resinas hojas de seguridad

7/18/2019 Resinas Hojas de Seguridad

1/35


2/35


3/35

____________________________________________________________________________________________

Page 1 / 7

SAFETY DATA SHEET

Issue Date 19-Nov-2013 Revision Date 22-May-2014 Version 2

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product identifier

Product Name SUBSTANCE G+

Other means of identification

Synonyms SubG+

Recommended use of the chemical and restrictions on use

Recommended Use General Purpose UV Cure Resin

Uses advised against No information available

Details of the supplier of the safety data sheet

Manufacturer Address

MakerJuice Labs LLC

14100 Santa Fe Trail Drive

Suite #105

Lenexa, KS 66215 USA

Email: [email protected]

Website: http://www.makerjuice.com

Emergency telephone number

Company Phone Number (913) 777-4996 [9-5PM CST, M-F]

2. HAZARDS IDENTIFICATION

Classification

OSHA Regulatory Status

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Skin corrosion/irritation Category 2

Serious eye damage/eye irritation Category 1

Skin sensitization Category 1

Label elements

Emergency Overview

Danger

Hazard statementsCauses skin irritationCauses serious eye damageMay cause an allergic skin reaction

Appearance viscous Physical state liquid Odor Ester


4/35

SubG+ Revision Date 22-May-2014_____________________________________________________________________________________________

_____________________________________________________________________________________________

Page 2 / 7

Precautionary Statements - Prevention

Wash face, hands and any exposed skin thoroughly after handling

Wear protective gloves/protective clothing/eye protection/face protection

Avoid breathing dust/fume/gas/mist/vapors/spray

Contaminated work clothing should not be allowed out of the workplace

Precautionary Statements - Response

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician

IF ON SKIN: Wash with plenty of soap and water

Take off contaminated clothing and wash before reuse

If skin irritation or rash occurs: Get medical advice/attention

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not Applicable

Other Information

Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No. Weight-% Trade Secret

acrylate ester proprietary >60 *

photoinitiator proprietary


5/35


_____________________________________________________________________________________________

Page 3 / 7

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Dry chemical, CO2, alcohol-resistant foam or water spray.

Unsuitable extinguishing media: Do not use a solid water stream as it may scatter and spread fire.

Specific hazards arising from the chemical

In the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact. Thermal

decomposition can lead to release of irritating and toxic gases and vapors.

Hazardous combustion products: Formaldehyde.

Explosion data

Sensitivity to Mechanical Impact: None.

Sensitivity to Static Discharge: None.

Protective equipment and precautions for firefighters

Wear self-contained breathing apparatus for f irefighting if necessary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Ensure adequate ventilation, especially in confined areas. Use personal protective

equipment as required. Avoid contact with eyes and skin. Evacuate personnel to safe

areas. Keep people away from and upwind of spill/leak.

Environmental precautions

Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional

ecological information.

Methods and material for containment and cleanup

Methods for containmentPrevent further leakage or spillage if safe to do so.

Methods for cleaning upSoak up with inert absorbent material. Pick up and transfer to properly labeled containers.

After cleaning, flush away traces with water.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Use only in well-ventilated areas. Avoid breathing fumes from hot material. Use personal

protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated

place. Keep in properly labeled containers. Protect from direct sunlight and ultraviolet (UV).Keep away from heat.

Incompatible materials Strong oxidizing agents. Strong acids. Strong bases.


6/35


_____________________________________________________________________________________________

Page 4 / 7

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational

exposure limits established by the region specific regulatory bodies.

Appropriate engineering controls

Engineering Controls Ensure adequate ventilation, especially in confined areas.

Individual protection measures, such as personal protective equipment

Eye/face protection Tight sealing safety goggles.

Skin and body protection Wear protective nitrile rubber gloves.

Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.

General Hygiene Considerations When using do not eat, drink or smoke. Wash face, hands and any exposed skin thoroughly

after handling. Wash contaminated clothing before reuse. Regular cleaning of equipment,work area and clothing is recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state liquid

Appearance viscous Odor Ester

Color red, yellow, green, blue, black, white Odor threshold No information available

Property Values Remarks Method

pH No information availableMelting point/freezing point No information available

Boiling point / boiling range No information available

Flash point > 100 C (> 212 F)

Evaporation rate No information available

Flammability (solid, gas) No information available

Flammability Limit in Air

Upper flammability limit: No information available

Lower flammability limit: No information available

Vapor pressure No information available

Vapor density No information available

Specific Gravity Approx. 1

Water solubility Low solubilitySolubility in other solvents No information available

Partition coefficient No information available

Autoignition temperature No information available

Decomposition temperature No information available

Kinematic viscosity No information available

Dynamic viscosity 90 cP @ 20 C

Explosive properties No information available

Oxidizing properties No information available

Softening point No information available

Molecular weight No information available

VOC Content (%) No information available

Density No information available

Bulk density No information available


7/35


_____________________________________________________________________________________________

Page 5 / 7

10. STABILITY AND REACTIVITY

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Possibility of Hazardous Reactions

None under normal processing.

Conditions to avoid

Heat, flames and sparks. Extremes of temperature and direct sunlight. To avoid thermal decomposition, do not overheat. UV-

radiation/sunlight.

Incompatible materials

Strong oxidizing agents. Strong acids. Strong bases.

Hazardous Decomposition Products

Formaldehyde.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

InhalationNo data available.

Eye contactRisk of serious damage to eyes.

Skin ContactMay cause sensitization by skin contact.

Ingestion

Component Information

No data available.

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

acrylate ester = 4600 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) -

Information on toxicological effects

Symptoms May cause an allergic skin reaction.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Corrosivity Risk of serious damage to eyes.

Sensitization May cause sensitization by skin contact.

Germ cell mutagenicity No information available.

Carcinogenicity May release formaldehyde when heated to high temperatures [> 150 C (> 212 F)] in

the presence of air. Formaldehyde is a known skin and lung sensitizer and is regulated

as a carcinogen.

Reproductive toxicity No information available.

STOT - single exposure No information available.

STOT - repeated exposure No information available.

Aspiration hazard No information available.

Numerical measures of toxicity - Product Information

Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity


8/35


_____________________________________________________________________________________________

Page 6 / 7

12. ECOLOGICAL INFORMATION

Ecotoxicity

Toxic to aquatic life

Persistence and degradability

No information available.

Bioaccumulation

No information available.

Other adverse effects No information available

15. REGULATORY INFORMATION

International InventoriesTSCA Complies

Legend:

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory

US Federal RegulationsSARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any

chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories

Acute health hazard Yes

Chronic Health Hazard No

Fire hazard No

Sudden release of pressure hazard No

Reactive Hazard No

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws andregulations.

Contaminated packaging Do not reuse container.

14. TRANSPORT INFORMATION

DOT Not regulated

TDG Not regulated

IATA Not regulated

IMDG Not regulated

ADR Not regulated


9/35


_____________________________________________________________________________________________

Page 7 / 7

CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40

CFR 122.42)

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive

Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and

Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this material

US State Regulations

California Proposition 65

This product does not contain any Proposition 65 chemicals

U.S. State Right-to-Know Regulations

This product does not contain any substances regulated by state right-to-know regulations

Canada

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and

the MSDS contains all the information required by the CPR WHMIS Hazard Class

D2B - Toxic materials

16. OTHER INFORMATION

NFPA Health hazards 2 Flammability 0 Instability 0 Physical and Chemical

Properties -

HMIS Health hazards 2 Flammability 0 Physical hazards 0 Personal protection X

Issue Date 19-Nov-2013

Revision Date 22-May-2014

Disclaimer

The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief

at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The

information relates only to the specific material designated and may not be valid for such material used in combination

with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet


10/35


11/35

MATERIAL SAFETY DATA SHEET FILE NO.: 004Spot-HT MSDS DATE: 08 / April / 2012

SECTION 1: ROD!CT AND COMANY IDENTIFICATION

ROD!CT NAME: Spot-HTSYNONYMS: S"#$o%ROD!CT CODES:

MAN!FACT!RER: Spot-A M&t'ri&l(DI)ISION: Spot-A M&t'ri&l(

ADDRESS:

EMER*ENCY HONE +E"rop',: 112CHEMTREC HONE:OTHER CALLS: 4 4 8 1 8FA HONE:

CHEMICAL NAME:CHEMICAL FAMILY: A3rl&t'5 A3rl&t' Oli%o6'r(CHEMICAL FORM!LA:

ROD!CT !SE: 7oto&3ti' R'(i#REARED 9Y:

SECTION 1 NOTES:

SECTION 2: COMOSITION/INFORMATION ON IN*REDIENTS

IN*REDIENT: CAS NO. ;T )OL SARA 1REORTA9LEAlip7&ti3 A3rl&t' 0-80Alip7&ti3 A3rl&t'( 10-20!r't7' A3rll&t' 20-0

A EL or TL) 7&( #ot


12/35


INHALATION: M& 3&"(' r'(pir&tor tr&3t irrit&tio#

CHRONIC HEALTH HA=ARDS: No &ppropri&t' 7"6 or i6&l 37ro#i3 7'&lt7 ''3t( $&t& >#o# to 'i(t.

MEDICAL CONDITIONS *ENERALLY A**RA)ATED 9Y EOS!RE:

SECTION NOTES:

SECTION 4: FIRST AID MEAS!RES

INHALATION

If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial respiration as needed. Obtain emergency medicalattention. Prompt action is essential.

EYE CONTACT

In case of eye contact, immediately rinse with clean water for 20!0 minutes. "etract eyelids often. Obtain emergency medical attention.

S?IN CONTACT

"emove contaminated clothing as needed. #ash s$in thoroughly with mild soap%water. &lush with lu$ewarm water for '( minutes. If stic$y, awaterless cleaner may be used.

IN*ESTION

Ingestion unli$ely. )owever, if ingested, obtain emergency medical attention.

EMER*ENCY MEDICAL TREATMENT ROCED!RES

If pain, blin$ing, tears, or redness continue, patient should contact ophthalmologist.

SECTION 4 NOTES:

SECTION : FIRE-FI*HTIN* MEAS!RES

FLASH OINT METHOD+MCC, A!TOI*NITION TEM. METHODG* +!%200& -%/

FLAMMA9LE LIMITS + )OL!ME IN AIR,

LO;ER: N/DA

!ER: N/DA

FIRE AND ELOSION HA=ARDS

)igh temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or oxidiers may cause spontaneous polymeriingreaction generating heat%pressure. losed containers may rupture or explode during runaway polymeriation.

ETIN*!ISHIN* MEDIA

ry chemicalO2#ater spray&oam#ater fog

A*E 2OF 8


13/35

MATERIAL SAFETY DATA SHEET FILE NO.: 004Spot-HT MSDS DATE: 08 / April / 2012SECIAL FIREFI*HTIN* ROCED!RES

o not enter fire area without proper protection. 1ee 1ection decomposition products possible. &ight fire from safe distance%protected

location. )eat%impurities may increase temperature%build pressure%rupture closed containers, spreading fire, increasing ris$ of burns%in3uries.#ater may be ineffective in firefighting due to low solubility. 4se water spray%fog for cooling. Pressure relief system may plug with solids,increasing ris$ of overpressure. -otify authorities if li5uid enters sewer%public waters.

SECTION NOTES:

SECTION : ACCIDENTAL RELEASE MEAS!RES

ACCIDENTAL RELEASE MEAS!RES:

RECA!TIONS IF MATERIAL IS SILLED OR RELEASED

1pilled or released material may polymerie and release heat%gases. 6xtinguish all ignition sources and ventilate area. #ear protectivee5uipment during cleanup. i$e and recover large spill. 1oa$ up small spill with inert solids 7such as vermiculite, clay8 and sweep%shovel intovented disposal container. #ash spill area with a strong detergent and water solution9 rinse with water but minimie water use duringcleanup. &or spills on water, contain, minimie dispersion and collect. ispose%report per regulatory re5uirements.

;ASTE DISOSAL METHODS

-oncontaminated, properly inhibited material is not a ""/ haardous waste. )owever, contaminated material%soil%water may be""/%O1)/ haardous waste due to potential for internal heat generation 7see 0 &" 2:' and 2+ &" '+'08.

It is the responsibility of the generator to determine at the time of disposal whether the material meets the criteria of a haardous waste.omply with all applicable federal, state and local regulations. 4se registered transporters. isposal options include landfilling solids atpermitted sites9 fuel blending or incinerating li5uids. /ssure emissions comply with applicable regulations. ilute a5ueous waste maybiodegrade9 avoid overloading%poisoning plant biomass. /ssure effluent complies with applicable regulations.

SECTION NOTES:

SECTION : HANDLIN* AND STORA*E

HANDLIN* AND STORA*E ROCED!RES

#ear appropriate protective e5uipment when handling this material 71ee 1ection ; of which may affectproduct 5uality or result in product degradation. Product is pac$aged with inhibitor7s8. 4nless inhibited, product can polymerie, raisingtemperature and pressure possibly rupturing container. hec$ inhibitor content periodically, adding to bul$ material if needed. In addition, theproduct?s inhibitor7s8 re5uire the presence of dissolved oxygen.


14/35


EYE ROTECTION

6ye protection such as chemical splash goggles and%or face shield must be worn when possibility exists for eye contact due to splashing orspraying li5uid, airborne particles, or vapor. ontact lenses should not be worn.

S?IN ROTECTION

epending on the conditions of use, protective gloves, apron, boots, head and face protection should be worn. *his e5uipment should becleaned thoroughly after each use.

EN*INEERIN* CONTROLS

If this material is handled at elevated temperature or under mist forming conditions, -IO1)%


15/35

MATERIAL SAFETY DATA SHEET FILE NO.: 004Spot-HT MSDS DATE: 08 / April / 2012MOLEC!LAR ;EI*HT: N/DA)ISCOSITY: A 100 to 10 3p( &t 2C/F

SECTION NOTES:

SECTION 10: STA9ILITY AND REACTI)ITY

STA9LE !NSTA9LE

STA9ILITY: St&


16/35


/lthough no appropriate human or animal health effects data is $nown to exist, this material is not expected to be an ingestion haard.

MEDICAL CONDITIONS A**RA)ATED 9Y EOS!RE

*his material or its emissions may induce an allergic or sensitiation reaction and thereby aggravate systemic disease.

SECTION 11 NOTES:

SECTION 12: ECOLO*ICAL INFORMATION

ECOLO*ICAL INFORMATION:

DECONTAMINATION ROCED!RES

&ollow standard plant procedures or supervisor?s instructions for decontamination operations.

SECTION 12 NOTES:

SECTION 1: DISOSAL CONSIDERATIONS

RECA!TIONS IF MATERIAL IS SILLED OR RELEASED

1pilled or released material may polymerie and release heat%gases. 6xtinguish all ignition sources and ventilate area. #ear protectivee5uipment during cleanup. i$e and recover large spill. 1oa$ up small spill with inert solids 7such as vermiculite, clay8 and sweep%shovel intovented disposal container. #ash spill area with a strong detergent and water solution9 rinse with water but minimie water use duringcleanup. &or spills on water, contain, minimie dispersion and collect. ispose%report per regulatory re5uirements.

;ASTE DISOSAL METHODS

-oncontaminated, properly inhibited material is not a ""/ haardous waste. )owever, contaminated material%soil%water may be""/%O1)/ haardous waste due to potential for internal heat generation 7see 0 &" 2:' and 2+ &" '+'08.

It is the responsibility of the generator to determine at the time of disposal whether the material meets the criteria of a haardous waste.

omply with all applicable federal, state and local regulations. 4se registered transporters. isposal options include landfilling solids atpermitted sites9 fuel blending or incinerating li5uids. /ssure emissions comply with applicable regulations. ilute a5ueous waste maybiodegrade9 avoid overloading%poisoning plant biomass. /ssure effluent complies with applicable regulations.

SECTION 14: TRANSORT INFORMATION

!.S. DEARTMENT OF TRANSORTATION ROER SHIIN* NAME:

HA=ARD CLASS:ID N!M9ER:AC?IN* *RO!:LA9EL STATEMENT:

;ATER TRANSORTATION ROER SHIIN* NAME:

HA=ARD CLASS:ID N!M9ER:AC?IN* *RO!:LA9EL STATEMENTS:

AIR TRANSORTATION ROER SHIIN* NAME:

HA=ARD CLASS:ID N!M9ER:AC?IN* *RO!:LA9EL STATEMENTS:

A*E 6OF 8


17/35


OTHER A*ENCIES:

SECTION 14 NOTES:

SECTION 1: RE*!LATORY INFORMATION

!.S. FEDERAL RE*!LATIONSTSCA +TOIC S!9STANCE CONTROL ACT,:

TSCA (t&t"(: All 3o6po#'#t( o t7i( pro$"3t &r' li(t'$5 or '3l"$'$ ro6li(ti#%5 o# t7' !#it'$ St&t'( E#iro#6'#t&l rot'3tio#

TSCA S'3tio# 12+


18/35


JNot' - G"&lii'r( $ 3o$'( "('$ i# t7i( MSDS

EK EG"&lB A Approi6&t'lB LT L'(( T7B *T *r'&t'r T7B

TR Tr&3'B !? !#>#o#B N/A Not Appli3&


19/35


20/35

3D-Materials - Advanced Photopolymer Resins - 3DM-ABS series / MSDS - - update 22/08/2014 1

3D-MaterialsAdvanced Photopolymer Resins

MATERIAL SAFETY DATA SHEETaccording to regulation (EC) No 1907/2006 (REACH)

HARMFUL & IRRITANT SUBSTANCE

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Identification : Photopolymer 3DM-ABS seriesProduct Class : Mixture of acrylic acid esters, acrylated monomers, oligomers and photoinitiators.Product Use :Use for stereolitography 3D printers with UV-light systems (Laser or LED).

Company :3D-MaterialsFranceMail : [email protected] : www.3d-materials.org

Date of Preparation: 09/30/2013

For Emergencies: call 112 (for UE) or 911 (for USA)


A. EMERGENCY OVERVIEW

This product is a liquid acrylic based resin with a characteristic light odor. This product may causeskin, eyes and respiratory system irritation, and skin sensitization/allergic reaction by skin contact.Inhalation of high vapor concentration may cause headaches and nausea.

B. TARGET ORGANS OR SYSTEMS

Skin, Eyes, Respiratory System, Central Nervous System

C. ROUTE OF EXPOSURE:

Skin Contact, Eye Contact, Inhalation, Ingestion

D. SIGNS AND SYMPTOMS OF EXPOSURE:

Acute:

Skin Contact -- May cause skin irritation. Symptoms may include a slightly localized redness or rashand swelling. Repeated exposure may cause sensitization and allergic skin reaction in someindividuals resulting in contact dermatitis, severe irritation, dryness and cracking.

Eye Contact -- May cause eye irritation. Symptoms may include excessive tearing, itching, irritation,blinking and redness.

Inhalation -- This product is a suspect slight respiratory tract irritation hazard, especially if used at

elevated temperature or processes which may generate aerosols or mists. Symptoms of irritation mayinclude coughing, headache and nausea, mucous production and shortness of breath.


21/35


Ingestion -- The product may be harmful if swallowed. It may cause nausea, headache, vomiting,diarrhea, and/or central nervous system effects. Keep all food in an area separate from storage anduse locations.Prohibit eating, drinking and smoking in areas where there is a potential for significant exposure to thismaterial. Thoroughly wash hands before eating.

Chronic:

Inhalation -- Prolonged or repeated overexposure may cause irritation, headache, and nausea.

Skin Contact -- May cause sensitization and allergic reaction. May cause more significant irritation inpeople with pre-existing skin conditions.

Eye Contact -- May cause redness of eye tissue.

Ingestion -- May be a slight ingestion hazard if swallowed. Chronic ingestion of high doses may causedamage to testes, as shown in animal studies.

Carcinogens:

There are no carcinogens in concentrations of 0.1 percent or greater in this product.Potential Environmental Effects: Not readily biodegradable. Avoid release to the environment. Disposeof in accordance with all applicable federal, state and local regulations.


Components Approximate C.A.S. No. & UK/EU Classification% by weight EINECS No. Directive 67/548/EEC

Acrylated momomer Proprietary Proprietary Xi(Irritant),N(Harmful), R36/37/38

R43/51/53S3, S7/9, S20, S26,S29,S37/39

Acrylated oligomer Proprietary Proprietary Xi(Irritant), R36/37/38,R43S3, S7/9, S20, S26,S29, S37/39

Photoinitiators Proprietary Proprietary H303, H402

4. FIRST-AID MEASURES

Emergency Overview:This product is a liquid acrylic based resin with an acrylat characteristic odor.This product may cause skin and eye irritation. The inhalation of high vapor concentration may causea headache and nausea.

Inhalation:In case of exposure to a high concentration of vapor or mist, remove person to fresh air.If breathing has stopped, administer artificial respiration and seek medical attention.

Eye Contact:Immediately flush with plenty of clean water (under eye lids) for at least 20 minutes.Hold eyelids apart to ensure flushing.Washing within one minute of contact is essential to achieve maximum effectiveness. Seek medicalattention immediately. Do not apply oil or oily ointments unless ordered by a physician.


22/35


Skin Contact:Remove contaminated clothing and rinse contact area thoroughly with soap and water.Particular attention should be paid to hair, nose, and ears, and other areas not easily cleaned. Washclothing before reuse. If irritation develops, consult a physician.

Ingestion:If ingested dilute with water by giving glasses of water or milk to the victim. Do not giveanything by mouth if the victim is rapidly losing consciousness, is unconscious, or convulsing. Do not

induce vomiting. If vomiting occurs naturally, keep airways clear. Get medical attention. Provide anestimate of the time at which the material was ingested and the amount of the substance that wasswallowed.


Flash point: > 100C / 212FMethod: SetaflashIgnition temperature: n.dLower explosion limit: n.dUpper explosion limit: n.d

Extinguishing media:Use carbon dioxide or dry chemical for small fires; aqueous foam or waterspray for large fires.

Special firefighting procedures:Firefighters should wear full protection clothing and self-containedbreathing apparatus (SCBA).Thoroughly decontaminate firefighting equipment including all firefighting apparel after the incident.

Unusual Fire & Explosion:Emits irritating vapors. High temperatures, accidental impurities, orexposure to radiation or oxidizers may cause spontaneous polymerization generating heat/pressureand rupture/explosion of closed containers.

Exposure Hazard(s): Material Harmfull & Irritant


Procedures of Personal Precautions: Wear adequate personal protective clothing and equipment,as outlined in Section 8.

Environmental Precautions:Contain spill to prevent spread into drains, sewers, water supplies, orsoil. Avoid release to the Environment. Dispose of in accordance with all applicable federal, state andlocal regulations.

Methods of Cleaning Up:In the event of a spill, immediately remove all sources of ignition. Cover theliquid with inert absorbent. Using appropriate personal protective equipment and non-sparking tools,contain spilled material.

Waste Disposal Method:Do not dispose to sewers, lakes, rivers or streams. Scoop all contaminatedmaterial into compatible bottles or drums for proper disposal. Dispose of in accordance with allapplicable federal, state and local regulations. National or regional provisions may also be in force.


Handling Precautions:User Exposure -- This product should be used in well-ventilated areas.Product may cause irritation. Avoid contact with eyes. Avoid prolonged or repeated contact with skin.Wash hands with soap and water before eating, drinking, smoking, applying cosmetics, or using toiletfacilities. Launder contaminated clothing before reuse. Contaminated leather articles, including shoes,

cannot be decontaminated and should be destroyed to prevent reuse. Solvents should never be usedto clean hands or skin because they increase the penetration of the material into skin.


23/35


Storage Precautions: Suitable -- Store in a cool, dry place out of direct sun light, in opaque or ambercontainers. Store the containers at 10-35C (50-95F). Do not exceed 50C (122F) when in storage.Keep containers closed. Avoid ignition sources.

Special Requirements:Do not heat containers with steam or electrical equipment. Heating thisproduct above 100C (210F) in the presence of air may cause slow oxidative decomposition; above

150C (300F) polymerization may occur. Fumes and vapors from this thermal decomposition may bedangerous for health (nitrous vapors, carbon monoxide-carbon dioxide). Do not breathe fumes.

8. EXPOSURE CONTROLS & PERSONAL PROTECTION

EXPOSURE LIMITS:

Components HSIS Australia IOELVs (UK) ACGIH TLV OSHA PEL WEEL

Acrylated monomer None None None None NoneAcrylated oligomer None None None None NonePhotoinitiators None None None None None

No occupational exposure limit values exist for the materials contained in this product.

Notations:IOELVs (Indicative Occupational Exposure Limit Values)TWA (time weighted average)OEL (Occupational Exposure Limits)PEL (Permissible Exposure Limit)TLV (Threshold Limit Value)STEL (Short Term Exposure Limit)WEEL (Workplace Environmental Exposure Level by the American Industrial Hygiene Association)

EXPOSURE CONTROLS:

Ventilation Controls:Ensure adequate ventilation.

Respiratory Protection:Respirators are generally not needed under normal conditions of use. If thismaterial is handled at elevated temperature, under mist forming conditions or in case of accidentalrelease of large quantities of product use a full-face respirator with multi-purpose combination (US) ortype ABEK (EN 14387) respirator cartridges as a backup to engineering controls. Use respirators andcomponents tested and approved under appropriate government standards such as NIOSH (US) orCEN (EU).

Protective Gloves:Wear impervious gloves (nitrile or neoprene) for routine handling.

Eye and Face Protection:Chemical splash goggles or a face shield is recommended during

operations where splashing could occur.

Skin Protection:Avoid all skin contact. Depending on the conditions of use, cover as much of theexposed skin area as possible by wearing gloves, aprons, long pants, and long sleeved shirts.

Other Controls:For operations where contact can occur a safety shower and eye wash facility shouldbe available. Always use good personal hygiene and housekeeping practices. Wash thoroughly afterhandling.

Environmental Exposure Controls:Keep product from waterways and watersheds. This substanceis not readily biodegradable and dangerous for the environment. Avoid release to the environment.

9. PHYSICAL & CHEMICAL PROPERTIES


24/35


Appearance: Liquid resinOdor: Characteristic / AcrylateSpecific Gravity: 1.11 1.18 g/cmBoiling Point: > 100 C

Flash Point: > 100 CIgnition Temperature: n.d.

Lower Explosion Limit: n.d.Upper Explosion Limit: n.d.Viscosity @ 25C (77F) n.d.Vapour pressure: not establishedSolubility in water: not establishedSolubility in organic solvents: soluble in organic solventsVolatile characteristics: negligibleElectrostatic discharge: safeElectric conductivity: dielectric


Stability:Stable when stored in original container designed for use with light sensitive materials under35C (95F) in dark, cool place.

Conditions to Avoid:Storage > 40C (100F),exposure to light, loss of dissolved air, andcontamination with incompatible materials.

Incompatible Materials to Avoid: Polymerization initiators, including peroxides, strong oxidizingagents, alcohols, copper, copper alloys, carbon steel, iron, rust, and strong bases.

Hazardous Decomposition Products:Hazardous decomposition products may include oxides ofcarbon, nitrogen and various hydrocarbon fragments.Hazardous Polymerization:Hazardous polymerization may occur. Uncontrolled polymerization maycause rapid evolution of heat and increase in pressure that could result in violent rupture of sealed

storage vessels or containers.


Acrylated monomer Acute Oral toxicity LD50 > 5300 mg/kg body weight (supplier info)

Acrylated oligomer Acute Oral toxicity LD50 > 5000 mg/kg body weight (supplier info)

Photoinitiators Acute Oral Toxicity LD50 > 2500 mg/kg body weight (tested in rats)(supplier info)Acute Dermal Toxicity LD50 > 5000 mg/kg body weight (supplier info)

Individual components of this product are not reported to produce mutagenic effects in humans.None of the components of this material are listed by IARC, NTP, OSHA or ACGIH as carcinogens.


Keep product from waterways and watersheds. This substance is not readily biodegradable. Disposeof in accordance with all applicable federal, state and local regulations.

Acrylated monomer No data available

Acrylated oligomer No data available

Photoinitiators No data available


25/35



Dispose of in accordance with governmental regulations (community, national or regional). Contact alicensed professional waste disposal service to dispose of this mixture. As with all foreign substances,do not allow to enter the storm or sewer drainage systems. Avoid release to the Environment.Contaminated Packaging: Dispose of as unused product. Expose the open emptied container to light,

then dispose.


Department of transportation classification:Not hazardous by D.O.T. regulations

D.O.T. proper shipping name: Not regulated

Other requirements:N/A


The following provides a summary of the legal requirements.

EUROPEAN ECONOMIC COMMUNITY (EEC) CANADA REGS----------------------------------------------------------------------------------------------------------------------------------------Composants EPA* CA EINECS European Listed as EEC Symbol DSL NDSL

TSCA Prop65 Community dangerousStandards chemicals

per ESIS

Xi : Irritant,N : HarmfulR36/37/38,

Acrylated Yes No Yes None No R43/51/53 Yes Yesmonomer S3,S7/9,S20,

S26,S29,S37/39

Xi; Irritant,R36/37/38,

Acrylated Yes No Yes None No R43 Yes Yesoligomer S3,S7/9,S20,

S26,S29,S37/39

Photoinitiators Yes No Yes None No H303, H402 Yes No

All the components present in this product at concentrations equal to or greater than 0.1% are listed,or excluded from listing, on the United States Environmental Protection Agency Toxic SubstancesControl Act (TSCA) inventory.

Substance Preparation Classification : Harmful & Irritant

FULL TEXT OF ANY R-PHRASES AND S-PHRASES:

Risk Phrases:R36/37/38 -- Irritating to eyes, respiratory system and skin

R43 -- May cause sensitization by skin contactR51/53 -- Toxic to aquatic organisms, may cause long-term adverse effects inthe aquatic environment.


26/35


Safety Phrases:S3 -- Keep in a cool placeS7/9 -- Keep containerS20 When using do not eat or drinkS26 -- In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS29 Do not empty into drains

S36 -- Wear suitable protective clothingS37/39 -- Wear suitable gloves and eye/face protection

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III,Section 302.

Pursuant to Title III of the Superfund Amendments and Reauthorization Act of 1986, (SARA) and 40CFR 372 Part 372, this product does not contain chemicals subject to the reporting requirementsunder Section 313.

California Proposition 65: This product does not contain chemicals which are known to the state ofCalifornia to cause cancer.


HMIS (Hazardous Materials Information System) for secondary labeling:

HEALTH 2

FIRE HAZARD 1

REACTIVITY 1

PERSONAL PROTECTIVE EQUIPMENT D

REFERENCES:

1. 2011 Threshold Limit Values and Biological Exposure Indices. American Conference ofGovernmental Industrial Hygienists.2. MSDS + Cheminfo CD-ROM, Canadian Centre for Occupational Health and Safety3. SAXS Dangerous Properties of Industrial Materials, Tenth Edition4. TSCA & SARA Title III, U.S. Environmental Protection Agency and the National TechnicalInformation Services5. Raw Material Manufacturers Material Safety Data Sheets6. US National Institute of Medicines Toxnet current edition7. ESIS: European Chemical Substance Information System, http://ecb.jrc.it/esis8. NOHSC Hazardous Information Substances Information System, Department of Employment and

Workplace Relations, Australian Government, 2005

To the best of our knowledge the information contained herein is accurate. However, 3D-Materials makesno warranty, expressed or implied regarding the accuracy of these results to be obtained from the usethereof. Although certain hazards are described herein, we cannot guarantee that these are the onlyhazards that exist. 3D-Materials assumes no responsibility for injury from the use of the productdescribed herein.

DISCLAIMER OF LIABILITY: The following supersedes any provision in the forms, letters and agreementsbetween your business and 3D-Materials.3D-Materials makes no direct or indirect guarantee for this product, including warranties ofmerchantability or fitness for a particular purpose. 3D-Materials shall in no event be liable for incidental,consequential or other resulting from alleged negligence, breach of warranty, strict liability or any othertheory is, after the use or handling of this product. The sole liability of 3D-Materials, as part of anapplication any compensation in connection with the manufacture, use or sale of its products is limited to

the purchase price paid by the purchaser. The content of this MSDS may be changed without notice.3D-Materials invites you to periodically check their website to make sure you have the most recent MSDS.


27/35


28/35

3D-Materials - Advanced Photopolymer Resins - 3DM-Cast series / MSDS - update 14/11/2014 1

3D-MaterialsAdvanced Photopolymer Resins

MATERIAL SAFETY DATA SHEETaccording to regulation (EC) No 1907/2006 (REACH)

HARMFUL & IRRITANT SUBSTANCE

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Identification : Photopolymer 3DM-Cast seriesProduct Class : Mixture of acrylic acid esters, acrylated monomers, oligomers, synthetic waxes andphotoinitiators.Product Use :Use for stereolitography 3D printers with UV-Visible light systems.

Company :3D-MaterialsFranceMail : [email protected] : www.3d-materials.org

Date of Preparation: 06/21/2014

For Emergencies: call 112 (for UE) or 911 (for USA)


A. EMERGENCY OVERVIEW

This product is a liquid acrylic based resin with a characteristic light odor. This product may causeskin, eyes and respiratory system irritation, and skin sensitization/allergic reaction by skin contact.Inhalation of high vapor concentration may cause headaches and nausea.

B. TARGET ORGANS OR SYSTEMS

Skin, Eyes, Respiratory System, Central Nervous System

C. ROUTE OF EXPOSURE:

Skin Contact, Eye Contact, Inhalation, Ingestion

D. SIGNS AND SYMPTOMS OF EXPOSURE:

Acute:

Skin Contact -- May cause skin irritation. Symptoms may include a slightly localized redness or rashand swelling. Repeated exposure may cause sensitization and allergic skin reaction in someindividuals resulting in contact dermatitis, severe irritation, dryness and cracking.

Eye Contact -- May cause eye irritation. Symptoms may include excessive tearing, itching, irritation,blinking and redness.

Inhalation -- This product is a suspect slight respiratory tract irritation hazard, especially if used atelevated temperature or processes which may generate aerosols or mists. Symptoms of irritation mayinclude coughing, headache and nausea, mucous production and shortness of breath.


29/35


Ingestion -- The product may be harmful if swallowed. It may cause nausea, headache, vomiting,diarrhea, and/or central nervous system effects. Keep all food in an area separate from storage anduse locations.Prohibit eating, drinking and smoking in areas where there is a potential for significant exposure to thismaterial. Thoroughly wash hands before eating.

Chronic:

Inhalation -- Prolonged or repeated overexposure may cause irritation, headache, and nausea.

Skin Contact -- May cause sensitization and allergic reaction. May cause more significant irritation inpeople with pre-existing skin conditions.

Eye Contact -- May cause redness of eye tissue.

Ingestion -- May be a slight ingestion hazard if swallowed. Chronic ingestion of high doses may causedamage to testes, as shown in animal studies.

Carcinogens:

There are no carcinogens in concentrations of 0.1 percent or greater in this product.Potential Environmental Effects: Not readily biodegradable. Avoid release to the environment. Disposeof in accordance with all applicable federal, state and local regulations.


Components Approximate C.A.S. No. & UK/EU Classification% by weight EINECS No. Directive 67/548/EEC

Acrylated momomer Proprietary Proprietary Xi(Irritant),N(Harmful), R36/37/38

R43/51/53S3, S7/9, S20, S26,S29,S37/39

Acrylated oligomer Proprietary Proprietary Xi(Irritant), R36/37/38,R43S3, S7/9, S20, S26,S29, S37/39

Synthetic waxes Proprietary Proprietary None

Photoinitiators Proprietary Proprietary H303, H402

4. FIRST-AID MEASURES

Emergency Overview:This product is a liquid opaque acrylic based resin with an acrylatecharacteristic odor. This product may cause skin and eye irritation. The inhalation of high vaporconcentration may cause a headache and nausea.

Inhalation:In case of exposure to a high concentration of vapor or mist, remove person to fresh air.If breathing has stopped, administer artificial respiration and seek medical attention.

Eye Contact:Immediately flush with plenty of clean water (under eye lids) for at least 20 minutes.Hold eyelids apart to ensure flushing.


30/35


Washing within one minute of contact is essential to achieve maximum effectiveness. Seek medicalattention immediately. Do not apply oil or oily ointments unless ordered by a physician.

Skin Contact:Remove contaminated clothing and rinse contact area thoroughly with soap and water.Particular attention should be paid to hair, nose, and ears, and other areas not easily cleaned. Washclothing before reuse. If irritation develops, consult a physician.

Ingestion:If ingested dilute with water by giving glasses of water or milk to the victim. Do not giveanything by mouth if the victim is rapidly losing consciousness, is unconscious, or convulsing. Do notinduce vomiting. If vomiting occurs naturally, keep airways clear. Get medical attention. Provide anestimate of the time at which the material was ingested and the amount of the substance that wasswallowed.


Flash point: > 100C / 212FMethod: SetaflashIgnition temperature: n.d

Lower explosion limit: n.dUpper explosion limit: n.d

Extinguishing media:Use carbon dioxide or dry chemical for small fires; aqueous foam or waterspray for large fires.

Special firefighting procedures:Firefighters should wear full protection clothing and self-containedbreathing apparatus (SCBA).Thoroughly decontaminate firefighting equipment including all firefighting apparel after the incident.

Unusual Fire & Explosion:Emits irritating vapors. High temperatures, accidental impurities, orexposure to radiation or oxidizers may cause spontaneous polymerization generating heat/pressureand rupture/explosion of closed containers.

Exposure Hazard(s): Material Harmfull & Irritant


Procedures of Personal Precautions: Wear adequate personal protective clothing and equipment,as outlined in Section 8.

Environmental Precautions:Contain spill to prevent spread into drains, sewers, water supplies, orsoil. Avoid release to the Environment. Dispose of in accordance with all applicable federal, state andlocal regulations.

Methods of Cleaning Up:In the event of a spill, immediately remove all sources of ignition. Cover theliquid with inert absorbent. Using appropriate personal protective equipment and non-sparking tools,contain spilled material.

Waste Disposal Method:Do not dispose to sewers, lakes, rivers or streams. Scoop all contaminatedmaterial into compatible bottles or drums for proper disposal. Dispose of in accordance with allapplicable federal, state and local regulations. National or regional provisions may also be in force.


Handling Precautions:User Exposure -- This product should be used in well-ventilated areas.

Product may cause irritation. Avoid contact with eyes. Avoid prolonged or repeated contact with skin.Wash hands with soap and water before eating, drinking, smoking, applying cosmetics, or using toiletfacilities. Launder contaminated clothing before reuse. Contaminated leather articles, including shoes,


31/35


cannot be decontaminated and should be destroyed to prevent reuse. Solvents should never be usedto clean hands or skin because they increase the penetration of the material into skin.

Storage Precautions: Suitable -- Store in a cool, dry place out of direct sun light, in opaque or ambercontainers. Store the containers at 10-35C (50-95F). Do not exceed 50C (122F) when in storage.Keep containers closed. Avoid ignition sources.

Special Requirements:Do not heat containers with steam or electrical equipment. Heating thisproduct above 100C (210F) in the presence of air may cause slow oxidative decomposition; above150C (300F) polymerization may occur. Fumes and vapors from this thermal decomposition may bedangerous for health (nitrous vapors, carbon monoxide-carbon dioxide). Do not breathe fumes.

8. EXPOSURE CONTROLS & PERSONAL PROTECTION

EXPOSURE LIMITS:

Components HSIS Australia IOELVs (UK) ACGIH TLV OSHA PEL WEEL

Acrylated monomer None None None None NoneAcrylated oligomer None None None None NoneSynthetic waxes None None None None NonePhotoinitiators None None None None None

No occupational exposure limit values exist for the materials contained in this product.

Notations:IOELVs (Indicative Occupational Exposure Limit Values)TWA (time weighted average)OEL (Occupational Exposure Limits)PEL (Permissible Exposure Limit)TLV (Threshold Limit Value)

STEL (Short Term Exposure Limit)WEEL (Workplace Environmental Exposure Level by the American Industrial Hygiene Association)

EXPOSURE CONTROLS:

Ventilation Controls:Ensure adequate ventilation.

Respiratory Protection:Respirators are generally not needed under normal conditions of use. If thismaterial is handled at elevated temperature, under mist forming conditions or in case of accidentalrelease of large quantities of product use a full-face respirator with multi-purpose combination (US) ortype ABEK (EN 14387) respirator cartridges as a backup to engineering controls. Use respirators andcomponents tested and approved under appropriate government standards such as NIOSH (US) orCEN (EU).

Protective Gloves:Wear impervious gloves (nitrile or neoprene) for routine handling.

Eye and Face Protection:Chemical splash goggles or a face shield is recommended duringoperations where splashing could occur.

Skin Protection:Avoid all skin contact. Depending on the conditions of use, cover as much of theexposed skin area as possible by wearing gloves, aprons, long pants, and long sleeved shirts.

Other Controls:For operations where contact can occur a safety shower and eye wash facility shouldbe available. Always use good personal hygiene and housekeeping practices. Wash thoroughly afterhandling.

Environmental Exposure Controls:Keep product from waterways and watersheds. This substanceis not readily biodegradable and dangerous for the environment. Avoid release to the environment.


32/35


9. PHYSICAL & CHEMICAL PROPERTIES

Appearance: Liquid resinOdor: Characteristic / AcrylateSpecific Gravity: 0.98 1.05 g/cmBoiling Point: > 100 C

Flash Point: > 100 CIgnition Temperature: n.d.Lower Explosion Limit: n.d.Upper Explosion Limit: n.d.Viscosity @ 25C (77F) n.d.Vapour pressure: not establishedSolubility in water: not establishedSolubility in organic solvents: soluble in organic solventsVolatile characteristics: negligibleElectrostatic discharge: safeElectric conductivity: dielectric


Stability:Stable when stored in original container designed for use with light sensitive materials under35C (95F) in dark, cool place.

Conditions to Avoid:Storage > 40C (100F),exposure to light, loss of dissolved air, andcontamination with incompatible materials.

Incompatible Materials to Avoid: Polymerization initiators, including peroxides, strong oxidizingagents, alcohols, copper, copper alloys, carbon steel, iron, rust, and strong bases.

Hazardous Decomposition Products:Hazardous decomposition products may include oxides ofcarbon, nitrogen and various hydrocarbon fragments.Hazardous Polymerization:Hazardous polymerization may occur. Uncontrolled polymerization maycause rapid evolution of heat and increase in pressure that could result in violent rupture of sealedstorage vessels or containers.


Acrylated monomer Acute Oral toxicity LD50 > 5300 mg/kg body weight (supplier info)

Acrylated oligomer Acute Oral toxicity LD50 > 5000 mg/kg body weight (supplier info)

Synthetic waxes Acute Oral toxicity LD50 > 5000 mg/kg body weight (supplier info)

Acute Dermal Toxicity LD50 > 2000 mg/kg body weight (supplier info)

Photoinitiators Acute Oral Toxicity LD50 > 2500 mg/kg body weight (supplier info)

Acute Dermal Toxicity LD50 > 5000 mg/kg body weight (supplier info)

Individual components of this product are not reported to produce mutagenic effects in humans.None of the components of this material are listed by IARC, NTP, OSHA or ACGIH as carcinogens.


Keep product from waterways and watersheds. This substance is not readily biodegradable. Dispose

of in accordance with all applicable federal, state and local regulations.


33/35


Acrylated monomer No data available

Acrylated oligomer No data available

Synthetic waxes No data available

Photoinitiators No data available


Dispose of in accordance with governmental regulations (community, national or regional). Contact alicensed professional waste disposal service to dispose of this mixture. As with all foreign substances,do not allow to enter the storm or sewer drainage systems. Avoid release to the Environment.Contaminated Packaging: Dispose of as unused product. Expose the open emptied container to light,then dispose.


Department of transportation classification:Not hazardous by D.O.T. regulations

D.O.T. proper shipping name: Not regulated

Other requirements:N/A


The following provides a summary of the legal requirements.

EUROPEAN ECONOMIC COMMUNITY (EEC) CANADA REGS----------------------------------------------------------------------------------------------------------------------------------------Composants EPA* CA EINECS European Listed as EEC Symbol DSL NDSL

TSCA Prop65 Community dangerousStandards chemicals

per ESIS

Xi : Irritant,N : HarmfulR36/37/38,

Acrylated Yes No Yes None No R43/51/53 Yes Yesmonomer S3,S7/9,S20,

S26,S29,S37/39

Xi; Irritant,R36/37/38,

Acrylated Yes No Yes None No R43 Yes Yesoligomer S3,S7/9,S20,

S26,S29,S37/39

Synthetic Yes No Yes None No None Yes Yeswaxes

Photoinitiators Yes No Yes None No H303, H402 Yes No


34/35


All the components present in this product at concentrations equal to or greater than 0.1% are listed,or excluded from listing, on the United States Environmental Protection Agency Toxic SubstancesControl Act (TSCA) inventory.

Substance Preparation Classification : Harmful & Irritant

FULL TEXT OF ANY R-PHRASES AND S-PHRASES:

Risk Phrases:R36/37/38 -- Irritating to eyes, respiratory system and skinR43 -- May cause sensitization by skin contactR51/53 -- Toxic to aquatic organisms, may cause long-term adverse effects inthe aquatic environment.Safety Phrases:S3 -- Keep in a cool placeS7/9 -- Keep containerS20 When using do not eat or drinkS26 -- In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS29 Do not empty into drains

S36 -- Wear suitable protective clothingS37/39 -- Wear suitable gloves and eye/face protection

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III,Section 302.

Pursuant to Title III of the Superfund Amendments and Reauthorization Act of 1986, (SARA) and 40CFR 372 Part 372, this product does not contain chemicals subject to the reporting requirementsunder Section 313.

California Proposition 65: This product does not contain chemicals which are known to the state ofCalifornia to cause cancer.


HMIS (Hazardous Materials Information System) for secondary labeling:

HEALTH 2

FIRE HAZARD 1

REACTIVITY 1

PERSONAL PROTECTIVE EQUIPMENT D

REFERENCES:

1. 2011 Threshold Limit Values and Biological Exposure Indices. American Conference ofGovernmental Industrial Hygienists.2. MSDS + Cheminfo CD-ROM, Canadian Centre for Occupational Health and Safety3. SAXS Dangerous Properties of Industrial Materials, Tenth Edition4. TSCA & SARA Title III, U.S. Environmental Protection Agency and the National TechnicalInformation Services5. Raw Material Manufacturers Material Safety Data Sheets6. US National Institute of Medicines Toxnet current edition7. ESIS: European Chemical Substance Information System, http://ecb.jrc.it/esis

8. NOHSC Hazardous Information Substances Information System, Department of Employment andWorkplace Relations, Australian Government, 2005


35/35

To the best of our knowledge the information contained herein is accurate. However, 3D-Materials makesno warranty, expressed or implied regarding the accuracy of these results to be obtained from the usethereof. Although certain hazards are described herein, we cannot guarantee that these are the onlyhazards that exist. 3D-Materials assumes no responsibility for injury from the use of the productdescribed herein.

DISCLAIMER OF LIABILITY: The following supersedes any provision in the forms, letters and agreementsbetween your business and 3D-Materials.

3D-Materials makes no direct or indirect guarantee for this product, including warranties ofmerchantability or fitness for a particular purpose. 3D-Materials shall in no event be liable for incidental,consequential or other resulting from alleged negligence, breach of warranty, strict liability or any othertheory is, after the use or handling of this product. The sole liability of 3D-Materials, as part of anapplication any compensation in connection with the manufacture, use or sale of its products is limited tothe purchase price paid by the purchaser. The content of this MSDS may be changed without notice.3D-Materials invites you to periodically check their website to make sure you have the most recent MSDS.

resinas hojas de seguridad

Documents