.50 1.0 10/17/15 10:010.50Chlorobenzene ug/L <0.50 1.0 10/17/15 10:010.50Chloroethane ug/L <0.37 1.0 10/17/15 10:010.37Chloroform ug/L <2.5 5.0 10/17/15 10:012.5Chloromethane ug/L <0.50 1.0 10/17/15 10:010.50cis-1,2-Dichloroethene ug/L <0.26 1.0 10/17/15 10:010.26cis-1,3-Dichloropropene ug/L <0.50 1.0 10/17/15 10:010.50
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40123013023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1241397Associated Lab Samples: 40123013001, 40123013002
Matrix: Water
AnalyzedMDL
Dibromochloromethane ug/L <0.50 1.0 10/17/15 10:010.50Dibromomethane ug/L <0.43 1.0 10/17/15 10:010.43Dichlorodifluoromethane ug/L <0.22 1.0 10/17/15 10:010.22Dichlorofluoromethane ug/L <0.21 1.0 10/17/15 10:010.21Diethyl ether (Ethyl ether) ug/L <2.2 5.0 10/17/15 10:012.2Ethylbenzene ug/L <0.50 1.0 10/17/15 10:010.50Hexachloro-1,3-butadiene ug/L <2.1 5.0 10/17/15 10:012.1Isopropylbenzene (Cumene) ug/L <0.14 1.0 10/17/15 10:010.14m&p-Xylene ug/L <1.0 2.0 10/17/15 10:011.0Methyl-tert-butyl ether ug/L <0.17 1.0 10/17/15 10:010.17Methylene Chloride ug/L <0.23 1.0 10/17/15 10:010.23n-Butylbenzene ug/L <0.50 1.0 10/17/15 10:010.50n-Propylbenzene ug/L <0.50 1.0 10/17/15 10:010.50Naphthalene ug/L <2.5 5.0 10/17/15 10:012.5o-Xylene ug/L <0.50 1.0 10/17/15 10:010.50p-Isopropyltoluene ug/L <0.50 1.0 10/17/15 10:010.50sec-Butylbenzene ug/L <2.2 5.0 10/17/15 10:012.2Styrene ug/L <0.50 1.0 10/17/15 10:010.50tert-Butylbenzene ug/L <0.18 1.0 10/17/15 10:010.18Tetrachloroethene ug/L <0.50 1.0 10/17/15 10:010.50Tetrahydrofuran ug/L <2.0 5.0 10/17/15 10:012.0Toluene ug/L <0.50 1.0 10/17/15 10:010.50trans-1,2-Dichloroethene ug/L <0.26 1.0 10/17/15 10:010.26trans-1,3-Dichloropropene ug/L <0.23 1.0 10/17/15 10:010.23Trichloroethene ug/L <0.33 1.0 10/17/15 10:010.33Trichlorofluoromethane ug/L <0.18 1.0 10/17/15 10:010.18Vinyl chloride ug/L <0.18 1.0 10/17/15 10:010.184-Bromofluorobenzene (S) % 90 70-130 10/17/15 10:01Dibromofluoromethane (S) % 107 70-130 10/17/15 10:01Toluene-d8 (S) % 98 70-130 10/17/15 10:01
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1241398LABORATORY CONTROL SAMPLE:LCSSpike
1,1,1-Trichloroethane ug/L 61.650 123 70-1301,1,2,2-Tetrachloroethane ug/L 55.050 110 70-1301,1,2-Trichloroethane ug/L 57.350 115 70-1301,1,2-Trichlorotrifluoroethane ug/L 57.050 114 50-1501,1-Dichloroethane ug/L 58.350 117 70-1301,1-Dichloroethene ug/L 54.650 109 70-1301,2,4-Trichlorobenzene ug/L 54.650 109 70-1301,2-Dibromo-3-chloropropane ug/L 53.050 106 50-1501,2-Dibromoethane (EDB) ug/L 58.050 116 70-1301,2-Dichlorobenzene ug/L 53.650 107 70-130
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40123013023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1241398LABORATORY CONTROL SAMPLE:LCSSpike
1,2-Dichloroethane ug/L 57.850 116 70-1311,2-Dichloropropane ug/L 54.150 108 70-1301,3-Dichlorobenzene ug/L 52.250 104 70-1301,4-Dichlorobenzene ug/L 52.450 105 70-130Benzene ug/L 61.150 122 70-130Bromodichloromethane ug/L 56.150 112 70-130Bromoform ug/L 57.850 116 68-130Bromomethane ug/L 41.550 83 38-137Carbon tetrachloride ug/L 57.150 114 70-130Chlorobenzene ug/L 55.750 111 70-130Chloroethane ug/L 49.450 99 70-136Chloroform ug/L 60.450 121 70-130Chloromethane ug/L 51.050 102 48-144cis-1,2-Dichloroethene ug/L 55.250 110 70-130cis-1,3-Dichloropropene ug/L 47.950 96 70-130Dibromochloromethane ug/L 57.750 115 70-130Dichlorodifluoromethane ug/L 42.850 86 33-157Ethylbenzene ug/L 57.250 114 70-132Isopropylbenzene (Cumene) ug/L 57.950 116 70-130m&p-Xylene ug/L 117100 117 70-131Methyl-tert-butyl ether ug/L 54.050 108 48-141Methylene Chloride ug/L 56.150 112 70-130o-Xylene ug/L 57.250 114 70-131Styrene ug/L 53.950 108 70-130Tetrachloroethene ug/L 57.050 114 70-130Toluene ug/L 56.350 113 70-130trans-1,2-Dichloroethene ug/L 55.750 111 70-130trans-1,3-Dichloropropene ug/L 48.750 97 70-130Trichloroethene ug/L 55.950 112 70-130Trichlorofluoromethane ug/L 58.050 116 50-150Vinyl chloride ug/L 51.550 103 65-1424-Bromofluorobenzene (S) % 99 70-130Dibromofluoromethane (S) % 109 70-130Toluene-d8 (S) % 99 70-130
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1241474MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40123030002
1241475
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 50 121 70-130117 3 2050<0.50 60.3 58.51,1,2,2-Tetrachloroethane ug/L 50 110 70-130106 3 2050<0.25 54.8 53.11,1,2-Trichloroethane ug/L 50 113 70-130108 4 2050<0.20 56.3 54.01,1,2-Trichlorotrifluoroethane ug/L 50 112 50-151110 2 2050<0.81 55.9 55.11,1-Dichloroethane ug/L 50 116 70-134112 3 2050<0.24 57.9 56.21,1-Dichloroethene ug/L 50 109 70-139106 3 2050<0.41 54.5 53.1
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Page 11 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40123013023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1241474MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40123030002
1241475
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,2,4-Trichlorobenzene ug/L 50 108 70-130104 4 2050<2.2 54.2 52.11,2-Dibromo-3-chloropropane
ug/L 50 102 50-150104 2 2050<2.2 51.0 52.1
1,2-Dibromoethane (EDB) ug/L 50 115 70-130112 2 2050<0.18 57.3 55.91,2-Dichlorobenzene ug/L 50 106 70-130100 5 2050<0.50 52.8 50.21,2-Dichloroethane ug/L 50 117 70-132113 3 2050<0.17 58.3 56.51,2-Dichloropropane ug/L 50 107 70-130102 4 2050<0.23 53.4 51.01,3-Dichlorobenzene ug/L 50 103 70-13098 5 2050<0.50 51.7 49.21,4-Dichlorobenzene ug/L 50 104 70-13099 5 2050<0.50 52.2 49.5Benzene ug/L 50 121 70-130117 4 2050<0.50 60.5 58.3Bromodichloromethane ug/L 50 111 70-132106 4 2050<0.50 55.3 52.9Bromoform ug/L 50 116 68-130112 3 2050<0.50 58.1 56.1Bromomethane ug/L 50 88 38-14190 2 2050<2.4 43.8 44.9Carbon tetrachloride ug/L 50 112 70-130112 0 2050<0.50 56.0 55.9Chlorobenzene ug/L 50 111 70-130106 4 2050<0.50 55.6 53.2Chloroethane ug/L 50 96 66-15291 5 2050<0.37 48.2 45.7Chloroform ug/L 50 118 70-130114 4 2050<2.5 59.1 56.9Chloromethane ug/L 50 96 44-15197 0 2050<0.50 48.1 48.3cis-1,2-Dichloroethene ug/L 50 109 70-130105 4 2050<0.26 54.6 52.5cis-1,3-Dichloropropene ug/L 50 95 70-13091 4 2050<0.50 47.4 45.7Dibromochloromethane ug/L 50 114 70-130110 3 2050<0.50 57.0 55.2Dichlorodifluoromethane ug/L 50 82 29-16080 3 2050<0.22 40.9 39.8Ethylbenzene ug/L 50 113 70-132107 6 2050<0.50 56.7 53.7Isopropylbenzene (Cumene) ug/L 50 114 70-130110 4 2050<0.14 57.2 55.1m&p-Xylene ug/L 100 115 70-131111 4 20100<1.0 115 111Methyl-tert-butyl ether ug/L 50 107 48-143106 1 2050<0.17 53.4 53.0Methylene Chloride ug/L 50 110 70-130109 2 2050<0.23 55.2 54.3o-Xylene ug/L 50 112 70-131107 5 2050<0.50 56.1 53.6Styrene ug/L 50 106 70-130102 4 2050<0.50 53.2 51.1Tetrachloroethene ug/L 50 112 70-130107 4 2050<0.50 56.0 53.7Toluene ug/L 50 112 70-130107 5 2050<0.50 55.9 53.3trans-1,2-Dichloroethene ug/L 50 110 70-132108 1 2050<0.26 54.9 54.2trans-1,3-Dichloropropene ug/L 50 96 70-13094 2 2050<0.23 47.9 47.1Trichloroethene ug/L 50 109 70-130104 4 2050<0.33 54.6 52.2Trichlorofluoromethane ug/L 50 114 50-153112 1 2050<0.18 56.9 56.2Vinyl chloride ug/L 50 103 60-15599 4 2050<0.18 51.5 49.54-Bromofluorobenzene (S) % 100 70-130100Dibromofluoromethane (S) % 109 70-130109Toluene-d8 (S) % 98 70-13098
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#=QL#
QUALIFIERS
Pace Project No.:Project:
40123013023-6105-015 CP-SHOREHAM YARD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Green BayPASI-G
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:Project:
40123013023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch
40123013001 MSV/30735101515-0800-200 EPA 826040123013002 MSV/30735SE EFFLUENT EPA 8260
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 10/20/2015 02:57 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 14 of 16
Pag
e 15
of 1
6
UPPER MIDWEST REGION
Company Name:
Branch/Location:
Project Contact:
MN: 612-607-1700 WI: 920-469-
ceAnalytical e www.paoetabs..com
' Quote#:
Phone: CHAIN OF CUSTODY Mail To Contact:
*Preservation Codes Project Number: A=None B=HCL C=H2S04 D=HN03 E=OI Water F=Methanol G=NaOH
Project Name:
Project State:
Sampled By (Print):
Sampled By (Sign):
PO#:
Data Package Options (billable)
0 EPA Level 111
0 EPA Level IV
Regulatory Program:
H=Sodium Bisulfate Solution
FILTERED? (YES/NO)
PRESERVATION (CODE)*
Matrix Codes A= Air B =Biota C= Charcoal O=Oil S=Soil
MS/llllSD 0 On your sample
(billable) 0 NOT needed on
your sample Sl=Slud e WP=Wi
PACE LAB# CLIENT FIELD ID
Rush Turnaround Time Requested - Prelims (Rush TAT subject to approval/surcharge)
Date Needed: it Prelim Rush Results by (complete what you want):
Samples on HOLD are subject to
special pricing and release of llabllity
C019a(27 Jun2006)
COLLECTION
l=Sodium Thiosulfate J=Other
Date/Time:
Oatemme: Received By:
Mail To Company:
Mail To Address:
Invoice To Contact:
Invoice To Company:
Invoice To Address:
Invoice To Phone:
CLIENT COMMENTS
Date/Time:
Date/Time:
PACE Project No.
OK I Adjusted
Cooler Custody Seal
Present~ Intact I Not Intact
V n 6.0 06/14106
Page 16 of 16
aAna/yfical" Sample Condition Upon Receipt Pace Analytical Services, Inc.
1241 Bellevue Street, Suite 9 Green Bay, WI 54302
;~lient Name: {:2 0 /de Y Project#: WOl.40123013
1111111111111111111111 Courier: r Fed Ex r U~ 2-gient r Pace ::>ther: Tracking #: )?9{1 c?"--'-J J Custody Seal on Cooler/Box Present: ~es - no Seals intact: }f yes r no
Custody Seal on Samples Present: r yes 1)2'...no Seals intact: r yes - no
40123013
Packing Material: r Bub~e)'.Y~P ti'-Bubble Bags r None r Other
Thermometer Used l!{ld Type of le~ Blue Dry None Jt:- Samples on ice, cooling process has begun
Coole< Temperatu"' Uororr' r IC-Orr "1;;i;1.,.;ca1 Tissue ;s F•o•en' r yes ' Temp Blank Present: ryes no r no Person exami~~~~,: .f
Temp should be above freezing to 6°C for all sample except Biota. Date: //)-- - , Initials: ~.,,V
Frozen Biota Samples should be received s 0°C. Comments:
Chain of Custody Present: i)Jves 0No ON/A 1.
Chain of Custody Filled Out: ~es ONo ON/A 2.
Chain of Custody Relinquished: r/tves ONo ON/A 3.
Sampler Name & Signature on COC: r'i/.ves ONo ON/A 4.
Samples Arrived within Hold Time: r/ves ONo ON/A 5.
- VOA Samples frozen upon receipt DYes ONo Daterrime:
Short Hold Time Analysis (<72hr): 0Yes u/ro ON/A 6.
Rush Turn Around Time Requested: DYes ciNo ON/A 7.
Sufficient Volume: '¢jyes ONo ON/A 8.
Correct Containers Used: ¢ves ONo ON/A 9.
-Pace Containers Used: !:¢es ONo ON/A
-Pace IR Containers Used: 0Yes ONo [j1J\17A
Containers Intact: ~es ONo ON/A 10.
Filtered volume received for Dissolved tests DYes ONo f/mtA 11.
Sample Labels match COC: Vo
ON/A 12.
-Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. ~ -r HN03 r H2S04 r NaOH r NaOH +ZnAct (Non-Compliance noted in 13.) DYes ONo /A 13. ----- -- ------------------- ----- ---- -All containers needing preservation are found to be in compliance with EPA recommendation. OYes ONo r:fNiA (HN9.?·@s_2.i, ~<?~+Znf'-9~9.:. ~aOf:l ~12) ______________ exception VO , coliform, TOC, TOX, TOH, ~ Initial when ILab Std #ID of l~iate1 O&G, WIDROW, Phenolics, OTHER: es 0No completed preservative me:
Headspace in VOA Vials ( >6mm): OYes ~ON/A 14.
Trip Blank Present: qOyes ONo ON/A 15.
Trip Blank Custody Seals Present /&as ONo ON/A
Pace Trip Blank Lot# (if purchased): {!~iJ /o"fH\ ~/ Client Notification/ Resolution: If checked, see attached form for additional comments LJ
Project Manager Review: Date: __ t_o..,.l,.,w...,lc ...... ___ _
F-GB-C-031-Rev.03 (9April2015) SCUR Form
#=CL#
November 20, 2015
LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40124929
40124929Project:Pace Project No.:
RE:
Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102
023-6105-015 CP-SHOREHAM YARD
Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on November 18, 2015.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Laurie [email protected] Manager
Enclosures
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:Project:
40124929023-6105-015 CP-SHOREHAM YARD
Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334Virginia VELAP ID: 460263
North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Virginia VELAP ID: 460263Virginia VELAP Certification ID: 460263Wisconsin Certification #: 405132750
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:Project:
40124929023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID Matrix Date Collected Date Received
40124929001 111715-0800-200 Water 11/17/15 08:00 11/18/15 08:35
40124929002 SE EFFLUENT Water 11/17/15 14:05 11/18/15 08:35
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 3 of 16
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:Project:
40124929023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts
40124929001 111715-0800-200 EPA 8260 71 PASI-GLAP
40124929002 SE EFFLUENT EPA 8260 71 PASI-GLAP
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 4 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40124929023-6105-015 CP-SHOREHAM YARD
Sample: 111715-0800-200 Lab ID: 40124929001 Collected: 11/17/15 08:00 Received: 11/18/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 11/19/15 13:18 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 11/19/15 13:18 107-05-15.0 2.2 1Benzene <0.50 ug/L 11/19/15 13:18 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 11/19/15 13:18 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 11/19/15 13:18 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 11/19/15 13:18 75-27-41.0 0.50 1Bromoform <0.50 ug/L 11/19/15 13:18 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 11/19/15 13:18 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 11/19/15 13:18 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 11/19/15 13:18 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 11/19/15 13:18 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 11/19/15 13:18 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 11/19/15 13:18 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 11/19/15 13:18 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 11/19/15 13:18 75-00-31.0 0.37 1Chloroform <2.5 ug/L 11/19/15 13:18 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 11/19/15 13:18 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 11/19/15 13:18 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 11/19/15 13:18 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 11/19/15 13:18 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 11/19/15 13:18 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 11/19/15 13:18 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 11/19/15 13:18 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 11/19/15 13:18 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 11/19/15 13:18 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 11/19/15 13:18 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 11/19/15 13:18 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 11/19/15 13:18 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 11/19/15 13:18 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 11/19/15 13:18 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 11/19/15 13:18 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 11/19/15 13:18 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 11/19/15 13:18 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 11/19/15 13:18 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 11/19/15 13:18 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 11/19/15 13:18 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 11/19/15 13:18 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 11/19/15 13:18 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 11/19/15 13:18 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 11/19/15 13:18 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 11/19/15 13:18 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 11/19/15 13:18 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 11/19/15 13:18 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 11/19/15 13:18 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 11/19/15 13:18 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 11/19/15 13:18 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/20/2015 02:49 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40124929023-6105-015 CP-SHOREHAM YARD
Sample: 111715-0800-200 Lab ID: 40124929001 Collected: 11/17/15 08:00 Received: 11/18/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 11/19/15 13:18 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 11/19/15 13:18 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 11/19/15 13:18 103-65-11.0 0.50 1Styrene <0.50 ug/L 11/19/15 13:18 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 11/19/15 13:18 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 11/19/15 13:18 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 11/19/15 13:18 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 11/19/15 13:18 109-99-95.0 2.0 1Toluene <0.50 ug/L 11/19/15 13:18 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 11/19/15 13:18 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 11/19/15 13:18 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 11/19/15 13:18 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 11/19/15 13:18 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 11/19/15 13:18 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 11/19/15 13:18 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 11/19/15 13:18 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 11/19/15 13:18 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 11/19/15 13:18 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 11/19/15 13:18 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 11/19/15 13:18 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 11/19/15 13:18 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 11/19/15 13:18 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 96 % 11/19/15 13:18 460-00-470-130 1Dibromofluoromethane (S) 105 % 11/19/15 13:18 1868-53-770-130 1Toluene-d8 (S) 99 % 11/19/15 13:18 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/20/2015 02:49 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 6 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40124929023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40124929002 Collected: 11/17/15 14:05 Received: 11/18/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 11/19/15 10:39 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 11/19/15 10:39 107-05-15.0 2.2 1Benzene <0.50 ug/L 11/19/15 10:39 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 11/19/15 10:39 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 11/19/15 10:39 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 11/19/15 10:39 75-27-41.0 0.50 1Bromoform <0.50 ug/L 11/19/15 10:39 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 11/19/15 10:39 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 11/19/15 10:39 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 11/19/15 10:39 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 11/19/15 10:39 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 11/19/15 10:39 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 11/19/15 10:39 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 11/19/15 10:39 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 11/19/15 10:39 75-00-31.0 0.37 1Chloroform <2.5 ug/L 11/19/15 10:39 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 11/19/15 10:39 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 11/19/15 10:39 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 11/19/15 10:39 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 11/19/15 10:39 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 11/19/15 10:39 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 11/19/15 10:39 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 11/19/15 10:39 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 11/19/15 10:39 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 11/19/15 10:39 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 11/19/15 10:39 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 11/19/15 10:39 75-71-81.0 0.22 11,1-Dichloroethane 18.8 ug/L 11/19/15 10:39 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 11/19/15 10:39 107-06-21.0 0.17 11,1-Dichloroethene 6.9 ug/L 11/19/15 10:39 75-35-41.0 0.41 1cis-1,2-Dichloroethene 14.5 ug/L 11/19/15 10:39 156-59-21.0 0.26 1trans-1,2-Dichloroethene 0.32J ug/L 11/19/15 10:39 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 11/19/15 10:39 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 11/19/15 10:39 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 11/19/15 10:39 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 11/19/15 10:39 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 11/19/15 10:39 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 11/19/15 10:39 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 11/19/15 10:39 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 11/19/15 10:39 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 11/19/15 10:39 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 11/19/15 10:39 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 11/19/15 10:39 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 11/19/15 10:39 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 11/19/15 10:39 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 11/19/15 10:39 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/20/2015 02:49 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 7 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40124929023-6105-015 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40124929002 Collected: 11/17/15 14:05 Received: 11/18/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 11/19/15 10:39 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 11/19/15 10:39 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 11/19/15 10:39 103-65-11.0 0.50 1Styrene <0.50 ug/L 11/19/15 10:39 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 11/19/15 10:39 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 11/19/15 10:39 79-34-51.0 0.25 1Tetrachloroethene 45.0 ug/L 11/19/15 10:39 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 11/19/15 10:39 109-99-95.0 2.0 1Toluene <0.50 ug/L 11/19/15 10:39 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 11/19/15 10:39 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 11/19/15 10:39 120-82-15.0 2.2 11,1,1-Trichloroethane 17.2 ug/L 11/19/15 10:39 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 11/19/15 10:39 79-00-51.0 0.20 1Trichloroethene 6.2 ug/L 11/19/15 10:39 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 11/19/15 10:39 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 11/19/15 10:39 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 11/19/15 10:39 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 11/19/15 10:39 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 11/19/15 10:39 108-67-81.0 0.50 1Vinyl chloride 0.19J ug/L 11/19/15 10:39 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 11/19/15 10:39 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 11/19/15 10:39 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 96 % 11/19/15 10:39 460-00-470-130 1Dibromofluoromethane (S) 102 % 11/19/15 10:39 1868-53-770-130 1Toluene-d8 (S) 99 % 11/19/15 10:39 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/20/2015 02:49 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 8 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40124929023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
MSV/31339EPA 8260
EPA 82608260 MSV
Associated Lab Samples: 40124929001, 40124929002
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1261987Associated Lab Samples: 40124929001, 40124929002
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 11/19/15 08:230.181,1,1-Trichloroethane ug/L <0.50 1.0 11/19/15 08:230.501,1,2,2-Tetrachloroethane ug/L <0.25 1.0 11/19/15 08:230.251,1,2-Trichloroethane ug/L <0.20 1.0 11/19/15 08:230.201,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 11/19/15 08:230.811,1-Dichloroethane ug/L <0.24 1.0 11/19/15 08:230.241,1-Dichloroethene ug/L <0.41 1.0 11/19/15 08:230.411,1-Dichloropropene ug/L <0.44 1.0 11/19/15 08:230.441,2,3-Trichlorobenzene ug/L <2.1 5.0 11/19/15 08:232.11,2,3-Trichloropropane ug/L <0.50 1.0 11/19/15 08:230.501,2,4-Trichlorobenzene ug/L <2.2 5.0 11/19/15 08:232.21,2,4-Trimethylbenzene ug/L <0.50 1.0 11/19/15 08:230.501,2-Dibromo-3-chloropropane ug/L <2.2 5.0 11/19/15 08:232.21,2-Dibromoethane (EDB) ug/L <0.18 1.0 11/19/15 08:230.181,2-Dichlorobenzene ug/L <0.50 1.0 11/19/15 08:230.501,2-Dichloroethane ug/L <0.17 1.0 11/19/15 08:230.171,2-Dichloropropane ug/L <0.23 1.0 11/19/15 08:230.231,3,5-Trimethylbenzene ug/L <0.50 1.0 11/19/15 08:230.501,3-Dichlorobenzene ug/L <0.50 1.0 11/19/15 08:230.501,3-Dichloropropane ug/L <0.50 1.0 11/19/15 08:230.501,4-Dichlorobenzene ug/L <0.50 1.0 11/19/15 08:230.502,2-Dichloropropane ug/L <0.48 1.0 11/19/15 08:230.482-Butanone (MEK) ug/L <3.0 20.0 11/19/15 08:233.02-Chlorotoluene ug/L <0.50 1.0 11/19/15 08:230.504-Chlorotoluene ug/L <0.21 1.0 11/19/15 08:230.214-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 11/19/15 08:232.1Acetone ug/L <3.0 20.0 11/19/15 08:233.0Allyl chloride ug/L <2.2 5.0 11/19/15 08:232.2Benzene ug/L <0.50 1.0 11/19/15 08:230.50Bromobenzene ug/L <0.23 1.0 11/19/15 08:230.23Bromochloromethane ug/L <0.34 1.0 11/19/15 08:230.34Bromodichloromethane ug/L <0.50 1.0 11/19/15 08:230.50Bromoform ug/L <0.50 1.0 11/19/15 08:230.50Bromomethane ug/L <2.4 5.0 11/19/15 08:232.4Carbon tetrachloride ug/L <0.50 1.0 11/19/15 08:230.50Chlorobenzene ug/L <0.50 1.0 11/19/15 08:230.50Chloroethane ug/L <0.37 1.0 11/19/15 08:230.37Chloroform ug/L <2.5 5.0 11/19/15 08:232.5Chloromethane ug/L <0.50 1.0 11/19/15 08:230.50cis-1,2-Dichloroethene ug/L <0.26 1.0 11/19/15 08:230.26cis-1,3-Dichloropropene ug/L <0.50 1.0 11/19/15 08:230.50
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 9 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40124929023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1261987Associated Lab Samples: 40124929001, 40124929002
Matrix: Water
AnalyzedMDL
Dibromochloromethane ug/L <0.50 1.0 11/19/15 08:230.50Dibromomethane ug/L <0.43 1.0 11/19/15 08:230.43Dichlorodifluoromethane ug/L <0.22 1.0 11/19/15 08:230.22Dichlorofluoromethane ug/L <0.21 1.0 11/19/15 08:230.21Diethyl ether (Ethyl ether) ug/L <2.2 5.0 11/19/15 08:232.2Ethylbenzene ug/L <0.50 1.0 11/19/15 08:230.50Hexachloro-1,3-butadiene ug/L <2.1 5.0 11/19/15 08:232.1Isopropylbenzene (Cumene) ug/L <0.14 1.0 11/19/15 08:230.14m&p-Xylene ug/L <1.0 2.0 11/19/15 08:231.0Methyl-tert-butyl ether ug/L <0.17 1.0 11/19/15 08:230.17Methylene Chloride ug/L <0.23 1.0 11/19/15 08:230.23n-Butylbenzene ug/L <0.50 1.0 11/19/15 08:230.50n-Propylbenzene ug/L <0.50 1.0 11/19/15 08:230.50Naphthalene ug/L <2.5 5.0 11/19/15 08:232.5o-Xylene ug/L <0.50 1.0 11/19/15 08:230.50p-Isopropyltoluene ug/L <0.50 1.0 11/19/15 08:230.50sec-Butylbenzene ug/L <2.2 5.0 11/19/15 08:232.2Styrene ug/L <0.50 1.0 11/19/15 08:230.50tert-Butylbenzene ug/L <0.18 1.0 11/19/15 08:230.18Tetrachloroethene ug/L <0.50 1.0 11/19/15 08:230.50Tetrahydrofuran ug/L <2.0 5.0 11/19/15 08:232.0Toluene ug/L <0.50 1.0 11/19/15 08:230.50trans-1,2-Dichloroethene ug/L <0.26 1.0 11/19/15 08:230.26trans-1,3-Dichloropropene ug/L <0.23 1.0 11/19/15 08:230.23Trichloroethene ug/L <0.33 1.0 11/19/15 08:230.33Trichlorofluoromethane ug/L <0.18 1.0 11/19/15 08:230.18Vinyl chloride ug/L <0.18 1.0 11/19/15 08:230.184-Bromofluorobenzene (S) % 97 70-130 11/19/15 08:23Dibromofluoromethane (S) % 102 70-130 11/19/15 08:23Toluene-d8 (S) % 100 70-130 11/19/15 08:23
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1261988LABORATORY CONTROL SAMPLE:LCSSpike
1,1,1-Trichloroethane ug/L 53.850 108 70-1301,1,2,2-Tetrachloroethane ug/L 54.750 109 70-1301,1,2-Trichloroethane ug/L 52.750 105 70-1301,1,2-Trichlorotrifluoroethane ug/L 56.350 113 50-1501,1-Dichloroethane ug/L 55.350 111 70-1301,1-Dichloroethene ug/L 53.150 106 70-1301,2,4-Trichlorobenzene ug/L 48.250 96 70-1301,2-Dibromo-3-chloropropane ug/L 50.950 102 50-1501,2-Dibromoethane (EDB) ug/L 53.150 106 70-1301,2-Dichlorobenzene ug/L 54.250 108 70-130
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40124929023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1261988LABORATORY CONTROL SAMPLE:LCSSpike
1,2-Dichloroethane ug/L 53.150 106 70-1311,2-Dichloropropane ug/L 56.550 113 70-1301,3-Dichlorobenzene ug/L 53.250 106 70-1301,4-Dichlorobenzene ug/L 52.650 105 70-130Benzene ug/L 50.550 101 70-130Bromodichloromethane ug/L 52.150 104 70-130Bromoform ug/L 48.750 97 68-130Bromomethane ug/L 37.050 74 38-137Carbon tetrachloride ug/L 53.650 107 70-130Chlorobenzene ug/L 54.050 108 70-130Chloroethane ug/L 39.550 79 70-136Chloroform ug/L 56.350 113 70-130Chloromethane ug/L 32.050 64 48-144cis-1,2-Dichloroethene ug/L 52.550 105 70-130cis-1,3-Dichloropropene ug/L 52.650 105 70-130Dibromochloromethane ug/L 51.150 102 70-130Dichlorodifluoromethane ug/L 23.950 48 33-157Ethylbenzene ug/L 52.450 105 70-132Isopropylbenzene (Cumene) ug/L 56.050 112 70-130m&p-Xylene ug/L 109100 109 70-131Methyl-tert-butyl ether ug/L 50.450 101 48-141Methylene Chloride ug/L 56.950 114 70-130o-Xylene ug/L 51.650 103 70-131Styrene ug/L 54.350 109 70-130Tetrachloroethene ug/L 53.750 107 70-130Toluene ug/L 50.950 102 70-130trans-1,2-Dichloroethene ug/L 55.250 110 70-130trans-1,3-Dichloropropene ug/L 50.750 101 70-130Trichloroethene ug/L 54.650 109 70-130Trichlorofluoromethane ug/L 51.850 104 50-150Vinyl chloride ug/L 40.950 82 65-1424-Bromofluorobenzene (S) % 96 70-130Dibromofluoromethane (S) % 105 70-130Toluene-d8 (S) % 99 70-130
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1262201MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40124929002
1262202
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 50 110 70-130116 4 205017.2 72.4 75.51,1,2,2-Tetrachloroethane ug/L 50 101 70-130107 6 2050<0.25 50.6 53.41,1,2-Trichloroethane ug/L 50 104 70-130105 1 2050<0.20 51.8 52.41,1,2-Trichlorotrifluoroethane ug/L 50 117 50-151126 8 2050<0.81 58.3 62.91,1-Dichloroethane ug/L 50 108 70-134114 4 205018.8 72.7 75.71,1-Dichloroethene ug/L 50 113 70-139120 6 20506.9 63.5 67.2
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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Page 11 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40124929023-6105-015 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1262201MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40124929002
1262202
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,2,4-Trichlorobenzene ug/L 50 96 70-130101 6 2050<2.2 48.3 51.11,2-Dibromo-3-chloropropane
ug/L 50 94 50-15096 2 2050<2.2 46.9 48.1
1,2-Dibromoethane (EDB) ug/L 50 103 70-130105 2 2050<0.18 51.4 52.51,2-Dichlorobenzene ug/L 50 102 70-130106 5 2050<0.50 50.8 53.11,2-Dichloroethane ug/L 50 103 70-132107 4 2050<0.17 51.3 53.31,2-Dichloropropane ug/L 50 106 70-130111 5 2050<0.23 53.0 55.71,3-Dichlorobenzene ug/L 50 103 70-130106 4 2050<0.50 51.6 53.41,4-Dichlorobenzene ug/L 50 101 70-130105 5 2050<0.50 50.4 52.7Benzene ug/L 50 102 70-130106 4 2050<0.50 50.8 52.9Bromodichloromethane ug/L 50 99 70-132105 5 2050<0.50 49.7 52.3Bromoform ug/L 50 92 68-13096 4 2050<0.50 46.0 47.8Bromomethane ug/L 50 86 38-14190 5 2050<2.4 43.0 45.0Carbon tetrachloride ug/L 50 109 70-130112 3 2050<0.50 54.3 56.1Chlorobenzene ug/L 50 106 70-130108 2 2050<0.50 52.9 53.9Chloroethane ug/L 50 88 66-15290 3 2050<0.37 43.8 44.9Chloroform ug/L 50 109 70-130115 5 2050<2.5 54.7 57.7Chloromethane ug/L 50 80 44-15179 2 2050<0.50 40.2 39.4cis-1,2-Dichloroethene ug/L 50 103 70-130111 6 205014.5 65.9 69.9cis-1,3-Dichloropropene ug/L 50 101 70-130106 5 2050<0.50 50.5 53.1Dibromochloromethane ug/L 50 99 70-130103 4 2050<0.50 49.3 51.4Dichlorodifluoromethane ug/L 50 84 29-16087 2 2050<0.22 42.2 43.3Ethylbenzene ug/L 50 104 70-132106 2 2050<0.50 52.2 53.2Isopropylbenzene (Cumene) ug/L 50 111 70-130112 1 2050<0.14 55.4 56.1m&p-Xylene ug/L 100 107 70-131109 2 20100<1.0 107 109Methyl-tert-butyl ether ug/L 50 101 48-143102 2 2050<0.17 50.3 51.1Methylene Chloride ug/L 50 112 70-130114 1 2050<0.23 56.2 57.0o-Xylene ug/L 50 103 70-131103 0 2050<0.50 51.6 51.6Styrene ug/L 50 107 70-130108 2 2050<0.50 53.4 54.2Tetrachloroethene ug/L 50 112 70-130116 2 205045.0 101 103Toluene ug/L 50 101 70-130104 3 2050<0.50 50.5 52.0trans-1,2-Dichloroethene ug/L 50 114 70-132115 1 20500.32J 57.3 58.0trans-1,3-Dichloropropene ug/L 50 100 70-130108 8 2050<0.23 50.0 54.2Trichloroethene ug/L 50 107 70-130114 6 20506.2 59.5 63.0Trichlorofluoromethane ug/L 50 112 50-153116 4 2050<0.18 56.0 58.2Vinyl chloride ug/L 50 98 60-155100 3 20500.19J 49.0 50.44-Bromofluorobenzene (S) % 100 70-13098Dibromofluoromethane (S) % 101 70-130108Toluene-d8 (S) % 100 70-13099
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
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#=QL#
QUALIFIERS
Pace Project No.:Project:
40124929023-6105-015 CP-SHOREHAM YARD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Green BayPASI-G
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:Project:
40124929023-6105-015 CP-SHOREHAM YARD
Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch
40124929001 MSV/31339111715-0800-200 EPA 826040124929002 MSV/31339SE EFFLUENT EPA 8260
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Page 14 of 16
Pag
e 15
of 1
6
Page UPPER MIDWEST REGION f MN: 612-607-1700 WI: 920-4 9-2436 ~ f C: e V1
~~~ Oct Company Name: . 0 I J. er- ssoc~"\ tc.s Branch/Location: f\f, kv (ft- j tJ J
Phone: q 7 ~ ~ 6 '1 5 - f ., 2. l. CHAIN OF CUSTODY *Preservatfon Codes
A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH Project Number: (!') 2.. '.)- 61 () 5 , () I 5"
Project Name: C P -~~O(C."ct!Nl '(ct rd( H=Sodium Bisulfate Solution !=Sodium Thlosulfate J=Other
Project State: J"' /\.) Sampled By (Print): . ..f I~ tt'l P Sampled By (Sign):
PO#:
Data Package Options (billable)
0 EPALevellll
0 EPA Level IV
MS/MSD O On your sample
(billable) 0 NOT needed on
your sample
PACE LAB# CLIENT FIELD ID
Regulatory Program:
FILTERED? (YES/NO)
PRESERVATION (CODE)*
Matrix Codes A= Air W;:;::; Water B = Biota OW = Drinking Water C ~ Charcoal GW = Ground Water O = Oil SW = Surface Water S =Soil WW= Waste Water Sl=Slu e WP=Wi
COLLECTION
DATE
Quote#:
Mail To Contact:
Mail To Company:
Mail To Address:
Invoice To Contact:
Invoice To Company:
Invoice To Address:
Invoice To Phone:
CU ENT COMMENTS
LAB COMMENTS (lab Use Only}
Profile#
Rush Turnaround Time Requested - Prelims PACE Project No.
(Rush TAT subject to approval/surcharge) ilft/1/6' Date Needed:
Samples on HOLD are subject to
special pricing and release of liability
C019a(27 Jun2006)
Dateffime:
DatefTime:
Received By: DatefTime:
Received By: Date/Time:
Page 16 of 16
Sample Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9
Green Bay, WI 54302 aAna!Yfica'-~lient Name: l.10LJt'r Project#f WO#· 40124929
::::~:.:: ::::: : ... ::~ ;:~c~ "~:•' Seal::::;:;no l Ut~Jllll llllllll Ill Custody Seal on Samples Present: r yes ft no Seals intact: r yes - no
Packing Material: ~ Bubble Wrap JlZ'.-Bubble Bags r None . r Other
Thermometer Used SR..3 ~ Typ1e ;. ice~ Blue Dry None pc-samples on ice, cooling process has begun
Cooler Temperature Uncorr: i..f /Corr: "::[_ Biological Tissue is Frozen: r yes
Temp Blank Present: ryes ~no rno Person ?/mining c~~ts: ) Temp should be above freezing to 6°C for all sample except Biota. Date: '-I 'ff-I
Initials: ....~IA/
Frozen Biota Samples should be received s 0°c. Comments:
Chain of Custody Present: ~es ONo ON/A 1.
Chain of Custody Filled Out: ~es ONo ON/A 2.
Chain of Custody Relinquished: l4Yes ONo ON/A 3.
Sampler Name & Signature on COG: rives ONo ON/A 4.
Samples Arrived within Hold Time: 4Ztves ONo ON/A 5.
- VOA Samples frozen upon receipt 0Yes ONo Date/Time:
Short Hold Time Analysis (<72hr}: 0Yes r$No ON/A 6.
Rush Turn Around Time Requested: 0Yes 0No ON/A 7.
Sufficient Volume: ~es ONo ON/A 8.
Correct Containers Used: gt'res ONo ON/A 9.
-Pace Containers Used: ~es ONo ON/A
-Pace IR Containers Used: 0Yes ONo iJrNIA
Containers Intact: Gves ONo ON/A 10.
Filtered volume received for Dissolved tests 0Yes ONo ~A 11.
Sample Labels match COG: ~r~r ON/A 12.
-Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. ~ (Non-Compliance noted in 13.) 0Yes ONo · /A 13.
r HN03 r H2S04 r NaOH r NaOH +ZnAct - --- ------ --- -- - -- - --- ---- -- --- -- -- --All containers needing preservation are found to be in
~ compliance with EPA recommendation. 0Yes ONo (~f'~. H~ ~~ ~Q~+Zllf\_?~9! ~~':! ~12) _______ • ______ exceptions: , coliform, TOC, TOX, TOH, ~ Initial when I Lab Std #ID of l~ate/ O&G, WID , Phenolics, OTHER: es 0No completed preservative ime:
Headspace in VOA Vials ( >6mm): 0Yes GtNo ON/A 14.
Trip Blank Present: ~ ONo ON/A 15.
Trip Blank Custody Seals Present ~ ONo ON/A u Pace Trip Blank Lot# (if purchased): ~ IHS-€8:;A Client Notification/ Resolution: If checked, see attached form for additional comments D
Person Contacted: Date/Time: --------------------------- ------------------Comments/ Resolution: ---------------------------------------------------------------------------------
Project Manager Review: oate: __ \~ .. t\f_.(1rci.....-----
F-GB-C-031-Rev.03 (9April2015) SCURFonn
#=CL#
December 28, 2015
LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40126180
40126180Project:Pace Project No.:
RE:
Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102
023-6105-016 CP-SHOREHAM YARD
Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2015.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Laurie [email protected] Manager
Enclosures
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Page 1 of 29
#=CP#
CERTIFICATIONS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334Virginia VELAP ID: 460263
North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Virginia VELAP ID: 460263Virginia VELAP Certification ID: 460263Wisconsin Certification #: 405132750
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#=SS#
SAMPLE SUMMARY
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Lab ID Sample ID Matrix Date Collected Date Received
40126180001 121515-0800-200 Water 12/15/15 08:00 12/16/15 08:45
40126180002 RW07-39-SP-1215-100 Water 12/15/15 15:45 12/16/15 08:45
40126180003 RW07-40-SP-1215-100 Water 12/15/15 15:50 12/16/15 08:45
40126180004 RW06-28-I-1215-100 Water 12/15/15 15:53 12/16/15 08:45
40126180005 RW07-38-I-1215-100 Water 12/15/15 15:57 12/16/15 08:45
40126180006 RW06-27-BR-1215-100 Water 12/15/15 16:01 12/16/15 08:45
40126180007 SE EFFLUENT Water 12/15/15 16:05 12/16/15 08:45
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Page 3 of 29
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts
40126180001 121515-0800-200 EPA 8260 71 PASI-GHNW
40126180002 RW07-39-SP-1215-100 EPA 8260 71 PASI-GHNW
40126180003 RW07-40-SP-1215-100 EPA 8260 71 PASI-GHNW
40126180004 RW06-28-I-1215-100 EPA 8260 71 PASI-GHNW
40126180005 RW07-38-I-1215-100 EPA 8260 71 PASI-GHNW
40126180006 RW06-27-BR-1215-100 EPA 8260 71 PASI-GHNW
40126180007 SE EFFLUENT EPA 8260 71 PASI-GHNW
SM 2540D 1 PASI-GDDY
SM 4500-H+B 1 PASI-GALY
EPA 410.4 1 PASI-GTJJ
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Page 4 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: 121515-0800-200 Lab ID: 40126180001 Collected: 12/15/15 08:00 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 12/17/15 10:51 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 12/17/15 10:51 107-05-15.0 2.2 1Benzene <0.50 ug/L 12/17/15 10:51 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 12/17/15 10:51 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 12/17/15 10:51 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 12/17/15 10:51 75-27-41.0 0.50 1Bromoform <0.50 ug/L 12/17/15 10:51 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 12/17/15 10:51 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 12/17/15 10:51 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 12/17/15 10:51 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 12/17/15 10:51 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 12/17/15 10:51 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 12/17/15 10:51 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 12/17/15 10:51 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 12/17/15 10:51 75-00-31.0 0.37 1Chloroform <2.5 ug/L 12/17/15 10:51 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 12/17/15 10:51 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 12/17/15 10:51 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 12/17/15 10:51 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 12/17/15 10:51 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 12/17/15 10:51 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 12/17/15 10:51 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 12/17/15 10:51 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 12/17/15 10:51 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 12/17/15 10:51 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 12/17/15 10:51 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 12/17/15 10:51 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 12/17/15 10:51 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 12/17/15 10:51 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 12/17/15 10:51 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 12/17/15 10:51 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 12/17/15 10:51 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 12/17/15 10:51 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 12/17/15 10:51 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 12/17/15 10:51 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 12/17/15 10:51 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 12/17/15 10:51 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 12/17/15 10:51 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 12/17/15 10:51 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 12/17/15 10:51 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 12/17/15 10:51 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 12/17/15 10:51 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 12/17/15 10:51 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 12/17/15 10:51 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 12/17/15 10:51 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 12/17/15 10:51 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 5 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: 121515-0800-200 Lab ID: 40126180001 Collected: 12/15/15 08:00 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 12/17/15 10:51 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 12/17/15 10:51 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 12/17/15 10:51 103-65-11.0 0.50 1Styrene <0.50 ug/L 12/17/15 10:51 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 12/17/15 10:51 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 12/17/15 10:51 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 12/17/15 10:51 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 12/17/15 10:51 109-99-95.0 2.0 1Toluene <0.50 ug/L 12/17/15 10:51 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 12/17/15 10:51 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 12/17/15 10:51 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 12/17/15 10:51 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 12/17/15 10:51 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 12/17/15 10:51 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 12/17/15 10:51 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 12/17/15 10:51 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 12/17/15 10:51 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 12/17/15 10:51 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 12/17/15 10:51 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 12/17/15 10:51 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 12/17/15 10:51 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 12/17/15 10:51 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 96 % 12/17/15 10:51 460-00-470-130 1Dibromofluoromethane (S) 97 % 12/17/15 10:51 1868-53-770-130 1Toluene-d8 (S) 98 % 12/17/15 10:51 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 6 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: RW07-39-SP-1215-100 Lab ID: 40126180002 Collected: 12/15/15 15:45 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <14.8 ug/L 12/17/15 10:28 67-64-1100 14.8 5Allyl chloride <10.8 ug/L 12/17/15 10:28 107-05-125.0 10.8 5Benzene <2.5 ug/L 12/17/15 10:28 71-43-25.0 2.5 5Bromobenzene <1.2 ug/L 12/17/15 10:28 108-86-15.0 1.2 5Bromochloromethane <1.7 ug/L 12/17/15 10:28 74-97-55.0 1.7 5Bromodichloromethane <2.5 ug/L 12/17/15 10:28 75-27-45.0 2.5 5Bromoform <2.5 ug/L 12/17/15 10:28 75-25-25.0 2.5 5Bromomethane <12.2 ug/L 12/17/15 10:28 74-83-925.0 12.2 52-Butanone (MEK) <14.9 ug/L 12/17/15 10:28 78-93-3100 14.9 5n-Butylbenzene <2.5 ug/L 12/17/15 10:28 104-51-85.0 2.5 5sec-Butylbenzene <10.9 ug/L 12/17/15 10:28 135-98-825.0 10.9 5tert-Butylbenzene <0.90 ug/L 12/17/15 10:28 98-06-65.0 0.90 5Carbon tetrachloride <2.5 ug/L 12/17/15 10:28 56-23-55.0 2.5 5Chlorobenzene <2.5 ug/L 12/17/15 10:28 108-90-75.0 2.5 5Chloroethane <1.9 ug/L 12/17/15 10:28 75-00-35.0 1.9 5Chloroform <12.5 ug/L 12/17/15 10:28 67-66-325.0 12.5 5Chloromethane <2.5 ug/L 12/17/15 10:28 74-87-35.0 2.5 52-Chlorotoluene <2.5 ug/L 12/17/15 10:28 95-49-85.0 2.5 54-Chlorotoluene <1.1 ug/L 12/17/15 10:28 106-43-45.0 1.1 51,2-Dibromo-3-chloropropane <10.8 ug/L 12/17/15 10:28 96-12-825.0 10.8 5Dibromochloromethane <2.5 ug/L 12/17/15 10:28 124-48-15.0 2.5 51,2-Dibromoethane (EDB) <0.89 ug/L 12/17/15 10:28 106-93-45.0 0.89 5Dibromomethane <2.1 ug/L 12/17/15 10:28 74-95-35.0 2.1 51,2-Dichlorobenzene <2.5 ug/L 12/17/15 10:28 95-50-15.0 2.5 51,3-Dichlorobenzene <2.5 ug/L 12/17/15 10:28 541-73-15.0 2.5 51,4-Dichlorobenzene <2.5 ug/L 12/17/15 10:28 106-46-75.0 2.5 5Dichlorodifluoromethane <1.1 ug/L 12/17/15 10:28 75-71-85.0 1.1 51,1-Dichloroethane 48.8 ug/L 12/17/15 10:28 75-34-35.0 1.2 51,2-Dichloroethane <0.84 ug/L 12/17/15 10:28 107-06-25.0 0.84 51,1-Dichloroethene 20.2 ug/L 12/17/15 10:28 75-35-45.0 2.1 5cis-1,2-Dichloroethene 28.4 ug/L 12/17/15 10:28 156-59-25.0 1.3 5trans-1,2-Dichloroethene <1.3 ug/L 12/17/15 10:28 156-60-55.0 1.3 5Dichlorofluoromethane <1.1 ug/L 12/17/15 10:28 75-43-45.0 1.1 51,2-Dichloropropane <1.2 ug/L 12/17/15 10:28 78-87-55.0 1.2 51,3-Dichloropropane <2.5 ug/L 12/17/15 10:28 142-28-95.0 2.5 52,2-Dichloropropane <2.4 ug/L 12/17/15 10:28 594-20-75.0 2.4 51,1-Dichloropropene <2.2 ug/L 12/17/15 10:28 563-58-65.0 2.2 5cis-1,3-Dichloropropene <2.5 ug/L 12/17/15 10:28 10061-01-55.0 2.5 5trans-1,3-Dichloropropene <1.1 ug/L 12/17/15 10:28 10061-02-65.0 1.1 5Diethyl ether (Ethyl ether) <11.1 ug/L 12/17/15 10:28 60-29-725.0 11.1 5Ethylbenzene <2.5 ug/L 12/17/15 10:28 100-41-45.0 2.5 5Hexachloro-1,3-butadiene <10.5 ug/L 12/17/15 10:28 87-68-325.0 10.5 5Isopropylbenzene (Cumene) <0.72 ug/L 12/17/15 10:28 98-82-85.0 0.72 5p-Isopropyltoluene <2.5 ug/L 12/17/15 10:28 99-87-65.0 2.5 5Methylene Chloride <1.2 ug/L 12/17/15 10:28 75-09-25.0 1.2 54-Methyl-2-pentanone (MIBK) <10.7 ug/L 12/17/15 10:28 108-10-125.0 10.7 5
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 7 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: RW07-39-SP-1215-100 Lab ID: 40126180002 Collected: 12/15/15 15:45 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.87 ug/L 12/17/15 10:28 1634-04-45.0 0.87 5Naphthalene <12.5 ug/L 12/17/15 10:28 91-20-325.0 12.5 5n-Propylbenzene <2.5 ug/L 12/17/15 10:28 103-65-15.0 2.5 5Styrene <2.5 ug/L 12/17/15 10:28 100-42-55.0 2.5 51,1,1,2-Tetrachloroethane <0.90 ug/L 12/17/15 10:28 630-20-65.0 0.90 51,1,2,2-Tetrachloroethane <1.2 ug/L 12/17/15 10:28 79-34-55.0 1.2 5Tetrachloroethene 232 ug/L 12/17/15 10:28 127-18-45.0 2.5 5Tetrahydrofuran <10.2 ug/L 12/17/15 10:28 109-99-925.0 10.2 5Toluene <2.5 ug/L 12/17/15 10:28 108-88-35.0 2.5 51,2,3-Trichlorobenzene <10.7 ug/L 12/17/15 10:28 87-61-625.0 10.7 51,2,4-Trichlorobenzene <11.0 ug/L 12/17/15 10:28 120-82-125.0 11.0 51,1,1-Trichloroethane 106 ug/L 12/17/15 10:28 71-55-65.0 2.5 51,1,2-Trichloroethane <0.99 ug/L 12/17/15 10:28 79-00-55.0 0.99 5Trichloroethene 12.2 ug/L 12/17/15 10:28 79-01-65.0 1.7 5Trichlorofluoromethane <0.92 ug/L 12/17/15 10:28 75-69-45.0 0.92 51,2,3-Trichloropropane <2.5 ug/L 12/17/15 10:28 96-18-45.0 2.5 51,1,2-Trichlorotrifluoroethane <4.1 ug/L 12/17/15 10:28 76-13-125.0 4.1 51,2,4-Trimethylbenzene <2.5 ug/L 12/17/15 10:28 95-63-65.0 2.5 51,3,5-Trimethylbenzene <2.5 ug/L 12/17/15 10:28 108-67-85.0 2.5 5Vinyl chloride <0.88 ug/L 12/17/15 10:28 75-01-45.0 0.88 5m&p-Xylene <5.0 ug/L 12/17/15 10:28 179601-23-110.0 5.0 5o-Xylene <2.5 ug/L 12/17/15 10:28 95-47-65.0 2.5 5Surrogates4-Bromofluorobenzene (S) 94 % 12/17/15 10:28 460-00-470-130 5Dibromofluoromethane (S) 99 % 12/17/15 10:28 1868-53-770-130 5Toluene-d8 (S) 99 % 12/17/15 10:28 2037-26-570-130 5
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 8 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: RW07-40-SP-1215-100 Lab ID: 40126180003 Collected: 12/15/15 15:50 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 12/17/15 11:13 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 12/17/15 11:13 107-05-15.0 2.2 1Benzene <0.50 ug/L 12/17/15 11:13 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 12/17/15 11:13 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 12/17/15 11:13 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 12/17/15 11:13 75-27-41.0 0.50 1Bromoform <0.50 ug/L 12/17/15 11:13 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 12/17/15 11:13 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 12/17/15 11:13 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 12/17/15 11:13 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 12/17/15 11:13 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 12/17/15 11:13 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 12/17/15 11:13 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 12/17/15 11:13 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 12/17/15 11:13 75-00-31.0 0.37 1Chloroform <2.5 ug/L 12/17/15 11:13 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 12/17/15 11:13 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 12/17/15 11:13 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 12/17/15 11:13 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 12/17/15 11:13 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 12/17/15 11:13 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 12/17/15 11:13 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 12/17/15 11:13 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 12/17/15 11:13 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 12/17/15 11:13 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 12/17/15 11:13 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 12/17/15 11:13 75-71-81.0 0.22 11,1-Dichloroethane 2.5 ug/L 12/17/15 11:13 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 12/17/15 11:13 107-06-21.0 0.17 11,1-Dichloroethene 1.5 ug/L 12/17/15 11:13 75-35-41.0 0.41 1cis-1,2-Dichloroethene 1.3 ug/L 12/17/15 11:13 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 12/17/15 11:13 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 12/17/15 11:13 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 12/17/15 11:13 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 12/17/15 11:13 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 12/17/15 11:13 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 12/17/15 11:13 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 12/17/15 11:13 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 12/17/15 11:13 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 12/17/15 11:13 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 12/17/15 11:13 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 12/17/15 11:13 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 12/17/15 11:13 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 12/17/15 11:13 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 12/17/15 11:13 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 12/17/15 11:13 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 9 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: RW07-40-SP-1215-100 Lab ID: 40126180003 Collected: 12/15/15 15:50 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 12/17/15 11:13 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 12/17/15 11:13 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 12/17/15 11:13 103-65-11.0 0.50 1Styrene <0.50 ug/L 12/17/15 11:13 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 12/17/15 11:13 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 12/17/15 11:13 79-34-51.0 0.25 1Tetrachloroethene 47.5 ug/L 12/17/15 11:13 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 12/17/15 11:13 109-99-95.0 2.0 1Toluene <0.50 ug/L 12/17/15 11:13 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 12/17/15 11:13 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 12/17/15 11:13 120-82-15.0 2.2 11,1,1-Trichloroethane 9.3 ug/L 12/17/15 11:13 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 12/17/15 11:13 79-00-51.0 0.20 1Trichloroethene 2.6 ug/L 12/17/15 11:13 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 12/17/15 11:13 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 12/17/15 11:13 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 12/17/15 11:13 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 12/17/15 11:13 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 12/17/15 11:13 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 12/17/15 11:13 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 12/17/15 11:13 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 12/17/15 11:13 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 93 % 12/17/15 11:13 460-00-470-130 1Dibromofluoromethane (S) 99 % 12/17/15 11:13 1868-53-770-130 1Toluene-d8 (S) 99 % 12/17/15 11:13 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 10 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: RW06-28-I-1215-100 Lab ID: 40126180004 Collected: 12/15/15 15:53 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 12/17/15 11:36 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 12/17/15 11:36 107-05-15.0 2.2 1Benzene <0.50 ug/L 12/17/15 11:36 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 12/17/15 11:36 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 12/17/15 11:36 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 12/17/15 11:36 75-27-41.0 0.50 1Bromoform <0.50 ug/L 12/17/15 11:36 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 12/17/15 11:36 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 12/17/15 11:36 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 12/17/15 11:36 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 12/17/15 11:36 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 12/17/15 11:36 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 12/17/15 11:36 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 12/17/15 11:36 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 12/17/15 11:36 75-00-31.0 0.37 1Chloroform <2.5 ug/L 12/17/15 11:36 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 12/17/15 11:36 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 12/17/15 11:36 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 12/17/15 11:36 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 12/17/15 11:36 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 12/17/15 11:36 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 12/17/15 11:36 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 12/17/15 11:36 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 12/17/15 11:36 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 12/17/15 11:36 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 12/17/15 11:36 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 12/17/15 11:36 75-71-81.0 0.22 11,1-Dichloroethane 6.8 ug/L 12/17/15 11:36 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 12/17/15 11:36 107-06-21.0 0.17 11,1-Dichloroethene 1.7 ug/L 12/17/15 11:36 75-35-41.0 0.41 1cis-1,2-Dichloroethene 1.9 ug/L 12/17/15 11:36 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 12/17/15 11:36 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 12/17/15 11:36 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 12/17/15 11:36 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 12/17/15 11:36 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 12/17/15 11:36 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 12/17/15 11:36 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 12/17/15 11:36 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 12/17/15 11:36 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 12/17/15 11:36 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 12/17/15 11:36 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 12/17/15 11:36 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 12/17/15 11:36 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 12/17/15 11:36 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 12/17/15 11:36 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 12/17/15 11:36 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 11 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: RW06-28-I-1215-100 Lab ID: 40126180004 Collected: 12/15/15 15:53 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 12/17/15 11:36 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 12/17/15 11:36 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 12/17/15 11:36 103-65-11.0 0.50 1Styrene <0.50 ug/L 12/17/15 11:36 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 12/17/15 11:36 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 12/17/15 11:36 79-34-51.0 0.25 1Tetrachloroethene 10.0 ug/L 12/17/15 11:36 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 12/17/15 11:36 109-99-95.0 2.0 1Toluene <0.50 ug/L 12/17/15 11:36 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 12/17/15 11:36 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 12/17/15 11:36 120-82-15.0 2.2 11,1,1-Trichloroethane 5.7 ug/L 12/17/15 11:36 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 12/17/15 11:36 79-00-51.0 0.20 1Trichloroethene 0.99J ug/L 12/17/15 11:36 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 12/17/15 11:36 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 12/17/15 11:36 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 12/17/15 11:36 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 12/17/15 11:36 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 12/17/15 11:36 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 12/17/15 11:36 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 12/17/15 11:36 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 12/17/15 11:36 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 94 % 12/17/15 11:36 460-00-470-130 1Dibromofluoromethane (S) 98 % 12/17/15 11:36 1868-53-770-130 1Toluene-d8 (S) 98 % 12/17/15 11:36 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 12 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: RW07-38-I-1215-100 Lab ID: 40126180005 Collected: 12/15/15 15:57 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 12/17/15 11:58 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 12/17/15 11:58 107-05-15.0 2.2 1Benzene <0.50 ug/L 12/17/15 11:58 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 12/17/15 11:58 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 12/17/15 11:58 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 12/17/15 11:58 75-27-41.0 0.50 1Bromoform <0.50 ug/L 12/17/15 11:58 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 12/17/15 11:58 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 12/17/15 11:58 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 12/17/15 11:58 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 12/17/15 11:58 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 12/17/15 11:58 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 12/17/15 11:58 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 12/17/15 11:58 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 12/17/15 11:58 75-00-31.0 0.37 1Chloroform <2.5 ug/L 12/17/15 11:58 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 12/17/15 11:58 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 12/17/15 11:58 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 12/17/15 11:58 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 12/17/15 11:58 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 12/17/15 11:58 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 12/17/15 11:58 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 12/17/15 11:58 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 12/17/15 11:58 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 12/17/15 11:58 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 12/17/15 11:58 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 12/17/15 11:58 75-71-81.0 0.22 11,1-Dichloroethane 13.2 ug/L 12/17/15 11:58 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 12/17/15 11:58 107-06-21.0 0.17 11,1-Dichloroethene 3.9 ug/L 12/17/15 11:58 75-35-41.0 0.41 1cis-1,2-Dichloroethene 5.1 ug/L 12/17/15 11:58 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 12/17/15 11:58 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 12/17/15 11:58 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 12/17/15 11:58 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 12/17/15 11:58 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 12/17/15 11:58 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 12/17/15 11:58 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 12/17/15 11:58 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 12/17/15 11:58 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 12/17/15 11:58 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 12/17/15 11:58 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 12/17/15 11:58 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 12/17/15 11:58 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 12/17/15 11:58 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 12/17/15 11:58 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 12/17/15 11:58 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 13 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: RW07-38-I-1215-100 Lab ID: 40126180005 Collected: 12/15/15 15:57 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 12/17/15 11:58 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 12/17/15 11:58 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 12/17/15 11:58 103-65-11.0 0.50 1Styrene <0.50 ug/L 12/17/15 11:58 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 12/17/15 11:58 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 12/17/15 11:58 79-34-51.0 0.25 1Tetrachloroethene 35.8 ug/L 12/17/15 11:58 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 12/17/15 11:58 109-99-95.0 2.0 1Toluene <0.50 ug/L 12/17/15 11:58 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 12/17/15 11:58 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 12/17/15 11:58 120-82-15.0 2.2 11,1,1-Trichloroethane 7.3 ug/L 12/17/15 11:58 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 12/17/15 11:58 79-00-51.0 0.20 1Trichloroethene 4.6 ug/L 12/17/15 11:58 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 12/17/15 11:58 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 12/17/15 11:58 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 12/17/15 11:58 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 12/17/15 11:58 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 12/17/15 11:58 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 12/17/15 11:58 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 12/17/15 11:58 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 12/17/15 11:58 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 94 % 12/17/15 11:58 460-00-470-130 1Dibromofluoromethane (S) 99 % 12/17/15 11:58 1868-53-770-130 1Toluene-d8 (S) 99 % 12/17/15 11:58 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 14 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: RW06-27-BR-1215-100 Lab ID: 40126180006 Collected: 12/15/15 16:01 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 12/17/15 12:21 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 12/17/15 12:21 107-05-15.0 2.2 1Benzene <0.50 ug/L 12/17/15 12:21 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 12/17/15 12:21 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 12/17/15 12:21 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 12/17/15 12:21 75-27-41.0 0.50 1Bromoform <0.50 ug/L 12/17/15 12:21 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 12/17/15 12:21 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 12/17/15 12:21 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 12/17/15 12:21 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 12/17/15 12:21 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 12/17/15 12:21 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 12/17/15 12:21 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 12/17/15 12:21 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 12/17/15 12:21 75-00-31.0 0.37 1Chloroform <2.5 ug/L 12/17/15 12:21 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 12/17/15 12:21 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 12/17/15 12:21 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 12/17/15 12:21 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 12/17/15 12:21 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 12/17/15 12:21 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 12/17/15 12:21 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 12/17/15 12:21 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 12/17/15 12:21 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 12/17/15 12:21 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 12/17/15 12:21 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 12/17/15 12:21 75-71-81.0 0.22 11,1-Dichloroethane 12.9 ug/L 12/17/15 12:21 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 12/17/15 12:21 107-06-21.0 0.17 11,1-Dichloroethene 4.2 ug/L 12/17/15 12:21 75-35-41.0 0.41 1cis-1,2-Dichloroethene 16.6 ug/L 12/17/15 12:21 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 12/17/15 12:21 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 12/17/15 12:21 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 12/17/15 12:21 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 12/17/15 12:21 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 12/17/15 12:21 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 12/17/15 12:21 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 12/17/15 12:21 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 12/17/15 12:21 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 12/17/15 12:21 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 12/17/15 12:21 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 12/17/15 12:21 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 12/17/15 12:21 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 12/17/15 12:21 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 12/17/15 12:21 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 12/17/15 12:21 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 15 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: RW06-27-BR-1215-100 Lab ID: 40126180006 Collected: 12/15/15 16:01 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 12/17/15 12:21 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 12/17/15 12:21 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 12/17/15 12:21 103-65-11.0 0.50 1Styrene <0.50 ug/L 12/17/15 12:21 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 12/17/15 12:21 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 12/17/15 12:21 79-34-51.0 0.25 1Tetrachloroethene 30.1 ug/L 12/17/15 12:21 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 12/17/15 12:21 109-99-95.0 2.0 1Toluene <0.50 ug/L 12/17/15 12:21 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 12/17/15 12:21 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 12/17/15 12:21 120-82-15.0 2.2 11,1,1-Trichloroethane 7.3 ug/L 12/17/15 12:21 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 12/17/15 12:21 79-00-51.0 0.20 1Trichloroethene 5.8 ug/L 12/17/15 12:21 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 12/17/15 12:21 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 12/17/15 12:21 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 12/17/15 12:21 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 12/17/15 12:21 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 12/17/15 12:21 108-67-81.0 0.50 1Vinyl chloride 0.31J ug/L 12/17/15 12:21 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 12/17/15 12:21 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 12/17/15 12:21 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 93 % 12/17/15 12:21 460-00-470-130 1Dibromofluoromethane (S) 98 % 12/17/15 12:21 1868-53-770-130 1Toluene-d8 (S) 99 % 12/17/15 12:21 2037-26-570-130 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
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Page 16 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40126180007 Collected: 12/15/15 16:05 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Acetone <3.0 ug/L 12/17/15 12:43 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 12/17/15 12:43 107-05-15.0 2.2 1Benzene <0.50 ug/L 12/17/15 12:43 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 12/17/15 12:43 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 12/17/15 12:43 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 12/17/15 12:43 75-27-41.0 0.50 1Bromoform <0.50 ug/L 12/17/15 12:43 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 12/17/15 12:43 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 12/17/15 12:43 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 12/17/15 12:43 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 12/17/15 12:43 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 12/17/15 12:43 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 12/17/15 12:43 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 12/17/15 12:43 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 12/17/15 12:43 75-00-31.0 0.37 1Chloroform <2.5 ug/L 12/17/15 12:43 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 12/17/15 12:43 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 12/17/15 12:43 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 12/17/15 12:43 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 12/17/15 12:43 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 12/17/15 12:43 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 12/17/15 12:43 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 12/17/15 12:43 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 12/17/15 12:43 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 12/17/15 12:43 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 12/17/15 12:43 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 12/17/15 12:43 75-71-81.0 0.22 11,1-Dichloroethane 13.8 ug/L 12/17/15 12:43 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 12/17/15 12:43 107-06-21.0 0.17 11,1-Dichloroethene 4.6 ug/L 12/17/15 12:43 75-35-41.0 0.41 1cis-1,2-Dichloroethene 11.7 ug/L 12/17/15 12:43 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 12/17/15 12:43 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 12/17/15 12:43 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 12/17/15 12:43 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 12/17/15 12:43 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 12/17/15 12:43 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 12/17/15 12:43 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 12/17/15 12:43 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 12/17/15 12:43 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 12/17/15 12:43 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 12/17/15 12:43 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 12/17/15 12:43 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 12/17/15 12:43 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 12/17/15 12:43 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 12/17/15 12:43 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 12/17/15 12:43 108-10-15.0 2.1 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
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Page 17 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Sample: SE EFFLUENT Lab ID: 40126180007 Collected: 12/15/15 16:05 Received: 12/16/15 08:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 82608260 MSV
Methyl-tert-butyl ether <0.17 ug/L 12/17/15 12:43 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 12/17/15 12:43 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 12/17/15 12:43 103-65-11.0 0.50 1Styrene <0.50 ug/L 12/17/15 12:43 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 12/17/15 12:43 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 12/17/15 12:43 79-34-51.0 0.25 1Tetrachloroethene 39.8 ug/L 12/17/15 12:43 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 12/17/15 12:43 109-99-95.0 2.0 1Toluene <0.50 ug/L 12/17/15 12:43 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 12/17/15 12:43 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 12/17/15 12:43 120-82-15.0 2.2 11,1,1-Trichloroethane 11.4 ug/L 12/17/15 12:43 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 12/17/15 12:43 79-00-51.0 0.20 1Trichloroethene 5.2 ug/L 12/17/15 12:43 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 12/17/15 12:43 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 12/17/15 12:43 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 12/17/15 12:43 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 12/17/15 12:43 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 12/17/15 12:43 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 12/17/15 12:43 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 12/17/15 12:43 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 12/17/15 12:43 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 95 % 12/17/15 12:43 460-00-470-130 1Dibromofluoromethane (S) 98 % 12/17/15 12:43 1868-53-770-130 1Toluene-d8 (S) 100 % 12/17/15 12:43 2037-26-570-130 1
Analytical Method: SM 2540D2540D Total Suspended Solids
Total Suspended Solids <0.95 mg/L 12/17/15 14:402.0 0.95 1
Analytical Method: SM 4500-H+B4500H+ pH, Electrometric
pH 7.2 Std. Units 12/16/15 12:30 H60.10 0.010 1
Analytical Method: EPA 410.4 Preparation Method: EPA 410.4410.4 COD
Chemical Oxygen Demand 17.5J mg/L 12/23/15 12:0012/23/15 08:5350.0 11.6 1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 18 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
MSV/31647EPA 8260
EPA 82608260 MSV
Associated Lab Samples: 40126180001, 40126180002, 40126180003, 40126180004, 40126180005, 40126180006, 40126180007
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1275240Associated Lab Samples: 40126180001, 40126180002, 40126180003, 40126180004, 40126180005, 40126180006, 40126180007
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 12/17/15 08:270.181,1,1-Trichloroethane ug/L <0.50 1.0 12/17/15 08:270.501,1,2,2-Tetrachloroethane ug/L <0.25 1.0 12/17/15 08:270.251,1,2-Trichloroethane ug/L <0.20 1.0 12/17/15 08:270.201,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 12/17/15 08:270.811,1-Dichloroethane ug/L <0.24 1.0 12/17/15 08:270.241,1-Dichloroethene ug/L <0.41 1.0 12/17/15 08:270.411,1-Dichloropropene ug/L <0.44 1.0 12/17/15 08:270.441,2,3-Trichlorobenzene ug/L <2.1 5.0 12/17/15 08:272.11,2,3-Trichloropropane ug/L <0.50 1.0 12/17/15 08:270.501,2,4-Trichlorobenzene ug/L <2.2 5.0 12/17/15 08:272.21,2,4-Trimethylbenzene ug/L <0.50 1.0 12/17/15 08:270.501,2-Dibromo-3-chloropropane ug/L <2.2 5.0 12/17/15 08:272.21,2-Dibromoethane (EDB) ug/L <0.18 1.0 12/17/15 08:270.181,2-Dichlorobenzene ug/L <0.50 1.0 12/17/15 08:270.501,2-Dichloroethane ug/L <0.17 1.0 12/17/15 08:270.171,2-Dichloropropane ug/L <0.23 1.0 12/17/15 08:270.231,3,5-Trimethylbenzene ug/L <0.50 1.0 12/17/15 08:270.501,3-Dichlorobenzene ug/L <0.50 1.0 12/17/15 08:270.501,3-Dichloropropane ug/L <0.50 1.0 12/17/15 08:270.501,4-Dichlorobenzene ug/L <0.50 1.0 12/17/15 08:270.502,2-Dichloropropane ug/L <0.48 1.0 12/17/15 08:270.482-Butanone (MEK) ug/L <3.0 20.0 12/17/15 08:273.02-Chlorotoluene ug/L <0.50 1.0 12/17/15 08:270.504-Chlorotoluene ug/L <0.21 1.0 12/17/15 08:270.214-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 12/17/15 08:272.1Acetone ug/L <3.0 20.0 12/17/15 08:273.0Allyl chloride ug/L <2.2 5.0 12/17/15 08:272.2Benzene ug/L <0.50 1.0 12/17/15 08:270.50Bromobenzene ug/L <0.23 1.0 12/17/15 08:270.23Bromochloromethane ug/L <0.34 1.0 12/17/15 08:270.34Bromodichloromethane ug/L <0.50 1.0 12/17/15 08:270.50Bromoform ug/L <0.50 1.0 12/17/15 08:270.50Bromomethane ug/L <2.4 5.0 12/17/15 08:272.4Carbon tetrachloride ug/L <0.50 1.0 12/17/15 08:270.50Chlorobenzene ug/L <0.50 1.0 12/17/15 08:270.50Chloroethane ug/L <0.37 1.0 12/17/15 08:270.37Chloroform ug/L <2.5 5.0 12/17/15 08:272.5Chloromethane ug/L <0.50 1.0 12/17/15 08:270.50cis-1,2-Dichloroethene ug/L <0.26 1.0 12/17/15 08:270.26cis-1,3-Dichloropropene ug/L <0.50 1.0 12/17/15 08:270.50
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 19 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1275240Associated Lab Samples: 40126180001, 40126180002, 40126180003, 40126180004, 40126180005, 40126180006, 40126180007
Matrix: Water
AnalyzedMDL
Dibromochloromethane ug/L <0.50 1.0 12/17/15 08:270.50Dibromomethane ug/L <0.43 1.0 12/17/15 08:270.43Dichlorodifluoromethane ug/L <0.22 1.0 12/17/15 08:270.22Dichlorofluoromethane ug/L <0.21 1.0 12/17/15 08:270.21Diethyl ether (Ethyl ether) ug/L <2.2 5.0 12/17/15 08:272.2Ethylbenzene ug/L <0.50 1.0 12/17/15 08:270.50Hexachloro-1,3-butadiene ug/L <2.1 5.0 12/17/15 08:272.1Isopropylbenzene (Cumene) ug/L <0.14 1.0 12/17/15 08:270.14m&p-Xylene ug/L <1.0 2.0 12/17/15 08:271.0Methyl-tert-butyl ether ug/L <0.17 1.0 12/17/15 08:270.17Methylene Chloride ug/L <0.23 1.0 12/17/15 08:270.23n-Butylbenzene ug/L <0.50 1.0 12/17/15 08:270.50n-Propylbenzene ug/L <0.50 1.0 12/17/15 08:270.50Naphthalene ug/L <2.5 5.0 12/17/15 08:272.5o-Xylene ug/L <0.50 1.0 12/17/15 08:270.50p-Isopropyltoluene ug/L <0.50 1.0 12/17/15 08:270.50sec-Butylbenzene ug/L <2.2 5.0 12/17/15 08:272.2Styrene ug/L <0.50 1.0 12/17/15 08:270.50tert-Butylbenzene ug/L <0.18 1.0 12/17/15 08:270.18Tetrachloroethene ug/L <0.50 1.0 12/17/15 08:270.50Tetrahydrofuran ug/L <2.0 5.0 12/17/15 08:272.0Toluene ug/L <0.50 1.0 12/17/15 08:270.50trans-1,2-Dichloroethene ug/L <0.26 1.0 12/17/15 08:270.26trans-1,3-Dichloropropene ug/L <0.23 1.0 12/17/15 08:270.23Trichloroethene ug/L <0.33 1.0 12/17/15 08:270.33Trichlorofluoromethane ug/L <0.18 1.0 12/17/15 08:270.18Vinyl chloride ug/L <0.18 1.0 12/17/15 08:270.184-Bromofluorobenzene (S) % 93 70-130 12/17/15 08:27Dibromofluoromethane (S) % 98 70-130 12/17/15 08:27Toluene-d8 (S) % 99 70-130 12/17/15 08:27
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1275241LABORATORY CONTROL SAMPLE:LCSSpike
1,1,1-Trichloroethane ug/L 45.350 91 70-1301,1,2,2-Tetrachloroethane ug/L 51.550 103 70-1301,1,2-Trichloroethane ug/L 52.350 105 70-1301,1,2-Trichlorotrifluoroethane ug/L 47.750 95 50-1501,1-Dichloroethane ug/L 43.950 88 70-1301,1-Dichloroethene ug/L 44.550 89 70-1301,2,4-Trichlorobenzene ug/L 47.150 94 70-1301,2-Dibromo-3-chloropropane ug/L 45.650 91 50-1501,2-Dibromoethane (EDB) ug/L 51.850 104 70-1301,2-Dichlorobenzene ug/L 50.550 101 70-130
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 20 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1275241LABORATORY CONTROL SAMPLE:LCSSpike
1,2-Dichloroethane ug/L 43.950 88 70-1311,2-Dichloropropane ug/L 46.950 94 70-1301,3-Dichlorobenzene ug/L 50.650 101 70-1301,4-Dichlorobenzene ug/L 49.850 100 70-130Benzene ug/L 49.050 98 70-130Bromodichloromethane ug/L 46.850 94 70-130Bromoform ug/L 56.350 113 68-130Bromomethane ug/L 39.050 78 38-137Carbon tetrachloride ug/L 47.750 95 70-130Chlorobenzene ug/L 54.550 109 70-130Chloroethane ug/L 36.350 73 70-136Chloroform ug/L 46.450 93 70-130Chloromethane ug/L 34.650 69 48-144cis-1,2-Dichloroethene ug/L 44.250 88 70-130cis-1,3-Dichloropropene ug/L 46.050 92 70-130Dibromochloromethane ug/L 55.150 110 70-130Dichlorodifluoromethane ug/L 36.250 72 33-157Ethylbenzene ug/L 50.750 101 70-132Isopropylbenzene (Cumene) ug/L 50.950 102 70-130m&p-Xylene ug/L 104100 104 70-131Methyl-tert-butyl ether ug/L 39.650 79 48-141Methylene Chloride ug/L 44.650 89 70-130o-Xylene ug/L 50.150 100 70-131Styrene ug/L 50.950 102 70-130Tetrachloroethene ug/L 53.950 108 70-130Toluene ug/L 51.150 102 70-130trans-1,2-Dichloroethene ug/L 45.450 91 70-130trans-1,3-Dichloropropene ug/L 45.750 91 70-130Trichloroethene ug/L 50.950 102 70-130Trichlorofluoromethane ug/L 45.750 91 50-150Vinyl chloride ug/L 46.350 93 65-1424-Bromofluorobenzene (S) % 97 70-130Dibromofluoromethane (S) % 98 70-130Toluene-d8 (S) % 100 70-130
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1275242MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40126180002
1275243
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 250 94 70-13098 3 20250106 341 3521,1,2,2-Tetrachloroethane ug/L 250 103 70-130104 1 20250<1.2 257 2601,1,2-Trichloroethane ug/L 250 104 70-130105 1 20250<0.99 260 2621,1,2-Trichlorotrifluoroethane ug/L 250 97 50-15198 1 20250<4.1 244 2451,1-Dichloroethane ug/L 250 88 70-13489 1 2025048.8 269 2721,1-Dichloroethene ug/L 250 91 70-13991 0 2025020.2 247 247
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
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Green Bay, WI 54302(920)469-2436
Page 21 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1275242MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40126180002
1275243
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,2,4-Trichlorobenzene ug/L 250 95 70-13098 2 20250<11.0 238 2441,2-Dibromo-3-chloropropane
ug/L 250 92 50-15093 1 20250<10.8 231 233
1,2-Dibromoethane (EDB) ug/L 250 104 70-130105 1 20250<0.89 261 2631,2-Dichlorobenzene ug/L 250 103 70-130105 2 20250<2.5 257 2631,2-Dichloroethane ug/L 250 88 70-13287 0 20250<0.84 219 2191,2-Dichloropropane ug/L 250 94 70-13096 2 20250<1.2 236 2401,3-Dichlorobenzene ug/L 250 103 70-130104 1 20250<2.5 259 2611,4-Dichlorobenzene ug/L 250 101 70-130103 2 20250<2.5 253 258Benzene ug/L 250 99 70-130100 1 20250<2.5 248 250Bromodichloromethane ug/L 250 95 70-13296 1 20250<2.5 238 240Bromoform ug/L 250 111 68-130112 1 20250<2.5 278 280Bromomethane ug/L 250 91 38-14195 4 20250<12.2 229 239Carbon tetrachloride ug/L 250 98 70-13097 2 20250<2.5 246 242Chlorobenzene ug/L 250 110 70-130111 0 20250<2.5 276 276Chloroethane ug/L 250 74 66-15275 1 20250<1.9 186 187Chloroform ug/L 250 94 70-13095 1 20250<12.5 237 239Chloromethane ug/L 250 73 44-15173 0 20250<2.5 182 183cis-1,2-Dichloroethene ug/L 250 89 70-13089 1 2025028.4 251 252cis-1,3-Dichloropropene ug/L 250 93 70-13095 2 20250<2.5 233 237Dibromochloromethane ug/L 250 112 70-130111 0 20250<2.5 279 279Dichlorodifluoromethane ug/L 250 72 29-16073 0 20250<1.1 181 182Ethylbenzene ug/L 250 103 70-132102 1 20250<2.5 257 255Isopropylbenzene (Cumene) ug/L 250 103 70-130104 1 20250<0.72 258 261m&p-Xylene ug/L 500 104 70-131106 2 20500<5.0 519 530Methyl-tert-butyl ether ug/L 250 79 48-14380 1 20250<0.87 198 200Methylene Chloride ug/L 250 91 70-13092 0 20250<1.2 228 229o-Xylene ug/L 250 100 70-131102 2 20250<2.5 251 256Styrene ug/L 250 103 70-130103 0 20250<2.5 258 258Tetrachloroethene ug/L 250 117 70-130112 2 20250232 523 511Toluene ug/L 250 105 70-130104 1 20250<2.5 262 260trans-1,2-Dichloroethene ug/L 250 93 70-13293 0 20250<1.3 233 233trans-1,3-Dichloropropene ug/L 250 93 70-13093 0 20250<1.1 232 233Trichloroethene ug/L 250 104 70-130104 0 2025012.2 271 272Trichlorofluoromethane ug/L 250 92 50-15393 1 20250<0.92 231 234Vinyl chloride ug/L 250 95 60-15596 1 20250<0.88 237 2414-Bromofluorobenzene (S) % 96 70-13096Dibromofluoromethane (S) % 99 70-13097Toluene-d8 (S) % 101 70-13099
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 22 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
WET/24058SM 2540D
SM 2540D2540D Total Suspended Solids
Associated Lab Samples: 40126180007
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1275841Associated Lab Samples: 40126180007
Matrix: Water
AnalyzedMDL
Total Suspended Solids mg/L <0.48 1.0 12/17/15 14:400.48
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1275842LABORATORY CONTROL SAMPLE:LCSSpike
Total Suspended Solids mg/L 94.0100 94 80-120
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401261770011275843SAMPLE DUPLICATE:
Total Suspended Solids mg/L 161 4 5167
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401261820011275844SAMPLE DUPLICATE:
Total Suspended Solids mg/L 30.0 R117 535.5
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 23 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
WET/24049SM 4500-H+B
SM 4500-H+B4500H+B pH
Associated Lab Samples: 40126180007
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
401260990011275202SAMPLE DUPLICATE:
pH Std. Units 9.8 H60 59.8
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 24 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:QC Batch Method:
Analysis Method:Analysis Description:
WETA/31828EPA 410.4
EPA 410.4410.4 COD
Associated Lab Samples: 40126180007
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 1277626Associated Lab Samples: 40126180007
Matrix: Water
AnalyzedMDL
Chemical Oxygen Demand mg/L <11.6 50.0 12/23/15 12:0011.6
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
1277627LABORATORY CONTROL SAMPLE:LCSSpike
Chemical Oxygen Demand mg/L 527500 105 90-110
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1277628MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40126228001
1277629
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
Chemical Oxygen Demand mg/L 5000 100 90-110105 3 1050002230 7240 7470
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
1277630MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
40126230001
1277631
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
Chemical Oxygen Demand mg/L 526 108 90-110105 3 10526<12.2 582 562
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 25 of 29
#=QL#
QUALIFIERS
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Green BayPASI-G
ANALYTE QUALIFIERS
Analysis initiated outside of the 15 minute EPA recommended holding time.H6RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 26 of 29
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:Project:
40126180023-6105-016 CP-SHOREHAM YARD
Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch
40126180001 MSV/31647121515-0800-200 EPA 826040126180002 MSV/31647RW07-39-SP-1215-100 EPA 826040126180003 MSV/31647RW07-40-SP-1215-100 EPA 826040126180004 MSV/31647RW06-28-I-1215-100 EPA 826040126180005 MSV/31647RW07-38-I-1215-100 EPA 826040126180006 MSV/31647RW06-27-BR-1215-100 EPA 826040126180007 MSV/31647SE EFFLUENT EPA 8260
40126180007 WET/24058SE EFFLUENT SM 2540D
40126180007 WET/24049SE EFFLUENT SM 4500-H+B
40126180007 WETA/31828 WETA/31831SE EFFLUENT EPA 410.4 EPA 410.4
REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/28/2015 02:38 PM
Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9
Green Bay, WI 54302(920)469-2436
Page 27 of 29
Pag
e 28
of 2
9
----:::=::=-.::::~~~--
UPPER MIDWEST REGION ~-MN: 612-601-1100 wi: 92<:::-2436 G re e "'1
Quote#:
CHAIN OF CUSTODY Mail To Contact:
*Preservation Code! Project Number: QL3 - 6 ( 0 J ~0 l 6 A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH
Project Name: C p ~ S'~o re lil"l wt Yct: ro( H=Sodium Bisulfate Solution
Project State: fa\ N FILTERED? (YES/NO)
Sampled By (Print): .A{q .II ft f' PRESERVATION (CODE)*
Sampled By (Sign):
PO#: l. -I 'Lo "l.. Data Package Options
(billable)
0 EPA level Ill
0 EPA Level IV
MSIMSD 0 On your sample
(billable) O NOT needed on
your sample
PACE LAB# CLIENT FIELD ID
I 2J515-C'SOO .-.2.00
Regulatory Pr ram:
Matrix Codes A=Air W=Water B = Biota OW = Drinking Water C = Charcoal GW = Ground Water O =Oil SW= Surface Water S = Soil WW = Waste Water Sl=Slud e WP=Wi
COLLECTION
DATI! TIME
f\.Wl96-2..7~~fl-12...t5-l~
!=Sodium Thiosulfate J=Other
Mail To Company:
Mail To Address:
Invoice To Contact:
Invoice To Company:
Invoice To Address:
Invoice To Phone:
CLIENT COMMENTS
LAB COMMENTS Profile#
Rush Turnaround Time Requested - Prelims (Rush TAT subject to approval/surcharge)
Date Needed:
PACE Project No.
Transmit Prelim Rush Results by (complete what you want):
Emall#1:
Emall#2:
11-T_e_le"-ph_o_n_e_: -1-----------------i!Relinquished By: Fax:
Samples on HOLD are subject to
special pricing and release of llablllty
C019a(27Jun2006)
Relinquished By:
Date/Time:
Date/Time: Received By: Date/Time:
Date/Time: Received By: Date/Time:
Page 29 of 29
aeAnalytica/" ~lient Name: \1-t\~€{'
Sample Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9
Green Bay, WI 54302
Project#:
Courier: r Fed. Exr UPS ~ Client r Pace ::>ther: \},.')Cl}.\c_n Tracking #: C\ ::)~ :J "3 ~ · .3 Custody Seal on Cooler/Box Present: rf yes - no Seals intact: r/ yes r no
Custody Seal on Samples Present: r yes f( no Seals intact: r yes f no
WO#: 40126180~
111111 1111111111111111 40126180
Packing Material: r/ Bubble Wrap Bubble Bags r None . r Other
Thermometer Used "'5 . - \.\ Type of Ice~ Blue Dry None Samples on ice, cooling process has begun
Cooler Temperature Uncorr: \ /Corr: \ 'iiofogical Tissue is Frozen: r yes
Temp Blank Present: r yes f'{ no
Temp should be above freezing to 6°C for all sample except Biota. Frozen Biota Samples should be received s o•c. Comments:
Chain of Custody Present:
Chain of Custody Filled Out:
Chain of Custody Relinquished:
Sampler Name & Signature on COC:
Samples Arrived within Hold Time:
- VOA Samples frozen upon receipt
Short Hold Time Analysis (<72hr):
Rush Turn Around Time Requested:
Sufficient Volume:
Correct Containers Used:
-Pace Containers Used:
-Pace IR Containers Used:
Containers Intact:
Filtered volume received for Dissolved tests
Sample Labels match COC:
-Includes date/time/ID/Analysis Matrix:
lj]Yes 0No
/rj.Jves ONo
'l}l'ves ONo
¢ves ONo
¢ves ONo
0Yes ONo
0Yes ONo
0Yes OJNo
c/ves ONo
~es ONo
es ONo
0Yes ONo
ON/A 1.
ON/A 2.
ON/A 3.
ON/A 4.
ON/A 5.
Date/Time:
ON/A 6.
ON/A 7.
ON/A 8.
ON/A 9.
ON/A
i;z1N/A
r;ives ONo ON/A 10.
0Yes ONo r/JN/A 11.
r;ves ONo ON/A 12.
\ i \
r no Person examining co1t::3: Date: \;.:;l- \la · ~ Initials: ~" •
• F\
All containers needing preservation have been checked. .J. -(Non-Compliance noted in 13.) )l.JYes ONo ON/A 13. AU co~tainer5 needing preserv"'atioo are fou~d to be-in - - - - - - - - - - - -
r HN03 1 H2S04 r NaOH r NaOH +ZnAct
complianc0 '" i=~• recommendation. riiv ON ON/A
(HN03, i6S04 .:;~aOH+ZnAct ~9. NaOH ~12) T es 0
e~Piions: l"Q_9oiitorm~ foe, TOX, TOH,- - - - - - - - - ,.I. - - - - - - - - _..,.ln""'it""ia..,..I wh_,...e_n ____ ....., IL'""ab_S.,..t-d'""'#""'ID,...o""f------.11""""1..1•a11""e...-1-------i O&G, WIDRbW, Phenolics, OTHER: tpYes ONo completed t\I\~ \fpreservative Time:
Headspace in VOA Vials ( >6mm): Oves [lf No ON/A 14.
Trip Blank Present: r/Jves ONo ON/A 15.
Trip Blank Custody Seals Present }tlves ONo ON/A
Pace Trip Blank Lot# (if purchased):(' C\~ ·~ I l,-.,'-\ \ · 0 \ ~ \ Client Notification/ Resolution: If checked, see attached form for additional comments LJ
Project Manager Review: Date:
F-GB-C-031-Rev.03 (9April2015) SCUR Fonn