the roesky working group: facilities, collaborations, · pdf filethe roesky working group:...

The Roesky Working Group:

Facilities, Collaborations, and Science

P W Roesky Institut für Anorganische ChemieP. W. Roesky, Institut für Anorganische Chemie

KIT – Universität des Landes Baden-Württemberg undnationales Großforschungszentrum in der Helmholtz-Gemeinschaft www.kit.edu

TeamTeam

Institut für Anorganische ChemieP. W. Roesky

Institut für Anorganische ChemieP. W. Roesky

Invited Speakers

Polly Arnold, University of Edinburgh, UK

Isabelle Billard, IPHC/DRS, Strasbourg, France, , g,

William J. Evans, UC Irvine, USA

Sophie M. Guillaume, Université de Rennes, France

Peter C. Junk, Monash University, Clayton, Australia

Arndt Simon, MPI, Stuttgart, Germany

33 O h L33 Other Lectures

150 Participants

Institut für Anorganische ChemieP. W. Roesky

Research BackgroundExpertise:Expertise:

Strong background in the synthesis of organometallic and coordination compounds.

Catalysis:y

• Hydroamination

• Polymerization

We do not handle radioactive material but we cooperate with the INE and the ITU in K l hKarlsruhe.

Institut für Anorganische ChemieP. W. Roesky

FacilitiesEquipment

State of the art equipment for handling air stable to highly air sensitive compoundsState of the art equipment for handling air stable to highly air sensitive compounds

• Different kinds of Schlenk lines

• Glove boxes

Institut für Anorganische ChemieP. W. Roesky

FacilitiesInstrumentation

• NMR• NMR

• Single Crystal X-ray diffraction

Institut für Anorganische ChemieP. W. Roesky

FacilitiesInstrumentation

IR and Raman Spectroscopy• IR and Raman Spectroscopy

• Elemental Analysis

Institut für Anorganische ChemieP. W. Roesky

FacilitiesInstrumentation

• Mass spectroscopy (EI and ESI)

• HPLC

Institut für Anorganische ChemieP. W. Roesky

Collaborations

Collaborations with French Groups

Long term collaboration in the field of polymerization

Dr. Sophie Guillaume: Université de Rennes 1 Polymerization

Prof. Laurent Maron: Université Paul Sabatier TheoryTheory

4 Joint Publications since 2007 + 1 submitted4 Joint Publications since 2007 1 submitted

Institut für Anorganische ChemieP. W. Roesky

CollaborationsCollaborations in the field of Nuclear Waste Disposal

Collaboration with the Institut für Nukleare Entsorgung, KIT

and the Universität Heidelbergg

Dr. Melissa A. DeneckeEXAFS

Dr. Andreas Geist Actinide(III) / lanthanide(III) separation 02NUK012

Prof. Dr. Petra J. PanakTRLFS

1 Joint Publication since 2010 + 1 submitted

Institut für Anorganische ChemieP. W. Roesky

Science

Sc

Y

La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu

Institut für Anorganische ChemieP. W. Roesky

Science: An Overview

Lanthanides

Homogenous catalysis: HydroaminationPolymerization

Cluster und porous strucrtures (MOF): MagnetismCluster und porous strucrtures (MOF): MagnetismLuminescens

M t l t t l b dMetal-to-metal-bonds

Nuclear waste disposalp

Institut für Anorganische ChemieP. W. Roesky

Science

Ca

Sr

Ba

Institut für Anorganische ChemieP. W. Roesky

Science: An Overview

Alkaline Earth Metals

H t l i H d i tiHomogenous catalysis: Hydroamination

Metal-to-metal-bonds

Institut für Anorganische ChemieP. W. Roesky

Science

Zn

Institut für Anorganische ChemieP. W. Roesky

Science: An Overview

Zinc

Homogenous catalysis: HydroaminationPolymerization

M t l t t l b dMetal-to-metal-bonds

Institut für Anorganische ChemieP. W. Roesky

Science

Au

Institut für Anorganische ChemieP. W. Roesky

Science: An Overview

GoldGold

Heterogenous catalysis

Metal-to-metal-bonds

L minescensLuminescens

Institut für Anorganische ChemieP. W. Roesky

The First Main-Group-Lanthanide Metal-to-Metal bonds

1/4 [(5 C5Me5)Al]4 + [(5 C5Me5)2Eu] Eu Al1/4 [( -C5Me5)Al]4 + [( -C5Me5)2Eu] Eu Al

d: Al-Eu 3.3652(10) Å

space group P1R1 = 0.0237 wR2 = 0.0659

M T Gamer P W Roesky S N Konchenko P Nava R Ahlrichs

Institut für Anorganische ChemieP. W. Roesky

M. T. Gamer, P. W. Roesky, S. N. Konchenko, P. Nava, R. Ahlrichs Angew. Chem., Int. Ed. 2006, 45, 4447-4451.

The first Molecular Polyphosphide of the Rare-Earth Elements

P

Sm + 2

P

P P4

S N Konchenko N A Pushkarevsky M T Gamer R Köppe H Schnöckel P W Roesky

Institut für Anorganische ChemieP. W. Roesky

S. N. Konchenko, N. A. Pushkarevsky, M. T. Gamer, R. Köppe, H. Schnöckel, P. W. Roesky J. Am. Chem. Soc. 2009, 131, 5740–5741.

The first Polyphosphide Triple-decker Complexes of the Rare-Earth Elements p

PP

Fe

PPP

P P

DIPSmTHF THFIII

N DIPDIP

NN

T Li J Wiecko N A Pushkarevsky M T Gamer R Köppe S N Konchenko M Scheer An

First mixed d /f metals triple-decker complex

Institut für Anorganische ChemieP. W. Roesky

T. Li, J. Wiecko, N. A. Pushkarevsky, M. T. Gamer, R. Köppe, S. N. Konchenko, M. Scheer, AnAngew. Chem. Int. Ed. 2011, 50, 9491-9495.