msds 03-03-007 p 150-q a

Safety Data SheetProduct name : PETREPAR 150 - QCod. CEPSA : 77759

Date of issue:Version:

22/03/2011.

2

PETREPAR 150 - QProduct name :

Highly pure normal paraffin cut with an average of 12 carbon atoms per molecule.Other means ofidentificationChemical formula CH3-(CH2)n-CH3 (n=10 - 13)

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1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

Liquid.Product type :

Email : [email protected]

CAS number : Not available.

Product description :

1.2 Relevant identified uses of the substance or mixture and uses advised against

SECTION 1: Identification of the substance/mixture and of the company/undertaking

REACH Registrationnumber

EC number : 929-018-5

Product code : 77759

1.4 Emergency telephone numberTelephone number :

Hours of operation :

+34 956 582341

01-2119475608-26-0002

(24h)

Chemical family : Alkane.

Supplier : CEPSA QUIMICA, S.A.Avda. del Partenn, 12ES-28042 MADRID (ESPAA)

Emergency telephonenumber

: Fbrica de Puente Mayorga - Cdiz+34 956 582 200

:

Hydrocarbons, C10-C13, n-alkanes,



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:Other hazards which do notresult in classification

Not available.

Prevention :Precautionary statements

Response :

Storage :Disposal :

IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOTinduce vomiting.Store locked up.Not applicable.

Supplemental labelelements

Containers to be fitted withchild-resistant fastenings

Not applicable.

Tactile warning of danger Not applicable.

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: Repeated exposure may cause skin dryness or cracking.

Special packaging requirements

Hazardous ingredients : Hydrocarbons, C10-C13, n-alkanes,



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Get medical attention immediately. Call a poison center or physician. Wash outmouth with water. Remove dentures if any. Remove victim to fresh air and keep atrest in a position comfortable for breathing. If material has been swallowed and theexposed person is conscious, give small quantities of water to drink. Stop if theexposed person feels sick as vomiting may be dangerous. Aspiration hazard ifswallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomitingoccurs, the head should be kept low so that vomit does not enter the lungs. Nevergive anything by mouth to an unconscious person. If unconscious, place in recoveryposition and get medical attention immediately. Maintain an open airway. Loosentight clothing such as a collar, tie, belt or waistband.

Skin contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lowereyelids. Check for and remove any contact lenses. Continue to rinse for at least 10minutes. Get medical attention.

Wash skin thoroughly with soap and water or use recognized skin cleanser. Removecontaminated clothing and shoes. Get medical attention if symptoms occur. Washclothing before reuse. Clean shoes thoroughly before reuse.

4.1 Description of first aid measures

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Ifnot breathing, if breathing is irregular or if respiratory arrest occurs, provide artificialrespiration or oxygen by trained personnel. It may be dangerous to the personproviding aid to give mouth-to-mouth resuscitation. Get medical attention if adversehealth effects persist or are severe. If unconscious, place in recovery position and getmedical attention immediately. Maintain an open airway. Loosen tight clothing suchas a collar, tie, belt or waistband.

Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if largequantities have been ingested or inhaled.

Ingestion

Inhalation

Eye contact

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Specific treatments

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It maybe dangerous to the person providing aid to give mouth-to-mouth resuscitation.

SECTION 4: First aid measures

4.2 Most important symptoms and effects, both acute and delayedPotential acute health effects

Inhalation : No known significant effects or critical hazards.

May be fatal if swallowed and enters airways.:IngestionSkin contact : Defatting to the skin. May cause skin dryness and irritation.

No known significant effects or critical hazards.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No specific data.

Adverse symptoms may include the following:nausea or vomiting

Adverse symptoms may include the following:irritationdrynesscracking

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Eye contact : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed

No specific treatment.:

Date of issue/Date of revision : 22/03/2011.CEPSA QUIMICA, S.A.Avda. del Partenn, 12ES-28042 MADRID (ESPAA)

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Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining.

Hazardous thermaldecomposition products

Hazards from thesubstance or mixture

Decomposition products may include the following materials:carbon dioxidecarbon monoxide

In a fire or if heated, a pressure increase will occur and the container may burst.

Fire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode. Clothing for fire-fighters (including helmets, protective boots and gloves)conforming to European standard EN 469 will provide a basic level of protection forchemical incidents.

Special protectiveequipment for fire-fighters

Use dry chemical, CO2, water spray (fog) or foam.5.1 Extinguishing media

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Do not use water jet.

Suitable :

Not suitable :

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefightersSpecial protective actionsfor fire-fighters

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Fire-fighting measures : Shut off all ignition sources. If fire cannot be extinguished, withdraw from area andallow the fire to burn. Use water spray to keep fire-exposed containers cool.

6.2 Environmentalprecautions

Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Prevent entry into sewers, water courses, basements or confined areas.Wash spillages into an effluent treatment plant or proceed as follows. Contain andcollect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculiteor diatomaceous earth and place in container for disposal according to localregulations (see section 13). Dispose of via a licensed waste disposal contractor.Contaminated absorbent material may pose the same hazard as the spilled product.Note: see section 1 for emergency contact information and section 13 for waste

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).

Large spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mopup if water-soluble. Alternatively, or if water-insoluble, absorb with an inert drymaterial and place in an appropriate waste disposal container. Dispose of via alicensed waste disposal contractor.

Small spill :6.3 Methods and materials for containment and cleaning up

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency proceduresFor non-emergencypersonnel

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For emergency responders :

No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Avoid breathing vapor ormist. Provide adequate ventilation. Wear appropriate respirator when ventilation isinadequate. Put on appropriate personal protective equipment.If specialised clothing is required to deal with the spillage, take note of any informationin Section 8 on suitable and unsuitable materials. See also the information in "Fornon-emergency personnel".

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2disposal.

6.4 Reference to othersections

See Section 1 for emergency contact information.See Section 8 for information on appropriate personal protective equipment.See Section 13 for additional waste treatment information.

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Store in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatiblematerials (see section 10) and food and drink. Store locked up. Keep containertightly closed and sealed until ready for use. Containers that have been opened mustbe carefully resealed and kept upright to prevent leakage. Do not store in unlabeledcontainers. Use appropriate containment to avoid environmental contamination.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).

7.1 Precautions for safe handlingProtective measures :

Advice on generaloccupational hygiene

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7.2 Conditions for safestorage, including anyincompatibilities

7.3 Specific end use(s)Recommendations :

:Industrial sector specificsolutions

Not available.Not available.

Put on appropriate personal protective equipment (see Section 8). Do not swallow.Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in theoriginal container or an approved alternative made from a compatible material, kepttightly closed when not in use. Empty containers retain product residue and can behazardous. Do not reuse container.Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipmentbefore entering eating areas. See also Section 8 for additional information on hygienemeasures.

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Product/ingredient name Exposure limit values

Recommended monitoringprocedures

Occupational exposure limits

If this product contains ingredients with exposure limits, personal, workplaceatmosphere or biological monitoring may be required to determine the effectivenessof the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European Standard EN 689 formethods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardoussubstances.

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n-paraffins INSHT (Spain, 5/2010). Absorbed through skin. TWA: 5 mg/m 8 hour(s). Form: mist STEL: 10 mg/m 15 minute(s). Form: mist

No DELs available.

Predicted effect concentrations

SECTION 8: Exposure controls/personal protection


8.1 Control parameters

Derived effect levels


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Hand protection

Use a properly fitted, particulate filter respirator complying with an approved standardif a risk assessment indicates this is necessary.

Chemical-resistant, impervious gloves complying with an approved standard shouldbe worn at all times when handling chemical products if a risk assessment indicatesthis is necessary. >8 hours (breakthrough time): Chemical-resistant, imperviousgloves complying with an approved standard should be worn at all times whenhandling chemical products if a risk assessment indicates this is necessary. Nitrilegloves. polyethylene (PE) Viton PVA gloves. PVC gloves.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. Recommended: Splash goggles.

Eye/face protection

Respiratory protection :

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Skin protection

Chemical-resistant protective suit.:

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the process equipmentwill be necessary to reduce emissions to acceptable levels.

Appropriate engineeringcontrols

: No special ventilation requirements. Good general ventilation should be sufficient tocontrol worker exposure to airborne contaminants. If this product containsingredients with exposure limits, use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure below any recommended orstatutory limits.

Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations andsafety showers are close to the workstation location.

8.2 Exposure controls

Hygiene measures :

No PECs available.

Individual protection measures

Body protection :Other skin protection Suitable protective footwear.

155 to 244C

Physical state

Melting point/freezing pointInitial boiling point and boilingrange

Vapor pressureVapor density

Liquid.

-23C

5,7 [Air = 1]0,044 kPa [20C]

Characteristic.Odor

pH

Clear sparkling liquid. Colorless.Color

Evaporation rate Not available.Flash point Open cup: 74C

Lower: 0,6%Upper: 7%

Not available.Not available.Odor threshold

Upper/lower flammability orexplosive limits

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9.1 Information on basic physical and chemical propertiesAppearance

Burning time Not applicable.Burning rate Not applicable.

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SECTION 9: Physical and chemical properties

Flammability (solid, gas) : Not available.


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22/03/2011.

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Solubility(ies)

0,73 to 0,8

Insoluble in the following materials: cold water and hot water.

Auto-ignition temperature >200C

Not available.

>1

Viscosity Kinematic: 0,0166 cm2/s [ASTM D 445]Kinematic (40C): 0,014 cm2/s [ASTM D 445]

Partition coefficient: n-octanol/water

Explosive properties

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Not available.Oxidizing properties :

9.2 Other information

Decomposition temperature : Not applicable.

No additional information.

:Density 0,74 to 0,76 g/cm3 [15C]

10.6 Hazardousdecomposition products

10.4 Conditions to avoid No specific data.

Under normal conditions of storage and use, hazardous decomposition productsshould not be produced.

The product is stable.10.2 Chemical stability

No specific data.

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10.5 Incompatible materials :

10.3 Possibility of hazardousreactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Acute toxicity

Hydrocarbons, C10-C13, n-alkanes, 5000 mg/kg -

LD50 Oral Rat >5000 mg/kg -

Product/ingredient name Result Species Dose Exposure

Conclusion/Summary : Not available.Irritation/Corrosion




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Potential acute health effects

Inhalation : No known significant effects or critical hazards.

May be fatal if swallowed and enters airways.:IngestionSkin contact : Defatting to the skin. May cause skin dryness and irritation.

No known significant effects or critical hazards.:Eye contact

CarcinogenicityConclusion/Summary : No known significant effects or critical hazards.

Mutagenicity




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Potential chronic health effects

Prolonged or repeated contact can defat the skin and lead to irritation, crackingand/or dermatitis.

General :

No known significant effects or critical hazards.Carcinogenicity :No known significant effects or critical hazards.Mutagenicity :No known significant effects or critical hazards.Teratogenicity :

Hydrocarbons, C10-C13, n-alkanes, 5000 mg/kg 90 days

Sub-chronic NOAELInhalation Vapor

Rat >10400 mg/m3 90 days

Product/ingredient name Result Species Dose Exposure

Conclusion/Summary : Not available.

Developmental effects : No known significant effects or critical hazards.Fertility effects : No known significant effects or critical hazards.

Skin contact

Ingestion Adverse symptoms may include the following:nausea or vomiting

Adverse symptoms may include the following:irritationdrynesscracking

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Delayed and immediate effects and also chronic effects from short and long term exposureShort term exposure

Long term exposure

Potential immediate effects

Potential delayed effects :

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Potential immediate effectsPotential delayed effects :

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Other information :

Not available.

Not available.

Not available.Not available.

Not available.

Product/ingredient name Aquatic half-life Photolysis BiodegradabilityHydrocarbons, C10-C13, n-alkanes, 10000 mg/l Crustaceans - Arcadia tonsa 48 hoursChronic NOEC 0,361 mg/l Crustaceans 21 daysChronic NOEC 0,139 mg/l Fish 28 days

Product/ingredient name SpeciesResult Exposure

Conclusion/Summary : Not available.

12.2 Persistence and degradability

Hydrocarbons, C10-C13, n-alkanes, 96% eliminado en 24 horas

SECTION 12: Ecological information


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Mobility Not available.:

LogPow BCF Potential

12.3 Bioaccumulative potential

12.6 Other adverse effects No known significant effects or critical hazards.

Product/ingredient nameHydrocarbons, C10-C13, n-alkanes, 1 - low

PBT : No.PBT: Specified

vPvB : No.vPvB: Specified

12.4 Mobility in soil

Soil/water partitioncoefficient (KOC)

Not available.:

12.5 Results of PBT and vPvB assessment

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The classification of the product may meet the criteria for a hazardous waste.Hazardous waste :

:Methods of disposal

SECTION 13: Disposal considerations


13.1 Waste treatment methodsProduct

PackagingMethods of disposal :

Special precautions :

The generation of waste should be avoided or minimized wherever possible. Wastepackaging should be recycled. Incineration or landfill should only be consideredwhen recycling is not feasible.This material and its container must be disposed of in a safe way. Care should betaken when handling emptied containers that have not been cleaned or rinsed out.Empty containers or liners may retain some product residues. Avoid dispersal ofspilled material and runoff and contact with soil, waterways, drains and sewers.

The generation of waste should be avoided or minimized wherever possible.Significant quantities of waste product residues should not be disposed of via the foulsewer but processed in a suitable effluent treatment plant. Dispose of surplus andnon-recyclable products via a licensed waste disposal contractor. Disposal of thisproduct, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and anyregional local authority requirements.

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Not regulated.

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Not regulated.Not regulated. Not regulated.

SECTION 14: Transport information

ADR/RID IMDG IATA

14.1 UN number

14.2 UN propershipping name

ADN/ADNR


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14.3 Transporthazard class(es)

14.4 Packing group

Additionalinformation

14.5 Environmentalhazards

14.6 Specialprecautions foruser

14.7 Transport in bulkaccording to Annex II ofMARPOL 73/78 and the IBCCode

No. No. No. No.

Not available. Not available. Not available. Not available.

n-ALKANES (C10+)Proper shipping name :Ship type : 3

Pollution category : Y

Other EU regulations

Not applicable.Annex XVII - Restrictions onthe manufacture, placingon the market and use ofcertain dangeroussubstances, mixtures andarticles

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Europe inventory : This material is listed or exempted.Black List Chemicals : Not listedPriority List Chemicals : Not listedIntegrated pollutionprevention and control list(IPPC) - Air

: Not listed

Integrated pollutionprevention and control list(IPPC) - Water

: Not listed

Chemical WeaponsConvention List Schedule IChemicals

: Not listed

Chemical WeaponsConvention List Schedule IIChemicals

: Not listed

Chemical WeaponsConvention List Schedule IIIChemicals

: Not listed

International regulations

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixtureEU Regulation (EC) No. 1907/2006 (REACH)Annex XIV - List of substances subject to authorizationSubstances of very high concernNone of the components are listed.


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215.2 Chemical SafetyAssessment

Complete.:

22/03/2011.Date of printingDate of issue/ Date ofrevision

Version

To the best of our knowledge, the information contained herein is accurate. However, neither the above-namedsupplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that exist.

Notice to reader

Date of previous issue

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Full text of abbreviated Rphrases

: R65- Harmful: may cause lung damage if swallowed.R66- Repeated exposure may cause skin dryness or cracking.Xn - Harmful:Full text of classifications

[DSD/DPD]

Indicates information that has changed from previously issued version.

22/03/2011.

No previous validation.

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SECTION 16: Other information

Full text of abbreviated Hstatements

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Abbreviations and acronyms : ATE = Acute Toxicity EstimateCLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.1272/2008]DNEL = Derived No Effect LevelEUH statement = CLP-specific Hazard statementPNEC = Predicted No Effect ConcentrationRRN = REACH Registration Number

Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification JustificationAsp. Tox. 1, H304 Expert judgment

Full text of classifications[CLP/GHS]

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H304 May be fatal if swallowed and enters airways.

Asp. Tox. 1, H304 ASPIRATION HAZARD - Category 1


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msds 03-03-007 p 150-q a

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