safety data sheet...cleantechs hand cleaning gel page: 5/13 7. handling and storage 7.1 precautions...

SAFETY DATA SHEET

Page: 1/13

1. IDENTIFICATION OF THE PRODUCT/COMPANY UNDERTAKING

1.1 Product Identifiers

Product NameBrand

CLEANTECHS HAND CLEANING GEL CLEANTECHS

1.2 Relevant Identified Uses/Uses Advised Against

Identified Uses Hand sanitizer

Uses Advised

Against

No specific uses advised against are identified.

1.3 Details of the Supplier of the Safety Data Sheet

Supplier

Company

Address

Telephone

Fax

Web Address

CLEANTECHSYeniBosna Merkez Mah.Çınar cad.No:8 Bahçelievler-İstanbul - Türkiye

08504802211

http://cleantechs.net/E-mail Address [email protected]

Person responsible for the safety data sheet

Name

Telephone

E-mail

Manufacturer

Company

Address

Telephone

Fax

Web Address

Adem Ademoğlu+90 0 543 598 82 [email protected]

CLEANTECHSYeniBosna Merkez Mah.Çınar cad.No:8 Bahçelievler-İstanbul - Türkiye

08504802211

http://cleantechs.net/E-mail Address [email protected]

1.4 Emergency Telephone Numbers

Supplier Company Emergency +90 0 543 598 82 10

CLEANTECHS

HAND CLEANING GEL

SDS No: 131093

Version: 01

Date of Issue: 10.04.2020

Revision Date: First issue

According to Regulation No

1907/2006/EC (REACH), Annex

II, as amended by Commission

Regulation (EU) 2015/830 and

Regulation No 1272/2008/EC

(CLP)

http://www.greenx.com.tr/

mailto:[email protected]


http://www.greenx.com.tr/


SAFETY DATA SHEET

According to Regulation No 1907/2006/EC (REACH), Annex II, as amended by

Commission Regulation (EU) 2015/830 and Regulation No 1272/2008/EC (CLP)

SDS No: 131093 Version: 01

Date of Issue: 10.04.2020 Revision Date: First issue

CLEANTECHS HAND CLEANING GELPage: 2/13

2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification according CLP regulation (Regulation (EC) No. 1272/2008, as amended)

Flammable liquids, Category 2; H225

Eye irritation, Category 2; H319

NOTE: See Section 4.2 for symptoms and Section 11 for more detailed information on health effects.

2.2 Label elements

2.2.1 Labeling according CLP regulation (Regulation (EC) No. 1272/2008, as amended)

Hazard symbols

DANGER

Hazard statements

H225 Highly flammable liquid and vapour.

H319 Causes serious eye irritation.

EUH208 Contains 2,2',2''-nitrilotriethanol and perfume. May produce an allergic reaction.

Precautionary statements

P102 Keep out of reach of children.

P210 Keep away from heat/sparks/open flames/hot surfaces – No smoking.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P337+P313 If eye irritation persists: Get medical advice/attention.

P403+P235 Store in a well ventilated place. Keep cool.

P501 Dispose of container only when totally empty.

2.3 Other hazards

No additional hazards are known except those derived from the labeling.

Hazard-determining components of labeling: Ethanol

This mixture does not meet the PBT and vPvB criteria of REACH Regulation, Annex XIII.

3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances

Not applicable, product is a mixture.

3.2 Mixtures

INGREDIENT IDENTIFIERS % CLASSIFICATION

Ethanol (96%)

EINECS1 NO: 200-578-6

CAS2 NO: 64-17-5

INDEX NO3: 603-002-00-5

INCI NAME: Alcohol

REACH REGIST. NO:

1-2119457610-43-XXXX

<70 DANGER

Flammable liquids, Cat. 2; H225

Eye irritation, Cat. 2; H319

Glycerol (98%)

EINECS NO: 200-289-5

CAS NO: 56-81-5

INDEX NO: -

INCI NAME: Glycerin

REACH REGIST. NO:

01-2119471987-18-XXXX

≤1 Not classified as hazardous according to the EC Regulation

1272/2008/EC

SAFETY DATA SHEET






2-Propenoic acid, homopolymer


CAS NO: 9003-01-4

INDEX NO: -

INCI NAME: Polyacrylic acid

REACH REGIST. NO:

01-2120754771-50-XXXX

≤0,5

DANGER

Acute toxicity, Oral, Cat. 4; H302

Serious eye damage, Cat. 1, H318

STOT, Single exposure, Cat. 3; H335

Hazardous to the aquatic environment, Acute, Cat. 1; H400

Hazardous to the aquatic environment, Chronic, Cat. 2; H411

2,2',2''-nitrilotriethanol


CAS NO: 102-71-6

INDEX NO: -

INCI NAME: Triethanolamine

REACH REGIST. NO:

01-2119486482-31-XXXX

<0,5

WARNING

Skin irritation, Cat. 2; H315

Skin sensitization, Cat. 1; H317

Serious eye irritation, Cat. 2; H319

STOT, Single exposure, Cat. 3; H335

Fragrance

EINECS NO: -

CAS NO: -

INDEX NO: -

INCI NAME: Parfum

REACH REGIST. NO: -

<0,5

WARNING

Skin irritation, Cat. 2; H315

Skin sensitization, Cat. 1; H317

Serious eye irritation, Cat. 2; H319

Hazardous to the aquatic environment, Chronic, Cat. 2; H411

NOTE: Any impurities required to be classified or that affect the classification of the product: None

See Section 16 for the full text of the H statements declared above.

4. FIRST AID MEASURES

4.1 Description of first aid measures

Following inhalation Remove from contaminated area, lay patient down, keep warm and rested.

Obtain medical attention.

In case of skin contact Wash with plenty of water and soap.

If irritation occurs, continues and/or worsens, stop using the product, consult a physician

In case of eye contact Wash out immediately with fresh running water for several minutes.

Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the

eyelids by occasionally lifting the upper and lower lids, seek medical attention if irritation occurs.

If swallowed Do not induce vomiting, if the person is conscious, wash out mouth thoroughly with water.

Never give anything to a person showing signs of being sleepy or with reduced awareness; i.e.

becoming unconscious. Obtain medical attention.

4.2 Most important symptoms and effects, both acute and delayed

Inhalation May be harmful when inhaled, may cause irritation of the respiratory tract.

Ethanol [CAS# 64-17-5]:

At concentrations above 50% may cause local mucosal wounds due to dehydration and

precipitation of albumin. Rhinitis (nasal membrane inflammation) may occur. Cough, headache,

fatigue may be seen.

Skin Although no adverse effects are expected, the product contains ingredients which may cause

sensitization by skin contact, people who are sensitive to chemicals should be careful when using

the product.

Eyes Causes serious eye irritation. Burning sensation, increased lacrimation and redness may be seen.

Ingestion May be harmful if swallowed. May cause irritation in the gastrointestinal tract. Nausea, vomiting

and diarrhea may also be seen.

4.3 Indication of any immediate medical attention and special treatment needed

Central nervous system depression, narcosis, nausea, vomiting may be seen when swallowed.

Thoroughly observe the patient and treat symptomatically.

SAFETY DATA SHEET






5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing

media

Use alcohol resistant foam, carbon dioxide (CO2), dry chemical and water spray.

Unsuitable extinguishing

media

Do not use water jet since it may expand the fire.

5.2 Special hazards arising from the substance or mixture

Hazardous combustion

products

Upon burning toxic fumes of carbon monoxide (CO), carbon dioxide (CO2) and various

hydrocarbons may be emitted.

Unusual fire & explosion

hazards

Vapours may travel long distances toward sources of ignition (flash back).

Closed containers may rupture violently and suddenly when exposed to fire or excessive heat for a

sufficient period of time.

5.3 Advice for firefighters

Special firefighting

procedures

Do not approach containers suspected to be hot.

Cool fire exposed containers with water spray from a protected location.

If safe to do so, remove containers from path of fire.

Water used to extinguish fire should not enter drainage systems, soil, or stretches of water.

Contaminated fire-extinguishing water must be disposed of in accordance with the regulations

issued by the appropriate local authorities.

Special protective

equipment for firefighting

Use self-contained breathing apparatus, and full protective clothing in case of fire.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

6.1.1 For non-emergency personnel

Ensure adequate ventilation, avoid inhalation of vapors/fumes and contact with eyes.

Remove all sources of ignition.

Prevent further leakage or spillage if safe to do so, keep away from incompatible products.

Evacuate the area.

6.1.2 For emergency responders

Evacuate personnel to safe areas.

Remove all sources of ignition.

Ensure adequate ventilation, avoid inhalation of vapors/fumes and contact with eyes.

Consider exposure limits and use personal protective equipment referred in Section 8.

6.2 Environmental precautions

Try to prevent the material from entering drains or water courses.

Spillages or uncontrolled discharges into watercourses must be alerted to the Environmental Agency or other appropriate

regulatory body.

6.3 Methods and materials for containment and cleaning up

Remove with an inert non-combustible absorbent (like vermiculite, sand, cat litter) and dispose of absorbent as hazardous waste.

Wash the contaminated surface with water.

Dispose of waste material according to local, state and federal regulations.

6.4 Reference to other sections

See Section 7 for safe handling.

See Section 8 for exposure controls and personal protection.

See Section 13 for disposal considerations.

SAFETY DATA SHEET






7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Use ex-proof equipment when handling.

Ethanol vapors may form explosive mixtures with air (Lower Explosion Limit 3,1% v/v, Upper Explosion Limit 27,7% v/v), do

not work in confined spaces and fume hoods with unknown performance.

The product is flammable; do not spray directly on fire or hot surfaces.

Handle in accordance with the general rules of occupational hygiene and safety.

Avoid inhalation of vapours, wear protective clothing when risk of exposure occurs, ensure adequate ventilation.

Do not eat, drink or smoke in areas where the material is used, wash thoroughly after handling the material.

Remove contaminated clothing and protective equipment before entering eating areas.

7.2 Conditions for safe storage including any incompatibilities

Store in a cool, dry, well-ventilated area protected from environmental extremes.

Protect from heat, flames and sparks, extremes of temperature and direct sunlight.

Store away from food, drink and animal feeding stuffs and foodstuff containers.

Containers which are opened must be carefully resealed and kept upright to prevent leakage.

All equipment must be grounded - bonded when transferring product in order to avoid static discharge from the equipment, and

subsequent possible fire.

Storage class 3 (Flammable liquid substances), only substances of the same storage class should be stored together.

Observe manufacturer's storing and handling recommendations, take all precautions mentioned in this document.

Store away from alkali metals, ammonia, oxidizing agents and peroxides.

Observe the national and local regulations concerning handling and storage.

7.3 Specific end use(s)

The identified uses for this product are given in Section 1.2.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

8.1.1 Occupational exposure limits


MAK4: 1900 mg/m3 (TRGS5 900 1993)

TLV6: 1880 mg/m3 (ACGIH7 1991-1992)

2,2',2''-nitrilotriethanol [CAS# 102-71-6]:

TLV: 5 mg/m3 (UK HSE EH40, 1993)

DNEL8/DMEL9 values:

Component Route of exposure Personnel Exposure frequency Limit value Remarks

Ethanol

[CAS# 64-17-5]

Inhalation General population Short Term (systemic) 950 mg/m3 DNEL

Inhalation General population Long Term (systemic) 114 mg/m3 DNEL

Oral General population Long Term (systemic) 87 mg/kg DNEL

Dermal General population Long Term (systemic) 206 mg/kg DNEL

Inhalation Professional Long Term (systemic) 1900 mg/m3 DNEL

Inhalation Professional Short Term (systemic) 950 mg/m3 DNEL

Dermal Professional Long Term (systemic) 343 mg/kg DNEL

Glycerol

[CAS# 56-81-5]

Inhalation General population Long term (local) 33 mg/m3 DNEL

Oral General population Long Term (systemic) 229 mg/kg DNEL

Inhalation Professional Long term (local) 56 mg/m3 DNEL

2,2',2''-nitrilotriethanol

[CAS# 102-71-6]

Inhalation Professional Long Term (systemic) 5 mg/m3 DNEL

Dermal Professional Long Term (systemic) 6,3 mg/kg DNEL

SAFETY DATA SHEET






PNEC10 values:

Component Environmental compartment Limit value

Ethanol

[CAS# 64-17-5]

Fresh water 0,96 mg/l

Marine water 0,79 mg/l

Soil 0,63 mg/kg

Wastewater 580 mg/l

Sediment (fresh water) 3,6 mg/kg

Glycerol

[CAS# 56-81-5]

Fresh water 0,885 mg/l

Marine water 0,0885 mg/l

Soil 0,141 mg/kg

8.2 Exposure controls

8.2.1 Process conditions/Engineering measures

Handle in accordance with good industrial hygiene and safety practice, wash hands before breaks and at the end of workday.

Use closed apparatus if possible.

If release of the substance cannot be prevented, then it should be suctioned off at the point of exit.

Ensure adequate ventilation, do not breathe vapors, consider emission limit values, use ex-proof ventilation equipment.

Label containers clearly, do not leave containers open.

The substance must not be present at workplaces in quantities above that required for work to be progressed.

Wash thoroughly after using product, wash hands before eating or drinking.

8.2.2 Personal protective equipment

Respiratory protection

Not necessary under conditions of normal use.

In case of emergency, conditions like insufficient ventilation or unintentional release of the substance, wear

respirators with type A11 filter (Color code: Brown) complying with EN14112.

Eye/Face protection


In an emergency or during manufacture wear goggles or glasses with side protection complying with EN166.13

Hand protection

Not necessary under conditions of normal use. Wear butyl rubber protective gloves (Thickness: 0,7 mm, Break

through time: > 480 min) complying with EN 37414 during manufacture.

Body protection


During manufacture, wear flame retardant antistatic protective clothing complying with EN 34015

8.2.3 Environmental exposure controls

Avoid release to the environment, try to prevent the material from entering drains or water courses.

Spillages or uncontrolled discharges into watercourses must be alerted to the Environmental Agency or other appropriate

regulatory body.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Physical State (@ STP) Liquid (gel)

Color Colorless

Odor Characteristic

Flash point (°C) ~ 21,0 - 22,5

Solubility in water Miscible

9.2 Other information

Partition coefficient n-Octanol/Water (log Po/w) Not determined

SAFETY DATA SHEET






10. STABILITY AND REACTIVITY

10.1 Reactivity

Not reactive under normal conditions of use.

10.2 Chemical stability

The product is chemically stable under standard ambient conditions (room temperature).

10.3 Possibility of hazardous reactions

Closed containers may rupture violently and suddenly when exposed to fire or excessive heat for a sufficient period of time.

Forms an explosive mixture with air due to its low flash point.

May give hazardous reactions with alkali/alkaline earth metals, fluorine, reducing agents, acetylene bromide, acetylene chloride,

barium perchlorate, bromine trifluoride, caesium oxide, chromium trioxide, chromyl chloride, oxiran, iodine heptafluoride,

potassium tert.-butoxide, lithium hydride, phosphorus trioxide, platinum black, nitric acid/potassium permanganate, acid

anhydrides, acids, uranium hexafluoride, zirconium(IV)-chloride, zirconium(IV)-iodide

Risk of explosion in contact with:

Chlorine, strong oxidizing agents, nitric acid, calcium hypochlorite, halogen oxides, disulphur difluoride, acetic anhydride + salts

+ acids, isocyanates, potassium, potassium dioxide, potassium permanganate/sulfuric acid, sodium, sodium hypochloride, sodium

peroxide, perchlorates, peracids, perchloro nitrile, mercury nitrate, oxygen (liquid), sulfuric acid + hydrogen peroxide, silver/nitric

acid, silver nitrate, silver nitrate/ammonia, silver oxide/ammonia, nitrogen dioxide, conc. hydrogen peroxide

10.4 Conditions to avoid

Heat, flames and sparks, extremes of temperature and direct sunlight.

Vapours may travel long distances toward sources of ignition (flash back).

Closed containers may rupture violently and suddenly when exposed to fire or excessive heat for a sufficient period of time.

10.5 Incompatible materials

Alkali metals, ammonia, oxidizing agents and peroxides.

10.6 Hazardous decomposition products

Upon burning toxic fumes of carbon monoxide (CO), carbon dioxide (CO2) and various hydrocarbons may be emitted.

11. TOXICOLOGICAL INFORMATION

During normal use primary route of exposure is by skin contact.

The information given in this section does not belong to the product itself but derived from the toxicity data of its ingredients.

11.1 Information on toxicological effects

Acute toxicity Ethanol [CAS# 64-17-5]:

LD50 Oral: 7060 mg/kg (Rat)16

LD50 Dermal: 12800 mg/kg (Rabbit)

LC50 Inhalation: 20000 ppm (10 hours, Rat)

Glycerol [CAS# 56-81-5]:


LD50 Dermal: 10000 mg/kg (Rabbit)18

2-Propenoic acid, homopolymer [CAS# 9003-01-4]:



LD50 Oral: 5530 mg/kg (Mouse)20

LD50 Dermal: 22500 mg/kg (Rabbit)21

Skin Corrosion/Irritation No test results available for the product.

Eye Corrosion/Irritation Causes serious eye irritation.

Respiratory or Skin

Sensitisation

Contains ingredients which may cause sensitization by skin contact. May produce an

allergic reaction.

SAFETY DATA SHEET







There is no information about sensitizing effects.


May cause allergic contact dermatitis in some people.22

Mutagenicity Based on available data, the classification criteria are not met.

Ethanol [CAS# 64-17-5];

Mutagenic effects were definitely determined in animal experiments, however the

corresponding dosages were already distinctly toxic. Therefore, the germ cell-mutagenic

potential is considered to be negligible under these conditions.


In various bacterial test systems, in cell cultures and in a micronucleus test on mice, did

not show any genotoxic activity.23 Nevertheless, a mutagenic effect was not excluded as a

consequence of exposure to Triethanolamine in a mixture with diethanolamine and nitrite

as contaminants (formation of the nitrosamine).

Carcinogenicity This product contains a component which is identified as carcinogen by NTP,24 IARC25 or

OSHA26 in case of long-term intake of large amounts in the form of alcoholic beverages.


IARC Group 1: Carcinogenic to humans (Only for the ethanol in alcoholic beverages)


Not classifiable as to its carcinogenicity to humans (IARC Group 3).

In a two-year study, female B6C3F1 mice were exposed to Triethanolamine via skin (100,

300, 1000 mg/kg, 5 days a week). Carcinogenic activity has been observed in the form of

increased hepatocellular adenoma. It was concluded that this effect is likely caused by

choline-depletion.

IARC Group 1: Carcinogenic to humans. Long term intake of large amounts in the form of alcoholic

beverages can cause tumors in the oral cavity/pharynx, larynx, gullet, liver and probably also in the

breast and bowels.

IARC Group 3: This category is used most commonly for agents, mixtures and exposure

circumstances for which the evidence of carcinogenicity is inadequate in humans and inadequate or

limited in experimental animals.

Fertility, Reproductive and

Developmental Toxicity

(Teratogenicity)

Based on available data, the classification criteria are not met.

Ethanol [CAS# 64-17-5];

Reduced fertility and an influence on the sex hormone level for humans and in animal

experiments were clearly detected only following oral intake of high doses. Developmental-

toxic effects (alcohol embryopathy) following oral intake of high doses has also been clearly

demonstrated.


In the dermal subchronic studies, neither rats nor mice showed any significant changes to

motility, morphology and quantity of the sperm or the estrus cycle.

Specific Target Organ Toxicity

-Single exposure


Specific Target Organ Toxicity

-Repeated exposure


Aspiration hazard Based on available data, the classification criteria are not met

12. ECOLOGICAL INFORMATION

General information

The information given in this section does not belong to the product itself but derived from the eco-toxicity data of its ingredients.

12.1 Toxicity


Acute Fish Toxicity (LC50, 96 hours): 11000 mg/l (Alburnus alburnus)27

SAFETY DATA SHEET






Acute Aquatic Invertebrates Toxicity (LC50, 48 hours): 9268-14221 mg/l (Daphnia magna)28

Acute Aquatic Invertebrates Toxicity (EC50, 48 hours): 9950 mg/l (Daphnia obtusa)29

Chronic Aquatic Invertebrates Toxicity (LC50, 9 days): 454 mg/l (Daphnia magna)30


Acute Fish Toxicity (LC50, 96 hours): 68100 mg/l31

Acute Aquatic Invertebrates Toxicity (EC50, 24 hours): >10000 mg/l (Daphnia magna)32


Acute Fish Toxicity (LC50, 96 hours): 11800 mg/l33

Acute Aquatic Invertebrates Toxicity (EC50, 24 hours): 1850 mg/l (Daphnia magna)34

Acute Aquatic Plants Toxicity (EC50, 72 hours): 216 mg/l (Scenedesmus subspicatus)35

Acute Aquatic Crustaceans Toxicity (EC50, 48 hours): 610 mg/l36

12.2 Persistence and degradability


Degrades by reaction with photochemically produced hydroxyl radical. The half-life of this reaction is estimated to be 10 days.37

74% biodegration under aerobic conditions after 5 days.38

COD: ~1700 mg/g

BOD5/COD: 0,57


Readily biodegradable (63% in 14 days, Aerobic)39

BOD5: 700 mg O2/l

COD: 1160 mg/g


Readily biodegradable (82% in 8 days).40 Due to its high solubility in water (Koc: <1x10-7) it is not expected to be adsorbed by

soil.41 Degrades photochemically by the catalization of OH- radicals which are formed photochemically in the atmosphere.42 Half-

life of photochemical degradation is 4 hours.43

BOD5: 0,17 mgO2/l COD: 1,5 mg/g

12.3 Bio accumulative potential


Does not bio-concentrate in aquatic organisms.44

Log Pow: -0,3


Does not bio accumulate (LogPow: -2,66 ‒ -2,47 (Calculated value)45


Does not bio accumulate.46

Log Pow: -147 BCF: <3,9

12.4 Mobility in soil


The chemical will volatilize from soil surface and partition in air.48

Not expected to be absorbed by soil because of its low log Pow value.49

12.5 Results of PBT and vPvB assessment


Does not meet any of the criteria for Persistent, Bioaccumulative and Toxic (PBT) substances or the very Persistent, very

Bioaccumulative (vPvB) category.50







SAFETY DATA SHEET






12.6 Other adverse effects

No additional information available.

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product Dispose of in accordance with appropriate local regulations.

Legislation addressing waste disposal requirements may differ by country, state and/or

territory.

Each user must refer to laws operating in their area, in some areas, certain wastes must be

tracked.

Do not allow wash water from cleaning or process equipment to enter drains, it may be

necessary to collect all wash water for treatment before disposal.

In all cases disposal to sewer may be subject to local laws and regulations and these should be

considered first, where in doubt contact the responsible authority.

Recycle wherever possible or consult manufacturer for recycling options.

Consult State Land Waste Management Authority for disposal.

According to the European Waste Catalogue (EWC53), waste codes are not product specific

but application specific, Waste Codes should be assigned by the user based on the application

in which the product is used.

The final classification has to be done together with the local waste disposal

company/authority.

Contaminated packaging Empty containers may contain hazardous residue.

Never weld, cut or grind empty containers.

Empty containers may be rinsed with water.

Dispose of packaging only when totally empty.

14. TRANSPORT INFORMATION

UN 1170 ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION), 3, III (D/E)

TRANSPORT SYMBOL CLASS PACK.

GROUP

CLASS.

CODE

LABEL.

NO

HIN

NO54 EmS

MARINE

POLLUTANT

ADR55/RID56

(Road /

Railroad)

3 III F1 3 30 - -

ADNR57

(River) 3 III - 3 - - -

IMDG58

(Marine) 3 III - 3 - F-E;S-D

YES

ICAO59/IATA60

(Airways) 3 III - 3 - - -

MARPOL 73/78 Annex II 61 / Carriage of chemicals in bulk (IBC62 Code): IBC03

Special provisions: 144, 601

Limited Quantity/Excepted Quantity: 5 l/E1

DGR Passenger Aircraft/DGR Cargo Aircraft: 60 l/220 l

Tunnel Restriction C: D/E

SAFETY DATA SHEET






15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV (List of substances

subject to authorization- Substances of very high concern)

None of the components are listed Annex XVII

EU Regulation (EC) No. 1907/2006 (REACH) Annex XVII (Restrictions on

the manufacture, placing on the market and use of certain dangerous

substances, mixtures and articles)


Annex XVII, Point 3, 40

Directives 67/548/EWG and 99/45/EG No identification according to criteria needed

EU Regulation (EC) No 2037/2000

(Ozone Depleting Substances)

Not applicable

Regulation (EC) No 850/2004

(Persistent Organic Pollutants)

Not applicable

Regulation (EC) No 689/2008

(Export and import of dangerous substances)

Not applicable

Directive 2002/95/EC (RoHS) Not applicable

Directive 2002/96/EC (WEEE) Not applicable

Directive 1999/13/EC (VOC) Not applicable

Directive 2012/18/EU (SEVESO III)

(Control of major-accident hazards involving dangerous substances)


Annex I Part 1 Section: P5a

Annex I Part 1 Section: P5b

Annex I Part 1 Section: P5c

EU Regulation (EC) No 528/2012

(Biocidal Products Regulation)

Applicable

German regulations concerning the classification of hazards for water (WGK63) No information available

15.2 Chemical safety assessment

A Chemical Safety Assessment has not been carried out.

16. OTHER INFORMATION

Revision comments

This safety datasheet, dated 10.04.2020, is the first issue and complies with the requirements of Regulation 1907/2006/EC

(REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 and Regulation No 1272/2008/EC (CLP).

Full text of H-Statements referred to under Section 3

H225 Highly flammable liquid and vapour.

H302 Harmful if swallowed.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

H400 Very toxic to aquatic life.

H411 Toxic to aquatic life with long lasting effects.

Any abbreviations and acronyms used in this document: See footnotes

SDS prepared by

Ayşenur TOROSLU – Chemical Engineer, MSc.

[email protected]

Competent Person Accreditation No: TSE GBF-A-0-2731 (09.02.2018 – 09.02.2021)

Legal disclaimer

The purpose of the above information is to describe the products only in terms of health and safety requirements. The information

given should not, therefore, be construed as guaranteeing specific properties or as specification. Customers should satisfy

themselves as to the suitability and completeness of such information for their own particular use. The information provided in

this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication.


SAFETY DATA SHEET






The above information relates only to the specific material(s) designated herein and may not be valid for such material(s) used in

combination with any other materials or in any process or if the material is altered or processed, unless specified in the text.

The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and

release and is not to be considered a warranty or quality specification. Due to the many factors outside our control when using

this product, we cannot accept liability for any injury, accident, loss or damage caused through its use.

1 EINECS No: European Inventory of Existing Commercial Chemical Substances. 2 CAS No: Chemical Abstracts Service. 3 INDEX No European number attributed to dangerous chemical substances in accordance with European regulations on classifying, packaging and labeling dangerous

chemical substances. 4 MAK: Maximum allowable concentration. 5 TRGS: Die Technischen Regeln für Gefahrstoffe 6 TLV: Threshold Limit Value 7 ACGIH: American Conference of Governmental Industrial Hygienists 8 DNEL: Derived No-Effect Level 9 DMEL: Derived Minimal Effect Level 10 PNEC: Predicted No-Effect Concentration 11 Type A Filter: Filter for organic vapors and solvents. 12 EN141: European standard for respiratory protective devices. 13 EN 166:European standard for eye and face protection 14 EN 374: European standard for gloves giving protection from chemicals and micro-organisms. 15 EN340: European standard for protective clothing: General requirements 16 Ref: Toxicology and Applied Pharmacology. Vol. 16, Pg. 718, 1970. 17 Ref: Federation Proceedings, Federation of American Societies for Experimental Biology. Vol. 4, Pg. 142, 1945. 18 Ref: BIOFAX Industrial Bio-Test Laboratories, Inc., Data Sheets. Vol. 9-4/1970. 19 Ref: Angewandte Chemie, International Edition in English. Vol. 14, Pg. 94, 1975. 20 Ref: National Technical Information Service. Vol. OTS0516797. 21 Ref: Union Carbide Data Sheet. Vol. 3/18/1965. 22 Ref: OSHA. 23 Ref: IARC - International Agency for research on cancer: Monographs on the evaluation of carcinogenic risks to humans WHO, Lyon; Serie. 24 NTP: National Toxicology Program 25 IARC: The International Agency for Research on Cancer 26 OSHA: Occupational Safety and Health Association 27 Ref: Bengtsson, B.E., L. Renberg, and M. Tarkpea 1984. Molecular Structure and Aquatic Toxicity - an Example with C1-C13 Aliphatic Alcohols. Chemosphere

13(5/6):613-622. 28 Ref: Takahashi, I.T., U.M. Cowgill, and P.G. Murphy 1987. Comparison of Ethanol Toxicity to Daphnia magna and Ceriodaphnia dubia Tested at Two Different

Temperatures: Static Acute Toxicity Test Results. Bull.Environ.Contam.Toxicol. 39(2):229-236; Ziegenfuss, P.S., W.J. Renaudette, and W.J. Adams 1986. Methodology for

Assessing the Acute Toxicity of Chemicals Sorbed to Sediments: Testing the Equilibrium Partitioning Theory. In: T.M.Poston and R.Purdy (Eds.), Aquatic Toxicology and

Environmental Fate, 9th Volume, ASTM STP 921, Philadelphia, PA :479-493. 29 Ref: Barera, Y., and W.J. Adams 1983. Resolving Some Practical Questions About Daphnia Acute Toxicity Tests. In: W.E.Bishop (Ed.), Aquatic Toxicology and Hazard

Assessment, 6th Symposium, ASTM STP 802, Philadelphia, PA :509-518; Rossini, G.D.B., and A.E. Ronco 1996. Acute Toxicity Bioassay Using Daphnia obtusa as a Test

Organism. Environ.Toxicol.Water Qual. 11(3):255-258. 30 Ref: Cowgill, U.M. and Milazzo, D.P., The Sensitivity of Ceriodaphnia dubia and Daphnia magna to Seven Chemicals Utilizing the Three-brood Test, Arch. Environ.

Contam. Toxicol., 20, 211-217. 31 Ref: Mayer, F.L.Jr., and M.R. Ellersieck 1986. Manual of Acute Toxicity: Interpretation and Data Base for 410 Chemicals and 66 Species of Freshwater Animals. Resour.

Publ.No.160, U.S. Dep.Interior, Fish Wildl. Serv., Washington, DC: 505 p. (USGS Data File). 32 Ref: Bringmann, G. & Kuehn, R., Z. Wasser Abwasser Forsch., 15, 1977, 161-166. 33 Ref: Geiger, D.L., L.T. Brooke, and D.J. Call 1990. Acute Toxicities of Organic Chemicals to Fathead Minnows (Pimephales promelas), Volume 5. Ctr.for Lake Superior

Environ.Stud., Univ.of Wisconsin-Superior, Superior, WI :332 p. 34 Ref: Bringmann, G., Kuhn, R., Z. Wasser Abwasser Forsch., 1982, V15, N1, P6-11, (Ger-Eng Summary). 35 Ref: Amann, W. And Stainhauser, Umweltforshungsplan des BMI, UFOPLAN, Nr. 102 05 308, im Auftrag des Umweltbundesamtes, Mai 1986. 36 Ref: Warne, M.S.J., and A.D. Schifko 1999. Toxicity of Laundry Detergent Components to a Freshwater Cladoceran and Their Contribution to Detergent Toxicity.

Ecotoxicol.Environ.Saf. 44(2):196-206. 37 Ref: Campbell, I. M. et al., 1976, Rate Constants for Reactions of Hydroxyl Radicals with Alcohol Vapours at 292 K. Chem. Phys. Letters 38, 362-364. 38 Ref: Price, K.S. et al., 1974, Brine Shrimp Bioassay and Seawater BOD of Petrochemicals, J. Water Pollut. Control Fed., 46,63-77. 39 Ref: MITI Japan, 1992: Biodegradation and bioaccumulation data of existing chemicals based on the CSCL Japan, ed. By chemicals inspection & testing institute Japan, 2-

42. 40 Ref: Gerike, P., Fishcer, W. K., A Correlation Study of Biodegrability Determinations with Various Chemical in Various Tests. ECETOX. Environ. Safety, 1979, V3, p

159-73.41 Ref: Hine, J., Moorkerjee, P. K., J. Org. Chem., 40, 292-298, 1975. 42 Ref: Atkinson, R., Inter. J. Chem. Kinet., 19, 799-828, 1987. 43 Ref: Atkinson, R., Inter. J. Chem. Kinet., 19, 799-828, 1987. 44 Ref: OECD Ecological Categorization Results from the Canadian Domestic Substance List. 45 Ref: Criteria document for an occupational exposure limit value of: Glycerol, SEG/CDO/30, 1992. 46 Ref: OECD Ecological Categorization Results from the Canadian Domestic Substance List. 47 Ref: Recommended value of LOG KOW Databank. 48 Ref: HSDB (1993) Hazardous Substances Databank, US National Library for Medicine, Silver Platter, Chem-Bank, October 1993. 49 Ref: Handbook of Environmental Fate and Exposure Data for Organic Chemicals (1990). Eds Howard, P.H. et al, Lewis Publishers, Michigan. 50 Ref: ECHA, European Chemicals Agency, Ethanol 51 Ref: ECHA, European Chemicals Agency, Glycerol 52 Ref: ECHA, European Chemicals Agency, 2,2',2''-nitrilotriethanol 53 EWC: European Waste Catalogue 54 HIN NO: Hazard Identification Number. 55 ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.

SAFETY DATA SHEET






56 RID: Regulations Concerning the International Transport of Dangerous Goods by Rail. 57 ADNR: European Agreement Concerning the International Carriage of Dangerous Goods by Inland Waterways. 58 IMDG: International Maritime Code for Dangerous Goods. 59 ICAO: International Civil Aviation Organization. 60 IATA: International Air Transport Association. 61 MARPOL 73/78 Annex II: International Convention for the Prevention of Pollution from Ships, Annex II: Regulations for the Control of Pollution by Noxious Liquid

Substances in Bulk. 62 IBC Code: International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk 63 WGK: Wassergefährdungsklasse / Water hazard classification

safety data sheet...cleantechs hand cleaning gel page: 5/13 7. handling and storage 7.1 precautions...

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