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Laboratory of Metal Complex Activation of Small Molecules.
Head of the laboratory: Prof. Shur Vladimir Borisovich
Selected Publications
Molecular Nitrogen Fixation in Solutions
1) M.E. Vol'pin, V.B. Shur. Nitrogen Fixation on Complex Catalysts. Dokl. Akad. Nauk SSSR, 156
(1964) 1102-1104.
2) M.E. Vol'pin, V.B. Shur, M.A. Ilatovskaya. Fixation of Nitrogen by Systems Based on Dicyclo-
pentadienyltitanium Dichloride. Izv. Akad. Nauk SSSR, Ser.Khim., (1964) 1728-1729 [Bull.
Acad. Sci. USSR., Div. Chem. Sci., 13 (1964) 1644 (Engl. Transl.)].
3) M.E. Vol'pin, V.B. Shur, L.P. Bichin. Study of the Fixation of Nitrogen on Complex Catalysts
Using 15N. Izv. Akad. Nauk SSSR, Ser.Khim., (1965) 720-721 [Bull. Acad. Sci. USSR, Div. Chem.
Sci., 14 (1965) 698-699 (Engl. Transl.)].
4) M.E. Vol'pin, V.B. Shur. Problems of Chemical Fixation of Molecular Nitrogen. Vestnik Akad.
Nauk SSSR, № 1 (1965) 51-58.
5) M.E. Vol'pin, A.A. Belyi, V.B. Shur. Fixation of Nitrogen by Systems Based on Compounds of
the Transition Metals and Inorganic Reducing Agents. Izv. Akad. Nauk SSSR, Ser.Khim., (1965)
2225-2226 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 14 (1965) 2196 (Engl. Transl.)].
6) M.E. Vol'pin, V.B. Shur. Nitrogen Fixation by Transition Metal Complexes. Nature, 209 (1966)
1236.
7) M.E. Vol'pin, V.B. Shur. Preparation of Amines in the Reactions of Molecular Nitrogen. Izv.
Akad. Nauk SSSR, Ser.Khim., (1966) 1873-1874 [Bull. Acad. Sci. USSR., Div. Chem. Sci., 15
(1966) 1819 (Engl. Transl.)].
8) M.E. Vol'pin, V.B. Shur, V.N. Latyaeva, L.I. Vyshinskaya, L.A. Shul’gaitser. Reaction of
Nitrogen with Bis-Cyclopentadienyl Derivatives of Titanium. Izv. Akad. Nauk SSSR, Ser.Khim.,
(1966) 385 [Bull. Acad. Sci. USSR., Div. Chem. Sci., 15 (1966) 364 (Engl. Transl.)].
9) M.E. Vol'pin, V.B. Shur. Complexation As a Way of the Activation of Molecular Nitrogen.
Zh. Vses. Khim. Obshchestva im. D.I. Mendeleeva, 12 (1967) 31-41.
10) M.E. Vol'pin, V.B. Shur, R.V. Kudryavtsev, L.A. Prodayko. Amine Formation in Molecular
Nitrogen Fixation: Nitrogen Insertion into Transition Metal–Carbon Bonds. Chem. Commun.,
№ 17 (1968) 1038-1040.
11) M.E. Vol'pin, M.A. Ilatovskaya, L.V. Kosyakova, V.B. Shur. Catalytic Nitrogen Fixation in the
Presence of Transition Metal Compounds. Dokl. Akad. Nauk SSSR, 180 (1968) 103-105.
12) M.E. Vol'pin, M.A. Ilatovskaya, L.V. Kosyakova, V.B. Shur. Catalytic Fixation of Nitrogen.
Chem. Commun., № 18 (1968) 1074-1075.
13) M.E. Vol'pin, V.B. Shur. Chemical Fixation of Molecular Nitrogen. Priroda, № 11 (1969) 29-
34.
14) M.E. Vol'pin, A.A. Belyi, N.A. Katkov, R.V. Kudryavtsev, V.B. Shur. Formation of Amines
from Aromatic Hydrocarbons and Molecular Nitrogen During the Reducing Fixation of N2.
Izv. Akad. Nauk SSSR, Ser.Khim., (1969) 2858-2859 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 18
(1969) 2697 (Engl. Transl.)].
15) M.E. Vol'pin, M.A. Ilatovskaya, V.B. Shur. Catalytic Nitrogen Fixation. Kinetika i Kataliz, 11
(1970) 333-341.
16) M.E. Vol'pin, V.B. Shur. Chemical Fixation of Molecular Nitrogen. In: "Organometallic
Reactions" (Eds. E. Becker and M. Tsutsui), Vol. 1, J. Wiley, N.Y., 1970, p. 55-117.
17) M.E. Vol'pin, A.A. Belyi, V.B. Shur, Yu.I. Lyakhovetskyi, R.V. Kudryavtsev, N.N. Bubnov.
Study of Nitrogen Fixing Systems. Investigation of the Mechanism of the Reduction of
Titanocene Dichloride by Metallic Magnesium. Dokl. Akad. Nauk SSSR, 194 (1970) 577-579.
18) M.E. Vol'pin, A.A. Belyi, V.B. Shur, N.A. Katkov, I.M. Nekaeva, R.V. Kudryavtsev. Formation
of Amines from Aromatic Hydrocarbons in Molecular Nitrogen Fixation Reactions. Chem.
Commun., № 6 (1971) 246.
19) V.B. Shur, E.G. Berkovich, M.E. Vol'pin. Formation of Aniline During the Thermal
Decomposition of Diphenyltitanocene in the Presence of Nitrogen. Izv. Akad. Nauk SSSR,
Ser.Khim., (1971) 2358 [Bull. Acad. Sci. USSR., Div. Chem. Sci., 20 (1971) 2248 (Engl.
Transl.)].
20) V.B. Shur, E.G. Berkovitch, L.B. Vasiljeva, R.V. Kudryavtsev, M.E. Vol'pin. Amine Formation
in the Thermodecomposition of Diaryltitanocenes in the Presence of Dinitrogen. J. Organomet.
Chem., 78 (1974) 127-132.
21) V.B. Shur, E.G. Berkovich, S.M. Yunusov, Sh.M. Mamedov, I.L. Nizker, M.E. Vol'pin. New
Systems Capable of Binding Molecular Nitrogen with the Formation of Amines. Izv. Akad. Nauk
SSSR, Ser.Khim., (1977) 2841 [Bull. Acad. Sci. USSR., Div. Chem. Sci., 26 (1977) 2630 (Engl.
Transl.)].
22) E.G. Berkovich, V.B. Shur, M.E. Vol'pin, B. Lorenz, S. Rummel, M. Wahren. Die Reaktion von
Stickstoff mit Dehydrobenzol in der Koordinationssphäre von Titan. Chem. Ber., 113 (1980) 70-
78.
23) M.E. Vol'pin, V.B. Shur. Fixation of Molecular Nitrogen in Aprotic Media. In: "New Trends in
the Chemistry of Nitrogen Fixation" (Eds. J.Chatt, L.M. da Câmara Pina and R.L. Richards),
Acad. Press, London, 1980, p. 67-100.
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24) M.E. Vol'pin, V.B. Shur. Nitrogen Fixation by Transition Metal Compounds: Results and
Prospects. J. Organomet. Chem., 200 (1980) 319-334.
25) M.N. Bochkarev, A.A. Trifonov, G.A. Razuvaev, M.A. Ilatovskaya, V.B. Shur. Fixation of
Molecular Nitrogen by Rare-Earth Metal Compounds. Izv. Akad. Nauk SSSR, Ser.Khim., (1986)
1898-1900 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 35 (1986) 1726-1728 (Engl. Transl.)].
26) M.N. Bochkarev, A.A. Trifonov, G.A. Razuvaev, M.A. Ilatovskaya, V.B. Shur, M.E. Vol’pin.
Activation of Molecular Nitrogen by Compounds of the Lanthanides. Dokl. Akad. Nauk SSSR,
295 (1987) 1381-1384 [Dokl. Chem., 295 (1987) 378-380 (Engl. Transl.)].
27) M.E. Vol’pin, V.B. Shur, E.G. Berkovich. Transformations of Molecular Nitrogen into Aromatic
Amines under the Action of Titanium Compounds. Inorg. Chim. Acta, 280 (1998) 264-274.
Development of Catalysts for the Low-Temperature Ammonia Synthesis
from Dinitrogen and Dihydrogen
1) M.E. Vol'pin, M.A. Ilatovskaya, E.I. Larikov, M.L. Khidekel’, Yu.A. Shvetsov, V.B. Shur.
Nitrogen Fixation by Transition Metal Complexes Activating Molecular Hydrogen. Dokl. Akad.
Nauk SSSR, 164 (1965) 331-333.
2) M.E. Vol'pin, M.A. Ilatovskaya, V.B. Shur. Catalytic Nitrogen Fixation. Kinetika i Kataliz, 11
(1970) 333-341.
3) M.E. Vol'pin, V.B. Shur. Chemical Fixation of Molecular Nitrogen. In: "Organometallic
Reactions" (Eds. E. Becker and M. Tsutsui), Vol. 1, J. Wiley, N.Y., 1970, p. 55-117.
4) V.A. Postnikov, L.M. Dmitrienko, R.F. Ivanova, N.L. Dobrolyubova, M.A. Golubeva,
T.I. Gapeeva, Yu.N. Novikov, V.B. Shur, M.E. Vol’pin. Investigation of the Catalytic Activity
of Lamellar Graphite-Transition Metal Compounds in the Synthesis of Ammonia. Izv. Akad.
Nauk SSSR, Ser.Khim., (1975) 2642-2646 [Bull. Acad. Sci. USSR., Div. Chem. Sci., 24 (1975)
2529-2532 (Engl. Transl.)].
5) A.V. Nefed’ev, R.A. Stukan, V.A. Postnikov, V.B. Shur, Yu.N. Novikov, M.E. Vol’pin. Study
of Catalysts for the Synthesis of Ammonia Based on Lamellar Compounds of Graphite with
Ferric Chloride and Potassium by Gamma-Resonance Spectroscopy Method. Izv. Akad. Nauk
SSSR, Ser. Khim., (1976) 2376-2378 [Bull. Acad. Sci. USSR., Div. Chem. Sci., 25 (1976) 2219-
2221 (Engl. Transl.)].
6) M.E. Vol'pin, Yu.N. Novikov, V.A. Postnikov, V.B. Shur, B. Bayerl, L. Kaden, M. Wahren,
L.M. Dmitrienko, R.A. Stukan, A.V. Nefed'ev. Untersuchungen zur Katalyse der Ammoniak-
synthese und des Stickstoffisotopenaustausches dürch Schichtverbindungen von Graphit mit
Eisen, Ruthenium und Osmium. Z. anorg. allg. Chem., 428 (1977) 231-236.
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7) V.B. Shur, S.M. Yunusov, M.E. Vol'pin. Ammonia Synthesis from Nitrogen and Hydrogen
Using Catalysts Based on Potassium Salts of Iron Carbonyl Hydrides and Metallic Potassium.
Dokl. Akad. Nauk SSSR, 277 (1984) 884-888 [Dokl. Chem., 277 (1984) 246-250 (Engl. Transl.)].
8) V.B. Shur, S.M. Yunusov, S. Rummel, M. Wahren, M.E. Vol'pin. Stepwise Synthesis of
Ammonia from Nitrogen and Hydrogen by the Action of Catalysts Based on Potassium Salts of
Transition Metal Carbonyl Hydrides and Potassium Metal. Dokl. Akad. Nauk SSSR, 292 (1987)
1409-1413 [Dokl. Chem., 292 (1987) 100-103 (Engl. Transl.)].
9) I.L. Arkhipov, R.A. Stukan, S.M. Yunusov, B.V. Lokshin, M.G. Ezernitskaya, V.B. Shur,
M.E. Vol'pin. Mössbauer and Infrared Spectroscopic Study of the Reactions of K2[Fe2(CO)8]
under the Influence of Activated Charcoal. Metalloorg. Khim., 1 (1988) 314-320 [Organomet.
Chem. USSR, 1 (1988) 174-177 (Engl. Transl.)].
10) K.S. Rama Rao, P. Kanta Rao, S.K. Masthan, E. Kaluschnaya, V.B. Shur. New Type of Carbon
Coated Alumina Supports for the Preparation of Highly Active Ruthenium Catalysts for
Ammonia Synthesis. Appl. Cat., 62 (1990) L19-L22.
11) V.B. Shur, S.M. Yunusov, E.S. Kalyuzhnaya, M.E. Vol'pin. Ammonia Synthesis Catalysts
Derived from Potassium Salts of Ruthenium and Osmium Carbonyl Hydrides Supported on
Activated Charcoal and Metallic Potassium. Dokl. Akad. Nauk SSSR, 320 (1991) 353-356 [Dokl.
Chem., 320 (1991) 254-257 (Engl. Transl.)].
12) V.B. Shur, S.M. Yunusov, M.A. Ilatovskaya, S. Rummel, M.E. Vol'pin. Interaction of
Ammonia-Synthesis Catalyst, K2[Fe2(CO)8] + K on SKT Carbon, with Dinitrogen in the Absence
and Presence of Dihydrogen. Dokl. Akad. Nauk SSSR, 336 (1994) 631-635 [Dokl. Chem., 336
(1994) 116-119 (Engl. Transl.)].
13) V.B. Shur, S.M. Yunusov, M.A. Ilatovskaya, S. Rummel, M.E. Vol'pin. Nitrogen Isotope
Exchange under Effect of Ammonia Synthesis Catalyst, K2[Fe2(CO)8] + K on SKT Carbon.
Dokl. Akad. Nauk SSSR, 336 (1994) 789-794 [Dokl. Chem., 336 (1994) 126-130 (Engl. Transl.)].
14) S.M. Yunusov, V.A. Likholobov, V.B. Shur. Supported Ammonia Synthesis Catalysts Based on
Anionic Ruthenium Cluster K2[Ru4(CO)13]. The Promoting Effect of Cesium Nitrate. Appl. Cat.
A: General, 158 (1997) L35-L39.
15) S.M. Yunusov, B.L. Moroz, A.S. Ivanova, V.A. Likholobov, V.B. Shur. Anionic Ruthenium
Cluster K2[Ru4(CO)13] as Precursor of Catalytically Active Ruthenium Particles and Potassium
Promoter. New Efficient Ammonia Synthesis Catalysts Based on Supported K2[Ru4(CO)13].
J. Molec. Cat. A: Chem., 132 (1998) 263-265.
16) V.B. Shur, S.M. Yunusov. On the Path to Catalysts for the Low-Temperature Ammonia
Synthesis. Izv. Akad. Nauk, Ser. Khim., (1998) 796-806 [Russ. Chem. Bull., 47 (1994) 765-775
(Engl. Transl.)] .
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17) S.M. Yunusov, E.S. Kalyuzhnaya, H. Mahapatra, V.K. Puri, V.A. Likholobov, V.B. Shur.
Supported Ammonia Synthesis Catalysts Based on Potassium Derivatives of Anionic
Ruthenium, Osmium and Iron Carbonyl Clusters. The First Catalysts on Carbon Support
Exhibiting Activity in Ammonia Synthesis in the Absence of a Specially Added Electron
Promoter. J. Molec. Cat. A: Chem., 139 (1999) 219-225.
18) S.M. Yunusov, E.S. Kalyuzhnaya, B.L. Moroz, S.N. Agafonova, V.A. Likholobov, V.B. Shur.
The Effect of Co and Ir on the Activity of the K2[Fe2(CO8)]- and K2[Ru4(CO)13]-based Systems
in Ammonia Synthesis. The Synergistic Acceleration of the Ammonia Synthesis over the
K2[Fe2(CO8)] + K Catalysts by Iridium. J. Molec. Cat. A: Chem., 165 (2001) 143-149.
19) S.M. Yunusov, E.S. Kalyuzhnaya, B.L. Moroz, S.N. Agafonova, V.A. Likholobov, V.B. Shur.
The Synergistic Acceleration of the Ammonia Synthesis over the K2[Fe2(CO8)] + K Catalysts on
Carbon “Sibunit” by Rhodium. Appl. Cat. A: General, 218 (2001) 251-256.
20) S.M. Yunusov, E.S. Kalyuzhnaya, B.L. Moroz, A.S. Ivanova, T.V. Reshetenko, L.B. Avdeeva,
V.A. Likholobov, V.B. Shur. New Ammonia Synthesis Catalysts Based on Supported Carbonyl
Ruthenates as Precursors of Catalytically Active Ruthenium Particles and Potassium Promoter.
J. Molec. Cat. A: Chem., 219 (2004) 149-153.
21) A.S. Ivanova, E.S. Kalyuzhnaya, G.S. Litvak, E.M. Moroz, S.M. Yunusov, V.S. Lenenko,
B.L. Moroz, V.B. Shur, V.A. Likholobov. New Y(La)-M-O Binary Systems (M=Ca, Sr, Ba):
Synthesis, Physicochemical Characterization, and Application as the Supports of Ruthenium
Catalysts for Ammonia Synthesis. Kinetika i Kataliz, 45 (2004) 574-579 [Kinetics and Catalysis,
45 (2004) 541-546 (Engl. Transl.)].
22) Yu.V. Larichev, B.L. Moroz, E.M. Moroz, V.I. Zaikovskii, S.M. Yunusov, E.S. Kalyuzhnaya,
V.B. Shur, V.I. Bukhtiyarov. Effect of the Support on the Nature of Metal-Promoter Interactions
in Ru-Cs+/MgO and Ru-Cs+/Al2O3 Catalysts for Ammonia Synthesis. Kinetika i Kataliz, 46
(2005) 940-948 [Kinetics and Catalysis, 46 (2005) 891-899 (Engl. Transl.)].
23) Yu.V. Larichev, B.L. Moroz, V.I. Zaikovskii, S.M. Yunusov, E.S. Kalyuzhnaya, V.B. Shur,
V.I. Bukhtiyarov. XPS and TEM Studies on the Role of the Support and Alkali Promoter in
Ru/MgO and Ru–Cs+/MgO Catalysts for Ammonia Synthesis. J. Phys. Chem. C, 111 (2007)
9427-9436.
24) S.M. Yunusov, E.S. Kalyuzhnaya, B.L. Moroz, A.S. Ivanova, V.B. Shur. Ammonia Synthesis
from Dinitrogen and Dihydrogen over the Catalysts Based on the Supported Mononuclear
Potassium Carbonylruthenate. Promoting Effect of Lithium Alkyls. Izv. Akad. Nauk, Ser. Khim.,
2011, in press [Russ. Chem. Bull., Int.Ed., 60 (2011) in press].
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Molecular Nitrogen Complexes
1) V.B. Shur, I.A. Tikhonova, E.F. Isaeva, M.E. Vol'pin. Formation of Nitrogen Complexes
by the Reaction of a Ru(III) Derivative with Monoarylhydrazines. Izv. Akad. Nauk SSSR, Ser.
Khim., (1971) 2357-2358 [Bull. Acad. Sci. USSR., Div. Chem. Sci., 20 (1971) 2247 (Engl.
Transl.)].
2) V.I. Nefedov, V.S. Lenenko, V.B. Shur, M.E. Vol'pin, J.E. Salyn, M.A. Porai-Koshits.
Molecular Nitrogen as a Ligand. A Study of Dinitrogen Complexes of Transition Metals,
Diazocompounds and Azides by X-Ray Photoelectron Spectroscopy. Inorg. Chim. Acta, 7 (1973)
499-502.
3) I.A. Tikhonova, K. Jähnisch, V.G. Andrianov, S.F. Byalotskii, Yu.T. Struchkov, V.B. Shur,
É. Schmitz, M.E. Vol'pin. Reaction of 3,3-Pentamethylenediazirine with Nonacarbonyliron and
Aquapentaammine Derivative of Divalent Ruthenium. New Pathway to the [Ru(NH3)5H2О]2+
Complex. Koord. Khim., 2 (1976) 1653-1658 [Sov. J. Coord. Chem., (1976) 1274-1278 (Engl.
Transl.)].
4) V.B. Shur, I.A. Tikhonova, M.E. Vol'pin. Formation of Dinitrogen Complexes in the
Interaction of the [Ru(NH3)5H2О]2+ Ion with Diazoacetic Ester and Aromatic Diazonium Salts.
Koord. Khim., 4 (1978) 1248-1255 [Sov. J. Coord. Chem., (1978) (Engl. Transl.)].
5) A.L. Blumenfel’d, V.S. Lenenko, B. Lorentz, I. Mebius, M. Wahren, V.B. Shur,
M.E. Vol’pin. Investigation of Diazo Compounds, Azides, and Nitrogen Complexes of
Transition Metals by NMR 15N Spectroscopy. Dokl. Akad. Nauk SSSR, 251 (1980) 611-615
[Dokl. Chem., 251 (1980) 143-148 (Engl. Transl.)].
6) V.B. Shur, I.A. Tikhonova, G.G. Aleksandrov, Yu.T. Struchkov, M.E. Vol'pin, E. Schmitz,
K. Jähnisch. The Diazirine Complex [(NH3)5Ru(N2C6H10)]2+: Synthesis, Structure and Conver-
sion into the Dinitrogen Complex [(NH3)5RuN2)]2+. Inorg. Chim. Acta, 44 (1980) L275-L277.
7) V.S. Lenenko, A.G. Knizhnik, E.I. Mysov, V.B. Shur, M.E. Vol’pin. Reduction of
Aromatic Diazo Compounds by Alcohols to Hydrocarbons Catalyzed by the Nitrogen Complex
trans-(Ph2PCH2CH2PPh2)2W(N2)2. Dokl. Akad. Nauk SSSR, 255 (1980) 1131-1135 [Dokl. Chem.,
255 (1980) 591-594 (Engl. Transl.)].
8) V.S. Lenenko, A.P. Borisov, V.D. Makhaev, E.I. Mysov, V.B. Shur, M.E. Vol’pin. New
Catalysts for the Reduction of Aromatic Diazo Compounds by Alcohols to Hydrocarbons.
Izv. Akad. Nauk SSSR, Ser. Khim., (1983) 947-950 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 32
(1983) 858-860 (Engl. Transl.)].
9) V.B. Shur, I.A. Tikhonova, M.E. Vol'pin. Catalytic Oxidation-Reduction
Disproportionation of Phenylhydrazine by the Action of [Ru(NH3)5Cl]Cl2. Izv. Akad. Nauk SSSR,
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Ser. Khim., (1988) 943-944 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 37 (1988) 824 (Engl.
Transl.)].
10) V.S. Lenenko, P. Kränke, M. Wahren, V.B. Shur, M.E. Vol’pin. Acid-Catalyzed Attack of
the Dinitrogen Ligand in the cis-(Ме2PhP)4Mo(N2)2 and trans-(Ph2PCH2CH2PPh2)2W(N2)2
Complexes by Nitronium and Nitrosonium Cations with the Formation of Nitrogen Oxides.
Izv. Akad. Nauk, Ser. Khim., (1995) 1340-1346 [Russ. Chem. Bull., 44 (1995) 1293-1299 (Engl.
Transl.)].
11) E.G. Berkovich, V.S. Lenenko, L.I. Vyshinskaya, G.A. Vasil'eva, V.B. Shur, M.E. Vol'pin.
Formation of Aromatic Amines from Dinitrogen Complexes [Cp2TiAr]2N2 (Ar = C6H5, m-
CH3C6H4). J. Organomet. Chem., 535 (1997) 169-173.
Hexaazabenzene Molecule N6 and Possible Ways of Its Stabilization
1) E.G. Gal’pern, I.V. Stankevich, A.L. Chistyakov, V.B. Shur, M.E. Vol’pin. Is It Possible to
Stabilize the Hexaazabenzene Cyclic System? Izv. Akad. Nauk SSSR, Ser. Khim., (1987) 1675
[Bull. Acad. Sci. USSR, Div. Chem. Sci., 36 (1987) 1552 (Engl. Transl.)].
2) E.G. Gal’pern, I.V. Stankevich, A.L. Chistyakov, V.B. Shur, M.E. Vol’pin. Possibility of
Stabilizing the Cyclic Hexaazabenzene System. Dokl. Akad. Nauk SSSR, 302 (1988) 1384-1388
[Dokl. Chem., 302 (1988) 302-305 (Engl. Transl.)].
3) I.V. Stankevich, A.L. Chistyakov, V.B. Shur, M.E. Vol’pin. Possible Existence of a Cyclic
Trimer of Nitrous Oxide. Dokl. Akad. Nauk SSSR, 313 (1990) 118-120 [Dokl. Chem., 313 (1990)
194-195 (Engl. Transl.)].
Activation of С–Н Bonds
1) V.N. Latyaeva, L.I. Vyshinskaya, V.B. Shur, L.A. Fedorov, M.E. Vol'pin. Reaction of Dicyclo-
pentadienyldiphenyltitanium with Phenyllithium. J. Organomet. Chem., 16 (1969) 103-109.
2) M.E. Vol'pin, A.A. Belyi, V.B. Shur, Yu.I. Lyakhovetsky, R.V. Kudryavtsev, N.N. Bubnov.
Study of Nitrogen Fixing Systems. Investigation of the Mechanism of the Reduction of
Titanocenedichloride by Magnesium. Dokl. Akad. Nauk SSSR, 194 (1970) 577-579.
3) M.E. Vol'pin, A.A. Belyi, V.B. Shur, Yu.I. Lyakhovetsky, R.V. Kudryavtsev, N.N. Bubnov.
Cyclopentadienyl Ligands as a Hydrogen Source in the Formation of Titanium Hydride
Complexes. J. Organomet. Chem., 27 (1971) C5-C8.
4) V.B. Shur, E.G. Berkovich, E.I. Mysov, M.E. Vol’pin. Catalytic Activity of Cyclopentadienyl
Titanium Complexes in Isotopic Exchange Reactions of Aromatic Hydrocarbons with Molecular
Deuterium. Izv. Akad. Nauk SSSR, Ser. Khim., (1987) 2435-2439 [Bull. Acad. Sci. USSR, Div.
Chem. Sci., 36 (1987) 2259-2263 (Engl. Transl.)].
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5) M.A. Ilatovskaya, S. Rummel, Yu.V. Isaev, S.M. Yunusov, N.D. Lenenko, M. Herrmann,
M. Wahren, Yu.N. Novikov, V.B. Shur. Lamellar Graphite Compounds with Metallic Potassium
As Catalysts for Deuterium-Hydrogen Exchange in Hydrocarbons. Izv. Akad. Nauk SSSR, Ser.
Khim., (1991) 1935-1936 [Bull. Acad. Sci. USSR., Div. Chem. Sci., 40 (1991) 1722].
6) S.M. Yunusov, S. Rummel, M.A. Ilatovskaya, M. Herrmann, V.A. Likholobov, V.B. Shur,
M.E. Vol’pin Activation of Hydrocarbon С–Н Bonds by Catalysts Based on Potassium Salts of
Transition Metal Carbonyl Hydrides on a Carbon Support. Metalloorg. Khim., 5 (1992) 1395-
1396 [Organomet. Chem. USSR, 5 (1992) 685 (Engl. Transl.)].
7) S. Rummel, M.A. Ilatovskaya, E.I. Mysov, V.S. Lenenko, H. Langguth, V.B. Shur. Catalytic
Activation of C–H Bonds in Aromatic Hydrocarbons, Ethene, and Methane by the
Naphthalene/Sodium System in Tetrahydrofuran. Angew. Chem. Int. Ed. Engl., 35 (1996) 2489-
2491.
8) S. Rummel, S.M. Yunusov, M.A. Ilatovskaya, H. Langguth, E.I. Mysov, M. Wahren,
V.A. Likholobov, V.B. Shur. Catalytic Activation of C–H Bonds of Alkanes, Ethene and
Aromatic Hydrocarbons by the Adducts of Active Carbons with Metallic Potassium. J. Molec.
Cat. A: Chem., 132 (1998) 277-280.
9) S. Rummel, M.A. Ilatovskaya, S.M. Yunusov, E.S. Kalyuzhnaya, V.B. Shur. Activation of C–H
Bonds of Hydrocarbons by the ArH–Alkali Metal Systems in THF (ArH – Naphthalene,
Biphenyl, Anthracene, Phenanthrene, trans-Stilbene, Pyrene). Alkylation of Naphthalene and
Toluene with Ethene. J. Organomet. Chem., 694 (2009) 1459-1466.
10) S. Rummel, S.M. Yunusov, E.S. Kalyuzhnaya, V.B. Shur. Synergistic Effects of Alkali Metals in
the Alkylation of Naphthalene and Toluene with Ethene in the ArH–Alkali Metal Systems in
THF (ArH – Naphthalene, Phenanthrene). J. Organomet. Chem., 694 (2009) 1467-1472.
Acetylene Complexes of Group IVB Metallocenes
1) V.B. Shur, E.G. Berkovich, M.E. Vol'pin, B. Lorenz, M. Wahren. Interaction of Titanocene
Generated in the System Cp2TiCl2 + Mg in THF with Benzyne and Tolane. A Novel Route to
Titanaindene and Titanacyclopentadiene Complexes. J. Organomet. Chem., 228 (1982) C36-C38.
2) V.B. Shur, S.Z. Bernadyuk, V.V. Burlakov, V.G. Andrianov, A.I. Yanovsky, Yu.T. Struchkov,
M.E. Vol'pin. Synthesis and X-Ray Structure Determination of an Organometallic Titanoxane
[Cp2TiC(Ph)=CH(Ph)]2O. Evidence for the Formation of a Titanocene Complex with Tolane.
J. Organomet. Chem., 243 (1983) 157-163.
3) V.B. Shur, V.V. Burlakov, M.E. Vol'pin. Synthesis of Unsymmetrical Titanacyclopentadienes by
Reacting a Titanocene Tolan Complex with Acetylenes. Izv. Akad. Nauk SSSR, Ser. Khim.,
(1983) 1929-1930 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 32 (1983) 1753 (Engl. Transl.)] .
8
4) V.B. Shur, V.V. Burlakov, A.I. Yanovsky, P.V. Petrovsky, Yu.T. Struchkov, M.E. Vol'pin.
Reaction of a Tolane Complex of Titanocene with Carbonyl Compounds. Synthesis of
Titanadihydrofuran Metallacycles. J. Organomet. Chem., 297 (1985) 51-59.
5) V.B. Shur, V.V. Burlakov, M.E. Vol'pin. Complex of Titanocene with Tolane. Isolation, Spectral
Characteristics, Reactivity. J. Organomet. Chem., 347 (1988) 77-83.
6) V.V. Burlakov, U. Rosenthal, P.V. Petrovskii, V.B. Shur, M.E. Vol'pin. A Complex of
Titanocene with Bis(trimethylsilyl)acetylene. Metalloorg. Khim., 1 (1988) 953-954 [Organomet.
Chem. USSR, 1 (1988) 526-527].
7) U. Rosenthal, G. Oehme, V.V. Burlakov, P.V. Petrovskii, V.B. Shur, M.E. Vol'pin. 13C{1H}NMR
Studies of Selected Transition Metal Alkyne Complexes. J. Organomet. Chem., 391 (1990) 119-
122.
8) V.B. Shur, V.V. Burlakov, M.E. Vol’pin. Catalytic Activity of the Titanocene Complex with
Tolane in Homogeneous Hydrogenation of Unsaturated Hydrocarbons. J. Organomet. Chem., 439
(1992) 303-308.
9) U. Rosenthal, H. Görls, V.V. Burlakov, V.B. Shur, M.E. Vol’pin. Alkinkomplexe des Titanocens
und Permethyltitanocens ohne zusätzliche Liganden – Erste Structurvergleiche. J. Organomet.
Chem., 426 (1992) C53-C57.
10) U. Rosenthal, A. Ohff, M. Michalik, H. Görls, V.V. Burlakov, V.B. Shur. Transformation of the
First Zirconocene Alkyne Complex without an Additional Phosphane Ligand into a Dinuclear σ-
Alkenyl Complex by Hydrogen Transfer from η5-C5H5 to the Alkyne Ligand. Angew. Chem. Int.
Ed. Engl., 32 (1993) 1193-1195.
11) U. Rosenthal, A. Ohff, M. Michalik, H. Görls, V.V. Burlakov, V.B. Shur. Interaction of the
Zirconocene Alkyne Complex Cp2Zr(THF).(Me3SiC2SiMe3) and the Binuclear Zirconium -
Alkenyl Complex {Cp[-(1:5-C5H4)]ZrC(SiMe3)=CH(SiMe3)}2 with Carbon Dioxide and
Water. Organometallics, 12 (1993) 5016-5019.
12) V.V. Burlakov, A.V. Polyakov, A.I. Yanovsky, Yu.T. Struchkov, V.B. Shur, M.E. Vol’pin,
U. Rosenthal, H. Görls. Novel Acetylene Complexes of Titanocene and Permethyltitanocene
without Additional Ligands. The Synthesis, Spectral Characteristics and X-Ray Diffraction
Study. J. Organomet. Chem., 476 (1994) 197-206.
13) U. Rosenthal, A. Ohff, W. Baumann, A. Tillack, H. Görls, V.V. Burlakov, V.B. Shur. Zirkona-
dihydrofuran-Komplexe: Darstellung, Structur und Reactivitäts-Betrachtungen. J. Organomet.
Chem., 484 (1994) 203-207.
14) U. Rosenthal, A. Ohff, W. Baumann, A. Tillack, H. Görls, V.V. Burlakov, V.B. Shur. Structur,
Eigenschaften und NMR-spectroscopische Charakterisierung von Cp2Zr(Pyridin)-
(Me3SiCCSiMe3). Z. anorg. allg. Chem., 621 (1995) 77-83.
9
15) V.V. Burlakov, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, V.B. Shur, U. Rosenthal,
U. Thewalt. Interaction of Carbon Dioxide with the Bis(trimethylsilyl)acetylene Complex of
Permethyltitanocene: Synthesis and Structure of the Binuclear Carbonate Complex of
Permethyltitanocene (Cp*2Ti)2CO3. J. Organomet. Chem., 522 (1996) 241-247.
16) L.I. Strunkina, M.Kh. Minacheva, P.V. Petrovskii, Z.S. Klemenkova, B.V. Lokshin,
V.V. Burlakov, V.B. Shur. Interactions of Hafnocene and Zirconocene Dihydrides with
Acetylenes. Synthesis of the First Acetylene Complex of Hafnium. Izv. Akad. Nauk, Ser. Khim.,
(1997) 853-856 [Russ. Chem. Bull., 46 (1997) 820-823 (Engl. Transl.)].
17) V.V. Burlakov, A.I. Yanovsky, Yu.T. Struchkov, U. Rosenthal, A. Spannenberg, R. Kempe,
O.G. Ellert, V.B. Shur. Interaction of Carbon Dioxide with Acetylene Complexes of Titanocene
Cp2Ti(RC2R) (R=Ph, SiMe3). Synthesis and Structure of Binuclear -Alkenylcarboxylate
Complexes of Titanium (III) Cp2TiC(R)=C(R)COOTiCp2 and Unexpected Transformation of
These Complexes into Titanafuranone Metallacycles Under the Action of Air Oxygen.
J. Organomet. Chem., 542 (1997) 105-112.
18) V.V. Burlakov, A.V. Usatov, K.A. Lyssenko, M.Yu. Antipin, Yu.N. Novikov, V.B. Shur.
Synthesis and Structure of the First Fullerene Complex of Titanium Cp2Ti(2-C60). Eur. J. Inorg.
Chem., (1999) 1855-1857.
19) L.I. Strunkina, M.Kh. Minacheva, K.A. Lyssenko, Z.S. Klemenkova, A.Yu. Volkonsky,
P.V. Petrovskii, V.V. Burlakov, V.B. Shur. Interaction of Bis(trimethylsilyl)acetylene Complex
of Titanocene with Mercury Trifluoroacetate. Izv. Akad. Nauk, Ser. Khim., (2003) 1299-1301
[Russ. Chem. Bull., Int. Ed., 52 (2003) 1372-1375].
Zwitterionic Group IVB Metallocenes
1)V.V. Burlakov, S.I. Troyanov, A.V. Letov, E.I. Mysov, G.G. Furin, V.B. Shur. Synthesis of a
Zwitterionic Metallocene of a New Type by the Reaction of the Bis(trimethylsilyl)acetylene
Complex of Titanocene with Tris(pentafluorophenyl)borane. Izv. Akad. Nauk, Ser. Khim., (1999)
1022-1024 [Russ. Chem. Bull., 48 (1999) 1012-1013 (Engl. Transl.)].
2)V.V. Burlakov, S.I. Troyanov, A.V. Letov, L.I. Strunkina, M.Kh. Minacheva, G.G. Furin,
U. Rosenthal, V.B. Shur. Interaction of Bis(trimethylsilyl)acetylene Complex of Titanocene with
Tris(pentafluorophenyl)borane. Synthesis and Structure of a New Type of Zwitterionic
Metallocene (5-C5H5){5-[C5H4B(C6F5)3]}Ti. J. Organomet. Chem., 598 (2000) 243-247.
3)V.V. Burlakov, P.-M. Pellny, P. Arndt, W. Baumann, A. Spannenberg, V.B. Shur, U. Rosenthal.
Reactions of Permethylmetallocene Alkyne Complexes of Titanium and Zirconium with
Tris(perfluorophenyl)borane. J. Chem. Soc. Chem. Commun., (2000) 241-242.
10
4)V.V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, A.V. Letov,
K.A. Lyssenko, A.A. Korlyukov, L.I. Strunkina, M.Kh. Minacheva, V.B. Shur. Synthesis and
X-Ray Crystal Structure Determination of New Zwitterionic Complexes of Titanocene.
Organometallics, 20 (2001) 4072-4079.
5)A. Spannenberg, V.V. Burlakov, P. Arndt, W. Baumann, V.B. Shur, U. Rosenthal. Crystal
Structure of [1,2-ethylene-1,1′-bis(η5-tetrahydroindenyl)][hydroxytris(pentafluorophenyl)bora-
to]titanium (III), C38H24BF15OTi. Z. Kristallogr. NCS, 217 (2002) 546-548.
6)L.I. Strunkina, M.Kh. Minacheva, K.A. Lyssenko, O.I. Haustova, V.V. Burlakov, U. Rosenthal,
V.B. Shur. Synthesis of Zwitterionic Titanocene Monochloride Cp[5-C5H4B(C6F5)3]TiCl
Containing Tris(pentafluorophenyl)borane Moiety in the 5-Cyclopentadienyl Ring. Izv. Akad.
Nauk, Ser. Khim., (2003) 737-738 [Russ. Chem. Bull., Int. Ed., 52 (2003) 773-774].
7)P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, V.V. Burlakov, V.B. Shur. Reactions of
Titanium and Zirconium Derivatives of Bis(trimethylsilyl)acetylene with Tris(pentafluoro-
phenyl)borane: A Titanium(III) Complex of an Alkynylboranate. Angew. Chem. Int. Ed., 42
(2003) 1414-1418.
8)V.V. Burlakov, A.V. Letov, P. Arndt, W. Baumann, A. Spannenberg, Ch. Fisher, L.I. Strunkina,
M.Kh. Minacheva, Ya.S. Vygodskii, U. Rosenthal, V.B. Shur. Zwitterionic Titanoxanes
{Cp[5-C5H4B(C6F5)3]Ti}2O and {(5-iPrC5H4)[5-{1,3-iPrC5H3B(C6F5)3}]Ti}2O as Catalysts for
Cationic Ring-Opening Polymerization. J. Molec. Cat. A: Chem., 200 (2003) 63-67.
9)U. Rosenthal, V.V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, V.B. Shur. Titanocene and
Zirconocene Bis(trimethylsilyl)acetylene Complexes: Recent Chemistry and Reactions with
Lewis Acids. Eur. J. Inorg. Chem., (2004) 4739-4749.
10) L.I. Strunkina, M.Kh. Minacheva, K.A. Lyssenko, P.V. Petrovskii, V.V. Burlakov, U. Rosenthal,
V.B. Shur. Protolytic B–C6F5 Bond Cleavage in Zwitterioniс Titanocene Monochloride Cp[5-
C5H4B(C6F5)3]TiCl with Water to Form Titanocene Chloride Hydroxide Complex Cp[5-
C5H4B(C6F5)2]TiCl(-OH). Izv. Akad. Nauk, Ser. Khim., (2006) 169-171 [Russ. Chem. Bull., Int.
Ed., 55 (2006) 174-176].
11) L.I. Strunkina, M.Kh. Minacheva, K.A. Lyssenko, V.V. Burlakov, W. Baumann, P. Arndt,
B.N. Strunin, V.B. Shur. Interaction of Titanium (III) Zwitterionic Complex Cp[5-
C5H4B(C6F5)3]Ti with Organic Halides: Synthesis and X-Ray Crystal Structure Determination of
Zwitterionic Titanocene Monohalides Cp[5-C5H4B(C6F5)3]TiX (X = Cl, Br) and their Catalytic
Activity in the Ring-Opening Polymerization of -Caprolactone. J. Organomet. Chem., 691
(2006) 557-565.
12) L.I. Strunkina, M.Kh. Minacheva, K.A. Lyssenko, P.V. Petrovskii, N.E. Mysova, B.N. Strunin,
V.V. Burlakov, U. Rosenthal, V.B. Shur. Electrophilic Reactivity of the Zwitterionic Titanocene
11
Monohalides Cp[5-C5H4B(C6F5)3]TiX (X = Cl, Br): Reactions with Water and Methanol.
J. Organomet. Chem., 692 (2007) 4321-4326.
Metallacyclic Derivatives of Group IV B Metallocenes
and Their Reactions with Lewis Acids
1)V.V. Burlakov, V.S. Bogdanov, K.A. Lyssenko, P.V. Petrovskii, T. Beweries, P. Arndt,
U. Rosenthal, V.B. Shur. First Structurally Characterized Five-Membered Hafnacyclocumulene
Сp2Hf(4-tBuС4tBu). Izv. Akad. Nauk, Ser. Khim., (2008) 1294-1295 [Russ. Chem. Bull., Int. Ed.,
57 (2008) 1319-1320].
2)V.V. Burlakov, T. Beweries, V.S. Bogdanov, P. Arndt, W. Baumann, P.V. Petrovskii,
A. Spannenberg, K.A. Lyssenko, V.B. Shur, U. Rosenthal. Synthesis and Isolation of Di-n-
butylhafnocene and Its Application as a Versatile Starting Material for the Synthesis of New
Hafnacycles. Organometallics, 28 (2009) 2864-2870.
3)V.V. Burlakov, V.S. Bogdanov, K.A. Lyssenko, L.I. Strunkina, M.Kh. Minacheva, B.N. Strunin,
U. Rosenthal, V.B. Shur. Formation of the Five-Membered Zirconacyclocumulene Cp2Zr(η4-
ButC4But) and the Binuclear Zirconocene Butatrienyl Complex Cp2(Bun)Zr(ButC4But)Zr(Bun)Cp2
in the Reaction of the Negishi Reagent with 1,4-Di(tert-butyl)butadiyne. Izv. Akad. Nauk, Ser.
Khim., (2010) 653-655 [Russ. Chem. Bull., Int. Ed., 59 (2010) 668-670].
4)V.V. Burlakov, T. Beweries, K. Kaleta, V.S. Bogdanov, P. Arndt, W. Baumann, A. Spannenberg,
V.B. Shur, U. Rosenthal. Reactions of the Five-Membered Hafnacyclocumulene Cp2Hf(4-t-Bu-
C4-t-Bu) with the Lewis Acids Tris(pentafluorophenyl)borane and Diisobutylaluminum Hydride.
Organometallics, 29 (2010) 2367-2371.
5)V.V. Burlakov, V.S. Bogdanov, K.A. Lyssenko,A. Spannenberg, P.V. Petrovskii, W. Baumann,
L.I. Strunkina, M.Kh. Minacheva, B.N. Strunin, P. Arndt, U. Rosenthal, V.B. Shur., Interaction
of the Negishi Reagent Cp2ZrBun2 with 1,4-bis(tert-butyl)butadiyne. Izv. Akad. Nauk, Ser. Khim.,
(2011) in press [Russ. Chem. Bull., Int. Ed., 60 (2011) in press].
6)V.V. Burlakov, T. Beweries, K. Kaleta, V.S. Bogdanov, P. Arndt, W. Baumann, A. Spannenberg,
V.B. Shur, U. Rosenthal. Reactions of the Five-Membered Metallacyclocumulenes Cp2M(4-t-
Bu-C4-t-Bu) (M = Ti, Zr) with Diisobutylaluminum Hydride. Organometallics, (2011) in press.
Anticrowns
1)V.B. Shur, I.A. Tikhonova, P.V. Petrovskii, M.E. Vol'pin. Complex Formation Between Trimeric
o-Phenylenemercury and Halide Anions and the Phase Transfer Catalysis of the Azo-Coupling
Reaction. Metalloorg. Khim., 2 (1989) 1431-1432 [Organomet. Chem. USSR, 2 (1989) 759-760
(Engl. Transl.)].
2)V.B. Shur, I.A. Tikhonova, A.I. Yanovsky, Yu.T. Struchkov, P.V. Petrovskii, S.Yu. Panov,
G.G. Furin, M.E. Vol'pin. Crown Compounds for Anions. Unusual Complex of Trimeric
12
Perfluoro-o-phenylenemercury with the Bromide Anion Having a Polydecker Sandwich
Structure. J. Organomet. Chem., 418 (1991) C29-C32.
3)V.B. Shur, I.A. Tikhonova, A.I. Yanovskii, Yu.T. Struchkov, P.V. Petrovskii, S.Yu. Panov,
G.G. Furin, M.E. Vol'pin. Multideck Sandwich Complex of Trimeric Perfluoro-o-
phenylenemercury with Iodide Anion. Dokl. Akad. Nauk SSSR, 321 (1991) 1002-1004 [Dokl.
Chem., 321 (1991) 391-393 (Engl. Transl.)].
4)V.B. Shur, I.A. Tikhonova, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, A.Yu. Volkonsky,
E.V. Solodova, S.Yu. Panov, P.V. Petrovskii, M.E. Vol'pin. Crown Compounds for Anions.
A Spinning Top-Shaped Complex of Cyclic Pentameric Perfluoroisopropylidenemercury with
Two Chloride Anions. J. Organomet. Chem., 443 (1993) C19-C20.
5)V.B. Shur, I.A. Tikhonova, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, A.Yu. Volkonsky,
P.V. Petrovskii, E.V. Solodova, S.Yu. Panov, M.E. Vol'pin. Crown Compounds for Anions. A
Spinning Top-Shaped Complex of Cyclic Pentameric Perfluoroisopropylidenemercury with Two
Bromide Anions. Dokl. Akad. Nauk, 328 (1993) 339-341.
6)A.P. Zaraiskii, O.I. Kachurin, L.I. Velichko, I.A. Tikhonova, G.G. Furin, V.B. Shur, M.E. Vol'pin.
Cyclic Trimeric Perfluoro-o-phenylenemercury as the Phase Transfer Catalyst for Nitration with
Dilute Nitric Acid. Izv. Akad. Nauk, Ser. Khim., (1994) 547-548 [Russ. Chem. Bull., 43 (1994)
507-508 (Engl. Transl.)].
7)A.P. Zaraiskii, O.I. Kachurin, L.I. Velichko, I.A. Tikhonova, A.Yu. Volkonsky, V.B. Shur. New
Highly Efficient Phase Transfer Catalyst for Nitration with Dilute Nitric Acid. Izv. Akad. Nauk,
Ser. Khim., (1994) 2047-2048 [Russ. Chem. Bull., 43 (1994) 1936-1937 (Engl. Transl.)].
8)A.L. Chistyakov, I.V. Stankevich, N.P. Gambaryan, I.A. Tikhonova, V.B. Shur. Crown
Compounds for Anions. The Nature of Chemical Bonds in the Complexes of Halide Anions with
Cyclic Trimeric Perfluoro-o-phenylenemercury and Some of Its Analogs. Izv. Akad. Nauk, Ser.
Khim., (1995) 1035-1042 [Russ. Chem. Bull., 44 (1995) 997-1004 (Engl. Transl.)].
9)I.A. Tikhonova, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, A.N. Gavrilova,
L.N. Saitkulova, E.S. Shubina, L.M. Epstein, G.G. Furin, V.B. Shur. Crown Compounds for
Anions. A Polymeric Complex of Cyclic Trimeric Perfluoro-o-phenylenemercury with
Thiocyanate Anion Containing an Infinite Helical Chain of Alternating Molecules of Mercury-
Containing Macrocycle and SCN– Ions. J. Organomet. Chem., 508 (1996) 271-273.
10) A.L. Chistyakov, I.V. Stankevich, N.P. Gambaryan, I.A. Tikhonova, V.B. Shur. Crown
Compounds for Anions. MNDO Calculations of Complexes of Halide Anions with Cyclic
Pentameric Difluoromethylidenemercury. Izv. Akad. Nauk, Ser. Khim., (1996) 44-48 [Russ.
Chem. Bull., 45 (1995) 37-41 (Engl. Transl.)].
13
11) A.L. Chistyakov, I.V. Stankevich, N.P. Gambaryan, Yu.T. Struchkov, A.I. Yanovsky,
I.A. Tikhonova, V.B. Shur. Crown Compounds for Anions. A New Approach to the Description
of Chemical Bonds in the Complexes of Halide Anions with Polymercury-containing
Macrocycles. J. Organomet. Chem., 536-537 (1997) 413-424.
12) A.P. Zaraiskii, O.I. Kachurin, L.I. Velichko, V.B. Shur, I.A. Tikhonova, G.G. Furin. Phase-
Transfer Catalysis in Electrophilic Substitution Reactions: VIII. Nitration of Arenes with Sodium
Nitrite in Acid Medium under Conditions of Phase-Transfer Catalysis. Zh. Org. Khim., 35 (1999)
1063-1067 [Russ. J. Org. Chem., 35 (1999) 1039-1043 (Engl. Transl.)].
13) L.N. Saitkulova, E.V. Bakhmutova, E.S. Shubina, I.A. Tikhonova, G.G. Furin, V.I. Bakhmutov,
N.P. Gambaryan, A.L. Chistyakov, I.V. Stankevich, V.B. Shur, L.M. Epstein. Crown
Compounds for Anions. Spectroscopic and Theoretical Studies of Complexation of Borohydride
Anions with Cyclic Trimeric Perfluoro-o-phenylenemercury. J. Organomet. Chem., 585 (1999)
201-210.
14) I.A. Tikhonova, F.M. Dolgushin, A.I. Yanovsky, Z.A. Starikova, P.V. Petrovskii, G.G. Furin,
V.B. Shur. Complexation of Cyclic Trimeric Perfluoro-o-phenylenemercury with Nitriles.
A Remarkable Sensitivity of the Composition and Structure of the Resulting Complexes to the
Nature of a Nitrile. J. Organomet. Chem., 613 (2000) 60-67.
15) E.S. Shubina, I.A. Tikhonova, E.V. Bakhmutova, F.M. Dolgushin, M.Yu. Antipin,
V.I. Bakhmutov, I.B. Sivaev, L.N. Teplitskaya, I.T. Chizhevsky, I.V. Pisareva, V.I. Bregadze,
L.M. Epstein, V.B. Shur. Crown Compounds for Anions: Sandwich and Half-Sandwich
Complexes of Cyclic Trimeric Perfluoro-o-phenylenemercury with Polyhedral closo-[B10H10]2–
and closo-[B12H12]2– Anions. Chem. Eur. J., 7 (2001) 3783-3790.
16) I.A. Tikhonova, F.M. Dolgushin, K.I. Tugashov, G.G. Furin, P.V. Petrovskii, V.B. Shur.
Coordination Chemistry of Macrocyclic Multidentate Lewis Acids. Synthesis and Structures of
Complexes of Cyclic Trimeric Perfluoro-o-phenylenemercury with N,N-Dimethylacetamide and
n-Butyronitrile. Izv. Akad. Nauk, Ser. Khim., (2001) 1595-1600 [Russ. Chem. Bull., Int. Ed., 50
(2001) 1673-1678].
17) I.A. Tikhonova, F.M. Dolgushin, K.I. Tugashov, P.V. Petrovskii, G.G. Furin, V.B. Shur.
Coordination Chemistry of Polymercuramacrocycles. Complexation of Cyclic Trimeric
Perfluoro-o-phenylenemercury with Neutral Oxygeneous Lewis Bases. J. Organomet. Chem.,
654 (2002) 123-131.
18) I.A. Tikhonova, E.S. Shubina, F.M. Dolgushin, K.I. Tugashov, L.N. Teplitskaya, A.M. Filin,
I.B. Sivaev, P.V. Petrovskii, G.G. Furin, V.I. Bregadze, L.M. Epstein, V.B. Shur. Crown
Compounds for Anions. Sandwich Complex of Cyclic Trimeric Perfluoro-o-phenylenemercury
14
with [B12H11SCN]2– Anion. Izv. Akad. Nauk, Ser. Khim., (2003) 570-576 [Russ. Chem. Bull., Int.
Ed., 52 (2003) 594-600].
19) V.B. Shur, I.A. Tikhonova. Perfluorinated Polymercuramacrocycles as Anticrowns. Applications
in Catalysis. Izv. Akad. Nauk, Ser. Khim., (2003) 2401-2416 [Russ. Chem. Bull., Int. Ed., 52
(2003) 2539-2554].
20) I.A. Tikhonova, F.M. Dolgushin, K.I. Tugashov, O.G. Ellert, V.M. Novotortsev, G.G. Furin,
M.Yu. Antipin, V.B. Shur. Crown Compounds for Anions. Sandwich Complexes of Cyclic
Trimeric Perfluoro-o-phenylenemercury with Hexacyanoferrate(III) and Nitroprusside Anions.
J. Organomet. Chem., 689 (2004) 82-87.
21) V.B. Shur, I.A. Tikhonova. Anticrowns. In: “Encyclopedia of Supramolecular Chemistry”
(Eds. J.L. Atwood and J.W. Steed), Marcel Dekker, Inc., New York, 2004, 68-75.
22) I.A. Tikhonova, F.M. Dolgushin, K.I. Tugashov, P.V. Petrovskii, M.Yu. Antipin, V.B. Shur.
Binding of Ferrocene by Cyclic Trimeric Perfluoro-o-phenylenemercury. Synthesis and
Structure of the First Double-Decker Sandwich Complex of a Sandwich. Izv. Akad. Nauk, Ser.
Khim., (2004) 2754-2756 [Russ. Chem. Bull., Int. Ed., 53 (2004) 2871-2873].
23) A.P. Zaraisky, O.I. Kachurin, L.I. Velichko, I.A. Tikhonova, G.G. Furin, V.B. Shur. Cyclic
Trimeric Perfluoro-o-phenylenemercury: A Highly Efficient Phase Transfer Catalyst for
Nitration of Aromatic Substrates with Dilute Nitric Acid. J. Molec. Cat. A: Chem., 231 (2005)
103-111.
24) Z. Yan, I.A. Tikhonova, Z. Zhou, V.B. Shur, Y. Wu. Cyclic Trimeric Perfluoro-o-phenylenemer-
cury as a New Ionophore for Quaternary Ammonium Cation Selective Membrane Electrodes.
Anal. Lett., 38 (2005) 377-388.
25) I.A. Tikhonova, F.M. Dolgushin, A.A. Yakovenko, K.I. Tugashov, P.V. Petrovskii, G.G. Furin,
V.B. Shur. Binding of Dienophiles by Macrocyclic Multidentate Lewis Acids. Synthesis and X-
Ray Crystal Structure Determination of Unusual Complexes of Cyclic Trimeric Perfluoro-o-
phenylenemercury with p-Benzoquinone and Maleic Anhydride. Organometallics, 24 (2005)
3395-3400.
26) I.A. Tikhonova, K.I. Tugashov, F.M. Dolgushin, A.A. Yakovenko, B.N. Strunin, P.V. Petrovskii,
G.G. Furin, V.B. Shur. Coordination Chemistry of Anticrowns: Synthesis and X-Ray Crystal
Structure Determination of the Polydecker Sandwich Complexes of Cyclic Trimeric Perfluoro-o-
phenylenemercury with Azulene and 6-(N,N-Dimethylamino)pentafulvene. Inorg. Chim. Acta,
359 (2006) 2728-2735.
27) I.A. Tikhonova, A.A. Yakovenko, K.I. Tugashov, F.M. Dolgushin, V.V. Novikov, M.Yu. Antipin,
V.B. Shur. Selective Binding of the Keto Form of Acetylacetone by Cyclic Trimeric Perfluoro-o-
15
phenylenemercury. Quantitative Shift of the Keto-Enol Equilibrium in Acetylacetone Toward its
Keto Form Stabilized by the Complexation. Organometallics, 25 (2006) 6155-6158.
28) I.A. Tikhonova, K.I. Tugashov, F.M. Dolgushin, A.A. Yakovenko, P.V. Petrovskii, G.G. Furin,
A.P. Zaraisky, V.B. Shur. Coordination Chemistry of Anticrowns: Complexation of Cyclic
Trimeric Perfluoro-o-phenylenemercury with Nitro Compounds. J. Organomet. Chem., 692
(2007) 953-962.
29) I.A. Tikhonova, K.I. Tugashov, F.M. Dolgushin, P.V. Petrovskii, V.B. Shur. Complexation of
[9]Thiacrown-3 and 1,3,5-Trithiane with Cyclic Trimeric Perfluoro-o-phenylenemercury.
Synthesis and Structures of the First Complexes of Crown Compounds with an Anticrown.
Organometallics, 26 (2007) 5193-5198.
30) V.N. Tsupreva, O.A. Filippov, F.M. Dolgushin, K.I. Tugashov, A.I. Krylova, V.I. Bragin,
I.A. Tikhonova, V.B. Shur, L.M. Epstein, E.S. Shubina. Coordination Chemistry of Anticrowns.
Complexation of Cyclic Trimeric Perfluoro-o-phenylenemercury (o-C6F4Hg)3 with the
Cyanoborohydride Anion [H3BCN]− and Triethylamineborane Et3NBH3. Izv. Akad. Nauk, Ser.
Khim., (2008) 2489-2496 [Russ. Chem. Bull., Int. Ed.., 57 (2008) 2540-2547].
31) I.A. Tikhonova, K.I. Tugashov, F.M. Dolgushin, A.A. Korlyukov, P.V. Petrovskii,
Z.S. Klemenkova, V.B. Shur. Coordination Chemistry of Mercury-Containing Anticrowns.
Synthesis and Structures of the Complexes of Cyclic Trimeric Perfluoro-o-phenylenemercury
with Ethanol, THF and Bis-2,2-Tetrahydrofuryl Peroxide. J. Organomet. Chem., 694 (2009)
2604-2610.
32) I.A. Tikhonova, D.A. Gribanyov, K.I. Tugashov, F.M. Dolgushin, A.F. Smol’yakov,
A.S. Peregudov, Z.S. Klemenkova, V.B. Shur. Complexation of [12]Crown-4, [18]Crown-6 and
1,3,5-Trioxane with Cyclic Trimeric Perfluoro-o-phenylenemercury. Synthesis and Structures of
the First Complexes of Crown Ethers with an Anticrown. Organometallics, 28 (2009) 6567-
6573.
33) I.A. Tikhonova, D.A. Gribanyov, K.I. Tugashov, F.M. Dolgushin, A.S. Peregudov,
D.Yu. Antonov, V.I. Rosenberg, V.B. Shur. Coordination Chemistry of Mercury-Containung
Anticrowns. Synthesis and Structure of an Unusual Discrete, Double-Decker Sandwich Complex
of Cyclic Trimeric Perfluoro-o-phenylenemercury with an Aromatic Hydrocarbon.
J. Organomet. Chem., 695 (2010) 1949-1952.
34) I.A. Tikhonova, D.A. Gribanyov, K.I. Tugashov, F.M. Dolgushin, A.F. Smol’yakov,
A.S. Peregudov, Z.S. Klemenkova, V.B. Shur. Coordination Chemistry of Mercury-Containing
Anticrowns. Self-Assembly of Unusual Supramolecular Aggregates in the Interaction of the
Three-Mercury Anticrown (o-C6F4Hg)3 with Crown Ethers in the Presence of Neutral
Monodentate Oxygenous Lewis Bases. Arkivoc, (2011) in press.
16
Some Other Publications
1) M.Kh. Grigoryan, I.S. Kolomnikov, E.G. Berkovich, T.V. Lysyak, V.B. Shur, M.E. Vol’pin.
Reaction of Carbon Dioxide with Ditolyltitanocenes under Thermal Decomposition Conditions.
Izv. Akad. Nauk, Ser. Khim., (1978) 1177-1180 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 27
(1978) 1024-1026 (Engl. Transl.)].
2) V.B. Shur, S.M. Yunusov, E.I. Mysov, A.A. Belyi, M.E. Vol’pin. Synthesis of Unsolvated
Organopotassium and Organosodium Compounds by the Reaction of Solid Unsaturated
Hydrocarbons with Fused Potassium and Sodium. Izv. Akad. Nauk, Ser. Khim., (1982) 2638
[Bull. Acad. Sci. USSR, Div. Chem. Sci., 31 (1982) 2336 (Engl. Transl.)].
3) V.S. Lenenko, A.I. Yanovsky, Yu.T. Struchkov, V.B. Shur, M.E. Vol’pin. Synthesis and
Structure of Dihydridodichlorotetrakis(dimethylphenylphosphine)molybdenum. Koord. Khim.,
12 (1986) 636-642.
4) E.Yu. Baukova, L.M. Bronshtein, P.M. Valetskii, M.G. Ezernitskaya, B.V. Lokshin,
L.I. Strunkina, O.A. Mikhailova, M.H. Minacheva, V.B. Shur. Interaction of Zirconocene
Hydrides with Polybutadiene. Synthesis of Zirconium-Containing Polymers. Metalloorg. Khim.,
5 (1992) 1386-1390 [Organomet. Chem. USSR, 5 (1992) 680-683 (Engl. Transl.)].
5) O.A. Mikhailova, M.H. Minacheva, V.V. Burlakov, V.B. Shur, A.P. Pisarevsky, A.I. Yanovsky,
Yu.T. Struchkov. Trimeric Bis(cyclopentadienyl)oxozirconium(IV) Benzene Solvate. Acta
Cryst., Sect. C, 49 (1993) 1345-1347.
6) I.I. Tverdokhlebova, V.V. Ivanov, S.A. Bashkirova, V.M. Men’shov, T.A. Larina,
E.A. Chernyshov, I.A. Tikhonova, V.B. Shur. Synthesis of Monomodal Polysilane by the Würts
Reaction in the Presence of Mercury. Vysokomol. Soedin., Ser. B, 37 (1995) 1227.
7) I.I. Tverdokhlebova, V.V. Ivanov, T.A. Larina, V.M. Men’shov, I.A. Tikhonova,
S.A. Bashkirova, G.G. Furin, V.B. Shur. Effect of Mercury and its Derivatives on the Synthesis
of Polysilanes by the Würts Reaction. Vysokomol. Soedin., Ser. B, 38 (1996) 1601-1604
[Polymer Science, Ser. B, 38 (1996) 356-360].
8) O.A. Mikhailova, M.Kh. Minacheva, Z.S. Klemenkova, V.B. Shur. Interaction of Carbon
Dioxide with Zirconocene and Hafnocene Dihydrides. Izv. Akad. Nauk, Ser. Khim., (1996) 2366-
2368 [Russ. Chem. Bull., Int. Ed., 45 (1996) 2248-2250].
In Memory of Mark Vol’pin
1) I. Levitin, V. Shur. Mark Vol’pin (Obituary). Inorg. Chim. Acta, 254 (1997) 203-207.
2) I. Levitin, V. Shur. Mark Vol’pin: Glorious Path in Science. Inorg. Chim. Acta, 280 (1998) xv-
xix.
Selected Publications in 2008-2010
17
1) V.V. Burlakov, V.S. Bogdanov, K.A. Lyssenko, P.V. Petrovskii, T. Beweries, P. Arndt,
U. Rosenthal, V.B. Shur. First structurally characterized five-membered hafnacyclocumulene
Сp2Hf(4-tBuС4tBu). Izv. Akad. Nauk, Ser. Khim., (2008) 1294-1295 [Russ. Chem. Bull., Int. Ed.,
57 (2008) 1319-1320].
2) V.N. Tsupreva, O.A. Filippov, F.M. Dolgushin, K.I. Tugashov, A.I.Krylova, V.I.Bragin,
I.A. Tikhonova, V.B. Shur, L.M. Epstein, E.S. Shubina. Coordination Chemistry of Anticrowns.
Complexation of Cyclic Trimeric Perfluoro-o-phenylenemercury (o-C6F4Hg)3 with the
Cyanoborohydride Anion [H3BCN]− and Triethylamineborane Et3NBH3. Izv. Akad. Nauk, Ser.
Khim., (2008) 2489-2496 [Russ. Chem. Bull., Int. Ed.., 57 (2008) 2540-2547].
3) S. Rummel, M.A. Ilatovskaya, S.M. Yunusov, E.S. Kalyuzhnaya, V.B. Shur. Activation
of C–H Bonds of Hydrocarbons by the ArH–Alkali Metal Systems in THF (ArH – Naphthalene,
Biphenyl, Anthracene, Phenanthrene, trans-Stilbene, Pyrene). Alkylation of Naphthalene and
Toluene with Ethene. J. Organomet. Chem., 694 (2009) 1459-1466.
4) S. Rummel, S.M. Yunusov, E.S. Kalyuzhnaya, V.B. Shur. Synergistic Effects of Alkali
Metals in the Alkylation of Naphthalene and Toluene with Ethene in the ArH–Alkali Metal
Systems in THF (ArH – Naphthalene, Phenanthrene). J. Organomet. Chem., 694 (2009) 1467-
1472.
5) V.V. Burlakov, T. Beweries, V.S. Bogdanov, P. Arndt, W. Baumann, P.V. Petrovskii,
A. Spannenberg, K.A. Lyssenko, V.B. Shur, U. Rosenthal. Synthesis and Isolation of Di-n-
butylhafnocene and Its Application as a Versatile Starting Material for the Synthesis of New
Hafnacycles. Organometallics, 28 (2009) 2864-2870.
6) I.A. Tikhonova, K.I. Tugashov, F.M. Dolgushin, A.A. Korlyukov, P.V. Petrovskii,
Z.S. Klemenkova, V.B. Shur. Coordination Chemistry of Mercury-Containing Anticrowns.
Synthesis and Structures of the Complexes of Cyclic Trimeric Perfluoro-o-phenylenemercury
with Ethanol, THF and Bis-2,2-Tetrahydrofuryl Peroxide. J. Organomet. Chem., 694 (2009)
2604-2610.
7) I.A. Tikhonova, D.A. Gribanyov, K.I. Tugashov, F.M. Dolgushin, A.F. Smol’yakov,
A.S. Peregudov, Z.S. Klemenkova, V.B. Shur. Complexation of [12]Crown-4, [18]Crown-6 and
1,3,5-Trioxane with Cyclic Trimeric Perfluoro-o-phenylenemercury. Synthesis and Structures of
the First Complexes of Crown Ethers with an Anticrown. Organometallics, 28 (2009) 6567-
6573.
8) V.V. Burlakov, V.S. Bogdanov, K.A. Lyssenko, L.I. Strunkina, M.Kh. Minacheva,
B.N. Strunin, U. Rosenthal, V.B. Shur. Formation of the five-membered zirconacyclocumulene
Cp2Zr(η4-ButC4But) and the binuclear zirconocene butatrienyl complex
Cp2(Bun)Zr(ButC4But)Zr(Bun)Cp2 in the reaction of the Negishi reagent with 1,4-di(tert-
18
butyl)butadiyne. Izv. Akad. Nauk, Ser. Khim., (2010) 653-655 [Russ. Chem. Bull., Int. Ed., 59
(2010) 668-670].
9) V.V. Burlakov, T. Beweries, K. Kaleta, V.S. Bogdanov, P. Arndt, W. Baumann,
A. Spannenberg, V.B. Shur, U. Rosenthal. Reactions of the Five-Membered
Hafnacyclocumulene Cp2Hf(4-t-Bu-C4-t-Bu) with the Lewis Acids
Tris(pentafluorophenyl)borane and Diisobutylaluminum Hydride. Organometallics, 29 (2010)
2367-2371.
10) I.A. Tikhonova, D.A. Gribanyov, K.I. Tugashov, F.M. Dolgushin, A.S. Peregudov,
D.Yu. Antonov, V.I. Rosenberg, V.B. Shur. Coordination Chemistry of Mercury-Containung
Anticrowns. Synthesis and Structure of an Unusual Discrete, Double-Decker Sandwich Complex
of Cyclic Trimeric Perfluoro-o-phenylenemercury with an Aromatic Hydrocarbon. J.
Organomet. Chem., 695 (2010) 1949-1952.
19