discriminación del origen de aerosoles urbanos y regionales en el...
TRANSCRIPT
1
DAUREDiscriminación del origen de Aerosoles Urbanos y REgionales en el NE de la Península Ibérica
Identification of the origin of atmospheric aerosols in NE Iberian Peninsula
CSIC, 26th May 2009
Querol X., Alastuey A., Pandolfi M., Pey J., Cusack M., Reche C., Moreno T., Viana M., Amato F., Pérez N., Moreno N.
Barcelona Montseny
PM1
PMcoarse
PM2.5
NO3
SO4
NH4
Org
Number
23/02/2009
24/02/2009
25/02/2009
26/02/2009
27/02/2009
28/02/2009
01/03/2009
02/03/2009
03/03/2009
04/03/2009
05/03/2009
06/03/2009
07/03/2009
08/03/2009
09/03/2009
10/03/2009
11/03/2009
12/03/2009
13/03/2009
14/03/2009
15/03/2009
16/03/2009
17/03/2009
18/03/2009
19/03/2009
20/03/2009
21/03/2009
22/03/2009
23/03/2009
24/03/2009
25/03/2009
26/03/2009
27/03/2009
28/03/2009
29/03/2009
BC
A1a
2
26/02/2009
A1a
0
90
180
270
360
0:00 2:00 4:00 6:00 8:00 10:00 12:00 14:00 16:00 18:00 20:00 22:00 0:00
Win
d di
rect
ion
(º)
0
1
2
3
4
Win
d sp
eed
MSY BCN
No breeze circulation.Regional pollution affecting all sites.Mixing layer well developed.
DUST
POLLUTION-SMOG
26/02/2009 (A1a)
3
LIDAR measurements @ 532 nm (UPC); 26/02/2009 18:52 UTC (A1a)
Barcelona Montseny
PM1
PMcoarse
PM2.5
NO3
SO4
NH4
Org
Number
23/02/2009
24/02/2009
25/02/2009
26/02/2009
27/02/2009
28/02/2009
01/03/2009
02/03/2009
03/03/2009
04/03/2009
05/03/2009
06/03/2009
07/03/2009
08/03/2009
09/03/2009
10/03/2009
11/03/2009
12/03/2009
13/03/2009
14/03/2009
15/03/2009
16/03/2009
17/03/2009
18/03/2009
19/03/2009
20/03/2009
21/03/2009
22/03/2009
23/03/2009
24/03/2009
25/03/2009
26/03/2009
27/03/2009
28/03/2009
29/03/2009
BC
A1aA2b
4
0
90
180
270
360
0:00 2:00 4:00 6:00 8:00 10:00 12:00 14:00 16:00 18:00 20:00 22:00 0:00
Win
d di
rect
ion
(º)
0
1
1
2
2
3
3
4
4
Win
d sp
eed
MSY BCN
28/02/2009
A2b
Regional pollution only affecting BCN.
Barcelona Montseny
PM1
PMcoarse
PM2.5
NO3
SO4
NH4
Org
Number
23/02/2009
24/02/2009
25/02/2009
26/02/2009
27/02/2009
28/02/2009
01/03/2009
02/03/2009
03/03/2009
04/03/2009
05/03/2009
06/03/2009
07/03/2009
08/03/2009
09/03/2009
10/03/2009
11/03/2009
12/03/2009
13/03/2009
14/03/2009
15/03/2009
16/03/2009
17/03/2009
18/03/2009
19/03/2009
20/03/2009
21/03/2009
22/03/2009
23/03/2009
24/03/2009
25/03/2009
26/03/2009
27/03/2009
28/03/2009
29/03/2009
BC
A1aA2b A3a
5
2/03/2009
A3a
Well established breeze circulation.Regional pollution affecting all sites.Low PBL + multilayers. 0
90
180
270
360
0:00 2:00 4:00 6:00 8:00 10:00 12:00 14:00 16:00 18:00 20:00 22:00 0:00
Win
d di
rect
ion
(º)
0
1
1
2
2
3
3
4
4
Win
d sp
eed
MSY BCN
LIDAR measurements @ 532 nm (UPC); 02/03/2009 18:05 UTC (A3a)
6
Barcelona Montseny
PM1
PMcoarse
PM2.5
NO3
SO4
NH4
Org
Number
23/02/2009
24/02/2009
25/02/2009
26/02/2009
27/02/2009
28/02/2009
01/03/2009
02/03/2009
03/03/2009
04/03/2009
05/03/2009
06/03/2009
07/03/2009
08/03/2009
09/03/2009
10/03/2009
11/03/2009
12/03/2009
13/03/2009
14/03/2009
15/03/2009
16/03/2009
17/03/2009
18/03/2009
19/03/2009
20/03/2009
21/03/2009
22/03/2009
23/03/2009
24/03/2009
25/03/2009
26/03/2009
27/03/2009
28/03/2009
29/03/2009
BC
A1aA2b A3aB
05/03/2009
B
0
90
180
270
360
0:00 2:00 4:00 6:00 8:00 10:00 12:00 14:00 16:00 18:00 20:00 22:00 0:00
Win
d di
rect
ion
(º)
0
2
4
6
8
10
12
Win
d sp
eed
MSY BCN
Intense northerly winds.Very low PM pollution at all sites.Low develop of the mixing layer.
7
LIDAR measurements @ 532 nm (UPC); 06/03/2009 16:08 UTC (B)
Barcelona Montseny
PM1
PMcoarse
PM2.5
NO3
SO4
NH4
Org
Number
23/02/2009
24/02/2009
25/02/2009
26/02/2009
27/02/2009
28/02/2009
01/03/2009
02/03/2009
03/03/2009
04/03/2009
05/03/2009
06/03/2009
07/03/2009
08/03/2009
09/03/2009
10/03/2009
11/03/2009
12/03/2009
13/03/2009
14/03/2009
15/03/2009
16/03/2009
17/03/2009
18/03/2009
19/03/2009
20/03/2009
21/03/2009
22/03/2009
23/03/2009
24/03/2009
25/03/2009
26/03/2009
27/03/2009
28/03/2009
29/03/2009
BC
A1aA2b A3aB
C1a
8
C1a
0
90
180
270
360
0:00 2:00 4:00 6:00 8:00 10:00 12:00 14:00 16:00 18:00 20:00 22:00 0:00
Win
d di
rect
ion
(º)
0
1
2
3
4
5
6
Win
d sp
eed
MSY BCN
Breeze circulation.Regional pollution levels growing upMixing layer increasing.
11/03/2009
LIDAR measurements @ 532 nm (UPC); 12/03/2009 10:33 UTC (C1a)
9
Barcelona Montseny
PM1
PMcoarse
PM2.5
NO3
SO4
NH4
Org
Number
23/02/2009
24/02/2009
25/02/2009
26/02/2009
27/02/2009
28/02/2009
01/03/2009
02/03/2009
03/03/2009
04/03/2009
05/03/2009
06/03/2009
07/03/2009
08/03/2009
09/03/2009
10/03/2009
11/03/2009
12/03/2009
13/03/2009
14/03/2009
15/03/2009
16/03/2009
17/03/2009
18/03/2009
19/03/2009
20/03/2009
21/03/2009
22/03/2009
23/03/2009
24/03/2009
25/03/2009
26/03/2009
27/03/2009
28/03/2009
29/03/2009
BC
A1aA2b A3aB
C1a
C2a
DUST
POLLUTION-SMOG
18/03/2009 (C2a)
10
0
90
180
270
360
0:00 2:00 4:00 6:00 8:00 10:00 12:00 14:00 16:00 18:00 20:00 22:00 0:00
Win
d di
rect
ion
(º)
0
1
2
3
4
5
6
Win
d sp
eed
MSY BCN
C2a
19/03/2009
Breeze circulation.Regional pollution levels growing upMixing layer increasing.
LIDAR measurements @ 532 nm (UPC); 19/03/2009 18:51 UTC (C2a)
11
Barcelona Montseny
PM1
PMcoarse
PM2.5
NO3
SO4
NH4
Org
Number
23/02/2009
24/02/2009
25/02/2009
26/02/2009
27/02/2009
28/02/2009
01/03/2009
02/03/2009
03/03/2009
04/03/2009
05/03/2009
06/03/2009
07/03/2009
08/03/2009
09/03/2009
10/03/2009
11/03/2009
12/03/2009
13/03/2009
14/03/2009
15/03/2009
16/03/2009
17/03/2009
18/03/2009
19/03/2009
20/03/2009
21/03/2009
22/03/2009
23/03/2009
24/03/2009
25/03/2009
26/03/2009
27/03/2009
28/03/2009
29/03/2009
BC
A1aA2b A3aB
C1a
C2a C3a
24/03/2009
C3a
0
90
180
270
360
0:00 2:00 4:00 6:00 8:00 10:00 12:00 14:00 16:00 18:00 20:00 22:00 0:00
Win
d di
rect
ion
(º)
0
1
2
3
4
5
6
7
8
Win
d sp
eed
MSY BCN
Well established breezes at MSY and BCN.Regional pollution affecting all sites
12
DAUREDiscriminación del origen de Aerosoles Urbanos y REgionales en el NE de la Península Ibérica
Identification of the origin of atmospheric aerosols in NE Iberian Peninsula
CSIC, 26th May 2009
DAURE measurements by CSIC: PART-1: BCN
Querol X., Alastuey A., Pandolfi M., Pey J., Cusack M., Reche C., Moreno T., Viana M., Amato F., Pérez N., Moreno N.
0
5
10
15
20
25
30
35
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24
h (GMT)
PM (µ
g/m
3 )
PM2.5-10 PM1-2.5 PM1
0
10
20
30
40
50
60
70
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24
h (GMT)
PM
(µg/
m3 )
PM10 PM2.5 PM1
BCN (corrected)
0102030405060708090
100110120130140150160170180190200
22/02 23/02 24/02 25/02 26/02 27/02 28/02 01/03 02/03 03/03 04/03 05/03 06/03 07/03 08/03 09/03 10/03 11/03 12/03 13/03 14/03 15/03 16/03 17/03 18/03 19/03 20/03 21/03 22/03 23/03 24/03 25/03 26/03 27/03 28/03
PM (µ
g/m
3 )
PM10 PM2.5 PM1
Frequent PM10 episodes due to resuspension: construction/demolition
13
BCN
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
22/02
23/02
24/02
25/02
26/02
27/02
28/02
01/03
02/03
03/03
04/03
05/03
06/03
07/03
08/03
09/03
10/03
11/03
12/03
13/03
14/03
15/03
16/03
17/03
18/03
19/03
20/03
21/03
22/03
23/03
24/03
25/03
26/03
27/03
28/03
29/03
30/03
31/03
01/04
N (n
/cm
3 , 5-5
00 n
m)
0
2000
4000
6000
8000
10000
12000
BC
(AC
, ng/
m3 )
N/cm3 (5-500 nm) BC (AC)
BCN
0
10
20
30
40
50
60
70
22/02
23/02
24/02
25/02
26/02
27/02
28/02
01/03
02/03
03/03
04/03
05/03
06/03
07/03
08/03
09/03
10/03
11/03
12/03
13/03
14/03
15/03
16/03
17/03
18/03
19/03
20/03
21/03
22/03
23/03
24/03
25/03
26/03
27/03
28/03
29/03
30/03
31/03
01/04
PM(µ
g/m
3 )
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
N/c
m3 (5
-500
nm)
PM1 N/cm3(5-500nm)
BCN
0
10
20
30
40
50
60
70
22/02
23/02
24/02
25/02
26/02
27/02
28/02
01/03
02/03
03/03
04/03
05/03
06/03
07/03
08/03
09/03
10/03
11/03
12/03
13/03
14/03
15/03
16/03
17/03
18/03
19/03
20/03
21/03
22/03
23/03
24/03
25/03
26/03
27/03
28/03
29/03
30/03
31/03
01/04
PM(µ
g/m
3 )
0
2000
4000
6000
8000
10000
12000
BC
(AC
, ng/
m3 )
PM1 BC(AC)
Barcelona
0
2000
4000
6000
8000
10000
12000
07/03
/2009
08/03
/2009
09/03
/2009
10/03
/2009
11/03
/2009
12/03
/2009
13/03
/2009
14/03
/2009
15/03
/2009
16/03
/2009
17/03
/2009
18/03
/2009
19/03
/2009
20/03
/2009
[ng/
m3 ]
0
0.2
0.4
0.6
0.8
1
1.2
1.4
1.6
1.8
2[p
pb]
BC (CSIC)benzene_CREAF_BCN
14
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 240.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
NBCPM1 (x 1000)CO
0
5000
10000
15000
20000
25000
30000
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 240
500
1000
1500
2000
2500
3000
3500
4000
4500
N/cm3(5-500nm) BC(AC)
Barcelona
0
2000
4000
6000
8000
10000
12000
07/03
/2009
08/03
/2009
09/03
/2009
10/03
/2009
11/03
/2009
12/03
/2009
13/03
/2009
14/03
/2009
15/03
/2009
16/03
/2009
17/03
/2009
18/03
/2009
19/03
/2009
20/03
/2009
[ng/
m3 ]
0
0.5
1
1.5
2
2.5[p
pb]
BC (CSIC)benzene_CREAF_BCNmonoterpenes_CREAF_BCNacetonitrile_CREAF_BCN
15
DAUREDiscriminación del origen de Aerosoles Urbanos y REgionales en el NE de la Península Ibérica
Identification of the origin of atmospheric aerosols in NE Iberian Peninsula
CSIC, 26th May 2009
DAURE measurements by CSIC: PART-2: MSY
Querol X., Alastuey A., Pandolfi M., Pey J., Cusack M., Reche C., Moreno T., Viana M., Amato F., Pérez N., Moreno N.
MSY
0
10
20
30
40
50
60
70
19/02 20/02 21/02 22/02 23/02 24/02 25/02 26/02 27/02 28/02 01/03 02/03 03/03 04/03 05/03 06/03 07/03 08/03 09/03 10/03 11/03 12/03 13/03 14/03 15/03 16/03 17/03 18/03 19/03 20/03 21/03 22/03 23/03 24/03 25/03 26/03 27/03
PM (µ
g/m
3)
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
20000
N (#
/cm
3, 1
0-50
0 nm
)
PM-10 PM-2.5
PM-1.0 Concentration (n/cm3)
MSY
05
1015
202530
3540
4550
17/02 18/02 19/02 20/02 21/02 22/02 23/02 24/02 25/02 26/02 27/02 28/02 01/03 02/03 03/03 04/03 05/03 06/03 07/03 08/03 09/03 10/03 11/03 12/03 13/03 14/03 15/03 16/03 17/03 18/03 19/03 20/03 21/03 22/03 23/03 24/03 25/03 26/03 27/03
PM (µ
g/m
3)
0
500
1000
1500
2000
2500
3000
3500
4000
4500
BC
(AC
, ng/
m3 )
PM-1.0 Black Carbon
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
20000
19/02 20/02 21/02 22/02 23/02 24/02 25/02 26/02 27/02 28/02 01/03 02/03 03/03 04/03 05/03 06/03 07/03 08/03 09/03 10/03 11/03 12/03 13/03 14/03 15/03 16/03 17/03 18/03 19/03 20/03 21/03 22/03 23/03 24/03 25/03 26/03 27/03 28/03
N (#
/cm
3, 1
0-50
0 nm
)
0
500
1000
1500
2000
2500
3000
3500
4000
4500
BC
(AC
, ng/
m3 )
CPC MAAP
16
MSY
0
10
20
30
40
50
60
70
80
17/02 18/02 19/02 20/02 21/02 22/02 23/02 24/02 25/02 26/02 27/02 28/02 01/03 02/03 03/03 04/03 05/03 06/03 07/03 08/03 09/03 10/03 11/03 12/03 13/03 14/03 15/03 16/03 17/03 18/03 19/03 20/03 21/03 22/03 23/03 24/03 25/03 26/03 27/03
PM (µ
g/m
3 )PM-10 PM-2.5 PM-1.0
0.0
5.0
10.0
15.0
20.0
25.0
30.0
0 4 8 12 16 20 24
Mas
s m
gm-3
PM2,5 PM10 PM1
0.0
2.0
4.0
6.0
8.0
10.0
12.0
14.0
16.0
0 4 8 12 16 20 24
Mas
s m
gm-3
PM1-2.5 PM2.5-10 PM1
MSY
0
500
1000
1500
2000
2500
3000
3500
4000
4500
17/02 19/02 21/02 23/02 25/02 27/02 01/03 03/03 05/03 07/03 09/03 11/03 13/03 15/03 17/03 19/03 21/03 23/03 25/03 27/03
BC
(ng/
m3 )
0
100
200
300
400
500
600
mix
ing
ratio
(ppt
)
Black Carbon Acetonitrile
Benzene Monoterpenes
(Innsbruck University)
(Innsbruck University)(Innsbruck Univ.)
17
0
1000
2000
3000
4000
5000
6000
7000
8000
0 4 8 12 16 20 24
N (#
/cm
3, 1
0-50
0 nm
)
0
200
400
600
800
1000
1200
1400
Bla
ck C
arbo
n [n
g/m
3 ]
Concentration (N/cm3) Black Carbon
0.0
2.0
4.0
6.0
8.0
10.0
12.0
14.0
0 4 8 12 16 20 24
μg/
m3
0.0
0.5
1.0
1.5
2.0
2.5
μg/
m3
NO2_ugm3_MSYO3_ugm3_MSY ScaledNO_ugm3_MSY
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
20000
19/02
20/02
21/02
22/02
23/02
24/02
25/02
26/02
27/02
28/02
01/03
02/03
03/03
04/03
05/03
06/03
07/03
08/03
09/03
10/03
11/03
12/03
13/03
14/03
15/03
16/03
17/03
18/03
19/03
20/03
21/03
22/03
23/03
24/03
25/03
26/03
27/03
28/03
N (#
/cm
3, 1
0-50
0 nm
)
0
500
1000
1500
2000
2500
3000
3500
4000
4500
BC
(AC
, ng/
m3 )
CPC MAAP SO2 Scaled
MONTSENY
0
3000
6000
9000
12000
19/03/2009 0:00 20/03/2009 0:00 21/03/2009 0:00 22/03/2009 0:00 23/03/2009 0:00 24/03/2009 0:00 25/03/2009 0:00 26/03/2009 0:00 27/03/2009 0:00
#/cm
3
0
5
10
15
20
25
30
35
40
[ μg/
m3 ]
WCPC CSIC SMPS Ciemat
SO2_ugm3_MSY NO2_ugm3_MSY
18
DAUREDiscriminación del origen de Aerosoles Urbanos y REgionales en el NE de la Península Ibérica
Identification of the origin of atmospheric aerosols in NE Iberian Peninsula
CSIC, 26th May 2009
Querol X., Alastuey A., Pandolfi M., Pey J., Cusack M., Reche C., Moreno T., Viana M., Amato F., Pérez N., Moreno N.
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