27139883 001 page 1 of 32 · 2018-05-03 · 3. chemical oxygen demand (cod) pass na 4. total...

TÜV Rheinland Uluslararası Standartlar Sertifikasyon ve Denetim A.Ş.

Kozyatagi Mah. Saniye Ermutlu Sok. No:12

Colakoglu Plaza B Blok 34742 Kadikoy Istanbul,

Tel. +902166653200, Fax +902166653299, e-mail: [email protected]

MS-0010698/6_en

Test Report No.: 27139883 001 of 32

Client: SADIRLAR TEKSTİL

Buyer’s name: -

Factory name: SADIRLAR TEKSTİL

Factory Address: Geyve Org.San. Bölg. No:1 Geyve /SAKARYA

Discharge type of waste water:

Direct Discharged Waste Water

Sample Type: 1) Treated Waste Water 2) Sludge 3) Incoming water

Sampling Date: 2017-12-21

Sampling Time Procedure:

Sampling has been done manually; for 6 hours of intervals of 60 mins

Testing Period: 2017-12-21 to 2018-01-16

Test Specification: Test result:

2016 Wastewater Guidelines Please refer to page 2, 3

Other Information:

For and on behalf of


Date: 2018-01-16

Tomris Hasançebi /

Customer Relations Senior Manager

Duygu Öztürk /

Chemical Laboratory Senior Manager

Test result is drawn according to the kind and extent of tests performed. This test report relates to the a. m. test sample. Without permission of the test center this test report is not permitted to be duplicated in extracts. This test report does not entitle to carry any safety mark on this or similar products.

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Test Report No.: 27139883 001

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MS-0010698/6_en

Test specification: Test result

M001- Discharged Waste Water (*)

Test result

M002- Sludge

Conventional Parameters

1. Temperature PASS NA

2. Total Suspended Solids (TSS) PASS NA

3. Chemical Oxygen Demand (COD) PASS NA

4. Total Nitrogen PASS NA

5. pH value PASS NA

6. Colour PASS NA

7. Biochemical Oxygen Demand (BOD5) – 5 Days

PASS NA

8. Ammonium Nitrogen PASS NA

9. Total Phosphorous FAIL NA

10. Adsorbable Organic Halogens (AOX) PASS NA

11. Oil and Grease PASS NA

12. Phenols PASS NA

13. Coliform [MPN/ 100ml] PASS NA

14. Persistent Foam PASS NA

15. Dissolved Anion - Sulfide PASS NA

16. Dissolved Anion - Sulfite PASS NA

17. Cyanide PASS NA

18. Metals PASS NA

Antimony (Sb) FAIL NA

Chromium (Cr, total) PASS NA

Cobalt (Co) PASS NA

Copper (Cu) PASS NA

Nickel (Ni) PASS NA

Silver (Ag) PASS NA

Zinc (Zn) PASS NA

Arsenic (As) PASS See Results

Cadmium (Cd) PASS See Results

Lead (Pb) PASS See Results

Mercury (Hg) PASS See Results

Chromium (Cr VI) PASS See Results

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M001- Discharged Waste Water (*)

Test result

M002- Sludge

ZDHC Manufacturing Restricted Substances List (MRSL)

19. Alkylphenol (AP) and Alkylphenol Ethoxylates

(APEOs) PASS

See results

20. Chlorobenzenes and Chlorotoluenes PASS See results

21. Chlorophenols PASS See results

22. Dyes – Azo (Forming Restricted Amines) PASS See results

23. Dyes – Carcinogenic or Equivalent Concern PASS See results

24. Dyes – Disperse (Sensitizing) PASS See results

25. Flame Retardants (included SCCP) PASS See results

26. Glycols PASS See results

27. Halogenated Solvents PASS See results

28. Organotin Compounds PASS See results

29. Perfluorinated and Polyfluorinated Chemicals

(PFCs) PASS

See results

30. Phthalates PASS See results

31. Polycyclic Aromatic Hydrocarbons (PAHs) PASS See results

32. Volatile Organic Compounds (VOC) PASS See results

(*) Remark: Test result of Discharge Waste Water is evaluated based on Foundational limit


M003- Incoming water

Test result

M002- Sludge

18. Metals

Antimony (Sb) See results

Chromium (Cr, total) See results

Cobalt (Co) See results

Copper (Cu) See results

Nickel (Ni) See results

Silver (Ag) See results

Zinc (Zn) See results

Arsenic (As) See results

Cadmium (Cd) See results

Lead (Pb) See results

Mercury (Hg) See results

Chromium (Cr VI) See results

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MATERIAL LIST

Material No. Material Sampling

M001 - Treated Wastewater

M002 - Sludge

M003 - Incoming water

*Conventional tests have been carried out by a contracted laboratory (Cevre Endustriyel Analiz Lab.)

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1. Temperature Test method: SM 2550:B

Parameter Result

M001 (oC)

Temperature 26

Abbreviation: NA = Not Applicable

Remarks: The limits of range of Temperature according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter Reporting Limit

(oC)

ZDHC Limit (oC)

Foundational

Temperature NA ∆ 15 or max 35

2. Total Suspended Solids (TSS)

Test Method: SM 2540:D

Parameter Result

M001 (mg/L)

Total Suspended Solids (TSS) <10

Abbreviation: mg/L = milligram per litre n.d. = not detected (< Reporting Limit)

Remarks: The limits of Total Suspended Solids (TSS) according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)


(mg/L)

ZDHC Limit (mg/L)

Foundational

Total Suspended Solids (TSS)

10 50

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3. Chemical Oxygen Demand (COD)

Test Method: SM 5220:B

Parameter Result

M001 (mgO2/L)

Chemical Oxygen Demand (COD) 24


Remarks: The limits of Chemical Oxygen Demand (COD) according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)


(mg/L)

ZDHC Limit (mg/L)

Foundational

Chemical Oxygen Demand

(COD) 30 150

4. Total Nitrogen (TN) Test Method: SM – 4500Norg:B, SM 4500–NO3:E

Parameter Result

M001 (mg/L)

Total Nitrogen 9.9


Remarks: The limits of Total Nitrogen according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)


(mg/L)

ZDHC Limit (mg/L)

Foundational

Total Nitrogen 2 20

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5. pH value

Test Method: SM 4500-H+:B

Parameter Result

M001

pH value (25°C) 8.75


Remarks: The limits of pH according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter Reporting

Limit

ZDHC Limit

Foundational

pH value NA 6-9

6. Colour

Test Method: ISO 7887

Parameter Result

M001

Colour [m-1] (436nm; 525nm; 620nm)

1;0.6;0.4

Abbreviation: nm = nanometer

Remarks: The limits of Colour according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter Reporting

Limit

ZDHC Limit

Foundational

Colour NA 7;5;3

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7. Biochemical Oxygen Demand (BOD5) – 5 Days

Test Method: TS 4957-1; EN 1899-1

Parameter Result

M001 (mg/L)

Biochemical Oxygen Demand (BOD5) 5


Remarks: The limits of Biochemical Oxygen Demand (BOD5) – 5 Days according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)


(mg/L)

ZDHC Limit (mg/L)

Foundational

Biochemical Oxygen Demand (BOD5)

5 30

8. Ammonium Nitrogen

Test Method: SM 4500-NH3:B,F

Parameter Result

M001 (mg/L)

Ammonium Nitrogen 1.1


Remarks: The limits of Ammonium Nitrogen according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)


(mg/L)

ZDHC Limit (mg/L)

Foundational

Ammonium Nitrogen 0.5 10

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9. Total Phosphorous

Test Method: SM 4500-P:B,C

Parameter Result

M001 (mg/L)

Total Phosphorous 4.7


Remarks: The limits of Total Phosphorous according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)


(mg/L)

ZDHC Limit (mg/L)

Foundational

Total Phosphorous 0.1 3

10. Adsorbable Organic Halogens (AOX)

Test Method: TS EN ISO 9562

Parameter Result

M001 (mg/L)

Adsorbable Organic Halogens (AOX) 1.96


Remarks: The limits of Adsorbable Organic Halogens (AOX) according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)


(mg/L)

ZDHC Limit (mg/L)

Foundational

Adsorbable Organic Halogens (AOX)

0.1 5

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11. Oil and Grease


Parameter Result

M001 (mg/L)

Oil and Grease <10


Remarks: The limits of Oil and Grease according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)


(mg/L)

ZDHC Limit (mg/L)

Foundational

Oil and Grease 10 10

12. Phenols

Test Method: TS 6227 - ISO 6439

Parameter Result

M001 (mg/L)

Phenols <0.03


Remarks: The limits of Phenols according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)


(mg/L)

ZDHC Limit (mg/L)

Foundational

Phenols 0.001 0.5

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13. Coliform


Parameter Result

M001 (cfu/ 100ml)

Coliform n.d.

Abbreviation: n.d. = not detected

Remarks: The limits of Coliform [cfu/ 100ml] according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)


(cfu/ 100ml)

ZDHC Limit (cfu/ 100ml)

Foundational

Coliform 10 400

14. Persistent Foam

Test Method: DMS 97459

Parameter Result

M001

Persistent Foam Not Visible


Remarks: The limits of Persistent Foam according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter Reporting Limit ZDHC Limit

Foundational

Persistent Foam NA Not Visible

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15. Anion – Sulfide

Test Method: SM 4500 S2-:D

Parameter Result

M001 (mg/L)

Anion – Sulfide <0.1


Remarks: The limits of Dissolved Anion – Sulfide according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)


(mg/L)

ZDHC Limit (mg/L)

Foundational

Anion – Sulfide 0.01 0.5

16. Anion – Sulfite

Test Method: SM 4500 SO32- :C

Parameter Result

M001 (mg/L)

Anion – Sulfite <0.2


Remarks: The limits of Dissolved Anion – Sulfite according to ZDHC limit (Table 1 of ZDHC wastewater guidelines, issued in Nov 2016)


(mg/L)

ZDHC Limit (mg/L)

Foundational

Anion – Sulfite 0.2 2

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17. Cyanide

Test Method: For waste water: EPA 9010C – EPA 9014 For sludge: EPA 9013A – EPA 9014

Parameter Result

M001 (mg/L) M002 (mg/kg)

Cyanide <0.03 <0,14

Abbreviation: mg/L = milligram per litre mg/kg = milligram per kilogram

n.d. = not detected (< Reporting Limit)

Remarks: The limits of Cyanide according to ZDHC limit (Table 1 and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter

Reporting Limit ZDHC Limit

Wastewater

(mg/L)

Sludge

(mg/kg)

Wastewater (mg/L) Sludge

(mg/kg)

Foundational -

Cyanide 0.05 0.05 0.2 -

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18. Heavy Metals

Test Method: Wastewater: Metals: USEPA 200.8, USEPA 3015a and USEPA 6020a with modification.

Cr (VI): ISO 18412:2005

Parameter

Reporting

Limit Result

mg/L M001 (mg/L) M002 (mg/L) M003 (mg/L)

Antimony (Sb) 0.05 0.27 - 0.1

Chromium (Cr, total) 0.01 n.d. - n.d.

Cobalt (Co) 0.01 n.d. - 0.032

Copper (Cu) 0.05 0.096 - n.d.

Nickel (Ni) 0.01 0.015 - n.d.

Silver (Ag) 0.005 n.d. - n.d.

Zinc (Zn) 0.05 0.22 - n.d.

Arsenic (As) 0.01 n.d. 0.94 0.013

Cadmium (Cd) 0.01 n.d. 0.73 n.d.

Lead (Pb) 0.01 0.012 3.3 n.d.

Mercury (Hg) 0.01 n.d. n.d. n.d.

Chromium (Cr VI) 0.05 n.d. n.d. n.d.

Abbreviation: mg/L = milligram per litre mg/kg = milligram per kilogram NA = Not Applicable n.d. = not detected (< Reporting Limit) Remarks: The limits of Heavy Metals according to ZDHC limit (Table 1 and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameters

Reporting Limit ZDHC Limit ZDHC Limit

Wastewater

(mg/L)

Wastewater (mg/L) Sludge (mg/kg)

Foundational -

Antimony (Sb) 0.001 0.1 -

Chromium (Cr, total) 0.001 0.2 -

Cobalt (Co) 0.001 0.05 -

Copper (Cu) 0.001 1 -

Nickel (Ni) 0.001 0.2 -

Silver (Ag) 0.001 0.1 -

Zinc (Zn) 0.001 5.0 -

Arsenic (As) 0.001 0.05 -

Cadmium (Cd) 0.001 0.1 -

Lead (Pb) 0.001 0.1 -

Mercury (Hg) 0.001 0.01 -

Chromium (Cr VI) 0.001 0.05 -

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19. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): Including All isomers

Test Method: ISO 18857-2 (modified dichloromethane extraction); ASTM D7065-06, ISO 18254-1, GC-MS and LC-MS/MS

Parameter Result

M001 (µg/L) M002 (mg/kg)

NP n.d. n.d.

OP n.d. n.d.

NPEO n.d. n.d.

OPEO n.d. n.d.

.

Abbreviation: µg/ L = microgram per litre mg/kg = milligram per kilogram RL = Reporting Limit n.d. = not detected (< Reporting Limit)

Remarks: List of AP and APEOs being tested (Table 2A and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

Nonylphenol (NP),

mixed isomers

104-40-5

25154-52-3

11066-49-2

84852-15-3

1 0.2 5 -

Octylphenol (OP),

mixed isomers

140-66-9

1806-26-4

27193-28-8

Nonylphenol ethoxylates (NPEO)

9016-45-9

26027-38-3

37205-87-1

68412-54-4

127087-87-0

Octylphenol ethoxylates (OPEO)

9002-93-1

9036-19-5

68987-90-6

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20. Chlorobenzenes and Chlorotoluenes

Test Method: US EPA 8260B, US EPA 8070D, Dichloromethane extraction followed by GC-MS

Parameter Result

M001 (µg/L) M002 (mg/kg)

Chlorobenzenes n.d. n.d.

Chlorotoluenes n.d. n.d.

Abbreviation: µg/ L = microgram per litre mg/kg = milligram per kilogram n.d. = not detected (< Reporting Limit)

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Remarks: List of Chlorobenzenes and Chlorotoluenes being tested (Table 2B and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

Monochlorobenzene 108-90-7

0.1 0.05 0.2 -

1,2-Dichlorobenzene 95-50-1



1,2,3-Trichlorobenzene 87-61-6



1,2,3,4-Tetrachlorobenzene

634-66-2


634-90-2


95-94-3

Pentachlorobenzene 608-93-5

Hexachlorobenzene 118-74-1

2-Chlorotoluene 95-49-8



2,3-dichlorotoluene 32768-54-0






2,3,4-Trichlorotoluene 7359-72-0





2,3,4,5-Tetrachlorotoluene 76057-12-0



Pentachlorotoluene 877-11-2

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21. Chlorophenols

Test Method: USEPA 8270 D, Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC/MS ISO 14154:2005

Parameter Result

M001 (µg/L) M002 (mg/kg)

Chlorophenols n.d. n.d.


Remarks: List of Chlorophenols being tested (Table 2C and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

2-Chlorophenol 95-57-8

0.5 0.03 0.5 -

3-chlorophenol 108-43-0

4-chlorophenol 106-48-9

2,3-Dichlorophenol 576-24-9





3,5- Dichlorophenol 591-35-5

2,3,4-Trichlorophenol 15950-66-0






2,3,4,5-Tetrachlorophenol

4901-51-3


58-90-2


935-95-5

Pentachlorophenol 87-86-5

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22. Dyes – Azo (Forming Restricted Amines)

Test Method: EN 14362-1, EN 14362-3, Reduction step with Sodiumdithionite, solvent extraction, GC/MS or LC-MS/MS

Parameter Result

M001 (µg/L) M002 (mg/kg)

Dyes – Azo (Forming Restricted Amines)

n.d. n.d.


Remarks List of Dyes – Azo (Forming Restricted Amines) being tested (Table 2D and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

4,4'-Methylene-bis(2-chloroaniline) 101-14-4

0.1 0.2 0.1 -

4,4'-Diaminodiphenylmethane 101-77-9

4,4'-Oxydianiline 101-80-4

4-Chloroaniline 106-47-8

3,3'-Dimethoxybenzidine 119-90-4

3,3'-Dimethylbenzidine 119-93-7

6-methoxy-m-toluidine 120-71-8

2,4,5-Trimethylaniline 137-17-7

4,4'-Thiodianiline 139-65-1

4-Aminoazobenzene 60-09-3

4-Methoxy-m-phenylenediamine 615-05-4

4,4'-methylenedi-o-toluidine 838-88-0

2,6-Xylidine 87-62-7

o-Anisidine 90-04-0

2-Naphthylamine 91-59-8

3,3'-Dichlorobenzidine 91-94-1

4-Aminobiphenyl 92-67-1

Benzidine 92-87-5

o-Toluidine 95-53-4

2,4-Xylidine 95-68-1

4-Chloro-o-toluidine 95-69-2

4-methyl-m-phenylenediamine 95-80-7

o-Aminoazotoluene 97-56-3

5-Nitro-o-toluidine 99-55-8

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23. Dyes – Carcinogenic or Equivalent Concern

Test Method: Liquid extraction, LC/MSMS

Parameter Result

M001 (µg/L) M002 (mg/kg)

Dyes – Carcinogenic or Equivalent Concern

n.d. n.d.


Remarks: List of Dyes – Carcinogenic or Equivalent Concern being tested (Table 2E and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

C.I. Direct Black 38 1937-37-7

50 1 500 -

C.I. Direct Blue 6 2602-46-2

C.I. Acid Red 26 3761-53-3

C.I. Basic Red 9 569-61-9

C.I. Direct Red 28 573-58-0

C.I. Basic Violet 14 632-99-5

C.I. Disperse Blue 1 2475-45-8

C.I. Disperse Blue 3 2475-46-9

C.I. Basic Blue 26 (with Michler’s Ketone >0.1%)

2580-56-5

C.I Basic Green 4 (malachite green chloride)

569-64-2

C.I Basic Green 4 (malachite green oxalate)

2437-29-8

C.I Basic Green 4 (malachite green)

10309-95-2

Disperse Orange 11 82-28-0

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24. Dyes – Disperse (Sensitizing)

Test Method: Liquid extraction, LC/MSMS

Parameter Result

M001 (µg/L) M002 (mg/kg)

Dyes – Disperse (Sensitizing) n.d. n.d.


Remarks: List of Dyes – Carcinogenic or Equivalent Concern being tested (Table 2F and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

Disperse Yellow 1 119-15-3

50 1 50 -

Disperse Blue 102 12222-97-8



Disperse Orange 37/59/76 13301-61-6

Disperse Brown 1 23355-64-8



Disperse Red 11 2872-48-2











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25. Flame Retardants Test Method: US EPA 8270; ISO 22032; US EPA 527 and US EPA 8321B. Dichloromethane extraction, GC-MS, GC-MS/MS and LC-MS/MS

Parameter Result

M001 (µg /L) M002 (mg/kg)

TCEP n.d. n.d.

DecaBDE n.d. n.d.

TRIS n.d. n.d.

PentaBDE n.d. n.d.

OctaBDE n.d. n.d.

BIS n.d. n.d.

TEPA n.d. n.d.

PBB n.d. n.d.

TBBPA n.d. n.d.

HBCDD n.d. n.d.

BBMP n.d. n.d.

TDCP n.d. n.d.

SCCP n.d. n.d.

Abbreviation: µg/ L = microgram per litre mg/kg = milligram per kilogram


Remarks: List of Flame Retardants being tested (Table 2G and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

Tris-(2-chloro-ethyl)-phosphate (TCEP) 115-96-8

5 0.3 5 -

Decabromodiphenyl ether (DecaBDE) 1163-19-5

Tri-(2,3-di-bromo-propyl)-phosphate (TRIS) 126-72-7

Pentabromodiphenyl ether (PentaBDE) 32534-81-9

Octabromodiphenyl ether (OctaBDE) 32536-52-0

Bis-(2,3-di-bromo-propyl)-phosphate (BIS) 5412-25-9

Tris(1-aziridinyl)phosphine oxide) (TEPA) 545-55-1

Polybromobiphenyls (PBB) 59536-65-1

Tetra-bromo-bisphenol-A (TBBPA) 79-94-7

Hexabromocyclododecan (HBCDD) 3194-55-6

2,2-bis(bromomethyl)-1,3-propanediol (BBMP) 3296-90-0

Tris-(1,3-di-chloro-iso-propyl)-phosphate (TDCP)

13674-87-8

Short chain chlorinated paraffins,C10-C13 (SCCP)

85535-84-8

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26. Glycols

Test Method: US EPA 8270, Liquid Extraction, GCMS

Parameter Result

M001 (µg/L) M002 (mg/kg)

Bis(2-methoxyethyl)-ether n.d. n.d.

2-Ethoxyethanol n.d. n.d.

2-Ethyoxyethyl acetate n.d. n.d.

Ethylene glycol dimethyl ether n.d. n.d.

2-Methoxyethanol n.d. n.d.

2-Methoxyethyl acetate n.d. n.d.

2-Methoxypropyl acetate n.d. n.d.

Triethylene Glycol Dimethyl Ether n.d. n.d.



Remarks: List of Glycols being tested (Table 2H and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

Bis(2-methoxyethyl)-ether 111-96-6

50 3 50 -

2-Ethoxyethanol 110-80-5

2-Ethyoxyethyl acetate 111-15-9

Ethylene glycol dimethyl ether 110-71-4

2-Methoxyethanol 109-86-4

2-Methoxyethyl acetate 110-49-6

2-Methoxypropyl acetate 70657-70-4

Triethylene Glycol Dimethyl Ether

112-49-2

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27. Halogenated Solvents

Test Method: USEPA 8260B, Purge and-Trap GC-MS

Parameter Result

M001 (µg/L) M002 (mg/kg)

1,2-Dichloroethane n.d. n.d.

Methylene chloride n.d. n.d.

Tetrachloroethylene n.d. n.d.

Trichloroethylene n.d. n.d.



Remarks: List of Halogenated Solvents being tested (Table 2I and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

1,2-Dichloroethane 107-06-2

0.5 0.3 1 - Methylene chloride 75-09-2

Tetrachloroethylene 127-18-4

Trichloroethylene 79-01-6

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28. Organotin Compounds

Test Method: ISO 17353, Derivatisation with NaB (C2H5), GC/MS

Parameter Result

M001 (µg/L) M002 (mg/kg)

Mono-,di-and tri-methyltin derivatives n.d. n.d.

Mono-,di-and tri-butyltin derivatives n.d. n.d.

Mono-,di-and tri-phenyltin derivatives n.d. n.d.

Mono-,di-and tri-octyltin derivatives n.d. n.d.



Remarks: List of Organotin Compounds being tested (Table 2J and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

Mono-,di-and tri-methyltin derivatives

Multiple

0.01 0.01 0.01 -

Mono-,di-and tri-butyltin derivatives

Multiple

Mono-,di-and tri-phenyltin derivatives

Multiple

Mono-,di-and tri-octyltin derivatives

Multiple

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29. Perfluorinated and Polyfluorinated Chemicals (PFCs)

Test Method: DIN 38407-42 (modified), Ionic PFC: Concentration or direct injection, LC/MS (-MS); Non-ionic PFC (FTOH): derivatisation with acetic anhydride followed by GC/MS

Parameter Result

M001 (µg/L) M002 (mg/kg)

PFOS n.d. n.d.

PFOA n.d. n.d.

PFBS n.d. n.d.

PFHxA n.d. n.d.

8:2 FTOH n.d. n.d.

6:2 FTOH n.d. n.d.



Remarks: List of Perfluorinated and Polyfluorinated Chemicals (PFCs) being tested (Table 2K and Table 3 of ZDHC Waste water guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

PFOS 355-46-4

432-50-7

0.007 0.05 0.01 - PFOA 335-67-1

PFBS 29420-49-3

29420-43-3

PFHxA 307-24-4

8:2 FTOH 678-39-7 0.5 5 1 -

6:2 FTOH 647-42-7

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30. Phthalates – Including all other esters of phthalic acid

Test Method: US EPA 8270D, ISO 18856, Dichloromethane extraction GC-MS

Parameter Result

M001 (µg/L) M002 (mg/kg)

DEHP n.d. n.d.

DMEP n.d. n.d.

DNOP n.d. n.d.

DIDP n.d. n.d.

DINP n.d. n.d.

DnHP n.d. n.d.

DBP n.d. n.d.

BBP n.d. n.d.

DNP n.d. n.d.

DEP n.d. n.d.

DPRP n.d. n.d.

DIBP n.d. n.d.

DCHP n.d. n.d.

DIOP n.d. n.d.

DHNUP n.d. n.d.

DIHP n.d. n.d.



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Remarks: List of Phthalates being tested (Table 2L and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

Di(ethylhexyl)phthalate (DEHP) 117-81-7

5 1 10 -

Bis (2-methoxyethyl) phthalate (DMEP)

117-82-8

Di-n-octyl phthalate (DNOP) 117-84-0

Di-iso-decyl phthalate (DIDP) 26761-40-0

Di-isononyl phthalate (DINP) 28553-12-0

Di-n-hexyl phthalate (DnHP) 84-75-3

Di-n-butyl phthalate (DBP) 84-74-2

Butyl benzyl phthalate (BBP) 85-68-7

Dinonyl phthalate (DNP) 84-76-4

Diethyl phthalate (DEP) 84-66-2

Di-n-propyl phthalate (DPRP) 131-16-8

Di-isobutyl phthalate (DIBP) 84-69-5

Di-cyclohexyl phthalate (DCHP) 84-61-7

Di-iso-octyl phthalate (DIOP) 27554-26-3

1,2-benzenedicarboxylic acid, di-C7- 11-branched and linearalkyl esters (DHNUP)

68515-42-4

1,2-benzenedicarboxylic acid, di-C6-8-branched alkyl esters, C7-rich (DIHP)

71888-89-6

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31. Polycyclic Aromatic Hydrocarbons (PAHs)

Test Method: US EPA 8270 DIN 38407-39 Solvent extraction GC-MS

Parameter Result

M001 (µg/L) M002 (mg/kg)

Benzo(a)pyrene n.d. n.d.

Anthracene n.d. n.d.

Pyrene n.d. n.d.

Benzo[ghi]perylene n.d. n.d.

Benzo(e)pyrene n.d. n.d.

Indeno[1,2,3-cd]pyrene n.d. n.d.

Benzo(j)fluoranthene n.d. n.d.

Benzo[b]fluoranthene n.d. n.d.

Fluoranthene n.d. n.d.

Benzo[k]fluoranthene n.d. n.d.

Acenaphthylene n.d. n.d.

Chrysene n.d. n.d.

Dibenz(a,h)anthracene n.d. n.d.

Benzo[a]anthracene n.d. n.d.

Acenaphthene n.d. n.d.

Phenanthrene n.d. n.d.

Fluorene n.d. n.d.

Naphthalene n.d. n.d.



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Remarks: List of PAH being tested (Table 2M and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

Benzo(a)pyrene 50-32-8

1 1 1 -

Anthracene 120-12-7

Pyrene 129-00-0

Benzo[ghi]perylene 191-24-2

Benzo(e)pyrene 192-97-2

Indeno[1,2,3-cd]pyrene 193-39-5

Benzo(j)fluoranthene 205-82-3

Benzo[b]fluoranthene 205-99-2

Fluoranthene 206-44-0

Benzo[k]fluoranthene 207-08-9

Acenaphthylene 208-96-8

Chrysene 218-01-9

Dibenz(a,h)anthracene 53-70-3

Benzo[a]anthracene 56-55-3

Acenaphthene 83-32-9

Phenanthrene 85-01-8

Fluorene 86-73-7

Naphthalene 91-20-3

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32. Volatile Organic Compounds (VOC)

Test Method: Wastewater: ISO 11423-1, Purge & Trap, GCMS

Parameter Result

M001 (µg/L) M002 (mg/kg)

Benzene n.d. n.d.

Xylene n.d. n.d.

o-cresol n.d. n.d.

p-cresol n.d. n.d.

m-cresol n.d. n.d.



Remarks: List of VOC being tested (Table 2N and Table 3 of ZDHC wastewater guidelines, issued in Nov 2016)

Parameter CAS No.


Wastewater

(µg/L)

Sludge

(mg/kg)

Wastewater

(µg/L)

Sludge

(mg/kg)

Benzene 71-43-2

1 0.1 1 -

Xylene 1330-20-7

o-cresol 95-48-7

p-cresol 106-44-5

m-cresol 108-39-4

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SAMPLING PHOTOS

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27139883 001 page 1 of 32 · 2018-05-03 · 3. chemical oxygen demand (cod) pass na 4. total...

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