atomic layer deposition: ald 101 - chip history · atomic layer deposition or ald •it’s much...

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VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.com Copyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC. 1 Atomic Layer Deposition: ALD 101 The Chip History Center Preserving the History of Semiconductors for Future Generations

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Page 1: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

1

Atomic Layer Deposition:

ALD 101

The Chip History CenterPreserving the History of Semiconductors for Future Generations

Page 2: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

2

Did you know that

chip makers

routinely make films

one atom at a time?

Page 3: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

3

Those atoms are better

organized than these tulips.

Page 4: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

4

It’s called:

Atomic Layer Deposition

or ALD• It’s much finer than either . . .

–Chemical Vapor Deposition (CVD)

–or Physical Vapor Deposition (PVD)

Page 5: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

5

CVD and PVD

throw down molecules haphazardly.

Page 6: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

6

ALD uses the natural bonds

on the base layer to self-assemble.

Page 7: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

7

Bonds in molecule ‘A’ hook up

with those on the green base layer.

Page 8: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

8

The bonds are like parking spaces for the A

atoms, filling up with more molecules.

Page 9: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

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The A atoms also have bonds

for the yellow ‘B’ atoms.

Page 10: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

10

The atoms will not adhere . . .

Page 11: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

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Unless they can find a bond.

Page 12: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

12

As more atoms flow over the surface of the

A atoms . . .

Page 13: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

13

The A level parking lot is filled up

with B atoms.

Page 14: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

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Then it starts all over again.

Page 15: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

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The A atoms are now linking to the open

bonds on the B atom layer.

Page 16: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

16

Soon the B level is filled up with A atoms

It won’t stop until the lot is saturated!

Page 17: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

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But the atoms will only stick

were there are open bonds,

Page 18: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

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making for perfectly uniform layers

a single atom thick.

Page 19: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

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You can continue until the perfect film is

made to your exact specifications.

Page 20: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

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And that’s ALD!

Page 21: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

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Photography by

Dan Hutcheson

Story by

Jan & Dan Hutcheson

With many thanks for the support and

encouragement of

Aviza Technology

Page 22: Atomic Layer Deposition: ALD 101 - Chip History · Atomic Layer Deposition or ALD •It’s much finer than either . . . –Chemical Vapor Deposition (CVD) –or Physical Vapor Deposition

VLSIRESEARCH.com CHIPHISTORY.org WILDPHOTONS.comCopyright © 2006 VLSI Research Inc. All rights reserved. Reprinted with permission from VLSI RESEARCH INC.

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The Chip History CenterPreserving the History of Semiconductors for Future Generations