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    The ChemicalComposition of Cells

    Chapter 2

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    LEARNING OBJECTIVE 1

    Describe the basic structure of an atom,and explain ionic, covalent, and hydrogen

    bonds

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    Atoms

    Atom smallest possible particle of anelement that still possesses and elements

    property

    Subatomic particles: Proton- positive electric charge, small mass Neutron- uncharged, about same mass as proton Electron- negative charge, extremely small mass

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    Neutron

    Electron

    Proton

    +

    +++

    ++

    +

    Fig. 2-1, p. 24

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    Isotopes of Hydrogen

    Isotopes similar elements that contain different numbers of neutrons

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    Electrons

    Move around the nucleus at differentenergy levels

    Allow elements to combine chemically toform chemical compounds

    Ions are atoms which tend to gain or loseelectrons

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    Electron Configurations

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    (b) Carbon (C)(6p, 6n)

    Electron

    Nucleus

    First (lowest)

    energy level

    Second energylevel

    (a) Hydrogen (H)(1p)

    Fig. 2-3ab, p. 25

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    (d) Nitrogen (N)

    (7p, 7n)

    (c) Oxygen (O)

    (8p, 8n)

    Fig. 2-3cd, p. 25

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    (e) Sodium (Na)

    (11p, 12n)

    (f) Chlorine (Cl)

    (17p, 18n)

    Fig. 2-3ef, p. 25

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    Atoms are capable of forming

    bonds Chemical bond attractive force that holds 2 or more

    atoms together

    Chemical bonds form compounds

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    KEY TERMS

    IONIC BOND An electrostatic attraction between oppositely

    charged ions

    COVALENT BOND A chemical bond involving one or more

    shared pairs of electrons

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    Ionic Bonding

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    11 protons 17 protons

    and

    11 electronsSodium (Na)

    17 electronsChlorine (Cl)

    10 electrons

    Sodium ion (Na+)

    18 electrons

    Chloride ion (Cl)

    +

    Fig. 2-4a, p. 26

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    Arrangement of atoms in acrystal of salt

    Sodium chloride (NaCl)

    Cl Na+

    Cl

    Cl

    Na+Na+

    Na+

    Fig. 2-4b, p. 26

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    Covalent Bonding in Hydrogen

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    Hydrogen (H) Hydrogen (H) Molecular hydrogen (H2)

    Fig. 2-5, p. 27

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    Covalent Bonding in Methane

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    Types of Covalent Bonds

    Nonpolar covalent bonds electrons are equally

    shared

    Polar covalent bonds electrons are unequally

    shared

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    KEY TERMS

    HYDROGEN BOND An attraction between a slightly positive hydrogen

    atom in one molecule and a slightly negative atom

    (usually oxygen) in another molecule

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    LEARNING OBJECTIVE 2

    Discuss the properties of water, andexplain the importance of water to life

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    Why is water important?

    Essential to life Controls our climate Shapes continents

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    Water is a polar substance

    Polar substance substances with partial charges

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    Water

    Has a strong dissolving ability Molecules form hydrogen bonds with one another

    (cohesion)

    Molecules form hydrogen bonds to substances withionic or polar regions (adhesion)

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    LEARNING OBJECTIVE 3

    Distinguish between acidsand bases, anddescribe the pH scale

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    Acids and Bases

    Definition Acidsdissociate in water to form hydrogen

    ions (protons, H+)

    Basesdissociate in water to yield negatively

    charged hydroxide ions (OH-)

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    pH Scale

    A measure of the relative concentrationsof H+and OH-in a solution

    A solutions acidity or alkalinity isexpressed in terms of the pH scale

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    ACID RAIN!!

    Accumulation of sulfur oxides andnitrogen oxides in the atmosphere

    Suflur oxide &nitrogen oxide combinewith water to form SULFURIC andNITRIC ACID

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    LEARNING OBJECTIVE 4

    Describe the chemical compositions andfunctions of carbohydrates, lipids, proteins,and nucleic acids

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    Carbohydrates Include sugars, starches, cellulose

    Important fuel molecules, components of molecules(nucleic acids) and cell walls

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    Carbohydrates

    Types of carbohydrates1. Monosaccharides - simple sugars

    2. Disaccharides-two monosaccharide units

    3. Polysaccharides- many monosaccharide

    units

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    Common Monosaccharides

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    Sucrose Synthesis

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    Starch: A Storage Polysaccharide

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    Cellulose: A Structural

    Polysaccharide

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    Lipids

    Organic compounds that have a greasy consistency, donot readily dissolve in water

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    Lipids

    Types of Lipids:1. Neutral fats2. Oils3. Phospholipids

    4.

    Pigments and Waxes

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    Lipids

    Neutral fats / oils1. Neutral fats solid at room temperature2. Oil- liquid at room temperature

    Contain a molecule of glyceroljoined to one, two orthree fatty acids

    Glycerol 3 carbon compound that contains ahydroxyl group

    Usually used as a source of energy

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    Formation of a Neutral Fat or Oil

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    Lipids

    Fatty acids Long, unbranched

    hydrocarbon chainwith a carboxyl group

    at one end Types:

    Saturated contain nocarbon to carbon

    double bonds

    Unsaturated contain1 or more carbon to

    carbon double bonds

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    Saturated Unsaturated

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    Lipids

    Phospholipids Important component of the cell membrane Consists of a glycerol molecule and 2 fatty acids

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    Lipids

    Waxes Cutin waxy substance found in the outer wall of

    epidermal cells

    Suberin substance found in the walls of cork cells

    Prevent water loss

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    Protein

    A macromolecule composed of amino acidsjoined bypeptide bonds

    Order of amino acids determines structure and functionof a protein molecule

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    Proteins

    Enzymes A protein which controls the rate at which a chemical

    reaction occurs

    Highly specific E.g. Sucrase

    Substrate the material in which theenzyme works on

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    Amino Acids

    Basic unit of proteins Contain a carbon atom bonded to an amino acid

    (-NH2), a carboxyl group (-COOH2) and a side

    chain, designated R

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    Peptide Bonds

    Bonds that links one amino acid to another as aresult of a condensation reaction

    Several amino acids connected to each othercan form a polypeptide chain

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    Organization of Protein Molecules

    Organization of Protein

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    Organization of Protein

    Molecules

    Primary linear sequence of amino acids Secondary spiral helix

    Tertiary over-all shape of a polypeptide chaindetermined by interactions of side chains of aa

    Quaternary 2 or more polypeptide chainsassociate to form one final protein molecule

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    (d) Quaternary(a) Primary (b) Secondary (c) Tertiary

    Fig. 2-15, p. 37

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    Nucleic Acids

    Macromolecules that are made out of carbon,hydrogen, nitrogen and phosphorous

    Control the cell

    s life processes

    Deoxyribonucleic acid (DNA) Transmits information from one generation to the next

    Ribonucleic acid (RNA) Involved in protein synthesis

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    Nucleotides

    Repeating units that form nucleic acids Order of nucleotides in a nucleic acid chain determines

    the specific information encoded

    Parts of a nucleotide1. Nitrogenous base2. 5-carbon sugar

    3. Phosphoric acid

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    Nucleic Acids

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    Nucleic Acids

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    Phosphate

    Adenine(a nitrogenous

    base)

    Deoxyribose(a five-carbon sugar)

    (a) Nucleic acids are composed of nucleotides. Like allnucleotides, this DNA nucleotide has three parts: a nitrogenous

    base, a five-carbon sugar, and a phosphate group.

    H H

    Fig. 2-18a, p. 39

    Two sugar-phosphatebackbones

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    backbones

    Pairedbases

    Region of

    hydrogen bonding

    (c) The DNA molecule is a double helix

    consisting of two nucleotide chainsjoined by their paired bases.

    (d) A small part of a DNA molecule isunwound to show how the bases pair

    (the region of hydrogen bonding).Fig. 2-18cd, p. 39

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    ATP Adenosine triphosphate Modified nucleotide Composition:

    Base adenine Sugar ribose 3 phosphate molecules

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    Enzymes

    Speed up a chemical reaction by loweringits activation energy(energy needed to

    initiate the reaction)

    Most enzymes are highly specific andcatalyze only a single chemical reaction

    Without enzymes, chemical reactions incells would occur too slowly to support life

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    Enzymes and Activation Energy

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    Enzyme-Substrate Complex

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    Active sites

    Enzyme Substrates Enzymesubstratecomplex

    Enzyme Products

    Fig. 2-17, p. 38Stepped Art

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    LEARNING OBJECTIVE 6

    State the firstand second laws ofthermodynamics, and describe how eachapplies to plants and other organisms

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    KEY TERMS

    FIRST LAW OF THERMODYNAMICS Energy cannot be created or destroyed,

    although it can be transformed from one form

    to another

    SECOND LAW OF THERMODYNAMICS When energy is converted from one form to

    another, some of it is degraded into a lower-

    quality, less useful form

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    Energy

    The ability to do work

    Plants and other organisms cannot createthe energy they require to live, but must

    capture energy from the environment and

    use it to do biological work

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    E

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    Entropy

    Measure of the disorder of less usable energy Continuously increases in the universe as

    usable energy is converted to lower-quality, lessusable form (heat)

    As each energy transformation occurs inorganisms, some energy changes to heat

    Given off into the surroundings Can never be used again for biological work

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    A i i H A B d

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    Animation: How Atoms Bond

    CLICKTO PLAY

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    Animation: Miller s Reaction

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    Animation: Millers Reaction

    Chamber Experiment

    CLICKTO PLAY

    Animation: Structure of Starch

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    Animation: Structure of Starch

    and Cellulose

    CLICKTO PLAY

    Animation: Triglyceride

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    Animation: Triglyceride

    Formation

    CLICKTO PLAY

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