kinetics and the virtual molecular dynamics lab kinetics made easy susan grillo jay chandler dan...
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Kinetics and the Virtual Molecular Dynamics Lab
Kinetics Made Easy
Susan Grillo
Jay Chandler
Dan Burton
Introduction
This is a traditional kinetic unit which incorporates Simulabs as a supplement.
Incorporation of SimuLab will aid the visual interpretation of the kinetics of a reaction.
Intended Audience
Advanced Placement or Chem II Students.The topics of kinetics and rate laws are incorporated in the SAT II to a very slight degree, and to a larger degree on the AP Chem Exam.The Simulabs are intended to enhance the students understanding of kinetics.
Placement in the Curriculum
The unit will enhance the curriculum already in place.The major revision is the use of the appropriate SimuLabs to enhance the understanding of 1st and 2nd order reactions and activation energy.Students need an understanding of reactions rates prior to starting this unit.
Adjustments / Adaptation
Honors 1 ChemistryNo Zero Order or fractional reaction rates.Substitute the Methyl Violet Lab with the Vitamin C Clock Lab.
Chemistry
No Graphing.
Only use Vitamin C Clock Lab.
Only show the relationship between initial conc., temp., and rate.
Goals and Objectives
Students will define the key terms involved in chemical kinetics and factors affecting rate.Students will use lab data and construct graphs to determine reaction order and the rate law. Students will apply the Arrhenius Equation to calculate activation energy and constants.Students will be able to develop a procedure to determine the rate law of a reaction.Given experimental data, students will be able to derive a rate law and select an appropriate mechanism for a reaction.
Time
Pre-Lab, Lab and Post-LabInstructional
•Five days are required for instruction related to zero, first, and second order reactions and to discuss the differential and integrated rate laws, half-life and slope equation.
• Two days are needed for a wet lab .• Two days are required for Simulabs 2.1; 2.2; 2.3.• One day is required for Poster/PowerPoint presentation.
Resources
Crystal violet lab:
Crystal violet (2.0 x 10 –5 M)
NaOH (0.10M)
Set-up time is approximately 1 hour.
Demonstrations
Surface area demonstration.Elephant’s toothpaste catalysis demonstration:
30% H2O2 ( 125 mL)KIDishwashing liquidFood coloring
Electronic Equipment
CBL/ Spec 20
Notes: If CBL’s used then only one is needed for graphing.
Simulab requires one computer
for every two to three students.
CBL Probes for colorimetry.
Instructional Activities Chronology
Day One:Introduction to reaction ratesDemonstrations
Days Two - Four: Average rate versus instantaneous rate:
Method of initial rateTypes of rate lawsUse of integrated ratesUse of zero order, 1st and 2nd order ratesGraphing of integrated rate lawsHalf-life
Instructional ActivitiesChronology Continued
Day five:Mechanisms/ rate-determining step/ intermediatesCollision modelCatalysis
Days six – nine:Laboratories:Crystal violetSimuLab # 2.1, 2.2; 2.3 (From the Yellow book)
Day ten- eleven:Poster/PowerPoint preparation & presentation
ln [red] vs time
y = -0.0036x + 6.0429
R2 = 0.9987
0
1
2
3
4
5
6
0 200 400 600 800 1000 1200
time
Ln
[re
d]
Students will complete the lab and graph:• [red] vs time• 1/[red] vs time • Ln [Red] versus time to determine k, half-life, and order of reaction
2.1 Simulab
Simulab 2.2:
Students will complete Simulab 2.2 and will graph:Students will complete the lab and graph:
• [red] vs time• 1/[red] vs time • Ln [red] versus time
to determine k, half-life, and order of reaction.
Students will:
run Simulab 2.3 three
times at different temperatures.
calculate k for each temperature.
use the Arrhenius equation to calculate the activation energy.
Simulab 2.3:
Assessment
Students must produce a traditional
lab report in response to the wet lab.
Students will submit problem sets to
be graded.
A traditional end of unit, criterion-
based test will be administered.
Assessment Continued
Students will produce a PowerPoint/Posterboard summary of their Simulab
work and answer the following questions:1. How is the rate constant determined graphically?2. How is the rate order determined graphically?3. How does the initial concentration affect the half-life?4. How does the change in temperature affect the rate
constant?5. Using collision theory, explain the difference
between first and second order reactions.
Rate Law Summary
By integrating Simulabs with wet labs:
Students will be exposed to visual
representations of the rate laws of
various order.
Students will make connections
between the dynamic molecular models
and the graphs and equations which define
the various rate laws.
Rate Law Summary Continued
Students will explore the relationships
between temperature, reaction rates,
and constants as well as initial
concentration and half-life.
Students will be able to calculate the
activation energy from their data.