Recent Reviews. 91compiled by Veronica M. Cornel

Department of Chemistry, Reedley College, 995 Reed Ave, Reedley, California 93654

Reviews are listed in order of appearance in the sources indicated. In multidisciplinary review journals, only those reviews which fall within the scope of this Journal are included. Sources are listed alphabetically in three categories: regularly issued review journals and series volumes, contributed volumes, and other monographs. Titles are numbered serially, and these numbers are used for reference in the index.

Major English-language sources of critical reviews are covered. Encyclopedic treatises, annual surveys such as Specialist Periodical Reports, and compilations of symposia proceedings are omitted.

This installment of Recent Reviews covers principally the middle part of the 2008 literature.

Supporting Information Available: A file containing this Recent Review compilation in Microsoft Word and the data in plain text that can be imported into Endnote (using Refer style) and Reference Manager databases. This material is available free of charge via the Internet at http://pubs.acs.org.

Regularly Issued Journals and Series Volumes

Accounts of Chemical Research

1. Hussain, M. M.; Walsh, P. J. Tandem Reactions for Streamlining Synthesis: Enantio- and Diastereoselective One-Pot Generation of Functionalized Epoxy Alcohols. 2008, 41(8), 883-93.

2. Wang, W.; Hunger, M. Reactivity of Surface Alkoxy Species on Acidic Zeolite Catalysts. 2008, 41(8), 895-904.

3. Cossio, F. P.; Arrieta, A.; Sierra, M. A. The Mechanism of the Ketene-Imine (Staudinger) Reaction in Its Centennial: Still an Unsolved Problem? 2008, 41(8), 925-36.

4. Sun, X.-L.; Tang, Y. Ylide-Initiated Michael Addition-Cyclization Reactions beyond Cyclopropanes. 2008, 41(8), 937-48.

5. Montagnon, T.; Tofi, M.; Vassilikogiannakis, G. Using Singlet Oxygen to Synthesize Polyoxygenated Natural Products from Furans. 2008, 41(8), 1001-11.

6. Lewis, J. C.; Bergman, R. G.; Ellman, J. A. Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C-H Bond Activation. 2008, 41(8), 1013-25.

7. Schmidt, R. R.; Vankar, Y. D. 2-Nitroglycals as Powerful Glycosyl Donors: Application in the Synthesis of Biologically Important Molecules. 2008, 41(8), 1059-73.

8. Hanessian, S.; Auzzas, L. The Practice of Ring Constraint in Peptidomimetics Using Bicyclic and Polycyclic Amino Acids. 2008, 41(10), 1241-51.

9. Gong, B. Hollow Crescents, Helices, and Macrocycles from Enforced Folding and Folding-Assisted Macrocyclization. 2008, 41(10), 1376-86.

10. Li, X.; Wu, Y.-D.; Yang, D. -Aminoxy Acids: New Possibilities from Foldamers to Anion Receptors and Channels. 2008, 41(10), 1428-38.

Advanced Synthesis and Catalysis

11. Ciriminna, R.; Carraro, M. L.; Campestrini, S.; Pagliaro, M. Heterogeneous Catalysis for Fine Chemicals in Dense Phase Carbon Dioxide. 2008, 350(2), 221-6.

Advances in Physical Organic Chemistry

12. Glover, S. A. N-Acyloxy-N-alkoxyamides-Structure, Properties, Reactivity and Biological Activity. 2008, (42), 35-123.

Aldrichimica Acta

13. Trost, B. M.; Fandrick, D. R. Palladium-Catalyzed Dynamic Kinetic Asymmetric Allylic Alkylation with the DPPBA Ligands. 2007, 40(3), 59-72.

14. Ooi, T.; Maruoka, K. Development and Applications of C2-Symmetric, Chiral, Phase-Transfer Catalysts. 2007, 40(3), 77-86.

15. Adair, G.; Mukherjee, S.; List, B. TRIP-a Powerful Bronsted Acid Catalyst for Asymmetric Synthesis. 2008, 41(2), 31-9.

Angewandte Chemie, International Edition in English

16. Enthaler, S.; Junge, K.; Beller, M. Sustainable Metal Catalysis with Iron: From Rust to a Rising Star? 2008, 47(18), 3317-21.

17. Prokopcova, H.; Kappe, C. O. Copper-Catalyzed C-C Coupling of Thiol Esters and Boronic Acids under Aerobic Conditions. 2008, 47(20), 3674-6.

18. Berkessel, A. Asymmetric Epoxidation of Olefins with Hydrogen Peroxide : Catalysis by an Aspartate-Containing Tripeptide. 2008, 47(20), 3677-9.

19. Kaufhold, O.; Hahn, F. E. Carbodicarbenes: Divalent Carbon(0) Compounds. 2008, 47(22), 4057-61.

20. Wills, M. Asymmetric Catalysis Using Air: Clean Kinetic Resolution of Secondary Alcohols. 2008, 47(23), 4264-7.

21. Michelet, V.; Toullec, P. Y.; Genet, J.-P. Cycloisomerization of 1,n-Enynes : Challenging Metal-Catalyzed Rearrangements and Mechanistic Insights. 2008, 47(23), 4268-315.

22. Defieber, C.; Grutzmacher, H.; Carreira, E. M. Chiral Olefins as Steering Ligands in Asymmetric Catalysis. 2008, 47(24), 4482-502.

23. Alcaide, B.; Almendros, P. Organocatalytic Reactions with Acetaldehyde. 2008, 47(25), 4632-4.

24. Dondoni, A.; Massi, A. Asymmetric Organocatalysis: From Infancy to Adolescence. 2008, 47(25), 4638-60.

25. Arndt, H.-D.; Riedrich, M. Synthesis of Marine Alkaloids from the Oroidin Family. 2008, 47(26), 4785-8.

26. Galli, C.; Gentili, P.; Lanzalunga, O. Hydrogen Abstraction and Electron Transfer with Aminoxyl Radicals: Synthetic and Mechanistic Issues. 2008, 47(26), 4790-6.

27. Meyer, G. Superbulky Ligands and Trapped Electrons: New Perspectives in Divalent Lanthanide Chemistry. 2008, 47(27), 4962-4.

28. Rosenthal, U. Discovering Chemical Terra Incognita: Unusual Metallacycles and Their Reactions. 2008, 47(28), 5118-21.

29. Butenschoen, H. Seven-Membered Rings by Cyclization at Transition Metals: [4+3], [3+2+2], [5+2]. 2008, 47(29), 5287-90.

30. Grela, K. The Joy and Challenge of Small Rings Metathesis. 2008, 47(30), 5504-7.

31. Duschek, A.; Kirsch, S. F. Combining the Concepts: Dual Catalysis with Carbophilic Lewis Acids. 2008, 47(31), 5703-5.

32. Metrangolo, P.; Meyer, F.; Pilati, T.; Resnati, G.; Terraneo, G. Halogen Bonding in Supramolecular Chemistry. 2008, 47(33), 6114-27.

33. Melchiorre, P.; Marigo, M.; Carlone, A.; Bartoli, G. Asymmetric Aminocatalysis Gold Rush in Organic Chemistry. 2008, 47(33), 6138-71.

34. Surry, D. S.; Buchwald, S. L. Biaryl Phosphane Ligands in Palladium-Catalyzed Amination. 2008, 47(34), 6338-61.

35. Carmona, E.; Galindo, A. Direct Bonds between Metal Atoms: Zn, Cd, and Hg Compounds with Metal-Metal Bonds. 2008, 47(35), 6526-36.

36. Hashmi, A. S. K. "High Noon" in Gold Catalysis: Carbene versus Carbocation Intermediates. 2008, 47(36), 6754-6.

37. Zehnacker, A.; Suhm, M. A. Chirality Recognition between Neutral Molecules in the Gas Phase. 2008, 47(37), 6970-92.

The Chemical Record

38. Nishiyama, H.; Ito, J.-I. Bis(oxazolinyl)phenyl Transition Metal Complexes: Synthesis, Asymmetric Catalysis, and Coordination Chemistry. 2007, 7(3), 159-66.

39. Lacour, J.; Linder, D. Hexacoordinated Phosphates: How to Teach Old Chiral Anions New Asymmetric Tricks. 2007, 7(5), 275-85.

40. Patil, M. L.; Sasai, H. Recent Developments on Chiral Ionic Liquids. Design, Synthesis, and Applications. 2008, 8(2), 98-108.

Chemical Reviews

41. Jutand, A. Contribution of Electrochemistry to Organometallic Catalysis. 2008, 108(7), 2300-47.

42. Alexakis, A.; Backvall, J. E.; Krause, N.; Pamies, O.; Dieguez, M. Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions. 2008, 108(8), 2796-823.

43. Harutyunyan, S. R.; den Hartog, T.; Geurts, K.; Minnaard, A. J.; Feringa, B. L. Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents. 2008, 108(8), 2824-52.

44. Shibasaki, M.; Kanai, M. Asymmetric Synthesis of Tertiary Alcohols and -Tertiary Amines via Cu-Catalyzed C-C Bond Formation to Ketones and Ketimines. 2008, 108(8), 2853-73.

45. Yamada, K.-i.; Tomioka, K. Copper-Catalyzed Asymmetric Alkylation of Imines with Dialkylzinc and Related Reactions. 2008, 108(8), 2874-86.

46. Stanley, L. M.; Sibi, M. P. Enantioselective Copper-Catalyzed 1,3-Dipolar Cycloadditions. 2008, 108(8), 2887-902.

47. Poulsen, T. B.; Jorgensen, K. A. Catalytic Asymmetric Friedel-Crafts Alkylation Reactions-Copper Showed the Way. 2008, 108(8), 2903-15.

48. Deutsch, C.; Krause, N.; Lipshutz, B. H. CuH-Catalyzed Reactions. 2008, 108(8), 2916-27.

49. Breit, B.; Schmidt, Y. Directed Reactions of Organocopper Reagents. 2008, 108(8), 2928-51.

50. Meldal, M.; Tornoe, C. W. Cu-Catalyzed Azide-Alkyne Cycloaddition. 2008, 108(8), 2952-3015.

51. Matsuo, Y.; Nakamura, E. Selective Multiaddition of Organocopper Reagents to Fullerenes. 2008, 108(8), 3016-28.

52. Gschwind, R. M. Organocuprates and Diamagnetic Copper Complexes: Structures and NMR Spectroscopic Structure Elucidation in Solution. 2008, 108(8), 3029-53.

53. Evano, G.; Blanchard, N.; Toumi, M. Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis. 2008, 108(8), 3054-131.

54. Naodovic, M.; Yamamoto, H. Asymmetric Silver-Catalyzed Reactions. 2008, 108(8), 3132-48.

55. Weibel, J.-M.; Blanc, A.; Pale, P. Ag-Mediated Reactions: Coupling and Heterocyclization Reactions. 2008, 108(8), 3149-73.

56. Alvarez-Corral, M.; Munoz-Dorado, M.; Rodriguez-Garcia, I. Silver-Mediated Synthesis of Heterocycles. 2008, 108(8), 3174-98.

57. Yamamoto, Y. Silver-Catalyzed Csp-H and Csp-Si Bond Transformations and Related Processes. 2008, 108(8), 3199-222.

58. Rasika Dias, H. V.; Lovely, C. J. Carbonyl and Olefin Adducts of Coinage Metals Supported by Poly(pyrazolyl)borate and Poly(pyrazolyl)alkane Ligands and Silver Mediated Atom Transfer Reactions. 2008, 108(8), 3223-38.

59. Li, Z.; Brouwer, C.; He, C. Gold-Catalyzed Organic Transformations. 2008, 108(8), 3239-65.

60. Arcadi, A. Alternative Synthetic Methods through New Developments in Catalysis by Gold. 2008, 108(8), 3266-325.

61. Jimenez-Nunez, E.; Echavarren, A. M. Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective. 2008, 108(8), 3326-50.

62. Gorin, D. J.; Sherry, B. D.; Toste, F. D. Ligand Effects in Homogeneous Au Catalysis. 2008, 108(8), 3351-78.

63. Diaz-Requejo, M. M.; Perez, P. J. Coinage Metal Catalyzed C-H Bond Functionalization of Hydrocarbons. 2008, 108(8), 3379-94.

64. Patil, N. T.; Yamamoto, Y. Coinage Metal-Assisted Synthesis of Heterocycles. 2008, 108(8), 3395-442.

65. Mueller, T. E.; Hultzsch, K. C.; Yus, M.; Foubelo, F.; Tada, M. Hydroamination: Direct Addition of Amines to Alkenes and Alkynes. 2008, 108(9), 3795-892.

66. Wong, O. A.; Shi, Y. Organocatalytic Oxidation. Asymmetric Epoxidation of Olefins Catalyzed by Chiral Ketones and Iminium Salts. 2008, 108(9), 3958-87.

67. Brandi, A.; Cicchi, S.; Cordero, F. M. Novel Syntheses of Azetidines and Azetidinones. 2008, 108(9), 3988-4035.

68. Ren, T. Peripheral Covalent Modification of Inorganic and Organometallic Compounds through C-C Bond Formation Reactions. 2008, 108(10), 4185-207.

Chemical Society Reviews

69. Correa, A.; Garcia Mancheno, O.; Bolm, C. Iron-Catalyzed Carbon-Heteroatom and Heteroatom-Heteroatom Bond Forming Processes. 2008, 37(6), 1108-17.

70. Ye, L.-W.; Zhou, J.; Tang, Y. Phosphine-Triggered Synthesis of Functionalized Cyclic Compounds. 2008, 37(6), 1140-52.

71. Dickstein, J. S.; Kozlowski, M. C. Organometal Additions to -Imino Esters: N-Alkylation via Umpolung. 2008, 37(6), 1166-73.

72. Nising, C. F.; Braese, S. The Oxa-Michael Reaction: From Recent Developments to Applications in Natural Product Synthesis. 2008, 37(6), 1218-28.

73. Greenberg, S.; Stephan, D. W. Stoichiometric and Catalytic Activation of P-H and P-P Bonds. 2008, 37(8), 1482-9.

74. Murahashi, S.-I.; Zhang, D. Ruthenium-Catalyzed Biomimetic Oxidation in Organic Synthesis Inspired by Cytochrome P-450. 2008, 37(8), 1490-501.

75. Mlynarski, J.; Paradowska, J. Catalytic Asymmetric Aldol Reactions in Aqueous Media. 2008, 37(8), 1502-11.

76. Perez, E. M.; Martin, N. Curves Ahead: Molecular Receptors for Fullerenes Based on Concave-Convex Complementarity. 2008, 37(8), 1512-9.

77. Polshettiwar, V.; Varma, R. S. Aqueous Microwave Chemistry. A Clean and Green Synthetic Tool for Rapid Drug Discovery. 2008, 37(8), 1546-57.

78. Zard, S. Z. Recent Progress in the Generation and Use of Nitrogen-Centered Radicals. 2008, 37(8), 1603-18.

79. Peng, X.; Pan, Q.; Rempel, G. L. Bimetallic Dendrimer-Encapsulated Nanoparticles as Catalysts. A Review of the Research Advances. 2008, 37(8), 1619-28.

80. Lee, V. Y.; Sekiguchi, A. Cyclic Polyenes of Heavy Group 14 Elements: New Generation Ligands for Transition-Metal Complexes. 2008, 37(8), 1652-65.

81. Gruttadauria, M.; Giacalone, F.; Noto, R. Supported Proline and Proline-Derivatives as Recyclable Organocatalysts. 2008, 37(8), 1666-88.

82. Lence, E.; Castedo, L.; Gonzalez-Bello, C. The Conformational Rigidity of Butane-1,2-Diacetals as a Powerful Synthetic Tool. 2008, 37(8), 1689-708.

83. Smits, R.; Cadicamo, C. D.; Burger, K.; Koksch, B. Synthetic Strategies to -Trifluoromethyl and -Difluoromethyl Substituted -Amino Acids. 2008, 37(8), 1727-39.

Chemistry - A European Journal

84. Widenhoefer, R. A. Recent Developments in Enantioselective Gold(I) Catalysis. 2008, 14(18), 5382-91.

85. Donohoe, T. J.; Fishlock, L. P.; Procopiou, P. A. Ring-closing Metathesis: Novel Routes to Aromatic Heterocycles. 2008, 14(19), 5716-26.

86. Yamazaki, S. Efficient Synthesis of Methylenetetrahydrofurans and Methylenepyrrolidines by Formal [3+2] Cycloadditions of Propargyl Substrates. 2008, 14(20), 6026-36.

87. Ekoue-Kovi, K.; Wolf, C. One-Pot Oxidative Esterification and Amidation of Aldehydes. 2008, 14(21), 6302-15.

88. Hill, M. D.; Movassaghi, M. New Strategies for the Synthesis of Pyrimidine Derivatives. 2008, 14(23), 6836-44.

Chemistry of Heterocyclic Compounds

89. Lebedev, A. Preparation of Chiral 4-Substituted -Lactams and the Corresponding -Aminobutyric Acids. 2007, 43(6), 673-84.

90. Selina, A. A.; Karlov, S. S.; Lermontova, E. K.; Zaitseva, G. S. Metallocanes of Group 14 Elements 2. Derivatives of Tin (Review). 2007, 43(7), 813-34.

91. Britsun, V. N.; Lozinskii, M. O. Cycloacylation of Thioamides and Their Derivatives by Compounds Containing an Activated Multiple Bond. 2007, 43(9), 1083-1110.

92. Potkin, V. I.; Kaberdin, R. V. Benzazetines and Their Derivatives. 2007, 43(12), 1493-511.

CHEMTRACTS: Organic Chemistry

93. Li, F.; Reiser, O. Recent Advances in Catalytic Intramolecular Cyclopropanation Reactions. 2006, 19(10), 391-401.

Collection of Czechoslovak Chemical Communications

94. Hajicek, J. A Review on Recent Developments in Syntheses of the Post-Secodine Indole Alkaloids. Part II: Modified Alkaloid Types. 2007, 72(7), 821-898.

Coordination Chemistry Reviews

95. Che, C.-M.; Ho, C.-M.; Huang, J.-S. Metal-Carbon Multiple Bonded Complexes. 2007, 251(17-20), 2145-66.

96. Leung, W.-H.; Zhang, Q.-F.; Yi, X.-Y. Recent Developments in the Coordination and Organometallic Chemistry of Klaeui Oxygen Tripodal Ligands. 2007, 251(17-20), 2266-79.

97. Weber, L. Recent Developments in the Chemistry of 1,3,2-Diazaborolines (2,3-Dihydro-1H-1,3,2-diazaboroles). 2008, 252(1+2), 1-31.

98. Bruneau, C.; Renaud, J.-L.; Jerphagnon, T. Synthesis of -Amino Acid Derivatives via Enantioselective Hydrogenation of -Substituted--(acylamino)acrylates. 2008, 252(5-7), 532-44.

Current Medicinal Chemistry

99. Saladino, R.; Gualandi, G.; Farina, A.; Crestini, C.; Nencioni, L.; Palamara, A. T. Advances and Challenges in the Synthesis of Highly Oxidized Natural Phenols with Antiviral, Antioxidant and Cytotoxic Activities. 2008, 15(15), 1500-19.

Current Organic Chemistry

100. Wendt, O. F. Transmetallation Reactions Involving Group 10 Metals. 2007, 11(16), 1417-33.

101. Rivas, J. C. M. Cooperation of Metals and Hydrogen Bonding Groups in Metal-Promoted Reactions. 2007, 11(16), 1434-49.

102. Shapiro, P. J. The Elusive Chemistry of Bent-Sandwich Chromocene. 2007, 11(17), 1482-90.

103. Lee, H. M.; Lee, C.-C.; Cheng, P.-Y. Recent Development of Functionalized N-Heterocyclic Carbene Ligands: Coordination Chemistry and Catalytic Applications. 2007, 11(17), 1491-524.

104. Necas, D.; Kotora, M. Rhodium-Catalyzed C-C Bond Cleavage Reactions. 2007, 11(17), 1566-91.

105. Shirini, F.; Zolfigol, M. A.; Salehi, P.; Abedini, M. Applications of Some Metal Hydrogen Sulfates in Organic Transformations. 2008, 12(3), 183-202.

Current Organic Synthesis

106. Ennis, E.; Handy, S. T. The Chemistry of the C-2 Position of Imidazolium Room Temperature Ionic Liquids. 2007, 4(4), 381-9.

European Journal of Organic Chemistry

107. Schall, A.; Reiser, O. Synthesis of Biologically Active Guaianolides with a Trans-Annulated Lactone Moiety. 2008, (14), 2353-64.

108. Bica, K.; Gaertner, P. Applications of Chiral Ionic Liquids. 2008, (19), 3235-50.

109. Calaza, M. I.; Cativiela, C. Stereoselective Synthesis of Quaternary Proline Analogues. 2008, (20), 3427-48.

110. Coudray, L.; Montchamp, J.-L. Recent Developments in the Addition of Phosphinylidene-Containing Compounds to Unactivated Unsaturated Hydrocarbons: Phosphorus-Carbon Bond Formation by Hydrophosphinylation and Related Processes. 2008, (21), 3601-13.

111. Falciola, C. A.; Alexakis, A. Copper-Catalyzed Asymmetric Allylic Alkylation. 2008, (22), 3765-80.

112. Schmidt, A.; Beutler, A.; Snovydovych, B. Recent Advances in the Chemistry

of Indazoles. 2008, (24), 4073-95.113. Ochiai, M.; Miyamoto, K. Catalytic Version of and Reuse in Hypervalent

Organo-3- and -5-Iodane Oxidation. 2008, (25), 4229-39.

Heterocycles

114. Abe, H.; Harayama, T. Palladium-Mediated Intramolecular Biaryl Coupling Reaction for Natural Product Synthesis. 2008, 75(6), 1305-20.

115. Levai, A. Synthesis and Chemical Transformations of Benzoxazepines. 2008, 75(9), 2155-85.

116. Ueda, T.; Kotsuki, H. Heteropoly Acids: Green Chemical Catalysts in Organic Synthesis. 2008, 76(1), 73-97.

Journal of the Brazilian Chemical Society

117. Singh, R.; Sharma, M.; Mamgain, R.; Rawat, D. S. Ionic Liquids: A Versatile Medium for Palladium-Catalyzed Reactions. 2008, 19(3), 357-79.

Journal of Combinatorial Chemistry

118. Testero, S. A.; Mata, E. G. Prospect of Metal-Catalyzed C-C Forming Cross-Coupling Reactions in Modern Solid-Phase Organic Synthesis. 2008, 10(4), 487-497.

Journal of Fluorine Chemistry

119. Uneyama, K. Fluoride Ion-Catalyzed Desilylative-Defluorination for Synthetic Organic Chemistry. 2007, 128(10), 1087-90.

120. Guo, Y.; Shreeve, J. n. M. Difluoromethylene Compounds as Precursors to Ketones, Carboxylic Acids, Esters, Amides and Carbonates. 2007, 128(10), 1280-5.

121. Tsuda, T.; Hagiwara, R. Chemistry in Heterocyclic Ammonium Fluorohydrogenate Room-Temperature Ionic Liquid. 2008, 129(1), 4-13.

122. Briza, T.; Kral, V.; Martasek, P.; Kaplanek, R. Electrophilic Polyfluoroalkylating Agents Based on Sulfonate Esters. 2008, 129(4), 235-47.

Journal of Heterocyclic Chemistry

123. Riabova, O. B.; Makarov, V. A.; Granik, V. G.; Parkanyi, C. Transformations of 5-Nitropyrimidines. 2008, 45(3), 621-43.

124. Hamama, W. S.; Ismail, M. A.; Shaaban, S.; Zoorob, H. H. Progress in the Chemistry of 4-Thiazolidinones. 2008, 45(4), 939-56.

Journal of Physical Organic Chemistry

125. Tantillo, D. J. Recent Excursions to the Borderlands Between the Realms of Concerted and Stepwise: Carbocation Cascades in Natural Products Biosynthesis. 2008, 21(7-8), 561-70.

126. Mayr, H.; Ofial, A. R. Do General Nucleophilicity Scales Exist? 2008, 21(7-8), 584-95.

127. Kaupp, G. Waste-Free Synthesis and Production All Across Chemistry with the Benefit of Self-Assembled Crystal Packings. 2008, 21(7-8), 630-43.

128. Bumpus, J. A.; Willoughby, P. H. On the Heat of Formation of Nitromethane. 2008, 21(9), 747-57.

129. Poutsma, M. L. Comparison of Mechanistic Models for Correlation of Activation Energies of Liquid-Phase Addition of Carbon-Centered Radicals to Terminal Olefins. 2008, 21(9), 758-82.

Natural Product Reports

130. Lachia, M.; Moody, C. J. The Synthetic Challenge of Diazonamide A, A Macrocyclic Indole Bis-Oxazole Marine Natural Product. 2008, 25(2), 227-53.

131. Sperry, J.; Bachu, P.; Brimble, M. A. Pyranonaphthoquinones-Isolation, Biological Activity and Synthesis. 2008, 25(2), 376-400.

132. Connolly, J. D.; Hill, R. A. Triterpenoids. 2008, 25(4), 794-830.

Organic Preparations and Procedures International

133. Bujnowski, K.; Adamczyk, A.; Synoradzki, L. o-Aminomethyl Derivatives of Phenols. Part 2. Benzoxazines and Dibenzylamines: Properties, Structure, Synthesis and Purification.  2007, 39(5), 417-46.

134. Wladislaw, B.; Marzorati, L.; Di Vitta, C. Sulfanylation Reactions of Carbonyl Compounds and Carboxylic Acid Derivatives Employing Sulfur Electrophiles. A Review.  2007, 39(5), 447,449-94.

135. Soldevilla, A.; Sampedro, D. Preparation and Application of Cyclopropylimines in Organic Synthesis. A Review.  2007, 39(6), 561-90.

136. Nakano, K.; Kotsuki, H.; Ichikawa, Y. Synthesis of Conagenin and -Methylserine.  2008, 40(1), 67-91.

Polymer

137. Newkome, G. R.; Shreiner, C. D. Poly(amidoamine), Polypropylenimine, and Related Dendrimers and Dendrons Possessing Different 1 --> 2 Branching Motifs: An Overview of the Divergent Procedures. 2008, 49(1), 1-173.

Progress in Nuclear Magnetic Resonance Spectroscopy

138. Elyashberg, M. E.; Williams, A. J.; Martin, G. E. Computer-Assisted Structure Verification and Elucidation Tools in NMR-Based Structure Elucidation. 2008, 53(1-2), 1-104.

Pure and Applied Chemistry

139. Shintani, R.; Murakami, M.; Hayashi, T. -Methylidene--Valerolactones as a

Coupling Partner for Cycloaddition: Palladium-Catalyzed [4+3] Cycloaddition with Nitrones. 2008, 80(5), 1135-40.

140. Chowdhury, S. A.; Scott, J. L.; MacFarlane, D. R. Ternary Mixtures of Phosphonium Ionic Liquids + Organic Solvents + Water. 2008, 80(6), 1325-35.

141. Kalchenko, V. I. Calixarene Receptors of Environmentally Hazardous and Biorelevant Molecules and Ions. 2008, 80(7), 1449-58.

142. Reymond, S.; Ferrie, L.; Guerinot, A.; Capdevielle, P.; Cossy, J. Chemoselective Reactions: Toward the Synthesis of Biologically Active Natural Products with Anticancer Activities. 2008, 80(8), 1683-91.

143. Goossen, L. J.; Goossen, K.; Rodriguez, N.; Blanchot, M.; Linder, C.; Zimmermann, B. New Catalytic Transformations of Carboxylic Acids. 2008, 80(8), 1725-33.

144. Paterson, I.; Findlay, A. D. Total Synthesis of Cytotoxic Marine Macrolides: Callipeltoside A, Aurisides A and B, and Dolastatin 19. 2008, 80(8), 1773-82.

145. Diaz, M. D.; Fernandez-Alonso, M. d. C.; Cuevas, G.; Canada, F. J.; Jimenez-Barbero, J. On the Role of Aromatic-Sugar Interactions in the Molecular Recognition of Carbohydrates: A 3D View by Using NMR. 2008, 80(8), 1827-35.

146. Nawrot, B.; Rebowska, B.; Michalak, O.; Bulkowski, M.; Blaziak, D.; Guga, P.; Stec, W. J. 1,3,2-Oxathiaphospholane Approach to the Synthesis of P-Chiral Stereo-Defined Analogs of Oligonucleotides and Biologically Relevant Nucleoside Polyphosphates. 2008, 80(8), 1859-71.

Research on Chemical Intermediates

147. Bejblova, M.; Zilkova, N.; Cejka, J. Transformations of Aromatic Hydrocarbons over Zeolites. 2008, 34(5-7), 439-54.

Russian Chemical Reviews

148. Matern, A. I.; Charushin, V. N.; Chupakhin, O. N. Progress in the Studies of Oxidation of Dihydropyridines and Their Analogues. 2007, 76(1), 23-40.

149. Goryunkov, A. A.; Ovchinnikova, N. S.; Trushkov, I. V.; Yurovskaya, M. A. Synthesis, Structures and Reactivity of Polyhalo[60]Fullerenes. 2007, 76(4), 289-312.

150. Voronkov, M. G.; Trofimova, O. M.; Bolgova, Y. I.; Chernov, N. F. Hypervalent Silicon-Containing Organosilicon Derivatives of Nitrogen Heterocycles. 2007, 76(9), 825-45.

151. Levitsky, M. M.; Zavin, B. G.; Bilyachenko, A. N. Chemistry of Metallasiloxanes. Current Trends and New Concepts. 2007, 76(9), 847-66.

Russian Journal of Organic Chemistry

152. Kas'yan, L. I.; Kas'yan, A. O.; Golodaeva, E. A. Methods and Mechanisms of Epoxy Compounds Reduction. 2008, 44(2), 153-83.

Science

153. Savee, J. D.; Mozhayskiy, V. A.; Mann, J. E.; Krylov, A. I.; Continetti, R. E. The Role of Excited-State Topology in Three-Body Dissociation of sym-Triazine. 2008, 321(5890), 826-30.

154. Douvris, C.; Ozerov, O. V. Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts. 2008, 321(5893), 1188-90.

Synlett

155. Flowers, R. A., II Mechanistic Studies on the Roles of Cosolvents and Additives in Samarium(II)-Based Reductions. 2008(10), 1427-39.

156. Kwong, F. Y.; Chan, A. S. C. Recent Developments on Hemilabile P,O-Type Ligands in Cross-Coupling Reactions. 2008, (10), 1440-8.

157. Aluri, B. R. 1,2-Dibromoethane, A Versatile Reagent in Organic Synthesis. 2008, (10), 1579-80.

158. Pedrosa, L. F. Synthetic Applications of Triphenylphosphine. 2008, (10), 1581-2.

159. Shibasaki, M.; Matsunaga, S.; Kumagai, N. Strategies for Constructing Diverse Chiral Environments in Multimetallic Bifunctional Asymmetric Catalysis. 2008, (11), 1583-602.

160. Vorbrueggen, H. Esterification of Carboxylic Acids and Etherification of Phenols with Amide Acetals. 2008, (11), 1603-17.

161. Miyake, Y.; Nishibayashi, Y.; Uemura, S. Optically Active Chiral Ligands, Ferrocenyloxazolinylphosphines, (FOXAPs): Development and Application to Catalytic Asymmetric Reactions. 2008, (12), 1747-58.

162. Bartoli, G.; Melchiorre, P. A Novel Organocatalytic Tool for the Iminium Activation of ,-Unsaturated Ketones. 2008, (12), 1759-72.

163. Zohreh, N. Diketene. 2008, (12), 1913-4.164. Zhang, Z. Trichlorosilane, (HSiCl3), A Cheap and Convenient Reducing

Agent. 2008, (12), 1915-6.165. Chen, Y.-C. The Development of Asymmetric Primary Amine Catalysts

Based on Cinchona Alkaloids. 2008, (13), 1919-30.166. Okamoto, H.; Yamaji, M.; Satake, K. Photochemistry of Nitrogen-Bridged

Cyclophanes: 2,11-Diaza[32]Anthracenoparacyclophane and 2,11-Diaza[32]Paracyclophane Systems. 2008, (13), 1931-45.

167. Rani, M. Application of Terminal Electrophilic Phosphinidene Complexes. 2008, (13), 2078-9.

168. Kalita, P. K. Allyltrimethylsilane. 2008, (13), 2080-1.

Synthesis-Stuttgart

169. Yamada, T. Enantioselective Borohydride Reduction Catalyzed by Cobalt Complexes: Discovery, Analysis, and Design for a Halogen-Free System. 2008, (10), 1628-40.

170. von Zezschwitz, P. Selectivity Control in 1,2- and 1,4-Additions of Aluminum Organyls to Carbonyl Compounds. 2008, (12), 1809-31.

171. Carraro, M.; Sartorel, A.; Scorrano, G.; Carofiglio, T.; Bonchio, M. Catalytic

Strategies for Sustainable Oxidations in Water. 2008, (12), 1971-8.172. Vogler, T.; Studer, A. Applications of TEMPO in Synthesis. 2008, (13), 1979-

93.173. Kwong, C. K.-W.; Fu, M. Y.; Lam, C. S.-L.; Toy, P. H. The Phosphine-

Catalyzed Alkyne to 1,3-Diene Isomerization Reaction. 2008, (15), 2307-17.

Tetrahedron

174. Ferreira, E. M.; Zhang, H.; Stoltz, B. M. C-H Bond Functionalizations with Palladium(II): Intramolecular Oxidative Annulations of Arenes. 2008, 64(26), 5987-6001.

175. Len, C.; Mondon, M.; Lebreton, J. Synthesis of Cyclonucleosides Having a C-C Bridge. 2008, 64(32), 7453-75.

176. Aversa, M. C.; Barattucci, A.; Bonaccorsi, P. Glycosulfoxides in Carbohydrate Chemistry. 2008, 64(33), 7659-83.

177. Shen, H. C. Recent Advances in Syntheses of Carbocycles and Heterocycles via Homogeneous Gold Catalysis. Part 2: Cyclizations and Cycloadditions. 2008, 64(34), 7847-70.

178. Prakash Rao, H. S.; Rafi, S.; Padmavathy, K. The Blaise Reaction. 2008, 64(35), 8037-43.

179. Legraverend, M. Recent Advances in the Synthesis of Purine Derivatives and Their Precursors. 2008, 64(37), 8585-603.

180. Clarke, M. L.; France, M. B. The Carbonyl Ene Reaction. 2008, 64(38), 9003-31.

181. Janosik, T.; Wahlstroem, N.; Bergman, J. Recent Progress in the Chemistry and Applications of Indolocarbazoles. 2008, 64(39), 9159-80.

Tetrahedron-Asymmetry

182. Abraham, E.; Davies, S. G.; Roberts, P. M.; Russell, A. J.; Thomson, J. E. Jaspine B (Pachastrissamine) and 2-Epi-Jaspine B: Synthesis and Structural Assignment. 2008, 19(9), 1027-47.

Topics in Catalysis

183. Hermans, I.; Peeters, J.; Jacobs, P. A. Autoxidation Chemistry: Bridging the Gap Between Homogeneous Radical Chemistry and (Heterogeneous) Catalysis. 2008, 48(1-4), 41-8.

Topics in Current Chemistry

184. Otto, S.; Severin, K. Dynamic Combinatorial Libraries for the Development of Synthetic Receptors and Sensors. 2007, 277(Creative Chemical Sensor Systems), 267-88.

185. Jung, N.; Wiehn, M.; Braese, S. Multifunctional Linkers for Combinatorial Solid Phase Synthesis. 2007, 278(Combinatorial Chemistry on Solid Supports), 1-88.

186. Ljungdahl, N.; Bromfield, K.; Kann, N. Solid Phase Organometallic Chemistry. 2007, 278, 89-134.

187. Hahn, F.; Schepers, U. Solid Phase Chemistry for the Directed Synthesis of Biologically Active Polyamine Analogs, Derivatives, and Conjugates. 2007, 278, 135-208.

188. Mentel, M.; Breinbauer, R. Combinatorial Solid-Phase Natural Product Chemistry. 2007, 278, 209-41.

189. Montgomery, J.; Sormunen, G. J. Nickel-Catalyzed Reductive Couplings of Aldehydes and Alkynes. 2007, 279, 1-23.

190. Gansaeuer, A.; Justicia, J.; Fan, C.-A.; Worgull, D.; Piestert, F. Reductive C-C Bond Formation after Epoxide Opening via Electron Transfer. 2007, 279, 25-52.

191. Hirao, T. Catalytic Reductive Coupling of Carbonyl Compounds - The Pinacol Coupling Reaction and Beyond. 2007, 279, 53-75.

192. Iida, H.; Krische, M. J. Catalytic Reductive Coupling of Alkenes and Alkynes to Carbonyl Compounds and Imines Mediated by Hydrogen. 2007, 279, 77-104.

193. Nishiyama, H.; Shiomi, T. Reductive Aldol, Michael, and Mannich Reactions. 2007, 279, 105-37.

194. Breit, B. Recent Advances in Alkene Hydroformylation. 2007, 279, 139-72.195. Kimura, M.; Tamaru, Y. Nickel-Catalyzed Reductive Coupling of Dienes and

Carbonyl Compounds. 2007, 279, 173-207.196. Broene, R. D. Reductive Coupling of Unactivated Alkenes and

Alkynes. 2007, 279, 209-48.197. Soai, K.; Kawasaki, T. Asymmetric Autocatalysis with Amplification of

Chirality. 2008, 284(Amplification of Chirality), 1-33.198. Brown, J. M.; Gridnev, I.; Klankermayer, J. Asymmetric Autocatalysis with

Organozinc Complexes; Elucidation of the Reaction Pathway. 2008, 284, 35-65.199. Lavabre, D.; Micheau, J.-C.; Islas, J. R.; Buhse, T. Kinetic Insight into

Specific Features of the Autocatalytic Soai Reaction. 2008, 284, 67-96.200. Saito, Y.; Hyuga, H. Rate Equation Approaches to Amplification of

Enantiomeric Excess and Chiral Symmetry Breaking. 2008, 284, 97-118.

Monographs

201. Attanasi, O. A.; Spinelli, D.; Eds. Chemistry and Properties. [In: Targets Heterocycl. Syst., 2007; 11]. Societa Chimica Italiana: Rome, Italy, 2007.

202. Boerner, A.; Ed. Phosphorus Ligands in Asymmetric Catalysis; Synthesis and Applications. Wiley-VCH: Weinheim, Germany, 2008.

203. Bruneau, C.; Dixneuf, P.; Eds. Metal Vinylidenes and Allenylidenes in Catalysis; From Reactivity to Application in Synthesis. Wiley-VCH: Weinheim, Germany, 2008.

204. Demchenko, A. V.; Ed. Handbook of Chemical Glycosylation; Advances in Stereoselectivity and Therapeutic Relevance. Wiley-VCH: Weinheim, Germany, 2008.

205. Kollar, L.; Ed. Modern Carbonylation Methods. Wiley-VCH: Weinheim, Germany, 2008.

206. Moloney, M. G.; Ed. Structure and Reactivity in Organic Chemistry.

Blackwell: Oxford, U.K., 2008. 207. Rappoport, Z.; Marek, I.; Eds. The Chemistry of Organomagnesium

Compounds; Part 1. John Wiley & Sons: Chichester, U.K., 2008. 208. Stanforth, S.; Ed. Natural Product Chemistry at a Glance. Blackwell: Ames,

Iowa, 2006. 209. Stepnicka, P.; Ed. Ferrocenes: Ligands, Materials and Biomolecules. John

Wiley & Sons: Chichester, U.K., 2008.

Index

Acetaldehyde, aldol reaction, 23Mannich reaction, 23

Acyloxy-N-alkoxyamides, 12Alcohols, secondary, kinetic resolution with aerobic oxidation, 20Aldehydes, amidation, 87

esterification, 87Aldol reactions, aqueous, 75Alkenes, hydroamination, 65Alkynes, hydroamination, 65

rearrangement to 1,3-dienes, 173Allylic alkylation, with Cu, 111Allyltrimethylsilane, allylation, 168Aluminum organyls, carbonyl additions, 170Amides, from aldehydes, 87Amidoacrylates, -, hydrogentation, 98Amine catalysts, from cinchona alkaloids, 165Amino acids, -difluoromethyl, 83

derivatives, -, 98Aminobutyric acids, -, 89Aminocatalysis, asymmetric, 33Aminoxy acids, -, 10Aminoxyl radicals, oxidation, 26Anticancer agents, migrastatin, 142Asymmetric autocatalysis, chirality amplification, 197

with organozinc, 198Azetidines, 67Azetidinones, 67Azide-alkyne cycloaddition, with Cu, 50Benzazetines, 92Benzoxazepines, 115Benzoxazines, 133 Biaryl coupling, with Pd, 114Biaryl phosphane ligands, C-N cross-coupling, 34Biaryl synthesis, 143Bimetallic dendrimer-encapsulated nanoparticles, 79

Biomimetic oxidation, with Ru, 74Bis(oxazolinyl)phenyl complexes, 38Blaise reaction, 178Butane-1,2-diacetals, protecting groups, 82Calixarene receptors, 141Carbocation cascade reactions, biosynthesis, 125Carbodicarbenes, 19Carbohydrates, glycosulfoxides, 176

molecular recognition, 145Carbon dioxide, dense phase, 11Carbon-heteroatom bonds, with Fe, 69Carbonyl ene reaction, 180Carbonylation, book, 205Carbonyls, borohydride reduction, Co, 169Carboxylic acids, catalytic transformation, 143

esterification, with amide acetals, 160C-C bond activation, with Rh, 104C-C bond formation, 68C-H bond functionalization, with Cu, Ag, Au, 63

with Pd, 174Chelating ligands, chiral olefins, 22Chemical sensors, combinatorial libraries, 184Chemistry and properties, 201Chromocene, bent-sandwich, 102Co-catalysis, 31Coinage metals, heterocycle synthesis, 64Combinatorial chemistry, cross-coupling, 118

multifunctional linkers, 185natural products, 188organometallic, 186polyamines, 187

Conagenin synthesis, 136Copper catalysts, 1,3-dipolar cycloaddition, 46

allylic substitution, 42conjugate addition, 42

Copper complexes, diamagnetic, 52Copper hydride catalysts, 48Copper, in coupling reactions, 53Crescents, aromatic oligoamides, 9Crystal packing, in solid state reactions, 127Cyclic carbocycles, via phosphines, 70Cycloheptanes, 29Cyclohexane autoxidation, 183Cyclonucleosides, C-C bridge, synthesis, 175Cyclophanes, N-bridged, 166Cyclopropanation, 93

Cyclopropylimines, synthesis, 135Desilylative-defluorination, 119Diazaborolines, 1,3,2-, 97Dibenzylamines, 133Dibromoethane, in synthesis, 157Difluoromethylenes, carbonyl precursors, 120Dihydropyridines, oxidation, 148Diketenes, 163Dimetallocenes, 35Diphenylphosphinobenzoic acid, chiral ligands, 13Dizirconocenes, 35Electrochemistry, organometallic catalysis, 41Enantiomer dimers, 37Enones, iminium activation, 162Enynes, cycloisomerization, 21, 61Epoxy alcohols, Ti tandem reactions, 1Epoxy compounds, reduction, 152Esters, from aldehydes, 87Ferrocenes, ligand, biomolecules, book, 209Ferrocenyloxazolinylphosphines, chiral ligands, 161Foldamers, aromatic oligoamides, 9

peptidomimetic, 10Friedel-Crafts alkylation, with Cu, 47Fullerenes, molecular receptors, 76

organocopper reagents, 51Furans, reaction with singlet oxygen, 5Germabenzene ligands, 80Germacyclopentadienide ligands, 80Glycosylation, stereoselective, book, 204Gold catalysts, 59, 60, 84

cyclizations, 177enyne cycloisomerization, 61intermediate, 36ligand effects, 62

Green chemistry, heteropoly acids, 116Green organic chemistry, 77Grignard reagents, allylic alkylation, with Cu, 43

conjugate addition, with Cu, 43Guaianolides, synthesis, 107Helices, aromatic oligoamides, 9Heteroarenes, 1,3,2-diazaborolines, 97Heteroatom-heteroatom bonds, with Fe, 69Heterocycles, Ag catalyst, 56

carbene ligands, 103N-, organosilicon, 150P-, synthesis, 167

ring-closing metathesis, 85via phosphines, 70

Heteropoly acids, 116Hydrodefluorination, 154Imines, alkylation with dialkylzinc and Cu, 45

cycloaddition with Ag, 56Imino esters, N-alkylation, 71Indazoles, 112Indole alkaloids, post-secodine, 94Indoles, olefin tethers, cyclization, 174Indolocarbozoles, 181Ionic liquids, chiral, 40, 108

Pd-catalyzed reactions, 117phosphonium, 140room temperature, ammonium fluorohydrogenate, 121room temperature, imidazole, 106

Iron catalyst, 16, 69Ketene-imine reaction, 3Klaeui tripodal ligands, 96Lactams, -, 89Lanostanes, 132Lanthanides, divalent, anionic complexes, 27Ligands, monophosphine P,O-type, 156Marine alkaloids, oroidin, biosynthesis, 25Marine macrolides, cytotoxic, 144Marine metabolites, diazonamide A, 130Metal allenylidene catalysts, book, 203Metal complexes, in reactions, 101Metal hydrogen sulfates, 105Metal vinylidene catalysts, book, 203Metallacycles, 28Metallacyclopenta-2,3-dienes A, 28Metallasiloxanes, 151Metallocanes, tin, 90Methylenepyrrolidines, synthesis, 86Methylenetetrahydrofurans, synthesis, 86Methylidene--valerolactones, 139Methylserine, -, synthesis, 136Microwave-assisted aqueous synthesis, 77Multimetallic complexes, 159Natural products, book, 208Nitriles, keto ester or enamino ester formation, 178Nitrogen heterocycles, functionalization with Rh, 6Nitroglycals, 7Nitromethane, heat of formation, 128Nitropyrimidines, 123

NMR, computer-aided structure elucidation, 138Nucleophilicity, 126Olefins metathesis, small ring, 30Olefins, asymmetric epoxidation, chiral ketones, 66

asymmetric epoxidation, iminium salts, 66asymmetric epoxidation, using aspartate tripeptide, 18chiral, chelating ligands, 22terminal, radical addition, 129

Organocatalysis, asymmetric, 24Organocopper reagents, 49Organocopper, tris(pyrasolyl)borate complexes, 58Organocuprates, 52Organogold, tris(pyrasolyl)borate complexes, 58Organoiodanes, hypervalent, 113Organomagnesium compounds, book, 207Organosilver, tris(pyrasolyl)borate complexes, 58Oxa-Michael reaction, 72Oxazepines, synthesis, 139Oxidations, aqueous, 171Peptidomimetics, ring constraints, 8P-H bond activation, 73Phenols, etherification, with amide acetals, 160Phosphates, hexacoordinated, 39Phosphinidene complexes, 110

cycloaddition, 167Phosphorothioate oligonucleotides, 146Phosphorus ligands, asymmetric catalysis, book, 202Poly(amidoamine) dendrimers, 1-2 branched, 137Polybromofullerenes, 149Polychlorofullerenes, 149Polycyclic carbocycles, via phosphines, 70Polyfluoroalkylating agents, sulfonates, 122Polyfluorofullerenes, 149Polyphenols, natural, oxidized, 99Polypropylenimine dendrimers, 1-2 branched, 137P-P bond activation, 73Prolinamides, supported catalysts, 81Protostanes, 132Purines, functionalization, 179Pyranonaphthoquinones, 131Pyrimidines, synthesis, 88Pyrrolidines, supported catalysts, 81Quaternary ammonium salts, chiral catalysts, 14Quaternary pralines, 109Radicals, nitrogen-centered, 78Reductive coupling, after titanocene epoxide opening, 190

aldehydes, alkynes, Ni, 189aldol, Michael, Mannich reactions, 193alkene hydroformylation, 194alkenes, alkynes, 196alkenes, alkynes, carbonyls, imines, hydrogenation, 192carbonyls, 191dienes, carbonyls, 195

Ru/Os porphyrin carbene complexes, 95Ruthenium allenylidene complexes, 95Ruthenium vinylidene complexes, 95Samarium(II) reductions, cosolvents, additives, 155Sesquiterpene lactones, synthesis, 107Silabenzene ligands, 80Silacyclopentadienide ligands, 80Silver catalysts, asymmetric reactions, 54

C-H and C-Si activation, 57cross-coupling, 55heterocycle synthesis, 55-6

Soai reaction, chirality amplification, 199-200Sphingosines, Jaspine B, synthesis, 182Spiro bis(pyridinium) salts, ionic liquids, 40Squalene derivatives, 132Stannocanes, 90Structure and reactivity, book, 206Sulfanylation of carbonyls, 134Supramolecules, halogen bonding, 32TEMPO, cooxidant, carbon-radicals, 172Tertiary alcohols, from ketones, with Cu, 44Tertiary amines, from ketimines, with Cu, 44Tetramethylpiperidin-1-oxyl, (TEMPO), 172Tetranortriterpenoids, 132Thiazolidinones, 124Thioamides, cyclo-acylation, 91Thiol ester/boronic acid coupling, with Cu, 17Transmetallation, 100Triazine, dissociation into HCN, 153Trichlorosilane, reducing agent, 164Triisopropylphenylbinaphthyldiylhydrogen phosphate (TRIP), 15TRIP catalyst, 15Triphenylphosphine, in synthesis, 158Triterpenoids, 132Ylides, Michael addition, cyclization, 4Zeolites, aromatic hydrocarbons, 147

mechanism of surface methoxy species, 2