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Polyurethane Binders And Applications Page 1 Dow Polyurethanes

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Page 2: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

2

Agenda

Dow Polyurethane System – Industrial Market portfolio

Binder and Applications

Isocyanate Prepolymers & Rubber Crumb Binding Applications

Binder Grades

DOW CONFIDENTIAL - Do not share without permission

DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

Page 3: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

BINDERS

Page 3

Moisture Cured Isocyanate Prepolymers

DOW CONFIDENTIAL - Do not share without permission

DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

Page 4: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

Moulded Tiles Auto Sound Dampening

PIP Playground PIP Track

Load Stabilization

Flooring Underlay

Industrial Binder

In-situ Binder

A full range of prepolymers designed for:

• Rubber industrial molding and in-situ applications ( Pour In Place Playgrounds, PIP athletic tracks)

•Flexible foam rebonding to create carpet cushion, underlayer, composites for automotive industry

Binders(Prepolymers)

DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

Page 5: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

APPLICATIONS

Page 5

RUBBER MOULDING (PREFABRICATED) :

• Absorbing / safety tiles for playgrounds

• Road building accessories

• Gymnasium flooring

• Vibration dampening mats / items for railroad tracks

• Flexible under layer mats for indoor / outdoor sport flooring

• Construction proofing mats (protection and sound proofing)

IN-situ” RUBBER REBONDING / OUTSIDE SPORT FLOORING:(Certification as per EN 1177 (2008) or ASTM F2373)

•Playground areas

• Bottom layer for athletic tracks

• Top or bottom layer for tennis courts

• Multi-purpose outside facilities

•Gymnasium Flooring

“In-situ” but inside rubber rebonding activity:

•Functional, decorative floor coverings

DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

Page 6: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

Outdoor Sports

IAAF certified athletic tracks use Dow binders

Other sports includes like Tennis, Badminton,

Basketball, etc.

Somaiya College, Mumbai

Patiala

Indian Air Force Station, DelhiMCA Recreation Centre, BKCCricket box, Thane

Certification of surfaces as per EN or ASTM standards from

IAAF accredited labs

Page 7: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

• Polyurethane for Binders Application

• Binders : Polyurethane polymer that binds, rubber, wood, foam, cork etc…

• Rubber is the major constituent; PU is ~ 20 %

Voramer Binders

Page 7

Polyurethane

Prepolymer

Rubber crumbs

+

DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

Page 8: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

• Characteristics:

• Rubber » SBR recycled rubber

» EPDM

• PU» Voramer MDI & MDI/ TDI prepolymers

» Controlled Reactivity Prepolymers

(CRPs)

Voramer Binders for Molded application

Page 8DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

Page 9: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

• Composition

• Rubber = 90-95 %

• Binder = 5 – 10 %

• Water = 0.1 – 0.5 %

Voramer Binders for Sheet application

Page 9

Mixing

2 m

Compression ~

12 hours

Peeling into mats

DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

Page 10: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

Page 10

Pour in Place Technology

DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

The fall height below which a life-threateninghead injury would not be expected to occur.

minimum required surface thickness to prevent injury

Page 11: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

• VR:

• Virgin rubber is sustainable

• ultimate design, performance and function

• SBR

• Styrene –butadiene-Rubber (Synthetic rubber copolymer)

• Used in car tires & truck tires

• EPDM

• Ethylene propylene diene Monomer

• Peroxide is used in cross linking

• Used in vibrators, seals, insulation etc application

• TPV

• TPV Elastoprene is a mixture of polypropylene and vulcanized EPDM Rubber

• Recyclable and reusable.

Rubber Crumbs and PU

Page 11DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

Page 12: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

• Characteristics:

• Rubber : SBR, EPDM, TPV

• PU : Aromatic MDI &MDI/ TDI Voramer Prepolymers

• % NCO : ~ 10

• Viscosity @ 20°C: 2000 – 6000 mPa.s

• Reactivity (slab preparation)

• Ratio, binder/ granules/ water spraying : 100/ 9/ 0.5

• dimension of slab : 30/30/4cm

• density: 800 g/l

• granules :SBR 1-3 mm

• Temperature: 125 – 130 oC, 5 -6 mins.

Voramer Binders

Page 12DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

Page 13: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

IN-situ” RUBBER REBONDING & MOULDING

•Absorbing / safety tiles for playgrounds

• Road building accessories

• Vibration dampening mats / items for railroad tracks

• Flexible under layer mats for indoor / outdoor sport flooring

• Construction proofing mats (protection and sound proofing)

DOW CONFIDENTIAL - Do not share without permission

DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

Product name Physical Characteristics Description

Typical viscosity, mPa.s % NCO

Voramer MR 1016 Isocyanate 3200 10.5 Standard binder for carpets manufacture for

Building Industry or Sport Flooring /

Processable with water or vapour

Voramer RR 1008/1009 Isocyanate 2800 - 4200 10 -13 Clear binder for PIP and moulded binding

Voramer MR 1073 Isocyanate 5000 8.3 Red coloured binder

Voramer MR 1072 Isocyanate 5000 8.3 Green coloured binder

PIP Playground Moulded Tiles

Page 13

Page 14: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

Rubber crumbs Rubber crumbs +PU prepolymer

Completed Playground

Troweling

Pour in Place Application

Page 14DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

Page 15: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

• Top layer Binder (EPDM)

• Resilience

• High performance

• Tensile strength

• Taber resistance

• Bottom layer Binder ( NR)

• Cushion layer

• Fibers or granules

• Challenges :

• On site application

• Specification

• Regulatory requirements

Pour in Place Construction

Page 15DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

Page 16: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

Page 16

Pour in Place Technology

Balanced reactivity profile: long open time (good process ability)

whilst providing fast and reliable cure

Fast return-back – to service times

Versatility of the binder towards outside climatic conditions

Less seasonality of the application job

Enhanced green strength and increased elasticity performance

Key Technical Requirements for PU Binder

→→ Fulfill all these requirements with Dow’s Controlled Reactivity

Prepolymers

DOW @ Rising Kerala Expo: Polyurethane Binders and Applications

Page 17: Polyurethane Binders And Applications...DOW @ Rising Kerala Expo: Polyurethane Binders and Applications Product name Physical Characteristics Description Typical viscosity, mPa.s %

Questions?