semi‐annual groundwater monitoring report

6835 International Center Boulevard, Suite 5, Fort Myers, Florida 33912 www.ermi.net • 888‐368‐6468 • Fax: 888‐368‐6329

SEMI‐ANNUAL GROUNDWATER MONITORING REPORT

West Felda Tank Battery Latitude: 26.527957, Longitude: ‐81.544631

Hendry County, Florida

PREPARED FOR:

Mr. Eric Hasso HSE Advisor I

Maverick Natural Resources, LLC 1111 Bagby Street, Suite 1600

Houston, Texas 77002

SUBMITTED TO:

Mr. Pierre Bruno Professional Geologist II

Florida DEP/Mining, Mitigation and Delineation Oil & Gas Section ‐ Fort Myers Field Office

2295 Victoria Avenue Suite 364

Fort Myers, Florida 33901

PREPARED BY:

ENVIRONMENTAL RISK MANAGEMENT, INC.

ERMI File No. E3492E

November 30, 2020


November 30, 2020 Mr. Eric W. Hasso HSE Advisor I Maverick Natural Resources, LLC (Parent of Breitburn Operating LP) 1111 Bagby Street, Suite 1600 Houston, Texas 77002 RE: Semi‐Annual Groundwater Monitoring Report

West Felda ‐ Tank Battery Latitude: 26.527957, Longitude: ‐81.544631 Hendry County, Florida ERMI File No. E3492E

Dear Mr. Hasso: Environmental Risk Management, Inc. (ERMI) is pleased to present the following report detailing the results of the recent groundwater assessment conducted at the above referenced facility. Should you have any questions or concerns, please contact either of the undersigned at (239) 415‐6406 to discuss the project.

Sincerely, ENVIRONMENTAL RISK MANAGEMENT, INC. Jonathan Ascher, LEP Barry Murphree, PG Project Manager Principal Geologist


CERTIFICATION

FOR

SEMI‐ANNUAL GROUNDWATER MONITORING REPORT

West Felda ‐ Tank Battery Latitude: 26.527957, Longitude: ‐81.544631

Hendry County, Florida ERMI File No. E3492E

PROFESSIONAL GEOLOGIST CERTIFICATION Environmental Risk Management, Inc. hereby certifies the reliability and accuracy of the services performed in this investigation, and the information presented in this report. This report is based on professional services that were conducted using sound geologic principles and “Standard of Industry” practices. Data derived through sampling and subsequent laboratory analysis are extrapolated to render an opinion about overall subsurface conditions. Actual conditions in areas not tested may differ from those inferred to exist. Prepared by Environmental Risk Management, Inc. 6835 International Center Boulevard, Suite 5 Fort Myers, Florida 33912 Certificate of Authorization #GB367 Signed, Sam B. Murphree IV, PG Licensed Professional Geologist State of Florida, License Number PG‐2664

The item has been electronically signed and sealed by Sam B. Murphree, IV, P.G., on the date adjacent to the seal using a SHA authentication code.

Printed copies of the document are not considered signed and sealed and the SHA authentication code must be verified on any electronic copies.

Table of Contents

1.0 INTRODUCTION ................................................................................................. 1 1.1 Site History ......................................................................................................................... 1

2.0 SCOPE OF WORK ............................................................................................... 1 3.0 GROUNDWATER ASSESSMENT ......................................................................... 1

3.1 Groundwater Sampling Methodology ............................................................................... 1 3.2 Groundwater Laboratory Analytical Results...................................................................... 2 3.3 Groundwater Elevation Summary ..................................................................................... 2

4.0 CONCLUSIONS ................................................................................................... 2

List of Figures

Figure 1: Site Map Figure 2: Groundwater Analytical Map Figure 3: Groundwater Elevation Map – October 5, 2020

List of Tables

Table 1: Groundwater Analytical Summary ‐ Chloride & TRPHs Table 2: Groundwater Elevation Summary

List of Appendices

Appendix A: Field Notes, Sampling Logs, and Instrument Calibration Forms Appendix B: Laboratory Analytical Report and Chain‐of‐Custody Documentation

West Felda – Tank Battery November 30, 2020 Semi‐Annual Groundwater Monitoring Report Page 1 of 2

Environmental Risk Management, Inc. ERMI File No. E3492E

1.0 INTRODUCTION

1.1 Site History

According to the regulatory file review, several spill incidents of crude oil and saltwater have occurred at the West Felda Tank Battery facility from 1982 through 2015. The spills have been attributed to overfill events, corrosion of flow lines, and equipment malfunctions. Prompt reporting of spill incidents and remedial action in the form of vacuum truck removal of spilled products, soil excavation of impacted areas, and groundwater monitoring were completed following each spill incident.

Since March 4, 2016, Environmental Risk Management, Inc. (ERMI) has conducted semi‐annual groundwater monitoring activities to identify potential contaminants associated with site operations. This report summarizes the groundwater monitoring activities conducted by ERMI staff at the above referenced facility on October 5, 2020.

2.0 SCOPE OF WORK

The following scope of work was completed:

On October 5, 2020, ERMI personnel collected groundwater samples from five (5) monitoring wells (WF‐P1, WF‐M14R, WF‐M23R, WF‐M24, and WF‐M27) for laboratory analysis of chloride using EPA Method 325.2. Additionally, groundwater samples collected from monitoring wells WF‐P1 and WF‐M27 were analyzed for total recoverable petroleum hydrocarbons (TRPHs) using the State of Florida FL‐PRO Method.

All groundwater samples collected during this assessment were submitted to TestAmerica Laboratories, Inc. (TAL) for laboratory analysis. TAL maintains Department of Health certification DOH #E81010.

ERMI prepared this Groundwater Monitoring Report to document on‐site groundwater quality at the above referenced facility.

3.0 GROUNDWATER ASSESSMENT

3.1 Groundwater Sampling Methodology

On October 5, 2020, ERMI personnel collected groundwater samples from five (5) monitoring wells (WF‐P1, WF‐M14R, WF‐M23R, WF‐M24, and WF‐M27) for laboratory analysis of chloride using EPA Method 325.2. Additionally, groundwater samples collected from monitoring wells WF‐P1 and WF‐M27 were analyzed for TRPHs using the State of Florida FL‐PRO Method.

West Felda – Tank Battery November 30, 2020 Semi‐Annual Groundwater Monitoring Report Page 2 of 2

Environmental Risk Management, Inc. ERMI File No. E3492E

All groundwater samples were collected in accordance with the Florida Department of Environmental Protection (FDEP) Standard Operating Procedures (SOP) 01/001 FS 2200 Groundwater Sampling protocol. The wells were purged prior to sampling using a peristaltic pump until the wells met purge completion criteria. Purge water was dispersed onto a nearby impervious surface and allowed to evaporate.

All groundwater samples were submitted to TAL for analysis under sample chain‐of‐custody procedure. Field notes, FDEP groundwater sampling logs, and instrument calibration forms are provided in Appendix A.

3.2 Groundwater Laboratory Analytical Results

Copies of the complete laboratory analytical data report and sample chain‐of‐custody documentation are included in Appendix B.

Laboratory analysis of groundwater samples collected from monitoring wells WF‐P1, WF‐M14R, WF‐M23R, WF‐M24, and WF‐M27 did not yield detections of chloride or TRPHs greater than the established State of Florida Groundwater Cleanup Target Levels (GCTLs) outlined in Tables I and Chapter 62‐777, Florida Administrative Code (F.A.C.).

Please refer to Table 1 for a Summary of Groundwater Analytical Results. Figure 1 and Figure 2 illustrates the groundwater sample locations and a summary of laboratory analytical results, respectively.

3.3 Groundwater Elevation Summary

On March 4, 2016, ERMI personnel conducted a top of casing (TOC) elevation survey on three (3) shallow monitoring wells (WF‐P1, WF‐M24, and WF‐M27) to determine the site‐specific groundwater flow direction. The TOC survey was conducted using a self‐leveling transit. An arbitrary benchmark was used for transit placement.

On October 5, 2020, ERMI personnel collected depth‐to‐water (DTW) measurements from each sampled well. According to the October 5, 2020 data, the groundwater gradient in the shallow well interval (2 to 20 feet below land surface [bls]) suggests that groundwater flows southwest across the site.

Relative groundwater elevations are summarized in Table 2.

Figure 3 depicts the water table contours and inferred groundwater flow direction using shallow monitoring wells.

4.0 CONCLUSIONS

Based on the site assessment activities, ERMI concludes the following:

Laboratory analysis of all groundwater samples collected on October 5, 2020 did not yield any detection of contaminants of concern (COCs) greater than the State of Florida CTLs.

FIGURES

WF-P1

WF-M27

WF-M14R

WF-M23R

WF-M24

WF-M25

Monitoring Well Location

Destroyed Monitoring Well Location

FIGURE 1:

Site Map

West Felda Tank Battery

Latitude: 26.527957

Longitude: -81.544631


APPROXIMATE SCALE

1" = 120'

LEGEND

October 2020ERMI FILE # E3492E

DRAFTED BY: ZJM

REVIEWED BY: JMA

WF-P1

WF-M27

WF-M14R

WF-M23R

WF-M24

Well Identification

Sample Date

T TRPHs

C Chloride

U = Below Detection Limit

Bold = Exceeds GCTL or NADC

-- = Not Analyzed

GCTLS = Groundwater

Cleanup Target Levels

NADCs = Natural Attenuation

Default Concentrations

TRPH = Total Recoverable

Petroleum Hydrocarbons

Contaminant Concentrations

all values in milligrams per Liter

WF-M25

WF-M14R

10/5/2020

T

C

--

240

WF-M24

10/5/2020

T

C

--

48

WF-P1

10/5/2020

T

C

0.33 U

1.4 U

WF-M23R

10/5/2020

T

C

--

38

WF-M27

10/5/2020

T

C

0.39 U

25



FIGURE 2:

Groundwater Analytical

Map


Latitude: 26.527957



APPROXIMATE SCALE

1" = 120'

LEGEND


DRAFTED BY: ZMA

REVIEWED BY: JMA

WF-P1

WF-M27

93.67

WF-M14R

WF-M23R

WF-M24

91.31

WF-M25

90.00

92.00

94.00

93.52


Relative Groundwater

Elevation (ft)

89.50

Groundwater Flow Direction


FIGURE 3:

Groundwater Elevation Map

October 5, 2020


Latitude: 26.527957



APPROXIMATE SCALE

1" = 120'

LEGEND


DRAFTED BY: ZMA

REVIEWED BY: JMA

TABLES

Facility Name: West Felda Tank Battery

Location Date (mg/L) (mg/L)

GCTLs 250 5

NADCs 2,500 500

WF-P1 April 2015 9.7 --

March 2016 3.2 0.35

September 2016 1.4 I 0.075 U

April 2017 35 1.6

October 2017 9.5 0.47

April 2018 4.3 3.0

October 2018 1.4 U 0.14 IV J3

April 2019 6.6 1.8

October 2019 2.2 0.35 U

April 2020 23 0.33 U

October 2020 1.4 U 0.33 U

WF-M14R April 2015 Not Sampled - inaccessible --

March 2016 550 --

September 2016 48 --

April 2017 930 --

October 2017 230 --

April 2018 400 --

October 2018 290 --

April 2019 290 --

October 2019 350 --

April 2020 320 --

October 2020 240

WF-M23R April 2015 660 --

March 2016 130 --


April 2017 73 --

October 2017 31 --

April 2018 48 --

October 2018 44 --

April 2019 45 --

October 2019 40 --

April 2020 46 --

October 2020 38

ChlorideSample TRPHs

TABLE 1: GROUNDWATER ANALYTICAL SUMMARY - Chloride & TRPHs

E3492E Analytical Data Table 1 of 2 ERMI File No. E3492E


Location Date (mg/L) (mg/L)

GCTLs 250 5

NADCs 2,500 500

ChlorideSample TRPHs

TABLE 1: GROUNDWATER ANALYTICAL SUMMARY - Chloride & TRPHs

WF-M24 April 2015 -- --

March 2016 49 --


April 2017 27 --

October 2017 48 --

April 2018 20 --

October 2018 48 --

April 2019 15 --

October 2019 46 --

April 2020 11 --

October 2020 48

WF-M25 April 2015 270 --

March 2016 13 --


April 2017 34 --

October 2017 8.5 --

April 2018 9.1 --

October 2018 Destroyed Well Destroyed Well

WF-M27 April 2015 270 --

March 2016 110 0.024 U

September 2016 640 0.075 U

April 2017 260 0.071 U

October 2017 130 0.16

April 2018 190 0.072 U

October 2018 99 0.073 U J3

April 2019 36 0.080 U

October 2019 190 0.35 U

April 2020 160 0.33 U

October 2020 25 0.39 U

Notes: all values in milligrams per liter (mg/L)GCTLs -- Groundwater Cleanup Target Levels from Table I of Chapter 62-777, F.A.C. & Table 6 of Chapter 62-550, FAC

U = BDL - Below Detection Limit I = Result is between MDL & PQLV = analyte detected at or above the method detection limit in both the sample and method blankJ3 = Estimated value; value may not be accurate. Spike recovery or RPD outside of criteria-- = Not SampledBold = Exceeds GCTL or NADC

NADCs -- Natural Attenuation Default Concentrations from Table V of Chapter 62-777, F.A.C.

E3492E Analytical Data Table 2 of 2 ERMI File No. E3492E


WELL NO. WF-P1 WF-M14R WF- M23R WF-M24 WF-M25 WF-M27

DIAMETER 2" 2" 2" 2" 2" 2"

AG RISER 3 3 3 3 3 3

WELL DEPTH 12'.2" 22' 13' 13' 16' 20'

SCREEN INTERVAL 2.2-12.2 2-22 3-13 3-13 1-16 2-20TOC ELEVATION 94.86 95.69 95.99

DATE ELEV DTW FP ELEV DTW FP ELEV DTW FP ELEV DTW FP ELEV DTW FP ELEV DTW FP

3/4/2016 92.06 2.80 No 6.60 No 4.86 No 92.59 3.10 No 5.57 No 91.55 4.44 No

9/16/2016 92.86 2.00 No 5.72 No 5.06 No 92.60 3.09 No 3.57 No 92.34 3.65 No

4/13/2017 88.19 6.67 No 9.15 No 7.22 No 89.59 6.10 No 7.21 No 88.79 7.20 No

10/23/2017 92.83 2.03 No 7.38 No 5.31 No 92.59 3.10 No 3.71 No 91.52 4.47 No

4/12/2018 88.06 6.80 No 9.81 No 7.05 No 89.67 6.02 No 7.38 No 88.48 7.51 No

10/15/2018 92.58 2.28 No 7.30 No 8.25 No 91.17 4.52 No Destroyed Monitoring Well 92.86 3.13 No

4/8/2019 90.69 4.17 No 7.23 No 5.70 No 94.39 1.30 No 91.15 4.84 No

10/7/2019 92.30 2.56 No 6.57 No 5.01 No 92.12 3.57 No 91.79 4.20 No

4/9/2020 89.15 5.71 No 8.04 No 7.22 No 89.89 5.80 No 89.51 6.48 No

10/5/2020 93.52 1.34 No 4.81 No 4.00 No 91.31 4.38 No 93.67 2.32 No

Top of Casing (TOC) elevation survey on March 4, 2016

No Data = Blank

TABLE 2: GROUNDWATER ELEVATION SUMMARY

All Measurements = Feet

E3492E GW Elevation Data Table 1 of 1 ERMI File No. E3492E

Appendix A:

Field Notes, Sampling Logs, and Instrument Calibration Forms

Appendix B:

Laboratory Analytical Report and Chain‐of‐Custody Documentation

ANALYTICAL REPORTEurofins TestAmerica, Pensacola3355 McLemore DrivePensacola, FL 32514Tel: (850)474-1001

Laboratory Job ID: 400-194026-1Client Project/Site: West Felda Tank Battery

For:Breitburn Management Co1165 Elkview DriveGaylord, Michigan 49735

Attn: Austin Tramell

Authorized for release by:10/13/2020 2:45:39 PM

Cheyenne Whitmire, Project Manager II(850)[email protected]

The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements foraccredited parameters, exceptions are noted in this report. This report may not be reproducedexcept in full, and with written approval from the laboratory. For questions please contact theProject Manager at the e-mail address or telephone number listed on this page.

This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

1

2

3

4

5

6

7

8

9

10

11

12

13

14

https://secure.testamericainc.com/TotalAccess/login.aspx

http://www.testamericainc.com/services-we-offer/ask-the-expert

http://www.eurofinsus.com/Env

mailto:[email protected]

Table of Contents

Client: Breitburn Management CoProject/Site: West Felda Tank Battery

Laboratory Job ID: 400-194026-1

Page 2 of 15Eurofins TestAmerica, Pensacola

10/13/2020

Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9

QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Case NarrativeClient: Breitburn Management Co Job ID: 400-194026-1Project/Site: West Felda Tank Battery

Job ID: 400-194026-1

Laboratory: Eurofins TestAmerica, Pensacola

Narrative

Job Narrative

400-194026-1

GC Semi VOA

Method FL-PRO: Two surrogates are used for this analysis. The laboratory's SOP allows one of these surrogates to be outside acceptance criteria without performing re-extraction/re-analysis. The following sample contained an allowable number of surrogate

compounds outside limits: (MB 400-505903/1-A). These results have been reported and qualified.

Method FL-PRO: Surrogate recovery for the following samples were outside the upper control limit: WF-P1 (400-194026-1) and WF-M27

(400-194026-5). This sample did not contain any target analytes; therefore, re-extraction and/or re-analysis was not performed.

General Chemistry

Method 325.2: The following sample was diluted to bring the concentration of target analytes within the calibration range: WF-M14R (400-194026-2). Elevated reporting limits (RLs) are provided.

Eurofins TestAmerica, PensacolaPage 3 of 15 10/13/2020

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Detection SummaryJob ID: 400-194026-1Client: Breitburn Management Co

Project/Site: West Felda Tank Battery

Client Sample ID: WF-P1 Lab Sample ID: 400-194026-1

No Detections.

Client Sample ID: WF-M14R Lab Sample ID: 400-194026-2

Chloride

PQL

20 mg/L

MDL

14

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA10240 325.2

Client Sample ID: WF-M23R Lab Sample ID: 400-194026-3

Chloride

PQL

2.0 mg/L

MDL

1.4


Total/NA138 325.2

Client Sample ID: WF-M24 Lab Sample ID: 400-194026-4

Chloride

PQL

2.0 mg/L

MDL

1.4


Total/NA148 325.2

Client Sample ID: WF-M27 Lab Sample ID: 400-194026-5

Chloride

PQL

2.0 mg/L

MDL

1.4


Total/NA125 325.2

Eurofins TestAmerica, Pensacola

This Detection Summary does not include radiochemical test results.

Page 4 of 15 10/13/2020

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Method SummaryJob ID: 400-194026-1Client: Breitburn Management Co


Method Method Description LaboratoryProtocol

FL-DEPFL-PRO Florida - Petroleum Range Organics (GC) TAL PEN

MCAWW325.2 Chloride TAL PEN

SW8463511 Microextraction of Organic Compounds TAL PEN

Protocol References:

FL-DEP = State Of Florida Department Of Environmental Protection, Florida Administrative Code.

MCAWW = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions.

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

TAL PEN = Eurofins TestAmerica, Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL (850)474-1001


Page 5 of 15 10/13/2020

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Sample SummaryJob ID: 400-194026-1Client: Breitburn Management Co


Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID

400-194026-1 WF-P1 Water 10/05/20 09:02 10/06/20 09:25

400-194026-2 WF-M14R Water 10/05/20 11:06 10/06/20 09:25

400-194026-3 WF-M23R Water 10/05/20 11:49 10/06/20 09:25

400-194026-4 WF-M24 Water 10/05/20 12:59 10/06/20 09:25

400-194026-5 WF-M27 Water 10/05/20 10:01 10/06/20 09:25


Page 6 of 15 10/13/2020

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Client Sample ResultsJob ID: 400-194026-1Client: Breitburn Management Co


Lab Sample ID: 400-194026-1Client Sample ID: WF-P1Matrix: WaterDate Collected: 10/05/20 09:02

Date Received: 10/06/20 09:25

Method: FL-PRO - Florida - Petroleum Range Organics (GC)PQL MDL

Total Petroleum Hydrocarbons

(C8-C40)

0.33 U 1.1 0.33 mg/L 10/07/20 14:07 10/08/20 06:18 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

n-C39 140 J1 40 - 129 10/07/20 14:07 10/08/20 06:18 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

o-Terphenyl 143 J1 10/07/20 14:07 10/08/20 06:18 166 - 139

General ChemistryPQL MDL

Chloride 1.4 U 2.0 1.4 mg/L 10/09/20 14:28 1


Lab Sample ID: 400-194026-2Client Sample ID: WF-M14RMatrix: WaterDate Collected: 10/05/20 11:06



Chloride 240 20 14 mg/L 10/09/20 15:07 10


Lab Sample ID: 400-194026-3Client Sample ID: WF-M23RMatrix: WaterDate Collected: 10/05/20 11:49



Chloride 38 2.0 1.4 mg/L 10/09/20 14:28 1


Lab Sample ID: 400-194026-4Client Sample ID: WF-M24Matrix: WaterDate Collected: 10/05/20 12:59



Chloride 48 2.0 1.4 mg/L 10/09/20 14:28 1


Lab Sample ID: 400-194026-5Client Sample ID: WF-M27Matrix: WaterDate Collected: 10/05/20 10:01


Method: FL-PRO - Florida - Petroleum Range Organics (GC)PQL MDL


(C8-C40)

0.39 U 1.3 0.39 mg/L 10/07/20 14:07 10/08/20 06:31 1


n-C39 139 J1 40 - 129 10/07/20 14:07 10/08/20 06:31 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

o-Terphenyl 142 J1 10/07/20 14:07 10/08/20 06:31 166 - 139


Chloride 25 2.0 1.4 mg/L 10/09/20 14:28 1



Page 7 of 15 10/13/2020

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Definitions/GlossaryJob ID: 400-194026-1Client: Breitburn Management Co


Qualifiers

GC Semi VOAQualifier Description

J1 Estimated value; value may not be accurate. Surrogate recovery outside of criteria.

Qualifier

U Indicates that the compound was analyzed for but not detected.

General ChemistryQualifier Description

I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.

Qualifier

U Indicates that the compound was analyzed for but not detected.

Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CFU Colony Forming Unit

CNF Contains No Free Liquid

DER Duplicate Error Ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL Detection Limit (DoD/DOE)

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision Level Concentration (Radiochemistry)

EDL Estimated Detection Limit (Dioxin)

LOD Limit of Detection (DoD/DOE)

LOQ Limit of Quantitation (DoD/DOE)

MCL EPA recommended "Maximum Contaminant Level"

MDA Minimum Detectable Activity (Radiochemistry)

MDC Minimum Detectable Concentration (Radiochemistry)

MDL Method Detection Limit

ML Minimum Level (Dioxin)

MPN Most Probable Number

MQL Method Quantitation Limit

NC Not Calculated

ND Not Detected at the reporting limit (or MDL or EDL if shown)

NEG Negative / Absent

POS Positive / Present

PQL Practical Quantitation Limit

PRES Presumptive

QC Quality Control

RER Relative Error Ratio (Radiochemistry)

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TNTC Too Numerous To Count


Page 8 of 15 10/13/2020

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Lab ChronicleClient: Breitburn Management Co Job ID: 400-194026-1Project/Site: West Felda Tank Battery

Client Sample ID: WF-P1 Lab Sample ID: 400-194026-1Matrix: WaterDate Collected: 10/05/20 09:02


Prep 3511 10/07/20 14:07 KWS505903 TAL PEN

Type

Batch Batch

MethodPrep Type LabAnalystRun

Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA

Analysis FL-PRO 1 505931 10/08/20 06:18 JAW TAL PENTotal/NA

Analysis 325.2 1 506271 10/09/20 14:28 NT TAL PENTotal/NA

Client Sample ID: WF-M14R Lab Sample ID: 400-194026-2Matrix: WaterDate Collected: 10/05/20 11:06


Analysis 325.2 10/09/20 15:07 NT10 506271 TAL PEN

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA

Client Sample ID: WF-M23R Lab Sample ID: 400-194026-3Matrix: WaterDate Collected: 10/05/20 11:49



Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA

Client Sample ID: WF-M24 Lab Sample ID: 400-194026-4Matrix: WaterDate Collected: 10/05/20 12:59



Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA

Client Sample ID: WF-M27 Lab Sample ID: 400-194026-5Matrix: WaterDate Collected: 10/05/20 10:01


Prep 3511 10/07/20 14:07 KWS505903 TAL PEN

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA

Analysis FL-PRO 1 505931 10/08/20 06:31 JAW TAL PENTotal/NA

Analysis 325.2 1 506271 10/09/20 14:28 NT TAL PENTotal/NA

Laboratory References:

TAL PEN = Eurofins TestAmerica, Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL (850)474-1001


Page 9 of 15 10/13/2020

1

2

3

4

5

6

7

8

9

10

11

12

13

14

QC Association SummaryJob ID: 400-194026-1Client: Breitburn Management Co


GC Semi VOA

Prep Batch: 505903

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Water 3511400-194026-1 WF-P1 Total/NA

Water 3511400-194026-5 WF-M27 Total/NA

Water 3511MB 400-505903/1-A Method Blank Total/NA

Water 3511LCS 400-505903/2-A Lab Control Sample Total/NA

Water 3511LCSD 400-505903/3-A Lab Control Sample Dup Total/NA

Analysis Batch: 505931


Water FL-PRO 505903400-194026-1 WF-P1 Total/NA

Water FL-PRO 505903400-194026-5 WF-M27 Total/NA

Water FL-PRO 505903MB 400-505903/1-A Method Blank Total/NA

Water FL-PRO 505903LCSD 400-505903/3-A Lab Control Sample Dup Total/NA



Water FL-PRO 505903LCS 400-505903/2-A Lab Control Sample Total/NA

General Chemistry



Water 325.2400-194026-1 WF-P1 Total/NA

Water 325.2400-194026-2 WF-M14R Total/NA

Water 325.2400-194026-3 WF-M23R Total/NA

Water 325.2400-194026-4 WF-M24 Total/NA

Water 325.2400-194026-5 WF-M27 Total/NA

Water 325.2MB 400-506271/6 Method Blank Total/NA

Water 325.2LCS 400-506271/7 Lab Control Sample Total/NA

Water 325.2MRL 400-506271/3 Lab Control Sample Total/NA

Water 325.2400-193917-A-1 MS Matrix Spike Total/NA

Water 325.2400-193917-A-1 MSD Matrix Spike Duplicate Total/NA

Water 325.2400-193917-A-6 MS Matrix Spike Total/NA

Water 325.2400-193917-A-6 MSD Matrix Spike Duplicate Total/NA


Page 10 of 15 10/13/2020

1

2

3

4

5

6

7

8

9

10

11

12

13

14

QC Sample ResultsJob ID: 400-194026-1Client: Breitburn Management Co


Method: FL-PRO - Florida - Petroleum Range Organics (GC)

Client Sample ID: Method BlankLab Sample ID: MB 400-505903/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 505931 Prep Batch: 505903

PQL MDL


(C8-C40)

0.35 U 1.1 0.35 mg/L 10/07/20 14:07 10/08/20 05:41 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

n-C39 134 J1 40 - 129 10/08/20 05:41 1

MB MB

Surrogate

10/07/20 14:07

Dil FacPrepared AnalyzedQualifier Limits%Recovery

139 10/07/20 14:07 10/08/20 05:41 1o-Terphenyl 66 - 139

Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-505903/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 506115 Prep Batch: 505903


(C8-C40)

14.2 15.8 mg/L 111 66 - 119

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

n-C39 40 - 129

Surrogate

117

LCS LCS

Qualifier Limits%Recovery

135o-Terphenyl 66 - 139

Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 400-505903/3-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 505931 Prep Batch: 505903


(C8-C40)

14.2 16.4 mg/L 116 66 - 119 4 20

Analyte

LCSD LCSD


Spike

Added

%Rec.

Limits LimitRPD

RPD

n-C39 40 - 129

Surrogate

127

LCSD LCSD

Qualifier Limits%Recovery

134o-Terphenyl 66 - 139

Method: 325.2 - Chloride

Client Sample ID: Method BlankLab Sample ID: MB 400-506271/6Matrix: Water Prep Type: Total/NAAnalysis Batch: 506271

PQL MDL

Chloride 1.4 U 2.0 1.4 mg/L 10/09/20 14:25 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-506271/7Matrix: Water Prep Type: Total/NAAnalysis Batch: 506271

Chloride 30.0 31.1 mg/L 104 90 - 110

Analyte

LCS LCS


Spike

Added

%Rec.

Limits


Page 11 of 15 10/13/2020

1

2

3

4

5

6

7

8

9

10

11

12

13

14

QC Sample ResultsJob ID: 400-194026-1Client: Breitburn Management Co


Method: 325.2 - Chloride (Continued)

Client Sample ID: Lab Control SampleLab Sample ID: MRL 400-506271/3Matrix: Water Prep Type: Total/NAAnalysis Batch: 506271

Chloride 2.00 1.96 I mg/L 98 50 - 150

Analyte

MRL MRL


Spike

Added

%Rec.

Limits

Client Sample ID: Matrix SpikeLab Sample ID: 400-193917-A-1 MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 506271

Chloride 5.2 10.0 16.8 mg/L 116 73 - 120

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: Matrix Spike DuplicateLab Sample ID: 400-193917-A-1 MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 506271

Chloride 5.2 10.0 16.9 mg/L 117 73 - 120 1 8

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Client Sample ID: Matrix SpikeLab Sample ID: 400-193917-A-6 MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 506271

Chloride 7.7 10.0 18.7 mg/L 110 73 - 120

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: Matrix Spike DuplicateLab Sample ID: 400-193917-A-6 MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 506271

Chloride 7.7 10.0 18.4 mg/L 107 73 - 120 2 8

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD


Page 12 of 15 10/13/2020

1

2

3

4

5

6

7

8

9

10

11

12

13

14

of 15

10/13/2020

1234567891011121314

Login Sample Receipt Checklist

Client: Breitburn Management Co Job Number: 400-194026-1

Login Number: 194026

Question Answer Comment

Creator: Conrady, Hank W

List Source: Eurofins TestAmerica, Pensacola

List Number: 1

N/ARadioactivity wasn't checked or is </= background as measured by a survey meter.

TrueThe cooler's custody seal, if present, is intact.

N/ASample custody seals, if present, are intact.

TrueThe cooler or samples do not appear to have been compromised or tampered with.

TrueSamples were received on ice.

TrueCooler Temperature is acceptable.

TrueCooler Temperature is recorded. 2.3°C IR-8

TrueCOC is present.

TrueCOC is filled out in ink and legible.

TrueCOC is filled out with all pertinent information.

TrueIs the Field Sampler's name present on COC?

TrueThere are no discrepancies between the containers received and the COC.

TrueSamples are received within Holding Time (excluding tests with immediate HTs)

TrueSample containers have legible labels.

TrueContainers are not broken or leaking.

TrueSample collection date/times are provided.

TrueAppropriate sample containers are used.

TrueSample bottles are completely filled.

N/ASample Preservation Verified.

TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs

TrueContainers requiring zero headspace have no headspace or bubble is <6mm (1/4").

TrueMultiphasic samples are not present.

TrueSamples do not require splitting or compositing.

N/AResidual Chlorine Checked.

Eurofins TestAmerica, PensacolaPage 14 of 15 10/13/2020

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Accreditation/Certification SummaryClient: Breitburn Management Co Job ID: 400-194026-1Project/Site: West Felda Tank Battery

Laboratory: Eurofins TestAmerica, PensacolaThe accreditations/certifications listed below are applicable to this report.

Authority Program Identification Number Expiration Date

Florida E81010NELAP 06-30-21


Page 15 of 15 10/13/2020

1

2

3

4

5

6

7

8

9

10

11

12

13

14

semi‐annual groundwater monitoring report

Documents