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    RadiationByNitin Oke

    For Safe Hands

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    Flow of heat

    Net Heat flow is from body with more heattemperature to body at less heat temperature

    Flow of heat can take place in three ways Conduction

    Conviction

    Radiation

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    Facts about flow-

    Heat flow

    ConvictionConduction Radiation

    No Motion ofparticle

    Slowest

    Mostefficient

    Motion ofparticle

    Moderate

    Moderateefficient

    Electromagnetic wave

    Fastest

    Leastefficient

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    Facts about Radiation-

    Heat flow

    ConvictionConduction Radiation

    No Motion ofparticle

    Slowest

    Mostefficient

    Motion ofparticle

    Moderate

    Moderateefficient

    Electromagnetic wave

    Fastest

    Leastefficient

    Co

    smic rays

    Gamma rays

    UV rays

    Visible rays

    IR rays

    Micro waves

    Radio waves

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    More about Electromagneticspectrum

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    Properties of heat radiation:

    It exhibits the phenomena of reflection,refraction, interference, diffraction andpolarization.

    Heat radiations can travel through vacuum andother transparent media.

    Heat radiations do not affect the medium throughwhich they pass.

    Heat radiation consists mostly of infrared rays,which are electromagnetic waves whose wavelengthrange from 8 x 10 7m to 4 x 10 4m.

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    Facts about Radiation-

    Heat radiation is with wave length rangingbetween 10-6m to 10-3m in reality thewavelength of heat radiation ranges from8 x 10 7 m to 4 x 10 4 m where as the wave

    length of visible light ranges from 4 x 10 7mto 8 x 10 7m. These waves are invisible to human

    Frequency ranges from 1011

    Hz to 1014

    Hz

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    QTQR

    What means a, r, t

    If Q amount of hest isincident on surface.

    QR is reflected

    QA is absorbed

    QT is transmitted

    By law of conservation of

    energy Q = QR+QA+ QT

    Q

    QA

    Q

    Qt,

    Q

    Qr

    Q

    Qa TRA === ,

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    Classification based on a, r and t

    If t = 1 then substances are called asdiathermanous.

    Examples of substances which are transparent toheat radiation are Quartz, glass, Rock salt, dry air, O2 , H2, NaCl,

    CCl4, CHCl3 If t = 0 then substances are called as

    athermanous. Examples of substances which are transparent toheat radiation are Water, Wood, C6H6, R-OH, Cu, Iron

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    Facts about Radiation- To detect these waves Crooks radiometer or Boys

    radiometer are used. Energy of radiation can be measured by Bolometer Heat Radiations spectrum was studied graphically by

    Langley ( Not black body spectrum )

    Spectrum of Black body was studied at differenttemperatures by Lummer and Prigsheim The black body used was constructed by Fery Wien found relation between temperature and maximum

    corresponding wavelength.

    Stefan and Boltzman related area under the curvemeans total heat and T4

    The graph was explained by Max Plank using Quantumtheory.

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    Observations of graph When radiations of Black body were studied at

    different temperatures by Lummer andPrigsheim the observations were as follows The graph is different at different temperature As temperature increases the graph shifts up

    The graphs maxima shifts backward as temperatureincreases. The area under the curve, means total energy per

    unit area per unit time means emissive power isproportional to T4 (Stefans law)

    The Emax is proportional to T5

    The wavelength corresponding to Emax is inverselyproportional to T. max.T = b The value of b is0.2892 x 10-2mK ( Wiens displacement law).

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    Prevost theory of heat exchange

    Every body continuously radiates heatenergy at all temperatures except absolutezero.

    The amount of radiant energy emitted perunit time depends only on absolutetemperature of body and NOT on

    surrounding temperature.

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    Hot

    Heat exchange is as --

    Less Hot

    Hot

    More Hot

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    Kirchhoffs Law of radiation

    The coefficient of absorption is same as coefficient ofemission.

    Theoretical proof of Kirchhoffs law

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    Ritchies Experiment

    aAEb 1xAE

    aAEb = 1.A.E

    a =E/Eb = e

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    Ritchies Experiment

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    Stefans Law and its applications

    The radiant energy emitted by perfectlyblack body per unit area per unit time isdirectly proportional to forth power of

    absolute temperature. The constant of proportionality is called as

    Stefans constant and denoted by .

    The value of is 5.67 x 10-8 J/m2.s.K4 (W/m2K4)

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    Generalization of Stefans Law

    Using Kirchhoffs law Stefans Law can be generalizedas Emissive power: The amount of heat radiation emitted

    by a body per unit time per unit area is called asemissive power of the body.

    If above body is black body then it is left hand side ofStefans law.

    Coefficient of emission or emissivity of a body is ratioof emissive power of a body and perfectly black body

    at same temperature. Denoted by e. e = E/Eb As a = e Hence E = a. Eb = a ..T4

    For ordinary bodies Stefans Law will be

    Q = a(A.t..T4

    )

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    Newtons law of heat

    The rate of loss of heat by a body is directlyproportional to the excess temperature of thebody over the surrounding.

    Please note that the law was stated quite earlierthan Stefans law and Provost's theory.

    )(

    dt

    dQ0

    Newtons law of cooling

    )k.(

    dt

    dQ0=

    dt

    dm.s.

    dt

    dQbut

    =

    )k(dt

    dm.s. 0= )K(dt

    d0=

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    Newtons law as approximation of Stefans Law

    Latter on when new theory was developed the Newtonslaw was obtained as approximation of Stefans BoltzmanLaw.

    Assuming T = T0 + x and using binomial expansion and the

    fact that T0 > > > x we get

    Obviously we need to use T-T0 = - 0

    )k.(dt

    dQ0=

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    Solar constant

    The solar constant is the amount of radiant energy receivedper second per unit area by a perfect black body placed onthe Earth with its surface perpendicular to the direction ofradiation from the Sun.

    Solar constant is different for different planets as theirdistance is different from Sun.

    Value of Solar constant is 1.388 x 103W/m2

    Instrument used to measure Solar constant is

    Pyro heliometre Simplest of all is Angstrongs Compensation pyro heliometre

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    Temperature of Sun Using Wiens Law

    If is wavelength of radiation for

    which Solar radiation is maximum( 4900 x 10-10m) then

    002892.0T. =maxlawWien'sUsing

    K590210x4900

    002892.0T

    10==

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    Note the following

    If two bodies are of surface area A

    1

    and A2

    coefficient of absorption a1 and a2 attemperature T1 and T2 then rate of emission

    of heat radiation is

    222

    111

    2

    1

    TAa

    TAa

    dt

    dQ

    dt

    dQ

    =

    If they are of same material then a1 = a2

    22

    11TA

    TA

    =If they are of same material then a

    1

    = a2

    and are at same temperature T1 = T2

    2

    2

    2

    1

    2

    1

    r

    r

    A

    A== If they are of same material then a1 = a2

    and are at same temperature T1 = T2 and

    spherical in shape.

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    Note the following If two bodies of mass m1 & m2 ,surface area

    A1 & A2 coefficient of absorption a1 and a2 attemperature T1 & T2 specific heats s1 and s2and densities 1& 2 then rate of cooling is

    11222

    22111

    22

    222

    11

    111

    2

    1

    smTAa

    smTAa

    sm

    TAa

    sm

    TAa

    dt

    d

    dt

    d

    =

    =

    If they are of same materialthen a1 = a2 and s1 = s2

    122

    211mTA

    mTA

    =

    In addition if are at same

    temperature T1 = T2 andspherical

    1

    2

    1

    3

    1

    2

    2

    2

    3

    2

    2

    1

    12

    21

    r

    r

    )r

    3

    4(r

    )r3

    4(r

    mA

    mA=

    ==