ece 6340 intermediate em waves - university of houstoncourses.egr.uh.edu/ece/ece6340/class...
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Debye Model
Molecule:
This model explains molecular effects.
Molecule at rest
Molecule with applied field Ex
0x =p
0>xp
We consider an electric field applied in the x direction. The dipole moment px of this single molecule represents the average dipole moment in the x direction for all of the dipoles in a little volume. A zero dipole moment px corresponds to a random dipole alignment in the actual material.
q
-q
x
y
xE
θ
2
3
Debye Model (cont.)
xE
θ
x
y Torque on dipole due to electric field:
( ) ( )( )
ET r q r q
r r q
p
+ −
+ −
= × + × −
= − ×
= ×
E E
E
E
Debye Model (cont.) 2
2
E S F
dT Idt
T T T T
θ=
= + +
cosE x
S
F
T qd
T sdT cdt
θ
θθ
=
= −
= −
E
s = spring constant
c = friction constant
Note: T = -Tz
ˆ sin2
cosE x
x
T z
qd
π θ
θ
= × = − −
=
p E pE
E
4
xE
θ
x
y
Hence
Assume
2
2cosxd dq d s c Idt dtθ θθ θ− − =E
1, cos 1θ θ<< ≈
2
2xd dq d s c Idt dtθ θθ≈ + +E
Debye Model (cont.)
5
(small fields)
( )sinx q d
q d
θ
θ
=
≈
pNote that
2
2xd dq d s c Idt dtθ θθ≈ + +E
Hence: θ ≈ x
q dp
Insert this into the top equation.
Debye Model (cont.)
6
xE
θ
Then we have:
Assume sinusoidal steady state:
or
2
2
1 1x x xx
d dq d s c I
q d q d dt q d dt
≈ + +
p p pE
( )2
22
x xx x
d ds c I q d
dt dt+ + =
p pp E
( )22x x x xsp j cp I p q d Eω ω+ − =
Debye Model (cont.)
7
Hence, we have
Then we have
( )( )
2
2x x
q dp E
s I j cω ω
=
− +
3
#moleculesmN
m=
Mx m xP N p=
The term P denotes the total
dipole moment per unit volume.
The M superscript reminds us that we are talking
about molecules.
Debye Model (cont.)
Denote
8
Also, for a linear material,
Hence
0M M
x e xP Eε χ=
0 0
MM x m xe
x x
P N pE E
χε ε
= =
Therefore ( ) ( )2
20
1M me
N q ds I j c
χε ω ω
=
− +
Assume 2I sω <<(The frequency is fairly low relative to molecular
resonance frequencies. That is, the frequency is at millimeter wave frequency and below.)
Debye Model (cont.)
9
Denote the time constant as:
( )2
0
1 1
1
M me
N q dcs js
χε ω
≈ +
cs
τ =
( ) ( )2
0
10M me
N q ds
χε
=
( )01
MM ee j
χχ
ωτ≈
+
Denote the zero-frequency value as:
Debye Model (cont.)
(real constant)
Then we have
10
( )01
MM ee j
χχ
ωτ≈
+
Debye Model (cont.)
This would imply that
( )01
1
Me
r jχ
εωτ
= ++
At high frequency the molecules cannot respond to the field, so the relative permittivity due to the molecules tends to unity. This equation gives the wrong result at high frequency, where atomic effects become important.
11
( )01
MeM
e jχ
χωτ
=+
Include BOTH molecule and atomic effects:
Debye Model (cont.)
Molecule effects:
Atomic effects:
0 0
0
M Ax x x
M Ae x e x
e x
P P PE E
Eε χ ε χε χ
= +
= +
=
Aeχ = constant (real)
Note: Atoms can respond much faster to the
field than molecules, so the atomic susceptibility is almost constant
(unless the frequency is very high, e.g., at THz frequencies and above).
12
Permittivity formula: 1r eε χ= +
( )
21
01
1
1
MeA
r e jaaj
χε χ
ωτ
ωτ
= + ++
= ++
( )1
2
1
0
Ae
Me
aa
χ
χ
= +
=
where
Debye Model (cont.)
(a1 and a2 are real constants.)
14
Hence, we have
( )( )
1 2
1
0r
r
a a
a
ε
ε
= +
∞ =
so ( )( ) ( )
1
2 0r
r r
a
a
ε
ε ε
= ∞
= − ∞
( ) ( ) ( )01
r rr r j
ε εε ε
ωτ− ∞
= ∞ ++
Note that:
Hence:
Debye Model (cont.)
21 1r
aaj
εωτ
= ++
15
( ) ( ) ( )( )
( ) ( )( )
2
2
01
01
r rr r
r rr
ε εε ε
ωτ
ε εε ωτ
ωτ
− ∞′ = ∞ +
+
− ∞′′=
+
( )rε ∞
( )0rε
rε
1/τ
rε ′
rε ′′
ω
Debye Model (cont.)
16
Frequency for maximum loss:
Let x ωτ=
( ) ( )( )2 01r r r
xx
ε ε ε ′′= − ∞ +
A maximum occurs at 1x =
1ωτ
=or
Debye Model (cont.)
17
Water obeys the Debye model quite well.
18
Water obeys the Debye model quite well.
Debye Model (cont.)
Complex relative permittivity for pure (distilled) water
Water obeys the Debye model quite well.
19
Ocean water: σ = 4 [S/m]
Example
Calculate the complex relative permittivity εrc for ocean water at 10.0 GHz.
0 0 0
1crc rj jε σ σε ε ε
ε ε ω ωε = = − = −
( ) ( )( )9 12
460 352 10.0 10 8.854 10rc j jεπ −
= − −× ×
from previous plot for distilled water
60 42.19rc jε = −( ) ( )60 35 7.19rc j jε = − −Hence
or
Cole-Cole Model
This is a modification of the Debye model.
( ) ( ) ( )( )1
01
r rr r j α
ε εε ε
ωτ −
− ∞= ∞ +
+
When α = 0, the model reduces to the Debye model.
This model has often been used to describe the permittivity of some polymers, as well as biological tissues.
20
Havriliak–Negami Model
This is another modification of the Debye model.
( ) ( ) ( )( )( )0
1
r rr r
jβα
ε εε ε
ωτ
− ∞= ∞ +
+
When α = 1 and β = 1, the model reduces to the Debye model.
This has been used to describe the permittivity of some polymers.
22
Lorentz Model Explains atom and electron resonance effects (usually observed
at high frequencies, such as THz frequencies and optical frequencies, respectively).
Dipole effect:
Atom:
xE
qn= - qe
qn qe
0=xE
Electrons
23
Lorentz Model (cont.)
Model:
Equation of motion for electrons in atom:
x
qn qe
m
xE
2
2x
E S Fx x x x
e x
d xmdt
dxq sx cdt
=
= + +
= − −
F
F F F F
E
The heavy positive nucleus is fixed.
24
so
Hence
2
2e xdx d xq sx c mdt dt
− − =E
( )x n eq x q x= − =p
22
2= + +x xe x x
d dq s c m
dt dtp p
E p
Sinusoidal Steady State:
2 2e x x x xq E s p j c p m pω ω= + −
For a single atom, = /x ex qpor
Lorentz Model (cont.)
25
Therefore,
( )2
2e
x xqp E
s m j cω ω
=
− +
0
Ax a x
Ae x
P N pEε χ
=
=
0
A a xe
x
N pE
χε
=
The term P denotes the total dipole
moment per unit volume.
The A superscript reminds us that we are
talking about atoms.
Lorentz Model (cont.)
26
3
#atomsaN
m=Denote
Denote:
( )2
20
2
20
1
A a ee
a e
N qs m j c
N qs cm jm m
χε ω ω
ε ω ω
=
− + = − +
220
0
a ef
N q s cA cm m m
ωε
= = =
Hence
(real constants)
Lorentz Model (cont.)
27
We then have
( )2 20
Ae
f
Aj c
χω ω ω
=− +
( )( ) ( ) ( ) ( )
2 20
2 22 22 2 2 20 0
1 fA Ar r
f f
A c A
c c
ω ω ωε ε
ω ω ω ω ω ω
−′ ′′= + =
− + − +
( )2 20
1Ar
f
Aj c
εω ω ω
= +− +
Permittivity formula: 1A Ar eε χ= +
Lorentz Model (cont.)
28
Hence
Real and imaginary parts:
A sharp resonance occurs at 0ω ω=
Lorentz Model (cont.)
Low frequency value for Aeχ
Arε
0ω ω
1
Arε ′
Arε ′′
201 /A ω+
(This is still "high" frequency in the Debye model.)
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Total Response
From the dielectric spectroscopy page of the research group of Dr. Kenneth A. Mauritz.
Frequency (Hz)
Response of a hypothetical material
103 106 109 1012 1015
MW THz UV Vis
ε ′
ε ′′
30
( )0c j σε εω
≈ −
Low frequency:
Atmospheric Attenuation (cont.) Atmospheric
absorption (% power absorbed) for
millimeter-wave frequencies
over a 1-km path
( )% 2 (1000)100 1absP e α−= −
( )
10
2 (1000)10
%
10
dB / km 10log
10log
10log 1100
out
in
abs
PP
e
P
α−
=
=
= −
Terabeam Document Number: 045-1038-0000 Revision: A / Release Date: 09-03-2002 Copyright © 2002 Terabeam Corporation. All Rights Reserved.
Attenuation in dB/km:
32
90 GHz
% power absorbed:
Plasma
Electrically neutral plasma medium (positive ions and electrons):
Ion (+)
Electron (-)
We assume that only the electrons are free to move when an electric field is applied. This causes a current to flow.
33
Plasma (cont.)
Equation of motion for average electron:
( ) ( )dvm e mvdt
υ= = − −F E
υ = collision frequency (rate of collisions per second of average electron)
Notes: (1) The last term assumes perfect inelastic collisions (loss mechanism). (2) We neglect the force due to the magnetic field.
Force due to electric field Force due to collisions with ions (loss of momentum)
There is no “spring” force now.
34
Plasma (cont.)
Sinusoidal steady state:
( ) ( )m j v e E mvω υ= − −
( )( )
ev E
m jω υ−
=+
Current: ( )
( )ve
ve
eJ v E
m jρ
ρω υ
−= = +
35
Plasma (cont.)
Amperes’ law:
( )( )
( )( )
0
0
0
ve
ve
c
H J j E
eE j E
m j
ej E
m j
j E
ωε
ρωε
ω υ
ρωε
ω υ
ωε
∇× = +
−= + +
−= + + =
( )( )
veve
eJ v E
m jρ
ρω υ
−= = +
We assume that there is no polarization current – only conduction
current. Hence we use ε0.
36
Plasma (cont.)
Hence: ( )
( )0ve
c
ej j
m jρ
ωε ωεω υ
−= + +
so ( )( )0
1 vec
ej m j
ρε ε
ω ω υ −
= + +
or ( )
( )01ve
c
em j
ρε ε
ω ω υ−
= −−
37
Plasma (cont.)
Define:
( )20
vep
em
ρε ω
−≡
( )
2
0 1 pc j
ωε ε
ω ω υ
= − −
(ωp ≡ plasma frequency)
We then have
( )( )0
1vec
em j
ρε ε
ω ω υ−
= −−
38
Plasma (cont.)
Lossless plasma:
2
0 1 pc
ωε ε
ω
= −
0υ =
(Drude equation)
0
0
: 0, ( )
: 0, ( )p c c c
p c c c
k
k j
ω ω ε ε ω µ ε β
ω ω ε ε ω µ ε α
> = > = =
< = − < = = −
propagation
attenuation
Plane wave in lossless plasma:
39
Plasma (cont.)
Measured complex relative permittivity of silver at optical frequencies
Rel
ativ
e pe
rmitt
ivity
The Drude model is an approximate model for how metals behave at optical frequencies.
40
“Plasmonic behavior”
149.23 10 [Hz]pf = ×
Visible
Plasma (cont.)
At microwave frequencies, a plasma-like medium can be simulated by using a wire medium.
d
d
2a
y
x
1
2 ln 0.52752p d
a
cd π π
ω
+=
0 0
1cµ ε
=
41