anexo iv hojas de seguridad

8/10/2019 Anexo IV Hojas de Seguridad

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Monday, April 23, 2012

To: GAS NATURAL SDG S.A Avenida SAN LUIS 77 pl. EN28033 Madrid (Espaa)

Re: Compliance with EU Regulation on Registration, Evaluation, Authorization and Restriction of Chemicals (EC 1907/2006) (REACH)

Dear Customer,

We are writing in relation to the above mentioned regulation which came into force in June 2007 and in responseto your recent inquiry.

REACH is an on-going compliance process which will have a significant impact to the business of allmanufacturers, importers and downstream chemical users. All have specific obligations under the newlegislation, and at M-I SWACO we are committed to ensuring full continuity of business relationships, throughoutthe implementation of REACH.

We wish to assure you that M-I SWACO (or our upstream supplier) has pre-registered all non exempt substanceswe manufacture and/or import into the EU.

REACH requires, amongst other obligations:

pre-registration with the European Chemicals Agency of certain substances (as such, or contained inpreparations/mixtures to the extent where they are not covered by other more specific legislation, or, inarticles if substance is intended to be released during conditions of use) manufactured/used in, or imported into, the European Economic Area (EEA) by December 1 2008; and

Subsequent registration of certain substances by specified deadlines, depending on the hazard profileand/or annual manufacture, use or import volumes of the substance by the registrant in question.

Further information and guidance on the REACH Regulation can be found on the European Chemicals Agency(ECHA) website (http://echa.europa.eu/home_en.asp).

Compliance with REACH is essential for the future marketing in the EEA of both M-I SWACO products and any of your products which incorporate M-I SWACOs product(s). M-I SWACO is therefore dedicated to ensuringeffective REACH compliance for all M-I SWACO products placed on the EEA market whilst maintaining our relationships with our customers and avoiding business interruption.

All of M-I SWACO chemicals used are either compliant with REACH requirements or are exempt from REACHregistration requirements either because they are listed in the relevant annex or covered under other legislation.


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Regarding your specific inquiry on the products, please see below answers:

Please note that the following products are considered exempt under REACH.

Product nameBARITECalcium CarbonateMICA FINEMICA MEDIUMNUT PLUG FINEKWIK-SEALMIKHART 0.35 0.7MIKHART 130MIKHART 10

MIKHART 10MIKHART 65NUT PLUG FINESUGAR

For the products below; please be assured that all the non exempt substances present in the product are REACHcompliant; non exempt substances will be registered by M-I SWACO or our upstream supplier.

Product nameKCLKOHXCD Polymer Polypac ULPOLYPAC REGULARSODA ASHBICARBONATEDEFOAM X-EHSOLTEXLUBE 167POTASSIUM CARBONATEGLYDRIL MCPOLYPLUS LIQUIDSAFE SCAV NASAFE CIDESAFE COR


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We trust this satisfies your initial inquiry and we will keep you updated on any developments affecting supply toyour company.

For further questions regarding REACH, you can contact any member of our REACH Implementation Team [email protected] or send an email to [email protected]. You can also find more about our commitment to REACH in the QHSE portion of the M-I SWACO website athttp://www.slb.com/services/miswaco/qhse/reach.aspx

Kind regards,

Chioma Smith

Chemical Regulatory Specialiston behalf of the M-I SWACO REACH Compliance Team


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32/94

SAFETY DATA SHEET

(According to Regulation (EC) No. 1907/2006 of 18.december 2006, article 31)

Date of issue: 14.1.2011 Page: 1 / 9Date of revision: 5.10.2011(CLP)Product name: POTASSIUM CARBONATE

AG CHEMI GROUP s.r.o. Tel.: +420 233 371 850Rybnin 18/1 Fax: +420 233 371 860162 00 Prague 6 E-mail: [email protected] Republic / Europe www.agchemigroup.eu

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THECOMPANY/UNDERTAKING 1.1 Product identifier:

Name: Potassium carbonate

Further names of the product:Annex I index: Substance is not listed in Annex XIV or XVII of REACH Regulation

Registration number: 01-2119532646-36-0010 111nvcncn1111

1.2 Appopriate specified applications ofthe substance /mixture and nonrecommended applications:Specified applications: Industrial and professional uses: In the ceramics, glass,

detergents and leather industries, alkalizing of the cocoaindustry, fertilizer industry, in preparations for constructions,water treatment agents, antifreeze or de-icing products. In theetching process and absorption of acid gases (CO 2 andH2S). Consumption uses De-icing or antifreeze products,disinfectants, paints, fertilizers, inks, detergents, plasticproducts, stone, concrete, glass, ceramic, metal, paper, rubber,wood.

Non recommended applications: No significant not recommended use is reported.

1.3 Detailed particulars about the providerof the safety data sheet:Importer: AG CHEMI GROUP s.r.o.Place of business or domicile: Rybnin 18/1 162 00 Praha 6Identification number: 61508195Telefon: +420 233 371 850Fax: +420 233 371 860E-mail: director@agchemiegroup. eu (ing.Igor evenko) Web: http://www . agchemigroup.euSkilled advisor: Ing. Ladislav Folberger

1.4 Emergency phone: In the Czech republic:Toxikologick informan stedisko, Na Bojiti 1, 128 08, Praha 2 Telefon (24 hours/day):+420 2 2491 9293+420 2 2491 5402
mailto:[email protected]:[email protected]://www/http://www/http://www/mailto:[email protected]


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SAFETY DATA SHEET




+420 2 2491 4575

Information concerning health risks acute poisoning of peopleand animals only

SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the substance/

mixture:Codes of class and category of dangerAccording to Regulation 1272/2008EC:

Skin irritation cat.2Eye irritation cat.2STOT Single Exp.3

Codes of standard hazard phrases H 315; H 319; H 335 According to European Directive67/548/EEC:

Xi - Irritant Classification: Xi - Irritant R - phrases R 36/37/38 Irritant to eyes, respiratory system and skin.

2.2 Label elements:

Signal word WarningStandard hazard phrases H 315 Causes skin irritation

H 319 Causes serious eye irritationH 335 May cause respiratory irritation

Precautionary statements P261: Avoid breathing dust/fume/gas/mist/vapours/spray.P264: Wash with soap and water thoroughly after handling.P280: Wear protective gloves/protective clothing/eye protection/face protection.P305+P351+P338: IF IN EYES: Rinse cautiously with waterfor several minutes. Re-move contact lenses, if present andeasy to do. Continue rinsing.P362: Take off contaminated clothing and wash before reuse.P403+P233: Store in a well-ventilated place. Keep containertightly closed.

2.3 Further hazards: Not applicable

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTSIdentifier of main substance:

Chemical name: Potassium carbonateSynonyms:


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SAFETY DATA SHEET




Content (%): 92,5 98,0 %CAS number: 584-08-7EC (EINECS) number: 209-529-3Index number: Not listedHazard: Skin Irrit.2 H 315; Eye Irrit. 2 H 319; STOT Single Exp.3 H 335;

Xi R 36/37/38Remark: -

For the full text of the H and R - Statements mentioned in this Section, see Section 16.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures: Immediately transport the victim from the contaminated area,tak deep breat hs of fresh air

In case of aspiration: Move to fresj air. Rinse immediately with plenty of water: mouth,face, eyes. Obtain medical treatment if necessary.

In case of skin contact: Wash off with plenty of water. Take off contaminated clothing.In case of eye contact: Rinse out with plenty of water with the eyelid held wide open. If

pain persists, call in ophthalmologist.

If swallowed: Make victim drink plenty of water. Induce vomiting. Summondoctor.

4.2 Most important acute and delayedsymptoms and effects:

May cause slight irritation to the respiratory tract, mucousmembranes of nose and throat. Irritating to eyes. Cancause redness, tearing, pain and weakness of vision. May causeirritation, dryness and redness of the skin. After consuming largeamounts casualty may experience vomiting, stomach pain,

diarrhea.4.3 Indication of any immediate medical

attention and special treatmentneeded:

Notes to physician: treat symptomatically. If large quantitiesswallowed, immediately contact a doctor specialized in poisoning.

SECTION 5: FIRE-FIGHTING MEASURESSuitable extinguishing media: Depending on materials stored in the nearest neighborhood All

extinguishing products are allowed: water, water/foam, carbondioxide CO2, extinguishing powder.

Unappropriate extinguishing media: Do not use dense streams of water.

5.2 Particular hazards resulting from thesubstance/mixture

When heated to decomposition toxic gas and fumes of carbondioxide CO2 are emitted.

5.3 Guidelines for fire-brigade Isolate the area by removing all persons from the surrounding ofthe accident, when a fire broke out. Do not tak any actioninvolving any personal risk. Fire fighters should wear appropriate


35/94

SAFETY DATA SHEET




protecitive equipment and breathing apparatus.

The product is not flammable.

SECTION 6: ACCIDENTAL RELEASE MEASURES6.1 Personal precautions : For non-emergency personnel:

Do not take any action that could cause personal risk unless youare properly trained. Do not touch or walk through spillage ofmaterial. Wear appropriate personal protective equipment.For emergency responders:Workwear, respiratory protection (fabric or protective masks withparticle filter P2), tight-fitting goggles, gloves.

6.2 Environmental precautions : Should not be released into the environment. When such

situation occurs, call the relevant health and environmentalprotection authorities.6.3 Methods and materials for containment

and cleaning up :Sweep up or vacuum up spillage and collect in suitable containerfor disposal. Avoid dust formation. Residues rinse with water.

6.4 References to others sections: Information on appropriate personal protective equipment isspecified in section 8. Information regarding waste treatment isgiven in section 13.

SECTION 7: HANDLING AND STORAGE7.1 Precautions for safe handling : Wear personal protective equipment. Use of the basic principles

of Industrial Hygiene. Ensure adequate ventilation. Do not get ineyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoiddust formation.Eating, drinking and smoking in areas where the material ishandled, stored and processed should be forbidden. Workersshould wash hands and face before eating, drinking and smoking.

7.2 Conditions for safe storage includingnon compatible matters and mixtures

Store in a tightly closed container. Keep containers in a cool, well-ventilated place. Do not use light-weight-metal containers. Do notstore together with alkalies. Warehouse personnel must beequipped with the necessary protec-tive equipment.

7.3 Specific final application/applications: No specific end uses

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Controlling parametres:

Limits of exposition set byGovermental decree No.361/2007 Sb.:

There is no specific emission limit set especially for thissubstance


36/94

SAFETY DATA SHEET




Substance name

(Component):Carbonates ofalcaline metals

CAS: PEL = 5 mg/m 3 NPK-P = 10 mg/m 3 Remark:

Producer announces treshold limit value for dust and power: 10 mg/m 3

Recommended monitoring procedures: atmosphere or biological monitoring may be required to determinethe effec-tiveness of the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European Standard EN 689 for methods for theassessment of exposure by inhala-tion to chemical agents and national guidance documents for methodsfor the determination of hazardous substances.DNEL No data availablePNEC No data available

8.2 Exposition minimising:

Exposition minimising of workers: After work wash the skin and take off contaminated clothes. Donot eat, drink, smoke or take drugs during the work.

Respiratory protection: Fabric or protective masks with particle filter P2.Eye protection: Tight-fitting goggles.Hand protection: Protective gloves resistant to chemicals, made of nitrile rubber or

other approved by the manufacturer to contact with the product.

Skin and body protection: Protective clothing of a compact fabric. Working boots.Additional information: Prior to handling with this product, please select the appropriate

footwear and addition-al skin protection measures, based on thetasks performed and the associated risks. They are subject toapproval by the Health and Safety Specialist

Environment protection: Emissions from ventilation or work process equipment should bechecked to ensure they comply with the requirements ofenvironmental protection legislation.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties

Appearance: Solid fine white crystalsOdour or smell: OdourlessTreshold value of odour: -pH (at 20 C): 11,5 12,5 (50 g/L)Melting point / Freezing point: 891 C Flash point (C): Not applicableInitial boilling point and distillationrange (C):

No data available

Solubility in water: 110 g/L 20 C


37/94

SAFETY DATA SHEET




Flammability: Not flammable

Relative density: 2270 2430 kg/m 3Bulk density: 750 kg/m 3

9.2 Additional information: No data

SECTION 10: STABILITY AND REACTIVITY10.1 Reactivity: No

10.2 Chemical stability: Stable10.3 Possibility of hazardous reactions: No possible reactions10.4 Conditions to avoid: Humidity10.5 Incompatible materials: Acids10.6 Hazardous decomposition products: Under normal conditions of storage and use the product does not

decompose.

SECTION 11: TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects

Acute toxicity: DL 50 Rat, oral > 2000 mg/kgSkin corrosion/irritation: Causes skin irritationSerious eye damage/eye irritation: Causes serious eye irritationRespiratory or skin sensitization: May cause respiratory irritationGerm cell mutagenicity: No data availableCarcinogenicity: No data availableReproductive toxicity: No data availableSpecific target organ toxicity - single

exposure:

May cause respiratory irritation

Specific target organ toxicity -repeated exposure:

No data available

Aspiration hazard No data available

Information on likely routes ofexposure:

Inhalation, skin/eyes,ingestion

Symptoms related to physical,chemicaland toxilogical characteristics:

Contact with skin:Irritation with redness. Defatting of the skin.Contact with eyes:Irritation with redness and tearing. Eyesight damage may occur.Inhalation of dust:Coughing,sore throat, respiratory tract irritation.Ingestion:Nausea, sore throat, esophagus, stomach pain. Swallowing largequantities can cause intestinaL perforation.


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SAFETY DATA SHEET




Delayed and immediate effects as well

as chronic effects from short and long-term exposure:

No data available

Interactive effects: No data available

Other information: No other information.

SECTION 12: ECOLOGICAL INFORMATION12.1 Toxicity:

Fish: LC 50 stickleback: 70 mg/L 48 hours Algae: No dataInvertebrates: EC 50 daphnia: 160 mg/L 6 hoursBacteries: No data

12.2 Persistence and degradability : Soluble in water, increases pH12.3 Bioaccumulative potential : Not applicable12.4 Soil mobility: No data12.5 PBT and vPvB assessment : This substance is neither PBT nor vPvB12.6 Other adverse effects Hard depands on the pH. In small quantities is not hazardous to

the environment.

SECTION 13: DISPOSAL CONSIDERATIONS:13.1 Methods for waste disposal: The generation of waste should be avoided or minimized

wherever possible. Significant quantities of waste productresidues should not be disposed of via the foul sewer butprocessed in a suitable effluent treatment plant. Dispose ofsurplus and non-recyclable products via a licensed wastedisposal contractor. Disposal of this product, solutions andany by-products should at all times comply with therequirements of environmental protection and wastedisposal legislation and any regional local authorityrequirements.

SECTION 14: TRANSPORT INFORMATION14.1 UN number: Not applicable14.5 Kemler code: Not applicable14.2 Proper shipping name UN for consignment: Not applicable

Surface transportation ADR: Not applicableRailway transportation RID: Not applicableSea transportation IMDG: Not applicable

Air transportation ICAO/IATA: Not applicable14.3 Class / Classes of danger for transportation : Not applicable


39/94

SAFETY DATA SHEET




14.4 Packing group: Not applicable14.6 Danger for environment: Not applicable14.7 Special safety measures for the user: Not applicable

Addition information: Durin transport avoid the influence of humidity!14.8 Bulk transportation according to appendix II MARPOL 73/78 and decree IBC: No data

SECTION 15: REGULATORY INFORMATION15.1 Regulation concerning safety, health and environement / specific legal regulations concerning the product

or mixture:In the Czech republic:Law 356/2003 Sb., and respective implementing regulationsLaw 102/2001 Sb., in valid versionLaw 185/2001 Sb., in valid version

see 44a of the Law 258/2000 Sb., Part 8 section (6); (8); (9) and (10) Regulation EU 1907/2006 (REACH)Regulation EU 1272/2008 (CLP)

15.2 Chemical safety assessment: Not applicable15.5 Further regulations: This substance is not SVHC and is not listed in the Annex XIV or

XVII of REACH Regulation

SECTION 16: OTHER INFORMATIONChanges of MSDS made within framework of revision:This MSDS was worked out in compliance with CLP demands. Compared to the previous version of14.01.2011 was further clarified industrial, professional and consumer use.

Explications or legend to the used abbreviations:Skin Irrit. 2 Skin corrosion/irritation, Category 2Eye Irrit. 2 Serious eye damage/eye irritation Category 2STOT Single Exp.3 Specific target organ toxicity Single exposure Category 3Important references to literature and sources of information:MSDS of the producerList of relevant standard phrases (H phrases) / ( P phrases):H 315 Causes skin irritationH 319 Causes serious eye irritationH 335 May cause respiratory irritationP261: Avoid breathing dust/fume/gas/mist/vapours/spray.P264: Wash with soap and water thoroughly after handling.

P280: Wear protective gloves/protective clothing/eye protection/face protection.P305+P351+P338: IF IN EYES: Rinse cautiously with water


40/94

SAFETY DATA SHEET




for several minutes. Re-move contact lenses, if present andeasy to do. Continue rinsing.P362: Take off contaminated clothing and wash before reuse.P403+P233: Store in a well-ventilated place. Keep containertightly closed.R 36/37/38 Irritant to eyes, respiratory system and skinInstructions for staff training:Regular training on handling with chemicals

The above information is believed to be correct but does not purport to be all inclusive and shall be usedonly as a guide. The information is based on the preset knowledge and is applicable to the product withregard to appropriate safety precaution. It does not represent any guarantee of the properties of theproduct

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.


41/94

Potassium chlorideSafety Data Sheet

according to Regulation (EC) No. 1907/2006

Version:2Date: 20-06-2011

Supersedes: 04-07-2008

OA00130

20-06-2011 EN (English) 1/4

1. Identification of the substance/mixture and of the company/undertaking1.1. Product i dentifier

Product name - Trade name : Potassium chloride

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identi f ied uses

No additional information available

1.2.2. Uses advi sed agains t


1.3. Detai l s of the supplier of the safety data sheet

Univar Zwijndrecht N.V.Noordweg 33336 LH Zwijndrecht - NederlandT +31 (0)78 6250 000 - F +31 (0)78 6250 [email protected] - www.univareurope.com

1.4. Em ergen cy tel ep ho ne n um ber

Country Official advisory body Address Emergency number NETHERLANDS National Poisons Information Centre

National Institute for Public Health and the Environment, NB thisservice is only available to health professionals

P.O. Box 13720 BABilthoven

+31 30 274 88 88

2. Hazards identification2.1. Clas si fi cat ion o f the subst ance or mix tu re

2.1.1. Classification according to Regulation (EC) No. 1272/2008 [CLP]

Not classified

2.1.2. Classification according to Directive 67/548/EEC or 1999/45/EC

Not classified

2.1.3. Adverse physicochemical, human health and environmental effects

No additional information available2.2. Label elements

2.2.1. Labelling according to Regulation (EC) No. 1272/2008 [CLP]

No labelling applicable

2.2.2. Labelling according to Directive 67/548/EEC or 1999/45/EC

No labelling applicable

2.3. Other hazards


3. Compos it ion/informat ion on ingred ien ts3.1. Substances

Name Product identifier % Classification according toDirective 67/548/EEC

Potassium chloride (CAS No.) 7447-40-7(EC no) 231-211-8

~ 98 Not classified

Name Product identifier % Classification according toRegulation (EC) No.1272/2008 [CLP]

Potassium chloride (CAS No.) 7447-40-7(EC no) 231-211-8

~ 98 Not classified

Full text of R-, H- and EUH-phrases: see section 16.

3.2. Mixtures

Not applicable
mailto:[email protected]://www.univareurope.com/http://www.univareurope.com/mailto:[email protected]


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Potassium chlori deSafety Data Sheet


20-06-2011 EN (English) 2/4

4. First aid measures4.1. Des cr ip ti on o f fi rs t ai d meas ur es

After inhalation : Dust of the product, if present, may cause respiratory irritation after an excessive inhalationexposure. Seek medical attention if ill effect or irritation develops. Remove the victim into freshair.

After skin contact : Wash skin thoroughly with mild soap and water. After eye contact : Flush with lukewarm water for 15 minutes. After swallowing : Rinse mouth.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation : Not expected to be an irritant.Skin contact : Not expected to be an irritant.Eye contact : Not expected to be an irritant.

4.3. Indication of any immediate medical attention and special treatment needed


5. Firefighting measures5.1. Extinguishing media

Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

5.2. Special hazards ar ising f rom the substance or mixture


5.3. A dvi ce for fi refi ghters


6. Accident al release meas ures6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment : Avoid making dust.

6.1.2. For emergency responders


6.2. En vi ro nm en tal p rec au ti on s

Avoid release to the environment.

6.3. Methods and mater ial for containment and c leaning up

Methods for cleaning up : Contain and collect as any solid. Prevent entry to sewers, ground and public waters.

6.4. Ref er en ce t o o th er sec ti on s


7. Handling and storage7.1. Pr ec au ti on s f or saf e h an dl in g


7.2. Conditions for safe storage, including any incompatibili t ies

Technical measures : No special requirements.Storage : Store in dry, well-ventilated area.

7.3. Specific end use(s)


8. Exposure controls/personal p ro tec tion8.1. Control parameters



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20-06-2011 EN (English) 3/4

8.2. Exposure controls

- Hand protection : Wear gloves.- Eye protection : Safety glasses with side guards should be worn to prevent injury from airborne particles and/or

other eye contact with this product.- Skin protection : If skin contact or contamination of clothing is likely, protective clothing should be worn.- Respiratory protection : Approved dust or mist respirator should be used if airborne particles are generated when

handling this material.

9. Phy si cal and c hemical propert ies9.1. Informat ion on bas ic physical and chemical proper t ies

Appearance : Solid.Physical state : SolidColour : White.Odour : Odourless.pH value : 5,4-8,6 (5%)Melting point : 770 CBoiling point : 1420 CDensity : 1987 kg/lWater solubility : 340 g/kg

9.2. Other information


10. St abi li ty an d reac ti vi ty10.1. Reactivity


10.2. Ch em ic al s tab il it y

Stable under normal conditions.

10.3. Possibi l ity of hazardous react ionsNo additional information available

10.4. Co ndi ti on s t o av oi d

Moisture.

10.5. Incompat ib le mater ial s


10.6. Hazardous decomposi tion products


11. Tox icologi cal in format ion11.1. Informat ion on toxicological effec ts


12. Ecological i nf ormation12.1. Toxicity


12.2. Pers is tence and degradabi li ty


12.3. B ioaccumulat ive pot en ti al


12.4. Mobility in soil


12.5. Results of PBT and vPvB assessment


12.6. Other adver se ef fec ts



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20-06-2011 EN (English) 4/4

13. Dis posal cons ider at ions13.1. Was te t reatmen t methods

Waste treatment methods : Dispose in a safe manner in accordance with local/national regulations. Additional information : After last use, the packing should be totally empty and closed.

14. Transport inf ormationNo dangerous good in sense of transport regulations.

15. Regul atory i nf ormat ion15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations


15.1.2. National regulations

Water hazard class : 11 - Low toxicity to aquatic organisms

Remediation Efforts : B - Minimize discharge; apply best available techniques

15.2. Chemical s af ety as ses smen t


16. Other informationFurther information : The contents and format of this MSDS are in accordance with regulation (EC) no. 1907/2006 of

the European Parliament and Council of 18 December 2006 concerning the registration,evaluation, authorisation and restriction of Chemicals (REACH). Appendix Of the raw materialsin chapter 3 at moment of reporting of this material safety data sheet, chemical safety reportshave not been registered in the scope of regulation (EC) no. 1907/2006.

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore beconstrued as guaranteeing any specific property of the product.


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Page : 1

MATERIAL SAFETY DATA SHEET Revision nr : 3Date : 23 / 3 / 2009

Supersedes : 30 / 5 / 2006

Potassium hydroxide flakes CA25041

{ CLabel 8 : Corrosive C : Corrosivesubstance.1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

Trade name : Potassium hydroxide flakesUse : Industrial.Company identification : Univar Zwijndrecht N.V.

Noordweg 33336 LH ZwijndrechtTel.: +31 786250000Fax: +31 786250050E-mail: [email protected]: www.univareurope.com

Emergency phone nr : Contact your National Anti Poison Centre. (Only to be contacted by a physician)

2. HAZARDS IDENTIFICATION

Hazards identification : Corrosive.

3. COMPOSITION / INFORMATION ON INGREDIENTS

This product is considered to be hazardous and contains hazardous components.Substance name Value(s) CAS EG EC index ClassificationPotassium hydroxide : 50 to 100 % 1310-58-3 215-181-3 019-002-00-8 Xn; R22

C; R35

Other information : Full text of R-Phrases : see under section 16.

4. FIRST AID MEASURES

First aid measures- Prevention : Immediately remove contaminated clothing.- Inhalation : Dust from this product, if present, may cause respiratory irritation following an

excessive inhalation exposure.Seek medical attention if ill effect or irritation develops.Remove victim to fresh air.

- Skin contact : Wash skin thoroughly with mild soap and water.

- Eye contact : Flush with lukewarm water for 15 minutes.- Ingestion : Seek medical attention immediately.

Rinse mouth.

5. FIRE-FIGHTING MEASURES

Flammable class : Not combustible.Extinguishing media- Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

.


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Supersedes : 30 / 5 / 2006


5. FIRE-FIGHTING MEASURES (continued)

- Unsuitable extinguishing media : Water Special procedures : Evacuate unnecessary personnel.

Stop release.Special protection measures : S36 : Wear suitable protective clothing.

Use self-contained breathing apparatus

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Avoid making dust.Environmental precautions : Avoid release to the environment.Clean up methods : Contain and collect as any solid.

Prevent entry to sewers, ground and public waters.

Contaminated product, soil, water : Dispose in a safe manner in accordance with local/national regulations.

7. HANDLING AND STORAGE

GeneralPrecautions in handling and storage : Use good housekeeping practices to avoid rendering dust airborne.

Handle in accordance with good industrial hygiene and safety procedures.Storage : Store in dry, well-ventilated area.Storage - away from : Acids

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational Exposure Limits : Potassium hydroxide : MAC Value - France : 2 mg/m3Personal protection- Respiratory protection : Approved dust or mist respirator should be used if airborne particles are generated

when handling this material.- Hand protection : Wear gloves.- Eye protection : Safety glasses with side guards should be worn to prevent injury from airborne

particles and/or other eye contact with this product.- Skin protection : If skin contact or contamination of clothing is likely, protective clothing should be

worn.- Ingestion : When using, do not eat, drink or smoke.Industrial hygiene [

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : Flakes.Colour : White.Odour : Odourless.pH value : 14 (56g/l)Density : 2.04Melting point [C] : 360

.


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Supersedes : 30 / 5 / 2006


9. PHYSICAL AND CHEMICAL PROPERTIES (continued)

Bulk density [kg/m3] : 1200Solubility in water [g/100ml] : 112

10. STABILITY AND REACTIVITY

Stability : Stable under normal conditions.Conditions to avoid : Moisture.Materials to avoid : Acids

Metals.

11. TOXICOLOGICAL INFORMATION

Toxicity informationAcute toxicityEffects by ingestion : Harmful if swallowed.Effects on skin contact : Severe skin irritant.Effects on inhalation : Severe irritationEffects on eye contact : Severe eye irritant.On ingredientsPotassium hydroxide : Rat oral LD50 [mg/kg] : 365

12. ECOLOGICAL INFORMATION

Ecological effects information

On ingredientsPotassium hydroxide : LC50-96 Hour - fish [mg/l] : 80Other informationNational prescriptionsWGK class (Germany) : Water hazard class 1 : slightly hazardous for water General evaluation method (NL) : Water hazard class 11

Sanitizing effort B

13. DISPOSAL CONSIDERATIONS

Disposal method : Dispose in a safe manner in accordance with local/national regulations.Treatment of dirty packing : After last use, the packing should be totally empty and closed.

14. TRANSPORT INFORMATION

UN No. : 1813- Class : 8- Packing group : IILabelling ADR {

.


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Page : 4


Supersedes : 30 / 5 / 2006


14. TRANSPORT INFORMATION (continued)

- Warning panel : 80Proper shipping name : UN1813 POTASSIUM HYDROXIDE, SOLID, 8, IISea transport- IMDG-Marine pollution : No.- EMS-Nr : F-A, S-B

15. REGULATORY INFORMATION

EC Labelling : Classification and labelling following EC directives 67/548/EEC and 1999/45/EC andtheir adaptions to technical progres

Symbol(s) : Corrosive.Contains : EG : 215-181-3

Potassium hydroxideR Phrase(s) : R22 : Harmful if swallowed.

R35 : Causes severe burns.S Phrase(s) : S1/2 : Keep locked up and out of reach of children.

S26 : In case of contact with eyes, rinse immediately with plenty of water and seekmedical advice.S36/37/39 : Wear suitable protective clothing, gloves and eye/face protection.S45 : In case of accident or if you feel unwell, seek medical advice immediately (show the label when possible).

16. OTHER INFORMATION

List of relevant R phrases : R22 : Harmful if swallowed.R35 : Causes severe burns.

The contents and format of this MSDS are in accordance with regulation (EC) no. 1907/2006 of the European Parliament andCouncil of 18 December 2006 concerning the registration, evaluation, authorisation and restriction of Chemicals (REACH).

Appendix Of the raw materials in chapter 3 at moment of reporting of this material safety data sheet, chemical safety reportshave not been registered in the scope of regulation (EC) no. 1907/2006.

DISCLAIMER OF LIABILITY The information in this MSDS was obtained from sources which we believe are reliable. However, theinformation is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling,

storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, wedo not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected withthe handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If theproduct is used as a component in another product, this MSDS information may not be applicable.

End of document

.


49/94

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Safety Data Sheet in accordance with Annex II of Regulation EC 1907/2006(REACH), Regulation (EC) 1272/2008 and Regulation (EC) 453/2010

Product : SODIUM CARBONATE REACH Registration Number : 012119485498 190018 Issue Number : 02 Revision 01 Issue Date : 01042011 Supercedes : Issue No. 02, dated 1001 2011

Page Number : Page 1 of 27

Winnington Lane, Northwich, Cheshire, CW8 4DT, United KingdomTel +44 (0) 1606 72400 Fax +44(0) 1606 781353 w ww .tatac hemi cals .com

1.1 Product Identifier Product Name : SODIUM CARBONATE

Chemical Name : Sodium carbonate Alternative Name : Disodium carbonate, soda ash Chemical Formula : Na2CO3 CAS Number : 497 19 8 EC Number : 207 838 8 Index Number : 011 005 00 2 1.2 Relevant identified uses : glass production; intermediate in chemicals production; water

treatment chemicals; washing and cleaning products; other industrial, professional and consumer uses. Exposure scenarios covering uses can be found in the Annex

1.2.1 Uses advised against : none identified 1.3 Company Details

Company Name : Tata Chemicals Europe Address : Winnington Lane : Mond House : Northwich : Cheshire : CW8 4DT

Telephone : +44 (0)1606 724000 : +44 (0)1606 781353 : www.tatachemicals.com/europe : msds [email protected] 1.4 Emergency Telephone Number

Emergency Number (24 hours) : +44 (0)1606 781000

2.1 Classification of the substance

2.1.1 Classification according to Regulation (EC) 1272/2008 [CLP/GHS]

Classification: Eye Irritant 2

2.1.2 Classification according to Directive 67/548/EEC

Classification: Irritating to eyes

2.2 Labelling

2.2.1 Labelling according to Regulation (EC) 1272/2008 [CLP/GHS]

Hazard Pictograms:

Signal Word : Warning

Hazard Statements H319 : Causes serious eye irritation

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

2. HAZARDS IDENTIFICATION


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Precautionary Statements:

P264

P280 P305 + P351 + P338

P337 + P313

: Wash

hands

and

face

thoroughly

after

handling

: Wear protective gloves/protective clothing/eye protection/face protection : IF IN EYES, rinse cautiously with water for several minutes, remove contact

lenses, if present and easy to do. Continue rinsing : If eye irritation persists: Get medical advice/attention

2.2.2 Labelling according to Directive 67/548/EEC

Symbol : Xi irritant

Risk Phrases: R36 : Irritating to eyes

Safety Phrases: S2 S22 S24

: Keep out of the reach of children : Do not breathe dust : Avoid contact with skin

2.3 Other hazards The substance does not meet the criteria for PBT or vPvB according to Annex XIII of the REACH Regulation

EC 1907/2006 (an inorganic substance)

No other

hazards

identified

3.1 Substance

Main constituent Formula Purity %w/w (typical) CAS Number EC Number Sodium carbonate Na2CO3 >99.0 497 198 207 838 8

IMPURITIES No impurities relevant for classification and labelling

4.1 Description of first aid measures General advice

No known delayed effects

Following inhalation Remove to fresh air, keep warm and at rest If symptoms persist, seek medical attention

Following skin contact Remove contaminated clothing and wash before re use Wash off with soap and water If symptoms persist, seek medical attention

Following eye

contact

Remove contact lenses if present Irrigate eye thoroughly with eye wash solution or clean water for at least 15 minutes

3. COMPOSITION INFORMATION ON INGREDIENTS

4. FIRST AID MEASURES


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Eyelids should be held away from the eyeball to ensure thorough rinsing

If eye irritation persists seek medical attention After ingestion

DO NOT induce vomiting Wash out mouth with water and give plenty of water to drink (at least 300 ml.) Obtain medical advice if necessary.

5.1 Extinguishing Media

5.1.1 Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment

5.1.2 Unsuitable extinguishing media None

5.2 Special hazards arising from the substance or mixture None

5.3 Advice for firefighters No special precautions required

6.1 Personal Precautions

6.1.1 For non emergency personnel Keep dust levels to a minimum Wear suitable protective equipment ( see Section 8)

6.2 Environmental Precautions Prevent uncontrolled discharges into the environment (rivers, water courses, sewers etc.) Avoid any mixture with an acid into sewer/drains (CO2 gas formation)

6.3 Methods for containment and clean up In all cases avoid dust formation Use vacuum suction, or shovel into bags Collect as much as possible in a suitable clean container, preferably for re use, otherwise for disposal (See

Section 13)

6.4 Reference to other sections For more information on exposure controls/personal protection or disposal considerations, please see

section 8 and 13

7.1 Precautions for Safe Handling

7.1.1 Protective measures Keep dust levels to a minimum Ensure adequate ventilation Wear protective equipment (see Section 8.2) Keep away incompatible materials

7.1.2 Advice on general occupational hygiene Good personal and housekeeping practices to be used No drinking, eating or smoking at the workplace

7.2 Conditions for safe storage, including any incompatibilities Store in a dry place

5. FIREFIGHTING MEASURES

6. ACCIDENTAL RELEASE MEASURES

7. HANDLING AND STORAGE


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Store in original, closed and correctly labelled container

Store away from incompatible materials

8.1 Control Parameters

8.1.1 Occupational Exposure Standards Not listed by H&SE (Guidance Note EH40) or ACGIH Recommended Limits: WEL 10mg/m 3 (total dust) (8hr TWA)

4mg/m 3 (respirable dust) (8hr TWA)

8.1.2 DNELs/PNEC

Exposure route DNELs (local effects)

of relevance Workers General population Long term Acute Long term Acute

Inhalation 10 mg/m 3

PNEC :

The lowest L(E)C50 value is > 100 mg/l (48 h EC50 is 200 mg/l in daphnids (Ceriodaphnia sp)). Therefore sodium carbonate need not be classified according to Directive 67/548/EEC and EU Classification, Labelling and Packaging of Substances and Mixtures (CLP) Regulation (EC) No. 1272/2008

Environmental Classification is not warranted

8.2 Exposure Controls

8.2.1 Appropriate engineering controls provide appropriate exhaust ventilation at places where dust is formed apply technical measures to comply with the occupational exposure limits

8.2.2 Personal protection

8.2.2.1 Eye/face protection wear eye/face protection rated to protect eyes against dust (EN166) eg.safety eye shields with dust

protection, goggles or face visor 8.2.2.2 Hand protection

wear suitable chemical resistant protective gloves, that comply with the specification of EC Directive 89/686/EEC and the related standard EN374. Suitable materials, Neoprene or natural rubber

8.2.2.3 Skin/body protection dust impervious protective suit rubber or plastic safety boots

8.2.2.4 Respiratory protection in the case of high dust levels wear suitable respiratory protective equipment eg.dust mask or

respirator, that conform to national/international standard, EN143. Recommended filter tpe P2

8.3 Environmental Exposure Controls contain any spillage avoid discharges to the environment dispose of any rinse water in accordance with local and

anexo iv hojas de seguridad

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