fluorescence line height (flh)

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Fluorescence Line Height (FLH) Ricardo Letelier, Mark Abbott, Jasmine Nahorniak Oregon State University

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Fluorescence Line Height (FLH). Ricardo Letelier, Mark Abbott, Jasmine Nahorniak Oregon State University. Outline. FLH basic alghorithm Comparison between field measurements and MODIS FLH FLH and [chl a] Chlorophyll Fluorescence Efficiency. Acknowledgments. - PowerPoint PPT Presentation

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Page 1: Fluorescence Line Height (FLH)

Fluorescence Line Height (FLH)

Ricardo Letelier,Mark Abbott,

Jasmine NahorniakOregon State University

Page 2: Fluorescence Line Height (FLH)

Outline

• FLH basic alghorithm• Comparison between field

measurements and MODIS FLH• FLH and [chl a]• Chlorophyll Fluorescence Efficiency

Page 3: Fluorescence Line Height (FLH)

Acknowledgments

• Mark Abbott, Jasmine Nahorniak (OSU)• Dennis Clark (NOAA)• Wayne Esaias, Frank Hoge (NASA)• Bob Evans, Kay Kilpatrick, Howard

Gordon, Ed Kearns (Univ. Miami)• Ken Carder (USF)• John Cullen & Yannick Huot (Dalhousie)

Page 4: Fluorescence Line Height (FLH)

0

0.002

0.004

0.006

0.008

0.01

0.012

0.014

0.016

400 450 500 550 600 650 700

Wavelength, nm

Lu/E

s

0

0.002

0.004

0.006

0.008

0.01

0.012

0.014

0.016

400 450 500 550 600 650 700

Wavelength, nm

Lu/E

s

Chlorophyll absorption

Increase in fluorescence

F = PAR x ([chl] x a*) x f

Page 5: Fluorescence Line Height (FLH)

MODIS FLH bands: avoid oxygen absorbance at 687 nm

Weighting factor used to compensate for off-center FLH

letelier
MODIS Fluorescence wavebands (!#, 14, and 15) superimposed to the upwelling light spectrum of the ocean for surface waters containing 0.01 and 10 mg chl/m3Note that band 14 is not centered around 683 nm. This is due to the fact that at 683 nm it would be affected by the absorption of oxygen at 685 nm in the atmosphere.
Page 6: Fluorescence Line Height (FLH)

0

2

4

6

8

10

12

650 670 690 710 730 750 770

0.00E+00

2.00E-02

4.00E-02

6.00E-02

8.00E-02

1.00E-01

1.20E-01

Rad

ianc

e, W

m-2

µm

-1 sr

-1

Nor

mal

ized

ban

d tr

ansm

itta

nce10 mg

0.01 mg

Wavelength, nm

650 670 690 710 730 750 7700.00

0.02

0.04

0.06

0.08

0.10

0.12

0

2

4

6

8

10

12

13 14 15

FLH (10 mg)

Negative FLH due to TOA curvature needs to be corrected empirically

Page 7: Fluorescence Line Height (FLH)

Field Observations

-In situ open ocean - MOBY - HOT cruises

-In situ Coastal - GLOBEC - COAST

- Southern Ocean

Page 8: Fluorescence Line Height (FLH)

Optical Drifters

- 29 off Oregon- 12 in the Southern Ocean- Noth Atlantic (John Cullen’s group)

Page 9: Fluorescence Line Height (FLH)

http://picasso.coas.oregonstate.edu/ORSOO/

Page 10: Fluorescence Line Height (FLH)

0

0.02

0.04

0.06

0.08

0.1

0.12

0.14

0.16

0.18

0 0.05 0.1 0.15 0.2 0.25

Oregon Drifters FLH, W m-2 m-1 sr-1

MO

DIS

Terr

a F

LH,

W m

-2

m-1 s

r-1

Page 11: Fluorescence Line Height (FLH)

From Hoge et al.

Testing the MODIS FLH Algorithm

FLH vs. chlorophyll

FLH vs. CDOM

Page 12: Fluorescence Line Height (FLH)

In situ chlorophyll, mg m-3

FLH

, W

m-2 µ

m-1 s

r-1

GLOBEC NEP AUGUST 2002

[chl] = .021 + 43.4 FLH1.866

All cruise dataOnly pixels of passes within 5 hrs of sampling time

Page 13: Fluorescence Line Height (FLH)

chlFLH empirical(this study)

chlFLH semi-analytical(Huot & Cullen

assuming f = 0.006)

In situ chl

GLOBEC NEP AUGUST 2002

-Both FLH derived chl algorithms appear to slightly overestimate chl a fields.-They do not seem to reproduce the low values observed in situ.-Some of the differences between in situ and FLH derived could be due to time differences and sampling depth (in situ = 5 m depth)

Page 14: Fluorescence Line Height (FLH)

GLOBEC NEP AUGUST 2002 (July 31st – August 19th)

In situ chl a, mg m-3 MODIS chl a_2, mg m-3

Page 15: Fluorescence Line Height (FLH)

In Situ Observations of F/[chl] suggest it can be a proxy for f

Initial slope proportional to F

letelier
Field observations of the quantum yield of fluorescence suggest that it is high in waters with low nutrient levels and low in coastal areas.
Page 16: Fluorescence Line Height (FLH)

Sea Surface Temperature Chl a Chl Fluorescence Line Height (°C) (mg m-3) (W m-2 m-1 sr-1)

MODIS Terra L2 1 km resolution scene from October 3rd 2001

From OSU-COAS EOS DB Station

Page 17: Fluorescence Line Height (FLH)
Page 18: Fluorescence Line Height (FLH)
Page 19: Fluorescence Line Height (FLH)
Page 20: Fluorescence Line Height (FLH)
Page 21: Fluorescence Line Height (FLH)

Southern Ocean Temp. Test

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

3/15/00 10/1/00 4/19/01 11/5/01 5/24/02 12/10/02 6/28/03

Date

Ch

l a, m

g m

-3

0

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0.08

0.09

FL

H, W

m-2

m

-1 s

r-1

Chl a 3

FLH

Seasonal patterns of FLH and chl a

Southern Ocean

Indian Ocean

0.02

0.03

0.04

0.05

0.06

0.07

0.08

3/15/00 10/1/00 4/19/01 11/5/01 5/24/02 12/10/02 6/28/03

Date

Ch

l a, m

g m

-3

0.05

0.07

0.09

0.11

0.13

0.15

0.17

0.19

0.21

0.23

0.25

FL

H, W

m-2

m

-1 s

r-1

Page 22: Fluorescence Line Height (FLH)

MODIS ARP Huot & Cullen ARPusing in situ chl to

Derive an average f

chlFLH empirical(this study)

Page 23: Fluorescence Line Height (FLH)

0 0.005 0.01 0.015 0.02 0.025 0.030

500

1000

1500

2000

2500

3000

# oc

cure

nces

CFE, non dimensional

Range covering mostoceanic regions(Gordon, 1979)

Mean oceanic value according to Fischer and Kronfeld (1990)

Page 24: Fluorescence Line Height (FLH)

GLOBEC NEP AUGUST 2002

MODIS CFE using MODIS ARP

MODIS CFE using Huot & Cullen ARP

chlFLH empirical(this study)

Page 25: Fluorescence Line Height (FLH)

0

0.005

0.01

0.015

0.02

0.025

0.03

0.035

0.04

0.045

0.05

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0

0.1

0.2

0.3

0.4

0.5

0.6

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Fv/

Fm

, n.d

.9

AM

CF

E, r

.u.

/max , n.d.

Thalassiosira weissflogii Chemostat results 2001-2002

After 3 days of constant cell counts

After 14 days

Page 26: Fluorescence Line Height (FLH)

Where do we stand?

• Field observations suggest that MODIS FLH is a robust product.

• Comparison of [chl]field vs FLHMODIS

suggest that FLH may prove of use to derive [chl] in turbid waters. However, and as expected, there is no single relation between FLH and [chl a]. (See also K Carder poster).

• CFE validation requires that of FLH and ARP.

• In order to interpret CFE we need field and laboratory based work that explores the effect of environmental variability and phytoplankton specific composition.

Page 27: Fluorescence Line Height (FLH)

FLH working group

• Charlie Yentsch ([email protected]), • Dave Siegel ([email protected]), • Greg Leptoukh ([email protected]), • Richard Sikorski ([email protected]), • Chuck McClain ([email protected]), • Heidi Dierssen ([email protected]), • Chuanmin Hu ([email protected]), • Paula Bontempi ([email protected]), • Alex Cunningham ([email protected]), • Mike Behrenfeld ([email protected]),• Ricardo Letelier ([email protected])