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    WELCOMEINSTRUCTOR NAME: Dean Frakes

    UNDERSTANDING THE MATERIAL SAFETY DATA SHEET

    SAFETY BY DESIGN TRAINING

    REGULATORY STANDARD

    29 CFR 1910.1200

    29 CFR 1926.59

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    BASIS FOR THIS COURSE

    32,000,000 Workers Exposed to Chemicals Daily 575,000+ Existing Chemical Products

    Bhopal India Tragedy December 1984

    OSHA Hazard Communication Standard

    Standard: 29 CFR 1910.1200 Establishes Worker Right-to-Know Program

    Requires Written Hazcom Program

    Requires Use of Material Safety Data Sheets

    Requires Use of Labels and Other Warnings Requires Chemicals to Be Listed

    Requires Hazards and Precautions Be Explained

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    Any Employee Potentially Exposed to Workplace Chemicals.

    Safety Committees.

    Department Managers.

    First Line Supervisors.

    Accident Investigation Team Members.

    COURSE ATTENDEES

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    COURSE OBJECTIVES

    Explain the Use of the Material Safety Data Sheet (MSDS)

    Discuss the Hazard Communication Standard

    Introduce 29 CFR 1910.1200 (General Industry)

    Introduce 29 CFR 1926.59 (Construction)

    Discuss the Requirements of the MSDS

    Discuss the Elements of the MSDS

    Discuss the Format of the MSDS

    Discuss the Need for the MSDS

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    STUDENT LEARNING OUTCOMES

    Interpret and Understand the Material Safety Data Sheet

    Understand the Need for an MSDS

    Understand the Different Sections of the MSDS

    Know the Different OSHA Regulations Governing the MSDS

    Understand the Access Requirements of MSDS

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    29CFR - SAFETY AND HEALTH STANDARDS

    1910 - INDUSTRIAL SAFETY

    1200 - HAZARD COMMUNICATION

    GENERAL INDUSTRY REGULATION

    DepartmentofLabor

    PARTS 1900 TO 1910

    Revised as ofJan 1, 2002

    29 CFR

    NationalArchives

    andRecords

    Administration

    29CFR

    U.S. Department of Labor

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    A Document That Contains Information on the Potential Health Effects of

    Exposure and How to Work Safely With a Specific Chemical Product.

    It Contains Hazard Evaluations on the Use, Storage, Handling and Emergency

    Procedures Related to The Product.

    The MSDS Contains Much More Information Than Provided on the Label and

    Is Prepared by the Supplier.

    It Tells What the Hazards of the Product Are, How to Use the Product Safely,What to Expect If the Recommendations Are Not Followed, What to Do If

    Accidents Occur, and How to Recognize Symptoms of Overexposure.

    WHAT IS A MATERIAL DATA SAFETY SHEET:

    BASICS OF THE MSDS

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    Every Material That Has a Possible Health Hazard, Whether Short Term Or

    Long Term to Any Employee Must Have an Accompanying MSDS That Is

    Specific to Each Individual Product or Material.

    Both the Product Name and Supplier on the MSDS Must Match the Material in

    Use.

    WHY DO I NEED A MATERIAL DATA SAFETY SHEET:

    BASICS OF THE MSDS

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    The American National Standards Institute (ANSI) Has Developed a New

    Standard (Z400.1-1993) to Assist With the Format and Preparation of Material

    Safety Data Sheets (MSDS).

    The Purpose of The Standard Is to Provide Information in a ConsistentManner and to Make It Easier to Find Information Regardless of the Supplier

    of the MSDS.

    The Occupational Safety and Health Administration (OSHA) Only Requires

    the Elements Stated in 29CFR 1910.1200(g) But Supports the 16 SectionFormat Recommended by ANSI.

    WHAT FORMAT IS REQUIRED FOR THE MSDS:

    BASICS OF THE MSDS

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    Section 1: Chemical Product and Company IdentificationSection 2: Composition, Information or IngredientsSection 3: Hazard IdentificationSection 4: First Aid Measures

    Section 5: Fire-Fighting MeasuresSection 6: Accidental Release MeasuresSection 7: Handling and StorageSection 8: Exposure Controls and Personal ProtectionSection 9: Physical and Chemical PropertiesSection 10: Stability and Reactivity

    Section 11: Toxicological InformationSection 12: Ecological InformationSection 13: Disposal ConsiderationsSection 14: Transport InformationSection 15: Regulatory InformationSection 16: Other Information

    WHAT INFORMATION IS INCLUDED IN THE MSDS:

    ELEMENTS OF THE MSDS

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    SECTIONS OF THE MSDS:

    ELEMENTS OF THE MSDS

    Section 1: Chemical Product and Company IdentificationLinks the chemical name on the label to the MSDS. The MSDS also liststhe name, address and the phone number of the company, manufactureror distributor who provides the chemical.

    Section 2: Composition, Information or IngredientsIdentifies all the hazardous ingredients of the material. This section mayalso include Permissible Exposure Limits.

    Section 3: Hazard IdentificationDiscusses the health effects one may encounter when exposed to the

    material. Describes the appearance of the material, the potential healtheffects and symptoms associated with exposure, routes of entry, targetorgans that could be affected, and so on.

    Section 4: First Aid MeasuresDescribes possible first aid procedures for each route of entry.

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    SECTIONS OF THE MSDS:

    ELEMENTS OF THE MSDS

    Section 5: Fire-Fighting MeasuresDescribes information on the fire and explosive properties of the material,extinguishing mediums, and general fire-fighting instructions.

    Section 6: Accidental Release Measures

    Provides information on how to respond when a material spills, leaks or isreleased into the air. This information may include how to contain a spillor the types of equipment that may be needed for protection.

    Section 7: Handling and StorageDiscusses information on handling and storage of the material. Topics

    that could be described are: general warnings to prevent overexposure,handling procedures, and hygiene instructions to prevent exposure.

    Section 8: Exposure Controls and Personal ProtectionDiscusses engineering controls and personal protective equipment thatwould help reduce exposure to the material.

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    SECTIONS OF THE MSDS:

    ELEMENTS OF THE MSDS

    Section 9: Physical and Chemical PropertiesIncludes information about the physical and chemical properties. Suchas; appearance, odor, physical state, pH, vapor pressure, vapor density,boiling point, freezing/melting point, specific gravity and others.

    Section 10: Stability and ReactivityRequires that potentially hazardous chemical reactions be identified. Itaddresses chemical stability, conditions to avoid, incompatibility withother materials, hazardous decomposition and hazardous polymerization.

    Section 11: Toxicological Information

    Discusses data used to determine the hazards that are given in Section3, "Hazard Identification."

    Section 12: Ecological InformationProvides Information to help determine the environmental impact shouldthe material ever be released into the environment.

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    SECTIONS OF THE MSDS:

    ELEMENTS OF THE MSDS

    Section 13: Disposal ConsiderationsProvides important information that may be helpful in the proper disposalof the material. Can cover disposal, recycling and reclamation.

    Section 14: Transport Information

    Provides basic shipping information. The shipping information caninclude: the hazardous materials description, hazard class and theidentification number (UN or NA numbers).

    Section 15: Regulatory InformationDiscusses information on the regulations under which the material falls.

    Examples include: OSHA, TSCA, CERCLA, SARA Title III, and others.

    Section 16: Other InformationDiscusses any other important information concerning the material. Thisinformation can include: hazard ratings, preparation and revisions of theMSDS, and label information.

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    By Law, Employers Are Required to Make MSD Sheets Available to

    Employees and Their Agents (Doctors, Lawyers Etc.).

    MSD Sheets Are Required to Placed in a Location Within the Facility That Is

    Convenient for Employees to Access.

    While You May Not Arbitrarily Remove MSD Sheets From Viewing Binders,

    You Can Request a Copy of Any MSDS You May Require.

    Remember, MDS Sheets Are for Your Protection and Information. You AreEncouraged to Read and Understand the Safety Requirements of The

    Chemicals Your Job Requires You to Work With.

    WHERE CAN I FIND AN MSDS:

    USING THE MSDS

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    Traditionally the Intended Readers of the MSDS Were Industrial Hygienists

    and Safety Professionals. Now the Readership Also Includes Employers,

    Workers, Supervisors, Nurses, Doctors, and Emergency Responders.

    Its Getting Better, Now Days, To Ensure That MSDS Users Can Quickly Find

    the Information That They Need, the Information Is Provided in an Easy-to-

    read Format and Written in a Clear, Precise, Standardized and

    Understandable Manner. If Yours Isnt, Try Getting an Updated MSDS.

    There Are Some Sections That Are Harder to Understand Than Others. If YouDont Understand Something, Ask Your Supervisor. Also, You Can Always

    Contact the Manufacturer for Clarification. Remember, If Youre Having

    Trouble Understanding It, Others Probably Are To.

    WHY IS MY MSDS HARD TO UNDERSTAND:

    USING THE MSDS

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    Not Necessarily. A Lot of Health Hazard Information, for Example, Is Written in

    General Terms.

    Your Health and Safety Specialist, Occupational Health Nurse or Family Doctor

    Should Be Able to Help You Find More Information If Needed.

    The Supplier of the MSDS Can Also Be Consulted for Additional Information.

    IS ALL THE INFORMATION I NEED ON THE MSDS:

    USING THE MSDS

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    Always Be Familiar With the Hazards of a Product BEFOREYou Start Using It.

    Use It To Determine Personal Protective Equipment Requirements.

    You Should Look at a MSDS, Match the Name of the Chemical on YourContainer to the One on the MSDS, Know the Hazards, Understand Safe

    Handling and Storage Instructions, As Well As Understand What to Do in an

    Emergency.

    WHEN WOULD I USE AN MSDS:

    USING THE MSDS

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    MSD Sheets Look Different Because Only the Content of the MSDS Is

    Specified by Law.

    The Format Is Left up to the Supplier Who Writes the MSDS.

    Some Suppliers Put More Details in Than What Is Required.

    The Information for the Basic Categories in the MSDS As a Minimum, Must

    Always Be in Accordance With the Requirements Outlined in

    29CFR1910.1200. The Sixteen Section Format Recommended by ANSI Is The Typical Format

    Used in the United States.

    WHY DO SOME MSDS LOOK DIFFERENT:

    USING THE MSDS