journal of catalyst & catalysis (vol1, issue2)
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May- August 2014
eISSN : 2349-4344
Journal of
Catalyst & Catalysis
STM JOURNALSSTM JOURNALSSTM JOURNALSScientific Technical MedicalScientific Technical MedicalScientific Technical Medical
(JoCC)
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Journal of Catalyst & Catalysis
eISSN: 2349-4344
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Industrial Tribology Machine Dynamics & Maintenance
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Alternative Energy Technology Laboratory,
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Abdul RajackAssociate Professor, Department of Chemistry, Maharaja Vijayaram Gajapathi Raj College of Engineering, Andhra Pradesh, India.
Abhijit MondalAssistant Professor, Chemical Engineering Dept. National Institute of Technology Agartala India.
Ajay BansalAssociate Professor Head, Department of Chemical Engineering National Institute of Technology, Jhallandhar, Punjab, India.
Ajaya Kumar SinghAssociate Professor Department of Chemistry Government V.Y.T.PG.Autonomous College Durg, Chhattisgarh, India.
Alirio RodriguesEmeritus Professor Laboratory of Separation & Reaction Engineering, Departamento de Engenharia Química, Faculdade de Engenharia da Universidade do Porto, Portugal.
Alekha Kumar SutarAssistant Professor Catalysis Research Lab Department of Chemistry Ravenshaw University Cuttack, Odisha, India.
Antonio GilProfessor of Chemical Engineering Department of Applied Chemistry Universidad Publica de Navarra, Spain.
Ankur BordoloiRefinery Technology Division Indian Institute of Peteroleum ,Dehradun, India.
Bharat ModheraAssistant Professor Chemical Engineering Maulana Azad National Institute of Technology, Bhopal, India.
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Gopal l TembeAsst.Vice president Reliance Research & Development Center Reliance Industries Limited, Navi Mumbai, India.
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Hemant S ChandakAssistant Professor, Department of Chemistry G. S. Science, Arts & Commerce College, Nandura Road,Maharashtra, India.
Jagannadharao YaddanapudiSiddaganga Institute of Technology, Tumkur M S R Institute of Technology,Bangalore Visvesvaraya Technological University, India.
Ibadur Rahman SiddiquiLaboratory of Green Synthesis, Department of Chemistry, University of Allahabad, India.
Kalpana MaheriaApplied Chemistry Department, Sardar VallabhbhaiNational Institute of Technology, Surat, Gujarat, India.
Jhansi. L. Kishore MamillaAssistant Professor Department of Chemical Engineering and Technology Birla Institute of Technology Mesra, Ranchi, India.
M. N. KumaraAssistant Professor Graduate and Postgraduate Center Department of Chemistry, Yuvaraja's College University of Mysore, Mysore, India.
Kamal K. PantPetrotech Chair Professor Department of Chemical Engineering Indian Institute of Technology Delhi India, India.
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Editorial Board
Mohammad MuneerProfessor, Department of Chemistry, Aligarh Muslim University India, India.
N SelvarajuAssistant Professor, Department of Chemical Engineering, National Institute of Technology Calicut India.
Nadeem Bashir GanaieAssistant Professor Govt. College for Women Nawakadal Jammu and Kashmir India, India.
Nagaraj P. ShettiHead, Department of Engineering Chemistry, KLE Institute of Technology, Hubli, Karnataka, India.
Nitin Kumar LabhsetwarSenior Principal Scientist / Deputy Director Environmental Materials Division National Environmental Research Institute(NEERI), Nagpur, India.
Neeraj AtreySenior Scientist Chemical Conversion Area Indian Institute of Petroleum, Dehradun.
Pavan Kumar Malladi VAssistant Professor Department of Chemical Engineering National Institute of Technology Calicut.
Parnesh Nath ChatterjeeAssistant Professor,HOD Department of Chemistry NIT Meghaalya, India.
Prabhas JanaPostdoctoral Researcher Thermochemical Processes Unit IMDEA Energy, Madrid, Spain.
Perumal SubramaniamHead & Associate Professor, Research Department of Chemistry, Aditanar College of Arts and Research, Tiruchendur, India.
Praveen Kumar TandonAssociate Professor Department of Chemistry, University of Allahabad, India.
Prakash SamnaniAssociate Professor Faculty Of Science Department of Chemistry Maharaja Sayajiao University Baroda Gujarat, India, India.
Priyanka SagarAssistant professor , Department of Chemistry Kumaon University, India.
Pravin Pandharinath UpareSenior Researcher Korea Research Institute of Chemical Technology, Daejeon, Korea, Republic Of.
Rakesh Kumar PandeyJSPS-Fellow, Electronic Functional Materials Group, National Institute for Materials Science (NIMS), Tsukuba, Japan.
R KarvembuAssociate Professor Department of Chemistry National Institute of Technology Tiruchirappalli, India.
Ravi Prakash VaidProfessor(Retired), Birla Institute of Technology & Science, Pilani Rajasthan, India, India.
Rakesh SharmaAssistant Professor Indian Institute of Technology Jodhpur India, India.
Sayed Hasan Razi AbdiCentral Salt & Marine Chemicals Research Institute Council for Scientific & Industrial Research, India.
Sankaranarayanan T.MInstituto IMDEA Energía Avda. Ramón de la Sagra, 3 Parque Tecnológico de Móstoles E-28935 Móstoles, Madrid (Spain), Spain.
Shankar MVNanocatalysis and Solar Fuels Research Lab Department of Materials Science & Nanotechnology Yogi Vemana University Kadapa, Andhra Pradesh, India.
Shailendra TripathiCatalysis Division CSIR-Indian Institute of Petroleum.
Editorial Board
Shiva B HalligudiRetired Scientist National Chemical Laboratory Council for Scientific and Industrial Research Pune, India.
Shivamurti A ChimatadarDepartment of Chemistry, Karnatak University, Dharwad, India.
Siva SankarDepartment of Chemical Engineering, National Institute of Technology Tiruchirappalli, India.
Sunaja DeviAssistant Professor Department of Chemistry Christ University, Hosur Road, Bangalore India, India.
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Sunil KumarScientist Biotechnology Conversion Area Indian Institute of Petroleum Dehradun.
Venkata Narayana KalevaruGroup Leader, Gas Phase Oxidations, Leibniz Institute for Catalysis at University Rostock Albert-Einstein, Germany.
Tungabidya MaharanaAssistant Professor Department Of Chemistry National Institute of Technology, Raipur India, India.
Virendra Kumar GuptaSr. Vice President & Head Reliance Technology Group, India.
Vijaya Kumar BulasaraAssistant Professor Department of Chemical Engineering Thapar University, Patiala, India.
Yogesh C SharmaSERC Visiting Fellow Department of Applied Chemistry Indian Institute of Technology(BHU)
Vishwanathan BalasubrananianNational Centre for Catalysis Research Indian Institute of Technology-Madras Chennai , India.
Indraneel PulidindiDepartment of Chemistry Bar Ilan University, Israel.
I take the privilege to present the print version for the Volume 1 Issue (2) of Journal of Catalyst and
Catalysis. The intension of JoCC is to create an atmosphere that stimulates creativeness, research
and growth in the area of Catalyst and Catalysis.
The development and growth of the mankind is the consequence of brilliant Research done by
eminent Scientists and Engineers in every field. JoCC provides an outlet for Research findings and
reviews in areas of Catalysis found to be relevant for National and International recent developments
& research initiative.
The aim and scope of the Journal is to provide an academic medium and an important reference for
the advancement and dissemination of Research results that support high level learning, teaching and
research in the domain of Catalysts and Catalysis.
Finally, I would like to thank Editors and Authors for their continued support and invaluable
contributions and suggestions in the form of authoring. I express my sincere gratitude and thanks to
our Editorial board for providing write ups, reviewing and providing constructive comments for the
advancement of the journals. With their continuous support and co-operation, we have been able to
publish quality Research/Reviews findings for our customers base.
I hope you will enjoy reading this issue and we welcome your feedback on any aspect of the Journal.
Dr. Archana Mehrotra
Director
STM Journals
Director's Desk
STM JOURNALS
1. An Efficient Synthesis of Annulated Novel Dihydropyridine Derivatives using Zeolite H-BEA and Zeolite BEA-SO H3
Manoj Kumar K. Rathod, Sunil R. Mistry, Suban K. Sahoo, Kalpana C. Maheria 1
2. CuO/TiO Nanocomposites: Effect of Calcination on Photocatalytic Hydrogen Production 2
D. Praveen Kumar, N. Lakshmana Reddy, M. Mamatha Kumari, B. Srinivas,V. Durga Kumari, M. V. Shankar 13
3. Catalytic Applications of Copper Species in Organic Transformations: A ReviewTandon P. K., Singh S. B. 21
4. Diaminoglyoxime Palladium (II) Chloride As An Efficient Catalyst for the Suzuki-Miyaura Cross-Coupling Reaction under Aerobic Conditions in H O/EtOH Solution2
Ali Reza Faraji, HojatVeisi, Ali Ghardashi, AntonioGil 35
ContentsJournal of Catalyst & Catalysis
JoCC (2014)© STM Journals 2014. All Rights Reserved
Journal of Catalyst & Catalysis ISSN: 2349-4344 (online)
Volume 1, Issue 2
www.stmjournals.com
An Efficient Synthesis of Annulated Novel
Dihydropyridine Derivatives using Zeolite H-BEA
and Zeolite BEA-SO3H
Manoj Kumar K. Rathod, Sunil R. Mistry, Suban K. Sahoo, Kalpana C. Maheria* Applied Chemistry Department, S. V. National Institute of Technology, Ichchhanath,
Surat-395007, Gujarat, India
Abstract Modified zeolite (zeolite BEA-SO3H) was synthesized with intent to improve the surface
area and Si/Al ratio by loading chlorosulphonic acid onto zeolite H-BEA. Parent and
modified zeolite were characterized by variety of characterization techniques such as, ICP, FT-IR, XRD, TGA, NH3-TPD, BET surface area, etc. The catalytic applications of
parent and modified zeolite H-BEA were demonstrated through the synthesis of novel quinoline and benzoquinoline substituted dihydropyridines (DHPs) via one pot Hantzsch
cyclocondensation reaction. This method affords high percentage yield of DHPs (93%)
within short reaction times. The effects of catalysts and substituent’s (different quinolines and benzoquinoline carbaldehydes) on the synthesis of DHPs were studied and related
reaction mechanism was proposed.
Keywords: Zeolite BEA-SO3H, Hantzsch reaction, MCRs, quinoline and
benzoquinoline substituted dihydropyridines
JoCC (2014)© STM Journals 2014. All Rights Reserved
Journal of Catalyst & Catalysis ISSN: 2349-4344 (online)
Volume 1, Issue 2
www.stmjournals.com
CuO/TiO2 Nanocomposites: Effect of Calcination on
Photocatalytic Hydrogen Production
D. Praveen Kumar1, N. Lakshmana Reddy
1, M. Mamatha Kumari
1, B. Srinivas
2,
V. Durga Kumari2, M. V. Shankar
1* 1Nano Catalysis and Solar Fuels Research Lab, Department of Materials Science and
Nanotechnology, Yogi Vemana University, Kadapa-516003, Andhra Pradesh, India 2Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology (IICT),
Hyderabad-500607, Telangana, India
Abstract Hydrothermally synthesized TiO2 nanorods were subjected to calcination from 350 to
550 C and tested their catalytic performance for hydrogen (H2) production in aqueous
glycerol solution under solar irradiation. High rate of H2 evolution ca.300 µmol.h−1
.g−1
cat
was recorded with TiO2 nanorods calcined at 500 C. The nanocomposites were prepared
by varying Cu-loading 0.1 to 2.0 wt% and activated at 350 or 500 C. About 25 folds
enhancement in H2 production rate was observed with 1.5% CuO/TiO2 nanorods than calcined ones. Catalyst characterization revealed that as-synthesized TiO2 material was
nanorods with trititanate crystal structure. The optimized photocatalyst confirmed presence of copper in + 2 state and mixed crystal structure of TiO2(B) and anatase.
Based on the experimental results high photocatalytic activity observed is due to
improved crystallanity of TiO2 nanorods and CuO as well.
Keywords: Nanorods, titanium dioxide, photocatalytic water splitting, biomass,
solar fuel
JoCC (2014)© STM Journals 2014. All Rights Reserved
Journal of Catalyst & Catalysis ISSN: 2349-4344 (online)
Volume 1, Issue 2
www.stmjournals.com
Catalytic Applications of Copper Species in Organic
Transformations: A Review
Tandon P. K.*, Singh S. B. Department of Chemistry, University of Allahabad, Allahabad 211002, U.P., India
Abstract Copper a naturally occurring element is present in the earth's crust, in oceans, lakes, and
rivers, from minute trace element levels through to rich mine deposits. It is essential to
life – plants, fish, animals and humans all need copper to function properly. Homogeneous copper catalyzed reactions are widely used for the construction of
important organic molecules, including pharmaceuticals, commodity chemicals, and
polymers. The development of copper catalysis has been used extensively in the formation of carbon–carbon and carbon–heteroatom bonds. This Review describes the recent
advances in the fundamental chemistry and the catalytic applications of copper and its complexes in various synthetically useful organic transformations. Present review also
provides a deeper mechanistic understanding of copper chemistry which may lead to the
development of the improved copper catalysts for known chemical reactions and may also inspire novel copper-catalyzed organic transformations.
Keywords: Copper, catalysis, organic transformations, nanocatalysis,
copper-nanoparticles
JoCC (2014)© STM Journals 2014. All Rights Reserved
Journal of Catalyst & Catalysis ISSN: 2349-4344 (online)
Volume 1, Issue 2
www.stmjournals.com
Diaminoglyoxime Palladium (II) Chloride As An Efficient
Catalyst for the Suzuki-Miyaura Cross-Coupling Reaction under
Aerobic Conditions in H2O/EtOH Solution
Ali Reza Faraji1*, HojatVeisi
2, Ali Ghardashi
2, AntonioGil
3
1Faculty of Chemistry, Pharmaceutical Sciences Branch, Islamic Azad University, Tehran, Iran
2Department of Chemistry, Payame Noor University, 19395-4697 Tehran, Iran
3Department of Applied Chemistry, Los Acebos Building, Public University of Navarra,
Campus of Arrosadia, E-31006, Pamplona, Spain
Abstract The preparation of diaminoglyoxime palladium (II) chloride (PdCl2/DAG complex) and the use of this catalytic system in Suzuki-Miyaura cross-coupling reactions under aerobic
and phosphine-free conditions in aqueous solutions is studied. Aryl halides, coupled with
phenylboronic acids smoothly afford the corresponding cross-coupling products with excellent yields (80–98%). The catalytic system showed excellent performance for the
Suzuki-Miyaura cross-coupling reaction of less reactive aryl chlorides with aryl boronic acids. The reaction conditions have been evaluated considering the effect of various
parameters such as reaction time, temperature, amount of catalyst, amount of base and
its nature and solvent.
Keywords: Suzuki-Miyaura, cross-coupling reaction, palladium catalyst, aryl halide,
aryl boronic acid
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