lihmds = lithium hexamethyldisilazide = lin(sime 3)2

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Nicolaou, K. C.; Tria, G. Scott; Edmonds, David J.; Kar, Moumita. Total Syntheses of ()-Platencin and (-)-Platencin. Journal of the American Chemical Society (2009), 131(43), 15909-15917.

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Nicolaou , K. C.; Tria , G. Scott; Edmonds, David J.; Kar , Moumita . Total Syntheses of ()- Platencin and (-)- Platencin . Journal of the American Chemical Society (2009), 131(43), 15909-15917. LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2. PMB = p-methoxybenzyl. - PowerPoint PPT Presentation

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Page 1: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2

Nicolaou, K. C.; Tria, G. Scott; Edmonds, David J.; Kar, Moumita. Total Syntheses of ()-Platencin and (-)-Platencin. Journal of the American Chemical Society (2009), 131(43), 15909-15917.

Page 2: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2
Page 3: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2

LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe3)2

Page 4: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2

PMB = p-methoxybenzyl

Page 5: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2
Page 6: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2
Page 7: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2
Page 8: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2
Page 9: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2
Page 10: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2
Page 11: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2
Page 12: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2
Page 13: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2

NMO = N-methylmorpholine-N-OxideTPAP = Tetrapropylammonium perruthenate

Page 14: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2
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Page 16: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2

Bn = Benzyl = CH2PH

TBS = tert-butyldimethylsilyl

Tf = Trifluoromethanesulfonyl

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Page 18: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2
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Page 20: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2

SEM-Cl =

Page 21: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2

TIPS = triisopropylsilyl

Page 22: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2
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Page 27: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2

TASF = Tris(dimethylamino)sulfonium difluorotrimethylsilicate

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Page 29: LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2